[Federal Register Volume 59, Number 136 (Monday, July 18, 1994)]
[Unknown Section]
[Page 0]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 94-16542]
[[Page Unknown]]
[Federal Register: July 18, 1994]
_______________________________________________________________________
Part II
Department of Transportation
_______________________________________________________________________
Research and Special Programs Administration
_______________________________________________________________________
49 CFR Part 171, et al.
Hazardous Materials: Transportation of Dangerous Goods in International
Commerce; Proposed Rule
DEPARTMENT OF TRANSPORTATION
Research and Special Programs Administration
49 CFR Parts 171, 172, 173, 175, 176, 177, and 178
[Docket No. HM-215A; Notice No. 94-6]
RIN 2137-AC42
Implementation of the United Nations Recommendations,
International Maritime Dangerous Goods Code, and International Civil
Aviation Organization's Technical Instructions
AGENCY: Research and Special Programs Administration (RSPA), DOT.
ACTION: Notice of proposed rulemaking.
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SUMMARY: This notice proposes to amend the Hazardous Materials
Regulations to maintain alignment with corresponding provisions of
international standards. Because of recent changes to the International
Maritime Dangerous Goods Code (IMDG Code), the International Civil
Aviation Organization's Technical Instructions for the Safe Transport
of Dangerous Goods by Air (ICAO Technical Instructions), and the United
Nations Recommendations on the Transport of Dangerous Goods (UN
Recommendations), these proposed revisions are necessary to facilitate
the transport of hazardous materials in international commerce.
DATES: Comments must be received by September 6, 1994.
ADDRESSES: Address comments to the Dockets Unit (DHM-30), Research and
Special Programs Administration, U.S. Department of Transportation,
Washington, DC 20590-0001. Comments should identify the docket and be
submitted in five copies. Persons wishing to receive confirmation of
receipt of their comments should include a self-addressed stamped post
card. The Dockets Unit is located in Room 8421 of the Nassif Building,
400 Seventh Street, SW., Washington, DC. Public dockets may be reviewed
between the hours of 8:30 a.m. and 5 p.m. Monday through Friday, except
for Federal holidays.
FOR FURTHER INFORMATION CONTACT: Bob Richard, Assistant International
Standards Coordinator, telephone (202) 366-0586, Beth Romo or John
Gale, Office of Hazardous Materials Standards, telephone (202) 366-
8553, Hazardous Materials Safety, Research and Special Programs
Administration, U.S. Department of Transportation, 400 Seventh Street,
SW., Washington, DC 20590-0001.
SUPPLEMENTARY INFORMATION: On December 21, 1990, the Research and
Special Programs Administration (RSPA) published a final rule [Docket
HM-181; 55 FR 52402] which comprehensively revised the Hazardous
Materials Regulations (HMR), 49 CFR Parts 171 to 180, with respect to
hazard communication, classification, and packaging requirements, based
on the UN Recommendations. One intended effect of the rule was to
facilitate the international transportation of hazardous materials by
ensuring a basic consistency between the HMR and international
regulations.
The UN Recommendations are not regulations, but are recommendations
issued by the UN Committee of Experts on the Transport of Dangerous
Goods. These recommendations are amended and updated biennially by the
Committee of Experts and are distributed to nations throughout the
world. They serve as the basis for international modal regulations;
specifically the IMDG Code, issued by the International Maritime
Organization (IMO), and the ICAO Technical Instructions. In 49 CFR
171.12, the HMR authorize shipments prepared in accordance with the
IMDG Code if all or part of the transportation is by vessel, subject to
certain conditions and limitations. Offering, accepting and
transporting hazardous materials by aircraft, in conformance with the
ICAO Technical Instructions, and by motor vehicle either before or
after being transported by aircraft, are authorized in Sec. 171.11
(with certain exceptions).
On December 22, 1992, RSPA issued an interim final rule [Docket HM-
215; 57 FR 60738] amending Sec. 171.7 by incorporating the 1993-1994
edition of the ICAO Technical Instructions and Amendment 26 to the IMDG
Code. This rulemaking action authorized the use of the updated
international regulations, effective January 1, 1993. Amendment 26
promulgated numerous miscellaneous changes to the IMDG Code regarding
classification, labeling, packaging, and documentation. The 1993-1994
edition of the ICAO Technical Instructions contained amendments
relating to the seventh revised edition of the UN Recommendations, as
well as changes specific to air transportation.
The HMR, as revised under Docket HM-181, are largely based on the
sixth revised edition of the UN Recommendations. Selected provisions
from the seventh and eighth revised editions of the UN Recommendations
have been incorporated into the HMR under subsequent Docket HM-181
rulemaking actions. This NPRM seeks to more fully align the HMR with
the seventh and eighth revised editions of the UN Recommendations.
These proposed changes to the HMR will provide consistency with the
international air and sea transport requirements which, effective
January 1, 1995, will be aligned with the eighth revised edition of the
UN Recommendations.
While the changes introduced in the seventh and eighth revised
editions are extensive and in some cases very detailed, some of the
more significant changes are highlighted below.
Major changes in the seventh revised edition include:
--Definitions and criteria for the classification for gases were
revised, three subdivisions for gases were created, and the physical
states of gases were defined (e.g. liquefied gas, refrigerated
liquefied gas, etc). Gases listed in the UN Recommendations were
reclassified according to the agreed criteria. This effort will lead to
improved harmonization of U.S. and European requirements for the
classification of gases. These changes have already been incorporated
in the HMR in Subpart D of Part 173.
--Training requirements similar to those introduced into Part 172
Subpart H of the HMR under Docket HM-126F were added.
--Criteria for self-reactive substances assigned to Division 4.1 were
developed. The applicable test methods and criteria for self-reactive
substances are based on organic peroxide tests and criteria. New
generic proper shipping names for self-reactive substances were
introduced.
--A number of new ``Not Otherwise Specified'' (N.O.S.) proper shipping
names for substances in Class 4 and Division 5.1 were introduced.
Proposals for introducing the new names originated from efforts in
Europe to adopt the classification criteria for Class 4 and Division
5.1 into European road and rail regulations.
--Provisions defining conditions under which minor variations of tested
design-type packagings and requirements for ``V'' marked packagings
were added. Proposals to include these requirements originated in the
U.S. out of concern for the extent of testing that would otherwise be
required to certify packagings in accordance with the UN performance
standards. These provisions have already been adopted in the HMR in
Subpart M of Part 178.
Major changes in the eighth revised edition include:
--Numerous additional types of packaging were added to the explosive
packing instructions. This was largely a U.S. initiative arising from a
concern for the number of packagings that would otherwise have to be
authorized through exemptions.
--Provisions for elevated temperature materials were added. These
provisions are consistent with those adopted in the HMR under Docket
HM-198A.
--Criteria defining substances not able to sustain combustion were
included. The criteria for flammable liquids were amended so that
certain substances which meet the flash point criteria for flammable
liquids, but which are shown to be incapable of sustaining combustion,
are excepted from the Recommendations. This proposal was originally
proposed by the United Kingdom, which had similar provisions in its
domestic regulations.
--The criteria for corrosive substances were modified to reference the
Organization for Economic Cooperation and Development test protocol for
skin corrosivity and to clarify the extent of skin damage needed for
substances to be classified as corrosives. This was done in response to
initial proposals by Germany and the European chemical industry.
--A number of new N.O.S. proper shipping names for substances in Class
3, Division 6.1 and Class 8 were introduced. Proposals for introducing
the new names originated from efforts in Europe to adopt the
classification criteria for these hazard classes into European road and
rail regulations. Proper shipping names for petroleum products also
were updated as part of this effort.
--The Recommendations were amended to require that a package bear
labels representing each subsidiary risk of a material described using
an N.O.S. proper shipping name. This amendment was based on a proposal
made by the United Kingdom.
--The current Division 6.1 Packing Group III label was deleted. For a
more detailed discussion of the events leading to this decision, see
RSPA's Notice 93-21 under Docket HM-217 published in the Federal
Register on November 8, 1993 [58 FR 59224].
--Requirements for a freight container packing certificate were added
on the basis of a United Kingdom proposal seeking to bring the UN
Recommendations in line with the IMDG Code requirements.
--A number of substances meeting the criteria of Division 6.1 Packing
Group I toxic by inhalation were reclassified based on U.S. proposals.
--Provisions on the marking of steel drums used to transport dangerous
goods and provisions clarifying the requirements applicable to drum
reconditioners and remanufacturers were included on the basis of
proposals by the International Association for Drum Reconditioners
(ICDR).
--Detailed test criteria for lithium batteries were added. The new
provisions allow batteries with a higher lithium content to be excepted
from regulation if they meet new tests and criteria. The initial
proposal on this topic was introduced by Canada.
--Criteria under which air bag modules and air bag inflators could be
transported as Class 9 items were introduced. Proper shipping names for
these articles were also added. These changes were made on the basis of
U.S. proposals.
With a few exceptions described in this paragraph, the following
changes are proposed to ensure a basic consistency with many changes
contained in the seventh and eighth revised editions of the UN
Recommendations, the 1993-1994 and the 1995-1996 ICAO Technical
Instructions, and Amendments 26 and 27 of the IMDG Code. However,
proposed changes to the KEEP AWAY FROM FOOD label and placard
provisions will be addressed in a notice of proposed rulemaking under
Docket HM-217. In addition, proposed amendments to provisions for
Division 6.2 materials (infectious substances) will be addressed in a
separate rulemaking action under Docket HM-181G. Although the eighth
revised edition of the UN Recommendations adopted a quality assurance
program for the manufacture of performance packagings, RSPA is not
proposing a formal quality assurance program in this document. RSPA
believes that periodic retest provisions in Subpart M of Part 178 offer
an equivalent measure of quality assurance, but RSPA may propose
adoption of a more formal quality assurance program in a future
rulemaking action. Comments are solicited on this issue.
Summary of Proposed Regulatory Changes by Section
Part 171
Section 171.7. Various standards such as those issued by the
International Organization for Standardization (ISO) and the American
Society for Testing and Materials (ASTM) would be added or updated, and
the most current versions of the ICAO Technical Instructions, the IMDG
Code, and the UN Recommendations would be incorporated.
Section 171.8. New definitions for ``Asphyxiant gas,'' ``Gas'' and
``Siftproof packaging'' would be added, and definitions for ``Box,''
``Liquid,'' ``Overpack'' and ``Solid'' would be revised for consistency
with the seventh and eighth revised editions of the UN Recommendations.
The definition for ``UN standard packaging'' would be revised to
clarify that it applies to both U.S-manufactured and foreign-
manufactured packagings and to delete reference to Subparts L and M of
Part 178.
Section 171.11. Paragraph (d)(5) would be revised to include the
word ``toxic'' when referring to a poison.
Section 171.12. Paragraph (c) would be revised to clarify that this
paragraph applies only to the shipment of hazardous materials through
U.S. port areas in the course of being transported from one foreign
country to another.
In addition, paragraph (b) would be revised for the following
reasons. RSPA received three petitions for rulemaking requesting an
amendment to the HMR to require a container packing certification
attesting that the freight container has been properly packed, stowed,
segregated and secured for transport. Those responsible for packing the
unit would be required to provide a certificate or declaration to the
carrier for international transportation by vessel.
A freight container packing certification requirement was adopted
several years ago under Amendment 24 to the IMDG Code and became
effective worldwide on January 1, 1994, as mandated under the
International Convention on Safety of Life at Sea (SOLAS Convention).
When hazardous materials are packed into a freight container or
transport vehicle for transportation by vessel, those responsible for
packing the unit must provide a certificate or declaration to the
carrier attesting that the container is suitable for transport, that it
contains compatible materials in packages that have been properly
inspected, packed, and secured, and the container and packages are
properly marked, labeled, and placarded. This certification may appear
either in a separate document or in a signed statement provided on the
dangerous goods shipping document.
Because the U.S. is a signatory to the SOLAS Convention,
petitioners urged RSPA to adopt a similar container packing
certification requirement under the HMR. RSPA is proposing to amend
Secs. 171.12(b) and 176.27(c) to reference IMDG Code requirements for a
container packing certification for freight containers and transport
units intended for carriage by vessel. A ``unit'' could be a freight
container, van trailer, or other transport vehicle. This requirement
would apply to persons who load hazardous materials for transportation
(including freight forwarders, freight consolidators and non-vessel
operating common carriers) or transport hazardous materials by vessel.
Section 171.14. Paragraph (c)(3) contains provisions for
intermixing old and new hazard communication requirements. Because of
the October 1, 1993 mandatory compliance date for new hazard
communication requirements, these provisions no longer apply.
Therefore, paragraph (c)(3) would be removed and reserved.
Part 172
Sections 172.101 and 172.102. RSPA is proposing to revise the
Hazardous Materials Table (HMT) and the list of special provisions in
Sec. 172.102 for basic conformance with the eighth revised edition of
the UN Recommendations, the ICAO Technical Instructions (1995-1996
edition) and the 27th edition of the IMDG Code. Under Docket HM-181,
the HMT was revised by consolidating the existing HMT, the Optional
Table in Sec. 172.102, the UN Recommendations' List of Dangerous Goods,
the ICAO Dangerous Goods List, the IMDG Code list of dangerous goods,
the list of dangerous goods found in Canada's Transport of Dangerous
Goods (TDG), and the IM Tank Table. The IM Tank Table, though not
codified in the HMR, authorized the transport of hazardous materials in
intermodal (IM) portable tanks. The Optional Table contained in the
pre-HM-181 HMR was the table used for selection of proper shipping
names to be used in domestic and international transportation by
vessel.
RSPA consolidated the tables under Docket HM-181 to simplify the
use and reduce the volume of the HMR, as well as to align HMR hazard
communication and classification requirements with the UN
Recommendations. Since publication of HM-181, the UN, ICAO, and IMO
have incorporated changes to their lists of dangerous goods. If RSPA
does not incorporate comparable changes to the HMT, the result will be
two sets of regulations (one for domestic and one for international
transportation) and confusion in the regulated community--which could
result in unsafe shipments and restrictions on international trade. In
addition, by not adopting such changes, RSPA will expend considerable
resources reviewing and issuing approvals and initiating separate
rulemakings to authorize shipments prepared in accordance with the
international standards.
Proposed changes to shipping descriptions are based primarily on
Chapters 2 and 3 of the UN Recommendations. In turn, the changes to the
IMO and ICAO lists of dangerous goods also are based on the UN
Recommendations. Proposed changes include additions, deletions and
revisions of shipping names, classifications, subsidiary hazards,
labeling requirements, and packing group assignments--such as adding or
changing a material's packing group. In addition, RSPA proposes to
permit a special provision to be assigned to a shipping description to
clarify the composition of a material described under a specific entry.
Except for certain materials, such as elevated temperature
materials and sodium batteries, proposed changes to a material's
packaging authorizations are based on a material's packing group and
subsidiary hazard, and physical state (solid, liquid, or gas).
Packaging authorizations would be consistent with corresponding entries
already appearing in the HMT. For example, the non-bulk packaging
section for a Class 3, Packing Group I material would be Sec. 173.201.
A Division 6.1, Packing Group III material would be assigned
Sec. 173.153 for a possible packaging exception, while a Division 6.1,
Packing Group I or II material would receive no packaging exception
section. A Class 8, Packing Group I liquid material would be assigned
Sec. 173.243 for bulk packaging requirements while a Class 8, Packing
Group II liquid material would be assigned to Sec. 173.242. It is
important to note that any change to a material's classification,
packing group, or subsidiary hazards could have an effect on the
material's packaging authorizations.
Under HM-181, IM tank authorizations were consolidated into the HMT
(through the use of special provisions prefaced by a ``T'') and were
consistent with the sixth revision of the UN Recommendations. In this
notice, RSPA is proposing to revise the IM tank authorizations for
consistency with the changes in Chapter 12 of the seventh and eighth
revised editions of the UN Recommendations. These proposed changes can
be found in the ``T-note'' authorizations that are listed in Column 7
of the HMT.
The aircraft quantity limitations in Column 9 and the vessel
stowage requirements in Column 10 would be revised for consistency with
the ICAO Technical Instructions and IMDG Code, respectively. In
Sec. 172.101(k)(1)-(k)(5), the definitions of the vessel stowage codes,
which are prescribed in the Sec. 172.101 Table, would be revised for
consistency with the IMDG Code. This proposed revision would broaden
current stowage provisions for hazardous materials on cargo vessels to
apply to hazardous materials (such as propane) on passenger vessels
carrying a limited number of passengers.
Changes proposed to the HMT are quite extensive--approximately 33%
of the entries in the HMT would be changed. Therefore, RSPA is
publishing the entire proposed HMT in this notice, but does not believe
it is necessary to discuss every proposed change in this section
review. However, in order to facilitate the reader's understanding of
the changes to the HMT, RSPA is providing a list of all entries that
would be added, deleted, or made more restrictive. This list includes
changes in (1) the shipping name, (2) IM tank authorization, (3)
subsidiary labeling, (4) classification, and (5) packaging. In
addition, a discussion of some of the more substantive changes is
provided.
Many proper shipping names were added in the 1995-1996 ICAO
Technical Instructions to reflect both singular and plural forms. The
eighth revised edition of the UN Recommendations added a provision
allowing the use of either the singular or plural form of a proper
shipping name. RSPA is not proposing to add separate entries in the HMT
to indicate both the singular and plural form of a proper shipping name
because Sec. 172.101(c)(1) currently permits use of either form.
Numerous editorial changes would be made to the HMT to correct
misspellings and errors, and to provide more consistency. An entry
having only a typographical error corrected is not shown in the list of
significant changes. Therefore, it is necessary to review the entire
HMT to determine every proposed change.
Currently under the HMR, compressed and liquefied gases of the same
material have the same shipping description and identification number
(I.D. number). RSPA is proposing to split the generic shipping
descriptions for ``Compressed or Liquefied gases'' into separate
entries and add new generic entries and I.D. numbers for liquefied
gases, consistent with the UN Recommendations. In addition, new generic
entries would be added for self-heating liquids and solids. Specific
entries for self-reactive materials would be removed from the HMT and
replaced with new generic entries.
The UN Recommendations, ICAO Technical Instructions, and IMDG Code
replaced the term ``poisonous'' with the term ``toxic.'' RSPA is
proposing to amend the proper shipping names in the HMT that contain
the word ``poisonous'' by replacing the word ``poisonous'' with the
word ``toxic'' to conform to international terminology. For example,
the proper shipping name ``Flammable liquid, poisonous, n.o.s.'' would
be revised to read ``Flammable liquid, toxic, n.o.s.''. However,
Sec. 172.101(c)(3) would be revised to allow the use of the word
``poisonous'' interchangeably with the word ``toxic''.
The words ``inorganic'' and ``organic'' would be added to certain
generic shipping descriptions. Comments are invited regarding the
safety benefits of these modified descriptions, and as to whether there
is a need for domestic exceptions. In addition, RSPA is proposing to
add new generic entries for a corrosive material to indicate whether
the material is ``basic'' or ``acidic.'' RSPA also is proposing to add
new entries, as adopted in the UN Recommendations, for solid materials
containing flammable, corrosive, or toxic liquids.
The eighth revised edition of the UN Recommendations added entries
and assigned new UN I.D. numbers for elevated temperature materials.
RSPA is proposing to change the I.D. numbers for elevated temperature
materials in the HMT to correspond with those in the UN
Recommendations.
Currently under the HMR, air bags are assigned to the Division 4.1
hazard class and the proper shipping name is limited to ``Air bag
inflators'' or ``Air bag modules.'' Based on changes in the UN
Recommendations, RSPA would revise the proper shipping name for air
bags to include seat belt pre-tensioners and modules. The new proper
shipping name would be ``Air bag inflators or Air bag modules or Seat-
belt modules or Seat-belt pre-tensioners.'' This entry also would
reflect a change in classification from Division 4.1 to Class 9,
adoption of a new UN number, and removal of the ``D'' in Column 1.
Two new domestic entries would be added for ``Toy caps'' and ``Toy
propellant devices''. Toy propellant devices containing 30 grams or
less propellant would be classed as Division 1.4S while items
containing more than 30 grams but not more than 62.5 grams would be
classed as Division 1.4C.
Two new entries for ``Batteries, containing sodium'' and ``Cells,
containing sodium'' would be added in the HMT based on the UN
Recommendations entry (UN 3292). Since these materials were previously
authorized only under the terms of an exemption or competent authority
approval, RSPA is proposing to add a new packaging section Sec. 173.189
that prescribes general packaging and transport requirements for these
materials consistent with the UN Recommendations.
Currently, in Column 1, a ``+'' is assigned to certain materials
meeting the criteria of Division 6.1, Packing Group I, toxic by
inhalation, but classed in another hazard class. The eighth revised
edition of the UN Recommendations incorporated revisions to the hazard
classification of these materials to Division 6.1, Packing Group I,
toxic by inhalation. Therefore, the ``+'' would be removed from Column
1 for any liquid poison by inhalation (PIH) material newly classed in
Division 6.1, Packing Group I.
The shipping name ``acetonitrile'' is proposed to replace the name
``methyl cyanide.'' The hazard class for ``Formaldehyde solutions''
currently shown as Class 9 would be revised to Class 8. Numerous
generic pesticide entries would be revised to remove the ``n.o.s.''
from the shipping names.
Previously under the UN Recommendations, ICAO Technical
Instructions, and the IMDG Code, a subsidiary hazard of Division 6.1,
Packing Group III was not recognized. However, the international
standards now take such a subsidiary hazard into account. Therefore,
numerous entries would appear for the first time with a Division 6.1,
Packing Group III subsidiary hazard. In addition, an exception in
Sec. 172.101(c)(12)(iii), which allows a subsidiary hazard of Division
6.1, Packing Group III to be disregarded when selecting a proper
shipping name, would be removed.
Revised generic shipping descriptions for Division 4.3 materials
would be prefaced by the words ``water-reactive'' in lieu of the words
``substances which in contact with water emit''. The prefix of the
identification number for ``Polyester resin kits'' would be changed to
``UN'' from ``NA'' and a special provision ``40'' would be added in
Column 7 that would specify contents and packaging requirements for
polyester resin kits. In addition, Special Provision ``117'' would be
removed from the entry corresponding to ``UN 0150.''
The entry for alcoholic beverages would be revised in Column 7 to
include Special Provision ``24'', which would indicate that alcoholic
beverages with more than 70 percent alcohol by volume would be assigned
Packing Group II and alcoholic beverages containing more than 24
percent but not more than 70 percent alcohol would be assigned Packing
Group III. In addition, Sec. 173.150 would be revised to increase (to
five liters per inner packaging) the quantity of alcoholic beverage in
a packaging excepted from the HMR and to provide an exception adopted
in the UN Recommendations to permit Packing Group III alcoholic
beverages transported in receptacles of 250 L (66 gallons) or less to
be excepted from the HMR unless transported by air.
The following tables identify those entries that would be: (1)
deleted; (2) significantly changed; or (3) added. An entry is
considered significantly changed if there is a change in (1) the
shipping name, (2) IM tank authorization, (3) subsidiary labeling, (4)
classification, or (5) packaging. Each entry is identified by its
identification number which, along with the cross-reference table
appearing in the HMR prior to the HMT, can be used to identify the
affected entries. Unless otherwise indicated, the identification
numbers are ``UN'' numbers:
List of Entries That Would Be Deleted From the Sec. 172.101 Table
NA2255*............ 0416 1270 1705 2497 3030-3043
NA2810*............ 1118 1271 1864 2553 NA9259*
NA2811*............ 1255 1584 2207 2860 NA9276*
0273............... 1256 1592 2229 2951-2955
0274............... 1257 1703 2449 2970-2973
*See new entry added by the UN recommendations.
List of Entries That Would Be Significantly Changed
NA1760............. 1322 1474 1731 2006 2379 2534 2818
NA1986............. 1325 1475 1740 2022 2382 2557 2821
NA2922............. 1328 1477 1747 2029 2383 2564 2823
1106............... 1334 1481 1750 2047 2386 2571 2826
1125............... 1336 1482 1751 2051 2389 2583 2834
1135............... 1337 1483 1752 2076 2399 2584 2837
1143............... 1344 1489 1755 2189 2401 2585 2841
1154............... 1348 1502 1757 2194 2407 2586 2845
1158............... 1349 1506 1761 2195 2417 2604 2846
1160............... 1350 1508 1773 2196 2418 2606 2857
1162............... 1353 1511 1783 2198 2420 2610 2869
1167............... 1354 1517 1787 2206 2421 2616 2874
1198............... 1355 1549 1788 2209 2427 2619 2881
1202............... 1356 1564 1789 2211 2428 2626 2904-2905
1210............... 1357 1566 1809 2218 2429 2670 2921-2930
1214............... 1361 1570 1811 2219 2430 2677 2938
1221............... 1364 1588 1814 2232 2438 2679 2945-2946
1228............... 1373 1589 1816 2242 2445 2681 2965
1235............... 1378 1590 1819 2251 2461 2684 2985-2988
1265............... 1395 1599 1824 2257 2478 2693 2991-3021
1268............... 1402 1601 1888 2258 2482 2733 3024-3027
1274............... 1408 1602 1908 2260 2484 2734 3049-3050
1277............... 1409 1605 1922 2264 2485 2735 3065-3066
1282............... 1415 1613 1952 2267 2495 2741 3071
1289............... 1418 1614 1953 2270 2501 2742 3079
1296............... 1420 1648 1954 2276 2502 2757-2787 3084
1297............... 1428 1660 1955 2332 2517 2789 3086-3088
1298............... 1454 1708 1956 2337 2521 2796 3094
1308............... 1455 1715 1975 2343 2526 2801 3096
1310............... 1458 1719 1986 2351 2529 2810 3098-3100
1320............... 1459 1722 1988 2359 2530 2813 3119-3150
1321............... 1462 1724 1992 2361 2533 2817
List of Additions to the Sec. 172.101 Table
------------------------------------------------------------------------
UN # SHIPPING NAME
------------------------------------------------------------------------
0491.... CHARGES, PROPELLING.
0492.... SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0493.... SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0494.... JET PERFORATING GUNS, CHARGED, oil well, without detonator.
0495.... PROPELLANT, LIQUID.
0496.... OCTONAL.
0497.... PROPELLANT, LIQUID.
0498.... PROPELLANT, SOLID.
0499.... PROPELLANT, SOLID.
1851.... MEDICINE, LIQUID, TOXIC, N.O.S.
1990.... BENZALDEHYDE.
3155.... PENTACHLOROPHENOL.
3156.... COMPRESSED GAS, OXIDIZING, N.O.S.
3157.... LIQUEFIED GAS, OXIDIZING, N.O.S.
3158.... GAS, REFRIGERATED LIQUID, N.O.S.
3159.... 1,1,1,2-TETRAFLUOROETHANE.
3160.... LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S.
3161.... LIQUEFIED GAS, FLAMMABLE, N.O.S.
3162.... LIQUEFIED GAS, TOXIC, N.O.S.
3163.... LIQUEFIED GAS, N.O.S.
3164.... ARTICLES, PRESSURIZED PNEUMATIC or HYDRAULIC (containing non-
flammable gas).
3166.... ENGINES, INTERNAL COMBUSTION, including when fitted in
machinery or vehicles.
3167.... GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not
refrigerated liquid.
3168.... GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not
refrigerated liquid.
3169.... GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated
liquid.
3170.... ALUMINIUM PROCESSING BY-PRODUCTS.
3171.... BATTERY-POWERED VEHICLE or BATTERY-POWERED EQUIPMENT (wet
battery).
3174.... TITANIUM DISULPHIDE.
3175.... SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S.
3176.... FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S.
3178.... FLAMMABLE SOLID, INORGANIC, N.O.S.
3179.... FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S.
3180.... FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S.
3181.... METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
3182.... METAL HYDRIDES, FLAMMABLE, N.O.S.
3183.... SELF-HEATING LIQUID, ORGANIC, N.O.S.
3184.... SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S.
3185.... SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.
3186.... SELF-HEATING LIQUID, INORGANIC, N.O.S.
3187.... SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S.
3188.... SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.
3189.... METAL POWDER, SELF-HEATING, N.O.S.
3190.... SELF-HEATING SOLID, INORGANIC, N.O.S.
3191.... SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S.
3192.... SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.
3194.... PYROPHORIC LIQUID, INORGANIC, N.O.S.
3200.... PYROPHORIC SOLID, INORGANIC, N.O.S.
3203.... PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.
3205.... ALKALINE EARTH METAL ALCOHOLATES, N.O.S.
3206.... ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.
3207.... ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND
DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S.
3208.... METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
3209.... METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S.
3210.... CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3211.... PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3212.... HYPOCHLORITES, INORGANIC, N.O.S.
3213.... BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3214.... PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3215.... PERSULPHATES, INORGANIC, N.O.S.
3216.... PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3217.... PERCARBONATES, INORGANIC, N.O.S.
3218.... NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3219.... NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3220.... PENTAFLUOROETHANE.
3221.... SELF-REACTIVE LIQUID TYPE B.
3222.... SELF-REACTIVE SOLID TYPE B.
3223.... SELF-REACTIVE LIQUID TYPE C.
3224.... SELF-REACTIVE SOLID TYPE C.
3225.... SELF-REACTIVE LIQUID TYPE D.
3226.... SELF-REACTIVE SOLID TYPE D.
3227.... SELF-REACTIVE LIQUID TYPE E.
3228.... SELF-REACTIVE SOLID TYPE E.
3229.... SELF-REACTIVE LIQUID TYPE F.
3230.... SELF-REACTIVE SOLID TYPE F.
3231.... SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED.
3232.... SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED.
3233.... SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED.
3234.... SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED.
3235.... SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED.
3236.... SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED.
3237.... SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED.
3238.... SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED.
3239.... SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED.
3240.... SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED.
3241.... 2-BROMO-2-NITROPROPANE-1,3-DIOL.
3242.... AZODICARBONAMIDE.
3243.... SOLIDS CONTAINING TOXIC LIQUID, N.O.S.
3244.... SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S.
3246.... METHANESULPHONYL CHLORIDE.
3247.... SODIUM PEROXOBORATE, ANHYDROUS.
3248.... MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.
3249.... MEDICINE, SOLID, TOXIC, N.O.S.
3250.... CHLOROACETIC ACID, MOLTEN.
3251.... ISOSORBIDE-5-MONONITRATE.
3252.... DIFLUOROMETHANE.
3253.... DISODIUM TRIOXOSILICATE, PENTAHYDRATE.
3254.... TRIBUTYLPHOSPHANE.
3255.... tert-BUTYL HYPOCHLORITE.
3256.... ELEVATED TEMPERATURE LIQUID, N.O.S. with flash point above
37.8 deg.C, at or above its flash point.
3257.... ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 deg.C
and below its flash point.
3258.... ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 deg.C.
3259.... AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID,
CORROSIVE, N.O.S.
3260.... CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
3261.... CORROSIVE, SOLID, ACIDIC, ORGANIC, N.O.S.
3262.... CORROSIVE, SOLID, BASIC, INORGANIC, N.O.S.
3263.... CORROSIVE, SOLID, BASIC, ORGANIC, N.O.S.
3264.... CORROSIVE, LIQUID, ACIDIC, INORGANIC, N.O.S.
3265.... CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S.
3266.... CORROSIVE, LIQUID, BASIC, INORGANIC, N.O.S.
3267.... CORROSIVE, LIQUID, BASIC, ORGANIC, N.O.S.
3268.... AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRE-
TENSIONERS or SEAT-BELT MODULES.
3269.... POLYESTER RESIN KIT.
3270.... NITROCELLULOSE MEBRANE FILTERS.
3271.... ETHERS, N.O.S.
3272.... ESTERS, N.O.S.
3273.... NITRILES, FLAMMABLE, TOXIC, N.O.S.
3274.... ALCOHOLATES SOLUTION, N.O.S., in alcohol.
3275.... NITRILES, TOXIC, FLAMMABLE, N.O.S.
3276.... NITRILES, TOXIC, N.O.S.
3277.... CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.
3278.... ORGANOPHOSPHORUS COMPOUND, TOXIC N.O.S.
3279.... ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.
3280.... ORGANOARSENIC COMPOUND, N.O.S.
3281.... METAL CARBONYLS, N.O.S.
3282.... ORGANOMETALLIC COMPOUND, TOXIC N.O.S.
3283.... SELENIUM COMPOUND, N.O.S.
3284.... TELLURIUM COMPOUND, N.O.S.
3285.... VANADIUM COMPOUND, N.O.S.
3286.... FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S.
3287.... TOXIC LIQUID, INORGANIC, N.O.S.
3288.... TOXIC SOLID, INORGANIC, N.O.S.
3289.... TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
3290.... TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S.
3292.... BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM.
3293.... HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine,
by mass.
3294.... HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45%
hydrogen cyanide.
3295.... HYDROCARBONS, LIQUID, N.O.S.
3296.... HEPTAFLUOROPROPANE.
3297.... ETHYLENE OXIDE AND CHLO-RO-TETRAFLUOROETHANE MIXTURE with not
more than 8.8% ethylene oxide.
3298.... ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more
than 7.9% ethylene oxide.
3299.... ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more
than 5.6% ethylene oxide.
3300.... ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87%
ethylene oxide.
3301.... CORROSIVE LIQUID, SELF-HEATING, N.O.S.
------------------------------------------------------------------------
Appendix B to Sec. 172.101. In a November 5, 1992 final rule
entitled ``Marine Pollutants'' [57 FR 52934], RSPA stated that it would
consider, in a future rulemaking action, a criteria-based system to
identify marine pollutants. Adoption of a criteria-based system would
provide continuity and harmony, as well as permit identification of
potential pollutants previously not identified. Therefore, RSPA is
proposing to add two notes which are consistent with recent IMO
decisions. The first, Note 4, would allow a material meeting criteria
for a marine pollutant in the IMDG Code but not listed in Appendix B of
Sec. 172.101, to be transported as a marine pollutant. Note 5 would
allow the Associate Administrator for Hazardous Materials Safety to
except from HMR requirements a material listed in Appendix B of the HMR
that does not meet the IMDG Code criteria for a marine pollutant. In
addition, a number of materials would be added to, or removed from, the
HMR's List of Marine Pollutants.
Section 172.102. Special Provisions 23, 24, 26, 32, 34-40, and 43-
51 would be added to Sec. 172.102. These special provisions relate to
certain materials' classifications and any special packaging
requirements that are necessary to safely transport these materials.
Due to an oversight, Special Provision 23 was already added in a final
rule published June 2, 1994 [Docket HM-166Z; 59 FR 28493]. This special
provision concerned classification of ammonium nitrate fertilizer.
Special Provision 23 in this notice does not apply to ammonium nitrate
fertilizer and is not intended to revise the recently adopted Special
Provision 23. However, because of a time constraint and the difficulty
in amending Column 7 of the HMT, the new provision will be proposed in
this notice under Special Provision 23, but will be renumbered to
Special Provision 38 in the final rule under Docket HM-215A.
Section 172.203. A new paragraph (o) would be added to require
additional information to be included in the shipping paper description
for organic peroxides and self-reactive materials. In addition,
paragraphs (k) and (m) would be revised based on changes to the HMT. In
paragraph (k), the list of shipping names requiring technical names
would be revised based on changes to the HMT. In paragraph (m), the
reference to ``Poison'' would be modified to include an alternative
reference to ``Toxic.''
Section 172.204. The certification statement in paragraph (a)(2)
would be revised to add ``placarded'' as a condition for declaring a
shipment to be properly prepared for transportation. This wording is
consistent with international declarations and would enable one shipper
certification statement to be used for both domestic and export
shipments so that different preprinted forms are not needed.
Section 172.320. Section 172.320 would be revised to permit all
product codes that are traceable to an ``EX-number'' to be marked on
boxes of explosives in lieu of the EX number.
Section 172.400a. A new paragraph (c) would be added to state that
a subsidiary POISON label is not required on a package bearing a
primary CORROSIVE label if the poison hazard of the material inside is
based solely on corrosive destruction of tissue and is not due to
systemic poisoning. This provision was omitted inadvertently in the
Docket HM-181 final rule, and reinstating it would be consistent with
international requirements.
Section 172.402. For consistency with revisions to the UN
Recommendations, ICAO Technical Instructions, and the IMDG Code,
labeling for certain subsidiary hazards would be required. The
subsidiary labeling table in paragraph (a)(2) would be revised to
exclude Class 3 Packing Group III subsidiary risk materials having a
flash point at or above 38 deg.C (100 deg.F) from the requirement to
label, except when transporting the materials by air or vessel. This
proposed revision would require that a material having a subsidiary
risk of Class 3 Packing Group III and a flash point below 38 deg.C
(100 deg.F) be labeled for the Class 3 subsidiary hazard in accordance
with this section. In addition, the exception from subsidiary hazard
labeling for Class 8 Packing Group III and Division 6.1 Packing Group
III materials transported by highway or rail would be removed.
Previously, a Division 6.1 Packing Group III subsidiary hazard was not
required internationally or domestically. Based on a change adopted in
the eighth revised edition of the UN Recommendations, which removed the
STOW AWAY FROM FOODSTUFFS label and placard, packages containing
materials having either a primary or subsidiary hazard in Division 6.1
Packing Group III are required to bear a POISON label. As noted
previously in this document, RSPA is addressing this issue in a
rulemaking action under Docket HM-217. However, RSPA believes that a
package containing a material meeting Division 6.1 Packing Group III
criteria as either a primary or subsidiary hazard should bear a label
which communicates a warning that the material must be kept separate
from foodstuffs. Therefore, RSPA is proposing that any material having
a subsidiary hazard of Division 6.1 Packing Group III must bear a KEEP
AWAY FROM FOOD subsidiary label when transported domestically by any
mode. Also, new subsidiary labeling requirements for Class 2 materials
would, under this proposal, be added as paragraphs (f) and (g).
Section 172.411. A requirement specifying a minimum height for the
compatibility group letter on certain EXPLOSIVE labels would be
removed.
Section 172.416. Section 172.416 would be revised to allow the use
of the words ``TOXIC GAS'' on the POISON GAS label.
Section 172.430. Section 172.430 would be revised to allow the use
of the word ``TOXIC'' on the POISON label.
Section 172.540. Section 172.540 would be revised to allow the use
of the words ``TOXIC GAS'' on the POISON GAS placard.
Section 172.547. Section 172.547 would be revised to reduce the
size requirement for the word ``spontaneously'' in the ``SPONTANEOUSLY
COMBUSTIBLE'' placard from 25 mm to 12 mm.
Section 172.554. Section 172.554 would be revised to allow the use
of the word ``TOXIC'' on the POISON placard.
Part 173
Section 173.2a. Consistent with the UN Recommendations, the
Precedence of Hazards Table would be amended to account for
combinations of Division 4.2 and Class 8 materials which currently are
denoted as impossible combinations. In addition, a new footnote 5 would
be added to the paragraph (b) table to specify that, for materials
having multiple risks which are not listed by technical name in the
Sec. 172.101 Table, the most stringent packaging group must be used.
Also, a note would be added to the paragraph (b) table to specify the
class assignment for a material which meets the definition of Class 8,
has an inhalation toxicity by dusts and mists at the Packing Group I
level and meets criteria for oral or dermal toxicity.
Section 173.21. A reference to the Sec. 173.224 self-reactive
materials table would be revised to reflect proposed changes to the
table.
Section 173.22. Paragraph (a)(3)(i) would be revised to indicate
that the marking appearing on the bottom of a metal or plastic drum in
accordance with Sec. 178.503 would not be an acceptable means of
determining if the drum is an authorized packaging.
Section 173.24. Paragraph (d) would be revised to specify the
conditions under which foreign-manufactured packagings may be used. The
proposed revision would stipulate the conditions under which foreign-
manufactured UN packagings may be filled and used in the U.S. Under
this proposal, only packagings from countries affording the same degree
of acceptance to U.S.-manufactured packagings may be used. Current
provisions of the regulations authorize their use only for import/
export shipments under Secs. 171.11 and 171.12. In addition, paragraph
(e)(4)(ii) would be revised to prohibit hazardous materials from being
packed or mixed with other hazardous or nonhazardous materials in the
same outer packaging if such materials are capable of reacting with
each other and causing the evolution of ``asphyxiant gases.''
Section 173.25. Paragraph (a) would be amended to refer to the
definition of ``Overpack'' in Sec. 171.8, which also would be amended
to provide examples of suitable overpacks. Paragraph (b) would be added
to authorize shrink-wrapped or stretch-wrapped trays as outer
packagings for inner packagings prepared under limited quantity or
consumer commodity provisions if the completed package is capable of
meeting the Packing Group III performance level and the gross weight of
the package does not exceed 20 kg.
Section 173.28. Paragraph (b)(4), as revised under the Docket HM-
181 final rule, currently requires that metal and plastic single
packagings meet certain minimum thicknesses and that the ``minimum''
thickness be marked on the package. Since issuance of the Docket HM-181
final rule, the eighth revised edition of the UN Recommendations and
the international regulations have adopted a provision that metal drums
with a capacity greater than 100 liters must be marked in accordance
with tolerances allowed under ISO standard 3574 for each nominal
thickness of steel.
Unless the below-described proposed changes to Sec. 173.28 are
adopted, thicknesses and thickness marking requirements that differ
between the HMR and international regulations could result in
confusion, with drum users and reconditioners unsure whether drums are
suitable for reuse or remanufacture. Drum manufacturers in the U.S.
might find it necessary to mark both minimum and nominal thicknesses on
each drum in order to satisfy DOT and international requirements.
Consistent with changes proposed in Sec. 178.503(a), RSPA is proposing
that metal drums and jerricans which are to be reused be marked with
the nominal thickness, in millimeters. The minimum thickness table in
paragraph (b)(4) would be revised for metal drums and jerricans to
reflect a minimum thickness corresponding to the minimum allowed under
ISO standard 3574 for various nominal thicknesses. In developing the
minimum thickness proposed for each listed capacity of packaging, the
thickness chosen is that most closely corresponding numerically (i.e.,
without regard to whether it is thicker or thinner) to the minimum
thickness previously required. That is, based on the tolerances allowed
under ISO 3574 for each nominal thickness of steel, the minimum
thickness corresponding to that nominal thickness was determined and
compared to the minimum thickness required under the current provisions
for the given capacity of packaging. Each proposed minimum thickness
would result in a minimum sheet thickness closely corresponding to that
required under the current regulations. However, for packagings with a
capacity up to and including 120 liters, the proposed minimum
thicknesses would result in slight increases in the required thickness.
Drums would continue to be suitable for reuse only if they meet the
minimum thickness criteria of the table in paragraph (b)(4). A person
reusing a metal drum or jerrican could not rely on the thickness
marking appearing on the packaging to satisfy the minimum thickness
requirements, since that marking would represent the nominal, rather
than the minimum, thickness in accordance with proposed
Sec. 178.503(a)(9). Because the eighth revised edition of the UN
Recommendations did not address thickness requirements for plastic
packagings, RSPA is not proposing any changes to the thickness
requirements for plastic packagings.
Based on the merits of a petition for rulemaking (P-1133), a new
paragraph (b)(7) would be added to waive retesting requirements for
certain packagings used in limited operations prior to each reuse. The
petitioner states that this proposed change would provide consistency
with corresponding provisions in international requirements. According
to both the HMR and the UN Recommendations, a packaging must be design-
qualification tested before use. However, unlike the HMR, the UN
Recommendations do not require a packaging to be leakproof tested
before it is reused for transport, but only after it is reconditioned.
Packagings that are reused without reconditioning include metal drums
that are refilled with the same or similar compatible contents and
transported within distribution chains controlled by the consignor of
the product. RSPA is proposing similar provisions in new paragraph
(b)(7) for certain packagings to be reused without leakproof testing.
Packagings would be limited to stainless steel, monel, or nickel drums
(or other packagings approved by the Associate Administrator for
Hazardous Materials Safety) refilled with the same or similar
compatible contents and transported by a private carrier, contract
carrier, or common carrier in a transport vehicle or freight container
used exclusively for such service, within a distribution chain
controlled by the offeror. In order to ensure an appropriate level of
safety, when stainless steel, monel, or nickel drums are reused without
undergoing leakproof testing, they would be required to meet more
stringent thickness standards than prescribed in paragraph (b)(4).
Other packagings could qualify only if approved by the Associate
Administrator for Hazardous Materials Safety. Packagings also would
require an inspection prior to each reuse, and any packaging showing
evidence of a reduction in integrity would not be authorized for reuse
without reconditioning.
Section 173.33. Paragraph (c)(5) would be revised to limit the
provisions of the paragraph to materials in Packing Groups I and II of
Division 6.1.
Section 173.52. In Sec. 173.52, the description of Compatibility
Group B would be revised to clarify that detonators and similar
articles are included within this description even if they do not
contain primary explosives. In addition, in the descriptions for
Compatibility Groups E and F, the word ``gel'' would be added to
clarify that articles with a propelling charge containing gel may not
be classified in Compatibility Group E or F.
Section 173.59. In Sec. 173.59, the definitions ``powder,
smokeless,'' ``propellants,'' and ``charges, propelling'' would be
revised and definitions for ``charges, propelling for cannon,''
``propellent, liquid,'' and ``propellant, solid'' would be added.
Section 173.60. In Sec. 173.60, paragraph (b)(15) would be added to
require all plastic packagings to be static-resistant.
Section 173.62. In Sec. 173.62, the Explosives Table would be
revised to add new descriptions for Class 1 materials. In addition, the
packing method for UN0075 and UN0143 would be revised to E-159. The
Table of Packing Methods would be editorially revised to change the
reference to steel and aluminum boxes from 4A1 or 4A2 and 4B1 or 4B2 to
4A and 4B, respectively. Several packing methods would be revised by
authorizing aluminum boxes (4B) as an alternate packaging. For clarity,
the entire proposed Explosive Packing Methods Table has been reprinted
with the Table of Particular Packaging Requirements and Exceptions
following. Paragraph (e) would be revised to update the military
packaging exception to allow explosives packaged prior to January 1,
1990, to be transported in accordance with the packaging provisions in
effect on that date.
Section 173.115. The definition of a Division 2.2 gas would be
expanded to include asphyxiant and oxidizing gases.
Section 173.120. Definitions for Class 3 liquids would be revised
to include provisions for evaluating a material's ability to sustain
combustion and to measure flame point. A new method of testing for
combustibility would be referenced and added as Appendix H to Part 173.
Specific exceptions consistent with the UN Recommendations would be
added as paragraphs (a)(3), (a)(4), and (a)(5). In addition, references
to ASTM standards would be revised to reflect updated versions.
Paragraph (b)(2) would be revised to clarify that an elevated
temperature material in Class 3 may not be reclassed as a combustible
liquid. As explained more fully in a notice of proposed rulemaking and
in a final rule issued under Docket HM-198A [54 FR 38931; September 21,
1989 and 56 FR 49981; October 2, 1991], when a liquid is intentionally
heated to a temperature that is equal to or greater than its flash
point, flammable vapors are produced above the liquid. If these
flammable vapors are exposed to an ignition source, an explosion or
fire could result.
Section 173.121. Criteria for including viscous Class 3 materials
in Packing Group III would be revised. ISO method ISO 1523-1983 would
be referenced for determination of flash point. Several modifications
to the method would be provided when the temperature of the flash point
is too low for the standard procedures. Reference to ISO method 2431-
1989 would reflect the latest revision. The table in
Sec. 173.121(b)(1)(iv) would be amended for consistency with the eighth
revision of the UN Recommendations.
Section 173.124. The definition of self-reactive materials would be
revised to conform to the changes in the UN Recommendations, which now
contains ``generic'' shipping descriptions. When a new self-reactive
material is introduced into commerce, its transportation hazards
currently are determined based on standard tests. The competent
authority then assigns the new self-reactive material to a generic type
based on the test results.
In the proposed revision to Sec. 173.124, seven types of self-
reactive material (Types A-G) are defined in paragraph (a)(2). The
procedure for assigning a specific self-reactive material to a generic
type is set forth in paragraph (a)(2)(vi). If a self-reactive material
is identified by technical name in the Self-Reactive Materials Table in
Sec. 173.224, the generic type is assigned in that Table. The lengthy
process by which importing and exporting countries agree on the
packaging requirements or assignment of a shipping description for a
new self-reactive material would be avoided by using this procedure.
Section 173.128. Editorial changes would be made in paragraphs (a),
(c)(2) and (c)(3), and procedures for obtaining approvals would be
clarified in revised paragraph (d).
Sections 173.136 and 173.137. The definition and packing group
assignment for Class 8 materials would be clarified. Specific test
protocols developed by the Organization for Economic Cooperation and
Development (OECD) and published in the 1992 OECD Guideline for Testing
of Chemicals, No. 404, ``Acute Dermal Irritation/Corrosion'' would be
incorporated. A copy of this guideline may be obtained from the OECD
Publications and Information Center, 2001 L Street, Suite 700,
Washington, DC 20036 or by contacting the RSPA Dockets Unit.
Section 173.150. Paragraph (a) would be revised to allow Class 3
materials that meet the definition of Class 8 Packing Group III or
Division 6.1 Packing Group III, to utilize limited quantity exceptions
provided in this section. Paragraph (b) would be expanded to include
limited quantity exceptions for combustible liquids to provide relief
from specification packaging and placarding requirements for
combustible liquids which are also hazardous substances or hazardous
wastes. The paragraph (d) provisions for alcoholic beverages would be
revised to clarify that an alcoholic beverage containing 24 percent or
less alcohol by volume is not subject to the HMR. The maximum quantity
per package of alcoholic beverage excepted from the HMR would be raised
from four liters to five liters, and a Packing Group III alcoholic
beverage in a packaging of 250 L or less would not be subject to the
HMR unless transported by air.
Section 173.152. The limited quantity provisions for organic
peroxides would be amended by increasing the authorized net capacity
per inner packaging for Type D, E, or F liquid and solid organic
peroxides and Type B or C solid organic peroxides. However, the
authorized net capacity for liquid Type B or C organic peroxides would
decrease from 30 ml to 25 ml per inner packaging.
Section 173.164. Certain exceptions for mercury (metallic and
articles containing mercury), would be clarified and a 4H2 solid
plastic box would be authorized as an outer packaging, consistent with
the ICAO Technical Instructions.
Section 173.166. This section would be amended to limit its
applicability to air bag inflators and modules showing certain
specified results when subjected to a bonfire test. Under this proposed
revision, airbag modules and inflators not meeting the test criteria
must be transported as explosives.
Section 173.168. This section would be added to define a
``nonspillable battery'', establish separate requirements for
nonspillable batteries (as opposed to the requirements for wet
batteries contained in Sec. 173.159), and provide vibration and
pressure differential testing criteria. Except when transporting a
wheelchair or other battery-powered mobility aid equipped with a non-
spillable battery by air as checked baggage, a nonspillable battery
which is protected against short circuits, securely packaged and
durably marked would not be subject to any other HMR requirements.
Section 173.171. Paragraph (a) would be revised to clarify that
smokeless powder must be examined and approved as both Division 1.3 and
Division 4.1.
Section 173.185. RSPA is proposing to amend the requirements for
lithium batteries consistent with changes in the UN Recommendations.
While the new requirements apply more severe test requirements to
lithium batteries, they also will allow batteries with higher
quantities of lithium to be transported without being subject to the
regulations, provided specified criteria are met. Existing batteries
previously allowed to be transported as Class 9 batteries may continue
to be transported under the present requirements indefinitely if the
present requirements are met.
Section 173.189. This new section would be added to establish the
packaging and general transport requirements for batteries and cells
containing sodium. The packagings and transport conditions proposed
reflect those prescribed for these articles in the UN Recommendations,
the ICAO Technical Instructions and the IMDG Code. Specific conditions
under which batteries containing liquid sodium may be transported are
proposed based on the conditions prescribed for the transport of
batteries containing liquid sodium under DOT-E 10917.
Section 173.196. The seventh edition of the UN Recommendations
revised a provision for infectious substances packagings to require
that either the primary receptacle or the secondary packaging be
capable of withstanding the prescribed pressure differential. RSPA is
proposing a similar revision to paragraph (f) to clarify that both the
inner and the outer packagings are not required to have this
capability.
Sections 173.211-213. These sections would be revised to change
packaging identification codes (for steel boxes from 4A1 and 4A2 to 4A
and for aluminum boxes from 4B1 and 4B2 to 4B) for consistency with
international requirements.
Section 173.224. This section would be revised based on the UN
Recommendations. Paragraph (b) sets forth the Self-Reactive Materials
Table which identifies the technical name for specific self-reactive
materials, the identification number which is used to select the
appropriate generic shipping description, specifications for
concentrations of the self-reactive material, packing methods that may
be used, temperature control requirements, and additional special
provisions. The existing packing methods for self-reactive materials
would be replaced with the packing methods for organic peroxides which
are prescribed in Sec. 173.225.
Paragraph (c) sets forth procedures for new self-reactive
materials, formulations and samples. New self-reactive materials and
formulations of currently identified self-reactive materials would have
to be approved in accordance with the provisions in
Sec. 173.124(a)(2)(vi). Paragraph (c)(4) contains provisions for the
shipping of samples of new formulations. Paragraph (d) would specify
that self-reactive materials of Type F may be transported in bulk only
under the approval of the Associate Administrator for Hazardous
Materials Safety.
Section 173.225. In Sec. 173.225, paragraph (a) would be revised to
prohibit the use of metallic non-bulk packagings meeting a Packing
Group I packaging standard. Paragraph (c)(5) would be added to
authorize the transportation of mixtures of organic peroxides that are
specifically identified in the Organic Peroxides Table without approval
by the Associate Administrator for Hazardous Materials Safety. In
addition, the Organic Peroxide Table would be revised to add new
organic peroxides adopted in the UN Recommendations.
Section 173.304. In the paragraph (a)(2) table, for the entry
``carbon dioxide,'' an erroneous reference to a DOT-311800 cylinder
would be corrected to authorize a DOT-3T1800 cylinder for carbon
dioxide.
Section 173.306. In paragraph (a)(3)(v), the hot water immersion
test for aerosols and small gas receptacles would include a reference
temperature of 50 deg.C (122 deg.F) in addition to the reference
temperature of 55 deg.C (131 deg.F). A reference temperature of 50
deg.C would be permitted if the liquid phase of the materials contained
in the receptacle does not exceed 95 percent of the capacity of the
receptacle at 50 deg.C. In addition, provisions would be added for
plastic receptacles or contents which are sensitive to heat.
Appendix A to Part 173. Appendix A, which provides a method of
testing corrosion to skin, would be removed and reserved for
consistency with proposed changes to the definition and packing group
assignment for Class 8 materials.
Appendix E to Part 173. New criteria would be added for self-
reactive materials possessing explosive properties, and an editorial
change would be made to clarify that powders of metals or metal alloys
that can be ignited are classified in Division 4.1.
Appendix F to Part 173. In paragraph 1., an editorial revision
would be made to correctly reference Division 5.1.
Appendix H to Part 173. A new Appendix H would be added to Part 173
to provide a method of testing for combustibility. This method outlines
a procedure for determining if a material can sustain combustion if
heated under test conditions and exposed to an external source of
flame.
Part 175
Section 175.10. The phrase ``environmental restoration or
protection'' would be added as an exception in paragraph (a)(12) to
clarify that certain aircraft operations pertaining to environmental
restoration may be conducted under the provisions of this paragraph.
Exceptions currently contained in paragraphs (a)(13) and (a)(17) for
carbon dioxide (dry ice) would be consolidated into paragraph (a)(13)
to except this material from regulation from Part 175 when it is used
as a refrigerant for a package, intended for use in food or beverage
service aboard an aircraft, or when used to pack perishables in carry-
on baggage. Paragraph (a)(4) would be revised for consistency with the
ICAO Technical Instructions which prohibit the carriage of undeclared
flammable aerosols in checked or carry-on luggage. The carriage of such
aerosols may create an unnecessary risk to ground handlers, passengers,
and air crew members. In addition, a new paragraph (a)(26) would be
added to except from regulation small medical or clinical mercury
thermometers carried by passengers or crew members for personal use.
Section 175.33. Paragraph (a)(1) would be revised and a new
paragraph (a)(9) would be added to require an aircraft operator, in the
written notification to the pilot-in-command, to include a
compatibility group letter for a Class 1 material and an air waybill
number where one has been issued.
Part 176
Section 176.27. A new paragraph (c) would be added to reference a
container packing certificate required under the provisions of the
SOLAS Convention. (See discussion under Sec. 171.12 of this section
review for additional information.)
Section 176.76. A new paragraph (i) is being proposed for inclusion
in Sec. 176.76 to address the transport of fumigated transport units on
vessels. These proposed fumigation requirements would be in addition to
the fumigation requirements contained in Sec. 173.9. The new vessel
requirements are generally consistent with the IMDG Code requirements
for transporting fumigated transport units and are consistent with
Special Permits currently being issued by the Coast Guard for U.S.
maritime transport of fumigated transport units. Contrary to the IMDG
Code but consistent with the UN Recommendations, RSPA is not proposing
that fumigated units be treated as items of Class 9. If the proposed
requirements for fumigated transport units on vessels are adopted in
the final rule, a Special Permit issued by the Coast Guard would no
longer be necessary.
Part 177
Section 177.841. Paragraph (e)(3) would be revised to specify
requirements for separating Division 6.1 Packing Group III materials
from foodstuffs, consistent with provisions in Sec. 177.848.
Part 178
Section 178.2. Paragraph (a) would be revised to clarify that Part
178 requirements for UN standard packagings apply only to packagings
manufactured in the U.S. See Sec. 173.24(d)(2) for foreign-manufactured
packagings. A new paragraph (e) would be added to include definitions
for ``manufacturer'' and ``specification markings.'' These new
definitions would specify who is to be identified through a
specification marking as the ``manufacturer'' and would clarify the
manufacturer's responsibility under Part 178.
Section 178.3. The introductory text in paragraph (a) and the text
in subparagraph (a)(2) would be revised editorially for clarity. A new
marking provision would be added to paragraph (a)(4) to permit markings
of an appropriate, rather than specific, size for packagings of 5 L (1
gallon) or 5 kg (11 pounds) or less capacity. Paragraph (b) would be
revised to clarify the requirements for UN standard packagings marked
in accordance with HMR requirements and UN standard packagings marked
in accordance with the ICAO Technical Instructions or the IMDG Code.
Section 178.502. In paragraph (a) introductory text and paragraph
(a)(1), the terms ``type'' or ``types'' of packagings would be amended
for consistency with international regulations to read ``kind'' or
``kinds'' of packagings.
Section 178.503. Consistent with the UN Recommendations, RSPA is
proposing revisions to certification marking requirements in this
section. Each packaging certified to a UN standard is required to have
a series of markings which describe the packaging and its
characteristics. Paragraph (a) would be revised to require, for
packagings having a gross mass greater than 30 kg (66 pounds), that
these markings appear on the top or side of the packaging. Currently,
Sec. 178.503 requires that metal or plastic drums or jerricans intended
for reuse be marked with the minimum thickness of the packaging
material. Consistent with the UN Recommendations, RSPA is proposing
that metal drums and jerricans intended for reuse be marked with the
nominal thickness. The nominal thickness marked would be in accordance
with ISO 3574; that is, the nominal thickness marked could only exceed
the actual minimum thickness of the packaging material by the tolerance
specified in ISO 3574. Packagings to be reused would still be subject
to the minimum thickness requirements of Sec. 173.28. Because the
eighth revised edition of the UN Recommendations did not address
thickness requirements for plastic packagings, RSPA is proposing that
plastic drums and jerricans intended for reuse continue to be marked
with the minimum thickness of the packaging material.
In addition to the full marking on the top or side of a metal or
plastic drum having a capacity greater than 100 liters and intended for
reuse or reconditioning as a single packaging or the outer packaging of
a composite packaging, RSPA is proposing to require a permanent marking
of the drum characteristics on the bottom of the drum. The country
authorizing the mark, the name and address of the manufacturer, and the
packaging thickness would not be required as part of this permanent
mark. This marking would identify the packaging as it was originally
manufactured, and could not necessarily be used to determine compliance
with packaging requirements. For example, if a non-removable head drum
had been converted to a removable head drum, this conversion would not
be reflected in the marking on the bottom of the drum, but would be
evident in the top or side marking. For drums marked permanently on the
bottom, the top or side mark would not be required to be permanent
(i.e., able to withstand the reconditioning process).
RSPA is proposing a new paragraph (d), which would specify
additional requirements for markings on reconditioned metal drums. The
paragraph would require that reconditioners reapply markings which no
longer appear on drums after the reconditioning process. A
reconditioner could duplicate the original markings or apply markings
which reflect a lower performance level, but could not apply markings
which identify a performance level greater than that for which the
original design type had been tested and marked.
Section 178.512. Standards for steel boxes and aluminum boxes would
be consolidated by removing the distinction between unlined/uncoated
steel or aluminum boxes and steel or aluminum boxes having an inner
liner or coating. Therefore, both unlined and lined steel boxes would
be identified as 4A and unlined and lined aluminum boxes would be
identified as 4B. Corresponding revisions would be reflected in the
packaging authorizations of Part 173.
Section 178.513. A new paragraph would be added to the standards
for natural wood boxes to specify fastening requirements.
Section 178.516. In paragraph (b)(1), the reference to ISO Standard
535-1976(E) would be updated. Paragraph (b)(2) would be revised to
authorize the ends of fiberboard boxes to be constructed of suitable
materials other than wood, which is already authorized.
Section 178.521. In paragraph (b)(2), the term ``water-resistant''
would be revised to ``waterproof'' and examples of a waterproof ply or
barrier would be provided.
Section 178.522. A composite packaging consisting of a plastic
receptacle in a protective plastic drum is designated as 6HH in the
current HMR standards. The UN Recommendations recently adopted a new
composite packaging standard to authorize a plastic receptacle in a
protective plastic box. Therefore, in paragraph (b)(3), the previous
6HH composite packaging would be redesignated as 6HH1 and the new
composite packaging (the plastic receptacle in a protective plastic
box) would be designated as 6HH2.
Section 178.601. Based on the merits of a petition (P-1195),
paragraph (b) would be revised to limit the responsibility of shippers
to those packaging assembly functions they actually perform or are
responsible for performing. The petitioner claims that Sec. 178.601(b)
currently requires any shipper who closes a package to ensure that each
package is capable of passing prescribed performance tests, thereby
making the shipper legally responsible for every aspect of the
manufacture and testing of the packaging. RSPA agrees, and is proposing
a revision to paragraph (b)(2) to remove the shipper responsibility
provision regarding packaging fabrication and testing functions not
performed by the shipper. Paragraph (g)(2)(i) would be revised to
clarify that selective testing under Variation 2 would require the
fragile inner packagings to contain liquids. A new sentence would be
added to the end of paragraph (g)(2)(vi) to clarify that where outer
packagings are not leakproof or siftproof and consequently require some
type of leakproof liner, plastic bag or other means of containment,
sufficient absorbent material must be placed inside the liner or bag. A
new paragraph (k) would be added to permit several tests to be
performed on one sample if the validity of test results is not affected
and if approved by the Associate Administrator for Hazardous Materials
Safety. Newly designated paragraph (l) would be revised to clarify
recordkeeping requirements and provide consistency with test report
requirements in the UN Recommendations.
Section 178.602. In paragraph (c) a reference to
``Sec. 178.603(d)(2)'' would be corrected to read ``Sec. 178.603(e)''.
Section 178.603. In paragraph (a), a new provision would be added
to require that the drop test be performed using the package
orientation most likely to result in failure if more than one
orientation is possible. Paragraph (c) would be revised to clarify that
the cold drop test outlined in this paragraph applies only to plastic
packagings. A proposed revision to paragraph (f)(1) would clarify that
inner packagings of combination packagings are not required to be
vented to reach equilibrium after the drop test.
Section 178.604. For consistency with a change in the UN
Recommendations, the length of time to conduct a leakproofness test,
other than for production testing, would be specified as five minutes
in revised paragraph (d).
Rulemaking Analyses and Notices
A. Executive Order 12866 and DOT Regulatory Policies and Procedures
This proposed rule is not considered a significant regulatory
action under section 3(f) of Executive Order 12866 and therefore, was
not reviewed by the Office of Management and Budget. The rule is not
considered a significant rule under the Regulatory Policies and
Procedures of the Department of Transportation [44 FR 11034]. A
preliminary regulatory evaluation is available for review in the
Docket.
B. Executive Order 12612
This proposed rule has been analyzed in accordance with the
principles and criteria contained in Executive Order 12612
(``Federalism''). The Hazardous Materials Transportation Act contains
an express preemption provision (49 App. U.S.C. 1804(a)(4)) that
preempts State, local, and Indian tribe requirements on certain covered
subjects. Covered subjects are:
(i) the designation, description, and classification of hazardous
materials;
(ii) the packing, repacking, handling, labeling, marking, and
placarding of hazardous materials;
(iii) the preparation, execution, and use of shipping documents
pertaining to hazardous materials and requirements respecting the
number, content, and placement of such documents;
(iv) the written notification, recording, and reporting of the
unintentional release in transportation of hazardous materials; or
(v) the design, manufacturing, fabrication, marking, maintenance,
reconditioning, repairing, or testing of a package or container which
is represented, marked, certified, or sold as qualified for use in the
transportation of hazardous materials.
This notice of proposed rulemaking addresses covered subjects under
items i, ii, iii and v above and, if adopted as final, would preempt
State, local, or Indian tribe requirements not meeting the
``substantively the same'' standard. The HMTA (49 App. U.S.C.
1804(a)(5), as amended, provides that if DOT issues a regulation
concerning any of the covered subjects, after November 16, 1990, DOT
must determine and publish in the Federal Register the effective date
of Federal preemption. The effective date may not be earlier than the
90th day following the date of issuance of the final rule and not later
than two years after the date of issuance. RSPA has determined that the
effective date of Federal preemption for these requirements will be
[insert date six months after date of publication]. Thus, RSPA lacks
discretion in this area, and preparation of a federalism assessment is
not warranted.
C. Regulatory Flexibility Act
This proposed rule would incorporate changes introduced in the
seventh and eighth revised editions of the UN Recommendations, the
1993-1994 and 1995-1996 ICAO Technical Instructions, and Amendments 26
and 27 to the IMDG Code. It would apply to offerors and carriers of
hazardous materials and would facilitate the transportation of
hazardous materials in international commerce by providing consistency
with international requirements. U.S. companies, including numerous
small entities competing in foreign markets, will be forced to comply
with a dual system of regulation, to their economic disadvantage, if
the changes proposed in this NPRM are not adopted. The proposed changes
are intended to avoid this result. I certify that this proposal will
not, if promulgated, have a significant economic impact on a
substantial number of small entities. This certification is subject to
modification as a result of a review of comments received in response
to this proposal.
D. Paperwork Reduction Act
The requirements for information collection have been approved by
the Office of Management and Budget (OMB) under the provisions of the
Paperwork Reduction Act Of 1980 (Pub. L. 96-511) under OMB control
number 2137-0034 for shipping papers and 2137-0557 for approvals.
E. Regulation Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory
action listed in the Unified Agenda of Federal Regulations. The
Regulatory Information Service Center publishes the Unified Agenda in
April and October of each year. The RIN number contained in the heading
of this document can be used to cross-reference this action with the
Unified Agenda.
List of Subjects
49 CFR Part 171
Exports, Hazardous materials transportation, Hazardous waste,
Imports, Incorporation by reference, Reporting and recordkeeping
requirements.
49 CFR Part 172
Hazardous materials transportation, Hazardous waste, Labels,
Markings, Packaging and containers, Reporting and recordkeeping
requirements.
49 CFR Part 173
Hazardous materials transportation, Packaging and containers,
Radioactive materials, Reporting and recordkeeping requirements,
Uranium.
49 CFR Part 175
Air carriers, Hazardous materials transportation, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 176
Hazardous materials transportation, Maritime carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 177
Hazardous materials transportation, Motor carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 178
Hazardous materials transportation, Motor vehicles safety,
Packaging and containers, Reporting and recordkeeping requirements.
In consideration of the foregoing, 49 CFR Chapter I would be
amended as follows:
PART 171--GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS
1. The authority citation for Part 171 would continue to read as
follows:
Authority: 49 App. U.S.C. 1802, 1803, 1804, 1805, 1808, and
1818; 49 CFR part 1.
2. In the Sec. 171.7(a)(3) Table, under the entry American Society
for Testing and Materials a new entry would be added in numerical
order; under the entry International Organization for Standardization,
two new entries would be added at the end of existing entries; and a
new entry would be added in alphabetical order, to read as follows:
Sec. 171.7 Reference material.
(a) * * *
(3) Table of material incorporated by reference. * * *
------------------------------------------------------------------------
49 CFR
Source and name of material reference
------------------------------------------------------------------------
* * * * * * *
American Society for Testing and Materials
* * * * * * *
ASTM G 31-72 Practice for Laboratory Immersion Corrosion
Testing of Metals (Reapproved 1990)........................ 173.137
* * * * * * *
International Organization for Standardization
* * * * * * *
ISO 3574-1986(E) Cold-reduced carbon steel sheet of
commercial and drawing qualities........................... 178.503
ISO 2592-1973 Petroleum Products--Determination of Flash and
Fire Points Cleveland Cup Method, 1973..................... 173.120
ISO 2604 (IV)-1975 Steel Products for Pressure Purposes--
Plates..................................................... 173.137
* * * * * * *
Organization for Economic Cooperation and Development (OECD)
OECD Publications and Information Center, 2001 L Street,
Suite 700, Washington, DC 20036............................
OECD Guideline for Testing of Chemicals, No.404 ``Acute
Dermal Irritation/Corrosion'', 1992........................ 173.136
* * * * * * *
------------------------------------------------------------------------
* * * * *
Sec. 171.7 [Amended]
3. In addition, in Sec. 171.7, in the table in paragraph (a)(3),
the following changes would be made:
a. In the entry ASTM D 56-79, the wording ``D 56-79'' would be
revised to read ``D 56-87''.
b. In the entry ASTM D 93-80, the wording ``D 93-80'' would be
revised to read ``D 93-90''.
c. In the entry ASTM D 3278-78, the wording ``D 3278-78'' would be
revised to read ``ASTM D 3278-89''.
d. In the entry ASTM D 4359-84, the wording ``D 4359-84'' would be
revised to read ``ASTM D 4359-90''.
e. Under International Civil Aviation Organization (ICAO), for the
entry ``Technical Instructions for the Safe Transport of Dangerous
Goods by Air'', the date ``1993-1994'' would be revised to read ``1995-
1996''.
f. Under International Maritime Organization (IMO), the entry
``International Maritime Dangerous Goods (IMDG) Code, 1990 Consolidated
Edition, as amended by Amendment 26 thereto'' would be amended by
removing the wording ``Amendment 26'' and replacing it with ``Amendment
27''.
g. Under International Organization for Standardization, the words
``ISO-535-1976(E)'' would be revised to read ``ISO-535-1991(E)''.
h. Under Transport Canada, the entry ``Transportation of Dangerous
Goods Regulations, as of July 1, 1985, incorporating Registration
Numbers SOR/85-77, SOR/85-585 and SOR/85-609'' would be revised to read
``Transportation of Dangerous Goods Regulations, 1 July 1985, SOR/85/
77, incorporating the following Registration Numbers: SOR/85-314, SOR/
85-585, SOR/85-609, SOR/86-526, SOR/88-635, SOR/87-335, SOR/87-186,
SOR/89-39, SOR/89-294, SOR/90-847, SOR/91-711, SOR/91-712, SOR/92-447,
SOR/92-600, SOR/93-203, SOR/93-274, SOR/93-525, SOR/94-146 and SOR/94-
264''.
i. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Sixth Revised Edition (1989)'' the
wording ``Sixth Revised Edition (1989)'' would be revised to read
``Eighth Revised Edition (1993)''.
j. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Tests and Criteria'', in column 2, the
references ``173.124;'' ``173.128;'' ``173.166;'' and ``173.185'' would
be added in appropriate numerical order.
4. In Sec. 171.8, the following definitions would be added or
revised, as indicated, in appropriate alphabetical order to read as
follows:
Sec. 171.8 Definitions and abbreviations.
[Add:]
* * * * *
Asphyxiant gas means a gas which dilutes or replaces oxygen
normally in the atmosphere.
* * * * *
Gas means a material which, at a standard pressure of 101.3 kPa
(14.7 psi), has a vapor pressure greater than 300 kPa (43.5 psi) at 50
deg.C (122 deg.F) or is completely gaseous at 20 deg.C (68 deg.F).
* * * * *
Siftproof packaging means a packaging impermeable to dry contents,
including fine solid material produced during transportation.
* * * * *
[Revise:]
* * * * *
Box means a packaging with complete rectangular or polygonal faces,
made of metal, wood, plywood, reconstituted wood, fiberboard, plastic,
or other suitable material. Small holes for purposes such as ease of
handling or opening, or to meet classification requirements, are
permitted as long as they do not compromise the integrity of the
packaging during transportation, and are not otherwise prohibited in
this subchapter.
* * * * *
Liquid means a material, other than an elevated temperature
material, with a melting point or initial melting point of 20 deg.C
(68 deg.F) or lower at a standard pressure of 101.3 kPa (14.7 psi). A
viscous material for which a specific melting point cannot be
determined must be subjected to the procedures specified in ASTM D
4359-90 ``Standard Test Method for Determining Whether a Material is
Liquid or Solid''.
* * * * *
Overpack, except as provided in subpart K of part 178 of this
subchapter, means an enclosure that is used by a single consignor to
provide protection or convenience in handling of a package or to
consolidate two or more packages. Overpack does not include a transport
vehicle, freight container, or aircraft unit load device. Examples of
overpacks are one or more packages:
(1) Placed or stacked onto a load board such as a pallet and
secured by strapping, shrink wrapping, stretch wrapping, or other
suitable means; or
(2) Placed in a protective outer packaging such as a box or crate.
* * * * *
Solid means a material which is not a gas or a liquid.
* * * * *
UN standard packaging means a packaging conforming to standards in
the UN Recommendations on the Transport of Dangerous Goods.
* * * * *
Sec. 171.11 [Amended]
5. In Sec. 171.11, in the last sentence of paragraph (d)(5), the
wording ``Poison'' would be revised to read ```Poison' or `Toxic'''.
Sec. 171.12 [Amended]
6. In Sec. 171.12, the following changes would be made:
a. In paragraph (b) introductory text, in the second sentence, the
wording ``stowed and segregated, and certified in accordance with the
IMDG Code'' would be revised to read ``stowed and segregated, and
certified (including a container packing certification, if applicable)
in accordance with the IMDG Code''.
b. In the first sentence of paragraph (c) introductory text, the
wording ``being imported into or exported from the United States or''
would be removed.
Sec. 171.14 [Amended]
7. In Sec. 171.14, paragraph (c)(3) would be removed.
PART 172--HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS
MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND
TRAINING REQUIREMENTS
8. The authority citation for part 172 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1805, 1808; 49 CFR part 1,
unless otherwise noted.
9. In Sec. 172.101, paragraphs (c)(3), (c)(13) and (k)(1) through
(k)(5) would be revised and, in paragraph (g), a new sentence would be
added as the last sentence to read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
(c) * * *
(3) The word ``poison'' or ``poisonous'' may be used
interchangeably with the word ``toxic'' when only domestic
transportation is involved. The abbreviation ``n.o.i.'' or
``n.o.i.b.n.'' may be used interchangeably with ``n.o.s.''.
* * * * *
(13) Self-reactive materials and organic peroxides. Generic proper
shipping names for self-reactive materials and organic peroxides, as
listed in Column 2 of the Table, must be selected based on the
material's technical name and concentration, in accordance with the
provisions of Secs. 173.224 or 173.225 of this subchapter,
respectively.
* * * * *
(g) * * * No label is required for a material classed as a
combustible liquid or for a Class 3 material that is reclassed as a
combustible liquid.
* * * * *
(k) * * *
(1) Stowage category ``A'' means the material may be stowed ``on
deck'' or ``under deck'' on a passenger or cargo vessel.
(2) Stowage category ``B'' means--
(i) The material may be stowed ``on deck'' or ``under deck'' on a
cargo vessel;
(ii) The material may be stowed ``under deck'' on a passenger
vessel carrying not more than 25 passengers or, alternatively, one
passenger per each three meters of overall vessel length, whichever is
larger; and
(iii) ``On deck only'' on passenger vessels in which the number of
passengers specified in paragraph (k)(2)(ii) of this section is
exceeded.
(3) Stowage category ``C'' means the material must be stowed ``on
deck only'' on a cargo vessel and on a passenger vessel.
(4) Stowage category ``D'' means material must be stowed ``on deck
only'' on a cargo vessel and on a passenger vessel carrying a number of
passengers limited to not more than the larger of 25 passengers, or one
passenger per each three meters of overall vessel length, but is
prohibited on passenger vessels in which the limiting number of
passengers is exceeded.
(5) Stowage category ``E'' means material may be stowed ``on deck''
or ``under deck'' on a cargo vessel and on a passenger vessel carrying
a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each three meters of overall vessel
length, but is prohibited from carriage on passenger vessels in which
the limiting number of passengers is exceeded.
* * * * *
Sec. 172.101 [Amended]
10. In addition, in Sec. 172.101, in paragraph (c)(12)(iii), the
last sentence would be removed.
11. In Sec. 172.101, the Hazardous Materials Table would be revised
to read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
Sec. 172.101 Hazardous Materials Table
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
(8) Packaging authorizations (9) Quantity limitations (10) Vessel stowage
(Sec. 173.***) -------------------------- requirements
Hazard Identification Packing Label(s) required (if Special ---------------------------------- ---------------------
Symbols Hazardous materials descriptions and proper shipping names class or Numbers group not excepted) provisions Passenger Cargo Other
Division Exceptions Non-bulk Bulk aircraft or aircraft Vessel stowage
packaging packaging railcar only stowage provisions
(1) (2).......................................................... (3) (4) (5) (6)................... (7)............. (8A) (8B) (8C) (9A)....... (9B)....... (10A).. (10B)
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
....... Accellerene, see p-Nitrosodimethylaniline.................... ........... .............. ...................... ................ ........... ........... .......
....... Accumulators, electric, see Batteries, wet etc............... ........... .............. ...................... ................ ........... ........... .......
D...... Accumulators, pressurized, pneumatic or hydraulic (containing 2.2 NA1956 NONFLAMMABLE GAS...... ................ 306 306 None No limit... No limit... A......
non-flammable gas).
....... Acetal....................................................... 3 UN1088 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Acetaldehyde................................................. 3 UN1089 I FLAMMABLE LIQUID...... A3, B16, T20, None 201 243 Forbidden.. 30 L....... E......
T26, T29.
A...... Acetaldehyde ammonia......................................... 9 UN1841 III CLASS 9............... ................ 155 204 240 200 kg..... 200 kg..... A...... 34
....... Acetaldehyde oxime........................................... 3 UN2332 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Acetic acid, glacial or Acetic acid solution, with more than 8 UN2789 II CORROSIVE, FLAMMABLE A3, A6, A7, A10 154 202 243 1 L........ 30 L....... A......
80 percent acid, by mass. LIQUID. B2, T8.
....... Acetic acid solution, with more than 10 percent but not more 8 UN2790 II CORROSIVE............. A3, A6, A7, A10 154 202 242 1 L........ 30 L....... A......
than 80 percent acid, by mass. B2, T8.
....... Acetic anhydride............................................. 8 UN1715 II CORROSIVE, FLAMMABLE A3, A6, A7, A10, 154 202 243 1 L........ 30 L....... A...... 40
LIQUID. B2, T8.
....... Acetone...................................................... 3 UN1090 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Acetone cyanohydrin, stabilized.............................. 6.1 UN1541 I POISON................ 2, A3, B9, B14, None 227 244 Forbidden.. 30 L....... D...... 25, 40, 49
B32, B76, B77,
N34, T38, T43,
T45.
....... Acetone oils................................................. 3 UN1091 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
....... Acetonitrile................................................. 3 UN1648 II FLAMMABLE LIQUID...... T14............. 150 202 242 1 L........ 60 L....... B...... 40
....... Acetonitrile, see Methyl cyanide............................. ........... .............. ...................... ................ ........... ........... .......
....... Acetyl acetone peroxide with more than 9 percent by mass Forbidden .............. ...................... ................ ........... ........... .......
active oxygen.
....... Acetyl benzoyl peroxide, solid, or with more than 40 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Acetyl bromide............................................... 8 UN1716 II CORROSIVE............. B2, T12, T26.... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl chloride.............................................. 3 UN1717 II FLAMMABLE LIQUID, A3, A6, A7, N34, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. T18, T26.
....... Acetyl cyclohexanesulfonyl peroxide, with more than 82 Forbidden .............. ...................... ................ ........... ........... .......
percent wetted with less than 12 percent water.
....... Acetyl iodide................................................ 8 UN1898 II CORROSIVE............. B2, T9.......... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl methyl carbinol....................................... 3 UN2621 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Acetyl peroxide, solid, or with more than 25 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Acetylene, dissolved......................................... 2.1 UN1001 FLAMMABLE GAS......... ................ None 303 None Forbidden.. 15 kg...... D...... 25, 40, 57
....... Acetylene (liquefied)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene silver nitrate..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene tetrabromide, see Tetrabromoethane................. ........... .............. ...................... ................ ........... ........... .......
....... Acid butyl phosphate, see Butyl acid phosphate............... ........... .............. ...................... ................ ........... ........... .......
....... Acid, sludge, see Sludge acid................................ ........... .............. ...................... ................ ........... ........... .......
....... Acridine..................................................... 6.1 UN2713 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Acrolein dimer, stabilized................................... 3 UN2607 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Acrolein, inhibited.......................................... 6.1 UN1092 I POISON, FLAMMABLE 1, B9, B12, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B42, B72,
B77, T38, T43,
T44.
....... Acrylamide................................................... 6.1 UN2074 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 12
....... Acrylic acid, inhibited...................................... 8 UN2218 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... C...... 25, 40
LIQUID.
....... Acrylonitrile, inhibited..................................... 3 UN1093 I FLAMMABLE LIQUID, B9, T18, T26.... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Actuating cartridge, explosive, see Cartridges, power device. ........... .............. ...................... ................ ........... ........... .......
....... Adhesives, containing a flammable liquid..................... 3 UN1133 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Adiponitrile................................................. 6.1 UN2205 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Aerosols, corrosive, Packing Group II or III, (each not 2.2 UN1950 NONFLAMMABLE GAS, A34............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
exceeding 1 L capacity). CORROSIVE.
....... Aerosols, flammable, (each not exceeding 1 L capacity)....... 2.1 UN1950 FLAMMABLE GAS......... N82............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
....... Aerosols, non-flammable, (each not exceeding 1 L capacity)... 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306, 307 None None 75 kg...... 150 kg..... A...... 48, 85
....... Aerosols, poison, each not exceeding 1 L capacity............ 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306 None None Forbidden.. Forbidden.. A...... 40, 48, 85
....... Air bag inflators or Air bag modules or Seat-belt pre- 9 UN3268 III CLASS 9............... ................ 166 166 166 25 kg...... 100 kg..... A......
tensioners or Seat-belt modules.
....... Air, compressed.............................................. 2.2 UN1002 NONFLAMMABLE GAS...... ................ 306 302 302 75 kg...... 150 kg..... A......
....... Air, refrigerated liquid, (cryogenic liquid)................. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. 150 kg..... D...... 51
OXIDIZER.
....... Air, refrigerated liquid, (cryogenic liquid) non-pressurized. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. Forbidden.. D...... 51
OXIDIZER.
....... Aircraft evacuation slides, see Life saving appliances etc... ........... .............. ...................... ................ ........... ........... .......
....... Aircraft hydraulic power unit fuel tank (containing a mixture 3 UN3165 I FLAMMABLE LIQUID, ................ None 172 None Forbidden.. 42 L....... E......
of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel). POISON, CORROSIVE.
....... Aircraft survival kits, see Life saving appliances etc....... ........... .............. ...................... ................ ........... ........... .......
....... Alcoholates solution, n.o.s., in alcohol..................... 3 UN3274 II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Alcoholic beverages.......................................... 3 UN3065 II FLAMMABLE LIQUID...... 24, B1, T1...... 150 202 242 5 L........ 60 L....... A......
............................................................. ........... .............. III FLAMMABLE LIQUID...... 24, B1, N11, T1. 150 203 242 60 L....... 220 L...... A......
....... Alcohols, n.o.s.............................................. 3 UN1987 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Alcohols, toxic, n.o.s....................................... 3 UN1986 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... None 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldehydes, n.o.s............................................. 3 UN1989 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Aldehydes, toxic, n.o.s...................................... 3 UN1988 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldol........................................................ 6.1 UN2839 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12
D...... Aldrin, liquid............................................... 6.1 NA2762 II POISON................ ................ None 202 243 5 L........ 60 L....... B......
D...... Aldrin, solid................................................ 6.1 NA2761 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
....... Alkali metal alcoholates, self-heating, corrosive, n.o.s..... 4.2 UN3206 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... B......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... B......
COMBUSTIBLE,
CORROSIVE.
....... Alkali metal alloys, liquid, n.o.s........................... 4.3 UN1421 I DANGEROUS WHEN WET.... A2, A3, B48, N34 None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amalgams........................................ 4.3 UN1389 I DANGEROUS WHEN WET.... A2, A3, N34..... None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amides.......................................... 4.3 UN1390 II DANGEROUS WHEN WET.... A6, A7, A8, A19, None 212 241 15 kg...... 50 kg...... E...... 40
A20.
....... Alkali metal dispersions, or Alkaline earth metal dispersions 4.3 UN1391 I DANGEROUS WHEN WET.... A2, A3.......... None 201 244 Forbidden.. 1 L........ D......
....... Alkaline corrosive liquids, n.o.s., see Caustic alkali ........... .............. ...................... ................ ........... ........... .......
liquids, n.o.s..
....... Alkaline earth metal alcoholates, n.o.s...................... 4.2 UN3205 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... B......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 15 kg...... 100 kg..... B......
COMBUSTIBLE.
....... Alkaline earth metal alloys, n.o.s........................... 4.3 UN1393 II DANGEROUS WHEN WET.... A19............. None 212 241 15 kg...... 50 kg...... E......
....... Alkaline earth metal amalgams................................ 4.3 UN1392 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
....... Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s.. 6.1 UN3140 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... A......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. 6.1 UN1544 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
poisonous.
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2584 II CORROSIVE............. B2, T8, T27..... 154 202 242 1 L........ 30 L....... B......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2586 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... B......
with not more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, 8 UN2583 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid 8 UN2585 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
with not more than 5 percent free sulfuric acid.
....... Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)... 8 UN3145 I CORROSIVE............. T8.............. None 201 243 0.5 L...... 2.5 L...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 202 242 1 L........ 30 L....... B......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Alkylphenols, solid, n.o.s. (including C2-C12 homologues).... 8 UN2430 I CORROSIVE............. T8.............. None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 213 240 25 kg...... 100 kg..... A......
....... Alkylsulfuric acids.......................................... 8 UN2571 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 14
....... Allethrin, see Pesticides, liquid, toxic, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Allyl acetate................................................ 3 UN2333 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Allyl alcohol................................................ 6.1 UN1098 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, B77, T38,
T43, T45.
....... Allyl bromide................................................ 3 UN1099 I FLAMMABLE LIQUID, T18............. None 201 243 Forbidden.. 30 L....... B...... 40
POISON.
....... Allyl chloride............................................... 3 UN1100 I FLAMMABLE LIQUID, T18, T26........ None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Allyl chlorocarbonate, see Allyl chloroformate............... ........... .............. ...................... ................ ........... ........... .......
....... Allyl chloroformate.......................................... 6.1 UN1722 I POISON, FLAMMABLE 1, A3, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID, CORROSIVE. B30, B72, N41,
T38, T43, T44.
....... Allyl ethyl ether............................................ 3 UN2335 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Allyl formate................................................ 3 UN2336 I FLAMMABLE LIQUID, T18, T26........ None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Allyl glycidyl ether......................................... 3 UN2219 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Allyl iodide................................................. 3 UN1723 II FLAMMABLE LIQUID, A3, A6, N34, T18 None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
+...... Allyl isothiocyanate, stabilized............................. 6.1 UN1545 II POISON................ 2, A3, A7, B9, None 227 244 Forbidden.. 60 L....... D...... 40
B14, B32, B74,
T38, T43, T45.
....... Allylamine................................................... 6.1 UN2334 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, T38, T43,
T45.
....... Allyltrichlorosilane, stabilized............................. 8 UN1724 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... Aluminium processing by-products............................. 4.3 UN3170 II DANGEROUS WHEN WET.... ................ None 212 242 15 kg...... 50 kg...... B...... 85, 103
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 213 241 25 kg...... 100 kg..... B...... 85, 103
....... Aluminum alkyl halides....................................... 4.2 UN3052 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum alkyl hydrides...................................... 4.2 UN3076 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum alkyls.............................................. 4.2 UN3051 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum borohydride or Aluminum borohydride in devices...... 4.2 UN2870 I SPONTANEOUSLY B11............. None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Aluminum bromide, anhydrous.................................. 8 UN1725 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Aluminum bromide, solution................................... 8 UN2580 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Aluminum carbide............................................. 4.3 UN1394 II DANGEROUS WHEN WET.... A20, N41........ None 212 242 15 kg...... 50 kg...... A......
....... Aluminum chloride, anhydrous................................. 8 UN1726 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Aluminum chloride, solution.................................. 8 UN2581 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Aluminum dross, wet or hot................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Aluminum ferrosilicon powder................................. 4.3 UN1395 II DANGEROUS WHEN WET, A19............. None 212 242 15 kg...... 50 kg...... A...... 40, 85, 103
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, A19, A20........ None 213 241 25 kg...... 100 kg..... A...... 40, 85, 103
KEEP AWAY FROM FOOD.
....... Aluminum hydride............................................. 4.3 UN2463 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
D...... Aluminum, molten............................................. 9 NA9260 III CLASS 9............... ................ None None 247 Forbidden.. Forbidden.. D......
....... Aluminum nitrate............................................. 5.1 UN1438 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Aluminum phosphate solution, see Corrosive liquids, n.o.s.... ........... .............. ...................... ................ ........... ........... .......
....... Aluminum phosphide........................................... 4.3 UN1397 I DANGEROUS WHEN WET, A8, A19, N40.... None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Aluminum phosphide pesticides................................ 6.1 UN3048 I POISON................ A8.............. None 211 242 Forbidden.. 15 kg...... E...... 40, 85
....... Aluminum powder, coated...................................... 4.1 UN1309 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... A...... 13, 39, 101
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... A...... 13, 39, 101
....... Aluminum powder, uncoated.................................... 4.3 UN1396 II DANGEROUS WHEN WET.... A19, A20........ None 212 242 15 kg...... 50 kg...... A...... 39
............................................................. ........... .............. III DANGEROUS WHEN WET.... A19, A20........ None 213 241 25 kg...... 100 kg..... A...... 39
....... Aluminum resinate............................................ 4.1 UN2715 III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... A......
....... Aluminum silicon powder, uncoated............................ 4.3 UN1398 III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... A...... 40, 85, 103
....... Amatols, see Explosives, blasting, type B.................... ........... .............. ...................... ................ ........... ........... .......
....... Amines, flammable, corrosive, n.o.s. or Polyamines, 3 UN2733 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... D...... 40
flammable, corrosive, n.o.s.. CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T8, T31..... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, 8 UN2734 I CORROSIVE, FLAMMABLE A3, A6, N34, T8, None 201 243 0.5 L...... 2.5 L...... A......
liquid, corrosive, flammable, n.o.s.. LIQUID. T31.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE T8, T31......... None 202 243 1 L........ 30 L....... A......
LIQUID.
....... Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, 8 UN2735 I CORROSIVE............. A3, A6, B10, None 201 243 0.5 L...... 2.5 L...... A......
corrosive, n.o.s.. N34, T42.
............................................................. ........... .............. II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Amines, solid, corrosive, n.o.s., or Polyamines, solid, 8 UN3259 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... A......
corrosive n.o.s..
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... 2-Amino-4-chlorophenol....................................... 6.1 UN2673 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... 2-Amino-5-diethylaminopentane................................ 6.1 UN2946 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... 2-(2-Aminoethoxy) ethanol.................................... 8 UN3055 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... N-Aminoethylpiperazine....................................... 8 UN2815 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 12
....... Aminophenols (o-; m-; p-).................................... 6.1 UN2512 III KEEP AWAY FROM FOOD... T1.............. 153 213 240 100 kg..... 200 kg..... A......
....... Aminopropyldiethanolamine, see Alkylamines, n.o.s............ ........... .............. ...................... ................ ........... ........... .......
....... n-Aminopropylmorpholine, see Alkylamines, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Aminopyridines (o-; m-; p-).................................. 6.1 UN2671 II POISON................ T7.............. None 212 242 25 kg...... 100 kg..... B...... 12, 40
I...... Ammonia, anhydrous, liquefied or Ammonia solutions, relative 2.3 UN1005 POISON GAS............ 4............... None 304 314, 315 Forbidden.. 25 kg...... D...... 40, 57
density less than 0.880 at 15 degrees C in water, with more
than 50 percent ammonia.
D...... Ammonia, anhydrous, liquefied or Ammonia solutions, relative 2.2 UN1005 NONFLAMMABLE GAS...... 13.............. None 304 314, 315 Forbidden.. 25 kg...... D...... 40, 57
density less than 0.880 at 15 degrees C in water, with more
than 50 percent ammonia.
....... Ammonia solutions, relative density between 0.880 and 0.957 8 UN2672 III CORROSIVE............. T14............. 154 203 241 5 L........ 60 L....... A...... 40, 85
at 15 degrees C in water, with more than 10 percent but not
more than 35 percent ammonia.
....... Ammonia solutions, relative density less than 0.880 at 15 2.2 UN2073 NONFLAMMABLE GAS...... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40, 57
degrees C in water, with more than 35 percent but not more
than 50 percent ammonia.
....... Ammonium arsenate............................................ 6.1 UN1546 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ammonium azide............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium bifluoride, solid, see Ammonium hydrogen fluoride, ........... .............. ...................... ................ ........... ........... .......
solid.
....... Ammonium bifluoride solution, see Ammonium hydrogen fluoride, ........... .............. ...................... ................ ........... ........... .......
solution.
....... Ammonium bromate............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium chlorate............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium dichromate.......................................... 5.1 UN1439 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A......
....... Ammonium dinitro-o-cresolate................................. 6.1 UN1843 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... B...... 36, 65, 66,
77
....... Ammonium fluoride............................................ 6.1 UN2505 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Ammonium fluorosilicate...................................... 6.1 UN2854 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Ammonium fulminate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium hydrogen difluoride, solid.......................... 8 UN1727 II CORROSIVE............. N34............. 154 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
....... Ammonium hydrogen difluoride, solution....................... 8 UN2817 II CORROSIVE, POISON..... N34, T15........ None 202 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T8.............. 154 203 241 5 L........ 60 L....... B...... 40, 95
FROM FOOD.
....... Ammonium hydrogen sulfate.................................... 8 UN2506 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Ammonium hydrosulfide, solution, see Ammonium sulfide ........... .............. ...................... ................ ........... ........... .......
solution.
D...... Ammonium hydroxide, see Ammonia solutions, etc............... ........... .............. ...................... ................ ........... ........... .......
....... Ammonium metavanadate........................................ 6.1 UN2859 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Ammonium nitrate fertilizers................................. 5.1 NA2072 III OXIDIZER.............. 7............... 152 213 240 25 kg...... 100 kg..... B...... 48, 59, 60,
117
AW..... Ammonium nitrate fertilizers: uniform non-segregating 9 UN2071 III CLASS 9............... ................ 155 213 240 200 kg..... 200 kg..... A......
mixtures of nitrogen/phosphate or nitrogen/potash types or
complete fertilizers of nitrogen/ phosphate/potash type,
with not more than 70 percent ammonium nitrate and not more
than 0.4 percent total added combustible material or with
not more than 45 percent ammonium nitrate with unrestricted
combustible material.
D...... Ammonium nitrate-fuel oil mixture containing only prilled 1.5D NA0331 II EXPLOSIVE 1.5D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
ammonium nitrate and fuel oil.
....... Ammonium nitrate, liquid (hot concentrated solution)......... 5.1 UN2426 OXIDIZER.............. B5, T25......... None None 243 Forbidden.. Forbidden.. D...... 59, 60
D...... Ammonium nitrate mixed fertlizers............................ 5.1 NA2069 III OXIDIZER.............. 10.............. 152 213 240 25 kg...... 100 kg..... B...... 48, 59, 60,
117
....... Ammonium nitrate, with more than 0.2 percent combustible 1.1D UN0222 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
substances, including any organic substance calculated as
carbon, to the exclusion of any other added substance.
....... Ammonium nitrate, with not more than 0.2 percent of 5.1 UN1942 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 48, 59, 60,
combustible substances, including any organic substance 116
calculated as carbon, to the exclusion of any other added
substance.
....... Ammonium nitrite............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium perchlorate......................................... 1.1D UN0402 II EXPLOSIVE 1.1D........ 107............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Ammonium perchlorate......................................... 5.1 UN1442 II OXIDIZER.............. 107, A9......... 152 212 242 5 kg....... 25 kg...... E...... 58, 69, 106
....... Ammonium permanganate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium persulfate.......................................... 5.1 UN1444 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Ammonium picrate, dry or wetted with less than 10 percent 1.1D UN0004 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
water, by mass.
....... Ammonium picrate, wetted with not less than 10 percent water, 4.1 UN1310 I FLAMMABLE SOLID....... 23, A2, N41..... None 211 None 0.5 kg..... 0.5 kg..... D...... 28, 36
by mass.
....... Ammonium polysulfide, solution............................... 8 UN2818 II CORROSIVE, POISON..... T14............. None 202 243 1 L........ 30 L....... B...... 12, 26, 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T7.............. 154 203 241 5 L........ 60 L....... B...... 12, 26, 40
FROM FOOD.
....... Ammonium polyvanadate........................................ 6.1 UN2861 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ammonium silicofluoride, see Ammonium fluorosilicate......... ........... .............. ...................... ................ ........... ........... .......
....... Ammonium sulfide solution.................................... 8 UN2683 II CORROSIVE, POISON, T14............. None 202 243 1 L........ 30 L....... B...... 12, 22, 26,
FLAMMABLE LIQUID. 100
....... Ammunition, blank, see Cartridges for weapons, blank......... ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, illuminating with or without burster, expelling 1.2G UN0171 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
charge or propelling charge.
....... Ammunition, illuminating with or without burster, expelling 1.3G UN0254 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
charge or propelling charge.
....... Ammunition, illuminating with or without burster, expelling 1.4G UN0297 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
charge or propelling charge.
....... Ammunition, incendiary liquid or gel, with burster, expelling 1.3J UN0247 II EXPLOSIVE 1.3J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 13E,
charge or propelling charge. 23E
....... Ammunition, incendiary (water-activated contrivances) with ........... .............. ...................... ................ ........... ........... .......
burster, expelling charge or propelling charge, see
Contrivances, water-activated, etc..
....... Ammunition, incendiary, white phosphorus, with burster, 1.2H UN0243 II EXPLOSIVE 1.2H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
expelling charge or propelling charge. 15E, 17E
....... Ammunition, incendiary, white phosphorus, with burster, 1.3H UN0244 II EXPLOSIVE 1.3H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
expelling charge or propelling charge. 15E, 17E
....... Ammunition, incendiary with or without burster, expelling 1.2G UN0009 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
charge, or propelling charge.
....... Ammunition, incendiary with or without burster, expelling 1.3G UN0010 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
charge, or propelling charge.
....... Ammunition, incendiary with or without burster, expelling 1.4G UN0300 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
charge or propelling charge.
....... Ammunition, practice......................................... 1.4G UN0362 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Ammunition, practice......................................... 1.3G UN0488 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Ammunition, proof............................................ 1.4G UN0363 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Ammunition, rocket, see Warheads, rocket etc................. ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, SA (small arms), see Cartridges for weapons, etc. ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, smoke (water-activated contrivances), white ........... .............. ...................... ................ ........... ........... .......
phosphorus, with burster, expelling charge or propelling
charge, see Contrivances, water-activated, etc. (UN 0248).
....... Ammunition, smoke (water-activated contrivances), without ........... .............. ...................... ................ ........... ........... .......
white phosphorus or phosphides, with burster, expelling
charge or propelling charge, see Contrivances, water-
activated, etc. (UN 0249).
....... Ammunition smoke, white phosphorus with burster,expelling 1.2H UN0245 II EXPLOSIVE 1.2H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
charge, or propelling charge. 15E, 17E
....... Ammunition, smoke, white phosphorus with burster, expelling 1.3H UN0246 II EXPLOSIVE 1.3H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
charge, or propelling charge. 15E, 17E
....... Ammunition, smoke with or without burster, expelling charge 1.2G UN0015 II EXPLOSIVE 1.2G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, smoke with or without burster, expelling charge 1.3G UN0016 II EXPLOSIVE 1.3G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, smoke with or without burster, expelling charge 1.4G UN0303 II EXPLOSIVE 1.4G, ................ 62 None Forbidden.. 75 kg...... E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, sporting, see Cartridges for weapons, etc. (UN ........... .............. ...................... ................ ........... ........... .......
0012; UN 0328; UN 0339).
....... Ammunition, tear-producing, non-explosive, without burster or 6.1 UN2017 II POISON, CORROSIVE..... ................ None 212 None Forbidden.. 50 kg...... E...... 13, 40
expelling charge, non-fuzed.
....... Ammunition, tear-producing with burster, expelling charge or 1.2G UN0018 II EXPLOSIVE 1.2G, ................ 62 None Forbidden.. Forbidden.. E...... 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, tear-producing with burster, expelling charge or 1.3G UN0019 II EXPLOSIVE 1.3G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, tear-producing with burster, expelling charge or 1.4G UN0301 II EXPLOSIVE 1.4G, ................ 62 None Forbidden.. 75 kg...... E...... 17E, 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, toxic, non-explosive, without burster or 6.1 UN2016 II POISON................ ................ None 212 None Forbidden.. 100 kg..... E...... 13, 40
expelling charge, non-fuzed.
....... Ammunition, toxic (water-activated contrivances), with ........... .............. ...................... ................ ........... ........... .......
burster, expelling charge or propelling charge, see
Contrivances, water-activated, etc..
....... Ammunition, toxic with burster, expelling charge, or 1.2K UN0020 II EXPLOSIVE 1.2K, POISON ................ 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
propelling charge. 11E, 17E
....... Ammunition, toxic with burster, expelling charge, or 1.3K UN0021 II EXPLOSIVE 1.3K, POISON ................ 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
propelling charge. 11E, 17E
....... Amyl acetates................................................ 3 UN1104 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl acid phosphate.......................................... 8 UN2819 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Amyl alcohols................................................ 3 UN1105 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B3, T1...... 150 203 242 60 L....... 220 L...... A......
....... Amyl butyrates............................................... 3 UN2620 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl chlorides............................................... 3 UN1107 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Amyl formates................................................ 3 UN1109 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl mercaptans.............................................. 3 UN1111 II FLAMMABLE LIQUID...... A3, T8.......... None 202 242 5 L........ 60 L....... B...... 95, 102
....... Amyl methyl ketone........................................... 3 UN1110 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl nitrate................................................. 3 UN1112 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Amyl nitrites................................................ 3 UN1113 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 40
....... Amylamines................................................... 3 UN1106 II FLAMMABLE LIQUID, T1.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1.............. 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... n-Amylene.................................................... 3 UN1108 I FLAMMABLE LIQUID...... T14............. 150 201 243 1 L........ 30 L....... E......
....... Amyltrichlorosilane.......................................... 8 UN1728 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Anhydrous ammonia see Ammonia, anhydrous, liquefied.......... ........... .............. ...................... ................ ........... ........... .......
....... Anhydrous hydrofluoric acid, see Hydrogen fluoride, anhydrous ........... .............. ...................... ................ ........... ........... .......
+...... Aniline...................................................... 6.1 UN1547 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Aniline hydrochloride........................................ 6.1 UN1548 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Aniline oil, see Aniline..................................... ........... .............. ...................... ................ ........... ........... .......
....... Anisidines................................................... 6.1 UN2431 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Anisole...................................................... 3 UN2222 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Anisoyl chloride............................................. 8 UN1729 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... C...... 40
....... Anti-freeze, liquid, see Flammable liquids, n.o.s............ ........... .............. ...................... ................ ........... ........... .......
....... Antimonous chloride, see Antimony trichloride................ ........... .............. ...................... ................ ........... ........... .......
....... Antimony compounds, inorganic, liquid, n.o.s................. 6.1 UN3141 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Antimony compounds, inorganic, solid, n.o.s.................. 6.1 UN1549 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony lactate............................................. 6.1 UN1550 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony pentachloride, liquid............................... 8 UN1730 II CORROSIVE............. B2, T8, T26..... None 202 242 1 L........ 30 L....... C...... 40
....... Antimony pentachloride, solutions............................ 8 UN1731 II CORROSIVE............. B2, T8, T27..... 154 202 242 1 L........ 30 L....... C...... 40
............................................................. ........... .............. III CORROSIVE............. T7, T26......... 154 203 241 5 L........ 60 L....... C...... 40
....... Antimony pentafluoride....................................... 8 UN1732 II CORROSIVE, POISON..... A3, A6, A7, A10, None 202 243 Forbidden.. 30 L....... D...... 40
N3, T12, T26.
....... Antimony potassium tartrate.................................. 6.1 UN1551 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony powder.............................................. 6.1 UN2871 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony sulfide and a chlorate, mixtures of................. Forbidden .............. ...................... ................ ........... ........... .......
....... Antimony sulfide, solid, see Antimony compounds, inorganic, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
D...... Antimony tribromide, solid................................... 8 NA1549 II CORROSIVE............. ................ 154 212 240 25 kg...... 100 kg..... A...... 13
D...... Antimony tribromide, solution................................ 8 NA1549 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 13
....... Antimony trichloride, liquid................................. 8 UN1733 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 40
....... Antimony trichloride, solid.................................. 8 UN1733 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 40
D...... Antimony trifluoride, solid.................................. 8 NA1549 II CORROSIVE............. ................ 154 212 240 25 kg...... 25 kg...... A...... 13
D...... Antimony trifluoride solution................................ 8 NA1549 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 13
....... Aqua ammonia, see Ammonia solution, etc...................... ........... .............. ...................... ................ ........... ........... .......
....... Argon, compressed............................................ 2.2 UN1006 NONFLAMMABLE GAS...... ................ 306 302 314, 315 75 kg...... 150 kg..... A......
....... Argon, refrigerated liquid (cryogenic liquid)................ 2.2 UN1951 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... B......
....... Arsenic...................................................... 6.1 UN1558 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic acid, liquid......................................... 6.1 UN1553 I POISON................ T18, T27........ None 201 243 1 L........ 30 L....... B...... 46
....... Arsenic acid, solid.......................................... 6.1 UN1554 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic bromide.............................................. 6.1 UN1555 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12, 40
....... Arsenic chloride, see Arsenic trichloride.................... ........... .............. ...................... ................ ........... ........... .......
....... Arsenic compounds, liquid, n.o.s. including arsenates n.o.s.; 6.1 UN1556 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic
compounds of arsenic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... B...... 40
....... Arsenic compounds, solid, n.o.s. including arsenates, n.o.s.; 6.1 UN1557 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic
compounds of arsenic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Arsenic pentoxide............................................ 6.1 UN1559 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Arsenic sulfide.............................................. 6.1 NA1557 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic sulfide and a chlorate, mixtures of.................. Forbidden .............. ...................... ................ ........... ........... .......
....... Arsenic trichloride.......................................... 6.1 UN1560 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
B74, T38, T43,
T45.
....... Arsenic trioxide............................................. 6.1 UN1561 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Arsenic trisulfide........................................... 6.1 NA1557 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic, white, solid, see Arsenic trioxide.................. ........... .............. ...................... ................ ........... ........... .......
....... Arsenical dust............................................... 6.1 UN1562 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenical pesticides, liquid, flammable, toxic, flash point 3 UN2760 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Arsenical pesticides, liquid, toxic.......................... 6.1 UN2994 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Arsenical pesticides, liquid, toxic, flammable flashpoint not 6.1 UN2993 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Arsenical pesticides, solid, toxic........................... 6.1 UN2759 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Arsenious acid, solid, see Arsenic trioxide.................. ........... .............. ...................... ................ ........... ........... .......
....... Arsenious and mercuric iodide solution, see Arsenic ........... .............. ...................... ................ ........... ........... .......
compounds, liquid, n.o.s..
....... Arsine....................................................... 2.3 UN2188 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Articles, explosive, extremely insensitive or Articles, EEI.. 1.6N UN0486 II EXPLOSIVE 1.6N........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.4S UN0349 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 100 kg..... A......
....... Articles, explosive, n.o.s................................... 1.4B UN0350 II EXPLOSIVE 1.4B........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4C UN0351 II EXPLOSIVE 1.4C........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4D UN0352 II EXPLOSIVE 1.4D........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4G UN0353 II EXPLOSIVE 1.4G........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.1L UN0354 II EXPLOSIVE 1.1L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.2L UN0355 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.3L UN0356 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.1C UN0462 II EXPLOSIVE 1.1C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1D UN0463 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1E UN0464 II EXPLOSIVE 1.1E........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1F UN0465 II EXPLOSIVE 1.1F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, explosive, n.o.s................................... 1.2C UN0466 II EXPLOSIVE 1.2C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2D UN0467 II EXPLOSIVE 1.2D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2E UN0468 II EXPLOSIVE 1.2E........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2F UN0469 II EXPLOSIVE 1.2F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, explosive, n.o.s................................... 1.3C UN0470 II EXPLOSIVE 1.3C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.4E UN0471 II EXPLOSIVE 1.4E........ 101............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Articles, explosive, n.o.s................................... 1.4F UN0472 II EXPLOSIVE 1.4F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, pressurized pneumatic or Hydraulic containing non- 2.2 UN3164 NONFLAMMABLE GAS...... ................ 306 302, 304 None No limit... No limit... A......
flammable gas.
....... Articles, pyrophoric......................................... 1.2L UN0380 II EXPLOSIVE 1.2L........ ................ None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, pyrotechnic for technical purposes................. 1.1G UN0428 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.2G UN0429 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.3G UN0430 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.4G UN0431 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Articles, pyrotechnic for technical purposes................. 1.4S UN0432 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Asbestos..................................................... 9 NA2212 III CLASS 9............... ................ 155 216 240 200 kg..... 200 kg..... A...... 34, 40
....... Ascaridole (organic peroxide)................................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Asphalt, at or above its flashpoint.......................... 3 NA1999 III FLAMMABLE LIQUID...... ................ 150 203 247 Forbidden.. Forbidden.. D......
D...... Asphalt, cut back, see Tars, liquid, etc..................... ........... .............. ...................... ................ ........... ........... .......
....... Automobile, motorcycle, tractor, or other self-propelled ........... .............. ...................... ................ ........... ........... .......
vehicle, engine, or other mechanical apparatus. see
Vehicles, self-propelled.
....... Azaurolic acid (salt of) (dry)............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azido guanidine picrate (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 5-Azido-1-hydroxy tetrazole.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Azido hydroxy tetrazole (mercury and silver salts)........... Forbidden .............. ...................... ................ ........... ........... .......
....... 3-Azido-1,2-Propylene glycol dinitrate....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azidodithiocarbonic acid..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azidoethyl nitrate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Aziridinyl phosphine oxide-(tris), see Tris-(1-aziridinyl) ........... .............. ...................... ................ ........... ........... .......
phosphine oxide, solution.
....... Azodicarbonamide............................................. 4.1 UN3242 II FLAMMABLE SOLID....... ................ 151 212 240 Forbidden.. Forbidden.. D...... 12, 61, 74
....... Azotetrazole (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Barium....................................................... 4.3 UN1400 II DANGEROUS WHEN WET.... A19............. None 212 241 15 kg...... 50 kg...... E......
....... Barium alloys, pyrophoric.................................... 4.2 UN1854 I SPONTANEOUSLY ................ None 181 None Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Barium azide, dry or wetted with less than 50 percent water, 1.1A UN0224 II EXPLOSIVE 1.1A, POISON 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
by mass.
....... Barium azide, wetted with not less than 50 percent water, by 4.1 UN1571 I FLAMMABLE SOLID, A2.............. None 182 None Forbidden.. 0.5 kg..... D...... 28
mass. POISON.
....... Barium bromate............................................... 5.1 UN2719 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium chlorate.............................................. 5.1 UN1445 II OXIDIZER, POISON...... A9, N34, T8..... None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium compounds, n.o.s...................................... 6.1 UN1564 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Barium cyanide............................................... 6.1 UN1565 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 26, 40
....... Barium hypochlorite with more than 22 percent available 5.1 UN2741 II OXIDIZER, POISON...... A7, A9, N34..... 152 212 None 5 kg....... 25 kg...... B...... 56, 58, 106
chlorine.
....... Barium nitrate............................................... 5.1 UN1446 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Barium oxide................................................. 6.1 UN1884 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Barium perchlorate........................................... 5.1 UN1447 II OXIDIZER, POISON...... T8.............. None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium permanganate.......................................... 5.1 UN1448 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Barium peroxide.............................................. 5.1 UN1449 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Barium selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Barium selenite, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
D...... Barium styphnate............................................. 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Batteries, containing sodium................................. 4.3 UN3292 II DANGEROUS WHEN WET.... ................ 189 189 189 Forbidden.. No limit... A......
....... Batteries, dry, containing potassium hydroxide solid, 8 UN3028 III CORROSIVE............. ................ None 213 None 25 kg gross 230 kg A......
electric, storage. gross.
....... Batteries, wet, filled with acid, electric storage........... 8 UN2794 III CORROSIVE............. ................ 159 159 None 25 kg gross No limit... A......
....... Batteries, wet, filled with alkali, electric storage......... 8 UN2795 III CORROSIVE............. ................ 159 159 None 25 kg gross No limit... A......
....... Batteries, wet, non-spillable, electric storage.............. 8 UN2800 III CORROSIVE............. ................ 159 159 None No Limit... No Limit... A......
....... Battery, dry, not subject to the requirements of this ........... .............. ...................... ................ ........... ........... .......
subchapter.
....... Battery fluid, alkali........................................ 8 UN2797 II CORROSIVE............. B2, N6, T8...... 154 202 242 1 L........ 30 L....... A......
....... Battery lithium type, see Lithium batteries etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Battery-powered vehicle or Battery-powered equipment wet 9 UN3171 CLASS 9............... ................ 220 220 None No limit... No limit... A......
battery.
....... Battery, wet, filled with acid or alkali with automobile (or ........... .............. ...................... ................ ........... ........... .......
named self-propelled vehicle or mechanical equipment
containing internal combustion engine) see Vehicles, self-
propelled etc..
....... Battery, wet, with wheelchair, see Wheelchair, electric...... ........... .............. ...................... ................ ........... ........... .......
....... Benzaldehyde................................................. 9 UN1990 III CLASS 9............... ................ 155 203 241 100 L...... 220 L...... A......
....... Benzene...................................................... 3 UN1114 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Benzene diazonium chloride (dry)............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Benzene diazonium nitrate (dry).............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Benzene phosphorus dichloride, see Phenyl phosphorus ........... .............. ...................... ................ ........... ........... .......
dichloride.
....... Benzene phosphorus thiodichloride, see Phenyl phosphorus ........... .............. ...................... ................ ........... ........... .......
thiodichloride.
....... Benzene sulfonyl chloride.................................... 8 UN2225 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Benzene triozonide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Benzenethiol, see Phenyl mercaptan........................... ........... .............. ...................... ................ ........... ........... .......
....... Benzidine.................................................... 6.1 UN1885 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Benzoic derivative pesticides, liquid, flammable, toxic, 3 UN2770 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E......
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Benzoic derivative pesticides, liquid, toxic................. 6.1 UN3004 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Benzoic derivative pesticides, liquid, toxic, flammable, 6.1 UN3003 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Benzoic derivative pesticides, solid toxic................... 6.1 UN2769 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Benzol, see Benzene.......................................... ........... .............. ...................... ................ ........... ........... .......
....... Benzonitrile................................................. 6.1 UN2224 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 26, 40
....... Benzoquinone................................................. 6.1 UN2587 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Benzotrichloride............................................. 8 UN2226 II CORROSIVE............. B2, T15......... 154 202 242 1 L........ 30 L....... A...... 40
....... Benzotrifluoride............................................. 3 UN2338 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Benzoxidiazoles (dry)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Benzoyl azide................................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Benzoyl chloride............................................. 8 UN1736 II CORROSIVE............. B2, T9, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Benzyl bromide............................................... 6.1 UN1737 II POISON, CORROSIVE..... A3, A7, N33, None 202 243 1 L........ 30 L....... D...... 13, 40
N34, T12, T26.
....... Benzyl chloride.............................................. 6.1 UN1738 II POISON, CORROSIVE..... A3, A7, B41, None 202 243 1 L........ 30 L....... D...... 13, 40
B70, N33, N43,
T12, T26.
....... Benzyl chloride unstabilized................................. 6.1 UN1738 II POISON, CORROSIVE..... A3, A7, B8, B11, None 202 243 1 L........ 30 L....... D...... 13, 40
N33, N34, N43,
T12, T26.
....... Benzyl chloroformate......................................... 8 UN1739 I CORROSIVE............. A3, A6, B4, N41, None 201 243 Forbidden.. 2.5 L...... D...... 40
T18, T26.
....... Benzyl iodide................................................ 6.1 UN2653 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B...... 12, 40
....... Benzyldimethylamine.......................................... 8 UN2619 II CORROSIVE, FLAMMABLE B2, T1.......... 154 202 243 1 L........ 30 L....... A...... 40, 48
LIQUID.
....... Benzylidene chloride......................................... 6.1 UN1886 II POISON................ T8.............. None 202 243 5 L........ 60 L....... D...... 40
....... Beryllium compounds, n.o.s................................... 6.1 UN1566 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Beryllium nitrate............................................ 5.1 UN2464 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Beryllium, powder............................................ 6.1 UN1567 II POISON, FLAMMABLE ................ None 212 242 15 kg...... 50 kg...... A......
SOLID.
....... Biphenyl triozonide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Bipyridilium pesticides, liquid, flammable, toxic, flash 3 UN2782 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E......
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Bipyridilium pesticides, liquid, toxic....................... 6.1 UN3016 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Bipyridilium pesticides, liquid, toxic, flammable, flashpoint 6.1 UN3015 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 21, 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 21, 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 21, 40
FLAMMABLE LIQUID.
....... Bipyridilium pesticides, solid, toxic........................ 6.1 UN2781 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Bis (Aminopropyl) piperazine, see Corrosive liquid, n.o.s.... ........... .............. ...................... ................ ........... ........... .......
....... Bisulfate, aqueous solution.................................. 8 UN2837 II CORROSIVE............. A7, B2, N34, T8, 154 202 242 1 L........ 30 L....... A......
T26.
............................................................. ........... .............. III CORROSIVE............. A7, N34, T7, T26 154 203 241 5 L........ 60 L....... A......
....... Bisulfites, aqueous solutions, n.o.s......................... 8 UN2693 III CORROSIVE............. T8.............. 154 203 241 1 L........ 30 L....... A...... 26, 40
....... Black powder, compressed or Gunpowder, compressed or Black 1.1D UN0028 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
powder, in pellets or Gunpowder, in pellets.
....... Black powder or Gunpowder, granular or as a meal............. 1.1D UN0027 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Blasting agent, n.o.s., see Explosives, blasting etc......... ........... .............. ...................... ................ ........... ........... .......
....... Blasting cap assemblies, see Detonator assemblies, non- ........... .............. ...................... ................ ........... ........... .......
electric, for blasting.
....... Blasting caps, electric, see Detonators, electric for ........... .............. ...................... ................ ........... ........... .......
blasting.
....... Blasting caps, non-electric, see Detonators, non-electric, ........... .............. ...................... ................ ........... ........... .......
for blasting.
....... Bleaching powder, see Calcium hypochlorite mixtures, etc..... ........... .............. ...................... ................ ........... ........... .......
I...... Blue asbestos (Crocidolite) or Brown asbestos (amosite, 9 UN2212 II CLASS 9............... ................ 155 216 240 Forbidden.. Forbidden.. A...... 34, 40
mysorite).
....... Bombs, photo-flash........................................... 1.1F UN0037 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs, photo-flash........................................... 1.1D UN0038 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, photo-flash........................................... 1.2G UN0039 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, photo-flash........................................... 1.3G UN0299 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, smoke, non-explosive, with corrosive liquid, without 8 UN2028 II CORROSIVE............. ................ None 160 None Forbidden.. 50 kg...... E...... 40
initiating device.
....... Bombs, with bursting charge.................................. 1.1F UN0033 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs, with bursting charge.................................. 1.1D UN0034 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Bombs, with bursting charge.................................. 1.2D UN0035 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Bombs, with bursting charge.................................. 1.2F UN0291 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs with flammable liquid, with bursting charge............ 1.1J UN0399 II EXPLOSIVE 1.1J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Bombs with flammable liquid, with bursting charge............ 1.2J UN0400 II EXPLOSIVE 1.2J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
D...... Boosters with detonator...................................... 1.4B NA0350 II EXPLOSIVE 1.4B........ 115............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Boosters with detonator...................................... 1.1B UN0225 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Boosters with detonator...................................... 1.2B UN0268 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 7E
....... Boosters, without detonator.................................. 1.1D UN0042 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Boosters, without detonator.................................. 1.2D UN0283 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Borate and chlorate mixtures, see Chlorate and borate ........... .............. ...................... ................ ........... ........... .......
mixtures.
....... Borneol...................................................... 4.1 UN1312 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
+...... Boron tribromide............................................. 8 UN2692 I CORROSIVE, POISON..... 2, A3, A7, B9, None 227 244 Forbidden.. 2.5 L...... C...... 12
B14, B32, B74,
N34, T38, T43,
T45.
....... Boron trichloride............................................ 2.3 UN1741 POISON GAS, CORROSIVE. 3, 25, B9, B14.. None 304 314 Forbidden.. Forbidden.. D...... 25, 40
....... Boron trifluoride............................................ 2.3 UN1008 POISON GAS............ 2, B9, B14...... None 302 314, 315 Forbidden.. Forbidden.. D...... 40
....... Boron trifluoride acetic acid complex........................ 8 UN1742 II CORROSIVE............. B2, B6, T9, T27. 154 202 242 1 L........ 30 L....... A......
....... Boron trifluoride diethyl etherate........................... 8 UN2604 I CORROSIVE, FLAMMABLE A19, T8, T26.... None 201 243 0.5 L...... 2.5 L...... D...... 40
LIQUID.
....... Boron trifluoride dihydrate.................................. 8 UN2851 II CORROSIVE............. T9, T27......... 154 212 240 15 kg...... 50 kg...... B...... 12, 40,
....... Boron trifluoride dimethyl etherate.......................... 4.3 UN2965 I DANGEROUS WHEN WET, A19, T12, T26... None 201 243 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE 49, 100
LIQUID.
....... Boron trifluoride propionic acid complex..................... 8 UN1743 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... A......
....... Box toe gum, see Nitrocellulose etc.......................... ........... .............. ...................... ................ ........... ........... .......
....... Bromates, inorganic, aqueous solution, n.o.s................. 5.1 UN3213 II OXIDIZER.............. T8.............. 152 2O2 242 1 L........ 5 L........ B...... 56, 58, 106
....... Bromates, inorganic, n.o.s................................... 5.1 UN1450 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Bromine azide................................................ Forbidden .............. ...................... ................ ........... ........... .......
+...... Bromine or Bromine solutions................................. 8 UN1744 I CORROSIVE, POISON..... 1, A3, A6, B9, None 226 249 Forbidden.. 2.5 L...... D...... 12, 40, 66,
B12, B64, B85, 74, 89, 90
N34, N43, T18,
T41.
....... Bromine chloride............................................. 2.3 UN2901 POISON GAS, CORROSIVE, 2, B9, B12, B14. None 304 314, 315 Forbidden.. Forbidden.. D...... 40, 89, 90
OXIDIZER.
+...... Bromine pentafluoride........................................ 5.1 UN1745 I OXIDIZER, POISON, 1, B9, B14, B30, None 228 244 Forbidden.. Forbidden.. D...... 25, 40, 66,
CORROSIVE. B72, T38, T43, 90
T44.
+...... Bromine trifluoride.......................................... 5.1 UN1746 I OXIDIZER, POISON, 2, B9, B14, B32, None 228 244 Forbidden.. Forbidden.. D...... 25, 40, 66,
CORROSIVE. B74, T38, T43, 90
T45.
....... 4-Bromo-1,2-dinitrobenzene................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C.)....... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Bromo-3-methylbutane....................................... 3 UN2341 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... 1-Bromo-3-nitrobenzene (unstable at 56 degrees C)............ Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Bromo-2-nitropropane-1,3-diol.............................. 6.1 UN3241 III KEEP AWAY FROM FOOD... 46.............. 153 213 240 50 kg...... 50 kg...... C...... 12, 25, 40
....... Bromoacetic acid, solid...................................... 8 UN1938 II CORROSIVE............. A7, N34, T9..... 154 212 240 15 kg...... 50 kg...... A......
....... Bromoacetic acid, solution................................... 8 UN1938 II CORROSIVE............. B2, T9.......... 154 202 242 1 L........ 30 L....... A...... 40
+...... Bromoacetone................................................. 6.1 UN1569 II POISON................ 2............... None 193 245 Forbidden.. Forbidden.. D...... 40
....... Bromoacetyl bromide.......................................... 8 UN2513 II CORROSIVE............. B2, T9, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Bromobenzene................................................. 3 UN2514 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Bromobenzyl cyanides, liquid................................. 6.1 UN1694 I POISON................ T18............. None 201 243 Forbidden.. 30 L....... D...... 12, 40
....... Bromobenzyl cyanides, solid.................................. 6.1 UN1694 I POISON................ T18............. None 211 242 Forbidden.. 50 kg...... D...... 12, 40
....... 2-Bromobutane................................................ 3 UN2339 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B...... 40
....... Bromochloromethane........................................... 6.1 UN1887 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Bromoethyl ethyl ether..................................... 3 UN2340 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Bromoform.................................................... 6.1 UN2515 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 12, 40
....... Bromomethylpropanes.......................................... 3 UN2342 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
....... 2-Bromopentane............................................... 3 UN2343 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 2-Bromopropanes.............................................. 3 UN2344 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... 3-Bromopropyne............................................... 3 UN2345 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... D...... 40
....... Bromosilane.................................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Bromotoluene-alpha, see Benzyl bromide....................... ........... .............. ...................... ................ ........... ........... .......
....... Bromotrifluoroethylene....................................... 2.1 UN2419 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Bromotrifluoromethane, R13B1................................. 2.2 UN1009 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Brucine...................................................... 6.1 UN1570 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
....... Bursters, explosive.......................................... 1.1D UN0043 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Butadienes, inhibited........................................ 2.1 UN1010 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Butane or Butane mixtures see also Petroleum gases, liquefied 2.1 UN1011 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Butane, butane mixtures and mixtures having similar ........... .............. ...................... ................ ........... ........... .......
properties in cartridges each not exceeding 500 grams, see
Receptacles, etc..
....... Butanedione.................................................. 3 UN2346 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 1,2,4-Butanetriol trinitrate................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Butanols..................................................... 3 UN1120 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... tert-Butoxycarbonyl azide.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Butoxyl...................................................... 3 UN2708 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl acetates............................................... 3 UN1123 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl acid phosphate......................................... 8 UN1718 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Butyl alcohols, see Butanols................................. ........... .............. ...................... ................ ........... ........... .......
....... Butyl benzenes............................................... 3 UN2709 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... n-Butyl bromide.............................................. 3 UN1126 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B...... 40
....... n-Butyl chloride, see Chlorobutanes.......................... ........... .............. ...................... ................ ........... ........... .......
D...... sec-Butyl chloroformate...................................... 6.1 NA2742 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 22,
LIQUID, CORROSIVE. B74, T38, T43, 25, 40,
T45. 48, 100
....... n-Butyl chloroformate........................................ 6.1 UN2743 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 21,
B74, T38, T43, 25, 40,
T45. 100
....... Butyl ethers, see Dibutyl ethers............................. ........... .............. ...................... ................ ........... ........... .......
....... Butyl ethyl ether, see Ethyl butyl ether..................... ........... .............. ...................... ................ ........... ........... .......
....... n-Butyl formate.............................................. 3 UN1128 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... tert-Butyl hydroperoxide, with more than 90 percent with Forbidden .............. ...................... ................ ........... ........... .......
water.
....... tert-Butyl hypochlorite...................................... 4.2 UN3255 I SPONTANEOUSLY ................ None 211 243 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
CORROSIVE.
....... N-n-Butyl imidazole.......................................... 6.1 UN2690 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... Tert-Butyl isocyanate........................................ 6.1 UN2484 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B72, T38,
T43, T44.
....... n-Butyl isocyanate........................................... 6.1 UN2485 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. 30 L....... D...... 40
LIQUID. B30, B72, B77,
T38, T43, T44.
....... Butyl mercaptans............................................. 3 UN2347 II FLAMMABLE LIQUID...... A3, T8.......... 150 202 242 5 L........ 60 L....... D...... 26, 95
....... n-Butyl methacrylate......................................... 3 UN2227 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl methyl ether........................................... 3 UN2350 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Butyl nitrites............................................... 3 UN2351 I FLAMMABLE LIQUID...... T8.............. 150 201 243 1 L........ 30 L....... E...... 40
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A...... 40
....... tert-Butyl peroxyacetate, with more than 76 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... n-Butyl peroxydicarbonate, with more than 52 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... tert-Butyl peroxyisobutyrate, with more than 77 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Butyl phosphoric acid, see Butyl acid phosphate.............. ........... .............. ...................... ................ ........... ........... .......
....... 5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene.......... 4.1 UN2956 III FLAMMABLE SOLID....... ................ None 214 None Forbidden.. Forbidden.. D...... 12
....... Butyl vinyl ether, inhibited................................. 3 UN2352 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Butylacrylate................................................ 3 UN2348 III FLAMMABLE LIQUID...... B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
....... n-Butylamine................................................. 3 UN1125 II FLAMMABLE LIQUID, T8.............. None 202 242 1 L........ 5 L........ B...... 40
CORROSIVE.
....... N-Butylaniline............................................... 6.1 UN2738 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... tert-Butylcyclohexylchloroformate............................ 6.1 UN2747 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 12, 13, 25
....... Butylene see also Petroleum gases, liquefied................. 2.1 UN1012 FLAMMABLE GAS......... 19.............. None 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... 1,2-Butylene oxide, stabilized............................... 3 UN3022 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 49
....... Butylpropionate.............................................. 3 UN1914 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyltoluenes................................................ 6.1 UN2667 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Butyltrichlorosilane......................................... 8 UN1747 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... 1,4-Butynediol............................................... 6.1 UN2716 III KEEP AWAY FROM FOOD... A1.............. None 213 240 100 kg..... 200 kg..... A...... 61, 70
....... Butyraldehyde................................................ 3 UN1129 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Butyraldoxime................................................ 3 UN2840 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyric acid................................................. 8 UN2820 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A...... 12
....... Butyric anhydride............................................ 8 UN2739 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Butyronitrile................................................ 3 UN2411 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Butyryl chloride............................................. 3 UN2353 II FLAMMABLE LIQUID, T9, T26......... None 202 243 1 L........ 5 L........ C...... 40
CORROSIVE.
....... Cacodylic acid............................................... 6.1 UN1572 II POISON................ ................ None 212 242 25 kg...... 100 kg..... E...... 26
....... Cadmium compounds............................................ 6.1 UN2570 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Caesium hydroxide............................................ 8 UN2682 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Caesium hydroxide solution................................... 8 UN2681 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Calcium...................................................... 4.3 UN1401 II DANGEROUS WHEN WET.... ................ None 212 241 15 kg...... 50 kg...... E......
....... Calcium arsenate............................................. 6.1 UN1573 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Calcium arsenate and calcium arsenite, mixtures, solid....... 6.1 UN1574 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Calcium arsenite, solid...................................... 6.1 NA1574 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Calcium bisulfite solution, see Bisulfites, inorganic, ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Calcium carbide.............................................. 4.3 UN1402 I DANGEROUS WHEN WET.... A1, A8, B55, N34 None 211 242 Forbidden.. 15 kg...... B......
............................................................. ........... .............. II DANGEROUS WHEN WET.... A1, A8, B55, N34 None 212 241 15 kg...... 50 kg...... B......
....... Calcium chlorate............................................. 5.1 UN1452 II OXIDIZER.............. N34............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium chlorate aqueous solution............................ 5.1 UN2429 II OXIDIZER.............. A2, N41, T8..... 152 202 242 1 L........ 5 L........ B...... 56, 58, 106
....... Calcium chlorite............................................. 5.1 UN1453 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium cyanamide with more than 0.1 percent of calcium 4.3 UN1403 III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... A......
carbide.
....... Calcium cyanide.............................................. 6.1 UN1575 I POISON................ N79, N80........ None 211 242 5 kg....... 50 kg...... A...... 26, 40
....... Calcium dithionite or Calcium hydrosulfite................... 4.2 UN1923 II SPONTANEOUSLY A19, A20........ None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Calcium hydride.............................................. 4.3 UN1404 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Calcium hydrosulfite, see Calcium dithionite................. ........... .............. ...................... ................ ........... ........... .......
....... Calcium hypochlorite, dry or Calcium hypochlorite mixtures 5.1 UN1748 II OXIDIZER.............. A7, A9, N34..... 152 212 None 5 kg....... 25 kg...... D...... 48, 56, 58,
dry with more than 39 percent available chlorine (8.8 69, 106,
percent available oxygen). 118
....... Calcium hypochlorite, hydrated or Calcium hypochlorite, 5.1 UN2880 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 50, 56, 58,
hydrated mixtures, with not less than 5.5 percent but not 69, 106
more than 10 percent water.
....... Calcium hypochlorite mixtures, dry, with more than 10 percent 5.1 UN2208 III OXIDIZER.............. A1, A29, N34.... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 69,
but not more than 39 percent available chlorine. 106
....... Calcium manganese silicon.................................... 4.3 UN2844 III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... A...... 85, 103
....... Calcium nitrate.............................................. 5.1 UN1454 III OXIDIZER.............. 34.............. 152 213 240 25 kg...... 100 kg..... A......
A...... Calcium oxide................................................ 8 UN1910 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Calcium perchlorate.......................................... 5.1 UN1455 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium permanganate......................................... 5.1 UN1456 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Calcium peroxide............................................. 5.1 UN1457 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Calcium phosphide............................................ 4.3 UN1360 I DANGEROUS WHEN WET, A8, A19, N40.... None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Calcium, pyrophoric or Calcium alloys, pyrophoric............ 4.2 UN1855 I SPONTANEOUSLY ................ None 187 None Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Calcium resinate............................................. 4.1 UN1313 III FLAMMABLE SOLID....... A1, A19......... None 213 240 25 kg...... 100 kg..... A......
....... Calcium resinate, fused...................................... 4.1 UN1314 III FLAMMABLE SOLID....... A1, A19......... None 213 240 25 kg...... 100 kg..... A......
....... Calcium selenate, see Selenates or Selenites................. ........... .............. ...................... ................ ........... ........... .......
....... Calcium silicide............................................. 4.3 UN1405 II DANGEROUS WHEN WET.... A19............. None 212 241 15 kg...... 50 kg...... B...... 85, 103
............................................................. ........... .............. III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... B...... 85, 103
....... Camphor oil.................................................. 3 UN1130 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Camphor, synthetic........................................... 4.1 UN2717 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
....... Cannon primers, see Primers, tubular......................... ........... .............. ...................... ................ ........... ........... .......
....... Caproic acid................................................. 8 UN2829 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A......
....... Caps, blasting, see Detonators, etc.......................... ........... .............. ...................... ................ ........... ........... .......
....... Carbamate pesticides, liquid, flammable, toxic, flash point 3 UN2758 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Carbamate pesticides, liquid, toxic.......................... 6.1 UN2992 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Carbamate pesticides, liquid, toxic, flammable, flash point 6.1 UN2991 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Carbamate pesticides, solid, toxic........................... 6.1 UN2757 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Carbolic acid, see Phenol, solid or Phenol, molten........... ........... .............. ...................... ................ ........... ........... .......
....... Carbolic acid solutions, see Phenol solutions................ ........... .............. ...................... ................ ........... ........... .......
I...... Carbon, activated............................................ 4.2 UN1362 III SPONTANEOUSLY ................ None 213 241 0.5 kg..... 0.5 kg..... A...... 12
COMBUSTIBLE.
I...... Carbon, animal or vegetable origin........................... 4.2 UN1361 II SPONTANEOUSLY ................ None 212 242 Forbidden.. Forbidden.. A...... 12
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A...... 12
COMBUSTIBLE.
....... Carbon bisulfide, see Carbon disulfide....................... ........... .............. ...................... ................ ........... ........... .......
....... Carbon dioxide............................................... 2.2 UN1013 NONFLAMMABLE GAS...... ................ 306 302, 304 302, 314, 75 kg...... 150 kg..... A......
315
....... Carbon dioxide and nitrous oxide mixtures.................... 2.2 UN1015 NONFLAMMABLE GAS...... ................ 306 None 314, 315 75 kg...... 150 kg..... A......
....... Carbon dioxide and oxygen mixtures........................... 2.2 UN1014 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Carbon dioxide, refrigerated liquid.......................... 2.2 UN2187 NONFLAMMABLE GAS...... B43............. 306 304 314, 315 50 kg...... 500 kg..... B......
AW..... Carbon dioxide, solid or Dry ice............................. 9 UN1845 III None.................. B12............. 217 217 240 200 kg..... 200 kg..... C...... 40
....... Carbon disulfide............................................. 3 UN1131 I FLAMMABLE LIQUID, B16, T18, T26, None 201 243 Forbidden.. Forbidden.. D...... 18, 40, 115
POISON. T29.
....... Carbon monoxide.............................................. 2.3 UN1016 POISON GAS, FLAMMABLE 4............... None 302 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Carbon monoxide and hydrogen mixture......................... 2.3 UN2600 POISON GAS, FLAMMABLE 6............... None 302 302 Forbidden.. Forbidden.. D...... 40
GAS.
D...... Carbon monoxide, refrigerated liquid (cryogenic liquid)...... 2.3 NA9202 POISON GAS, FLAMMABLE 4............... None 316 318 Forbidden.. Forbidden.. D......
GAS.
....... Carbon tetrabromide.......................................... 6.1 UN2516 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 25
....... Carbon tetrachloride......................................... 6.1 UN1846 II POISON................ N36, T8......... None 202 243 5 L........ 60 L....... A...... 40
....... Carbonyl chloride, see Phosgene.............................. ........... .............. ...................... ................ ........... ........... .......
....... Carbonyl fluoride............................................ 2.3 UN2417 POISON GAS, CORROSIVE. 2............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Carbonyl sulfide............................................. 2.3 UN2204 POISON GAS, FLAMMABLE 3, 25, B14...... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Cartridge cases, empty primed, see Cases, cartridge, empty, ........... .............. ...................... ................ ........... ........... .......
with primer.
....... Cartridges, actuating, for aircraft ejector seat catapult, ........... .............. ...................... ................ ........... ........... .......
fire extinguisher, canopy removal or apparatus, see
Cartridges, power device.
....... Cartridges, explosive, see Charges, demolition............... ........... .............. ...................... ................ ........... ........... .......
....... Cartridges, flash............................................ 1.1G UN0049 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, flash............................................ 1.3G UN0050 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges for weapons, blank................................ 1.1C UN0326 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, blank................................ 1.2C UN0413 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, blank or Cartridges, small arms, 1.4S UN0014 II None.................. 112............. None 62 None 25 kg...... 100 kg..... A......
blank.
....... Cartridges for weapons, blank or Cartridges, small arms, 1.3C UN0327 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
blank.
....... Cartridges for weapons, blank or Cartridges, small arms, 1.4C UN0338 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
blank.
....... Cartridges for weapons, inert projectile..................... 1.2C UN0328 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, inert projectile or Cartridges, small 1.4S UN0012 II None.................. 112............. None 62 None 25 kg...... 100 kg..... A......
arms.
....... Cartridges for weapons, inert projectile or Cartridges, small 1.4C UN0339 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... B......
arms.
....... Cartridges for weapons, inert projectile or Cartridges, small 1.3C UN0417 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
arms.
....... Cartridges for weapons, with bursting charge................. 1.1F UN0005 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.1E UN0006 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, with bursting charge................. 1.2F UN0007 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.2E UN0321 II EXPLOSIVE 1.2E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, with bursting charge................. 1.4F UN0348 II EXPLOSIVE 1.4F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.4E UN0412 II EXPLOSIVE 1.4E........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, oil well......................................... 1.3C UN0277 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, oil well......................................... 1.4C UN0278 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, power device..................................... 1.3C UN0275 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges, power device..................................... 1.4C UN0276 II EXPLOSIVE 1.4C........ 110............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, power device..................................... 1.4S UN0323 II EXPLOSIVE 1.4S........ 110, 112........ None 62 None 25 kg...... 100 kg..... A......
....... Cartridges, power device..................................... 1.2C UN0381 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, safety, blank, see Cartridges for weapons, blank ........... .............. ...................... ................ ........... ........... .......
(UN 0014).
....... Cartridges, safety, see Cartridges for weapons, other than ........... .............. ...................... ................ ........... ........... .......
blank or Cartridges, power device (UN 0323).
....... Cartridges, signal........................................... 1.3G UN0054 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges, signal........................................... 1.4G UN0312 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, signal........................................... 1.4S UN0405 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Cartridges, small arms....................................... ORM-D .............. None.................. 112............. 230 None None 30 kg gross 30 kg gross A......
....... Cartridges, sporting, see Cartridges for weapons, other than ........... .............. ...................... ................ ........... ........... .......
blank.
....... Cartridges, starter, jet engine, see Cartridges, power device ........... .............. ...................... ................ ........... ........... .......
I...... Cases, cartridge, empty with primer.......................... 1.4S UN0055 II EXPLOSIVE 1.4S........ 50.............. None 62 None 25 kg...... 100 kg..... A......
I...... Cases, cartridges, empty with primer......................... 1.4C UN0379 II EXPLOSIVE 1.4C........ 50.............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cases, combustible, empty, without primer.................... 1.4C UN0446 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cases, combustible, empty, without primer.................... 1.3C UN0447 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Casinghead gasoline see Natural gasoline..................... ........... .............. ...................... ................ ........... ........... .......
AW..... Castor beans or Castor meal or Castor pomace or Castor flake. 9 UN2969 II None.................. ................ 155 204 240 No limit... No limit... E...... 34, 40
....... Caustic alkali liquids, n.o.s................................ 8 UN1719 II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Caustic potash, see Potassium hydroxide etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Caustic soda, (etc.) see Sodium hydroxide etc................ ........... .............. ...................... ................ ........... ........... .......
....... Cells, containing sodium..................................... 4.3 UN3292 II DANGEROUS WHEN WET.... ................ 189 189 189 25 kg...... No limit... A......
....... Celluloid, in block, rods, rolls, sheets, tubes, etc., except 4.1 UN2000 III FLAMMABLE SOLID....... ................ None 213 240 25 kg...... 100 kg..... A......
scrap.
....... Celluloid, scrap............................................. 4.2 UN2002 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Cement, see Adhesives containing flammable liquid............ ........... .............. ...................... ................ ........... ........... .......
....... Cerium, slabs, ingots, or rods............................... 4.1 UN1333 II FLAMMABLE SOLID....... N34............. None 212 240 15 kg...... 50 kg...... A...... 74, 91
....... Cerium, turnings or gritty powder............................ 4.3 UN3078 II DANGEROUS WHEN WET.... A1.............. None 212 242 15 kg...... 50 kg...... E......
....... Cesium or Caesium............................................ 4.3 UN1407 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
....... Cesium nitrate or Caesium nitrate............................ 5.1 UN1451 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
D...... Charcoal briquettes, shell, screenings, wood, etc............ 4.2 NA1361 III SPONTANEOUSLY ................ 151 213 240 25 kg...... 100 kg..... A...... 12
COMBUSTIBLE.
....... Charges, bursting, plastics bonded........................... 1.1D UN0457 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, bursting, plastics bonded........................... 1.2D UN0458 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, bursting, plastics bonded........................... 1.4D UN0459 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, bursting, plastics bonded........................... 1.4S UN0460 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, demolition.......................................... 1.1D UN0048 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, depth............................................... 1.1D UN0056 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Charges, expelling, explosive, for fire extinguishers, see ........... .............. ...................... ................ ........... ........... .......
Cartridges, power device.
....... Charges, explosive, commercial without detonator............. 1.1D UN0442 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, explosive, commercial without detonator............. 1.2D UN0443 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, explosive, commercial without detonator............. 1.4D UN0444 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, explosive, commercial without detonator............. 1.4S UN0445 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, propelling.......................................... 1.1C UN0271 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.3C UN0272 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.2C UN0415 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.4C UN0491 EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.3C UN0242 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.1C UN0279 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.2C UN0414 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, shaped, commercial, without detonator............... 1.1D UN0059 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, shaped, commercial without detonator................ 1.2D UN0439 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, shaped, commercial without detonator................ 1.4D UN0440 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, shaped, commercial without detonator................ 1.4S UN0441 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, shaped, flexible, linear............................ 1.4D UN0237 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, shaped, flexible, linear............................ 1.1D UN0288 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Charges, supplementary explosive............................. 1.1D UN0060 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
D...... Chemical kit................................................. 8 NA1760 II CORROSIVE............. ................ 154 161 None 1 L........ 30 L....... B...... 40
....... Chemical kits (must be classified and labelled according to ........... .............. ...................... ................ ........... ........... .......
the hazard class of the constituent(s) and must meet the
requirements of special provision 15 in 172.102(c)(1)).
....... Chloral, anhydrous, inhibited................................ 6.1 UN2075 II POISON................ T14............. None 202 243 5 L........ 60 L....... D...... 40
....... Chlorate and borate mixtures................................. 5.1 UN1458 II OXIDIZER.............. A9, N34......... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
............................................................. ........... .............. III OXIDIZER.............. A9, N34......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Chlorate and magnesium chloride mixtures..................... 5.1 UN1459 II OXIDIZER.............. A9, N34, T8..... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
............................................................. ........... .............. III OXIDIZER.............. A9, N34, T8..... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Chlorate of potash, see Potassium chlorate................... ........... .............. ...................... ................ ........... ........... .......
....... Chlorate of soda, see Sodium chlorate........................ ........... .............. ...................... ................ ........... ........... .......
....... Chlorates, inorganic, aqueous solution, n.o.s................ 5.1 UN3210 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 56, 58, 106
....... Chlorates, inorganic, n.o.s.................................. 5.1 UN1461 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Chloric acid aqueous solution, with not more than 10 percent 5.1 UN2626 II OXIDIZER.............. T25............. None 229 None Forbidden.. Forbidden.. D...... 56, 58, 106
chloric acid.
....... Chloride of phosphorus, see Phosphorus trichloride........... ........... .............. ...................... ................ ........... ........... .......
....... Chloride of sulfur, see Sulfur chloride...................... ........... .............. ...................... ................ ........... ........... .......
....... Chlorinated lime, see Calcium hypochlorite mixtures, etc..... ........... .............. ...................... ................ ........... ........... .......
....... Chlorine..................................................... 2.3 UN1017 POISON GAS, CORROSIVE, 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40, 51, 55,
OXIDIZER. 62, 68,
89, 90
....... Chlorine azide............................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Chlorine dioxide, hydrate, frozen............................ 5.1 NA9191 II OXIDIZER, POISON...... ................ None 229 None Forbidden.. Forbidden.. E......
....... Chlorine dioxide (not hydrate)............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Chlorine pentafluoride....................................... 2.3 UN2548 POISON GAS, OXIDIZER, 1, B7, B9, B14.. None 304 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Chlorine trifluoride......................................... 2.3 UN1749 POISON GAS, OXIDIZER, 2, 25, B7, B9, None 304 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B14.
....... Chlorite solution with more than 5 percent but less than 16 8 UN1908 III CORROSIVE............. A3, A6, A7, B2, 154 203 241 5 L........ 60 L....... B...... 26
percent available chlorine. N34, T8.
....... Chlorite solution with not less than 16 percent available 8 UN1908 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... B...... 26
chlorine. N34, T8.
....... Chlorites, inorganic, n.o.s.................................. 5.1 UN1462 II OXIDIZER.............. A7, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... 1-Chloro-3-bromopropane...................................... 6.1 UN2688 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... 1-Chloro-1,1-difluoroethane, see Chlorodifluoroethanes....... ........... .............. ...................... ................ ........... ........... .......
....... 1-Chloro-1,1-difluoroethanes, R142b.......................... 2.1 UN2517 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... 3-Chloro-4-methylphenylisocyanate............................ 6.1 UN2236 II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
....... 1-Chloro-1,2,2,2,-tetrafluoroethane, R124.................... 2.2 UN1021 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... 4-Chloro-o-toluidine hydrochloride........................... 6.1 UN1579 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... 1-Chloro-2,2,2-trifluoroethane, R133a........................ 2.2 UN1983 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chloroacetic acid, molten.................................... 6.1 UN3250 II POISON, CORROSIVE..... T9.............. None 202 243 Forbidden.. Forbidden.. C...... 40
....... Chloroacetic acid, solid..................................... 6.1 UN1751 II POISON, CORROSIVE..... A3, A7, N34..... None 212 242 15 kg...... 50 kg...... A...... 40
....... Chloroacetic acid, solution.................................. 6.1 UN1750 II POISON, CORROSIVE..... A7, N34, T8, T27 None 202 243 1 L........ 30 L....... C...... 40
+...... Chloroacetone, stabilized.................................... 6.1 UN1695 II POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, N12, N32,
N34, T38, T43,
T45.
....... Chloroacetone (unstabilized)................................. Forbidden .............. ...................... ................ ........... ........... .......
+...... Chloroacetonitrile........................................... 6.1 UN2668 II POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... A...... 12, 26, 40
LIQUID. B74, T38, T43,
T45.
....... Chloroacetophenone (CN), liquid.............................. 6.1 UN1697 II POISON................ A3, N12, N32, None 202 243 Forbidden.. 60 L....... D...... 12, 40
N33.
....... Chloroacetophenone (CN), solid............................... 6.1 UN1697 II POISON................ A3, N12, N32, None 212 None Forbidden.. 100 kg..... D...... 12, 40
N33, N34.
....... Chloroacetyl chloride........................................ 6.1 UN1752 I POISON, CORROSIVE..... 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 40
B3, B8, B9,
B14, B32, B74,
B77, N34, N43,
T38, T43, T45.
....... Chloroanilines, liquid....................................... 6.1 UN2019 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Chloroanilines, solid........................................ 6.1 UN2018 II POISON................ T14, T38........ None 212 242 25 kg...... 100 kg..... A......
....... Chloroanisidines............................................. 6.1 UN2233 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chlorobenzene................................................ 3 UN1134 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Chlorobenzol, see Chlorobenzene.............................. ........... .............. ...................... ................ ........... ........... .......
....... Chlorobenzotrifluorides...................................... 3 UN2234 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Chlorobenzylchlorides........................................ 6.1 UN2235 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorobutanes................................................ 3 UN1127 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Chlorocresols, liquid........................................ 6.1 UN2669 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12
....... Chlorocresols, solid......................................... 6.1 UN2669 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12
....... Chlorodifluorobromomethane, R12B1............................ 2.2 UN1974 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorodifluoromethane and chloropentafluoroethane mixture 2.2 UN1973 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
with fixed boiling point, with approximately 49 percent
chlorodifluoromethane, R502.
....... Chlorodifluoromethane, R22................................... 2.2 UN1018 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorodinitrobenzenes........................................ 6.1 UN1577 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 91
....... 2-Chloroethanal.............................................. 6.1 UN2232 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... Chloroform................................................... 6.1 UN1888 III KEEP AWAY FROM FOOD... N36, T14........ 153 203 241 5 L........ 60 L....... A...... 40
....... Chloroformates, toxic, corrosive, flammable, n.o.s........... 6.1 UN2742 II POISON, CORROSIVE, 5............... None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
FLAMMABLE LIQUID. 25, 40,
100
....... Chloroformates, toxic, corrosive, n.o.s...................... 6.1 UN3277 II POISON, CORROSIVE..... T12, T26........ None 202 243 1 L........ 30 L....... A...... 12, 13, 25,
40
....... Chloromethyl ethyl ether..................................... 3 UN2354 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Chloromethylchloroformate.................................... 6.1 UN2745 II POISON, CORROSIVE..... T18............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... Chloronitroanilines.......................................... 6.1 UN2237 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
+...... Chloronitrobenzene, ortho, liquid............................ 6.1 UN1578 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
+...... Chloronitrobenzenes meta or para, solid...................... 6.1 UN1578 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Chloronitrotoluenes liquid................................... 6.1 UN2433 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... Chloronitrotoluenes, solid................................... 6.1 UN2433 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chloropentafluoroethane, R115................................ 2.2 UN1020 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorophenolates, liquid or Phenolates, liquid............... 8 UN2904 III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A......
....... Chlorophenolates, solid or Phenolates, solid................. 8 UN2905 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Chlorophenols, liquid........................................ 6.1 UN2021 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorophenols, solid......................................... 6.1 UN2020 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Chlorophenyltrichlorosilane.................................. 8 UN1753 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
+...... Chloropicrin................................................. 6.1 UN1580 I POISON................ 2, B7, B9, B14, None 227 244 Forbidden.. Forbidden.. D...... 40
B32, B46, B74,
T38, T43, T45.
....... Chloropicrin and methyl bromide mixtures..................... 2.3 UN1581 POISON GAS............ 2, B9, B14...... None 193 314, 315 Forbidden.. Forbidden.. D...... 25, 40
....... Chloropicrin and methyl chloride mixtures.................... 2.3 UN1582 POISON GAS............ 2............... None 193 245 Forbidden.. Forbidden.. D...... 25, 40
....... Chloropicrin mixture, flammable (pressure not exceeding 14.7 ........... .............. ...................... ................ ........... ........... .......
psia at 115 degrees F flash point below 100 degrees F) see
Poisonous liquids, flammable, n.o.s..
....... Chloropicrin mixtures, n.o.s................................. 6.1 UN1583 I POISON................ 5............... None 201 243 Forbidden.. Forbidden.. C...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 Forbidden.. Forbidden.. C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 Forbidden.. Forbidden.. C...... 40
D...... Chloropivaloyl chloride...................................... 6.1 NA9263 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
B74, T38, T43,
T45.
....... Chloroplatinic acid, solid................................... 8 UN2507 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Chloroprene, inhibited....................................... 3 UN1991 I FLAMMABLE LIQUID, B57, T15........ None 201 243 Forbidden.. 30 L....... D...... 40
POISON.
....... Chloroprene, uninhibited..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Chloropropane.............................................. 3 UN2356 I FLAMMABLE LIQUID...... N36, T14........ 150 201 243 1 L........ 30 L....... E......
....... 3-Chloropropanol-1........................................... 6.1 UN2849 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Chloropropene.............................................. 3 UN2456 I FLAMMABLE LIQUID...... A3, N36, T20.... 150 201 243 1 L........ 30 L....... E......
....... 2-Chloropropionic acid....................................... 8 UN2511 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 8
....... 2-Chloropyridine............................................. 6.1 UN2822 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Chlorosilanes, corrosive, flammable, n.o.s................... 8 UN2986 II CORROSIVE, FLAMMABLE ................ None 202 243 1 L........ 30 L....... C...... 40
LIQUID.
....... Chlorosilanes, corrosive, n.o.s.............................. 8 UN2987 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 40
....... Chlorosilanes, flammable, corrosive, n.o.s................... 3 UN2985 II FLAMMABLE LIQUID, T18, T26........ None 201 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Chlorosilanes, water-reactive, flammble, corrosive, n.o.s.... 4.3 UN2988 I DANGEROUS WHEN WET, A2.............. None 201 244 Forbidden.. 1 L........ D...... 21, 28, 40,
FLAMMABLE LIQUID, 49, 100
CORROSIVE.
+...... Chlorosulfonic acid (with or without sulfur trioxide)........ 8 UN1754 I CORROSIVE, POISON..... 2, A3, A6, A10, None 227 244 Forbidden.. Forbidden.. C...... 40
B9, B10, B14,
B32, B74, T38,
T43, T45.
....... Chlorotoluenes............................................... 3 UN2238 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Chlorotoluidines liquid...................................... 6.1 UN2239 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorotoluidines solid....................................... 6.1 UN2239 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chlorotrifluoromethane and trifluoromethane azeotropic 2.2 UN2599 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
mixture with approximately 60 percent
chlorotrifluoromethane, R503.
....... Chlorotrifluoromethane, R13.................................. 2.2 UN1022 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Chromic acid, solid.......................................... 5.1 NA1463 II OXIDIZER, CORROSIVE... ................ None 212 242 5 kg....... 25 kg...... A......
....... Chromic acid solution........................................ 8 UN1755 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 40
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 40
....... Chromic anhydride, see Chromium trioxide, anhydrous.......... ........... .............. ...................... ................ ........... ........... .......
....... Chromic fluoride, solid...................................... 8 UN1756 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 26
....... Chromic fluoride, solution................................... 8 UN1757 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Chromium nitrate............................................. 5.1 UN2720 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Chromium oxychloride......................................... 8 UN1758 I CORROSIVE............. A3, A6, A7, B10, None 201 243 0.5 L...... 2.5 L...... C...... 40, 66, 74,
N34, T12, T26. 89, 90
....... Chromium trioxide, anhydrous................................. 5.1 UN1463 II OXIDIZER, CORROSIVE... ................ None 212 242 5 kg....... 25 kg...... A......
....... Chromosulfuric acid.......................................... 8 UN2240 I CORROSIVE............. A3, A6, A7, B4, None 201 243 0.5 L...... 2.5 L...... B...... 40, 66, 74,
B6, N34, T12, 89, 90
T27.
....... Chromyl chloride, see Chromium oxychloride................... ........... .............. ...................... ................ ........... ........... .......
....... Cigar and cigarette lighters, charged with fuel, see Lighters ........... .............. ...................... ................ ........... ........... .......
for cigars, cigarettes, etc..
....... Coal briquettes, hot......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Coal gas..................................................... 2.3 UN1023 POISON GAS, FLAMMABLE 3............... None 302 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Coal tar distillates, flammable.............................. 3 UN1136 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or ........... .............. ...................... ................ ........... ........... .......
solid, n.o.s. or Dye intermediates, liquid or solid, n.o.s.,
corrosive.
....... Coating solution............................................. 3 UN1139 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Cobalt naphthenates, powder.................................. 4.1 UN2001 III FLAMMABLE SOLID....... A19............. 151 213 240 25 kg...... 100 kg..... A......
....... Cobalt resinate, precipitated................................ 4.1 UN1318 III FLAMMABLE SOLID....... A1, A19......... 151 213 240 25 kg...... 100 kg..... A......
....... Coke, hot.................................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Collodion, see Nitrocellulose etc............................ ........... .............. ...................... ................ ........... ........... .......
D...... Combustible liquid, n.o.s.................................... Combustible NA1993 III None.................. T1.............. 150 203 241 60 L....... 220 L...... A......
liquid
....... Components, explosive train, n.o.s........................... 1.2B UN0382 II EXPLOSIVE 1.2B........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 6E
....... Components, explosive train, n.o.s........................... 1.4B UN0383 II EXPLOSIVE 1.4B........ 101............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Components, explosive train, n.o.s........................... 1.4S UN0384 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 100 kg..... A......
....... Components, explosive train, n.o.s........................... 1.1B UN0461 II EXPLOSIVE 1.1B........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 6E
....... Composition B, see Hexolite, etc............................. ........... .............. ...................... ................ ........... ........... .......
D...... Compounds, cleaning liquid................................... 8 NA1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, N37, T14.... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. N37, T7......... 154 203 241 5 L........ 60 L....... A...... 40
D...... Compounds, cleaning liquid................................... 3 NA1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
D...... Compounds, tree killing, liquid or Compounds, weed killing, 8 NA1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
liquid.
............................................................. ........... .............. II CORROSIVE............. B2, N37, T14.... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. N37, T7......... 154 203 241 5 L........ 60 L....... A...... 40
D...... Compounds, tree killing, liquid or Compounds, weed killing, 3 NA1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
liquid.
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
D...... Compounds, tree killing, liquid or Compounds, weed killing, 6.1 NA2810 I POISON................ ................ 153 201 243 1 L........ 30 L....... B...... 40
liquid.
............................................................. ........... .............. II POISON................ ................ 153 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 40
....... Compressed gas, oxidizing, n.o.s............................. 2.2 UN3156 NONFLAMMABLE GAS, ................ 306 302 314, 315 75 kg...... 150 kg..... D......
OXIDIZER.
....... Compressed gases, flammable, n.o.s........................... 2.1 UN1954 FLAMMABLE GAS......... ................ 306 302, 305 314, 315 Forbidden.. 150 kg..... D...... 40
....... Compressed gases, n.o.s...................................... 2.2 UN1956 NONFLAMMABLE GAS...... ................ 306, 307 302, 305 314, 315 75 kg...... 150 kg..... A......
....... Compressed gases, toxic, flammable, n.o.s. Inhalation hazard 2.3 UN1953 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40, 95
Zone A. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation hazard 2.3 UN1953 POISON GAS, FLAMMABLE 2, B9, B14...... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone B. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN1953 POISON GAS, FLAMMABLE 3, B14.......... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone C. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN1953 POISON GAS, FLAMMABLE 4............... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone D. GAS.
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone A..... 2.3 UN1955 POISON GAS............ 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone B..... 2.3 UN1955 POISON GAS............ 2, B9, B14...... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone C..... 2.3 UN1955 POISON GAS............ 3, B14.......... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone D..... 2.3 UN1955 POISON GAS............ 4............... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
D...... Consumer commodity........................................... ORM-D .............. None.................. ................ 156, 306 156, 306 None 30 kg gross 30 kg gross A......
....... Contrivances, water-activated, with burster, expelling charge 1.2L UN0248 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
or propelling charge. 11E, 17E
....... Contrivances, water-activated, with burster, expelling charge 1.3L UN0249 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
or propelling charge. 11E, 17E
....... Copper acetoarsenite......................................... 6.1 UN1585 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Copper acetylide............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Copper amine azide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Copper arsenite.............................................. 6.1 UN1586 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Copper based pesticides, liquid, flammable, toxic, flash 3 UN2776 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Copper based pesticides, liquid, toxic....................... 6.1 UN3010 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Copper based pesticides, liquid, toxic, flammable flashpoint 6.1 UN3009 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Copper based pesticides, solid, toxic........................ 6.1 UN2775 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Copper chlorate.............................................. 5.1 UN2721 II OXIDIZER.............. A1.............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Copper chloride.............................................. 8 UN2802 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Copper cyanide............................................... 6.1 UN1587 II POISON................ ................ None 204 242 25 kg...... 100 kg..... A...... 26
....... Copper selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Copper selenite, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Copper tetramine nitrate..................................... Forbidden .............. ...................... ................ ........... ........... .......
AW..... Copra........................................................ 4.2 UN1363 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A...... 13, 19, 48,
COMBUSTIBLE. 119
....... Cord, detonating, flexible................................... 1.1D UN0065 II EXPLOSIVE 1.1D........ 102............. 63(a) 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating, flexible................................... 1.4D UN0289 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cord detonating or Fuse detonating metal clad................ 1.2D UN0102 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating or Fuse, detonating metal clad.............. 1.1D UN0290 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating, mild effect or Fuse, detonating, mild 1.4D UN0104 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
effect metal clad.
....... Cord, igniter................................................ 1.4G UN0066 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cordeau detonant fuse, see Cord, detonating, etc.; Cord, ........... .............. ...................... ................ ........... ........... .......
detonating, flexible.
....... Cordite, see Powder, smokeless............................... ........... .............. ...................... ................ ........... ........... .......
....... Corrosive liquid, acidic, inorganic, n.o.s................... 8 UN3264 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, acidic, organic, n.o.s..................... 8 UN3265 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, basic, inorganic, n.o.s.................... 8 UN3266 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, basic, organic, n.o.s...................... 8 UN3267 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, self-heating, n.o.s........................ 8 UN3301 I CORROSIVE, B10............ None 201 243 0.5 L...... 2.5 L...... D......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II CORROSIVE, B2.............. 154 202 242 1 L........ 30 L....... D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Corrosive liquids, flammable, n.o.s.......................... 8 UN2920 I CORROSIVE, FLAMMABLE B10, T42........ None 201 243 0.5 L...... 2.5 L...... C...... 25, 40
LIQUID.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE B2, T15, T26.... None 202 243 1 L........ 30 L....... C...... 25, 40
LIQUID.
....... Corrosive liquids, n.o.s..................................... 8 UN1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquids, oxidizing, n.o.s.......................... 8 UN3093 I CORROSIVE, OXIDIZER... ................ None 201 243 Forbidden.. 2.5 L...... C...... 89
............................................................. ........... .............. II CORROSIVE, OXIDIZER... ................ None 202 243 1 L........ 30 L....... C...... 89
....... Corrosive liquids, toxic, n.o.s.............................. 8 UN2922 I CORROSIVE, POISON..... A7, B10......... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE, POISON..... B3.............. None 202 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY ................ 154 203 241 5 L........ 60 L....... B...... 40
FROM FOOD.
....... Corrosive liquids, water-reactive, n.o.s..................... 8 UN3094 I CORROSIVE, DANGEROUS ................ None 201 243 Forbidden.. 1 L........ E......
WHEN WET.
............................................................. ........... .............. II CORROSIVE, DANGEROUS ................ None 202 243 1 L........ 5 L........ E......
WHEN WET.
....... Corrosive solid, acidic, inorganic, n.o.s.................... 8 UN3260 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, acidic, organic, n.o.s...................... 8 UN3261 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, basic, inorganic, n.o.s..................... 8 UN3262 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, basic, organic, n.o.s....................... 8 UN3263 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solids, flammable, n.o.s........................... 8 UN2921 I CORROSIVE, FLAMMABLE ................ None 211 242 1 kg....... 25 kg...... B...... 12, 25
SOLID.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE ................ None 212 242 15 kg...... 50 kg...... B...... 12, 25
SOLID.
....... Corrosive solids, n.o.s...................................... 8 UN1759 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solids, oxidizing, n.o.s........................... 8 UN3084 I CORROSIVE, OXIDIZER... ................ None 211 242 1 kg....... 25 kg...... C......
............................................................. ........... .............. II CORROSIVE, OXIDIZER... ................ None 212 242 15 kg...... 50 kg...... C......
....... Corrosive solids, self heating, n.o.s........................ 8 UN3095 I CORROSIVE, ................ None 211 243 1 kg....... 25 kg...... C......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II CORROSIVE, ................ None 212 242 15 kg...... 50 kg...... C......
SPONTANEOUSLY
COMBUSTIBLE.
....... Corrosive solids, toxic, n.o.s............................... 8 UN2923 I CORROSIVE, POISON..... ................ None 211 242 1 kg....... 25 kg...... B...... 40
............................................................. ........... .............. II CORROSIVE, POISON..... ................ None 212 240 15 kg...... 50 kg...... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY ................ 154 213 240 25 kg...... 100 kg..... B...... 40, 95
FROM FOOD.
....... Corrosive solids, water-reactive, n.o.s...................... 8 UN3096 I CORROSIVE, DANGEROUS ................ None 211 243 1 kg....... 25 kg...... D......
WHEN WET.
............................................................. ........... .............. II CORROSIVE, DANGEROUS ................ None 212 242 15 kg...... 50 kg...... D......
WHEN WET.
DW..... Cotton....................................................... 9 .............. CLASS 9............... W41............. None None None No limit... No limit... A......
AIW.... Cotton waste, oily........................................... 4.2 UN1364 III SPONTANEOUSLY N9.............. None 213 None Forbidden.. Forbidden.. A...... 54
COMBUSTIBLE.
AIW.... Cotton, wet.................................................. 4.2 .............. III SPONTANEOUSLY ................ None 204 241 Forbidden.. Forbidden.. A......
COMBUSTIBLE.
....... Coumarin derivative pesticides, liquid, flammable, toxic, 3 UN3024 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flashpoint less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Coumarin derivative pesticides, liquid, flammable, toxic, 6.1 UN3025 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
flashpoint less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE ................ None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1.............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Coumarin derivative pesticides, liquid, toxic................ 6.1 UN3026 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 40
....... Coumarin derivative pesticides, solid, toxic................. 6.1 UN3027 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Cresols...................................................... 6.1 UN2076 II POISON, CORROSIVE..... T8.............. None 202 243 1 L........ 30 L....... B......
....... Cresylic acid................................................ 6.1 UN2022 II POISON, CORROSIVE..... T8.............. None 202 243 1 L........ 30 L....... B......
....... Crotonaldehyde, stabilized................................... 6.1 UN1143 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... B...... 40
LIQUID. B74, B77, T38,
T43, T45.
....... Crotonic acid liquid......................................... 8 UN2823 III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A...... 12
....... Crotonic acid, solid......................................... 8 UN2823 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Crotonylene.................................................. 3 UN1144 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Cupriethylenediamine solution................................ 8 UN1761 II CORROSIVE, POISON..... T8, T26......... None 202 243 1 L........ 30 L....... A...... 95
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T7.............. 154 203 242 5 L........ 60 L....... A...... 95
FROM FOOD.
....... Cutters, cable, explosive.................................... 1.4S UN0070 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Cyanide solutions, n.o.s..................................... 6.1 UN1935 I POISON................ B37, T18, T26... None 201 243 1 L........ 30 L....... B...... 40, 52
............................................................. ........... .............. II POISON................ T18, T26........ None 202 243 5 L........ 60 L....... A...... 40, 52
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T18, T26........ 153 203 241 60 L....... 220 L...... A...... 40, 52
....... Cyanides, inorganic, solid, n.o.s............................ 6.1 UN1588 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 52
............................................................. ........... .............. II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 52
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N74, N75........ 153 213 240 100 kg..... 200 kg..... A...... 52
....... Cyanogen bromide............................................. 6.1 UN1889 I POISON, CORROSIVE..... 25, A6, A8...... None 211 242 Forbidden.. Forbidden.. D...... 40
....... Cyanogen chloride, inhibited................................. 2.3 UN1589 POISON GAS, CORROSIVE. 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Cyanogen, liquefied.......................................... 2.3 UN1026 POISON GAS, FLAMMABLE 2............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Cyanuric chloride............................................ 8 UN2670 II CORROSIVE............. ................ None 212 240 15 kg...... 50 kg...... A...... 12, 40
....... Cyanuric triazide............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Cyclobutane.................................................. 2.1 UN2601 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Cyclobutylchloroformate...................................... 6.1 UN2744 II POISON, CORROSIVE..... T18............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... 1,5,9-Cyclododecatriene...................................... 6.1 UN2518 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Cycloheptane................................................. 3 UN2241 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Cycloheptatriene............................................. 3 UN2603 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Cycloheptene................................................. 3 UN2242 II FLAMMABLE LIQUID...... B1, T7.......... 150 202 242 5 L........ 60 L....... B......
....... Cyclohexane.................................................. 3 UN1145 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Cyclohexanone................................................ 3 UN1915 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclohexene.................................................. 3 UN2256 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Cyclohexenyltrichlorosilane.................................. 8 UN1762 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
....... Cyclohexyl acetate........................................... 3 UN2243 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Cyclohexyl isocyanate........................................ 6.1 UN2488 II POISON................ 2, B9, B14, B32, None 227 244 5 L........ 60 L....... D...... 40
B74, B77, T38,
T43, T45.
....... Cyclohexyl mercaptan......................................... 3 UN3054 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40, 95
....... Cyclohexylamine.............................................. 8 UN2357 II CORROSIVE, FLAMMABLE T8, T26......... None 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Cyclohexyltrichlorosilane.................................... 8 UN1763 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
....... Cyclonite and cyclotetramethylenetetranitramine mixtures, ........... .............. ...................... ................ ........... ........... .......
wetted or desensitized see RDX and HMX mixtures, wetted or
desensitized etc.ed.
....... Cyclonite and HMX mixtures, wetted or desensitized see RDX ........... .............. ...................... ................ ........... ........... .......
and HMX mixtures, wetted or desensitized etc..
....... Cyclonite and octogen mixtures, wetted or desensitized see ........... .............. ...................... ................ ........... ........... .......
RDX and HMX mixtures, wetted or desensitized etc..
....... Cyclonite, see Cyclotrimethylenetrinitramine, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Cyclooctadiene phosphines, see 9-Phosphabicyclononanes....... ........... .............. ...................... ................ ........... ........... .......
....... Cyclooctadienes.............................................. 3 UN2520 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclooctatetraene............................................ 3 UN2358 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Cyclopentane................................................. 3 UN1146 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E......
....... Cyclopentane, methyl, see Methyl cyclopentane................ ........... .............. ...................... ................ ........... ........... .......
....... Cyclopentanol................................................ 3 UN2244 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclopentanone............................................... 3 UN2245 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclopentene................................................. 3 UN2246 II FLAMMABLE LIQUID...... T13............. 150 202 242 5 L........ 60 L....... E......
....... Cyclopropane, liquefied...................................... 2.1 UN1027 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Cyclotetramethylene tetranitramine (dry or unphlegmatized) Forbidden .............. ...................... ................ ........... ........... .......
(HMX).
....... Cyclotetramethylenetetranitramine, desensitized or Octogen, 1.1D UN0484 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
desensitized or HMX, desensitized.
....... Cyclotetramethylenetetranitramine, wetted or HMX, wetted or 1.1D UN0226 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Octogen, wetted with not less than 15 percent water, by mass.
....... Cyclotrimethylenenitramine and octogen, mixtures, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitrameie and ........... .............. ...................... ................ ........... ........... .......
cyclotetramethylenetetranitramine mixtures, wetted or
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitramine and HMX mixtures, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitramine, desensitized or Cyclonite, 1.1D UN0483 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
desensitized or Hexogen, desensitized or RDX, desensitized.
....... Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or 1.1D UN0072 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Hexogen, wetted or RDX, wetted with not less than 15 percent
water by mass.
....... Cymenes...................................................... 3 UN2046 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Decaborane................................................... 4.1 UN1868 II FLAMMABLE SOLID, A19, A20........ None 212 None Forbidden.. 50 kg...... A......
POISON.
....... Decahydronaphthalene......................................... 3 UN1147 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... n-Decane..................................................... 3 UN2247 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Deflagrating metal salts of aromatic nitroderivatives, n.o.s. 1.3C UN0132 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Delay electric igniter, see Igniters......................... ........... .............. ...................... ................ ........... ........... .......
D...... Denatured alcohol............................................ 3 NA1986 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... E...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... 150 203 242 60 L....... 220 L...... E...... 40
AWAY FROM FOOD.
D...... Denatured alcohol............................................ 3 NA1987 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Depth charges, see Charges, depth............................ ........... .............. ...................... ................ ........... ........... .......
....... Detonating relays, see Detonators, etc....................... ........... .............. ...................... ................ ........... ........... .......
....... Detonator assemblies, non-electric for blasting.............. 1.1B UN0360 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonator assemblies, non-electric, for blasting............. 1.4B UN0361 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, electric, for blasting........................... 1.1B UN0030 II EXPLOSIVE 1.1B........ ................ 63(f), 62 None Forbidden.. Forbidden.. B...... 2E, 6E
63(g)
....... Detonators, electric, for blasting........................... 1.4B UN0255 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, electric for blasting............................ 1.4S UN0456 II EXPLOSIVE 1.4S........ 104............. 63(f), 62 None 25 kg...... 100 kg..... A......
63(g)
....... Detonators for ammunition.................................... 1.1B UN0073 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators for ammunition.................................... 1.2B UN0364 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators for ammunition.................................... 1.4B UN0365 II EXPLOSIVE 1.4B........ 103............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Detonators for ammunition.................................... 1.4S UN0366 II EXPLOSIVE 1.4S........ 104............. None 62 None 25 kg...... 100 kg..... A......
....... Detonators, non-electric, for blasting....................... 1.1B UN0029 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators, non-electric, for blasting....................... 1.4B UN0267 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, non-electric for blasting........................ 1.4S UN0455 II EXPLOSIVE 1.4S........ 104............. None 62 None 25 kg...... 100 kg..... A......
....... Deuterium.................................................... 2.1 UN1957 FLAMMABLE GAS......... ................ 306 302 None Forbidden.. 150 kg..... E...... 40
....... Devices, small, hydrocarbon gas powered or Hydrocarbon gas 2.1 UN3150 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... B...... 40
refills for small devices with release device.
....... Di-n-amylamine............................................... 3 UN2841 III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Di-n-butyl peroxydicarbonate, with more than 52 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Di-n-butylamine.............................................. 8 UN2248 II CORROSIVE, FLAMMABLE T8.............. None 202 243 1 L........ 30 L....... A......
LIQUID.
....... 2,2-Di-(tert-butylperoxy) butane, with more than 55 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Di-(tert-butylperoxy) phthalate, with more than 55 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... 2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more Forbidden .............. ...................... ................ ........... ........... .......
than 42 percent with inert solid.
....... Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent Forbidden .............. ...................... ................ ........... ........... .......
with water.
....... 1,2-Di-(dimethylamino) ethane................................ 3 UN2372 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid ........... .............. ...................... ................ ........... ........... .......
phosphate.
....... Di-(1-hydroxytetrazole) (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Di-(1-naphthoyl) peroxide.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... a,a'-Di-(nitroxy) methylether................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Di-(beta-nitroxyethyl) ammonium nitrate...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diacetone alcohol............................................ 3 UN1148 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diacetone alcohol peroxides, with more than 57 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution with more than 9 percent hydrogen peroxide, less
than 26 percent diacetone alcohol and less than 9 percent
water; total active oxygen content more than 9 percent by
mass.
....... Diacetyl, see Butanedione.................................... ........... .............. ...................... ................ ........... ........... .......
....... Diacetyl peroxide, solid, or with more than 25 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Diallylamine................................................. 3 UN2359 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 21, 40, 100
POISON, CORROSIVE.
....... Diallylether................................................. 3 UN2360 II FLAMMABLE LIQUID, N12, T8......... None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... 4,4'-Diaminodiphenyl methane................................. 6.1 UN2651 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... p-Diazidobenzene............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,2-Diazidoethane............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1'-Diazoaminonaphthalene................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazoaminotetrazole (dry).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazodinitrophenol (dry)..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazodinitrophenol, wetted with not less than 40 percent 1.1A UN0074 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
water or mixture of alcohol and water, by mass.
....... Diazodiphenylmethane......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazonium nitrates (dry)..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazonium perchlorates (dry)................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3-Diazopropane............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dibenzyl peroxydicarbonate, with more than 87 percent with Forbidden .............. ...................... ................ ........... ........... .......
water.
....... Dibenzyldichlorosilane....................................... 8 UN2434 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Diborane..................................................... 2.3 UN1911 POISON GAS, FLAMMABLE 1............... None 302 None Forbidden.. Forbidden.. D...... 40, 57
GAS.
....... Diborane mixtures............................................ 2.1 NA1911 FLAMMABLE GAS......... 5............... None 302 245 Forbidden.. Forbidden.. D...... 40, 57
....... Dibromoacetylene............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dibromobenzene............................................... 3 UN2711 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,2-Dibromobutan-3-one....................................... 6.1 UN2648 II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
....... Dibromochloropropane......................................... 6.1 UN2872 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
A...... Dibromodifluoromethane, R12B2................................ 9 UN1941 III None.................. T22............. 155 203 241 100 L...... 220 L...... A...... 25
....... 1,2-Dibromoethane, see Ethylene dibromide.................... ........... .............. ...................... ................ ........... ........... .......
....... Dibromomethane............................................... 6.1 UN2664 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Dibutyl ethers............................................... 3 UN1149 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dibutylaminoethanol.......................................... 6.1 UN2873 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... N,N'-Dichlorazodicarbonamidine (salts of) (dry).............. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1-Dichloro-1-nitroethane................................... 6.1 UN2650 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12, 40
D...... 3,5-Dichloro-2,4,6-trifluoropyridine......................... 6.1 NA9264 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 40, 95
B74, T38, T43,
T45.
....... Dichloroacetic acid.......................................... 8 UN1764 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... A......
N34, T9, T27.
....... 1,3-Dichloroacetone.......................................... 6.1 UN2649 II POISON................ ................ None 212 242 25 kg...... 100 kg..... B...... 12, 40
....... Dichloroacetyl chloride...................................... 8 UN1765 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... D...... 40
B6, N34, T8,
T26.
....... Dichloroacetylene............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Dichloroanilines, liquid..................................... 6.1 UN1590 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Dichloroanilines, solid...................................... 6.1 UN1590 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 40
....... o-Dichlorobenzene............................................ 6.1 UN1591 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
D...... Dichlorobutene............................................... 8 NA2920 I CORROSIVE, FLAMMABLE ................ None 201 243 0.5 L...... 2.5 L...... C...... 12, 21, 25,
LIQUID. 40, 48
....... 2,2'-Dichlorodiethyl ether................................... 6.1 UN1916 II POISON, FLAMMABLE N33, N34, T8.... None 202 243 5 L........ 60 L....... A......
LIQUID.
....... Dichlorodifluoromethane and difluoroethane azeotropic mixture 2.2 UN2602 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
with approximately 74 percent dichlorodifluoromethane, R500.
....... Dichlorodifluoromethane, R12................................. 2.2 UN1028 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichlorodimethyl ether, symmetrical.......................... 6.1 UN2249 I POISON................ T25............. None 201 243 Forbidden.. Forbidden.. D...... 40
....... 1,1-Dichloroethane........................................... 3 UN2362 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... 1,2-Dichloroethane, see Ethylene dichloride.................. ........... .............. ...................... ................ ........... ........... .......
....... Dichloroethyl sulfide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Dichloroethylene............................................. 3 UN1150 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... B......
....... Dichlorofluoromethane, R21................................... 2.2 UN1029 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid 5.1 UN2465 II OXIDIZER.............. 28.............. 152 212 240 5 kg....... 25 kg...... A...... 13
salts.
....... Dichloroisopropyl ether...................................... 6.1 UN2490 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B......
....... Dichloromethane.............................................. 6.1 UN1593 III KEEP AWAY FROM FOOD... N36, T13........ 153 203 241 60 L....... 220 L...... A......
....... Dichloropentanes............................................. 3 UN1152 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dichlorophenyl isocyanates................................... 6.1 UN2250 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 25, 40, 48
....... Dichlorophenyltrichlorosilane................................ 8 UN1766 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Dichloropropane, see Propylene dichloride.................... ........... .............. ...................... ................ ........... ........... .......
....... 1,3-Dichloropropanol-2....................................... 6.1 UN2750 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12, 40
....... Dichloropropene and propylene dichloride mixture, see ........... .............. ...................... ................ ........... ........... .......
Propylene dichloride.
....... Dichloropropenes............................................. 3 UN2047 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Dichlorosilane............................................... 2.3 UN2189 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 17, 40
GAS, CORROSIVE.
....... Dichlorotetrafluoroethane, R114.............................. 2.2 UN1958 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichlorovinylchloroarsine.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dicycloheptadiene, see Norbornadiene......................... ........... .............. ...................... ................ ........... ........... .......
....... Dicyclohexylamine............................................ 8 UN2565 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Dicyclohexylammonium nitrite................................. 4.1 UN2687 III FLAMMABLE SOLID....... ................ 153 213 240 25 kg...... 100 kg..... A...... 48
....... Dicyclopentadiene............................................ 3 UN2048 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Didymium nitrate............................................. 5.1 UN1465 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
D...... Dieldrin..................................................... 6.1 NA2761 II POISON................ ................ None 212 242 0.5 kg..... 5 kg....... A...... 40
D...... Diesel fuel.................................................. 3 NA1993 III None.................. B1.............. 150 203 242 60 L....... 220 L...... A......
....... Diethanol nitrosamine dinitrate (dry)........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Diethoxymethane.............................................. 3 UN2373 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... 3,3-Diethoxypropene.......................................... 3 UN2374 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... N,N-Diethyl aniline.......................................... 6.1 UN2432 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Diethyl carbonate............................................ 3 UN2366 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethyl cellosolve, see Ethylene glycol diethyl ether........ ........... .............. ...................... ................ ........... ........... .......
....... Diethyl ether or Ethyl ether................................. 3 UN1155 I FLAMMABLE LIQUID...... T21............. 150 201 243 1 L........ 30 L....... E...... 40
....... Diethyl ketone............................................... 3 UN1156 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Diethyl peroxydicarbonate, with more than 27 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Diethyl sulfate.............................................. 6.1 UN1594 II POISON................ T14............. None 202 243 5 L........ 60 L....... C......
....... Diethyl sulfide.............................................. 3 UN2375 II FLAMMABLE LIQUID...... T14............. None 202 243 1 L........ 60 L....... E......
....... Diethylamine................................................. 3 UN1154 II FLAMMABLE LIQUID, N34, T8......... None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE.
....... Diethylaminoethanol.......................................... 3 UN2686 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethylaminopropylamine...................................... 3 UN2684 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Diethylbenzene............................................... 3 UN2049 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethyldichlorosilane........................................ 8 UN1767 II CORROSIVE, FLAMMABLE A7, B6, N34, T8, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T26.
....... Diethylene glycol dinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Diethyleneglycol dinitrate, desensitized with not less than 1.1D UN0075 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 4E, 21E
25 percent non-volatile water-insoluble phlegmatizer, by
mass.
....... Diethylenetriamine........................................... 8 UN2079 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A...... 40
....... N,N-Diethylethylenediamine................................... 8 UN2685 II CORROSIVE, FLAMMABLE T8.............. None 202 243 1 L........ 30 L....... A......
LIQUID.
....... Diethylgold bromide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diethylthiophosphoryl chloride............................... 8 UN2751 II CORROSIVE............. B2, T8.......... None 212 240 15 kg...... 50 kg...... C...... 40
....... Diethylzinc.................................................. 4.2 UN1366 I SPONTANEOUSLY B11, T28, T40... None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Difluorochloroethanes, see Chloro-1,1-difluoroethanes........ ........... .............. ...................... ................ ........... ........... .......
....... 1,1-Difluoroethane, R152a.................................... 2.1 UN1030 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... 1,1-Difluoroethylene, R1132a................................. 2.1 UN1959 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... E...... 40
....... Difluoromethane.............................................. 2.1 UN3252 FLAMMABLE GAS......... ................ 306 302 314, 315 Forbidden.. 150 kg..... D...... 40
....... Difluorophosphoric acid, anhydrous........................... 8 UN1768 II CORROSIVE............. A6, A7, B2, N5, None 202 242 1 L........ 30 L....... A...... 40
N34, T9, T27.
....... 2,3-Dihydropyran............................................. 3 UN2376 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... 1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic Forbidden .............. ...................... ................ ........... ........... .......
acid).
....... Diiodoacetylene.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Diisobutyl ketone............................................ 3 UN1157 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diisobutylamine.............................................. 3 UN2361 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Diisobutylene, isomeric compounds............................ 3 UN2050 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Diisooctyl acid phosphate.................................... 8 UN1902 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Diisopropyl ether............................................ 3 UN1159 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 40
....... Diisopropylamine............................................. 3 UN1158 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Diisopropylbenzene hydroperoxide, with more than 72 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Diketene, inhibited.......................................... 6.1 UN2521 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40, 49
LIQUID. B74, T38, T43,
T45.
....... 1,2-Dimethoxyethane.......................................... 3 UN2252 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 1,1-Dimethoxyethane.......................................... 3 UN2377 II FLAMMABLE LIQUID...... T13............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyl carbonate........................................... 3 UN1161 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl ........... .............. ...................... ................ ........... ........... .......
chloride.
....... 2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 Forbidden .............. ...................... ................ ........... ........... .......
percent with water.
....... Dimethyl disulfide........................................... 3 UN2381 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Dimethyl ether............................................... 2.1 UN1033 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Dimethyl-N-propylamine....................................... 3 UN2266 II FLAMMABLE LIQUID, T14, T26........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Dimethyl sulfate............................................. 6.1 UN1595 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Dimethyl sulfide............................................. 3 UN1164 II FLAMMABLE LIQUID...... T14............. None 202 242 5 L........ 60 L....... E...... 40
....... Dimethyl thiophosphoryl chloride............................. 6.1 UN2267 II POISON, CORROSIVE..... T7.............. None 202 243 1 L........ 30 L....... B...... 25
....... Dimethylamine, anhydrous..................................... 2.1 UN1032 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Dimethylamine solution....................................... 3 UN1160 II FLAMMABLE LIQUID, T8, T34......... None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... 2-Dimethylaminoacetonitrile.................................. 3 UN2378 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... A...... 26, 40
POISON.
....... 2-Dimethylaminoethanol....................................... 8 UN2051 III CORROSIVE, FLAMMABLE B1, T8.......... 154 203 242 60 L....... 220 L...... A......
LIQUID.
....... Dimethylaminoethyl methacrylate.............................. 6.1 UN2522 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B...... 40
....... N,N-Dimethylaniline.......................................... 6.1 UN2253 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... 2,3-Dimethylbutane........................................... 3 UN2457 II FLAMMABLE LIQUID...... T13............. 150 202 242 5 L........ 60 L....... E......
....... 1,3-Dimethylbutylamine....................................... 3 UN2379 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Dimethylcarbamoyl chloride................................... 8 UN2262 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A...... 40
....... Dimethylcyclohexanes......................................... 3 UN2263 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethylcyclohexylamine...................................... 8 UN2264 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Dimethyldichlorosilane....................................... 3 UN1162 II FLAMMABLE LIQUID, B77, T15, T26... None 202 243 Forbidden.. Forbidden.. B...... 40
CORROSIVE.
....... Dimethyldiethoxysilane....................................... 3 UN2380 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyldioxanes............................................. 3 UN2707 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... N,N-Dimethylformamide........................................ 3 UN2265 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dimethylhexane dihydroperoxide (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dimethylhydrazine, symmetrical............................... 6.1 UN2382 I POISON, FLAMMABLE 2, A7, B9, B14, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B32, B74, B77,
T38, T43, T45.
....... Dimethylhydrazine, unsymmetrical............................. 6.1 UN1163 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 21, 38, 40,
LIQUID, CORROSIVE. B74, B79, T38, 100
T43, T45.
....... 2,2-Dimethylpropane.......................................... 2.1 UN2044 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Dimethylzinc................................................. 4.2 UN1370 I SPONTANEOUSLY B11, B16, T28, None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. T29, T40.
....... Dinitro-o-cresol, solid...................................... 6.1 UN1598 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Dinitro-o-cresol, solution................................... 6.1 UN1598 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... 1,3-Dinitro-5,5-dimethyl hydantoin........................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitro-7,8-dimethylglycoluril (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3-Dinitro-4,5-dinitrosobenzene............................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry).... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4-Dinitro-1,3,5-trimethylbenzene........................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroanilines.............................................. 6.1 UN1596 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 91
....... Dinitrobenzenes, liquid...................................... 6.1 UN1597 II POISON................ 11, T14......... None 202 243 5 L........ 60 L....... A...... 91
....... Dinitrobenzenes, solid....................................... 6.1 UN1597 II POISON................ 11.............. None 212 242 25 kg...... 100 kg..... A...... 91
....... Dinitrochlorobenzene, see Chlorodinitrobenzene............... ........... .............. ...................... ................ ........... ........... .......
....... 1,2-Dinitroethane............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1-Dinitroethane (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrogen tetroxide, liquefied.............................. 2.3 UN1067 POISON GAS, OXIDIZER, 1, B7, B12, B14, None 336 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B45, B46, B61,
B66, B67, B77.
....... Dinitroglycoluril or Dingu................................... 1.1D UN0489 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Dinitromethane............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrophenol, dry or wetted with less than 15 percent water, 1.1D UN0076 II EXPLOSIVE 1.1D, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Dinitrophenol solutions...................................... 6.1 UN1599 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 36
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 36
....... Dinitrophenol, wetted with not less than 15 percent water, by 4.1 UN1320 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
mass. POISON. A20, N41.
....... Dinitrophenolates alkali metals, dry or wetted with less than 1.3C UN0077 II EXPLOSIVE 1.3C, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
15 percent water, by mass.
....... Dinitrophenolates, wetted with not less than 15 percent 4.1 UN1321 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
water, by mass. POISON. A20, N41.
....... Dinitropropylene glycol...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroresorcinol, dry or wetted with less than 15 percent 1.1D UN0078 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... 2,4-Dinitroresorcinol (heavy metal salts of) (dry)........... Forbidden .............. ...................... ................ ........... ........... .......
....... 4,6-Dinitroresorcinol (heavy metal salts of) (dry)........... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroresorcinol, wetted with not less than 15 percent 4.1 UN1322 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
water, by mass. A20, N41.
....... 3,5-Dinitrosalicylic acid (lead salt) (dry).................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrosobenzene............................................. 1.3C UN0406 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Dinitrosobenzylamidine and salts of (dry).................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,2-Dinitrostilbene.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrotoluenes, liquid...................................... 6.1 UN2038 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... Dinitrotoluenes, molten...................................... 6.1 UN1600 II POISON................ T14............. None 202 243 Forbidden.. Forbidden.. C......
....... Dinitrotoluenes, solid....................................... 6.1 UN2038 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... 1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry)........ Forbidden .............. ...................... ................ ........... ........... .......
....... Dioxane...................................................... 3 UN1165 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dioxolane.................................................... 3 UN1166 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Dipentene.................................................... 3 UN2052 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diphenylamine chloroarsine................................... 6.1 UN1698 I POISON................ ................ None 201 None Forbidden.. Forbidden.. D...... 40
....... Diphenylchloroarsine, liquid................................. 6.1 UN1699 I POISON................ A8, B14, B32, None 201 243 Forbidden.. 30 L....... D...... 40
N33, N34.
....... Diphenylchloroarsine, solid.................................. 6.1 UN1699 I POISON................ A8, B14, B32, None 211 242 Forbidden.. 15 kg...... D...... 40
N33, N34.
....... Diphenyldichlorosilane....................................... 8 UN1769 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
....... Diphenylmethane-4,4'diisocyanate............................. 6.1 UN2489 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 48
....... Diphenylmethyl bromide....................................... 8 UN1770 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... D...... 40
....... Dipicryl sulfide, dry or wetted with less than 10 percent 1.1D UN0401 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Dipicryl sulfide, wetted with not less than 10 percent water, 4.1 UN2852 I FLAMMABLE SOLID....... A2, N41......... None 211 None Forbidden.. 0.5 kg..... D...... 28
by mass.
....... Dipicrylamine, see Hexanitrodiphenylamine.................... ........... .............. ...................... ................ ........... ........... .......
....... Dipropionyl peroxide, with more than 28 percent in solution.. Forbidden .............. ...................... ................ ........... ........... .......
....... Dipropyl ether............................................... 3 UN2384 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Dipropylamine................................................ 3 UN2383 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Dipropylketone............................................... 3 UN2710 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Disinfectants, liquid, corrosive n.o.s....................... 8 UN1903 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A......
....... Disinfectants, liquid, toxic, n.o.s.......................... 6.1 UN3142 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... A...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Disinfectants, solid, toxic, n.o.s........................... 6.1 UN1601 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Disodium trioxosilicate, pentahydrate........................ 8 UN3253 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Dispersant gases, n.o.s. see Refrigerant gases, n.o.s........ ........... .............. ...................... ................ ........... ........... .......
....... Dithiocarbamate pesticides, liquid, flammable, toxic, flash 3 UN2772 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Dithiocarbamate pesticides, liquid, toxic.................... 6.1 UN3006 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Dithiocarbamate pesticides, liquid, toxic, flammable, 6.1 UN3005 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Dithiocarbamate pesticides, solid, toxic..................... 6.1 UN2771 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Divinyl ether, inhibited..................................... 3 UN1167 I FLAMMABLE LIQUID...... T14............. None 201 243 5 L........ 60 L....... E...... 40
D...... Dodecylbenzenesulfonic acid.................................. 8 NA2584 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... B...... 9
....... Dodecyltrichlorosilane....................................... 8 UN1771 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Dry ice, see Carbon dioxide, solid........................... ........... .............. ...................... ................ ........... ........... .......
....... Dyes, liquid, corrosive n.o.s. or Dye intermediates, liquid, 8 UN2801 II CORROSIVE............. 11, B2, T14..... 154 202 242 1 L........ 30 L....... A......
corrosive, n.o.s..
............................................................. ........... .............. III CORROSIVE............. 11, T7.......... 154 203 241 5 L........ 60 L....... A......
....... Dyes, liquid, toxic, n.o.s or Dye intermediates, liquid, 6.1 UN1602 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
toxic, n.o.s..
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220........ A......
....... Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, 8 UN3147 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
corrosive, n.o.s..
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, 6.1 UN3143 I POISON................ A5.............. None 211 242 5 kg....... 50 kg...... A......
toxic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Dynamite, see Explosive, blasting, type A.................... ........... .............. ...................... ................ ........... ........... .......
....... Electrolyte (acid or alkali) for batteries, see Battery ........... .............. ...................... ................ ........... ........... .......
fluid, acid or Battery fluid, alkali.
....... Elevated temperature liquid, flammable, n.o.s., with flash 3 UN3256 III FLAMMABLE LIQUID...... T1.............. None None 247 Forbidden.. Forbidden.. A......
point above 37.8 C, at or above its flash point.
....... Elevated temperature liquid, n.o.s., at or above 100 C and 9 UN3257 III CLASS 9............... T1.............. None None 247 Forbidden.. Forbidden.. A...... 85
below its flash point.
....... Elevated temperature solid, n.o.s., at or above 240 C, see 9 UN3258 III CLASS 9............... ................ 247(h)(4) None 247 Forbidden.. Forbidden.. A...... 85
section 173.247(h)(4).
....... Engine starting fluid, with flammable gas.................... 2.1 UN1960 FLAMMABLE GAS......... ................ None 304 None Forbidden.. 150 kg..... D...... 40
....... Engines, internal combustion, including when fitted in 9 UN3166 CLASS 9............... ................ 220 220 None Forbidden.. No limit... A......
machinery or vehicles.
....... Engines, internal combustion, see Vehicle, self-propelled.... ........... .............. ...................... ................ ........... ........... .......
....... Environmentally hazardous substances, liquid, n.o.s.......... 9 UN3082 III CLASS 9............... 8, N50, T1...... 155 203 241 None....... None....... A......
....... Environmentally hazardous substances, solid, n.o.s........... 9 UN3077 III CLASS 9............... 8, B50, B54..... 155 213 240 None....... None....... A......
....... Epibromohydrin............................................... 6.1 UN2558 I POISON................ T18, T26........ None 201 243 Forbidden.. Forbidden.. D...... 40
....... Epichlorohydrin.............................................. 6.1 UN2023 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... 1,2-Epoxy-3-ethoxypropane.................................... 3 UN2752 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Esters, n.o.s................................................ 3 UN3272 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Etching acid, liquid, n.o.s., see Hydrofluoric acid, solution ........... .............. ...................... ................ ........... ........... .......
etc..
....... Ethane, compressed........................................... 2.1 UN1035 FLAMMABLE GAS......... ................ 306 304 302 Forbidden.. 150 kg..... E...... 40
D...... Ethane-Propane mixture, refrigerated liquid.................. 2.1 NA1961 FLAMMABLE GAS......... ................ None 316 314, 315 Forbidden.. Forbidden.. D...... 40
....... Ethane, refrigerated liquid.................................. 2.1 UN1961 FLAMMABLE GAS......... ................ None None 315 Forbidden.. Forbidden.. D...... 40
....... Ethanol amine dinitrate...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl 3 UN1170 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... A......
alcohol solutions.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethanolamine or Ethanolamine solutions....................... 8 UN2491 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Ether, see Diethyl ether..................................... ........... .............. ...................... ................ ........... ........... .......
....... Ethers, n.o.s................................................ 3 UN3271 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl acetate................................................ 3 UN1173 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl acrylate, inhibited.................................... 3 UN1917 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Ethyl alcohol, see Ethanol................................... ........... .............. ...................... ................ ........... ........... .......
....... Ethyl aldehyde, see Acetaldehyde............................. ........... .............. ...................... ................ ........... ........... .......
....... Ethyl amyl ketone............................................ 3 UN2271 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... N-Ethyl-N-benzylaniline...................................... 6.1 UN2274 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Ethyl borate................................................. 3 UN1176 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl bromide................................................ 6.1 UN1891 II POISON................ T17............. None 202 243 5 L........ 60 L....... B...... 40, 85
....... Ethyl bromoacetate........................................... 6.1 UN1603 II POISON................ T14............. None 202 243 Forbidden.. Forbidden.. D...... 40
....... Ethyl butyl ether............................................ 3 UN1179 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Ethyl butyrate............................................... 3 UN1180 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl chloride............................................... 2.1 UN1037 FLAMMABLE GAS......... B63, B77........ None 322 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethyl chloroacetate.......................................... 6.1 UN1181 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Ethyl chloroformate.......................................... 6.1 UN1182 I POISON, FLAMMABLE 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B32,
B74, N34, T38,
T43, T45.
....... Ethyl-2-chloropropionate..................................... 3 UN2935 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Ethyl chlorothioformate...................................... 8 UN2826 II CORROSIVE, POISON, 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 40
FLAMMABLE LIQUID. B74, T38, T43,
T45.
....... Ethyl crotonate.............................................. 3 UN1862 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl cyanoacetate........................................... 6.1 UN2666 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 26
....... Ethyl ether, see Diethyl ether............................... ........... .............. ...................... ................ ........... ........... .......
....... Ethyl fluoride............................................... 2.1 UN2453 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Ethyl formate................................................ 3 UN1190 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Ethyl hydroperoxide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethyl isobutyrate............................................ 3 UN2385 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
+...... Ethyl isocyanate............................................. 3 UN2481 I FLAMMABLE LIQUID, 1, A7, B9, B14, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B30, B72, T38,
T43, T44.
....... Ethyl lactate................................................ 3 UN1192 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl mercaptan.............................................. 3 UN2363 I FLAMMABLE LIQUID...... T21............. None 201 243 Forbidden.. 30 L....... E...... 95, 102
....... Ethyl methacrylate........................................... 3 UN2277 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl methyl ether........................................... 2.1 UN1039 FLAMMABLE GAS......... B63............. None 324 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethyl methyl ketone or Methyl ethyl ketone................... 3 UN1193 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl nitrite solutions...................................... 3 UN1194 I FLAMMABLE LIQUID, ................ None 201 None Forbidden.. Forbidden.. E...... 40, 105
POISON.
....... Ethyl orthoformate........................................... 3 UN2524 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl oxalate................................................ 6.1 UN2525 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Ethyl perchlorate............................................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Ethyl phosphonothioic dichloride, anhydrous.................. 6.1 NA2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
B74, T38, T43,
T45.
D...... Ethyl phosphonous dichloride, anhydrous pyrophoric liquid.... 6.1 NA2845 I POISON, SPONTANEOUSLY 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. B74, T38, T43,
T45.
D...... Ethyl phosphorodichloridate.................................. 6.1 NA2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
B74, T38, T43,
T45.
....... Ethyl propionate............................................. 3 UN1195 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl propyl ether........................................... 3 UN2615 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Ethyl silicate, see Tetraethyl silicate...................... ........... .............. ...................... ................ ........... ........... .......
....... Ethylacetylene, inhibited.................................... 2.1 UN2452 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethylamine................................................... 2.1 UN1036 FLAMMABLE GAS......... B77............. None 321 314, 315 Forbidden.. 150 kg..... D...... 40
....... Ethylamine, aqueous solution with not less than 50 percent 3 UN2270 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 5 L........ B...... 40
but not more than 70 percent ethylamine. CORROSIVE.
....... N-Ethylaniline............................................... 6.1 UN2272 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Ethylaniline............................................... 6.1 UN2273 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Ethylbenzene................................................. 3 UN1175 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... N-Ethylbenzyltoluidines liquid............................... 6.1 UN2753 III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A......
....... N-Ethylbenzyltoluidines solid................................ 6.1 UN2753 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... 2-Ethylbutanol............................................... 3 UN2275 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 2-Ethylbutyl acetate......................................... 3 UN1177 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 2-Ethylbutyraldehyde......................................... 3 UN1178 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Ethyldichloroarsine.......................................... 6.1 UN1892 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... Ethyldichlorosilane.......................................... 4.3 UN1183 I DANGEROUS WHEN WET, A2, A3, A7, N34, None 201 244 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE T18, T26. 49, 100
LIQUID.
....... Ethylene, acetylene and propylene in mixtures, refrigerated 2.1 UN3138 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. Forbidden.. D...... 40
liquid with at least 71.5 percent ethylene with not more
than 22.5 percent acetylene and not more than 6 percent
propylene.
....... Ethylene chlorohydrin........................................ 6.1 UN1135 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, T38, T43,
T45.
....... Ethylene, compressed......................................... 2.1 UN1962 FLAMMABLE GAS......... ................ 306 304 302 Forbidden.. 150 kg..... E...... 40
....... Ethylene diamine diperchlorate............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethylene dibromide........................................... 6.1 UN1605 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Ethylene dibromide and methyl bromide liquid mixtures, see ........... .............. ...................... ................ ........... ........... .......
Methyl bromide and ethylene dibromide, liquid mixtures.
....... Ethylene dichloride.......................................... 3 UN1184 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Ethylene glycol diethyl ether................................ 3 UN1153 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol dinitrate.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethylene glycol monobutyl ether.............................. 6.1 UN2369 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Ethylene glycol monoethyl ether.............................. 3 UN1171 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monoethyl ether acetate...................... 3 UN1172 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monomethyl ether............................. 3 UN1188 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monomethyl ether acetate..................... 3 UN1189 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene oxide and carbon dioxide mixture with more than 87 2.3 UN3300 POISON GAS, FLAMMABLE 4............... None 304 314, 315 Forbidden.. 75 kg...... D...... 40
percent ethylene oxide. GAS.
....... Ethylene oxide and carbon dioxide mixtures, see Carbon ........... .............. ...................... ................ ........... ........... .......
dioxide and ethylene oxide mixtures, etc..
....... Ethylene oxide and carbon dioxide mixtures with more than 9 2.1 UN1041 FLAMMABLE GAS......... 25.............. 306 304 314, 315 Forbidden.. 25 kg...... B...... 40
percent but not more than 87 percent ethylene oxide.
....... Ethylene oxide and carbon dioxide mixtures with not more than 2.2 UN1952 NONFLAMMABLE GAS...... 25.............. 306 304 314, 315 75 kg...... 150 kg..... A......
9 percent ethylene oxide.
....... Ethylene oxide and chlorotetrafluoroethane mixture with not 2.2 UN3297 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
more than 8.8 percent ethylene oxide.
....... Ethylene oxide and dichlorodifluoromethane mixture, with not 2.2 UN3070 NONFLAMMABLE GAS...... 25.............. 306 304 314, 315 75 kg...... 150 kg..... A......
more than 12.5 percent ethylene oxide.
....... Ethylene oxide and pentafluoroethane mixture with not more 2.2 UN3298 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
than 7.9 percent ethylene oxide.
....... Ethylene oxide and propylene oxide mixtures, with not more 3 UN2983 I FLAMMABLE LIQUID, 5, A11, N4, N34, None 201 243 Forbidden.. 30 L....... E...... 40
than 30 percent ethylene oxide. POISON. T24, T29.
....... Ethylene oxide and tetrafluoroethane mixture with not more 2.2 UN3299 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
than 5.6 percent ethylene oxide.
....... Ethylene oxide or Ethylene oxide with nitrogen up to a total 2.3 UN1040 POISON GAS, FLAMMABLE 4, 25........... None 323 323 Forbidden.. 25 kg...... D...... 40
pressure of 1MPa (10 bar) at 50 degrees C. GAS.
....... Ethylene, refrigerated liquid (cryogenic liquid)............. 2.1 UN1038 FLAMMABLE GAS......... ................ None 316 318, 319 Forbidden.. Forbidden.. D...... 40
....... Ethylenediamine.............................................. 8 UN1604 II CORROSIVE, FLAMMABLE T14............. 154 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Ethyleneimine, inhibited..................................... 6.1 UN1185 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, B77, N25,
N32, T38, T43,
T44.
....... Ethylhexaldehyde, see Octyl aldehydes etc.................... ........... .............. ...................... ................ ........... ........... .......
....... 2-Ethylhexylamine............................................ 3 UN2276 III FLAMMABLE LIQUID, B1, T2.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... 2-Ethylhexylchloroformate.................................... 6.1 UN2748 II POISON, CORROSIVE..... T42............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... Ethylphenyldichlorosilane.................................... 8 UN2435 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C......
T26.
....... 1-Ethylpiperidine............................................ 3 UN2386 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... N-Ethyltoluidines............................................ 6.1 UN2754 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Ethyltrichlorosilane......................................... 3 UN1196 II FLAMMABLE LIQUID, A7, N34, T15, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. T26.
....... Etiologic agent, see Infectious substances, etc.)............ ........... .............. ...................... ................ ........... ........... .......
....... Explosive articles, see Articles, explosive , n.o.s. etc..... ........... .............. ...................... ................ ........... ........... .......
....... Explosive, blasting, type A.................................. 1.1D UN0081 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 21E
....... Explosive, blasting, type B.................................. 1.1D UN0082 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type B or Agent blasting, Type B........ 1.5D UN0331 II EXPLOSIVE 1.5D........ 105, 106........ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type C.................................. 1.1D UN0083 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type D.................................. 1.1D UN0084 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type E.................................. 1.1D UN0241 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Explosive, blasting, type E or Agent blasting, Type E........ 1.5D UN0332 II EXPLOSIVE 1.5D........ 105, 106........ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, forbidden. See Sec. 173.54........................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Explosive pest control devices............................... 1.1E NA0006 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. E......
D...... Explosive pest control devices............................... 1.4E NA0412 II EXPLOSIVE 1.4E........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Explosive substances, see Substances, explosive, n.o.s. etc.. ........... .............. ...................... ................ ........... ........... .......
....... Explosives, slurry, see Explosive, blasting, type E.......... ........... .............. ...................... ................ ........... ........... .......
....... Explosives, water gels, see Explosive, blasting, type E...... ........... .............. ...................... ................ ........... ........... .......
....... Extracts, aromatic, liquid................................... 3 UN1169 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Extracts, flavoring, liquid.................................. 3 UN1197 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Fabric with animal or vegetable oil, see Fibers or fabrics, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Ferric arsenate.............................................. 6.1 UN1606 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ferric arsenite.............................................. 6.1 UN1607 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ferric chloride, anhydrous................................... 8 UN1773 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Ferric chloride, solution.................................... 8 UN2582 III CORROSIVE............. B15, T8......... 154 203 241 5 L........ 60 L....... A......
....... Ferric nitrate............................................... 5.1 UN1466 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Ferrocerium.................................................. 4.1 UN1323 II FLAMMABLE SOLID....... A19............. 151 212 240 15 kg...... 50 kg...... A......
....... Ferrosilicon, with 30 percent or more but less than 90 4.3 UN1408 III DANGEROUS WHEN WET, A1, A19......... None 213 240 25 kg...... 100 kg..... A...... 13, 40, 85,
percent silicon. KEEP AWAY FROM FOOD. 103
....... Ferrous arsenate............................................. 6.1 UN1608 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Ferrous chloride, solid...................................... 8 NA1759 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
D...... Ferrous chloride, solution................................... 8 NA1760 II CORROSIVE............. B3.............. 154 202 242 1 L........ 30 L....... B...... 40
....... Ferrous metal borings or Ferrous metal shavings or Ferrous 4.2 UN2793 III SPONTANEOUSLY A1, A19......... None 213 241 25 kg...... 100 kg..... A......
metal turnings or Ferrous metal cuttings in a form liable to COMBUSTIBLE.
self-heating.
....... Fertilizer ammoniating solution with free ammonia............ 2.2 UN1043 NONFLAMMABLE GAS...... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
AIW.... Fibers or Fabrics, animal or vegetable or Synthentic, n.o.s. 4.2 UN1373 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A......
with animal or vegetable oil. COMBUSTIBLE.
....... Fibers or Fabrics impregnated with weakly nitrated 4.1 UN1353 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... D......
nitrocellulose, n.o.s..
....... Films, nitrocellulose base, from which gelatine has been ........... .............. ...................... ................ ........... ........... .......
removed; film scrap, see Celluloid scrap.
....... Films, nitrocellulose base, gelatine coated (except scrap)... 4.1 UN1324 III FLAMMABLE SOLID....... ................ None 183 None 25 kg...... 100 kg..... D...... 91
....... Fire extinguisher charges, corrosive liquid.................. 8 UN1774 II CORROSIVE............. N41............. 154 202 None 1 L........ 30 L....... A......
....... Fire extinguisher charges, expelling, explosive, see ........... .............. ...................... ................ ........... ........... .......
Cartridges, power device.
....... Fire extinguishers containing compressed or liquefied gas.... 2.2 UN1044 NONFLAMMABLE GAS...... ................ 309 309 None 75 kg...... 150 kg..... A......
....... Firelighters, solid with flammable liquid.................... 4.1 UN2623 II FLAMMABLE SOLID....... A19............. None 212 None 15 kg...... 50 kg...... A...... 119
............................................................. ........... .............. III FLAMMABLE SOLID....... A1, A19......... None 213 None 25 kg...... 100 kg..... A...... 119
....... Fireworks.................................................... 1.1G UN0333 II EXPLOSIVE 1.1G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.2G UN0334 II EXPLOSIVE 1.2G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.3G UN0335 II EXPLOSIVE 1.3G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.4G UN0336 II EXPLOSIVE 1.4G........ 108............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fireworks.................................................... 1.4S UN0337 II EXPLOSIVE 1.4S........ 108............. None 62 None 25 kg...... 100 kg..... A......
W...... Fish meal, stabilized or Fish scrap, stabilized.............. 9 UN2216 III None.................. ................ 155 218 218 No limit... No limit... A...... 88
....... Fish meal, unstablized or Fish scrap, unstabilized........... 4.2 UN1374 II SPONTANEOUSLY A1, A19......... None 212 241 15 kg...... 50 kg...... A...... 119, 120
COMBUSTIBLE.
....... Fissile radioactive materials, see Radioactive material, ........... .............. ...................... ................ ........... ........... .......
fissile, n.o.s..
....... Flammable compressed gas, see Compressed or Liquefied gas, ........... .............. ...................... ................ ........... ........... .......
flammable, etc..
....... Flammable compressed gas (small receptacles not fitted with a ........... .............. ...................... ................ ........... ........... .......
dispersion device, not refillable), see Receptacles, etc..
....... Flammable gas in lighters, see Lighters for cigars or ........... .............. ...................... ................ ........... ........... .......
cigarettes, with flammable gas.
....... Flammable liquid, toxic, corrosive, n.o.s.................... 3 UN3286 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 2.5 L...... E...... 21, 40, 100
POISON, CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 5 L........ B...... 21, 40, 100
POISON, CORROSIVE.
....... Flammable liquids, corrosive, n.o.s.......................... 3 UN2924 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... E...... 40
CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T15, T26........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T15, T26.... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Flammable liquids, n.o.s..................................... 3 UN1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
....... Flammable liquids, toxic, n.o.s.............................. 3 UN1992 I FLAMMABLE LIQUID, T42............. None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T18............. None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T18......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Flammable solid, corrosive, inorganic, n.o.s................. 4.1 UN3180 II FLAMMABLE SOLID, A1.............. 151 212 242 15 kg...... 50 kg...... D...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE SOLID, A1.............. 151 213 242 25 kg...... 100 kg..... D...... 40
CORROSIVE.
....... Flammable solid, inorganic, n.o.s............................ 4.1 UN3178 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B......
....... Flammable solid, organic, molten, n.o.s...................... 4.1 UN3176 II FLAMMABLE SOLID....... T9.............. 151 212 240 Forbidden.. Forbidden.. C......
............................................................. ........... .............. III FLAMMABLE SOLID....... T9.............. 151 213 240 Forbidden.. Forbidden.. C......
....... Flammable solid, toxic, inorganic, n.o.s..................... 4.1 UN3179 II FLAMMABLE SOLID, A1.............. 151 212 242 15 kg...... 50 kg...... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE SOLID, KEEP A1.............. 151 213 242 25 kg...... 100 kg..... B...... 40
AWAY FROM FOOD.
....... Flammable solids, corrosive, organic, n.o.s.................. 4.1 UN2925 II FLAMMABLE SOLID, A1.............. None 212 242 15 kg...... 50 kg...... D...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE SOLID, A1.............. 151 213 242 25 kg...... 100 kg..... D...... 40
CORROSIVE.
....... Flammable solids, organic, n.o.s............................. 4.1 UN1325 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B......
....... Flammable solids, toxic, organic, n.o.s...................... 4.1 UN2926 II FLAMMABLE SOLID, A1.............. None 212 242 15 kg...... 50 kg...... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE SOLID, KEEP A1.............. 151 213 242 25 kg...... 100 kg..... B...... 40
AWAY FROM FOOD.
....... Flares, aerial............................................... 1.3G UN0093 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Flares, aerial............................................... 1.4G UN0403 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Flares, aerial............................................... 1.4S UN0404 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Flares, aerial............................................... 1.1G UN0420 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, aerial............................................... 1.2G UN0421 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, airplane, see Flares, aerial......................... ........... .............. ...................... ................ ........... ........... .......
....... Flares, signal, see Cartridges, signal....................... ........... .............. ...................... ................ ........... ........... .......
....... Flares, surface.............................................. 1.3G UN0092 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Flares, surface.............................................. 1.1G UN0418 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, surface.............................................. 1.2G UN0419 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, water-activated, see Contrivances, water-activated, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Flash powder................................................. 1.1G UN0094 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Flash powder................................................. 1.3G UN0305 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Flue dusts, poisonous, see Arsenical dust.................... ........... .............. ...................... ................ ........... ........... .......
....... Fluoric acid, see Hydrofluoric acid, solution, etc........... ........... .............. ...................... ................ ........... ........... .......
....... Fluorine, compressed......................................... 2.3 UN1045 POISON GAS, OXIDIZER, 1............... None 302 None Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Fluoroacetic acid............................................ 6.1 UN2642 I POISON................ ................ None 211 242 1 kg....... 15 kg...... E......
....... Fluoroanilines............................................... 6.1 UN2941 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... Fluorobenzene................................................ 3 UN2387 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Fluoroboric acid............................................. 8 UN1775 II CORROSIVE............. A6, A7, B2, B15, 154 202 242 1 L........ 30 L....... A......
N3, N34, T15,
T27.
....... Fluorophosphoric acid anhydrous.............................. 8 UN1776 II CORROSIVE............. A6, A7, B2, N3, None 202 242 1 L........ 30 L....... A......
N34, T9, T27.
....... Fluorosilicates, n.o.s....................................... 6.1 UN2856 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Fluorosilicic acid........................................... 8 UN1778 II CORROSIVE............. A6, A7, B2, B15, None 202 242 1 L........ 30 L....... A......
N3, N34, T12,
T27.
....... Fluorosulfonic acid.......................................... 8 UN1777 I CORROSIVE............. A3, A6, A7, A10, None 201 243 0.5 L...... 2.5 L...... D...... 40
B6, B10, B41,
N3, T9, T27.
....... Fluorotoluenes............................................... 3 UN2388 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Forbidden materials. See 173.21.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Formaldehyde, solutions, flammable........................... 3 UN1198 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 1 L........ 60 L....... A...... 40
CORROSIVE.
....... Formaldehyde, solutions, with not less than 25 percent 8 UN2209 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A......
formaldehyde.
....... Formalin, see Formaldehyde, solutions........................ ........... .............. ...................... ................ ........... ........... .......
....... Formic acid.................................................. 8 UN1779 II CORROSIVE............. B2, B12, B28, T8 154 202 242 1 L........ 30 L....... A...... 40
....... Fracturing devices, explosive, without detonators for oil 1.1D UN0099 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
wells.
....... Fuel, aviation, turbine engine............................... 3 UN1863 I FLAMMABLE LIQUID...... T7.............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
D...... Fuel oil (No. 1, 2, 4, 5, or 6).............................. 3 NA1993 III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... A......
....... Fulminate of mercury (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminate of mercury, wet, see Mercury fulminate, etc........ ........... .............. ...................... ................ ........... ........... .......
....... Fulminating gold............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating mercury.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating platinum......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating silver........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminic acid................................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Fumaryl chloride............................................. 8 UN1780 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 8, 40
....... Furan........................................................ 3 UN2389 I FLAMMABLE LIQUID...... T18............. None 201 243 1 L........ 30 L....... E...... 40
....... Furfural..................................................... 3 UN1199 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Furfuryl alcohol............................................. 6.1 UN2874 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A...... 26, 74
....... Furfurylamine................................................ 3 UN2526 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Fuse, detonating, metal clad, see Cord, detonating, metal ........... .............. ...................... ................ ........... ........... .......
clad.
....... Fuse, detonating, mild effect, metal clad, see Cord, ........... .............. ...................... ................ ........... ........... .......
detonating, mild effect, metal clad.
....... Fuse, igniter tubular metal clad............................. 1.4G UN0103 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuse, instantaneous, non-detonating or Quickmatch............ 1.3G UN0101 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuse, safety................................................. 1.4S UN0105 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Fusee (railway or highway)................................... 4.1 NA1325 II FLAMMABLE SOLID....... ................ None 184 None 15 kg...... 50 kg...... B......
....... Fusel oil.................................................... 3 UN1201 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Fuses, tracer, see Tracers for ammunition.................... ........... .............. ...................... ................ ........... ........... .......
....... Fuzes, combination, percussion and time, see Fuzes, ........... .............. ...................... ................ ........... ........... .......
detonating (UN 0257, UN 0367); Fuzes, igniting (UN 0317, UN
0368).
....... Fuzes, detonating............................................ 1.1B UN0106 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Fuzes, detonating............................................ 1.2B UN0107 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Fuzes, detonating............................................ 1.4B UN0257 II EXPLOSIVE 1.4B........ 116............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, detonating............................................ 1.4S UN0367 II EXPLOSIVE 1.4S........ 116............. None 62 None 25 kg...... 100 kg..... A......
....... Fuzes, detonating, with protective features.................. 1.1D UN0408 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, detonating, with protective features.................. 1.2D UN0409 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, detonating, with protective features.................. 1.4D UN0410 II EXPLOSIVE 1.4D........ 116............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, igniting.............................................. 1.3G UN0316 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, igniting.............................................. 1.4G UN0317 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, igniting.............................................. 1.4S UN0368 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Galactsan trinitrate......................................... Forbidden .............. ...................... ................ ........... ........... .......
AW..... Gallium...................................................... 8 UN2803 III CORROSIVE............. ................ None 162 240 20 kg...... 20 kg...... B...... 48
....... Gas generator assemblies (aircraft), containing a non- 2.2 .............. NONFLAMMABLE GAS...... ................ None 335 None 75 kg...... 150 kg..... A......
flammable non-toxic gas and a propellant cartridge.
D...... Gas identification set....................................... 2.3 NA9035 POISON GAS............ 6............... None 194 None Forbidden.. Forbidden.. D......
....... Gas oil or Diesel fuel or Heating oil, light................. 3 UN1202 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Gas, refrigerated liquid, n.o.s.............................. 2.2 UN3158 NONFLAMMABLE GAS...... ................ 306 304 314, 315 50 kg...... 500 kg..... D......
....... Gas sample, non-pressurized, flammable, n.o.s., not 2.1 UN3167 FLAMMABLE GAS......... 35.............. 306 302, 304 None 1 L........ 5 L........ D......
refrigerated liquid.
....... Gas sample, non-pressurized, toxic, flammable, n.o.s., not 2.3 UN3168 POISON GAS, FLAMMABLE 35.............. 306 302 None Forbidden.. 1 L........ D......
refrigerated liquid. GAS.
....... Gas sample, non-pressurized, toxic, n.o.s., not refrigerated 2.3 UN3169 POISON GAS............ 35.............. 306 302, 304 None Forbidden.. 1 L........ D......
liquid.
D...... Gasohol gasoline mixed with ethyl alcohol, with not more than 3 NA1203 II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... E......
20 percent alcohol.
....... Gasoline..................................................... 3 UN1203 II FLAMMABLE LIQUID...... B33, T8......... 150 202 242 5 L........ 60 L....... E......
....... Gasoline, casinghead, see Natural gasoline................... ........... .............. ...................... ................ ........... ........... .......
....... Gelatine, blasting, see Explosive, blasting, type A.......... ........... .............. ...................... ................ ........... ........... .......
....... Gelatine dynamites, see Explosive, blasting, type A.......... ........... .............. ...................... ................ ........... ........... .......
....... Germane...................................................... 2.3 UN2192 POISON GAS, FLAMMABLE 2, 25........... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Glycerol-1,3-dinitrate....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol gluconate trinitrate................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol lactate trinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol alpha-monochlorohydrin.............................. 6.1 UN2689 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Glyceryl trinitrate, see Nitroglycerin, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Glycidaldehyde............................................... 3 UN2622 II FLAMMABLE LIQUID, T8.............. 150 202 243 1 L........ 60 L....... A...... 40
POISON.
D...... Grenades, empty primed....................................... 1.4S NA0349 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Grenades, hand or rifle, with bursting charge................ 1.1D UN0284 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, hand or rifle, with bursting charge................ 1.2D UN0285 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, hand or rifle, with bursting charge................ 1.1F UN0292 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Grenades, hand or rifle, with bursting charge................ 1.2F UN0293 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Grenades, illuminating, see Ammunition, illuminating, etc.... ........... .............. ...................... ................ ........... ........... .......
....... Grenades, practice, hand or rifle............................ 1.4S UN0110 II EXPLOSIVE 1.4S........ ................ 62 None 25 kg...... 100 kg..... A......
....... Grenades, practice, hand or rifle............................ 1.3G UN0318 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, practice, hand or rifle............................ 1.2G UN0372 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades practice Hand or rifle.............................. 1.4G UN0452 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Grenades, smoke, see Ammunition, smoke, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Guanidine nitrate............................................ 5.1 UN1467 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 73
....... Guanyl nitrosaminoguanylidene hydrazine (dry)................ Forbidden .............. ...................... ................ ........... ........... .......
....... Guanyl nitrosaminoguanylidene hydrazine, wetted with not less 1.1A UN0113 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
than 30 percent water, by mass.
....... Guanyl nitrosaminoguanyltetrazene (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, 1.1A UN0114 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
wetted with not less than 30 percent water or mixture of
alcohol and water, by mass.
....... Gunpowder, compressed or Gunpowder in pellets, see Black ........... .............. ...................... ................ ........... ........... .......
powder (UN 0028).
....... Gunpowder, granular or as a meal, see Black powder (UN 0027). ........... .............. ...................... ................ ........... ........... .......
....... Hafnium powder, dry.......................................... 4.2 UN2545 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, N34... None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Hafnium powder, wetted with not less than 25 percent water (a 4.1 UN1326 II FLAMMABLE SOLID....... A6, A19, A20, None 212 241 15 kg...... 50 kg...... E......
visible excess of water must be present) (a) mechanically N34.
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Halogenated irritating liquids, n.o.s........................ 6.1 UN1610 I POISON................ T42............. None 201 243 Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... D...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... D...... 40
....... Hand signal device, see Signal devices, hand................. ........... .............. ...................... ................ ........... ........... .......
....... Hazardous substances, liquid or solid, n.o.s., see ........... .............. ...................... ................ ........... ........... .......
Environmentally hazardous substances, etc..
D...... Hazardous waste, liquid, n.o.s............................... 9 NA3082 III CLASS 9............... ................ 155 203 241 No limit... No limit... A......
D...... Hazardous waste, solid, n.o.s................................ 9 NA3077 III CLASS 9............... B54............. 155 213 240 No limit... No limit... A......
....... Helium, compressed........................................... 2.2 UN1046 NONFLAMMABLE GAS...... ................ 306 302 302, 314 75 kg...... 150 kg..... A...... 85
....... Helium-oxygen mixture, see Rare gases and oxygen mixtures.... ........... .............. ...................... ................ ........... ........... .......
....... Helium, refrigerated liquid (cryogenic liquid)............... 2.2 UN1963 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... B......
....... Heptafluoropropane........................................... 2.2 UN3296 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... n-Heptaldehyde............................................... 3 UN3056 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Heptanes..................................................... 3 UN1206 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B......
....... n-Heptene.................................................... 3 UN2278 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Hexachloroacetone............................................ 6.1 UN2661 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... B...... 12, 40
....... Hexachlorobenzene............................................ 6.1 UN2729 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... Hexachlorobutadiene.......................................... 6.1 UN2279 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Hexachlorocyclopentadiene.................................... 6.1 UN2646 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Hexachlorophene.............................................. 6.1 UN2875 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Hexadecyltrichlorosilane..................................... 8 UN1781 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8.
....... Hexadienes................................................... 3 UN2458 II FLAMMABLE LIQUID...... T7.............. None 202 242 5 L........ 60 L....... B......
....... Hexaethyl tetraphosphate and compressed gas mixtures......... 2.3 UN1612 POISON GAS............ 3............... None 334 None Forbidden.. Forbidden.. D...... 40
....... Hexaethyl tetraphosphate liquid.............................. 6.1 UN1611 I POISON................ A4.............. None 201 243 1 L........ 30 L....... E...... 40
............................................................. ........... .............. II POISON................ N76............. None 202 243 5 L........ 60 L....... E...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. None 203 241 60 L....... 220 L...... E...... 40
....... Hexaethyl tetraphosphate, solid.............................. 6.1 UN1611 I POISON................ ................ None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II POISON................ N76............. None 212 242 25 kg...... 100 kg..... E...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. 153 213 240 100 kg..... 200 kg..... E...... 40
....... Hexafluoroacetone............................................ 2.3 UN2420 POISON GAS, CORROSIVE. 2, B9, B14...... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Hexafluoroacetone hydrate.................................... 6.1 UN2552 II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
....... Hexafluoroethane, R116....................................... 2.2 UN2193 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexafluorophosphoric acid.................................... 8 UN1782 II CORROSIVE............. A6, A7, B2, N3, None 202 242 1 L........ 30 L....... A......
N34, T9, T27.
D...... Hexafluoropropylene oxide.................................... 2.2 NA1956 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexafluoropropylene, R1216................................... 2.2 UN1858 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexaldehyde.................................................. 3 UN1207 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Hexamethylene diisocyanate................................... 6.1 UN2281 II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 13, 40
....... Hexamethylene triperoxide diamine (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexamethylenediamine, solid.................................. 8 UN2280 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Hexamethylenediamine solution................................ 8 UN1783 II CORROSIVE............. T8.............. None 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Hexamethyleneimine........................................... 3 UN2493 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Hexamethylenetetramine....................................... 4.1 UN1328 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Hexamethylol benzene hexanitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanes...................................................... 3 UN1208 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene (dry)...... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitroazoxy benzene....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry).......... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrodiphenyl urea....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,2',3',4,4',6-Hexanitrodiphenylamine........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrodiphenylamine or Dipicrylamine or Hexyl............. 1.1D UN0079 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... 2,3',4,4',6,6'-Hexanitrodiphenylether........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitroethane.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrooxanilide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrostilbene............................................ 1.1D UN0392 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Hexanoic acid, see Corrosive liquids, n.o.s.................. ........... .............. ...................... ................ ........... ........... .......
....... Hexanols..................................................... 3 UN2282 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1-Hexene..................................................... 3 UN2370 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Hexogen and cyclotetramethylenetetranitramine mixtures, ........... .............. ...................... ................ ........... ........... .......
wetted or desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Hexogen and HMX mixtures, wetted or desensitized see RDX and ........... .............. ...................... ................ ........... ........... .......
HMX mixtures, wetted or desensitized etc..
....... Hexogen and octogen mixtures, wetted or desensitized see RDX ........... .............. ...................... ................ ........... ........... .......
and HMX mixtures, wetted or desensitized etc..
....... Hexogen, see Cyclotrimethylenetrinitramine, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Hexolite, or Hexotol dry or wetted with less than 15 percent 1.1D UN0118 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Hexotonal.................................................... 1.1D UN0393 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Hexyl, see Hexanitrodiphenylamine............................ ........... .............. ...................... ................ ........... ........... .......
....... Hexyltrichlorosilane......................................... 8 UN1784 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... High explosives, see individual explosives' entries.......... ........... .............. ...................... ................ ........... ........... .......
....... HMX, see Cyclotetramethylenetetranitramine, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydrazine, anhydrous or Hydrazine aqueous solutions with more 8 UN2029 I CORROSIVE, FLAMMABLE A3, A6, A7, A10, None 201 243 Forbidden.. 2.5 L...... D...... 21, 40, 42,
than 64 percent hydrazine, by mass. LIQUID, POISON. B16, B53, T25. 100
....... Hydrazine, aqueous solution with not more than 37 percent 6.1 UN3293 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
hydrazine, by mass.
....... Hydrazine azide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine chlorate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine dicarbonic acid diazide............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine hydrate or Hydrazine aqueous solutions, with not 8 UN2030 II CORROSIVE, POISON..... B16, B53, T15... None 202 243 Forbidden.. 30 L....... D...... 40, 42, 82
less than 37 percent but not more than 64 percent hydrazine,
by mass.
....... Hydrazine perchlorate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine selenate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydriodic acid, anhydrous, see Hydrogen iodide, anhydrous.... ........... .............. ...................... ................ ........... ........... .......
....... Hydriodic acid, solution..................................... 8 UN1787 II CORROSIVE............. A3, A6, B2, N41, 154 202 242 1 L........ 30 L....... C......
T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 8
....... Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous. ........... .............. ...................... ................ ........... ........... .......
....... Hydrobromic acid solution, with more than 49 percent 8 UN1788 II CORROSIVE............. B2, B15, N41, 154 202 242 Forbidden.. Forbidden.. C......
hydrobromic acid. T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 Forbidden.. Forbidden.. C...... 8
....... Hydrobromic acid solution, with not more than 49 percent 8 UN1788 II CORROSIVE............. A3, A6, B2, B15, 154 202 242 1 L........ 30 L....... C......
hydrobromic acid. N41, T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 30 L....... C...... 8
....... Hydrocarbon gases, compressed, n.o.s. or Hydrocarbon gases 2.1 UN1964 FLAMMABLE GAS......... ................ 306 302 314, 315 Forbidden.. 150 kg..... E...... 40
mixtures, compressed, n.o.s..
....... Hydrocarbon gases, liquefied, n.o.s. or Hydrocarbon gases 2.1 UN1965 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
mixtures, liquefied, n.o.s..
....... Hydrocarbons, liquid, n.o.s.................................. 3 UN3295 I FLAMMABLE LIQUID...... ................ 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Hydrochloric acid, anhydrous, see Hydrogen chloride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Hydrochloric acid, solution.................................. 8 UN1789 II CORROSIVE............. A3, A6, B3, B15, 154 202 242 1 L........ 30 L....... C......
N41, T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 8
....... Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc........ ........... .............. ...................... ................ ........... ........... .......
....... Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, 6.1 UN1613 I POISON................ 2, B12, B61, None 195 244 Forbidden.. Forbidden.. D...... 40
aqueous solutions with not more than 20 percent hydrocyanic B65, B77, B82.
acid.
D...... Hydrocyanic acid, aqueous solutions with less than 5 percent 6.1 NA1613 II POISON................ B12, T18, T26... None 195 243 Forbidden.. 5 L........ D...... 40
hydrocyanic acid.
....... Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc....... ........... .............. ...................... ................ ........... ........... .......
....... Hydrocyanic acid (prussic), unstabilized..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrofluoric acid and Sulfuric acid mixtures................. 8 UN1786 I CORROSIVE, POISON..... A6, A7, B15, None 201 243 Forbidden.. 2.5 L...... D...... 40, 95
B23, N5, N34,
T18, T27.
....... Hydrofluoric acid, anhydrous, see Hydrogen fluoride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Hydrofluoric acid, solution, with more than 60 percent 8 UN1790 I CORROSIVE, POISON..... A6, A7, B4, B12, None 201 243 0.5 L...... 2.5 L...... D...... 12, 40
strength. B15, B23, N5,
N34, T18, T27.
....... Hydrofluoric acid, solution, with more than 60 percent 8 UN1790 II CORROSIVE, POISON..... A6, A7, B12, None 202 243 1 L........ 30 L....... D...... 12, 40
strength. B15, N5, N34,
T18, T27.
....... Hydrofluoroboric acid, see Fluoboric acid.................... ........... .............. ...................... ................ ........... ........... .......
....... Hydrofluorosilicic acid, see Fluorosilicic acid.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen and Methane mixtures, compressed.................... 2.1 UN2034 FLAMMABLE GAS......... ................ 306 302 302, 314, Forbidden.. 150 kg..... E...... 40
315
....... Hydrogen bromide, anhydrous.................................. 2.3 UN1048 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Hydrogen chloride, anhydrous................................. 2.3 UN1050 POISON GAS, CORROSIVE. 3............... None 304 None Forbidden.. Forbidden.. D...... 40
....... Hydrogen chloride, refrigerated liquid....................... 2.3 UN2186 POISON GAS, CORROSIVE. 3, B6, B43...... None None 314, 315 Forbidden.. Forbidden.. B...... 40
....... Hydrogen, compressed......................................... 2.1 UN1049 FLAMMABLE GAS......... ................ 306 302 302, 314 Forbidden.. 150 kg..... E...... 40, 57
....... Hydrogen cyanide, anhydrous, stabilized with less than 3 6.1 UN1051 I POISON, FLAMMABLE 1, B12, B35, None 195 244 Forbidden.. Forbidden.. D...... 40
percent water. LIQUID. B61, B65, B77,
B82.
....... Hydrogen cyanide, solution in alcohol with not more than 45 6.1 UN3294 I POISON................ T18, T26........ None 201 243 Forbidden.. Forbidden.. D...... 40
percent hydrogen cyanide.
....... Hydrogen cyanide, stabilized, with less than 3 percent water 6.1 UN1614 I POISON................ 5............... None 195 None Forbidden.. Forbidden.. D...... 25, 40
and absorbed in a porous inert material.
....... Hydrogen fluoride, anhydrous................................. 8 UN1052 I CORROSIVE, POISON..... 3, B7, B12, B46, None 163 243 Forbidden.. Forbidden.. D...... 40
B71, B77, T24,
T27.
....... Hydrogen iodide, anhydrous................................... 2.3 UN2197 POISON GAS............ 3, 25, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Hydrogen iodide solution, see Hydriodic acid, solution....... ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen peroxide and peroxyacetic acid mixtures, stabilized 5.1 UN3149 II OXIDIZER, CORROSIVE... A2, A3, A6, B12, None 202 243 1 L........ 5 L........ D...... 25, 66, 75,
with acids, water and not more than 5 percent peroxyacetic B53, T14. 106
acid.
....... Hydrogen peroxide, aqueous solutions with more than 40 5.1 UN2014 II OXIDIZER, CORROSIVE... 12, A3, A6, B12, None 202 243 Forbidden.. Forbidden.. D...... 25, 66, 75,
percent but not more than 60 percent hydrogen peroxide B53, B80, B81, 106
(stabilized as necessary). B85, T14, T37.
....... Hydrogen peroxide, aqueous solutions with not less than 8 5.1 UN2984 III OXIDIZER.............. 17, A1, T8, T37. 152 203 241 2.5 L...... 30 L....... B...... 25, 75, 106
percent but less than 20 percent hydrogen peroxide
(stabilized as necessary).
....... Hydrogen peroxide, aqueous solutions with not less than 20 5.1 UN2014 II OXIDIZER, CORROSIVE... A2, A3, A6, B12, None 202 243 1 L........ 5 L........ D...... 25, 66, 75,
percent but not more than 40 percent hydrogen peroxide B53, T14, T37. 106
(stabilized as necessary).
....... Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous 5.1 UN2015 I OXIDIZER, CORROSIVE... 12, A3, A6, B12, None 201 243 Forbidden.. Forbidden.. D...... 25, 66, 75,
solutions, stabilized with more than 60 percent hydrogen B53, B80, B81, 106
peroxide. B85, T15, T37.
....... Hydrogen, refrigerated liquid (cryogenic liquid)............. 2.1 UN1966 FLAMMABLE GAS......... ................ None 316 318, 319 Forbidden.. Forbidden.. D...... 40
....... Hydrogen selenide, anhydrous................................. 2.3 UN2202 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Hydrogen sulfate, see Sulfuric acid.......................... ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen sulfide, liquefied.................................. 2.3 UN1053 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
GAS.
....... Hydrogendifluorides, n.o.s. solid............................ 8 UN1740 II CORROSIVE............. N3, N34......... None 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
............................................................. ........... .............. III CORROSIVE............. N3, N34......... 154 213 240 25 kg...... 100 kg..... A...... 25, 26, 40
....... Hydrogendifluorides, n.o.s. solutions........................ 8 UN1740 II CORROSIVE............. N3, N34......... None 202 242 1 L........ 30 L....... A...... 25, 26, 40
............................................................. ........... .............. III CORROSIVE............. N3, N34......... 154 203 241 5 L........ 60 L....... A...... 25, 26, 40
....... Hydroquinone................................................. 6.1 UN2662 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Hydrosilicofluoric acid, see Fluorosilicic acid.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydroxyl amine iodide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydroxylamine sulfate........................................ 8 UN2865 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Hypochlorite solutions with more than 5 percent but less than 8 UN1791 III CORROSIVE............. N34, T7......... 154 203 241 5 L........ 60 L....... B...... 26
16 percent available chlorine.
....... Hypochlorite solutions with 16 percent or more available 8 UN1791 II CORROSIVE............. A7, B2, B15, 154 202 242 1 L........ 30 L....... B...... 26
chlorine. N34, T7.
....... Hypochlorites, inorganic, n.o.s.............................. 5.1 UN3212 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... D...... 48, 56, 58,
69, 106,
116, 118
....... Hyponitrous acid............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Igniter fuse, metal clad, see Fuse, igniter, tubular, metal ........... .............. ...................... ................ ........... ........... .......
clad.
....... Igniters..................................................... 1.1G UN0121 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Igniters..................................................... 1.2G UN0314 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Igniters..................................................... 1.3G UN0315 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Igniters..................................................... 1.4G UN0325 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Igniters..................................................... 1.4S UN0454 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... 3,3'-Iminodipropylamine...................................... 8 UN2269 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Infectious substances, affecting animals only................ 6.2 UN2900 INFECTIOUS SUBSTANCE.. ................ 196 196 None 50 mL or 50 4 L or 4 kg B......
g.
....... Infectious substances, affecting humans...................... 6.2 UN2814 INFECTIOUS SUBSTANCE.. ................ 196 196 None 50 mL or 50 4 L or 4 kg B......
g.
....... Inflammable, see Flammable................................... ........... .............. ...................... ................ ........... ........... .......
....... Initiating explosives (dry).................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Inositol hexanitrate (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Insecticide gases flammable n.o.s............................ 2.1 UN1968 FLAMMABLE GAS......... ................ 306 304 314, 315 75 kg...... 150 kg..... D......
....... Insecticide gases, n.o.s..................................... 2.2 UN1968 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Insecticide gases, toxic, n.o.s.............................. 2.3 UN1967 POISON GAS............ 3............... None 193, 334 245 Forbidden.. Forbidden.. D...... 40
....... Inulin trinitrate (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iodine azide (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iodine monochloride.......................................... 8 UN1792 II CORROSIVE............. B6, N41, T8, T26 None 212 240 Forbidden.. 50 kg...... D...... 40, 66, 74,
89, 90
....... Iodine pentafluoride......................................... 5.1 UN2495 I OXIDIZER, POISON, ................ None 205 243 Forbidden.. 2.5 L...... D...... 25, 40, 66,
CORROSIVE. 90
....... 2-Iodobutane................................................. 3 UN2390 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Iodomethylpropanes........................................... 3 UN2391 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Iodopropanes................................................. 3 UN2392 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Iodoxy compounds (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iridium nitratopentamine iridium nitrate..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iron chloride, see Ferric chloride........................... ........... .............. ...................... ................ ........... ........... .......
....... Iron oxide, spent, or Iron sponge, spent obtained from coal 4.2 UN1376 III SPONTANEOUSLY B18............. None 213 240 Forbidden.. Forbidden.. E......
gas purification. COMBUSTIBLE.
....... Iron pentacarbonyl........................................... 6.1 UN1994 I POISON, FLAMMABLE 1, B9, B14, B30, None 192 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, B77, T38,
T43, T44.
....... Iron sesquichloride, see Ferric chloride..................... ........... .............. ...................... ................ ........... ........... .......
....... Irritating material, see Tear gas substances, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Isobutane or Isobutane mixtures see also Petroleum gases, 2.1 UN1969 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
liquefied.
....... Isobutanol or Isobutyl alcohol............................... 3 UN1212 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl acetate............................................. 3 UN1213 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isobutyl acrylate............................................ 3 UN2527 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl alcohol, see Isobutanol............................. ........... .............. ...................... ................ ........... ........... .......
....... Isobutyl aldehyde, see Isobutyraldehyde...................... ........... .............. ...................... ................ ........... ........... .......
D...... Isobutyl chloroformate....................................... 6.1 NA2742 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 22,
LIQUID, CORROSIVE. B74, T38, T43, 25, 40,
T45. 48, 100
....... Isobutyl formate............................................. 3 UN2393 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isobutyl isobutyrate......................................... 3 UN2528 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Isobutyl isocyanate.......................................... 3 UN2486 II FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 1 L........ 60 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Isobutyl methacrylate........................................ 3 UN2283 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl propionate.......................................... 3 UN2394 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... B......
....... Isobutylamine................................................ 3 UN1214 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Isobutylene see also Petroleum gases, liquefied.............. 2.1 UN1055 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Isobutyraldehyde or Isobutyl aldehyde........................ 3 UN2045 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 40
....... Isobutyric acid.............................................. 3 UN2529 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Isobutyric anhydride......................................... 3 UN2530 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Isobutyronitrile............................................. 3 UN2284 II FLAMMABLE LIQUID, T17............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Isobutyryl chloride.......................................... 3 UN2395 II FLAMMABLE LIQUID, T9, T26......... None 202 243 1 L........ 5 L........ C...... 40
CORROSIVE.
....... Isocyanates, flammable, toxic, n.o.s. or Isocyanate 3 UN2478 II FLAMMABLE LIQUID, 5, A3, A7, T15.. None 202 243 1 L........ 60 L....... D...... 40
solutions, flammable, toxic, n.o.s. flashpoint less than 23 POISON.
degrees C.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Isocyanates, toxic, flammable, n.o.s. or Isocyanate 6.1 UN3080 II POISON, FLAMMABLE T15............. None 202 243 5 L........ 60 L....... D...... 25, 40, 48
solutions, toxic, flammable, n.o.s., flash point not less LIQUID.
than 23 degrees C but not more than 61 degrees C and boiling
point less than 300 degrees C.
....... Isocyanates, toxic, n.o.s. or Isocyanate, toxic, solutions, 6.1 UN2206 II POISON................ T15............. None 202 243 5 L........ 60 L....... D...... 25, 40, 48
n.o.s., flash point more than 61 degrees C and boiling point
less than 300 degrees C.
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... D...... 25, 40, 48
....... Isocyanatobenzotrifluorides.................................. 6.1 UN2285 II POISON................ 5, T14.......... None 202 243 5 L........ 60 L....... B...... 25, 40, 48
....... Isoheptenes.................................................. 3 UN2287 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Isohexenes................................................... 3 UN2288 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Isooctane, see Octanes....................................... ........... .............. ...................... ................ ........... ........... .......
....... Isooctenes................................................... 3 UN1216 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Isopentane, see n-Pentane.................................... ........... .............. ...................... ................ ........... ........... .......
....... Isopentanoic acid, see Corrosive liquids, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Isopentenes.................................................. 3 UN2371 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Isophorone diisocyanate...................................... 6.1 UN2290 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... B...... 40
....... Isophoronediamine............................................ 8 UN2289 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Isoprene, inhibited.......................................... 3 UN1218 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Isopropanol or Isopropyl alcohol............................. 3 UN1219 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropenyl acetate.......................................... 3 UN2403 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropenylbenzene........................................... 3 UN2303 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl acetate............................................ 3 UN1220 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropyl acid phosphate..................................... 8 UN1793 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
....... Isopropyl alcohol, see Isopropanol........................... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl butyrate........................................... 3 UN2405 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl chloroacetate...................................... 3 UN2947 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl chloroformate...................................... 6.1 UN2407 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
LIQUID, CORROSIVE. B74, B77, T38,
T43, T45.
....... Isopropyl-2-chloropropionate................................. 3 UN2934 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl isobutyrate........................................ 3 UN2406 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
+...... Isopropyl isocyanate......................................... 3 UN2483 I FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Isopropyl mercaptan, see Propanethiols....................... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl nitrate............................................ 3 UN1222 II FLAMMABLE LIQUID...... T25............. 150 202 None 5 L........ 60 L....... D......
....... Isopropyl phosphoric acid, see Isopropyl acid phosphate...... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl propionate......................................... 3 UN2409 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropylamine............................................... 3 UN1221 I FLAMMABLE LIQUID, T20............. None 201 243 0.5 L...... 2.5 L...... E......
CORROSIVE.
....... Isopropylbenzene............................................. 3 UN1918 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropylcumyl hydroperoxide, with more than 72 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Isosorbide dinitrate mixture with not less than 60 percent 4.1 UN2907 II FLAMMABLE SOLID....... ................ None 212 None 15 kg...... 50 kg...... E......
lactose, mannose, starch or calcium hydrogen phosphate.
....... Isosorbide-5-mononitrate..................................... 4.1 UN3251 III FLAMMABLE SOLID....... ................ 151 213 240 Forbidden.. Forbidden.. D...... 12
....... Isothiocyanic acid........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Jet fuel, see Fuel aviation, turbine engine.................. ........... .............. ...................... ................ ........... ........... .......
D...... Jet perforating guns, charged oil well, without detonator.... 1.4D NA0124 II EXPLOSIVE 1.4D........ 114............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Jet perforating guns, charged oil well, without detonator.... 1.1D UN0124 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Jet perforating guns, charged, oil well, without detonator... 1.4D UN0494 EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 300 kg..... A...... 24E
....... Jet perforators, see Charges, shaped, commercial etc......... ........... .............. ...................... ................ ........... ........... .......
....... Jet tappers, without detonator, see Charges, shaped ........... .............. ...................... ................ ........... ........... .......
commercial, etc..
....... Jet thrust igniters, for rocket motors or Jato, see Igniters. ........... .............. ...................... ................ ........... ........... .......
....... Jet thrust unit (Jato), see Rocket motors.................... ........... .............. ...................... ................ ........... ........... .......
....... Kerosene..................................................... 3 UN1223 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ketones, liquid, n.o.s....................................... 3 UN1224 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Krypton, compressed.......................................... 2.2 UN1056 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Krypton, refrigerated liquid (cryogenic liquid).............. 2.2 UN1970 NONFLAMMABLE GAS...... ................ 320 None None 50 kg...... 500 kg..... B......
....... Lacquer base or lacquer chips, nitrocellulose, dry, see ........... .............. ...................... ................ ........... ........... .......
Nitrocellulose, etc. (UN 2557).
....... Lacquer base or lacquer chips, plastic, wet with alcohol or ........... .............. ...................... ................ ........... ........... .......
solvent, see Nitrocellulose (UN 2059, UN 2060, UN 2555,
UN2556) or Paint etc. (UN1263).
....... Lead acetate................................................. 6.1 UN1616 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Lead arsenates............................................... 6.1 UN1617 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Lead arsenites............................................... 6.1 UN1618 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Lead azide (dry)............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Lead azide, wetted with not less than 20 percent water or 1.1A UN0129 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
mixture of alcohol and water, by mass.
....... Lead compounds, soluble, n.o.s............................... 6.1 UN2291 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Lead cyanide................................................. 6.1 UN1620 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Lead dioxide................................................. 5.1 UN1872 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 34
....... Lead dross, see Lead sulphate, with more than 3 percent free ........... .............. ...................... ................ ........... ........... .......
acid.
D...... Lead mononitroresorcinate.................................... 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Lead nitrate................................................. 5.1 UN1469 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Lead nitroresorcinate (dry).................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Lead perchlorate, solid...................................... 5.1 UN1470 II OXIDIZER, POISON...... T8.............. None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Lead perchlorate, solution................................... 5.1 UN1470 II OXIDIZER, POISON...... T8.............. None 202 243 1 L........ 5 L........ A...... 56, 58, 106
....... Lead peroxide, see Lead dioxide.............................. ........... .............. ...................... ................ ........... ........... .......
....... Lead phosphite, dibasic...................................... 4.1 UN2989 II FLAMMABLE SOLID....... ................ None 212 240 5 kg....... 25 kg...... B...... 34
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 15 kg...... 50 kg...... B...... 34
....... Lead picrate (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Lead styphnate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Lead styphnate, wetted or Lead trinitroresorcinate, wetted 1.1A UN0130 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
with not less than 20 percent water or mixture of alcohol
and water, by mass.
....... Lead sulfate with more than 3 percent free acid.............. 8 UN1794 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Lead trinitroresorcinate, see Lead styphnate, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Life-saving appliances, not self inflating containing 9 UN3072 None.................. ................ None 219 None No limit... No limit... A......
dangerous goods as equipment.
....... Life-saving appliances, self inflating....................... 9 UN2990 None.................. ................ None 219 None No limit... No limit... A......
....... Lighter replacement cartridges containing liquefied petroleum ........... .............. ...................... ................ ........... ........... .......
gases (and similar devices, each not exceeding 65 grams),
see Lighters for cigars, cigarettes, etc. with flammable gas.
D...... Lighters for cigars, cigarettes, etc., with lighter fluids... 3 NA1226 II FLAMMABLE LIQUID...... N10............. None 21 None Forbidden.. Forbidden.. B......
....... Lighters, fuse............................................... 1.4S UN0131 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Lighters or Lighter refills cigarettes containing flammable 2.1 UN1057 FLAMMABLE GAS......... N10............. None 21, 308 None 1 kg....... 15 kg...... B...... 40
gas.
....... Lime, unslaked, see Calcium oxide............................ ........... .............. ...................... ................ ........... ........... .......
....... Liquefied gas, flammable, n.o.s.............................. 2.1 UN3161 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Liquefied gas, n.o.s......................................... 2.2 UN3163 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Liquefied gas, oxidizing, n.o.s.............................. 2.2 UN3157 NONFLAMMABLE GAS, ................ 306 304 314, 315 75 kg...... 150 kg..... D......
OXIDIZER.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
Zone A. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone B. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone C. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 4............... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone D. GAS.
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A........ 2.3 UN3162 POISON GAS............ 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B........ 2.3 UN3162 POISON GAS............ 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C........ 2.3 UN3162 POISON GAS............ 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D........ 2.3 UN3162 POISON GAS............ 4............... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gases, non-flammable charged with nitrogen, carbon 2.2 UN1058 NONFLAMMABLE GAS...... ................ 306 304 None 75 kg...... 150 kg..... A......
dioxide or air.
....... Liquefied hydrocarbon gas, see Hydrocarbon gases, liquefied, ........... .............. ...................... ................ ........... ........... .......
n.o.s., etc..
....... Liquefied natural gas, see Methane, etc. (UN 1972)........... ........... .............. ...................... ................ ........... ........... .......
....... Liquefied petroleum gas see Petroleum gases, liquefied....... ........... .............. ...................... ................ ........... ........... .......
....... Lithium...................................................... 4.3 UN1415 I DANGEROUS WHEN WET.... A7, A19, N45.... None 211 244 Forbidden.. 15 kg...... E......
....... Lithium acetylide ethylenediamine complex, see Substances ........... .............. ...................... ................ ........... ........... .......
which in contact with water emit flammable gases.
....... Lithium alkyls............................................... 4.2 UN2445 I SPONTANEOUSLY B11, T28, T40... None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Lithium aluminum hydride..................................... 4.3 UN1410 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium aluminum hydride, ethereal........................... 4.3 UN1411 I DANGEROUS WHEN WET, A2, A3, A11, N34 None 201 244 Forbidden.. 1 L........ D...... 40
FLAMMABLE LIQUID.
....... Lithium batteries, contained in equipment.................... 9 UN3091 II CLASS 9............... 18, 29, A12..... 185(i) 185 None Forbidden.. See A12.... A......
....... Lithium battery, liquid cathode.............................. 9 UN3090 II CLASS 9............... 29.............. 185(i) 185 None Forbidden.. 35 kg gross A......
....... Lithium battery, solid cathode............................... 9 UN3090 II CLASS 9............... 29.............. 185(i) 185 None Forbidden.. 35 kg gross A......
....... Lithium borohydride.......................................... 4.3 UN1413 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium ferrosilicon......................................... 4.3 UN2830 II DANGEROUS WHEN WET.... A19............. None 212 241 15 kg...... 50 kg...... E...... 40, 85, 103
....... Lithium hydride.............................................. 4.3 UN1414 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium hydride, fused solid................................. 4.3 UN2805 II DANGEROUS WHEN WET.... A8, A19, A20.... None 212 241 15 kg...... 50 kg...... E......
....... Lithium hydroxide, monohydrate or Lithium hydroxide, solid... 8 UN2680 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Lithium hydroxide, solution.................................. 8 UN2679 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 96
....... Lithium hypochlorite, dry or Lithium hypochlorite mixtures, 5.1 UN1471 II OXIDIZER.............. A9, N34......... 152 212 240 5 kg....... 25 kg...... A...... 48, 56, 58,
dry. 69, 106,
116
....... Lithium in cartridges, see Lithium........................... ........... .............. ...................... ................ ........... ........... .......
....... Lithium nitrate.............................................. 5.1 UN2722 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Lithium nitride.............................................. 4.3 UN2806 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium peroxide............................................. 5.1 UN1472 II OXIDIZER.............. A9, N34......... 152 212 None 5 kg....... 25 kg...... A...... 13, 75, 106
....... Lithium silicon.............................................. 4.3 UN1417 II DANGEROUS WHEN WET.... A19, A20........ None 212 241 15 kg...... 50 kg...... A...... 85, 103
....... LNG, see Methane etc. (UN 1972).............................. ........... .............. ...................... ................ ........... ........... .......
....... London purple................................................ 6.1 UN1621 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... LPG, see Petroleum gases, liquefied.......................... ........... .............. ...................... ................ ........... ........... .......
....... Lye, see Sodium hydroxide, solutions......................... ........... .............. ...................... ................ ........... ........... .......
....... Magnesium alkyls............................................. 4.2 UN3053 I SPONTANEOUSLY B11, T28, T29, None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. T40.
....... Magnesium aluminum phosphide................................. 4.3 UN1419 I DANGEROUS WHEN WET, A19, N34, N40... None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON.
+...... Magnesium arsenate........................................... 6.1 UN1622 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Magnesium bisulfite solution, see Bisulfites, inorganic ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Magnesium bromate............................................ 5.1 UN1473 II OXIDIZER.............. A1.............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium chlorate........................................... 5.1 UN2723 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium diamide............................................ 4.2 UN2004 II SPONTANEOUSLY A8, A19, A20.... None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
....... Magnesium diphenyl........................................... 4.2 UN2005 I SPONTANEOUSLY ................ None 187 244 Forbidden.. Forbidden.. C......
COMBUSTIBLE.
....... Magnesium dross, wet or hot.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Magnesium fluorosilicate..................................... 6.1 UN2853 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Magnesium granules, coated particle size not less than 149 4.3 UN2950 III DANGEROUS WHEN WET.... A1, A19......... None 213 240 25 kg...... 100 kg..... A......
microns.
....... Magnesium hydride............................................ 4.3 UN2010 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Magnesium or Magnesium alloys with more than 50 percent 4.1 UN1869 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A...... 39
magnesium in pellets, turnings or ribbons.
....... Magnesium nitrate............................................ 5.1 UN1474 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Magnesium perchlorate........................................ 5.1 UN1475 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium peroxide........................................... 5.1 UN1476 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Magnesium phosphide.......................................... 4.3 UN2011 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Magnesium, powder or Magnesium alloys, powder................ 4.3 UN1418 I DANGEROUS WHEN WET, A19, B56........ None 211 244 Forbidden.. 15 kg...... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, A19, B56........ None 212 241 15 kg...... 50 kg...... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, A19, B56........ None 213 241 25 kg...... 100 kg..... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
....... Magnesium scrap, see Magnesium, etc. (UN 1869)............... ........... .............. ...................... ................ ........... ........... .......
....... Magnesium silicide........................................... 4.3 UN2624 II DANGEROUS WHEN WET.... A19, A20........ None 212 241 15 kg...... 50 kg...... B...... 85, 103
....... Magnetized material, see section 173.21...................... ........... .............. ...................... ................ ........... ........... .......
D...... Maleic acid.................................................. 8 NA2215 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Maleic anhydride............................................. 8 UN2215 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
....... Malononitrile................................................ 6.1 UN2647 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12
....... Maneb or Maneb preparations with not less than 60 percent 4.2 UN2210 III SPONTANEOUSLY A1, A19......... None 213 242 25 kg...... 100 kg..... A...... 34
maneb. COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Maneb stabilized or Maneb preparations, stabilized against 4.3 UN2968 III DANGEROUS WHEN WET.... A1, A19......... None 213 242 25 kg...... 100 kg..... B...... 34
self-heating.
....... Manganese nitrate............................................ 5.1 UN2724 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Manganese resinate........................................... 4.1 UN1330 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Mannitan tetranitrate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Mannitol hexanitrate (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Mannitol hexanitrate, wetted or Nitromannite, wetted with not 1.1A NA0133 II EXPLOSIVE 1.1A........ 111............. None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
less than 40 percent water, by mass or mixture of alcohol
and water.
....... Marine pollutants, liquid or solid, n.o.s., see ........... .............. ...................... ................ ........... ........... .......
Environmentally hazardous substances, liquid or solid,
n.o.s..
....... Matches, block, see Matches, 'strike anywhere'............... ........... .............. ...................... ................ ........... ........... .......
....... Matches, fusee............................................... 4.1 UN2254 III FLAMMABLE SOLID....... ................ 186 186 None Forbidden.. Forbidden.. A......
....... Matches, safety (book, card or strike on box)................ 4.1 UN1944 III FLAMMABLE SOLID....... ................ 186 186 None 25 kg...... 100 kg..... A......
....... Matches, strike anywhere..................................... 4.1 UN1331 III FLAMMABLE SOLID....... ................ 186 186 None Forbidden.. Forbidden.. B......
....... Matches, wax, Vesta.......................................... 4.1 UN1945 III FLAMMABLE SOLID....... ................ 186 186 None 25 kg...... 100 kg..... B......
....... Matting acid, see Sulfuric acid.............................. ........... .............. ...................... ................ ........... ........... .......
....... Medicine, liquid, flammable, toxic, n.o.s.................... 3 UN3248 II FLAMMABLE LIQUID, 36.............. None 202 None 1 L........ 5 L........ B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP 36.............. 150 203 None 5 L........ 5 L........ A......
AWAY FROM FOOD.
....... Medicine, liquid, toxic, n.o.s............................... 6.1 UN1851 II POISON................ ................ None 202 243 5 L........ 5 L........ C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 5 L........ 5 L........ C...... 40
....... Medicine, solid, toxic, n.o.s................................ 6.1 UN3249 II POISON................ 36.............. None 212 None 5 kg....... 5 kg...... C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... 36.............. 153 213 None 5 kg....... 5 kg....... C...... 40
D...... Medicines, corrosive, liquid, n.o.s.......................... 8 NA1760 II CORROSIVE............. B3.............. 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A...... 40
D...... Medicines, corrosive, solid, n.o.s........................... 8 NA1759 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
D...... Medicines, flammable, liquid, n.o.s.......................... 3 NA1993 I FLAMMABLE LIQUID...... ................ 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... A......
D...... Medicines, flammable, solid, n.o.s........................... 4.1 NA1325 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... B......
D...... Medicines, oxidizing substance, solid, n.o.s................. 5.1 NA1479 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... B...... 56, 58, 69,
106
....... Memtetrahydrophthalic anhydride, see Corrosive liquids, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan 3 UN1228 II FLAMMABLE LIQUID, T13............. None 202 243 Forbidden.. 60 L....... B...... 40, 95
mixtures, liquid, flammable, toxic, n.o.s.. POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 5 L........ 220 L...... A...... 40, 95
AWAY FROM FOOD.
....... Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan 6.1 UN3071 II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... C...... 40, 121
mixtures, liquid, toxic, flammable, n.o.s., flash point not LIQUID.
less than 23 degrees C.
....... 5-Mercaptotetrazol-1-acetic acid............................. 1.4C UN0448 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Mercuric arsenate............................................ 6.1 UN1623 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercuric chloride............................................ 6.1 UN1624 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercuric compounds, see Mercury compounds, etc............... ........... .............. ...................... ................ ........... ........... .......
....... Mercuric nitrate............................................. 6.1 UN1625 II POISON................ N73............. None 212 242 25 kg...... 100 kg..... A......
+...... Mercuric potassium cyanide................................... 6.1 UN1626 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 26
....... Mercuric sulfocyanate, see Mercury thiocyanate............... ........... .............. ...................... ................ ........... ........... .......
....... Mercurol, see Mercury nucleate............................... ........... .............. ...................... ................ ........... ........... .......
....... Mercurous azide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Mercurous compounds, see Mercury compounds, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Mercurous nitrate............................................ 6.1 UN1627 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
A, W... Mercury...................................................... 8 UN2809 III CORROSIVE............. ................ 164 164 240 35 kg...... 35 kg...... B...... 40, 97
....... Mercury acetate.............................................. 6.1 UN1629 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury acetylide............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury ammonium chloride.................................... 6.1 UN1630 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury based pesticides, liquid, flammable, toxic, flash 3 UN2778 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Mercury based pesticides, liquid, toxic...................... 6.1 UN3012 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Mercury based pesticides, liquid, toxic, flammable, 6.1 UN3011 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Mercury based pesticides, solid, toxic....................... 6.1 UN2777 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Mercury benzoate............................................. 6.1 UN1631 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury bromides............................................. 6.1 UN1634 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury compounds, liquid, n.o.s............................. 6.1 UN2024 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... B...... 40
....... Mercury compounds, solid, n.o.s.............................. 6.1 UN2025 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
A...... Mercury contained in manufactured articles................... 8 UN2809 I CORROSIVE............. ................ None 164 None No limit... No limit... B...... 40, 97
....... Mercury cyanide.............................................. 6.1 UN1636 II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 26
....... Mercury fulminate, wetted with not less than 20 percent 1.1A UN0135 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
water, or mixture of alcohol and water, by mass.
....... Mercury gluconate............................................ 6.1 UN1637 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury iodide............................................... 6.1 UN1638 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury iodide aquabasic ammonobasic (Iodide of Millon's Forbidden .............. ...................... ................ ........... ........... .......
base).
....... Mercury iodide, solution..................................... 6.1 UN1638 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Mercury nitride.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury nucleate............................................. 6.1 UN1639 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oleate............................................... 6.1 UN1640 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oxide................................................ 6.1 UN1641 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oxycyanide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury oxycyanide, desensitized............................. 6.1 UN1642 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26, 91
....... Mercury potassium iodide..................................... 6.1 UN1643 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury salicylate........................................... 6.1 UN1644 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
+...... Mercury sulfates............................................. 6.1 UN1645 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury thiocyanate.......................................... 6.1 UN1646 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mesityl oxide................................................ 3 UN1229 III FLAMMABLE LIQUID...... B1, T1.......... None 203 242 60 L....... 220 L...... A......
....... Metal alkyl halides, n.o.s. or Metal aryl halides, n.o.s..... 4.2 UN3049 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Metal alkyl hydrides, n.o.s. or Metal aryl hydrides, n.o.s... 4.2 UN3050 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
D...... Metal alkyl, solution, n.o.s................................. 3 NA9195 II FLAMMABLE LIQUID...... ................ 150 202 242 1 L........ 4 L........ B......
....... Metal alkyls, n.o.s. or Metal aryls, n.o.s................... 4.2 UN2003 I SPONTANEOUSLY B11, T42........ None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Metal carbonyls, n.o.s....................................... 6.1 UN3281 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Metal catalyst, dry.......................................... 4.2 UN2881 I SPONTANEOUSLY N34............. None 187 None Forbidden.. Forbidden.. C......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY N34............. None 187 None Forbidden.. 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY N34............. None 187 None 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Metal catalyst, wetted with a visible excess of liquid....... 4.2 UN1378 II SPONTANEOUSLY A2, A8, N34..... None 212 None Forbidden.. 50 kg...... C......
COMBUSTIBLE.
....... Metal hydrides, flammable, n.o.s............................. 4.1 UN3182 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... E......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... E......
....... Metal hydrides, water reactive, n.o.s........................ 4.3 UN1409 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
............................................................. ........... .............. II DANGEROUS WHEN WET.... A19, N34, N40... None 212 242 15 kg...... 50 kg...... D......
....... Metal powder, self-heating, n.o.s............................ 4.2 UN3189 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... C.....
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Metal powders, flammable, n.o.s.............................. 4.1 UN3089 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... B......
....... Metal salts of methyl nitramine (dry)........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Metal salts of organic compounds, flammable, n.o.s........... 4.1 UN3181 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B...... 40
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B...... 40
....... Metaldehyde.................................................. 4.1 UN1332 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Metallic substance, water-reactive, n.o.s.................... 4.3 UN3208 I DANGEROUS WHEN WET.... ................ None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... ................ None 212 242 15 kg...... 50 kg...... E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 213 241 25 kg...... 100 kg..... E...... 40
....... Metallic substance, water-reactive, self-heating, n.o.s...... 4.3 UN3209 I DANGEROUS WHEN WET, ................ None 211 242 Forbidden.. 15 kg...... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 242 25 kg...... 100 kg..... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
....... Methacrylaldehyde............................................ 3 UN2396 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Methacrylic acid, inhibited.................................. 8 UN2531 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
+..... Methacrylonitrile, inhibited................................. 3 UN3079 I FLAMMABLE LIQUID, 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... D...... 12, 40, 48
POISON. B74, T38, T43,
T45.
....... Methallyl alcohol............................................ 3 UN2614 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methane and hydrogen, mixtures, see Hydrogen and methane, ........... .............. ...................... ................ ........... ........... .......
mixtures, etc..
....... Methane, compressed or Natural gas, compressed (with high 2.1 UN1971 FLAMMABLE GAS......... ................ 306 302 302 Forbidden.. 150 kg..... E...... 40
methane content).
....... Methane, refrigerated liquid (cryogenic liquid) or Natural 2.1 UN1972 FLAMMABLE GAS......... ................ None None 318 Forbidden.. Forbidden.. D...... 40
gas, refrigerated liquid (cryogenic liquid, with high
methane content).
....... Methanesulphonyl chloride.................................... 6.1 UN3246 I POISON, CORROSIVE..... T24, T26........ None 201 243 0.5 L...... 2.5 L...... D...... 40
I...... Methanol, or Methyl alcohol.................................. 3 UN1230 II FLAMMABLE LIQUID, T8.............. 150 202 242 1 L........ 60 L....... B...... 40
POISON.
D...... Methanol, or Methyl alcohol.................................. 3 UN1230 II FLAMMABLE LIQUID...... T8.............. 150 202 242 1 L........ 60 L....... B...... 40
....... Methazoic acid............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 4-Methoxy-4-methylpentan-2-one............................... 3 UN2293 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1-Methoxy-2-propanol......................................... 3 UN3092 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Methoxymethyl isocyanate..................................... 3 UN2605 I FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Methyl acetate............................................... 3 UN1231 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl acetylene and propadiene mixtures, stabilized......... 2.1 UN1060 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Methyl acrylate, inhibited................................... 3 UN1919 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl alcohol, see Methanol................................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl allyl chloride........................................ 3 UN2554 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Methyl amyl ketone, see Amyl methyl ketone................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl benzoate.............................................. 6.1 UN2938 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl bromide............................................... 2.3 UN1062 POISON GAS............ 3, B14.......... None 193 314, 315 Forbidden.. 25 kg...... D...... 40
....... Methyl bromide and chloropicrin mixtures with more than 2 ........... .............. ...................... ................ ........... ........... .......
percent chloropicrin, see Chloropicrin and methyl bromide
mixtures.
....... Methyl bromide and chloropicrin mixtures with not more than 2 ........... .............. ...................... ................ ........... ........... .......
percent chloropicrin, see Methyl bromide.
....... Methyl bromide and ethylene dibromide mixtures, liquid....... 6.1 UN1647 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... C...... 40
B74, N65, T38,
T43, T45.
....... Methyl bromoacetate.......................................... 6.1 UN2643 II POISON................ T8.............. None 202 243 5 L........ 60 L....... D...... 40
....... 2-Methyl-1-butene............................................ 3 UN2459 I FLAMMABLE LIQUID...... T14............. None 201 243 1 L........ 30 L....... E......
....... 2-Methyl-2-butene............................................ 3 UN2460 II FLAMMABLE LIQUID...... T14............. None 202 242 5 L........ 60 L....... E......
....... 3-Methyl-1-butene............................................ 3 UN2561 I FLAMMABLE LIQUID...... T20............. None 201 243 1 L........ 30 L....... E......
....... Methyl tert-butyl ether...................................... 3 UN2398 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E......
....... Methyl butyrate.............................................. 3 UN1237 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl chloride.............................................. 2.1 UN1063 FLAMMABLE GAS......... ................ 306 304 314, 315 5 kg....... 100 kg..... D...... 40
....... Methyl chloride and chloropicrin mixtures, see Chloropicrin ........... .............. ...................... ................ ........... ........... .......
and methyl chloride mixtures.
....... Methyl chloride and methylene chloride mixtures.............. 2.1 UN1912 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Methyl chloroacetate......................................... 6.1 UN2295 II POISON................ T11............. None 202 243 5 L........ 60 L....... C......
....... Methyl chlorocarbonate, see Methyl chloroformate............. ........... .............. ...................... ................ ........... ........... .......
....... Methyl chloroform, see 1,1,1-Trichloroethane................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl chloroformate......................................... 6.1 UN1238 I POISON, FLAMMABLE 1, A3, A6, A7, None 226 244 Forbidden.. Forbidden.. D...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B30,
B72, N34, T38,
T43, T44.
....... Methyl-2-chloropropionate.................................... 3 UN2933 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Methyl cyclohexane........................................... 3 UN2296 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Methyl cyclohexanone......................................... 3 UN2297 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methyl cyclopentane.......................................... 3 UN2298 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl dichloroacetate....................................... 6.1 UN2299 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl ethyl ether, see Ethyl methyl ether................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl ethyl ketone, see Ethyl methyl ketone................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl ethyl ketone peroxide, in solution with more than 9 Forbidden .............. ...................... ................ ........... ........... .......
percent by mass active oxygen.
....... 2-Methyl-5-ethylpyridine..................................... 6.1 UN2300 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl fluoride.............................................. 2.1 UN2454 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Methyl formate............................................... 3 UN1243 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Methyl iodide................................................ 6.1 UN2644 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 12, 40
B74, T38, T43,
T45.
....... Methyl isobutyl carbinol..................................... 3 UN2053 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methyl isobutyl ketone....................................... 3 UN1245 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl isobutyl ketone peroxide, in solution with more than 9 Forbidden .............. ...................... ................ ........... ........... .......
percent by mass active oxygen.
....... Methyl isocyanate............................................ 6.1 UN2480 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 26, 40
LIQUID. B30, B72, T38,
T43, T44.
....... Methyl isopropenyl ketone, inhibited......................... 3 UN1246 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
+...... Methyl isothiocyanate........................................ 3 UN2477 II FLAMMABLE LIQUID, 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... A......
POISON. B74, T38, T43,
T45.
....... Methyl isovalerate........................................... 3 UN2400 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl magnesium bromide, in ethyl ether..................... 4.3 UN1928 I DANGEROUS WHEN WET, ................ None 201 243 Forbidden.. 1 L........ D......
FLAMMABLE LIQUID.
....... Methyl mercaptan............................................. 2.3 UN1064 POISON GAS, FLAMMABLE 3, 25, B7, B9, None 304 314, 315 Forbidden.. 25 kg...... D...... 40
GAS. B14.
....... Methyl mercaptopropionaldehyde, see Thia-4-pentanal.......... ........... .............. ...................... ................ ........... ........... .......
....... Methyl methacrylate monomer, inhibited....................... 3 UN1247 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Methyl nitramine (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl nitrate............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl nitrite............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl norbornene dicarboxylic anhydride, see Corrosive ........... .............. ...................... ................ ........... ........... .......
liquids, n.o.s..
....... Methyl orthosilicate......................................... 6.1 UN2606 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... E...... 40
LIQUID. B74, T38, T43,
T45.
D...... Methyl parathion liquid...................................... 6.1 NA3018 II POISON................ N76, T14........ None 202 243 Forbidden.. 1 L........ A...... 40
D...... Methyl parathion solid....................................... 6.1 NA2783 II POISON................ N77............. None 212 242 25 kg...... 100 kg..... A...... 40
D...... Methyl phosphonic dichloride................................. 6.1 NA9206 I POISON, CORROSIVE..... 2, A3, B9, B14, None 227 244 Forbidden.. Forbidden.. C......
B32, B74, N34,
N43, T38, T43,
T45.
....... Methyl phosphonothioic dichloride, anhydrous, see Corrosive ........... .............. ...................... ................ ........... ........... .......
liquid, n.o.s..
D...... Methyl phosphonous dichloride, pyrophoric liquid............. 6.1 NA2845 I POISON, SPONTANEOUSLY 2, B9, B14, B16, None 227 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. B32, B74, T38,
T43, T45.
....... Methyl picric acid (heavy metal salts of).................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl propionate............................................ 3 UN1248 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl propyl ether.......................................... 3 UN2612 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E...... 40
....... Methyl propyl ketone......................................... 3 UN1249 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl sulfate, see Dimethyl sulfate......................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl sulfide, see Dimethyl sulfide......................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl trichloroacetate...................................... 6.1 UN2533 III KEEP AWAY FROM FOOD... 45, T1.......... 153 203 241 60 L....... 220 L...... A......
....... Methyl trimethylol methane trinitrate........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl vinyl ketone.......................................... 3 UN1251 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methylal..................................................... 3 UN1234 II FLAMMABLE LIQUID...... T14............. None 202 242 5 L........ 60 L....... E......
....... Methylamine, anhydrous....................................... 2.1 UN1061 FLAMMABLE GAS......... 25.............. 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Methylamine, aqueous solution................................ 3 UN1235 II FLAMMABLE LIQUID, B1, T8.......... 150 202 243 1 L........ 5 L........ E...... 41
CORROSIVE.
....... Methylamine dinitramine and dry salts thereof................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamine nitroform........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamine perchlorate (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamyl acetate........................................... 3 UN1233 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... N-Methylaniline.............................................. 6.1 UN2294 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... alpha-Methylbenzyl alcohol................................... 6.1 UN2937 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... 3-Methylbutan-2-one.......................................... 3 UN2397 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... N-Methylbutylamine........................................... 3 UN2945 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Methylchloromethyl ether..................................... 6.1 UN1239 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, T38, T43,
T44.
....... Methylchlorosilane........................................... 2.3 UN2534 POISON GAS, FLAMMABLE 2, A2, A3, A7, None 226 314, 315 Forbidden.. Forbidden.. D...... 17, 40
GAS, CORROSIVE. B9, B14, N34.
....... Methylcyclohexanols, flammable............................... 3 UN2617 III FLAMMABLE LIQUID...... B1, T2.......... 150 203 242 60 L....... 220 L...... A......
D...... Methyldichloroarsine......................................... 6.1 NA1556 I POISON................ 2............... None 192 None Forbidden.. Forbidden.. D...... 40, 95
....... Methyldichlorosilane......................................... 4.3 UN1242 I DANGEROUS WHEN WET, A2, A3, A7, B6, None 201 243 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE B77, N34, T16, 49, 100
LIQUID. T26.
....... Methylene chloride, see Dichloromethane...................... ........... .............. ...................... ................ ........... ........... .......
....... Methylene glycol dinitrate................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Methylfuran................................................ 3 UN2301 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... a-Methylglucoside tetranitrate............................... Forbidden .............. ...................... ................ ........... ........... .......
....... a-Methylglycerol trinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 5-Methylhexan-2-one.......................................... 3 UN2302 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methylhydrazine.............................................. 6.1 UN1244 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 21, 40, 49,
LIQUID, CORROSIVE. B72, B77, N34, 100
T38, T43, T44.
....... Methylmorpholine............................................. 3 UN2535 II FLAMMABLE LIQUID, B6, T8.......... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Methylpentadienes............................................ 3 UN2461 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... 2-Methylpentan-2-ol.......................................... 3 UN2560 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methylpentanes, see Hexanes.................................. ........... .............. ...................... ................ ........... ........... .......
....... Methylphenyldichlorosilane................................... 8 UN2437 II CORROSIVE............. T8, T26......... 154 202 242 1 L........ 30 L....... C...... 40
....... 1-Methylpiperidine........................................... 3 UN2399 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Methyltetrahydrofuran........................................ 3 UN2536 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Methyltrichlorosilane........................................ 3 UN1250 I FLAMMABLE LIQUID, A7, B6, B77, None 201 243 Forbidden.. 2.5 L...... B...... 40
CORROSIVE. N34, T14, T26.
....... alpha-Methylvaleraldehyde.................................... 3 UN2367 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Mine rescue equipment containing carbon dioxide, see Carbon ........... .............. ...................... ................ ........... ........... .......
dioxide.
....... Mines with bursting charge................................... 1.1F UN0136 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Mines with bursting charge................................... 1.1D UN0137 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Mines with bursting charge................................... 1.2D UN0138 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Mines with bursting charge................................... 1.2F UN0294 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Mixed acid, see Nitrating acid, mixtures etc................. ........... .............. ...................... ................ ........... ........... .......
....... Mobility aids, see Wheel chair, electric..................... ........... .............. ...................... ................ ........... ........... .......
D...... Model rocket motor........................................... 1.4C NA0276 II EXPLOSIVE 1.4C........ 51.............. None 62 None Forbidden.. 75 kg...... A...... 24E
D...... Model rocket motor........................................... 1.4S NA0323 II EXPLOSIVE 1.4S........ 51.............. None 62 None 25 kg...... 100 kg..... A...... 9E
....... Molybdenum pentachloride..................................... 8 UN2508 III CORROSIVE............. T8, T26......... 154 213 240 25 kg...... 100 kg..... C...... 40
....... Monochloroacetone (unstabilized)............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Monochloroethylene, see Vinyl chloride, inhibited............ ........... .............. ...................... ................ ........... ........... .......
....... Monoethanolamine, see Ethanolamine, solutions................ ........... .............. ...................... ................ ........... ........... .......
....... Monoethylamine, see Ethylamine............................... ........... .............. ...................... ................ ........... ........... .......
....... Morpholine................................................... 3 UN2054 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Morpholine, aqueous, mixture, see Corrosive liquids, n.o.s... ........... .............. ...................... ................ ........... ........... .......
....... Motor fuel anti-knock compounds see Motor fuel anti-knock ........... .............. ...................... ................ ........... ........... .......
mixtures.
+...... Motor fuel anti-knock mixtures............................... 6.1 UN1649 I POISON, FLAMMABLE 14, B9, B12, None 201 244 Forbidden.. 30 L....... D...... 25, 40
LIQUID. B90, T26, T39.
....... Motor spirit, see Gasoline................................... ........... .............. ...................... ................ ........... ........... .......
....... Motor vehicle, see Vehicles, self-propelled.................. ........... .............. ...................... ................ ........... ........... .......
....... Motorcycles, see Vehicles, self-propelled.................... ........... .............. ...................... ................ ........... ........... .......
....... Muriatic acid, see Hydrochloric acid solution................ ........... .............. ...................... ................ ........... ........... .......
....... Musk xylene, see 5-tert-Butyl2,4,6-trinitro-m-xylene......... ........... .............. ...................... ................ ........... ........... .......
....... Naphthalene, crude or Naphthalene, refined................... 4.1 UN1334 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Naphthalene diozonide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Naphthalene, molten.......................................... 4.1 UN2304 III FLAMMABLE SOLID....... A1, T8.......... 151 213 241 Forbidden.. Forbidden.. C......
....... Naphthyl amineperchlorate.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... beta-Naphthylamine........................................... 6.1 UN1650 II POISON................ T12, T26........ None 212 242 25 kg...... 100 kg..... A......
....... alpha-Naphthylamine.......................................... 6.1 UN2077 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Naphthylthiourea............................................. 6.1 UN1651 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Naphthylurea................................................. 6.1 UN1652 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Natural gases (with high methane content), see Methane, etc. ........... .............. ...................... ................ ........... ........... .......
(UN 1971, UN 1972).
....... Neohexane, see Hexanes....................................... ........... .............. ...................... ................ ........... ........... .......
....... Neon, compressed............................................. 2.2 UN1065 NONFLAMMABLE GAS...... ................ 306 302 302 75 kg...... 150 kg..... A......
....... Neon, refrigerated liquid (cryogenic liquid)................. 2.2 UN1913 NONFLAMMABLE GAS...... ................ 320 316 None 50 kg...... 500 kg..... B......
....... New explosive or explosive device, see sections 173.51 and ........... .............. ...................... ................ ........... ........... .......
173.56.
....... Nickel carbonyl.............................................. 6.1 UN1259 I POISON, FLAMMABLE 1............... None 198 None Forbidden.. Forbidden.. D...... 18, 40
LIQUID.
....... Nickel cyanide............................................... 6.1 UN1653 II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 26
....... Nickel nitrate............................................... 5.1 UN2725 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Nickel nitrite............................................... 5.1 UN2726 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 56, 58
....... Nickel picrate............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nicotine..................................................... 6.1 UN1654 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Nicotine compounds, liquid, n.o.s. or Nicotine preparations, 6.1 UN3144 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... B...... 40
liquid, n.o.s..
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... B...... 40
....... Nicotine compounds, solid, n.o.s. or Nicotine preparations, 6.1 UN1655 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
solid, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nicotine hydrochloride or Nicotine hydrochloride solution.... 6.1 UN1656 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Nicotine salicylate.......................................... 6.1 UN1657 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nicotine sulfate, solid...................................... 6.1 UN1658 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nicotine sulfate, solution................................... 6.1 UN1658 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nicotine tartrate............................................ 6.1 UN1659 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nitrated paper (unstable).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrates, inorganic, aqueous solution, n.o.s................. 5.1 UN3218 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46
............................................................. ........... .............. III OXIDIZER.............. T8.............. 152 203 241 2.5 L...... 30 L....... B...... 46
....... Nitrates, inorganic, n.o.s................................... 5.1 UN1477 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 46
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 46
....... Nitrates of diazonium compounds.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrating acid mixtures, spent with more than 50 percent 8 UN1826 I CORROSIVE, OXIDIZER... B47, T12, T27... None 158 243 Forbidden.. 2.5 L...... D...... 40, 66
nitric acid.
....... Nitrating acid mixtures spent with not more than 50 percent 8 UN1826 II CORROSIVE............. B2, B47, T12, None 158 242 Forbidden.. 30 L....... D...... 40
nitric acid. T27.
....... Nitrating acid mixtures with more than 50 percent nitric acid 8 UN1796 I CORROSIVE, OXIDIZER... B47, T12, T27... None 158 243 Forbidden.. 2.5 L...... D...... 40, 66
....... Nitrating acid mixtures with not more than 50 percent nitric 8 UN1796 II CORROSIVE............. B2, B47, T12, None 158 242 Forbidden.. 30 L....... D...... 40
acid. T27.
....... Nitric acid other than red fuming, with more than 70 percent 8 UN2031 I CORROSIVE............. B12, B53, T9, None 158 243 Forbidden.. 2.5 L...... D...... 44, 66, 89,
nitric acid. T27. 90, 110,
111
....... Nitric acid other than red fuming, with not more than 70 8 UN2031 II CORROSIVE............. B2, B12, B53, None 158 242 Forbidden.. 30 L....... D...... 44, 66, 89,
percent nitric acid. T9, T27. 90, 110,
111
+...... Nitric acid, red fuming...................................... 8 UN2032 I CORROSIVE, OXIDIZER, 2, B9, B32, B74, None 227 244 Forbidden.. Forbidden.. D...... 40, 66, 74,
POISON. T38, T43, T45. 89, 90
....... Nitric oxide................................................. 2.3 UN1660 POISON GAS, OXIDIZER, 1, 25, B12, B37, None 337 None Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B46, B50, B60,
B77.
....... Nitric oxide and dinitrogen tetroxide mixtures or Nitric 2.3 UN1975 POISON GAS, OXIDIZER, 1, 25, B7, B9, None 337 None Forbidden.. Forbidden.. D...... 40, 89, 90
oxide and nitrogen dioxide mixtures. CORROSIVE. B12, B14, B45,
B46, B61, B66,
B67, B77.
....... Nitriles, flammable, toxic, n.o.s............................ 3 UN3273 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E...... 40, 52
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... B...... 40, 52
POISON.
....... Nitriles, toxic, flammable, n.o.s............................ 6.1 UN3275 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Nitriles, toxic, n.o.s....................................... 6.1 UN3276 I POISON................ ................ None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Nitrites, inorganic, aqueous solution, n.o.s................. 5.1 UN3219 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46, 56, 58
............................................................. ........... .............. III OXIDIZER.............. T8.............. 152 203 241 2.5 L...... 30 L....... B...... 46, 56, 58
....... Nitrites, inorganic, n.o.s................................... 5.1 UN2627 II OXIDIZER.............. 33.............. 152 212 None 5 kg....... 25 kg...... A...... 46, 56, 58
....... 3-Nitro-4-chlorobenzotrifluoride............................. 6.1 UN2307 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... 6-Nitro-4-diazotoluene-3-sulfonic acid (dry)................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitro isobutane triol trinitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... N-Nitro-N-methylglycolamide nitrate.......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Nitro-2-methylpropanol nitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitro urea................................................... 1.1D UN0147 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... N-Nitroaniline............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroanilines (o-; m-; p-;).................................. 6.1 UN1661 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Nitroanisole................................................. 6.1 UN2730 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A......
....... Nitrobenzene................................................. 6.1 UN1662 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... m-Nitrobenzene diazonium perchlorate......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrobenzenesulfonic acid.................................... 8 UN2305 II CORROSIVE............. ................ 154 202 242 1 L........ 30 L....... A......
....... Nitrobenzol, see Nitrobenzene................................ ........... .............. ...................... ................ ........... ........... .......
....... 5-Nitrobenzotriazol.......................................... 1.1D UN0385 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Nitrobenzotrifluorides....................................... 6.1 UN2306 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Nitrobromobenzenes liquid.................................... 6.1 UN2732 III KEEP AWAY FROM FOOD... T8, T38......... 153 203 241 60 L....... 220 L...... A......
....... Nitrobromobenzenes solid..................................... 6.1 UN2732 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitrocellulose, dry or wetted with less than 25 percent water 1.1D UN0340 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 4E, 27E
(or alcohol), by mass.
....... Nitrocellulose membrane filters.............................. 4.1 UN3270 II FLAMMABLE SOLID....... 43, A1.......... 151 212 240 1 kg....... 15 kg...... D......
....... Nitrocellulose, plasticized with not less than 18 percent 1.3C UN0343 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
plasticizing substance, by mass.
....... Nitrocellulose, solution, flammable with not more than 12.6 3 UN2059 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
percent nitrogen, by mass, and not more than 55 percent
nitrocellulose.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Nitrocellulose, unmodified or plasticized with less than 18 1.1D UN0341 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 4E, 27E
percent plasticizing substance, by mass.
....... Nitrocellulose, wetted with not less than 25 percent alcohol, 1.3C UN0342 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Nitrocellulose with alcohol with not less than 25 percent 4.1 UN2556 II FLAMMABLE SOLID....... ................ 151 212 None 1 kg....... 15 kg...... D...... 28
alcohol by mass, and with not more than 12.6 percent
nitrogen, by dry mass.
....... Nitrocellulose with plasticizer or Nitrocellulose without 4.1 UN2557 II FLAMMABLE SOLID....... 44.............. 151 212 None 1 kg....... 15 kg...... D...... 28
plasticizer or Nitrocellulose with pigment or Nitrocellulose
without pigmnet with not more than 12.6 percent nitrogen, by
dry mass.
....... Nitrocellulose with water with not less than 25 percent 4.1 UN2555 II FLAMMABLE SOLID....... ................ 151 212 None 15 kg...... 50 kg...... E...... 28
water, by mass.
....... Nitrochlorobenzene, see Chloronitrobenzenes etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Nitrocresols................................................. 6.1 UN2446 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitroethane.................................................. 3 UN2842 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Nitroethyl nitrate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroethylene polymer........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen, compressed......................................... 2.2 UN1066 NONFLAMMABLE GAS...... ................ 306 302 314, 315 75 kg...... 150 kg..... A......
....... Nitrogen dioxide, liquefied see Dinitrogen tetroxide, ........... .............. ...................... ................ ........... ........... .......
liquefied.
....... Nitrogen fertilizer solution, see Fertilizer ammoniating ........... .............. ...................... ................ ........... ........... .......
solution etc..
....... Nitrogen, mixtures with rare gases, see Rare gases and ........... .............. ...................... ................ ........... ........... .......
nitrogen mixtures.
....... Nitrogen peroxide, see Dinitrogen tetroxide, liquefied....... ........... .............. ...................... ................ ........... ........... .......
....... Nitrogen, refrigerated liquid cryogenic liquid............... 2.2 UN1977 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... D......
....... Nitrogen tetroxide and nitric oxide mixtures, see Nitric ........... .............. ...................... ................ ........... ........... .......
oxide and nitrogen tetroxide mixtures.
....... Nitrogen tetroxide, see Dinitrogen tetroxide, liquefied...... ........... .............. ...................... ................ ........... ........... .......
....... Nitrogen trichloride......................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Nitrogen trifluoride......................................... 2.2 UN2451 NONFLAMMABLE GAS, ................ None 302 None Forbidden.. 25 kg...... D...... 40
OXIDIZER.
I...... Nitrogen trifluoride......................................... 2.3 UN2451 POISON GAS, OXIDIZER.. ................ None 302 None Forbidden.. 25 kg...... D...... 40
....... Nitrogen triiodide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen triiodide monoamine................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen trioxide............................................ 2.3 UN2421 POISON GAS, OXIDIZER, 1............... None 336 245 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Nitroglycerin, desensitized with not less than 40 percent non- 1.1D UN0143 II EXPLOSIVE 1.1D, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 4E, 21E
volatile water insoluble phlegmatizer, by mass.
....... Nitroglycerin, liquid, not desensitized...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroglycerin, solution in alcohol, with more than 1 percent 3 UN3064 II FLAMMABLE LIQUID...... N8.............. None 202 None Forbidden.. 5 L........ E......
but not more than 5 percent nitroglycerin.
....... Nitroglycerin, solution in alcohol, with more than 1 percent 1.1D UN0144 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 21E
but not more than 10 percent nitrogylcerin.
....... Nitroglycerin solution in alcohol with not more than 1 3 UN1204 II FLAMMABLE LIQUID...... N34, T25........ None 202 None 5 L........ 60 L....... B......
percent nitroglycerin.
....... Nitroguanidine nitrate....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroguanidine or Picrite, dry or wetted with less than 20 1.1D UN0282 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Nitroguanidine, wetted or Picrite, wetted with not less than 4.1 UN1336 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28
20 percent water, by mass. A20, N41.
....... 1-Nitrohydantoin............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrohydrochloric acid....................................... 8 UN1798 I CORROSIVE............. A3, B10, N41, None 201 243 Forbidden.. 2.5 L...... D...... 40, 66, 74,
T18, T27. 89, 90
....... Nitromannite (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitromannite, wetted, see Mannitol hexanitrate, etc.......... ........... .............. ...................... ................ ........... ........... .......
....... Nitromethane................................................. 3 UN1261 II FLAMMABLE LIQUID...... T25............. 150 202 None Forbidden.. 60 L....... A......
....... Nitromuriatic acid, see Nitrohydrochloric acid............... ........... .............. ...................... ................ ........... ........... .......
....... Nitronaphthalene............................................. 4.1 UN2538 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Nitrophenols (o-; m-; p-;)................................... 6.1 UN1663 III KEEP AWAY FROM FOOD... T8, T38......... 153 213 240 100 kg..... 200 kg..... A......
....... m-Nitrophenyldinitro methane................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitropropanes................................................ 3 UN2608 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... p-Nitrosodimethylaniline..................................... 4.2 UN1369 II SPONTANEOUSLY A19, A20, N34... None 212 241 15 kg...... 50 kg...... D...... 34
COMBUSTIBLE.
D...... Nitrosoguanidine............................................. 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Nitrostarch, dry or wetted with less than 20 percent water, 1.1D UN0146 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Nitrostarch, wetted with not less than 20 percent water, by 4.1 UN1337 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... D...... 28
mass. A20, N41.
....... Nitrosugars (dry)............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrosyl chloride............................................ 2.3 UN1069 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Nitrosylsulfuric acid........................................ 8 UN2308 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... D...... 40, 66, 74,
N34, T9, T27. 89, 90
....... Nitrotoluenes, liquid o-; m-; p-;............................ 6.1 UN1664 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nitrotoluenes, solid m-, or p-............................... 6.1 UN1664 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Nitrotoluidines (mono)....................................... 6.1 UN2660 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitrotriazolone or NTO....................................... 1.1D UN0490 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Nitrous oxide and carbon dioxide mixtures, see Carbon dioxide ........... .............. ...................... ................ ........... ........... .......
and nitrous oxide mixtures.
....... Nitrous oxide, compressed.................................... 2.2 UN1070 NONFLAMMABLE GAS, ................ 306 304 314, 315 75 kg...... 150 kg..... A...... 40
OXIDIZER.
....... Nitrous oxide, refrigerated liquid........................... 2.2 UN2201 NONFLAMMABLE GAS...... B6.............. None 304 314, 315 75 kg...... 150 kg..... B...... 40
....... Nitroxylenes, (o-; m-; p-)................................... 6.1 UN1665 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nitroxylol, see Nitroxylenes................................. ........... .............. ...................... ................ ........... ........... .......
....... Nonanes...................................................... 3 UN1920 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Nonflammable gas, n.o.s., see Compressed or Liquefied gases, ........... .............. ...................... ................ ........... ........... .......
etc. (UN 1955, UN 1956).
....... Nonliquefied gases, see Compressed gases, etc................ ........... .............. ...................... ................ ........... ........... .......
....... Nonliquefied hydrocarbon gas, see Hydrocarbon gases, ........... .............. ...................... ................ ........... ........... .......
compressed, n.o.s..
....... Nonyltrichlorosilane......................................... 8 UN1799 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... 2,5 Norbornadiene or Dicycloheptadiene....................... 3 UN2251 II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... D......
....... Nordhausen acid, see Sulfuric acid, fuming etc............... ........... .............. ...................... ................ ........... ........... .......
....... Octadecyltrichlorosilane..................................... 8 UN1800 II CORROSIVE............. A7, B2, B6 N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8.
....... Octadiene.................................................... 3 UN2309 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... 1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid..... Forbidden .............. ...................... ................ ........... ........... .......
....... Octafluorobut-2-ene.......................................... 2.2 UN2422 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octafluorocyclobutane, RC318................................. 2.2 UN1976 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octafluoropropane, R218...................................... 2.2 UN2424 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octanes...................................................... 3 UN1262 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Octogen, see Cyclotetramethylene tetranitramine, etc......... ........... .............. ...................... ................ ........... ........... .......
....... Octolite or Octol, dry or wetted with less than 15 percent 1.1D UN0266 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Octonal...................................................... 1.1D UN0496 EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Octyl aldehydes, flammable................................... 3 UN1191 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... tert-Octylmercaptan.......................................... 6.1 UN3023 II POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... B...... 40, 102
LIQUID. B74, T38, T43,
T45.
....... Octyltrichlorosilane......................................... 8 UN1801 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Oil gas...................................................... 2.3 UN1071 POISON GAS, FLAMMABLE 6............... None 304 314, 315 Forbidden.. 150 kg..... D...... 40
GAS.
....... Oleum, see Sulfuric acid, fuming............................. ........... .............. ...................... ................ ........... ........... .......
....... Organic peroxide type A, liquid or solid..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Organic peroxide type B, liquid.............................. 5.2 UN3101 II ORGANIC PEROXIDE, 53.............. 152 225 None Forbidden.. Forbidden.. D...... 12, 40
EXPLOSIVE.
....... Organic peroxide type B, liquid, temperature controlled...... 5.2 UN3111 II ORGANIC PEROXIDE, 53.............. None 225 None Forbidden.. Forbidden.. D...... 2, 40
EXPLOSIVE.
....... Organic peroxide type B, solid............................... 5.2 UN3102 II ORGANIC PEROXIDE, 53.............. 152 225 None Forbidden.. Forbidden.. D...... 12, 40
EXPLOSIVE.
....... Organic peroxide type B, solid, temperature controlled....... 5.2 UN3112 II ORGANIC PEROXIDE, 53.............. None 225 None Forbidden.. Forbidden.. D...... 2, 40
EXPLOSIVE.
....... Organic peroxide type C, liquid.............................. 5.2 UN3103 II ORGANIC PEROXIDE...... ................ 152 225 None 5 L........ 10 L....... D...... 12, 40
....... Organic peroxide type C, liquid, temperature controlled...... 5.2 UN3113 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type C, solid............................... 5.2 UN3104 II ORGANIC PEROXIDE...... ................ 152 225 None 5 kg....... 10 kg...... D...... 12, 40
....... Organic peroxide type C, solid, temperature controlled....... 5.2 UN3114 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type D, liquid.............................. 5.2 UN3105 II ORGANIC PEROXIDE...... ................ 152 225 None 5 L........ 10 L....... D...... 12, 40
....... Organic peroxide type D, liquid, temperature controlled...... 5.2 UN3115 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type D, solid............................... 5.2 UN3106 II ORGANIC PEROXIDE...... ................ 152 225 None 5 kg....... 10 kg...... D...... 12, 40
....... Organic peroxide type D, solid, temperature controlled....... 5.2 UN3116 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type E, liquid.............................. 5.2 UN3107 II ORGANIC PEROXIDE...... ................ 152 225 None 10 L....... 25 L....... D...... 12, 40
....... Organic peroxide type E, liquid, temperature controlled...... 5.2 UN3117 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type E, solid............................... 5.2 UN3108 II ORGANIC PEROXIDE...... ................ 152 225 None 10 kg...... 25 kg...... D...... 12, 40
....... Organic peroxide type E, solid, temperature controlled....... 5.2 UN3118 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type F, liquid.............................. 5.2 UN3109 II ORGANIC PEROXIDE...... ................ 152 225 225 10 L....... 25 L....... D...... 12, 40
....... Organic peroxide type F, liquid, temperature controlled...... 5.2 UN3119 II ORGANIC PEROXIDE...... ................ 225 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type F, solid............................... 5.2 UN3110 II ORGANIC PEROXIDE...... T42............. 152 225 None 10 kg...... 25 kg...... D...... 12, 40
....... Organic peroxide type F, solid, temperature controlled....... 5.2 UN3120 II ORGANIC PEROXIDE...... ................ 225 225 None Forbidden.. Forbidden.. D...... 2, 40
D...... Organic phosphate, mixed with compressed gas or Organic 2.3 NA1955 POISON GAS............ 3............... None 334 None Forbidden.. Forbidden.. D...... 40
phosphate compound, mixed with compressed gas or Organic
phosphorus compound, mixed with compressed gas.
....... Organoarsenic compound, n.o.s................................ 6.1 UN3280 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Organochlorine pesticides liquid, flammable, toxic, flash 3 UN2762 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Organochlorine pesticides, liquid, toxic..................... 6.1 UN2996 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organochlorine pesticides, liquid, toxic, flammable, 6.1 UN2995 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organochlorine pesticides, solid toxic....................... 6.1 UN2761 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organometallic compound or Compound solution or Compound 4.3 UN3207 I DANGEROUS WHEN WET, ................ None 201 244 Forbidden.. 1 L........ E...... 40
dispersion, water-reactive, flammable, n.o.s.. FLAMMABLE LIQUID.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 40
FLAMMABLE LIQUID.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E...... 40
FLAMMABLE LIQUID.
....... Organometallic compound, toxic n.o.s......................... 6.1 UN3282 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Organophosphorus compound, toxic, flammable, n.o.s........... 6.1 UN3279 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Organophosphorus compound, toxic n.o.s....................... 6.1 UN3278 I POISON................ ................ None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Organophosphorus pesticides, liquid, flammable, toxic, flash 3 UN2784 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Organophosphorus pesticides, liquid, toxic................... 6.1 UN3018 I POISON................ N76, T42........ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ N76, T14........ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N76, T14........ 153 203 241 60 L....... 220 L...... A...... 40
....... Organophosphorus pesticides, liquid, toxic, flammable, 6.1 UN3017 I POISON, FLAMMABLE N76, T42........ None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE N76, T14........ None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, N76, T14.... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organophosphorus pesticides, solid, toxic.................... 6.1 UN2783 I POISON................ N77............. None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ N77............. None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organotin compounds, liquid, n.o.s........................... 6.1 UN2788 I POISON................ A3, N33, N34, None 201 243 1 L........ 30 L....... B...... 40
T42.
............................................................. ........... .............. II POISON................ A3, N33, N34, None 202 243 5 L........ 60 L....... A...... 40
T14.
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organotin compounds, solid, n.o.s............................ 6.1 UN3146 I POISON................ A5.............. None 211 242 5 kg....... 50 kg...... B...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organotin pesticides, liquid, flammable, toxic, flash point 3 UN2787 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Organotin pesticides, liquid, toxic.......................... 6.1 UN3020 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organotin pesticides, liquid, toxic, flammable, flashpoint 6.1 UN3019 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organotin pesticides, solid, toxic........................... 6.1 UN2786 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Orthonitroaniline, see Nitroanilines etc..................... ........... .............. ...................... ................ ........... ........... .......
....... Osmium tetroxide............................................. 6.1 UN2471 I POISON................ A8, N33, N34.... None 211 242 5 kg....... 50 kg...... B...... 40
AD..... Other regulated substances, liquid, n.o.s.................... 9 NA3082 III CLASS 9............... ................ 155 203 241 No limit... No limit... A......
AD..... Other regulated substances, solid, n.o.s..................... 9 NA3077 III CLASS 9............... B54............. 155 213 240 No limit... No limit... A......
....... Oxidizing, liquid, corrosive, n.o.s.......................... 5.1 UN3098 I OXIDIZER, CORROSIVE... ................ None 201 244 Forbidden.. 2.5 L...... B...... 34, 56, 58,
69, 106
............................................................. ........... .............. II OXIDIZER, CORROSIVE... ................ None 202 243 1 L........ 5 L........ D...... 34, 56, 58,
69, 106
............................................................. ........... .............. III OXIDIZER, CORROSIVE... ................ 152 203 242 2.5 L...... 30 L....... B...... 34, 56, 58,
69, 106
....... Oxidizing, liquid, n.o.s..................................... 5.1 UN3139 II OXIDIZER.............. A2.............. 152 202 242 1 L........ 5 L........ B...... 56, 58, 69,
106
............................................................. ........... .............. III OXIDIZER.............. A2.............. 152 203 241 2.5 L...... 30 L....... B...... 56, 58, 69,
106
....... Oxidizing, liquid, toxic, n.o.s.............................. 5.1 UN3099 I OXIDIZER, POISON...... ................ None 201 244 Forbidden.. 2.5 L...... D...... 56, 58, 95,
106
............................................................. ........... .............. II OXIDIZER, POISON...... ................ None 202 243 1 L........ 5 L........ B...... 56, 58, 95,
106
............................................................. ........... .............. III OXIDIZER, KEEP AWAY ................ 152 203 242 2.5 L...... 30 L....... B...... 56, 58, 95,
FROM FOOD. 106
....... Oxidizing, solid, corrosive, n.o.s........................... 5.1 UN3085 I OXIDIZER, CORROSIVE... ................ None 211 242 1 kg....... 15 kg...... D...... 13, 34, 56,
58, 69,
106
............................................................. ........... .............. II OXIDIZER, CORROSIVE... ................ None 212 242 5 kg....... 25 kg...... B...... 13, 34, 56,
58, 69,
106
............................................................. ........... .............. III OXIDIZER, CORROSIVE... ................ 152 213 240 25 kg...... 100 kg..... B...... 13, 34, 56,
58, 69,
106
....... Oxidizing, solid, flammable, n.o.s........................... 5.1 UN3137 I OXIDIZER, FLAMMABLE ................ None 214 214 Forbidden.. Forbidden.. .......
SOLID.
....... Oxidizing, solid, self heating, n.o.s........................ 5.1 UN3100 OXIDIZER, ................ None 214 214 Forbidden.. Forbidden.. .......
SPONTANEOUSLY
COMBUSTIBLE.
....... Oxidizing solid, toxic, n.o.s................................ 5.1 UN3087 I OXIDIZER, POISON...... ................ None 211 242 1 kg....... 15 kg...... D...... 56, 58, 69,
95, 106
............................................................. ........... .............. II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... B...... 56, 58, 69,
95, 106
............................................................. ........... .............. III OXIDIZER, KEEP AWAY ................ 152 213 240 25 kg...... 100 kg..... B...... 56, 58, 69,
FROM FOOD. 95, 106
....... Oxidizing, solid, water-reactive, n.o.s...................... 5.1 UN3121 OXIDIZER, DANGEROUS ................ None 214 214 Forbidden.. Forbidden.. .......
WHEN WET.
....... Oxidizing solid, n.o.s....................................... 5.1 UN1479 I OXIDIZER.............. ................ 152 211 242 1 kg....... 15 kg...... D...... 56, 58, 69,
106
............................................................. ........... .............. II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... B...... 56, 58, 69,
106
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... B...... 56, 58, 69,
106
....... Oxygen and carbon dioxide mixtures, see Carbon dioxide and ........... .............. ...................... ................ ........... ........... .......
oxygen mixtures.
....... Oxygen, compressed........................................... 2.2 UN1072 NONFLAMMABLE GAS, ................ 306 302 314, 315 75 kg...... 150 kg..... A......
OXIDIZER.
....... Oxygen difluoride............................................ 2.3 UN2190 POISON GAS, OXIDIZER, 1............... None 304 None Forbidden.. Forbidden.. D...... 13, 40, 89,
CORROSIVE. 90
....... Oxygen, mixtures with rare gases, see Rare gases and oxygen ........... .............. ...................... ................ ........... ........... .......
mixtures.
....... Oxygen, refrigerated liquid (cryogenic liquid)............... 2.2 UN1073 NONFLAMMABLE GAS, ................ 320 316 318 Forbidden.. Forbidden.. D......
OXIDIZER.
....... Paint including paint, lacquer, enamel, stain, shellac 3 UN1263 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
solutions, varnish, polish, liquid filler, and liquid
lacquer base.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Paint or Paint related material.............................. 8 UN3066 II CORROSIVE............. B2, N71, T14.... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. B52, N71, T7.... 154 203 241 5 L........ 60 L....... A......
....... Paint related material including paint thinning, drying, 3 UN1263 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
removing, or reducing compound.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Paper, unsaturated oil treated incompletely dried (including 4.2 UN1379 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A......
carbon paper). COMBUSTIBLE.
....... Paraformaldehyde............................................. 4.1 UN2213 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Paraldehyde.................................................. 3 UN1264 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Paranitroaniline, solid, see Nitroanilines etc............... ........... .............. ...................... ................ ........... ........... .......
D...... Parathion.................................................... 6.1 NA2783 I POISON................ T42............. None 201 243 Forbidden.. 1 L........ A...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 Forbidden.. 5 L........ A...... 40
D...... Parathion and compressed gas mixture......................... 2.3 NA1967 POISON GAS............ 3............... None 334 245 Forbidden.. Forbidden.. E...... 40
....... Paris green, solid, see Copper acetoarsenite................. ........... .............. ...................... ................ ........... ........... .......
A,W.... PCB, see Polychlorinated biphenyls........................... ........... .............. ...................... ................ ........... ........... .......
+...... Pentaborane.................................................. 4.2 UN1380 I SPONTANEOUSLY 1............... None 205 245 Forbidden.. Forbidden.. D......
COMBUSTIBLE, POISON.
....... Pentachloroethane............................................ 6.1 UN1669 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Pentachlorophenol............................................ 6.1 UN3155 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Pentaerythrite tetranitrate (dry)............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Pentaerythrite tetranitrate or Pentaerythritol tetranitrate 1.1D UN0411 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
or PETN, with not less than 7 percent wax by mass.
D...... Pentaerythrite tetranitrate, wetted or Pentaerythritol 1.1D UN0150 II EXPLOSIVE 1.1D........ 25.............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
tetranitrate, wetted, or PETN, wetted with not less than 25
percent water, by mass, or Pentaerythrite tetranitrate, or
Pentaerythritol tetranitrate or PETN, desensitized with not
less than 15 percent phlegmatizer by mass.
....... Pentaerythritol tetranitrate, see Pentaerythrite ........... .............. ...................... ................ ........... ........... .......
tetranitrate, etc..
....... Pentafluoroethane............................................ 2.2 UN3220 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Pentamethylheptane........................................... 3 UN2286 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Pentan-2,4-dione............................................. 3 UN2310 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Pentanes..................................................... 3 UN1265 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T20............. 150 202 242 5 L........ 60 L....... E......
....... Pentanitroaniline (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Pentol..................................................... 8 UN2705 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... B...... 38
....... Pentolite, dry or wetted with less than 15 percent water, by 1.1D UN0151 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
mass.
....... Percarbonates, inorganic, n.o.s.............................. 5.1 UN3217 III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 13
....... Perchlorates, inorganic, aqueous solution, n.o.s............. 5.1 UN3211 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46, 56, 58
....... Perchlorates, inorganic, n.o.s............................... 5.1 UN1481 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 46, 56
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 46, 56
....... Perchloric acid, with more than 72 percent acid by mass...... Forbidden .............. ...................... ................ ........... ........... .......
....... Perchloric acid with more than 50 percent but not more than 5.1 UN1873 I OXIDIZER, CORROSIVE... A2, A3, N41, T9, None 201 243 Forbidden.. 2.5 L...... D...... 66
72 percent acid, by mass. T27.
....... Perchloric acid with not more than 50 percent acid by mass... 8 UN1802 II CORROSIVE, OXIDIZER... N41, T9......... None 202 243 Forbidden.. 30 L....... C...... 66
....... Perchloroethylene, see Tetrachloroethylene................... ........... .............. ...................... ................ ........... ........... .......
....... Perchloromethylmercaptan..................................... 6.1 UN1670 I POISON................ 2, A3, A7, B9, None 227 244 Forbidden.. Forbidden.. D...... 40
B14, B32, B74,
N34, T38, T43,
T45.
....... Perchloryl fluoride.......................................... 2.3 UN3083 POISON GAS, OXIDIZER.. 2, 25, B9, B12, None 302 314, 315 Forbidden.. Forbidden.. D...... 40
B14.
....... Percussion caps, see Primers, cap type....................... ........... .............. ...................... ................ ........... ........... .......
....... Perfluoro-2-butene, see Octafluorobut-2-ene.................. ........... .............. ...................... ................ ........... ........... .......
....... Perfluoroethylvinyl ether.................................... 2.1 UN3154 FLAMMABLE GAS......... ................ 306 302, 304, 314, 315 Forbidden.. 150 kg..... E...... 40
305
....... Perfluoromethylvinyl ether................................... 2.1 UN3153 FLAMMABLE GAS......... ................ 306 302, 304, 314, 315 Forbidden.. 150 kg..... E...... 40
305
....... Perfumery products with flammable solvents................... 3 UN1266 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 15 L....... 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Permanganates, inorganic, aqueous solution, n.o.s............ 5.1 UN3214 II OXIDIZER.............. 26, T8.......... 152 2O2 242 1 L........ 5 L........ D...... 56, 58, 69,
106, 107
....... Permanganates, inorganic, n.o.s.............................. 5.1 UN1482 II OXIDIZER.............. 26, A30......... 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
............................................................. ........... .............. III OXIDIZER.............. 26, A30......... 152 213 240 25 kg...... 100 kg..... D...... 56, 58, 69,
106, 107
....... Peroxides, inorganic, n.o.s.................................. 5.1 UN1483 II OXIDIZER.............. A7, A20, N34.... None 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
............................................................. ........... .............. III OXIDIZER.............. A7, A20, N34.... 152 213 240 25 kg...... 100 kg..... A...... 13, 75, 106
....... Peroxyacetic acid, with more than 43 percent and with more Forbidden .............. ...................... ................ ........... ........... .......
than 6 percent hydrogen peroxide.
....... Persulphates, inorganic, aqueous solution, n.o.s............. 5.1 UN3216 III OXIDIZER.............. T2.............. 152 203 241 2.5 L...... 30 L....... A......
....... Persulphates, inorganic, n.o.s............................... 5.1 UN3215 III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A......
....... Pesticides, liquid, flammable, toxic, (flashpoint less than 3 UN3021 I FLAMMABLE LIQUID, B5.............. None 201 243 Forbidden.. 30 L....... B......
23 degrees C). POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B......
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B......
AWAY FROM FOOD.
....... Pesticides, liquid, toxic, flammable, n.o.s. flashpoint not 6.1 UN2903 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Pesticides, liquid, toxic, n.o.s............................. 6.1 UN2902 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Pesticides, solid, toxic, n.o.s.............................. 6.1 UN2588 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... PETN, see Pentaerythrite tetranitrate........................ ........... .............. ...................... ................ ........... ........... .......
....... PETN/TNT, see Pentolite, etc................................. ........... .............. ...................... ................ ........... ........... .......
....... Petrol, see Gasoline......................................... ........... .............. ...................... ................ ........... ........... .......
....... Petroleum crude oil.......................................... 3 UN1267 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Petroleum distillates, n.o.s. or Petroleum products, n.o.s... 3 UN1268 I FLAMMABLE LIQUID...... T8, T31......... 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Petroleum ether, see Petroleum spirit........................ ........... .............. ...................... ................ ........... ........... .......
....... Petroleum gases, liquefied or Liquefied petroleum gas........ 2.1 UN1075 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Petroleum naphtha, see Naphtha, petroleum.................... ........... .............. ...................... ................ ........... ........... .......
....... Phenacyl bromide............................................. 6.1 UN2645 II POISON................ ................ None 212 242 25 kg...... 100 kg..... B...... 40
....... Phenetidines................................................. 6.1 UN2311 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Phenol, molten............................................... 6.1 UN2312 II POISON................ B14, T8......... None 202 243 Forbidden.. Forbidden.. B...... 40
+...... Phenol, solid................................................ 6.1 UN1671 II POISON................ N78, T14........ None 212 242 25 kg...... 100 kg..... A......
....... Phenol solutions............................................. 6.1 UN2821 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Phenolsulfonic acid, liquid.................................. 8 UN1803 II CORROSIVE............. B2, N41, T8..... 154 202 242 1 L........ 30 L....... C...... 14
....... Phenoxy pesticides, liquid, flammable, toxic, flash point 3 UN2766 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phenoxy pesticides, liquid, toxic............................ 6.1 UN3000 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phenoxy pesticides, liquid, toxic, flammable, flashpoint not 6.1 UN2999 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phenoxy pesticides, solid, toxic............................. 6.1 UN2765 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
+...... Phenyl isocyanate............................................ 6.1 UN2487 II POISON................ 2, A3, B9, B14, None 227 244 5 L........ 60 L....... D...... 40
B32, B74, B77,
N33, N34, T38,
T43, T45.
....... Phenyl mercaptan............................................. 6.1 UN2337 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 26, 40
LIQUID. B74, B77, T38,
T43, T45.
....... Phenyl phosphorus dichloride................................. 8 UN2798 II CORROSIVE............. B2, B15, T8, T26 154 202 242 Forbidden.. 30 L....... B...... 40
....... Phenyl phosphorus thiodichloride............................. 8 UN2799 II CORROSIVE............. B2, B15, T8, T26 154 202 242 Forbidden.. 30 L....... B...... 40
....... Phenyl urea pesticides, liquid, flammable, toxic, flash point 3 UN2768 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phenyl urea pesticides, liquid, toxic........................ 6.1 UN3002 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phenyl urea pesticides, liquid, toxic, flammable, flash point 6.1 UN3001 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phenyl urea pesticides, solid, toxic......................... 6.1 UN2767 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Phenylacetonitrile, liquid................................... 6.1 UN2470 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 26
....... Phenylacetyl chloride........................................ 8 UN2577 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Phenylcarbylamine chloride................................... 6.1 UN1672 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... Phenylchloroformate.......................................... 6.1 UN2746 II POISON, CORROSIVE..... T12............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... m-Phenylene diaminediperchlorate (dry)....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Phenylenediamines (o-; m-; p-;).............................. 6.1 UN1673 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Phenylhydrazine.............................................. 6.1 UN2572 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Phenylmercuric acetate....................................... 6.1 UN1674 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenylmercuric compounds, n.o.s.............................. 6.1 UN2026 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Phenylmercuric hydroxide..................................... 6.1 UN1894 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenylmercuric nitrate....................................... 6.1 UN1895 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenyltrichlorosilane........................................ 8 UN1804 II CORROSIVE............. A7, B6, N34, T8. None 202 242 Forbidden.. 30 L....... C...... 40
....... Phosgene..................................................... 2.3 UN1076 POISON GAS, CORROSIVE. 1, B7, B46...... None 192 314 Forbidden.. Forbidden.. D...... 40
....... 9-Phosphabicyclononanes or Cyclooctadiene phosphines......... 4.2 UN2940 II SPONTANEOUSLY A19............. None 212 241 15 kg...... 50 kg...... A......
COMBUSTIBLE.
....... Phosphine.................................................... 2.3 UN2199 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Phosphoric acid.............................................. 8 UN1805 III CORROSIVE............. A7, N34, T7..... 154 203 241 5 L........ 60 L....... A......
....... Phosphoric acid triethyleneimine, see Tri-(1-aziridiyl) ........... .............. ...................... ................ ........... ........... .......
phosphine oxide, solution.
....... Phosphoric anhydride, see Phosphorus pentoxide............... ........... .............. ...................... ................ ........... ........... .......
....... Phosphorous acid............................................. 8 UN2834 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A...... 48
....... Phosphorus, amorphous........................................ 4.1 UN1338 III FLAMMABLE SOLID....... A1, A19, B1, B9, None 213 243 25 kg...... 100 kg..... A...... 74
B12, B26.
....... Phosphorus bromide, see Phosphorus tribromide................ ........... .............. ...................... ................ ........... ........... .......
....... Phosphorus chloride, see Phosphorus trichloride.............. ........... .............. ...................... ................ ........... ........... .......
....... Phosphorus heptasulfide, free from yellow or white phosphorus 4.1 UN1339 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
....... Phosphorus oxybromide........................................ 8 UN1939 II CORROSIVE............. B8, N41, N43.... None 212 240 Forbidden.. 50 kg...... C...... 12, 40
....... Phosphorus oxybromide, molten................................ 8 UN2576 II CORROSIVE............. B2, B8, N41, None 202 242 Forbidden.. Forbidden.. C...... 40
N43, T8, T27.
+...... Phosphorus oxychloride....................................... 8 UN1810 II CORROSIVE, POISON..... 2, A7, B9, B14, None 227 244 Forbidden.. 30 L....... C...... 40
B32, B74, B77,
N34, T38, T43,
T45.
....... Phosphorus pentabromide...................................... 8 UN2691 II CORROSIVE............. A7, N34......... 154 212 240 Forbidden.. 50 kg...... B...... 12, 40
....... Phosphorus pentachloride..................................... 8 UN1806 II CORROSIVE............. A7, N34......... None 212 240 Forbidden.. 50 kg...... C...... 40
....... Phosphorus pentafluoride..................................... 2.3 UN2198 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Phosphorus pentasulfide, free from yellow or white phosphorus 4.3 UN1340 II DANGEROUS WHEN WET.... A20, B59........ None 212 242 15 kg...... 50 kg...... B...... 74
....... Phosphorus pentoxide......................................... 8 UN1807 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Phosphorus sesquisulfide, free from yellow or white 4.1 UN1341 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
phosphorus.
....... Phosphorus tribromide........................................ 8 UN1808 II CORROSIVE............. A3, A6, A7, B2, None 202 242 Forbidden.. 30 L....... C...... 40
B25, N34, N43,
T8.
+...... Phosphorus trichloride....................................... 8 UN1809 I CORROSIVE, POISON..... 2, A3, A7, B9, None 227 244 Forbidden.. 2.5 L...... C...... 40
B14, B15, B32,
B74, B77, N34,
T38, T43, T45.
....... Phosphorus trioxide.......................................... 8 UN2578 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Phosphorus trisulfide, free from yellow or white phosphorus.. 4.1 UN1343 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
....... Phosphorus, white dry or Phosphorus, white, under water or 4.2 UN1381 I SPONTANEOUSLY B9, B12, B26, None 188 243 Forbidden.. Forbidden.. E......
Phosphorus white, in solution or Phosphorus, yellow dry or COMBUSTIBLE, POISON. N34, T15, T26,
Phosphorus, yellow, under water or Phosphorus, yellow, in T33.
solution.
....... Phosphorus white, molten..................................... 4.2 UN2447 I SPONTANEOUSLY B9, B12, B26, None 188 243 Forbidden.. Forbidden.. D......
COMBUSTIBLE, POISON. N34, T15, T26,
T29.
....... Phosphorus (white or red) and a chlorate, mixtures of........ Forbidden .............. ...................... ................ ........... ........... .......
....... Phosphoryl chloride, see Phosphorus oxychloride.............. ........... .............. ...................... ................ ........... ........... .......
....... Phthalic anhydride with more than .05 percent maleic 8 UN2214 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
anhydride.
....... Phthalimide derivative pesticides, liquid, flammable, toxic, 3 UN2774 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phthalimide derivative pesticides, liquid, toxic............. 6.1 UN3008 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phthalimide derivative pesticides, liquid, toxic, flammable 6.1 UN3007 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phthalimide derivative pesticides, solid, toxic.............. 6.1 UN2773 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Picolines.................................................... 3 UN2313 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Picric acid, see Trinitrophenol, etc......................... ........... .............. ...................... ................ ........... ........... .......
D...... Picric acid, wet, with not less than 10 percent water........ 4.1 NA1344 I FLAMMABLE SOLID....... A19, A20, N41... None 211 None Forbidden.. Forbidden.. D......
....... Picrite, see Nitroguanidine, etc............................. ........... .............. ...................... ................ ........... ........... .......
....... Picryl chloride, see Trinitrochlorobenzene................... ........... .............. ...................... ................ ........... ........... .......
....... Pine oil..................................................... 3 UN1272 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... alpha-Pinene................................................. 3 UN2368 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Piperazine................................................... 8 UN2579 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A...... 12
....... Piperidine................................................... 3 UN2401 II FLAMMABLE LIQUID, T2.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Pivaloyl chloride, see Trimethyl acetyl chloride............. ........... .............. ...................... ................ ........... ........... .......
A...... Plastic molding material in dough, sheet or extruded rope 9 .............. III CLASS 9............... ................ 155 213 None 100 kg..... 200 kg..... A......
form.
....... Plastic solvent, n.o.s., see Flammable liquids, n.o.s........ ........... .............. ...................... ................ ........... ........... .......
....... Plastics, nitrocellulose-based, self-heating, n.o.s.......... 4.2 UN2006 III SPONTANEOUSLY ................ None 213 None Forbidden.. Forbidden.. C......
COMBUSTIBLE.
....... Poisonous gases, n.o.s., see Compressed or liquefied gases, ........... .............. ...................... ................ ........... ........... .......
flammable or toxic, n.o.s..
....... Polyalkylamines, n.o.s., see Alkylamines, etc................ ........... .............. ...................... ................ ........... ........... .......
AW..... Polychlorinated biphenyls.................................... 9 UN2315 II CLASS 9............... 9, 81........... 155 202 241 100 L...... 220 L...... A...... 34
....... Polyester resin kit.......................................... 3 UN3269 FLAMMABLE LIQUID...... 40.............. None 225 None 5 kg....... 5 kg....... B......
....... Polyhalogenated biphenyls, liquid or Polyhalogenated 9 UN3151 II CLASS 9............... ................ 155 204 241 100 L...... 220 L...... A...... 34
terphenyls liquid.
....... Polyhalogenated biphenyls, solid or Polyhalogenated 9 UN3152 II CLASS 9............... ................ 155 204 241 100 kg..... 200 kg..... A...... 34
terphenyls, solid.
....... Polymeric beads, expandable, evolving flammable vapor........ 9 UN2211 III None.................. 32.............. 155 221 240 100 kg..... 200 kg..... A...... 85, 87
....... Potassium.................................................... 4.3 UN2257 I DANGEROUS WHEN WET.... A19, A20, B27, None 211 244 1 kg....... 15 kg...... D......
N6, N34, T15,
T26.
....... Potassium arsenate........................................... 6.1 UN1677 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium arsenite........................................... 6.1 UN1678 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium bisulfite solution, see Bisulfites, inorganic, ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Potassium borohydride........................................ 4.3 UN1870 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Potassium bromate............................................ 5.1 UN1484 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium carbonyl........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Potassium chlorate........................................... 5.1 UN1485 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium chlorate, aqueous solution......................... 5.1 UN2427 II OXIDIZER.............. A2, T8.......... 152 202 241 1 L........ 5 L........ B...... 56, 58, 106
....... Potassium chlorate mixed with mineral oil, see Explosive, ........... .............. ...................... ................ ........... ........... .......
blasting, type C.
....... Potassium cuprocyanide....................................... 6.1 UN1679 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Potassium cyanide............................................ 6.1 UN1680 I POISON................ B69, B77, N74, None 211 242 5 kg....... 50 kg...... B...... 52
N75, T18, T26.
....... Potassium dichloro isocyanurate or Potassium dichloro-s- ........... .............. ...................... ................ ........... ........... .......
triazinetrione, see Dichloroisocyanuric acid, dry or
Dichloroisocyanuric acid salts etc.
....... Potassium dithionite or Potassium hydrosulfite............... 4.2 UN1929 II SPONTANEOUSLY A8, A19, A20.... None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Potassium fluoride........................................... 6.1 UN1812 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 26
....... Potassium fluoroacetate...................................... 6.1 UN2628 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Potassium fluorosilicate..................................... 6.1 UN2655 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Potassium hydrate, see Potassium hydroxide, solid............ ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydrogen fluoride, see Potassium bifluoride........ ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydrogen fluoride solution, see Corrosive liquid, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Potassium hydrogen sulfate................................... 8 UN2509 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Potassium hydrogendifluoride, solid.......................... 8 UN1811 II CORROSIVE, POISON..... N3, N34, T8..... 154 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
....... Potassium hydrogendifluoride, solution....................... 8 UN1811 II CORROSIVE, POISON..... N3, N34, T8..... 154 202 243 1 L........ 30 L....... A...... 26, 40, 95
....... Potassium hydrosulfite, see Potassium dithionite............. ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydroxide, liquid, see Potassium hydroxide solution ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydroxide, solid................................... 8 UN1813 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Potassium hydroxide, solution................................ 8 UN1814 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Potassium hypochlorite, solution, see Hypochlorite solutions, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Potassium, metal alloys...................................... 4.3 UN1420 I DANGEROUS WHEN WET.... A19, A20, B27... None 211 244 1 kg....... 15 kg...... D......
....... Potassium metal, liquid alloy, see Alkali metal alloys, ........... .............. ...................... ................ ........... ........... .......
liquid.
....... Potassium metavanadate....................................... 6.1 UN2864 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium monoxide........................................... 8 UN2033 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Potassium nitrate............................................ 5.1 UN1486 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Potassium nitrate and sodium nitrite mixtures................ 5.1 UN1487 II OXIDIZER.............. B12, B78........ 152 212 240 5 kg....... 25 kg...... A...... 56, 58
....... Potassium nitrite............................................ 5.1 UN1488 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58
....... Potassium perchlorate, solid................................. 5.1 UN1489 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium perchlorate, solution.............................. 5.1 UN1489 II OXIDIZER.............. ................ 152 202 242 1 L........ 5 L........ A...... 56, 58, 106
....... Potassium permanganate....................................... 5.1 UN1490 II OXIDIZER.............. B12............. 152 212 240 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Potassium peroxide........................................... 5.1 UN1491 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Potassium persulfate......................................... 5.1 UN1492 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Potassium phosphide.......................................... 4.3 UN2012 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Potassium salts of aromatic nitro-derivatives, explosive..... 1.3C UN0158 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Potassium selenate, see Selenates or Selenites............... ........... .............. ...................... ................ ........... ........... .......
....... Potassium selenite, see Selenates or Selenites............... ........... .............. ...................... ................ ........... ........... .......
....... Potassium sodium alloys...................................... 4.3 UN1422 I DANGEROUS WHEN WET.... A19, B27, N34, None 211 244 Forbidden.. 15 kg...... D......
N40, T15, T26.
....... Potassium sulfide, anhydrous or Potassium sulfide with less 4.2 UN1382 II SPONTANEOUSLY A19, A20, B16, None 212 241 15 kg...... 50 kg...... A......
than 30 percent water of crystallization. COMBUSTIBLE. N34.
....... Potassium sulfide, hydrated with not less than 30 percent 8 UN1847 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 26
water of crystallization.
....... Potassium superoxide......................................... 5.1 UN2466 I OXIDIZER.............. A20............. None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Powder cake, wetted or Powder paste, wetted with not less 1.1C UN0433 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 17 percent alcohol by mass.
....... Powder cake, wetted or Powder paste, wetted with not less 1.3C UN0159 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 25 percent water, by mass.
....... Powder paste, see Powder cake, etc........................... ........... .............. ...................... ................ ........... ........... .......
....... Powder, smokeless............................................ 1.1C UN0160 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Powder, smokeless............................................ 1.3C UN0161 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Power device, explosive, see Cartridges, power device........ ........... .............. ...................... ................ ........... ........... .......
....... Primers, cap type............................................ 1.4S UN0044 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Primers, cap type............................................ 1.1B UN0377 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Primers, cap type............................................ 1.4B UN0378 II EXPLOSIVE 1.4B........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Primers, small arms, see Primers, cap type................... ........... .............. ...................... ................ ........... ........... .......
....... Primers, tubular............................................. 1.3G UN0319 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Primers, tubular............................................. 1.4G UN0320 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Primers, tubular............................................. 1.4S UN0376 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Printing ink, flammable...................................... 3 UN1210 I FLAMMABLE LIQUID...... T8, T31......... 150 173 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T7, T30......... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 173 242 60 L....... 220 L...... A......
....... Projectiles, illuminating, see Ammunition, illuminating, etc. ........... .............. ...................... ................ ........... ........... .......
....... Projectiles, inert with tracer............................... 1.4S UN0345 II EXPLOSIVE 1.4S........ ................ 62 None 25 kg...... 100 kg..... A...... 3E, 7E, 9E
....... Projectiles, inert, with tracer.............................. 1.3G UN0424 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, inert, with tracer.............................. 1.4G UN0425 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with burster or expelling charge................ 1.2D UN0346 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with burster or expelling charge................ 1.4D UN0347 II EXPLOSIVE 1.4D........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with burster or expelling charge................ 1.2F UN0426 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with burster or expelling charge................ 1.4F UN0427 II EXPLOSIVE 1.4F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with burster or expelling charge................ 1.2G UN0434 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with burster or expelling charge................ 1.4G UN0435 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with bursting charge............................ 1.1F UN0167 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with bursting charge............................ 1.1D UN0168 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with bursting charge............................ 1.2D UN0169 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with bursting charge............................ 1.2F UN0324 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with bursting charge............................ 1.4D UN0344 II EXPLOSIVE 1.4D........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Propadiene, inhibited........................................ 2.1 UN2200 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Propadiene mixed with methyl acetylene, see Methyl acetylene ........... .............. ...................... ................ ........... ........... .......
and propadiene mixtures, stabilized.
....... Propane or Propane mixtures see also Petroleum gases, 2.1 UN1978 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
liquefied.
....... Propanethiols................................................ 3 UN2402 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 95, 102
....... n-Propanol or Propyl alcohol normal.......................... 3 UN1274 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
D...... Propargyl alcohol............................................ 3 NA1986 II FLAMMABLE LIQUID, ................ None 202 243 Forbidden.. 1 L........ B...... 40
POISON.
D...... Propellant explosive, liquid................................. 1.1C NA0474 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
D...... Propellant explosive, liquid................................. 1.3C NA0477 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Propellant, liquid........................................... 1.3C UN0495 EXPLOSIVE 1.3C........ 37.............. None 62 None Forbidden.. Forbidden.. B......
....... Propellant, liquid........................................... 1.1C UN0497 EXPLOSIVE 1.1C........ 37.............. None 62 None Forbidden.. Forbidden.. B......
....... Propellant, solid............................................ 1.1C UN0498 EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Propellant, solid............................................ 1.3C UN0499 EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Propionaldehyde.............................................. 3 UN1275 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E......
....... Propionic acid............................................... 8 UN1848 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Propionic anhydride.......................................... 8 UN2496 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Propionitrile................................................ 3 UN2404 II FLAMMABLE LIQUID, T14............. None 202 243 Forbidden.. 60 L....... E...... 40
POISON.
....... Propionyl chloride........................................... 3 UN1815 II FLAMMABLE LIQUID, T8, T26......... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... n-Propyl acetate............................................. 3 UN1276 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Propyl alcohol, see Propanol................................. ........... .............. ...................... ................ ........... ........... .......
....... n-Propyl benzene............................................. 3 UN2364 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Propyl chloride.............................................. 3 UN1278 II FLAMMABLE LIQUID...... N34, T14........ None 202 242 Forbidden.. 60 L....... E......
....... n-Propyl chloroformate....................................... 6.1 UN2740 I POISON, FLAMMABLE 2, A3, A6, A7, None 227 244 Forbidden.. 2.5 L...... B...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B32,
B74, B77, N34,
T38, T43, T45.
....... Propyl formates.............................................. 3 UN1281 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... n-Propyl isocyanate.......................................... 6.1 UN2482 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B72, T38,
T43, T44.
....... Propyl mercaptan, see Propanethiols.......................... ........... .............. ...................... ................ ........... ........... .......
....... n-Propyl nitrate............................................. 3 UN1865 II FLAMMABLE LIQUID...... T25............. 150 202 None 5 L........ 60 L....... D......
....... Propylamine.................................................. 3 UN1277 II FLAMMABLE LIQUID, N34, T14........ None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE.
....... Propylene see also Petroleum gases, liquefied................ 2.1 UN1077 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Propylene chlorohydrin....................................... 6.1 UN2611 II POISON................ T9.............. None 202 243 5 L........ 60 L....... A...... 12, 40, 48
....... Propylene dichloride......................................... 3 UN1279 II FLAMMABLE LIQUID...... N36, T1......... 150 202 242 5 L........ 60 L....... B......
....... Propylene oxide.............................................. 3 UN1280 I FLAMMABLE LIQUID...... A3, N34, T20, None 201 243 1 L........ 30 L....... E...... 40
T29.
....... Propylene tetramer........................................... 3 UN2850 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,2-Propylenediamine......................................... 8 UN2258 II CORROSIVE, FLAMMABLE A3, A6, N34, T8. None 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Propyleneimine, inhibited.................................... 3 UN1921 I FLAMMABLE LIQUID...... A3, N34, T25.... None 201 243 1 L........ 30 L....... B...... 40
....... Propyltrichlorosilane........................................ 8 UN1816 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... Prussic acid, see Hydrogen cyanide........................... ........... .............. ...................... ................ ........... ........... .......
....... Pyridine..................................................... 3 UN1282 II FLAMMABLE LIQUID...... T8.............. None 202 242 5 L........ 60 L....... B...... 21, 100
....... Pyridine perchlorate......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Pyrophoric liquid, inorganic, n.o.s.......................... 4.2 UN3194 I SPONTANEOUSLY ................ None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Pyrophoric liquids, organic, n.o.s........................... 4.2 UN2845 I SPONTANEOUSLY B11, T42........ None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s....... 4.2 UN1383 I SPONTANEOUSLY B11............. None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric organometallic compound, n.o.s.................... 4.2 UN3203 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric solid, inorganic, n.o.s........................... 4.2 UN3200 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric solids, organic, n.o.s............................ 4.2 UN2846 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrosulfuryl chloride........................................ 8 UN1817 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 40
....... Pyroxylin solution or solvent, see Nitrocellulose............ ........... .............. ...................... ................ ........... ........... .......
....... Pyrrolidine.................................................. 3 UN1922 II FLAMMABLE LIQUID, T1.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Quebrachitol pentanitrate.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Quicklime, see Calcium oxide................................. ........... .............. ...................... ................ ........... ........... .......
....... Quinoline.................................................... 6.1 UN2656 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 12
....... R 114, see Dichlorotetrafluoroethane......................... ........... .............. ...................... ................ ........... ........... .......
....... R 115, see Chloropentafluoroethane........................... ........... .............. ...................... ................ ........... ........... .......
....... R 116, see Hexafluoroethane.................................. ........... .............. ...................... ................ ........... ........... .......
....... R 124, see Chlorotetrafluoroethane........................... ........... .............. ...................... ................ ........... ........... .......
....... R 133a, see Chlorotrifluoroethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 152a, see Difluoroethane................................... ........... .............. ...................... ................ ........... ........... .......
....... R 500, see Dichlorodifluoromethane and difluorethane, etc.... ........... .............. ...................... ................ ........... ........... .......
....... R 502, see Chlorodifluoromethane and chloropentafluoroethane ........... .............. ...................... ................ ........... ........... .......
mixture, etc..
....... R 503, see Chlorotrifluoromethane and trifluoromethane, etc.. ........... .............. ...................... ................ ........... ........... .......
....... R 12, see Dichlorodifluoromethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 12B1, see Chlorodifluorobromomethane....................... ........... .............. ...................... ................ ........... ........... .......
....... R 13, see Chlorotrifluoromethane............................. ........... .............. ...................... ................ ........... ........... .......
....... R 13B1, see Bromotrifluoromethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 14, see Tetrafluoromethane................................. ........... .............. ...................... ................ ........... ........... .......
....... R 21, see Dichlorofluoromethane.............................. ........... .............. ...................... ................ ........... ........... .......
....... R 22, see Chlorodifluoromethane.............................. ........... .............. ...................... ................ ........... ........... .......
....... Radioactive material, excepted package-articles manufactured 7 UN2910 None.................. ................ 421-1, 424 421-1, 421-1, ........... ........... A......
from natural or depleted uranium or natural thorium. 424 424
....... Radioactive material, excepted package-empty packaging....... 7 UN2910 EMPTY................. ................ 427 427 427 ........... ........... A......
....... Radioactive material, excepted package-instruments or 7 UN2910 None.................. ................ 421-1, 422 421-1, 421-1, ........... ........... A......
articles. 422 422
....... Radioactive material, excepted package-limited quantity of 7 UN2910 None.................. ................ 421, 421-1 421, 421- 421, 421- ........... ........... A......
material. 1 1
....... Radioactive material, fissile, n.o.s......................... 7 UN2918 RADIOACTIVE........... ................ 453 417 417 ........... ........... A...... 40, 95
....... Radioactive material, low specific activity, n.o.s. or 7 UN2912 RADIOACTIVE........... ................ 421, 422, 425 425 ........... ........... A......
Radioactive material, LSA, n.o.s.. 424
....... Radioactive material, n.o.s.................................. 7 UN2982 RADIOACTIVE........... ................ 421, 422, 415, 416 415, 416 ........... ........... A...... 40, 95
424
....... Radioactive material, special form, n.o.s.................... 7 UN2974 RADIOACTIVE........... ................ 421, 422 415, 416 415, 416 ........... ........... A......
....... Railway torpedo, see Signals, railway track, explosive....... ........... .............. ...................... ................ ........... ........... .......
....... Rare gases and nitrogen mixtures............................. 2.2 UN1981 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Rare gases and oxygen mixtures............................... 2.2 UN1980 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Rare gases, mixtures......................................... 2.2 UN1979 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... RC 318, see Octafluorocyclobutane............................ ........... .............. ...................... ................ ........... ........... .......
....... RDX and cyclotetramethylenetetranitramine, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized.
....... RDX and HMX mixtures, wetted with not less than 15 percent 1.1D UN0391 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water by mass or RDX and HMX mixtures, desensitized with not
less than 10 percent phlegmatizer by mass.
....... RDX and Octogen mixtures, wetted or desensitized see RDX and ........... .............. ...................... ................ ........... ........... .......
HMX mixtures, wetted or desensitized etc..
....... RDX, see Cyclotrimethylene trinitramine, etc................. ........... .............. ...................... ................ ........... ........... .......
....... Receptacles, small, containing gas flammable, without release 2.1 UN2037 FLAMMABLE GAS......... ................ 306 304 None 1 kg....... 15 kg...... B...... 40
device, not refillable and not exceeding 1 L capacity.
....... Receptacles, small, containing gas non-flammable, without 2.2 UN2037 NONFLAMMABLE GAS...... ................ 306 304 None 1 kg....... 15 kg...... B...... 40
release device, not refillable and not exceeding 1 L
capacity.
....... Red phosphorus, see Phosphorus, amorphous.................... ........... .............. ...................... ................ ........... ........... .......
....... Refrigerant gases, n.o.s..................................... 2.2 UN1078 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Refrigerant gases, n.o.s. or Dispersant gases, n.o.s......... 2.1 NA1954 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
D...... Refrigerating machine........................................ 3 NA1993 III FLAMMABLE LIQUID...... ................ 174 174 None 10 L....... 10 L....... A......
D...... Refrigerating machines, containing flammable, non-poisonous, 2.1 NA1954 FLAMMABLE GAS......... ................ 306 306 306 Forbidden.. 25 kg...... C...... 40
liquefied gas.
....... Refrigerating machines, containing non-flammable, non-toxic, 2.2 UN2857 NONFLAMMABLE GAS...... ................ 306, 307 306 306, 307 Forbidden.. 450 kg..... A......
liquefied gas or ammonia solutions (UN2073).
D...... Regulated medical waste...................................... 6.2 NA9275 II INFECTIOUS SUBSTANCE.. ................ 197 197 None Forbidden.. Forbidden.. E......
....... Release devices, explosive................................... 1.4S UN0173 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Resin solution, flammable.................................... 3 UN1866 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
....... Resorcinol................................................... 6.1 UN2876 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Rifle grenade, see Grenades, hand or rifle, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Rifle powder, see Powder, smokeless (UN 0160)................ ........... .............. ...................... ................ ........... ........... .......
....... Rivets, explosive............................................ 1.4S UN0174 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Road asphalt or tar liquid, see Tars, liquid, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Rocket motors................................................ 1.3C UN0186 II EXPLOSIVE 1.3C........ 109............. None 62 None Forbidden.. 220 kg..... B......
....... Rocket motors................................................ 1.1C UN0280 II EXPLOSIVE 1.1C........ 109............. None 62 None Forbidden.. Forbidden.. B......
....... Rocket motors................................................ 1.2C UN0281 II EXPLOSIVE 1.2C........ 109............. None 62 None Forbidden.. Forbidden.. B......
....... Rocket motors, liquid fueled................................. 1.2J UN0395 II EXPLOSIVE 1.2J........ 109............. None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rocket motors, liquid fueled................................. 1.3J UN0396 II EXPLOSIVE 1.3J........ 109............. None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rocket motors with hypergolic liquids with or without an 1.3L UN0250 II EXPLOSIVE 1.3L........ 109............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
expelling charge. 11E, 17E
....... Rocket motors with hypergolic liquids with or without an 1.2L UN0322 II EXPLOSIVE 1.2L........ 109............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
expelling charge. 11E, 17E
....... Rockets, line-throwing....................................... 1.2G UN0238 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, line-throwing....................................... 1.3G UN0240 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Rockets, line-throwing....................................... 1.4G UN0453 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Rockets, liquid fueled with bursting charge.................. 1.1J UN0397 II EXPLOSIVE 1.1J........ ................ None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rockets, liquid fueled with bursting charge.................. 1.2J UN0398 II EXPLOSIVE 1.2J........ ................ None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rockets, with bursting charge................................ 1.1F UN0180 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Rockets, with bursting charge................................ 1.1E UN0181 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with bursting charge................................ 1.2E UN0182 II EXPLOSIVE 1.2E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with bursting charge................................ 1.2F UN0295 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Rockets, with expelling charge............................... 1.2C UN0436 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with expelling charge............................... 1.3C UN0437 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with expelling charge............................... 1.4C UN0438 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Rockets, with inert head..................................... 1.3C UN0183 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rosin oil.................................................... 3 UN1286 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Rubber solution.............................................. 3 UN1287 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Rubidium..................................................... 4.3 UN1423 I DANGEROUS WHEN WET.... 22, A7, A19, None 211 242 Forbidden.. 15 kg...... D......
N34, N40, N45.
....... Rubidium hydroxide........................................... 8 UN2678 II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... A......
....... Rubidium hydroxide solution.................................. 8 UN2677 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Safety fuse, see Fuse, safety................................ ........... .............. ...................... ................ ........... ........... .......
....... Samples, explosive, other than initiating explosives......... ........... UN0190 II ...................... 113............. None 62 None Forbidden.. Forbidden.. E...... 12E
....... Sand acid, see Fluorosilicic acid............................ ........... .............. ...................... ................ ........... ........... .......
....... Seed cake, containing vegetable oil solvent extractions and 4.2 UN1386 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. A...... 13
expelled seeds, with not more than 10 percent of oil and
when the amount of moisture is higher than 11 percent, with
not more than 20 percent of oil and moisture combined..
I...... Seed cake with more than 1.5 percent oil and not more than 11 4.2 UN1386 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. E...... 13
percent moisture.
I...... Seed cake with not more than 1.5 percent oil and not more 4.2 UN2217 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. A...... 13
than 11 percent moisture.
....... Selenates or Selenites....................................... 6.1 UN2630 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Selenic acid................................................. 8 UN1905 I CORROSIVE............. N34............. None 211 242 Forbidden.. 25 kg...... A......
....... Selenites, see Selenates or Selenites........................ ........... .............. ...................... ................ ........... ........... .......
....... Selenium compound, n.o.s..................................... 6.1 UN3283 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Selenium disulfide........................................... 6.1 UN2657 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Selenium hexafluoride........................................ 2.3 UN2194 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Selenium nitride............................................. Forbidden .............. ...................... ................ ........... ........... .......
D...... Selenium oxide............................................... 6.1 NA2811 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
....... Selenium oxychloride......................................... 8 UN2879 I CORROSIVE, POISON..... A3, A6, A7, N34, None 201 243 0.5 L...... 2.5 L...... E...... 40
T12, T27.
....... Selenium powder.............................................. 6.1 UN2658 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Self-heating liquid, corrosive, inorganic, n.o.s............. 4.2 UN3188 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating liquid, corrosive, organic, n.o.s............... 4.2 UN3185 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating liquid, inorganic, n.o.s........................ 4.2 UN3186 II SPONTANEOUSLY ................ None 202 242 1 L........ 5 L........ C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE.
....... Self-heating liquid, organic, n.o.s.......................... 4.2 UN3183 II SPONTANEOUSLY ................ None 202 242 1 L........ 5 L........ C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE.
....... Self-heating liquid, toxic, inorganic, n.o.s................. 4.2 UN3187 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating liquid, toxic, organic, n.o.s................... 4.2 UN3184 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating solid, corrosive, inorganic, n.o.s.............. 4.2 UN3192 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C.....
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating, solid, corrosive, organic, n.o.s............... 4.2 UN3126 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating solid, inorganic, n.o.s......................... 4.2 UN3190 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Self-heating, solid, organic, n.o.s.......................... 4.2 UN3088 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Self-heating, solid, oxidizing, n.o.s........................ 4.2 UN3127 SPONTANEOUSLY ................ None 214 214 Forbidden.. Forbidden.. .......
COMBUSTIBLE, OXIDIZER.
....... Self-heating solid, toxic, inorganic, n.o.s.................. 4.2 UN3191 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating, solid, toxic, organic, n.o.s................... 4.2 UN3128 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-propelled vehicle, see Vehicles, self-propelled......... ........... .............. ...................... ................ ........... ........... .......
....... Self-reactive liquid type B.................................. 4.1 UN3221 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 61
....... Self-reactive liquid type B, temperature controlled.......... 4.1 UN3231 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type C.................................. 4.1 UN3223 II FLAMMABLE SOLID....... ................ None 224 None 5 L........ 10 L....... D...... 61
....... Self-reactive liquid type C, temperature controlled.......... 4.1 UN3233 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type D.................................. 4.1 UN3225 II FLAMMABLE SOLID....... ................ None 224 None 5 L........ 10 L....... D...... 61
....... Self-reactive liquid type D, temperature controlled.......... 4.1 UN3235 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type E.................................. 4.1 UN3227 II FLAMMABLE SOLID....... ................ None 224 None 10 L....... 25 L....... D...... 61
....... Self-reactive liquid type E, temperature controlled.......... 4.1 UN3237 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type F.................................. 4.1 UN3229 II FLAMMABLE SOLID....... ................ None 224 None 10 L....... 25 L....... D...... 61
....... Self-reactive liquid type F, temperature controlled.......... 4.1 UN3239 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type B................................... 4.1 UN3222 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 61
....... Self-reactive solid type B, temperature controlled........... 4.1 UN3232 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type C................................... 4.1 UN3224 II FLAMMABLE SOLID....... ................ None 224 None 5 kg....... 10 kg...... D...... 61
....... Self-reactive solid type C, temperature controlled........... 4.1 UN3234 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type D................................... 4.1 UN3226 II FLAMMABLE SOLID....... ................ None 224 None 5 kg....... 10 kg..... D...... 61
....... Self-reactive solid type D, temperature controlled........... 4.1 UN3236 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type E................................... 4.1 UN3228 II FLAMMABLE SOLID....... ................ None 224 None 10 kg...... 25 kg...... D...... 61
....... Self-reactive solid type E, temperature controlled........... 4.1 UN3238 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type F................................... 4.1 UN3230 II FLAMMABLE SOLID....... ................ None 224 None 10 kg...... 25 kg...... D...... 61
....... Self-reactive solid type F, temperature controlled........... 4.1 UN3240 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Shale oil.................................................... 3 UN1288 I FLAMMABLE LIQUID...... T7.............. None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Shaped charges, commercial, see Charges, shaped, commercial ........... .............. ...................... ................ ........... ........... .......
etc..
....... Signal devices, hand......................................... 1.4G UN0191 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signal devices, hand......................................... 1.4S UN0373 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Signals, distress, ship...................................... 1.1G UN0194 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, distress, ship...................................... 1.3G UN0195 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Signals, highway, see Signal devices, hand; Fireworks, type D ........... .............. ...................... ................ ........... ........... .......
....... Signals, railway track, explosive............................ 1.1G UN0192 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, railway track, explosive............................ 1.4S UN0193 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Signals, railway track, explosive............................ 1.3G UN0492 EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Signals, railway track, explosive............................ 1.4G UN0493 EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signals, ship distress, water-activated, see Contrivances, ........... .............. ...................... ................ ........... ........... .......
water-activated, etc..
....... Signals, smoke............................................... 1.1G UN0196 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, smoke............................................... 1.4G UN0197 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signals, smoke............................................... 1.2G UN0313 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, smoke............................................... 1.3G UN0487 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Silane....................................................... 2.1 UN2203 FLAMMABLE GAS......... ................ None 302 None Forbidden.. Forbidden.. E...... 40, 57, 104
....... Silicofluoric acid, see Fluorosilicic acid................... ........... .............. ...................... ................ ........... ........... .......
....... Silicon chloride, see Silicon tetrachloride.................. ........... .............. ...................... ................ ........... ........... .......
....... Silicon powder, amorphous.................................... 4.1 UN1346 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
....... Silicon tetrachloride........................................ 8 UN1818 II CORROSIVE............. A3, A6, B2, B6, 154 202 242 1 L........ 30 L....... C...... 40
T18, T26, T29.
....... Silicon tetrafluoride........................................ 2.3 UN1859 POISON GAS, CORROSIVE. 2, 25........... None 302 None Forbidden.. 25 kg...... D...... 40
....... Silver acetylide (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver arsenite.............................................. 6.1 UN1683 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Silver azide (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver chlorite (dry)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Silver cyanide............................................... 6.1 UN1684 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26, 40
....... Silver fulminate (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver nitrate............................................... 5.1 UN1493 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A......
....... Silver oxalate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver picrate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver picrate, wetted with not less than 30 percent water, 4.1 UN1347 I FLAMMABLE SOLID....... ................ None 211 None Forbidden.. Forbidden.. D...... 28, 36
by mass.
....... Sludge, acid................................................. 8 UN1906 II CORROSIVE............. A3, A7, B2, N34, None 202 242 Forbidden.. 30 L....... C...... 14
T9, T27.
D...... Smokeless powder for small arms (100 pounds or less)......... 4.1 NA3178 I FLAMMABLE SOLID....... 16.............. None 171 None Forbidden.. Forbidden.. A......
....... Soda lime with more than 4 percent sodium hydroxide.......... 8 UN1907 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Sodium....................................................... 4.3 UN1428 I DANGEROUS WHEN WET.... A7, A8, A19, None 211 244 1 kg....... 15 kg...... D......
A20, B9, B28,
B48, B68, N34,
T15, T29, T46.
....... Sodium aluminate, solid...................................... 8 UN2812 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Sodium aluminate, solution................................... 8 UN1819 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Sodium aluminum hydride...................................... 4.3 UN2835 II DANGEROUS WHEN WET.... A8, A19, A20.... None 212 242 Forbidden.. 50 kg...... E......
....... Sodium ammonium vanadate..................................... 6.1 UN2863 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium arsanilate............................................ 6.1 UN2473 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Sodium arsenate.............................................. 6.1 UN1685 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium arsenite, aqueous solutions........................... 6.1 UN1686 II POISON................ T15............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T15............. 153 203 241 60 L....... 220 L...... A......
....... Sodium arsenite, solid....................................... 6.1 UN2027 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium azide................................................. 6.1 UN1687 II POISON................ B28............. None 212 242 25 kg...... 100 kg..... A...... 36, 52, 91
....... Sodium bifluoride, see Sodium hydrogen fluoride.............. ........... .............. ...................... ................ ........... ........... .......
....... Sodium bisulfate, solution, see Sodium hydrogen sulfate, ........... .............. ...................... ................ ........... ........... .......
solution.
....... Sodium bisulfite, solution, see Bisulfites, inorganic, ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Sodium borohydride........................................... 4.3 UN1426 I DANGEROUS WHEN WET.... N40............. None 211 242 Forbidden.. 15 kg...... E......
....... Sodium bromate............................................... 5.1 UN1494 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium cacodylate............................................ 6.1 UN1688 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Sodium chlorate.............................................. 5.1 UN1495 II OXIDIZER.............. A9, N34, T8..... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium chlorate, aqueous solution............................ 5.1 UN2428 II OXIDIZER.............. A2, B6, T8...... 152 202 241 1 L........ 5 L........ B...... 56, 58, 106
....... Sodium chlorate mixed with dinitrotoluene, see Explosive ........... .............. ...................... ................ ........... ........... .......
blasting, type C.
....... Sodium chlorite.............................................. 5.1 UN1496 II OXIDIZER.............. A9, N34, T8..... None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium chloroacetate......................................... 6.1 UN2659 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Sodium cuprocyanide, solid................................... 6.1 UN2316 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 26
....... Sodium cuprocyanide, solution................................ 6.1 UN2317 I POISON................ T8, T26......... None 201 243 1 L........ 30 L....... B...... 26, 40
....... Sodium cyanide............................................... 6.1 UN1689 I POISON................ B69, B77, N74, None 211 242 5 kg....... 50 kg...... B...... 52
N75, T42.
....... Sodium dichloroisocyanurate or Sodium dichloro-s- ........... .............. ...................... ................ ........... ........... .......
triazinetrione, see Dichloroisocyanuric acid etc..
....... Sodium dinitro-o-cresolate, dry or wetted with less than 15 1.3C UN0234 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Sodium dinitro-o-cresolate, wetted with not less than 15 4.1 UN1348 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
percent water, by mass. POISON. A20, N41.
....... Sodium dithionite or Sodium hydrosulfite..................... 4.2 UN1384 II SPONTANEOUSLY A19, A20........ None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Sodium fluoride.............................................. 6.1 UN1690 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 26
....... Sodium fluoroacetate......................................... 6.1 UN2629 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Sodium fluorosilicate........................................ 6.1 UN2674 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Sodium hydrate, see Sodium hydroxide, solid.................. ........... .............. ...................... ................ ........... ........... .......
....... Sodium hydride............................................... 4.3 UN1427 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Sodium hydrogendifluoride.................................... 8 UN2439 II CORROSIVE............. N3, N34......... 154 212 240 15 kg...... 50 kg...... A...... 12, 25, 26,
40
....... Sodium hydrogendifluoride solution........................... 8 UN2439 II CORROSIVE............. N3, N34......... 154 202 242 1 L........ 30 L....... A...... 12, 25, 26,
40
D...... Sodium hydrosulfide, solution................................ 8 NA2922 II CORROSIVE, POISON..... B2.............. 154 202 243 1 L........ 30 L....... B...... 40, 95
....... Sodium hydrosulfide, with less than 25 percent water of 4.2 UN2318 II SPONTANEOUSLY A7, A19, A20.... None 212 241 15 kg...... 50 kg...... A......
crystallization. COMBUSTIBLE.
....... Sodium hydrosulfide with not less than 25 percent water of 8 UN2949 II CORROSIVE............. A7.............. 154 212 240 15 kg...... 50 kg...... A...... 26
crystallization.
....... Sodium hydrosulfite, see Sodium dithionite................... ........... .............. ...................... ................ ........... ........... .......
....... Sodium hydroxide, solid...................................... 8 UN1823 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Sodium hydroxide solution.................................... 8 UN1824 II CORROSIVE............. B2, N34, T8..... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. N34, T7......... 154 203 241 5 L........ 60 L....... A......
....... Sodium hypochlorite, solution, see Hypochlorite solutions ........... .............. ...................... ................ ........... ........... .......
etc..
....... Sodium metal, liquid alloy, see Alkali metal alloys, liquid, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Sodium methylate............................................. 4.2 UN1431 II SPONTANEOUSLY A19............. None 212 242 15 kg...... 50 kg...... B......
COMBUSTIBLE,
CORROSIVE.
....... Sodium methylate solutions in alcohol........................ 3 UN1289 II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 5 L........ B......
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T7, T30..... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Sodium monoxide.............................................. 8 UN1825 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Sodium nitrate............................................... 5.1 UN1498 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Sodium nitrate and potassium nitrate mixtures................ 5.1 UN1499 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Sodium nitrite............................................... 5.1 UN1500 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58
....... Sodium pentachlorophenate.................................... 6.1 UN2567 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium percarbonate.......................................... 5.1 UN2467 III OXIDIZER.............. 27, A1, A29..... 152 213 240 25 kg...... 100 kg..... A...... 13
....... Sodium perchlorate........................................... 5.1 UN1502 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium permanganate.......................................... 5.1 UN1503 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Sodium peroxide.............................................. 5.1 UN1504 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Sodium peroxoborate, anhydrous............................... 5.1 UN3247 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13, 25, 106
....... Sodium persulfate............................................ 5.1 UN1505 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Sodium phosphide............................................. 4.3 UN1432 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Sodium picramate, dry or wetted with less than 20 percent 1.3C UN0235 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Sodium picramate, wetted with not less than 20 percent water, 4.1 UN1349 I FLAMMABLE SOLID....... 23, A8, A19, N41 None 211 None Forbidden.. 15 kg...... E...... 28, 36
by mass.
....... Sodium picryl peroxide....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sodium potassium alloys, see Potassium sodium alloys......... ........... .............. ...................... ................ ........... ........... .......
....... Sodium salts of aromatic nitro-derivatives, n.o.s. explosive. 1.3C UN0203 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Sodium selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
D...... Sodium selenite.............................................. 6.1 NA2630 II POISON................ ................ None 212 242 25 kg...... 100 kg..... E......
....... Sodium sulfide, anhydrous or Sodium sulfide with less than 30 4.2 UN1385 II SPONTANEOUSLY A19, A20, N34... None 212 241 15 kg...... 50 kg...... A......
percent water of crystallization. COMBUSTIBLE.
....... Sodium sulfide, hydrated with at least 30 percent water...... 8 UN1849 II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... A...... 26
....... Sodium superoxide............................................ 5.1 UN2547 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... E...... 13, 75, 106
....... Sodium tetranitride.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Solids containing corrosive liquid, n.o.s.................... 8 UN3244 II CORROSIVE............. 49.............. 154 212 240 15 kg...... 50 kg...... B...... 40
....... Solids containing flammable liquid, n.o.s.................... 4.1 UN3175 II FLAMMABLE SOLID....... 47.............. 151 212 240 15 kg...... 50 kg...... B......
....... Solids containing toxic liquid, n.o.s........................ 6.1 UN3243 II POISON................ 48.............. None 212 240 25 kg...... 100 kg..... B...... 40
....... Sounding devices, explosive.................................. 1.2F UN0204 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Sounding devices, explosive.................................. 1.1F UN0296 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Sounding devices, explosive.................................. 1.1D UN0374 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Sounding devices, explosive.................................. 1.2D UN0375 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Spirits of salt, see Hydrochloric acid....................... ........... .............. ...................... ................ ........... ........... .......
....... Squibs, see Igniters etc..................................... ........... .............. ...................... ................ ........... ........... .......
....... Stannic chloride, anhydrous.................................. 8 UN1827 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C......
....... Stannic chloride, pentahydrate............................... 8 UN2440 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Stannic phosphide............................................ 4.3 UN1433 I DANGEROUS WHEN WET, A19, N40........ None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Steel swarf, see Ferrous metal borings, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Stibine...................................................... 2.3 UN2676 POISON GAS, FLAMMABLE 1............... None 304 None Forbidden.. Forbidden.. D...... 40
GAS.
....... Storage batteries, wet, see Batteries, wet etc............... ........... .............. ...................... ................ ........... ........... .......
....... Strontium arsenite........................................... 6.1 UN1691 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Strontium chlorate, solid.................................... 5.1 UN1506 II OXIDIZER.............. A1, A9, N34..... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Strontium chlorate, solution................................. 5.1 UN1506 II OXIDIZER.............. A1, A9, N34..... 152 202 242 1 L........ 5 L........ A...... 56, 58, 106
....... Strontium nitrate............................................ 5.1 UN1507 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Strontium perchlorate........................................ 5.1 UN1508 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Strontium peroxide........................................... 5.1 UN1509 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Strontium phosphide.......................................... 4.3 UN2013 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Strychnine or Strychnine salts............................... 6.1 UN1692 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
....... Styphnic acid, see Trinitroresorcinol, etc................... ........... .............. ...................... ................ ........... ........... .......
....... Styrene monomer, inhibited................................... 3 UN2055 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Substances, explosive, n.o.s................................. 1.1L UN0357 II EXPLOSIVE 1.1L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.2L UN0358 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.3L UN0359 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.1A UN0473 II EXPLOSIVE 1.1A........ 101, 111........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Substances, explosive, n.o.s................................. 1.1C UN0474 II EXPLOSIVE 1.1C........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.1D UN0475 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.1G UN0476 II EXPLOSIVE 1.1G........ 101............. None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Substances, explosive, n.o.s................................. 1.3C UN0477 II EXPLOSIVE 1.3C........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.3G UN0478 II EXPLOSIVE 1.3G........ 101............. None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Substances, explosive, n.o.s................................. 1.4C UN0479 II EXPLOSIVE 1.4C........ 101............. None 62 None Forbidden.. 75 kg...... A...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.4D UN0480 II EXPLOSIVE 1.4D........ 101............. None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Substances, explosive, n.o.s................................. 1.4S UN0481 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 75 kg...... A......
....... Substances, explosive, n.o.s................................. 1.4G UN0485 II EXPLOSIVE 1.4G........ 101............. None 62 None Forbidden.. 75 kg...... E...... 1E, 8E
....... Substances, explosive, very insensitive, n.o.s., or 1.5D UN0482 II EXPLOSIVE 1.5D........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Substances, EVI, n.o.s..
....... Substituted nitrophenol pesticides, liquid, flammable, toxic, 3 UN2780 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Substituted nitrophenol pesticides, liquid, toxic............ 6.1 UN3014 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Substituted nitrophenol pesticides, liquid, toxic, flammable 6.1 UN3013 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Substituted nitrophenol pesticides, solid, toxic............. 6.1 UN2779 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Sucrose octanitrate (dry).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sulfamic acid................................................ 8 UN2967 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
D...... Sulfur....................................................... 9 NA1350 III CLASS 9............... 30, A1.......... None None 240 25 kg...... 100 kg..... A...... 19, 74
I...... Sulfur....................................................... 4.1 UN1350 III FLAMMABLE SOLID....... A1, N20, T1..... 151 213 240 25 kg...... 100 kg..... A...... 19, 74
....... Sulfur and chlorate, loose mixtures of....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sulfur chlorides............................................. 8 UN1828 I CORROSIVE............. 5, A3, B10, B77, None 201 243 Forbidden.. 2.5 L...... C...... 40
N34.
....... Sulfur dichloride, see Sulfur chlorides...................... ........... .............. ...................... ................ ........... ........... .......
....... Sulfur dioxide, liquefied.................................... 2.3 UN1079 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Sulfur dioxide solution, see Sulfurous acid.................. ........... .............. ...................... ................ ........... ........... .......
....... Sulfur hexafluoride.......................................... 2.2 UN1080 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Sulfur, molten............................................... 9 NA2448 III CLASS 9............... T9, T38......... None 213 247 Forbidden.. Forbidden.. C...... 61
I...... Sulfur, molten............................................... 4.1 UN2448 III FLAMMABLE SOLID....... T9, T38......... None 213 247 Forbidden.. Forbidden.. C...... 61
....... Sulfur tetrafluoride......................................... 2.3 UN2418 POISON GAS, CORROSIVE. 1............... None 302 245 Forbidden.. 25 kg...... D...... 40
+...... Sulfur trioxide, inhibited................................... 8 UN1829 I CORROSIVE, POISON..... 2, A7, B9, B12, None 227 244 Forbidden.. 25 kg...... A...... 40
B14, B32, B49,
B74, B77, N34,
T38, T43, T45.
+, D... Sulfur trioxide, uninhibited................................. 8 NA1829 I CORROSIVE, POISON..... 2, A7, B9, B12, None 227 244 Forbidden.. 25 kg...... C...... 10, 40
B14, B32, B49,
B74, B77, N34,
T38, T43, T45.
....... Sulfuretted hydrogen, see Hydrogen sulfide, liquefied........ ........... .............. ...................... ................ ........... ........... .......
....... Sulfuric acid, fuming with less than 30 percent free sulfur 8 UN1831 I CORROSIVE............. A3, A7, B84, None 201 243 Forbidden.. 2.5 L...... C...... 14, 40
trioxide. N34, T18, T27.
+...... Sulfuric acid, fuming with 30 percent or more free sulfur 8 UN1831 I CORROSIVE, POISON..... 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. C...... 14, 40
trioxide. B9, B14, B32,
B74, B77, B84,
N34, T38, T43,
T45.
....... Sulfuric acid, spent......................................... 8 UN1832 II CORROSIVE............. A3, A7, B2, B83, None 202 242 Forbidden.. 30 L....... C...... 14
B84, N34, T9,
T27.
....... Sulfuric acid with more than 51 percent acid................. 8 UN1830 II CORROSIVE............. A3, A7, B3, B83, 154 202 242 1 L........ 30 L....... C...... 14
B84, N34, T9,
T27.
....... Sulfuric acid with not more than 51% acid, or Battery fluid, 8 UN2796 II CORROSIVE............. A3, A7, B2, B15, 154 202 242 1 L........ 30 L....... B......
acid. N6, N34, T9,
T27.
....... Sulfuric and hydrofluoric acid mixtures, see Hydrofluoric and ........... .............. ...................... ................ ........... ........... .......
sulfuric acid mixtures.
....... Sulfuric anhydride, see Sulfur trioxide, inhibited........... ........... .............. ...................... ................ ........... ........... .......
....... Sulfurous acid............................................... 8 UN1833 II CORROSIVE............. B3, T8.......... 154 202 242 1 L........ 30 L....... B...... 40
+...... Sulfuryl chloride............................................ 8 UN1834 I CORROSIVE, POISON..... 1, A3, B6, B9, None 226 244 Forbidden.. Forbidden.. C...... 40
B10, B14, B30,
B74, B77, N34,
T38, T43, T44.
....... Sulfuryl fluoride............................................ 2.3 UN2191 POISON GAS............ 4............... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Tars, liquid including road asphalt and oils, bitumen and cut 3 UN1999 II FLAMMABLE LIQUID...... B13, T7, T30.... 150 202 242 5 L........ 60 L....... B......
backs.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B13, T7, T30 150 203 242 60 L....... 220 L...... A......
....... Tear gas candles............................................. 6.1 UN1700 II POISON, FLAMMABLE ................ None 340 None Forbidden.. 50 kg...... D...... 40
SOLID.
....... Tear gas cartridges, see Ammunition, tear-producing, etc..... ........... .............. ...................... ................ ........... ........... .......
D...... Tear gas devices with more than 2 percent tear gas 6.1 NA1693 I POISON................ ................ None 340 None Forbidden.. Forbidden.. D...... 40
substances, by mass.
............................................................. ........... .............. II POISON................ ................ None 340 None Forbidden.. Forbidden.. D...... 40
....... Tear gas devices, with not more than 2 percent tear gas ........... .............. ...................... ................ ........... ........... .......
substances, by mass, see Aerosols, etc..
....... Tear gas grenades, see Tear gas candles...................... ........... .............. ...................... ................ ........... ........... .......
....... Tear gas substances, liquid, n.o.s........................... 6.1 UN1693 I POISON................ ................ None 201 None Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ ................ None 202 None Forbidden.. 5 L........ D...... 40
....... Tear gas substances, solid, n.o.s............................ 6.1 UN1693 I POISON................ ................ None 211 None Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ ................ None 212 None Forbidden.. 25 kg...... D...... 40
....... Tellurium compound, n.o.s.................................... 6.1 UN3284 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Tellurium hexafluoride....................................... 2.3 UN2195 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Terpene hydrocarbons, n.o.s.................................. 3 UN2319 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Terpinolene.................................................. 3 UN2541 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetraazido benzene quinone................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrabromoethane............................................. 6.1 UN2504 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Tetrachloroethane............................................ 6.1 UN1702 II POISON................ N36, T14........ None 202 243 5 L........ 60 L....... A...... 40
....... Tetrachloroethylene.......................................... 6.1 UN1897 III KEEP AWAY FROM FOOD... N36, T1......... 153 203 241 60 L....... 220 L...... A...... 40
....... Tetraethyl dithiopyrophosphate............................... 6.1 UN1704 II POISON................ ................ None 212 242 25 kg...... 100 kg..... D...... 40
D...... Tetraethyl lead, liquid...................................... 6.1 NA1649 I POISON, FLAMMABLE ................ None 201 None Forbidden.. Forbidden.. E...... 40
LIQUID.
D...... Tetraethyl pyrophosphate, liquid............................. 6.1 NA3018 I POISON................ ................ None 201 243 Forbidden.. 1 L........ A...... 40
D...... Tetraethyl pyrophosphate solid............................... 6.1 NA2783 I POISON................ N77............. None 211 242 Forbidden.. 50 kg...... A...... 40
....... Tetraethyl silicate.......................................... 3 UN1292 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetraethylammonium perchlorate (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetraethylenepentamine....................................... 8 UN2320 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... 1,1,1,2-Tetrafluoroethane.................................... 2.2 UN3159 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Tetrafluoroethylene, inhibited............................... 2.1 UN1081 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... E...... 40
....... Tetrafluoromethane, R14...................................... 2.2 UN1982 NONFLAMMABLE GAS...... ................ None 302 None 75 kg...... 150 kg..... A......
....... 1,2,3,6-Tetrahydrobenzaldehyde............................... 3 UN2498 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrahydrofuran.............................................. 3 UN2056 II FLAMMABLE LIQUID...... T8.............. None 202 242 5 L........ 60 L....... B......
....... Tetrahydrofurfurylamine...................................... 3 UN2943 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrahydrophthalic anhydrides with more than 0.05 percent of 8 UN2698 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
maleic anhydride.
....... 1,2,3,6-Tetrahydropyridine................................... 3 UN2410 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Tetrahydrothiophene.......................................... 3 UN2412 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Tetramethylammonium hydroxide................................ 8 UN1835 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
....... Tetramethylene diperoxide dicarbamide........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetramethylsilane............................................ 3 UN2749 I FLAMMABLE LIQUID...... T21, T26........ None 201 243 Forbidden.. 30 L....... D......
....... Tetranitro diglycerin........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetranitroaniline............................................ 1.1D UN0207 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
+...... Tetranitromethane............................................ 5.1 UN1510 I OXIDIZER, POISON...... 2, B9, B14, B32, None 227 None Forbidden.. Forbidden.. D...... 40, 66, 106
B74, T38, T43,
T45.
....... 2,3,4,6-Tetranitrophenol..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,4,6-Tetranitrophenyl methyl nitramine.................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,4,6-Tetranitrophenylnitramine............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetranitroresorcinol (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,5,6-Tetranitroso-1,4-dinitrobenzene...................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,5,6-Tetranitroso nitrobenzene (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrapropylorthotitanate..................................... 3 UN2413 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrazene, see Guanyl nitrosaminoguanyltetrazene............. ........... .............. ...................... ................ ........... ........... .......
....... Tetrazine (dry).............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrazol-1-acetic acid....................................... 1.4C UN0407 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Tetrazolyl azide (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetryl, see Trinitrophenylmethylnitramine.................... ........... .............. ...................... ................ ........... ........... .......
....... Thallium chlorate............................................ 5.1 UN2573 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Thallium compounds, n.o.s.................................... 6.1 UN1707 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Thallium nitrate............................................. 6.1 UN2727 II POISON, OXIDIZER...... ................ None 212 242 5 kg....... 25 kg...... A......
D...... Thallium sulfate, solid...................................... 6.1 NA1707 II POISON................ ................ None 212 242 5 kg....... 50 kg...... A......
....... 4-Thiapentanal............................................... 6.1 UN2785 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... D...... 25, 49
....... Thioacetic acid.............................................. 3 UN2436 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Thiocarbonylchloride, see Thiophosgene....................... ........... .............. ...................... ................ ........... ........... .......
....... Thioglycol................................................... 6.1 UN2966 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... Thioglycolic acid............................................ 8 UN1940 II CORROSIVE............. A7, B2, N34, T8. 154 202 242 1 L........ 30 L....... A......
....... Thiolactic acid.............................................. 6.1 UN2936 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... Thionyl chloride............................................. 8 UN1836 I CORROSIVE............. 25, A7, B6, B10, None 201 243 Forbidden.. Forbidden.. C...... 40
N34, T42.
....... Thiophene.................................................... 3 UN2414 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B...... 40
+...... Thiophosgene................................................. 6.1 UN2474 II POISON................ 2, A7, B9, B14, None 227 244 Forbidden.. 60 L....... B...... 26, 40
B32, B74, N33,
N34, T38, T43,
T45.
....... Thiophosphoryl chloride...................................... 8 UN1837 II CORROSIVE............. A3, A7, B2, B8, None 202 242 Forbidden.. 30 L....... C...... 40
B25, N34, T12.
....... Thorium metal, pyrophoric.................................... 7 UN2975 RADIOACTIVE, ................ None 418 None Forbidden.. Forbidden.. D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Thorium nitrate, solid....................................... 7 UN2976 RADIOACTIVE, OXIDIZER. ................ None 419 None Forbidden.. 15 kg...... A......
....... Tin chloride, fuming, see Stannic chloride, anhydrous........ ........... .............. ...................... ................ ........... ........... .......
....... Tin perchloride or Tin tetrachloride, see Stannic chloride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Tinctures, medicinal......................................... 3 UN1293 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Tinning flux, see Zinc chloride.............................. ........... .............. ...................... ................ ........... ........... .......
....... Titanium disulphide.......................................... 4.2 UN3174 III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... A......
COMBUSTIBLE.
....... Titanium hydride............................................. 4.1 UN1871 II FLAMMABLE SOLID....... A19, A20, N34... None 212 241 15 kg...... 50 kg...... E......
....... Titanium powder, dry......................................... 4.2 UN2546 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, N5, None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE. N34.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Titanium powder, wetted with not less than 25 percent water 4.1 UN1352 II FLAMMABLE SOLID....... A19, A20, N34... None 212 240 15 kg...... 50 kg...... E......
(a visible excess of water must be present) (a) mechanically
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Titanium sponge granules or Titanium sponge powders.......... 4.1 UN2878 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... D......
D...... Titanium sulfate solution.................................... 8 NA1760 II CORROSIVE............. B2, B15......... None 202 242 1 L........ 30 L....... B...... 40
+...... Titanium tetrachloride....................................... 8 UN1838 II CORROSIVE, POISON..... 2, A3, A6, B7, None 227 244 Forbidden.. 30 L....... C...... 40
B9, B14, B32,
B41, B74, B77,
N41, T38, T43,
T45.
....... Titanium trichloride mixtures................................ 8 UN2869 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A...... 40
............................................................. ........... .............. III CORROSIVE............. A7, N34......... 154 213 240 25 kg...... 100 kg..... A...... 40
....... Titanium trichloride, pyrophoric or Titanium trichloride 4.2 UN2441 I SPONTANEOUSLY A7, A8, A19, None 181 244 Forbidden.. Forbidden.. D...... 40
mixtures, pyrophoric. COMBUSTIBLE, A20, N34.
CORROSIVE.
....... TNT mixed with aluminum, see Tritonal........................ ........... .............. ...................... ................ ........... ........... .......
....... TNT, see Trinitrotoluene, etc................................ ........... .............. ...................... ................ ........... ........... .......
....... Toluene...................................................... 3 UN1294 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Toluene diisocyanate......................................... 6.1 UN2078 II POISON................ T14............. None 202 243 5 L........ 60 L....... D...... 25, 40
....... Toluene sulfonic acid, see Alkyl, Aryl or Toluene sulfonic ........... .............. ...................... ................ ........... ........... .......
acid etc..
....... Toluidines liquid............................................ 6.1 UN1708 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Toluidines solid............................................. 6.1 UN1708 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... 2,4-Toluylenediamine or 2,4-Toluenediamine................... 6.1 UN1709 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Torpedoes, liquid fueled, with inert head.................... 1.3J UN0450 II EXPLOSIVE 1.3J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Torpedoes, liquid fueled, with or without bursting charge.... 1.1J UN0449 II EXPLOSIVE 1.1J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Torpedoes with bursting charge............................... 1.1E UN0329 II EXPLOSIVE 1.1E........ ................ 62 None Forbidden.. Forbidden.. B......
....... Torpedoes with bursting charge............................... 1.1F UN0330 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. B......
....... Torpedoes with bursting charge............................... 1.1D UN0451 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Toxic liquid, corrosive, inorganic, n.o.s.................... 6.1 UN3289 I POISON, CORROSIVE..... ................ None 201 243 0.5 L...... 2.5 L...... A......
............................................................. ........... .............. II POISON, CORROSIVE..... T14............. None 202 243 1 L........ 30 L....... A......
....... Toxic liquid, corrosive, inorganic, n.o.s. Inhalation Hazard, 6.1 UN3289 I POISON, CORROSIVE..... 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. B...... 40
Packing Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquid, corrosive, inorganic, n.o.s. Inhalation Hazard, 6.1 UN3289 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
Packing Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquid, inorganic, n.o.s............................... 6.1 UN3287 I POISON................ ................ None 201 243 1 L........ 30 L....... A......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Toxic liquid, inorganic, n.o.s. Inhalation Hazard, Packing 6.1 UN3287 I POISON................ 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. B...... 40
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquid, inorganic, n.o.s. Inhalation Hazard, Packing 6.1 UN3287 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, corrosive, organic, n.o.s..................... 6.1 UN2927 I POISON, CORROSIVE..... T42............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II POISON, CORROSIVE..... ................ None 202 243 1 L........ 30 L....... B...... 40
....... Toxic liquids, corrosive, organic, n.o.s., inhalation hazard, 6.1 UN2927 I POISON, CORROSIVE..... 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquids, corrosive, organic, n.o.s., inhalation hazard, 6.1 UN2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, flammable, organic, n.o.s..................... 6.1 UN2929 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T15............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Toxic liquids, flammable, organic, n.o.s., inhalation hazard, 6.1 UN2929 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone A. LIQUID. B72, T38, T43,
T44.
....... Toxic liquids, flammable, organic, n.o.s., inhalation hazard, 6.1 UN2929 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone B. LIQUID. B74, T38, T43,
T45.
....... Toxic, liquids, organic, n.o.s............................... 6.1 UN2810 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing 6.1 UN2810 I POISON................ 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing 6.1 UN2810 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, oxidizing, n.o.s.............................. 6.1 UN3122 I POISON, OXIDIZER...... A4.............. None 201 243 Forbidden.. 2.5 L...... C......
............................................................. ........... .............. II POISON, OXIDIZER...... ................ None 202 243 1 L........ 5 L........ C......
....... Toxic liquids, oxidizing, n.o.s. Inhalation hazard, Packing 6.1 UN3122 I POISON, OXIDIZER...... 1, B9, B14, B30, None 226 244 Forbidden.. 2.5 L...... C......
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquids, oxidizing, n.o.s. Inhalation Hazard, Packing 6.1 UN3122 I POISON, OXIDIZER...... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. C......
Group I, Zone B. T38, T43, T45.
....... Toxic liquids, water-reative, n.o.s.......................... 6.1 UN3123 I POISON, DANGEROUS WHEN A4.............. one 201 243 Forbidden.. 1 L........ E...... 40
WET.
............................................................. ........... .............. II POISON, DANGEROUS WHEN ................ None 202 243 1 L........ 5 L........ E...... 40
WET.
....... Toxic liquids, water-reative, n.o.s. Inhalation hazard, 6.1 UN3123 I POISON, DANGEROUS WHEN 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. E...... 40
packing group I, Zone A. WET. B72, T38, T43,
T44.
....... Toxic liquids, water-reative, n.o.s. Inhalation hazard, 6.1 UN3123 I POISON, DANGEROUS WHEN 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. E...... 40
packing group I, Zone B. WET. B74, T38, T43,
T45.
....... Toxic solid, corrosive, inorganic, n.o.s..................... 6.1 UN3290 I POISON, CORROSIVE..... ................ None 211 242 1 kg....... 25 kg...... A......
............................................................. ........... .............. II POISON, CORROSIVE..... ................ None 212 242 15 kg...... 50 kg...... A......
....... Toxic solid, inorganic, n.o.s................................ 6.1 UN3288 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Toxic solids, corrosive, organic, n.o.s...................... 6.1 UN2928 I POISON, CORROSIVE..... ................ None 211 242 1 kg....... 25 kg...... B...... 40
............................................................. ........... .............. II POISON, CORROSIVE..... ................ None 212 242 15 kg...... 50 kg...... B...... 40
....... Toxic solids, flammable, organic, n.o.s...................... 6.1 UN2930 I POISON, FLAMMABLE ................ None 211 242 1 kg....... 15 kg...... B......
SOLID.
............................................................. ........... .............. II POISON, FLAMMABLE ................ None 212 242 15 kg...... 50 kg...... B......
SOLID.
....... Toxic solids, organic, n.o.s................................. 6.1 UN2811 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Toxic solids, oxidizing, n.o.s............................... 6.1 UN3086 I POISON, OXIDIZER...... ................ None 211 242 1 kg....... 15 kg...... C......
............................................................. ........... .............. II POISON, OXIDIZER...... ................ None 212 242 15 kg...... 50 kg...... C......
....... Toxic solids, self heating, n.o.s............................ 6.1 UN3124 I POISON, SPONTANEOUSLY A5.............. None 211 242 5 kg....... 15 kg...... D...... 40
COMBUSTIBLE.
............................................................. ........... .............. II POISON, SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... D...... 40
COMBUSTIBLE.
....... Toxic solids, water-reative, n.o.s........................... 6.1 UN3125 I POISON, DANGEROUS WHEN A5.............. None 211 242 5 kg....... 15 kg...... D...... 40
WET.
............................................................. ........... .............. II POISON, DANGEROUS WHEN ................ None 212 242 15 kg...... 50 kg...... D...... 40
WET.
D...... Toy Caps..................................................... 1.4S NA0337 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A...... 9E
....... Tracers for ammunition....................................... 1.3G UN0212 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Tracers for ammunition....................................... 1.4G UN0306 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Tractors, see Vehicles, self propelled....................... ........... .............. ...................... ................ ........... ........... .......
....... Tri-(b-nitroxyethyl) ammonium nitrate........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Triallyl borate.............................................. 6.1 UN2609 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 13
....... Triallylamine................................................ 3 UN2610 III FLAMMABLE LIQUID, B1, T1.......... None 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Triazine pesticides, liquid, flammable, toxic, flash point 3 UN2764 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Triazine pesticides, liquid, toxic........................... 6.1 UN2998 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Triazine pesticides, liquid, toxic, flammable, flashpoint not 6.1 UN2997 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Triazine pesticides, solid, toxic............................ 6.1 UN2763 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Tributylamine................................................ 8 UN2542 III CORROSIVE............. T2.............. None 203 241 5 L........ 60 L....... A......
....... Tributylphosphane............................................ 4.2 UN3254 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
D...... mono-(Trichloro) tetra-(monopotassium dichloro)-penta-s- 5.1 NA2468 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13
triazinetrione, dry (with more than 39 percent available
chlorine).
....... Trichloro-s-triazinetrione dry, with more than 39 percent ........... .............. ...................... ................ ........... ........... .......
available chlorine, see Trichloroisocyanuric acid, dry.
....... Trichloroacetic acid......................................... 8 UN1839 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Trichloroacetic acid, solution............................... 8 UN2564 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... B......
N34, T8.
............................................................. ........... .............. III CORROSIVE............. A3, A6, A7, N34, 154 203 241 5 L........ 60 L....... B...... 8
T7.
+...... Trichloroacetyl chloride..................................... 8 UN2442 II CORROSIVE, POISON..... 1, A3, A7, B9, None 226 244 Forbidden.. Forbidden.. D...... 40
B14, B30, B72,
N34, T38, T43,
T44.
....... Trichlorobenzenes, liquid.................................... 6.1 UN2321 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Trichlorobutene.............................................. 6.1 UN2322 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 25, 40
....... 1,1,1-Trichloroethane........................................ 6.1 UN2831 III KEEP AWAY FROM FOOD... N36, T7......... 153 203 241 60 L....... 220 L...... A...... 40
....... Trichloroethylene............................................ 6.1 UN1710 III KEEP AWAY FROM FOOD... N36, T1......... 153 203 241 60 L....... 220 L...... A...... 40
....... Trichloroisocyanuric acid, dry............................... 5.1 UN2468 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13
....... Trichloromethyl perchlorate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trichlorosilane.............................................. 4.3 UN1295 I DANGEROUS WHEN WET, A7, N34, T24, None 201 244 Forbidden.. Forbidden.. D...... 21, 28, 40,
FLAMMABLE LIQUID, T26. 49, 100
CORROSIVE.
....... Tricresyl phosphate with more than 3 percent ortho isomer.... 6.1 UN2574 II POISON................ A3, N33, N34, T8 None 202 243 5 L........ 60 L....... A......
....... Triethyl phosphite........................................... 3 UN2323 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Triethylamine................................................ 3 UN1296 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Triethylenetetramine......................................... 8 UN2259 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... B...... 40
....... Trifluoroacetic acid......................................... 8 UN2699 I CORROSIVE............. A3, A6, A7, B4, None 201 243 0.5 L...... 2.5 L...... B...... 12, 40
N3, N34, T18,
T27.
....... Trifluoroacetylchloride...................................... 2.3 UN3057 POISON GAS............ 2, 25, B9, B14.. None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Trifluorochloroethylene, inhibited, R1113.................... 2.3 UN1082 POISON GAS............ 3, 25, B14...... None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trifluoroethane, compressed, R143............................ 2.1 UN2035 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trifluoromethane............................................. 2.2 UN1984 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Trifluoromethane and chlorotrifluoromethane mixture (constant ........... .............. ...................... ................ ........... ........... .......
boiling mixture) (R-503). See Refrigerant gases, n.o.s..
....... Trifluoromethane, refrigerated liquid........................ 2.2 UN3136 NONFLAMMABLE GAS...... ................ 306 None 314, 315 50 kg...... 500 kg..... D......
....... 2-Trifluoromethylaniline..................................... 6.1 UN2942 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... 3-Trifluoromethylaniline..................................... 6.1 UN2948 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Triformoxime trinitrate...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Triisobutylene............................................... 3 UN2324 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Triisocyanatoisocyanurate of isophoronediisocyanate, 3 UN2906 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
solution, with 70 percent, by mass.
....... Triisopropyl borate.......................................... 3 UN2616 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... A......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
D...... Trimethoxysilane............................................. 6.1 NA9269 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. E...... 40
LIQUID. B74, T38, T43,
T45.
....... Trimethyl borate............................................. 3 UN2416 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... B......
....... Trimethyl phosphite.......................................... 3 UN2329 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,3,5-Trimethyl-2,4,6-trinitrobenzene........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Trimethylacetyl chloride..................................... 6.1 UN2438 I POISON, CORROSIVE, 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 25, 40
FLAMMABLE LIQUID. B3, B9, B14,
B32, B74, N34,
T38, T43, T45.
....... Trimethylamine, anhydrous.................................... 2.1 UN1083 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trimethylamine, aqueous solutions with not more than 50 3 UN1297 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... D...... 40, 41
percent trimethylamine by mass. CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, B1, T14......... None 202 243 1 L........ 5 L........ B...... 40, 41
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1.............. 150 203 242 5 L........ 60 L....... A...... 40, 41
CORROSIVE.
....... 1,3,5-Trimethylbenzene....................................... 3 UN2325 III FLAMMABLE LIQUID...... B1, T1.......... None 203 242 60 L....... 220 L...... A......
....... Trimethylchlorosilane........................................ 3 UN1298 II FLAMMABLE LIQUID, A3, A7, B77, None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE. N34, T14, T26.
....... Trimethylcyclohexylamine..................................... 8 UN2326 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Trimethylene glycol diperchlorate............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Trimethylhexamethylene diisocyanate.......................... 6.1 UN2328 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... B......
....... Trimethylhexamethylenediamines............................... 8 UN2327 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Trimethylol nitromethane trinitrate.......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitro-meta-cresol......................................... 1.1D UN0216 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... 2,4,6-Trinitro-1,3-diazobenzene.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitro-1,3,5-triazido benzene (dry).................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroacetic acid.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroacetonitrile......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroamine cobalt......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroaniline or Picramide................................. 1.1D UN0153 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroanisole.............................................. 1.1D UN0213 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrobenzene, dry or wetted with less than 30 percent 1.1D UN0214 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Trinitrobenzene, wetted with not less than 30 percent water, 4.1 UN1354 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
by mass. N41.
....... Trinitrobenzenesulfonic acid................................. 1.1D UN0386 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Trinitrobenzoic acid, dry or wetted with less than 30 percent 1.1D UN0215 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Trinitrobenzoic acid, wetted with not less than 30 percent 4.1 UN1355 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
water, by mass. N41.
....... Trinitrochlorobenzene or Picryl chloride..................... 1.1D UN0155 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroethanol.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroethylnitrate......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrofluorenone........................................... 1.1D UN0387 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitromethane.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3,5-Trinitronaphthalene.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitronaphthalene.......................................... 1.1D UN0217 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrophenetole............................................ 1.1D UN0218 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrophenol or Picric acid, dry or wetted with less than 1.1D UN0154 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
30 percent water, by mass.
....... Trinitrophenol, wetted with not less than 30 percent water, 4.1 UN1344 I FLAMMABLE SOLID....... 23, A8, A19, N41 None 211 None 1 kg....... 15 kg...... E...... 28, 36
by mass.
....... 2,4,6-Trinitrophenyl guanidine (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitrophenyl nitramine............................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate Forbidden .............. ...................... ................ ........... ........... .......
(dry).
....... Trinitrophenylmethylnitramine or Tetryl...................... 1.1D UN0208 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroresorcinol or Styphnic acid, dry or wetted with less 1.1D UN0219 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 20 percent water, or mixture of alcohol and water, by
mass.
....... Trinitroresorcinol, wetted or Styphnic acid, wetted with not 1.1D UN0394 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
less than 20 percent water, or mixture of alcohol and water
by mass.
....... 2,4,6-Trinitroso-3-methyl nitraminoanisole................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrotetramine cobalt nitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrotoluene and Trinitrobenzene mixtures or TNT and 1.1D UN0388 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
trinitrobenzene mixtures or TNT and hexanitrostilbene
mixtures or Trinitrotoluene and hexanitrostilnene mixtures.
....... Trinitrotoluene mixtures containing Trinitrobenzene and 1.1D UN0389 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Hexanitrostilbene or TNT mixtures containing trinitrobenzene
and hexanitrostilbene.
....... Trinitrotoluene or TNT, dry or wetted with less than 30 1.1D UN0209 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Trinitrotoluene, wetted with not less than 30 percent water, 4.1 UN1356 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
by mass. N41.
....... Tripropylamine............................................... 3 UN2260 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Tripropylene................................................. 3 UN2057 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tris-(1-aziridinyl) phosphine oxide, solution................ 6.1 UN2501 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Tris, bis-bifluoroamino diethoxy propane (TVOPA)............. Forbidden .............. ...................... ................ ........... ........... .......
....... Tritonal..................................................... 1.1D UN0390 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Tungsten hexafluoride........................................ 2.3 UN2196 POISON GAS, CORROSIVE. 3............... None 338 None Forbidden.. Forbidden.. D...... 40
....... Turpentine................................................... 3 UN1299 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Turpentine substitute........................................ 3 UN1300 I FLAMMABLE LIQUID...... T1.............. None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Undecane..................................................... 3 UN2330 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Uranium hexafluoride, fissile excepted or non-fissile........ 7 UN2978 RADIOACTIVE, CORROSIVE ................ 421-2 420, 425 420, 425 ........... ........... .......
....... Uranium hexafluoride, fissile (with more than 1 percent U- 7 UN2977 RADIOACTIVE, CORROSIVE ................ 453 417, 420 417, 420 ........... ........... A......
235).
....... Uranium metal, pyrophoric.................................... 7 UN2979 RADIOACTIVE, ................ None 418 None ........... ........... D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Uranyl nitrate hexahydrate solution.......................... 7 UN2980 RADIOACTIVE, CORROSIVE ................ 421, 425 415, 416, 415, 416, ........... ........... D......
417 417
....... Uranyl nitrate, solid........................................ 7 UN2981 RADIOACTIVE, OXIDIZER. ................ None 419 None Forbidden.. 15 kg...... A......
....... Urea hydrogen peroxide....................................... 5.1 UN1511 III OXIDIZER, CORROSIVE... A1, A7, A29..... 152 213 240 25 kg...... 100 kg..... A...... 13
....... Urea nitrate, dry or wetted with less than 20 percent water, 1.1D UN0220 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Urea nitrate, wetted with not less than 20 percent water, by 4.1 UN1357 I FLAMMABLE SOLID....... 39, A8, A19, N41 None 211 None 1 kg....... 15 kg...... A...... 28
mass.
....... Urea peroxide, see Urea hydrogen peroxide.................... ........... .............. ...................... ................ ........... ........... .......
....... Valeraldehyde................................................ 3 UN2058 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Valeric acid, see Corrosive liquids, n.o.s................... ........... .............. ...................... ................ ........... ........... .......
....... Valeryl chloride............................................. 8 UN2502 II CORROSIVE, FLAMMABLE A3, A6, A7, B2, 154 202 243 1 L........ 30 L....... C...... 40
LIQUID. N34, T8.
....... Vanadium compound, n.o.s..................................... 6.1 UN3285 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Vanadium oxytrichloride...................................... 8 UN2443 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 Forbidden.. 30 L....... C...... 40
B16, N34, T8,
T26.
....... Vanadium pentoxide, non-fused form........................... 6.1 UN2862 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Vanadium tetrachloride....................................... 8 UN2444 I CORROSIVE............. A3, A6, A7, B4, None 201 243 Forbidden.. 2.5 L...... C...... 40
N34, T8, T26.
....... Vanadium trichloride......................................... 8 UN2475 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 40
....... Vanadyl sulfate.............................................. 6.1 UN2931 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Vehicles, self-propelled including internal combustion ........... .............. ...................... ................ ........... ........... .......
engines or other apparatus containing an internal combustion
Engine or electric storage battery, see Engines etc. or
Battery powered etc. or Wheel chair, electric).
....... Very signal cartridge, see Cartridges, signal................ ........... .............. ...................... ................ ........... ........... .......
....... Vinyl acetate, inhibited..................................... 3 UN1301 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl bromide, inhibited..................................... 2.1 UN1085 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl butyrate, inhibited.................................... 3 UN2838 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl chloride, inhibited or Vinyl chloride, stabilized...... 2.1 UN1086 FLAMMABLE GAS......... B44............. 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl chloroacetate.......................................... 6.1 UN2589 II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... A......
LIQUID.
....... Vinyl ethyl ether, inhibited................................. 3 UN1302 I FLAMMABLE LIQUID...... A3, T14......... None 201 243 1 L........ 30 L....... D......
....... Vinyl fluoride, inhibited.................................... 2.1 UN1860 FLAMMABLE GAS......... B43............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Vinyl isobutyl ether, inhibited.............................. 3 UN1304 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl methyl ether, inhibited................................ 2.1 UN1087 FLAMMABLE GAS......... B44............. 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl nitrate polymer........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Vinyl toluene, inhibited mixed isomers....................... 3 UN2618 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Vinylidene chloride, inhibited............................... 3 UN1303 I FLAMMABLE LIQUID...... T23, T29........ 150 201 243 1 L........ 30 L....... E...... 40
....... Vinylpyridines, inhibited.................................... 6.1 UN3073 II POISON, FLAMMABLE T8.............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Vinyltrichlorosilane......................................... 3 UN1305 I FLAMMABLE LIQUID, A3, A7, B6, N34, None 201 243 Forbidden.. 2.5 L...... B...... 40
CORROSIVE. T14, T26.
....... Warheads, rocket with burster or expelling charge............ 1.4D UN0370 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Warheads, rocket with burster or expelling charge............ 1.4F UN0371 II EXPLOSIVE 1.4F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Warheads, rocket with bursting charge........................ 1.1D UN0286 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Warheads, rocket with bursting charge........................ 1.2D UN0287 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Warheads, rocket with bursting charge........................ 1.1F UN0369 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Warheads, torpedo with bursting charge....................... 1.1D UN0221 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Water-reactive liquid, corrosive, n.o.s...................... 4.3 UN3129 I DANGEROUS WHEN WET, ................ None 201 243 Forbidden.. 1 L........ D......
CORROSIVE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 85
CORROSIVE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E......
CORROSIVE.
....... Water-reactive liquid, n.o.s................................. 4.3 UN3148 I DANGEROUS WHEN WET.... ................ None 201 244 Forbidden.. 1 L........ E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... ................ None 202 243 1 L........ 5 L........ E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 203 242 5 L........ 60 L....... E...... 40
....... Water-reactive liquid, toxic, n.o.s.......................... 4.3 UN3130 I DANGEROUS WHEN WET, A4.............. None 201 243 Forbidden.. 1 L........ D......
POISON.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 85
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E...... 85
KEEP AWAY FROM FOOD.
....... Water-reactive solid, corrosive, n.o.s....................... 4.3 UN3131 I DANGEROUS WHEN WET, N40............. None 211 242 Forbidden.. 15 kg...... D......
CORROSIVE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E...... 85
CORROSIVE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 241 25 kg...... 100 kg..... E...... 85
CORROSIVE.
....... Water-reactive solid, flammable, n.o.s....................... 4.3 UN3132 I DANGEROUS WHEN WET, N40............. None 211 242 Forbidden.. 15 kg...... E......
FLAMMABLE SOLID.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E......
FLAMMABLE SOLID.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 241 25 kg...... 100 kg..... E......
FLAMMABLE SOLID.
....... Water-reactive solid, n.o.s.................................. 4.3 UN2813 I DANGEROUS WHEN WET.... N40............. None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... ................ None 212 242 15 kg...... 50 kg...... E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 213 241 25 kg...... 100 kg..... E...... 40
....... Water-reactive solid, oxidizing, n.o.s....................... 4.3 UN3133 DANGEROUS WHEN WET, ................ None 214 214 Forbidden.. Forbidden.. .......
OXIDIZER.
....... Water-reactive solid, self-heating, n.o.s.................... 4.3 UN3135 I DANGEROUS WHEN WET, N40............. None 211 242 Forbidden.. 15 kg...... E......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 241 25 kg...... 100 kg..... E......
SPONTANEOUSLY
COMBUSTIBLE.
....... Water-reactive solid, toxic, n.o.s........................... 4.3 UN3134 I DANGEROUS WHEN WET, A5, N40......... None 211 242 Forbidden.. 15 kg...... D......
POISON.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E...... 85
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 241 25 kg...... 100 kg..... E...... 85
KEEP AWAY FROM FOOD.
....... Water reactive substances, n.o.s., see Substances which in ........... .............. ...................... ................ ........... ........... .......
contact with water, etc..
AD..... Wheel chair, electric ( spillable or non-spillable type 9 .............. III CLASS 9............... ................ 222 222 None No limit... No limit... A......
batteries).
....... White acid, see Hydrofluoric acid mixtures................... ........... .............. ...................... ................ ........... ........... .......
I...... White asbestos (chrysotile, actinolite, anthophyllite, 9 UN2590 III CLASS 9............... ................ 155 216 240 200 kg..... 200 kg..... A...... 34, 40
tremolite).
....... Wood preservatives, liquid................................... 3 UN1306 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A...... 40
....... Xenon........................................................ 2.2 UN2036 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Xenon, refrigerated liquid (cryogenic liquids)............... 2.2 UN2591 NONFLAMMABLE GAS...... ................ 320 None None 50 kg...... 500 kg..... B......
....... Xylenes...................................................... 3 UN1307 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Xylenols..................................................... 6.1 UN2261 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... Xylidines, solid............................................. 6.1 UN1711 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Xylidines, solution.......................................... 6.1 UN1711 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Xylyl bromide................................................ 6.1 UN1701 II POISON................ A3, A6, A7, N33. None 340 None Forbidden.. 60 L....... D...... 40
....... p-Xylyl diazide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Zinc ammonium nitrite........................................ 5.1 UN1512 II OXIDIZER.............. ................ None 212 242 5 kg....... 25 kg...... E......
....... Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc 6.1 UN1712 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
arsenite mixtures..
....... Zinc ashes................................................... 4.3 UN1435 III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... A......
....... Zinc bisulfite solution see Bisulfites, inorganic aqueous ........... .............. ...................... ................ ........... ........... .......
solutions, n.o.s..
....... Zinc bromate................................................. 5.1 UN2469 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Zinc chlorate................................................ 5.1 UN1513 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Zinc chloride, anhydrous..................................... 8 UN2331 III CORROSIVE............. ................ None 213 240 25 kg...... 100 kg..... A......
....... Zinc chloride, solution...................................... 8 UN1840 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Zinc cyanide................................................. 6.1 UN1713 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 26
....... Zinc dithionite or Zinc hydrosulfite......................... 9 UN1931 III None.................. ................ 155 204 240 100 kg..... 200 kg..... A...... 49
....... Zinc ethyl, see Diethylzinc.................................. ........... .............. ...................... ................ ........... ........... .......
....... Zinc fluorosilicate.......................................... 6.1 UN2855 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Zinc hydrosulfite, see Zinc dithionite....................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc muriate solution, see Zinc chloride, solution........... ........... .............. ...................... ................ ........... ........... .......
....... Zinc nitrate................................................. 5.1 UN1514 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A......
....... Zinc permanganate............................................ 5.1 UN1515 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Zinc peroxide................................................ 5.1 UN1516 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Zinc phosphide............................................... 4.3 UN1714 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Zinc powder or Zinc dust..................................... 4.3 UN1436 I DANGEROUS WHEN WET, A19, N40........ None 211 242 Forbidden.. 15 kg...... A......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, A19............. None 212 242 15 kg...... 50 kg...... A......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 242 25 kg...... 100 kg..... A......
SPONTANEOUSLY
COMBUSTIBLE.
....... Zinc resinate................................................ 4.1 UN2714 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Zinc selenate, see Selenates or Selenites.................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc selenite, see Selenates or Selenites.................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc silicofluoride, see Zinc fluorosilicate................. ........... .............. ...................... ................ ........... ........... .......
....... Zirconium, dry, coiled wire, finished metal sheets, strip 4.1 UN2858 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
(thinner than 254 microns but not thinner than 18 microns).
....... Zirconium, dry, finished sheets, strip or coiled wire........ 4.2 UN2009 III SPONTANEOUSLY A1, A19......... None 213 240 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Zirconium hydride............................................ 4.1 UN1437 II FLAMMABLE SOLID....... A19, A20, N34... None 212 240 15 kg...... 50 kg...... E......
....... Zirconium nitrate............................................ 5.1 UN2728 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Zirconium picramate, dry or wetted with less than 20 percent 1.3C UN0236 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Zirconium picramate, wetted with not less than 20 percent 4.1 UN1517 I FLAMMABLE SOLID....... 23, N41......... None 211 None 1 kg....... 15 kg...... D...... 28, 36
water, by mass.
....... Zirconium powder, dry........................................ 4.2 UN2008 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, N5, None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE. N34.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Zirconium powder, wetted with not less than 25 percent water 4.1 UN1358 II FLAMMABLE SOLID....... A19, A20, N34... None 212 241 15 kg...... 50 kg...... E......
(a visible excess of water must be present) (a) mechanically
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Zirconium scrap.............................................. 4.2 UN1932 III SPONTANEOUSLY N34............. None 213 240 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
D...... Zirconium sulfate............................................ 8 NA9163 III CORROSIVE............. N34............. None 213 240 50 kg...... No limit... A......
....... Zirconium suspended in a liquid.............................. 3 UN1308 I FLAMMABLE LIQUID...... ................ None 201 243 Forbidden.. Forbidden.. B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... ................ None 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... B......
....... Zirconium tetrachloride...................................... 8 UN2503 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
12. In Appendix B to Sec. 172.101, two notes would be added to the
notes preceding the List of Marine Pollutants to read as follows:
Appendix B to Sec. 172.101--List of Marine Pollutants
* * * * *
4. If a material not listed in this appendix meets the criteria
for a marine pollutant, as provided in the General Introduction of
the IMDG Code, Guidelines for the Identification of Harmful
Substances in Packaged Form, the material may be transported as a
marine pollutant in accordance with the applicable requirements of
this subchapter.
5. If approved by the Associate Administrator for Hazardous
Materials Safety, a material listed in this appendix which does not
meet the criteria for a marine pollutant, as provided in the General
Introduction of the IMDG Code, Guidelines for the Identification of
Harmful Substances in Packaged Form, is excepted from the
requirements of this subchapter as a marine pollutant.
* * * * *
13. In addition, in Appendix B to Sec. 172.101, the List of
Marine Pollutants would be amended by removing the entry ``Ammonium
arsenate'' and adding the following materials to the List of Marine
Pollutants in appropriate alphabetical order:
Appendix B to Sec. 172.101--List of Marine Pollutants
* * * * *
------------------------------------------------------------------------
S.M.P. Marine pollutant
------------------------------------------------------------------------
[ADD]
(1) (2)
Acetal
Alkyl (C12-C14)dimethylamine
Alkyl (C7-C9)nitrates
n-Amylbenzene
Benomyl
Bromoacetone
1-Butanethiol
n-Butyl butyrate
Carbendazim
Chloroacetone, stabilized
2-Chloro-6-nitrotoluene
alpha-Chloropropylene
Copper arsenate
PP Copper chloride (solution)
Copper metal powder
Cupric sulfate
PP 1,5,9-Cyclododecatriene
Decyloxytetrahydrothiophene dioxide
Diethylbenzenes (mixed isomers)
Diisopropylnaphthalene
Dimethyl glyoxal (butanedione)
Dimethyl sulphide
4,4 deg.-Diaminodiphenylmethane
1,4-Di-tert-butylbenzene
Dinoseb acetate
Dodecyl diphenyl oxide disulphonate
Dodecyl hydroxypropyl sulfide
1-Dodecylamine
Epibromohydrin
Epichlorohydrin
Estenvalerate
Ethyl mercaptan
1-Ethyl-2-methylbenzene
2-Ethylhexyl nitrate
Fenbutatin oxide
n-Heptylbenzene
n-Hexylbenzene
Iron oxide, spent
Isobenzan
Isobutyl propionate
Isobutyl isobutyrate
Isobutyl butyrate
Isobutylbenzene
Isopropyltoluene
1-Methyl-2-ethylbenzene
3-Methylpyradine
Mononitrobenzene (nitro benzene)
Nitrotoluenes (o-: m-: p-)
Oleylamine
n-Pentylbenzene
d-Phenothrin
Propachlor
n-Propylbenzene
Propanethiols
Quizalofop
Quizalofop-p-ethyl
Tetrachlorvinphos
Tetramethrin
Tetramethylbenzenes
Triisopropylated phenyl phosphates
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
*****
------------------------------------------------------------------------
14. In Sec. 172.102, in paragraph (c)(1), Special Provision 41
would be removed, Special Provision 16 would be revised, and Special
Provisions 23 (Note: Since Special Provision 23 was already added at 59
FR 28493, this proposed 23 will be renumbered 38 in the final rule),
24, 26, 32, 34, 35, 36, 37, 39, 40, 43, 44, 45, 46, 47, 48, 49, 50, 51
would be added and in paragraph (c)(2), Special Provision A33 would be
removed, to read as follows:
Sec. 172.102 Special provisions.
* * * * *
(c) * * *
(1) * * *
* * * * *
16 This description applies to smokeless powder and other solid
propellants that are used as powder for small arms and have been
classed as Division 1.3 and 4.1 in accordance with Sec. 173.56 of this
subchapter.
* * * * *
23 This material may be transported under the provisions of
Division 4.1 only if it is so packed that the percentage of diluent
will not fall below that stated in the shipping description at any time
during transport.
24 Alcoholic beverages containing more than 70 percent alcohol by
volume must be transported as materials in Packing Group II. Alcoholic
beverages containing more than 24 percent but not more than 70 percent
alcohol by volume must be transported as materials in Packing Group
III.
* * * * *
26 This entry does not include ammonium permanganate, the
transport of which is prohibited except when approved by the Associate
Administrator for Hazardous Materials Safety.
* * * * *
32 These beads are made from polystyrene, poly(methyl
methacrylate) or other polymeric material.
* * * * *
34 The commercial grade of calcium nitrate fertilizer, when
consisting mainly of a double salt (calcium nitrate and ammonium
nitrate) containing not more than 10 percent ammonium nitrate and at
least 12 percent water of crystallization, is not subject to the
requirements of this subchapter.
35 The gas must be at a pressure corresponding to an ambient
atmospheric pressure at the time the containment system is closed and
not to exceed 105 kPa absolute (15.22 psig). The gas must be contained
in hermetically sealed glass or metal inner packagings and with a
maximum net quantity per package of 5 liters (1 gallon) or, in the case
of a toxic gas, a maximum net quantity per package of 1 liter (0.3
gallons).
36 The maximum net quantity per package is 5 liters (1 gallon) or
5 kg (11 pounds).
37 Unless it can be demonstrated by testing that the sensitivity
of the substance in its frozen state is no greater than in its liquid
state, the substance must remain liquid during normal transport
conditions. It must not freeze at temperatures above -15 deg.C
(5 deg.F).
39 This substance may be carried under provisions other than those
of Class 1 only if it is so packed that the percentage of water will
not fall below that stated at any time during transport. When
phlegmatized with water and inorganic inert material, the content of
urea nitrate must not exceed 75 percent by mass and the mixture should
not be capable of being detonated by test 1(a)(i) or test 1(a) (ii) in
the UN Recommendations Tests and Criteria.
40 Polyester resin kits consist of two components: a base material
(Class 3, Packing Group II or III) and an activator (organic peroxide),
each separately packed in an inner packaging. The organic peroxide must
be type D, E, or F, not requiring temperature control, and be limited
to a quantity of 125 ml (4.22 ounces) per inner packaging if liquid,
and 500 g (1 pound) if solid. The components may be placed in the same
outer packaging provided they will not interact dangerously in the
event of leakage. Packing group will be II or III, according to the
criteria for Class 3, applied to the base material.
* * * * *
43 The nitrogen content of the nitrocellulose must not exceed 11.5
percent. Each single filter sheet must be packed between sheets of
glazed paper. The portion of glazed paper between the filter sheets
must not be less than 65 percent, by mass. The membrane filters/paper
arrangement must not be liable to propagate a detonation as tested by
one of the tests described in the UN Recommendations, Tests and
Criteria, Part I, Test series 1 (a).
44 The formulation must be prepared so that it remains homogeneous
and does not separate during transport. Formulations with low
nitrocellulose contents and neither showing dangerous properties when
tested for their ability to detonate, deflagrate or explode when heated
under defined confinement by the appropriate test methods and criteria
in the UN Recommendations, Tests and Criteria, nor being a flammable
solid when tested in accordance with Appendix E to Part 173 of this
subchapter (chips, if necessary, crushed and sieved to a particle size
of less than 1.25 mm) are not subject to this subchapter.
45 Temperature should be maintained between 18 deg.C (64.4 deg.F)
and 40 deg.C (104 deg.F). Tanks containing solidified methacrylic acid
must not be reheated during transport.
46 This material must be packed in accordance with packing method
OP6B (see Sec. 173.225 of this subchapter). During transport, it must
be protected from direct sunshine and stored (or kept) in a cool and
well-ventilated place, away from all sources of heat.
47 Mixtures of solids which are not subject to this subchapter and
flammable liquids may be transported under this entry without first
applying the classification criteria of Division 4.1, provided there is
no free liquid visible at the time the material is loaded or at the
time the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level.
48 Mixtures of solids which are not subject to this subchapter and
toxic liquids may be transported under this entry without first
applying the classification criteria of Division 6.1, provided there is
no free liquid visible at the time the material is loaded or at the
time the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level. This entry may not be used for solids
containing a Packing Group I liquid.
49 Mixtures of solids which are not subject to this subchapter and
corrosive liquids may be transported under this entry without first
applying the classification criteria of Class 8, provided there is no
free liquid visible at the time the material is loaded or at the time
the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level.
50 Cases, cartridge, empty with primer which are made of metallic
casings and meeting the classification criteria of Division 1.4 are not
regulated for domestic transportation.
51 This description applies to items previously described as ``Toy
propellant devices, Class C'' and includes reloadable kits.
* * * * *
15. In Sec. 172.203, the list of shipping names in paragraph (k)(3)
would be revised and a new paragraph (o) would be added to read as
follows:
Sec. 172.203 Additional description requirements.
* * * * *
(k) * * *
(3) * * *
Alcoholates solution, n.o.s., in alcohol
Alcohols, toxic, n.o.s.
Aldehydes, toxic, n.o.s.
Alkali metal alcoholates, self-heating, corrosive, n.o.s.
Alkaline earth metal alcoholates, n.o.s.
Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid,
corrosive, flammable, n.o.s.
Amines, liquid, flammable, corrosive, n.o.s. or Polyamines, liquid,
flammable, corrosive, n.o.s.
Articles, explosive, n.o.s.
Caustic alkali liquids, n.o.s.
Charges, propelling
Chloroformates, toxic, corrosive, n.o.s.
Combustible liquid, n.o.s.
Components, explosive train, n.o.s.
Compounds, tree or weed killing, liquid, flammable, corrosive, toxic
Compounds, cleaning liquid, corrosive, flammable, toxic
Compressed or Liquefied gases, toxic, flammable, n.o.s.
Compressed or Liquefied gases, flammable, n.o.s.
Compressed or Liquefied gases, n.o.s.
Compressed or Liquefied gases, toxic, n.o.s.
Compressed or Liquefied gases, oxidizing, n.o.s.
Contrivances, water-activated
Corrosive, liquid, acidic, inorganic or organic, n.o.s.
Corrosive, liquid, basic, inorganic or organic, n.o.s.
Corrosive liquids, flammable, n.o.s.
Corrosive liquids, n.o.s.
Corrosive liquids, oxidizing, n.o.s.
Corrosive liquids, toxic, n.o.s.
Corrosive liquids, water-reactive, n.o.s.
Corrosive, solid, acidic, inorganic or organic, n.o.s.
Corrosive, solid, basic, inorganic or organic, n.o.s.
Corrosive solids, flammable, n.o.s.
Corrosive solids, n.o.s.
Corrosive solids, oxidizing, n.o.s.
Corrosive solids, self heating, n.o.s.
Corrosive solids, toxic, n.o.s.
Corrosive solids, water-reactive, n.o.s.
Disinfectants, liquid, toxic, n.o.s.
Disinfectants, solids, toxic, n.o.s.
Disinfectants, liquid, corrosive, n.o.s.
Dispersant gas, n.o.s.
Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic,
n.o.s.
Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid,
corrosive, n.o.s.
Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic,
n.o.s.
Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid,
corrosive, n.o.s.
Environmentally hazardous substances, liquid or solid, n.o.s.
Flammable gases, solid, corrosive, n.o.s.
Flammable liquids, corrosive, n.o.s.
Flammable liquids, n.o.s.
Flammable liquid, toxic, corrosive, n.o.s.
Flammable liquids, toxic, n.o.s.
Flammable solids, corrosive, organic or inorganic, n.o.s.
Flammable solids, organic, molten, n.o.s.
Flammable solids, organic or inorganic, n.o.s.
Flammable solids, toxic, organic or inorganic, n.o.s.
Halogenated irritating liquids, n.o.s.
Hazardous waste, liquid or solid, n.o.s.
Infectious substances, affecting animals
Infectious substances, affecting humans
Insecticide gases, n.o.s.
Insecticide gases, toxic, n.o.s.
Isocyanates, toxic, flammable, n.o.s. or Isocyanates solutions,
toxic, flammable, n.o.s.
Isocyanates, flammable, toxic, n.o.s. or Isocyanates solutions,
flammable, toxic, n.o.s.
Medicine, liquid, flammable, toxic, n.o.s.
Medicines, liquid, toxic, n.o.s.
Medicine, solid, toxic, n.o.s.
Metal powder, self-heating, n.o.s.
Metal salts of organic compounds, flammable, n.o.s.
Metal powders, flammable, n.o.s.
Metallic substance, water-reactive, n.o.s.
Metallic substance, water-reactive, self-heating, n.o.s.
Nitriles, toxic, flammable, n.o.s.
Nitriles, flammable, toxic, n.o.s.
Nitriles, toxic, n.o.s.
Organic peroxide type B, liquid
Organic peroxide type B, liquid, temperature controlled
Organic peroxide type B, solid
Organic peroxide type B, solid, temperature controlled
Organic peroxide type C, liquid
Organic peroxide type C, liquid, temperature controlled
Organic peroxide type C, solid
Organic peroxide type C, solid, temperature controlled
Organic peroxide type D, liquid
Organic peroxide type D, liquid, temperature controlled
Organic peroxide type D, solid
Organic peroxide type D, solid, temperature controlled
Organic peroxide type E, liquid
Organic peroxide type E, liquid, temperature controlled
Organic peroxide type E, solid
Organic peroxide type E, solid, temperature controlled
Organic peroxide type F, liquid
Organic peroxide type F, liquid, temperature controlled
Organic peroxide type F, solid
Organic peroxide type F, solid, temperature controlled
Organometallic compound dispersion, water-reactive, flammable,
n.o.s.
Organometallic compound solution, water-reactive, flammable, n.o.s.
Organometallic compound, toxic, n.o.s.
Other regulated substances, liquid, n.o.s.
Other regulated substances, solid, n.o.s.
Oxidizing solid, n.o.s.
Oxidizing solid, corrosive, n.o.s.
Oxidizing solid, flammable, n.o.s.
Oxidizing solid, self-heating, n.o.s.
Oxidizing solid, toxic, n.o.s.
Oxidizing solid, water-reactive, n.o.s.
Oxidizing liquid, n.o.s.
Oxidizing liquid, corrosive, n.o.s.
Oxidizing liquid, toxic, n.o.s.
Pesticides, liquid, toxic, flammable, n.o.s.
Pesticides, liquid, toxic, n.o.s.
Pesticides, liquid, flammable, toxic, n.o.s.
Pesticides, solid, toxic, n.o.s.
Propellant, liquid
Propellant, solid
Pyrophoric liquids, organic or inorganic, n.o.s.
Pyrophoric metals, n.o.s. or Pyrophoric alloys, n.o.s.
Pyrophoric organometallic compound, n.o.s.
Pyrophoric solids, organic or inorganic, n.o.s.
Refrigerant gases, n.o.s.
Samples, explosive (other than initiating explosives)
Self-heating liquid, corrosive, inorganic, n.o.s.
Self-heating liquid, corrosive, organic, n.o.s.
Self-heating liquid, inorganic, n.o.s.
Self-heating liquid, organic, n.o.s.
Self-heating liquid, toxic, inorganic, n.o.s.
Self-heating liquid, toxic, organic, n.o.s.
Self-heating solid, corrosive, inorganic, n.o.s.
Self-heating solid, corrosive, organic, n.o.s.
Self-heating solid, organic or inorganic, n.o.s.
Self-heating solid, oxidizing, n.o.s.
Self-heating solid, toxic, organic or inorganic, n.o.s.
Self-reactive liquid type B
Self-reactive liquid type B, temperature controlled
Self-reactive liquid type C
Self-reactive liquid type C, temperature controlled
Self-reactive liquid type D
Self-reactive liquid type D, temperature controlled
Self-reactive liquid type E
Self-reactive liquid type E, temperature controlled
Self-reactive liquid type F
Self-reactive liquid type F, temperature controlled
Self-reactive solid type B
Self-reactive solid type B, temperature controlled
Self-reactive solid type C
Self-reactive solid type C, temperature controlled
Self-reactive solid type D
Self-reactive solid type D, temperature controlled
Self-reactive solid type E
Self-reactive solid type E, temperature controlled
Self-reactive solid type F
Self-reactive solid type F, temperature controlled
Solids containing corrosive liquid, n.o.s.
Solids containing flammable liquid, n.o.s.
Solids containing toxic liquid, n.o.s.
Substances, explosive, n.o.s.
Substances, explosive, very insensitive (substances, EVI) n.o.s.
Tear gas substances, liquid or solid, n.o.s.
Toxic liquids, corrosive, organic or inorganic, n.o.s.
Toxic liquids, flammable, organic or inorganic, n.o.s.
Toxic liquids, organic or inorganic, n.o.s.
Toxic liquids, oxidizing, n.o.s.
Toxic liquids, water-reactive, n.o.s.
Toxic solids, corrosive, organic or inorganic, n.o.s.
Toxic solids, flammable, organic or inorganic, n.o.s.
Toxic solids, organic or inorganic, n.o.s.
Toxic solids, oxidizing, n.o.s.
Toxic solids, self-heating, n.o.s.
Toxic solids, water-reactive, n.o.s.
Water-reactive, liquid, n.o.s.
Water-reactive, liquid, corrosive, n.o.s.
Water-reactive, liquid, toxic, n.o.s.
Water-reactive, solid, n.o.s.
Water-reactive, solid, corrosive, n.o.s.
Water-reactive, solid, flammable n.o.s.
Water-reactive, solid, oxidizing, n.o.s.
Water-reactive, solid, self-heating, n.o.s.
Water-reactive, solid, toxic, n.o.s.
* * * * *
(o) Organic peroxides and self-reactive materials. The description
on a shipping paper for a Division 4.1 (self-reactive) material or a
Division 5.2 (organic peroxide) material must include the following
additional information, as appropriate:
(1) If notification or competent authority approval is required,
the shipping paper must contain a statement of approval of the
classification and conditions of transport.
(2) For Division 4.1 (self-reactive) and Division 5.2 (organic
peroxide) materials that require temperature control during transport,
the control and emergency temperature must be included on the shipping
paper.
(3) The word ``SAMPLE'' must be included in association with the
basic description when a sample of a Division 4.1 (self-reactive)
material (see Sec. 173.224(c)(4) of this subchapter) or Division 5.2
(organic peroxide) material (see Sec. 173.225(c)(4) of this subchapter)
is offered for transportation or transported.
Sec. 172.203 [Amended]
16. In addition, in Sec. 172.203, in paragraph (m)(1), the wording
``(Poison)'' would be revised to read ```Poison' or `Toxic'''.
Sec. 172.204 [Amended]
17. In Sec. 172.204, in paragraph (a)(2), the wording ``packed,
marked and labeled,'' would be revised to read ``packed, marked and
labeled/placarded,''.
Sec. 172.320 [Amended]
18. In Sec. 172.320, in paragraph (b), the wording ``or identifying
information'' would be revised to read ``or identifying information,
such as a product code''.
19. In Sec. 172.400a, a new paragraph (c) would be added to read as
follows:
Sec. 172.400a Exceptions from labeling.
* * * * *
(c) Notwithstanding the provisions of Sec. 172.402(a), a subsidiary
hazard label is not required on a package containing a Class 8
(corrosive) material which has a subsidiary hazard of Division 6.1
(poisonous) if the toxicity of the material is based solely on the
corrosive destruction of tissue rather than systemic poisoning.
20. In Sec. 172.402, new paragraphs (f) and (g) would be added to
read as follows:
Sec. 172.402 Additional labeling requirements.
* * * * *
(f) Division 2.2 materials. In addition to the label specified in
Column 6 of the Sec. 172.101 Table, each package of Division 2.2
material that also meets the definition for Division 5.1 (oxidizer)
must be labeled ``OXIDIZER''.
(g) Division 2.3 materials. In addition to the label specified in
Column 6 of the Sec. 172.101 Table, each package of Division 2.3
material that also meets the definition for:
(1) Division 2.1, must be labeled FLAMMABLE GAS;
(2) Division 5.1, must be labeled OXIDIZER; and
(3) Class 8, must be labeled ``CORROSIVE''.
Sec. 172.402 [Amended]
21. In addition, in Sec. 172.402, the following changes would be
made:
a. In paragraph (a)(2), in the text preceding the table, the
wording ``For other than Class 2 or Class 1 materials (for subsidiary
labeling requirements for Class 1 materials see paragraph (e) of this
section)'' would be revised to read ``For other than Class 1 or Class 2
materials (for subsidiary labeling requirements for Class 1 or Class 2
materials see paragraph (e) or paragraphs (f) and (g), respectively, of
this section)''.
b. In the paragraph (a)(2) table, in the column ``8'', for the
entry ``III'', the footnote reference ``**'' would be removed and
replaced with ``X'', and footnote ** would be removed and reserved.
c. In paragraph (a)(2), in the footnotes following the table, the
footnote identified as ``*'' would be revised to read ``If the flash
point of a material is at or above 38 deg.C (100 deg.F), required for
transport by air or vessel only.''
Sec. 172.411 [Amended]
22. In Sec. 172.411, in the third sentence of paragraph (d), the
wording ``measuring at least 12.7 mm (0.5 inches) in height'' would be
removed.
23. In Sec. 172.416, a new sentence would be added as the last
sentence of paragraph (b) to read as follows:
Sec. 172.416 POISON GAS label.
* * * * *
(b) * * * The words ``TOXIC GAS'' may be used in lieu of the words
``POISON GAS''.
24. In Sec. 172.430, a new sentence would be added as the last
sentence of paragraph (b) to read as follows:
Sec. 172.430 POISON label.
* * * * *
(b) * * * The word ``TOXIC'' may be used in lieu of the word
``POISON''.
25. In Sec. 172.540, a new sentence would be added to the end of
paragraph (b) to read as follows:
Sec. 172.540 POISON GAS placard.
* * * * *
(b) * * * The words ``TOXIC GAS'' may be used in lieu of the words
``POISON GAS''.
Sec. 172.547 [Amended]
26. In Sec. 172.547, in paragraph (b), the wording ``25 mm (0.98
inches)'' would be removed and replaced with ``12 mm (0.5 inch)''.
27. In Sec. 172.554, a new sentence would be added to the end of
paragraph (b) to read as follows:
Sec. 172.554 POISON placard.
* * * * *
(b) * * * The word ``TOXIC'' may be used in lieu of the word
``POISON''.
PART 173--SHIPPERS--GENERAL REQUIREMENTS FOR SHIPMENTS AND
PACKAGINGS
28. The authority citation for part 173 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1805, 1806, 1807, 1808,
1817; 49 CFR part 1, unless otherwise noted.
29. In Sec. 173.2a, in the paragraph (b) table, two notes would be
added at the end of the table to read as follows:
Sec. 173.2a Classification of a material having more than one hazard.
* * * * *
(b) * * *
Precedence of Hazard Table
* * * * *
Note 1: The most stringent packing group assigned to a hazard of
the material takes precedence over other packing groups; for
example, a material meeting Class 3 PG II and Division 6.1 PG I
(oral toxicity) is classified as Class 3 PG I.
Note 2: A material which meets the definition of Class 8 and has
an inhalation toxicity by dusts and mists which meets criteria for
Packing Group I specified in Sec. 173.133(a)(1) must be classed as
Division 6.1 if the oral or dermal toxicity meets criteria for
Packing Group I or II. If the oral or dermal toxicity meets criteria
for Packing Group III, the material must be classed as Class 8.
Sec. 173.2a [Amended]
30. In addition, in the paragraph (b) table, the following changes
would be made:
a. At the intersection of the line entry ``4.2 II'' and the column
entry ``8 I liquid'', the wording ``(\3\)'' would be revised to read
``8''.
b. At the intersection of the line entry ``4.2 II'' and the column
entry ``8 II liquid'', the wording ``(\3\)'' would be revised to read
``4.2''.
c. At the intersection of the line entry ``4.2 II'' and the column
entry ``8 III liquid'', the wording ``(\3\)'' would be revised to read
``4.2''.
d. At the intersection of the line entry ``4.2 III'' and the column
entry ``8 I liquid'', the wording ``(\3\)'' would be revised to read
``8''.
e. At the intersection of the line entry ``4.2 III'' and the column
entry ``8 II liquid'', the wording ``(\3\)'' would be revised to read
``8''.
f. At the intersection of the line entry ``4.2 III'' and the column
entry ``8 III liquid'', the wording ``(\3\)'' would be revised to read
``4.2''.
31. In Sec. 173.9, a new paragraph (e) would be added to read as
follows:
Sec. 173.9 Cars, truck bodies, freight containers, or trailers
containing lading which has been fumigated or treated with Class 3,
Division 2.1, 2.3, or 6.1 materials.
* * * * *
(e) See Sec. 176.76(i) of this subchapter for requirements for
fumigated transport units on vessels.
Sec. 173.21 [Amended]
32. In Sec. 173.21, in the first sentence of paragraph (f)(2), the
wording ``Columns 4a and 4b,'' would be revised to read ``Columns 5 and
6,''.
Sec. 173.22 [Amended]
33. In Sec. 173.22, in paragraph (a)(3)(i), the first word ``The''
would be removed and replaced with the wording ``Except for the marking
on the bottom of a metal or plastic drum with a capacity over 100
liters which has been reconditioned, remanufactured or otherwise
converted, the'' .
34. In Sec. 173.24, paragraph (d) would be revised to read as
follows:
Sec. 173.24 General requirements for packagings and packages.
* * * * *
(d) Specification packagings and UN standard packagings
manufactured outside the U.S.--(1) Specification packagings. A
specification packaging, including a UN standard packaging manufactured
in the United States, must conform in all details to the applicable
specification or standard in part 178 or part 179 of this subchapter.
(2) UN standard packagings manufactured outside the United States.
A UN standard packaging manufactured outside the United States, in
accordance with national or international regulations based on the UN
Recommendations on the Transport of Dangerous Goods, may be imported
and used as an authorized packaging under the provisions of paragraph
(c)(1) of this section, subject to the following conditions and
limitations:
(i) The packaging fully conforms to applicable provisions in the UN
Recommendations on the Transport of Dangerous Goods and the
requirements of this subpart, including reuse provisions;
(ii) The packaging is capable of passing the prescribed tests in
part 178 of this subchapter applicable to that standard; and
(iii) The competent authority of the country of manufacture
provides reciprocal treatment for UN standard packagings manufactured
in the U.S.
* * * * *
Sec. 173.24 [Amended]
35. In addition, in Sec. 173.24, in paragraph (e)(4)(ii), the
wording ``flammable or poisonous gases;'' would be revised to read
``flammable, poisonous, or asphyxiant gases;''.
36. In Sec. 173.25, paragraph (a) introductory text would be
revised and a new paragraph (b) would be added to read as follows:
Sec. 173.25 Authorized packages and overpacks.
(a) Authorized packages containing hazardous materials may be
offered for transportation in an overpack as defined in Sec. 171.8 of
this subchapter, if all of the following conditions are met:
* * * * *
(b) Shrink-wrapped or stretch-wrapped trays may be used as outer
packagings for inner packagings prepared in accordance with the limited
quantity provisions or consumer commodity provisions of this
subchapter, provided that the complete package is capable of meeting
performance standards at the Packing Group III performance level. Each
package may not exceed 20 kg (44 lbs) gross weight.
* * * * *
37. In Sec. 173.28, paragraph (b)(1) would be amended by adding a
new first sentence, paragraph (b)(4) would be revised and new
paragraphs (b)(7) and (c)(4) would be added to read as follows:
Sec. 173.28 Reuse, reconditioning and remanufacture of packagings.
* * * * *
(b) * * *
(1) Before reuse, a packaging must be examined and determined to be
capable of withstanding the performance tests specified in subpart M of
Part 178 of this subchapter. * * *
* * * * *
(4) Metal and plastic drums and jerricans used as single packagings
or the outer packagings of composite packagings are authorized for
reuse only when they are marked in a permanent manner (e.g., embossed)
in millimeters with the nominal or minimum thickness of the packaging
material, as required by Sec. 178.503(a)(9) of this subchapter, and
conform to the following minimum thickness criteria:
------------------------------------------------------------------------
Maximum Minimum thickness of packaging material
capacity -------------------------------------------------------------
not over Metal drum or jerrican Plastic drum or jerrican
------------------------------------------------------------------------
20 L...... 0.63 mm (0.025 inch)......... 1.1 mm (0.043 inch)
30 L...... 0.73 mm (0.029 inch)......... 1.1 mm (0.043 inch)
40 L...... 0.73 mm (0.029 inch)......... 1.8 mm (0.071 inch)
60 L...... 0.92 mm (0.036 inch)......... 1.8 mm (0.071 inch)
120 L..... 0.92 mm (0.036 inch)......... 2.2 mm (0.087 inch)
220 L..... 0.92 mm (0.036 inch)\1\...... 2.2 mm (0.087 inch)
450 L..... 1.77 mm (0.070 inch)......... 5.0 mm (0.197 inch)
------------------------------------------------------------------------
\1\Metal drums or jerricans constructed with a minimum thickness of 0.8
mm (0.03 inch) body and 1.1 mm (0.043 inch) heads are authorized.
* * * * *
(7) Notwithstanding the provisions of paragraph (b)(2) of this
section, a packaging otherwise authorized for reuse may be reused
without being subjected to the leakproofness test with air provided the
packaging:
(i) Is refilled with a material compatible with the previous
lading;
(ii) Is offered for transportation or transported by a private
carrier, contract carrier, or by a common carrier in a transport
vehicle or freight container used exclusively for such service, within
a distribution chain controlled by the offeror; and
(iii) Is constructed of stainless steel, monel or nickel with a
thickness not less than one and one-half times the nominal thickness
prescribed in paragraph (b)(4) of this section or, if constructed of
another material or thickness, is approved by the Associate
Administrator for Hazardous Materials Safety for reuse without
retesting in accordance with the provisions of this paragraph.
(c) * * *
(4) The markings applied by the reconditioner may be different from
those applied by the manufacturer at the time of original manufacture,
but may not identify a greater performance capability than that for
which the original design type had been tested (for example, the
reconditioner may mark a drum which was originally marked as 1A1/Y1.8
as 1A1/Y1.2 or 1A1/Z1.8).
* * * * *
Sec. 173.28 [Amended]
38. In addition, in Sec. 173.28(c)(3), in the first sentence, the
reference ``Sec. 178.503(c)'' would be revised to read
``Sec. 178.503(c) and (d)''.
Sec. 173.33 [Amended]
39. In Sec. 173.33, in paragraph (c)(5), the wording ``Division
6.1'' would be revised to read ``Division 6.1, Packing Group I or II''.
Sec. 173.52 [Amended]
40. In Sec. 173.52, in paragraph (b), Table 1, the following
changes would be made:
a. In the second entry, the wording ``Some articles, such as
detonators for blasting, detonator assemblies for blasting and primers,
cap-type, are included, even though they do not contain primary
explosives.'' would be added at the end of the entry following the
wording ``features.''.
b. In the fifth and sixth entries, the wording ``, gel'' would be
added immediately following the wording ``flammable liquid'' and
immediately preceding the wording ``or hypergolic liquid''.
41. In Sec. 173.59, the following definitions would be added in
appropriate alphabetical order to read as follows:
Sec. 173.59 Descriptions of terms for explosives.
* * * * *
Charges, propelling for cannon. Articles consisting of a propellant
charge in any physical form, with or without a casing, for use in a
cannon.
* * * * *
Propellant, liquid. Substances consisting of a deflagrating liquid
explosive, used for propulsion.
Propellant, solid. Substances consisting of a deflagrating solid
explosive, used for propulsion.
* * * * *
Sec. 173.59 [Amended]
42. In addition, in Sec. 173.59, the following changes would be
made:
a. For the description ``Charges, propelling'', the wording ``or
for reducing drag for projectiles'' would be added immediately
following ``in cannon or''.
b. For the description ``Powder, smokeless'', in the first
sentence, the word ``generally'' would be removed, and the wording
``and charges propelling for cannon'' would be added at the end of the
last sentence, immediately following the wording ``charges,
propelling''.
c. For the description ``Propellants'', the wording ``or for
reducing the drag of projectiles'' would be added at the end of the
sentence immediately following the word ``propulsion''.
43. In Sec. 173.60, paragraph (b)(15) would be added to read as
follows:
Sec. 173.60 General packaging requirements for explosives.
* * * * *
(b) * * *
(15) Plastic packagings must not be liable to generate or
accumulate sufficient static electricity that a discharge could cause
the packaged explosive to ignite or the packaged article to function.
44. In Sec. 173.62, paragraph (a) would be revised, a new sentence
would be added after the second sentence in paragraph (b), the
Explosives Table in paragraph (b) would be amended by adding or
removing entries, in appropriate alpha-numerical sequence; and the
Table of Packing Methods in paragraph (c) and paragraph (d) would be
revised to read as follows:
Sec. 173.62 Specific packaging requirements.
(a) Except as provided in paragraph (e) of this section, when the
Sec. 172.101 Table specifies that an explosive must be packaged in
accordance with this section, only non-bulk packagings which conform to
the provisions of paragraphs (b), (c), and (d) of this section, and the
applicable requirements in Secs. 173.60 and 173.61 may be used, unless
otherwise approved by the Associate Administrator for Hazardous
Materials Safety.
(b) * * * However, the packing method authorized under E-103 may
replace the packing method listed in the Explosives Table. * * *
Explosives Table
------------------------------------------------------------------------
Identification No. Packing methods
------------------------------------------------------------------------
[ADD]
UN0075............................. E-159
UN0143............................. E-159
UN0491............................. E-158
UN0492............................. E-151
UN0493............................. E-151
UN0494............................. E-140
UN0495............................. E-159
UN0496............................. E-13
UN0497............................. E-159
UN0498............................. E-22
UN0499............................. E-22
NA0276............................. E-114
NA0323............................. E-114
NA0337............................. E-134
[REMOVE]
UN0075............................. US001
UN0143............................. US001
UN0273............................. E-158(a),(b),(c)
UN0274............................. E-158(a),(b),(c)
NA0273............................. E-22(a),(b),(c)
NA0274............................. E-22(a),(b),(c)
------------------------------------------------------------------------
(c) * * *
Table of Packing Methods
Particular packaging
Packing method Inner packaging Outer packaging exception/requirement
(1) (2) (3) (4)
----------------------------------------------------------------------------------------------------------------
E-1(a).............. Not necessary Bags:
Paper, multiwall, water
resistant (5M2)
Textile, sift-proof (5L2)
Textile, water resistant
(5L3)
Plastic, woven, sift-proof
(5H2)
Plastic, woven, water
resistant (5H3)
Plastic, film (5H4)
E-1(b).............. Bags: Barrels:
Paper, Kraft Wood, removable head (2C2)
Plastic Boxes:
Sheets: Wood, ordinary (4C1)
Plastic Plywood (4D)
Reconstituted wood (4F)
Drums:
Steel, removable head (1A2)
E-2................. Receptacles: Barrels: 1 for all entries 2 for all
Metal Wood, removable head (2C2) entries except UN 0402.
Paper Boxes:
Plastic Fiberboard (4G)
Sheets: Wood, ordinary (4C1)
Plastic Plywood (4D)
Bags: Reconstituted wood (4F)
paper, multiwall, water Drums:
resistant woven plastics Fiber (1G)
Steel, removable head (1A2)
Note: Removable head plastic
drums (1H2) are authorized
for UN 0219.
E-3................. Bags: Barrels: 3, 4, D1.
Plastic Wood, removable head (2C2)
Rubber Drums:
Textile Plastic, removable head (1H2)
Rubberized textile Steel, removable head (1A2)
Intermediate
Bags:
Plastic
Rubber
Textile
Rubberized textile
Barrels:
Wood
Receptacles
Plastic
E-4(a).............. Receptacles: Barrels:
Fiberboard Wood, removable head (2C2)
Metal Boxes:
Paper Steel (4A)
Plastic Fiberboard (4G)
Rubberized textile natural wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
E-4(b).............. Optional Drums:
Aluminum, removable head
(1B2)
Fiber (1G)
Steel, removable head (1A2)
Note: steel drums (1A2) must
be dust tight
E-5................. Bags: Boxes:
Plastic Fiberboard (4G)
Sheets: Wood, sift-proof (4C2)
Paper, Kraft Plywood (4D)
Paper, waxed Reconstituted wood (4F)
E-6 (a)(i).......... For wetted explosives: Barrels: ............................
Bags: Wood, removable head (2C2)
Plastic Boxes:
Rubberized, textile Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Steel, removable head (1A2)
Fiber (1G)
E-6 (a)(ii)......... For wetted explosives: Barrels: ............................
Bags: Wood, removable head (2C2)
Rubber Drums:
Textile Steel, removable head (1A2)
Rubberized textile Fiber (1G)
Intermediate:
Bags:
Rubber
Rubberized textile
Plastics
E-6(b).............. For desensitized explosives: For desensitized explosives: ............................
Same as for wetted explosives Same as for wetted explosives
except that any fiberboard except that any fiberboard
boxes may be used as inner boxes may be used as inner
packaging and any textile packagings and any textile
bags as intermediate bags as intermediate
packaging packaging
E-8................. Receptacles: Barrels: D15, D13.
Waterproof material Wood, removable head (2C2)
Sheets: Boxes:
Waterproof Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-9................. Bags: Bags: D13
Oil-resistant Paper, multiwall water
Sheets: resistant (5M2)
Plastic Textile, sift-proof (5L2)
Cans: Textile, water resistant
Metal (5L3)
Woven plastic, without inner
lining or coating (5H1)
Woven plastic, sift- proof
(5H2)
Woven plastic, water
resistant (5H3)
Plastic film (5H4)
Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Note: If bags of 5H2, 5H3,
5H4, or 5M2 are used, no
inner packaging necessary.
E-10................ Bags: Barrels: ............................
Waxed paper Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4C1)
Sheets: waxed paper, Plywood (4D)
plastics, rubberized textile Reconstituted wood (4F)
E-11................ Bags: Barrels:
Waxed paper Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4C1)
Sheets: Fiberboard (4G)
Waxed paper Plywood (4D)
Plastic Reconstituted wood (4F)
Textile Drums:
Rubberized textile Fiber (1G)
E-12................ Bags: Bags: D14
Oil-resistant Paper, multiwall, water
Sheets: resistant (5M2)
Plastic Woven plastic, without inner
lining or coating (5H1)
Woven plastic, sift-proof
(5H2)
Woven plastic, water
resistant (5H3)
Plastic film (5H4)
Textile, sift-proof (5L2)
Textile, water resistant
(5L3)
Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Note: If bags of 5H2 or 5H3
are used, no inner packaging
is necessary.
E-13(a)............. For wetted explosives Barrels:
Bags: Wood, removable head (2C2)
Plastic Boxes:
Woven plastics Fiberboard (4G)
Paper, multiwall, water Wood, ordinary (4Cl)
resistant Plywood (4D)
Sheets: Reconstituted wood (4F)
Plastic Drums:
Fiber (1G)
E-13(b)............. For dry explosives Barrels:
Bags: Wood, removable head
Paper xl(2C2)
Plastic Boxes:
woven plastics Fiberboard (4G)
Paper, multiwall, water Wood, ordinary (4Cl)
resistant Plywood (4D)
Boxes: Reconstituted wood (4F)
Fiberboard Drums:
Sheets: Fiber (1G)
Plastic
E-15(a)............. Not necessary Drums:
Aluminum, removable head
(1B2)
Steel, removable head (1A2)
E-15(b)............. Bags: Barrels:
Waterproof paper Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4Cl)
Sheets: Plywood (4D)
Plastic Reconstituted wood (4F)
Rubberized textile Fiberboard (4G)
Drums:
Fiber (1G)
E-17................ Cans: Boxes:
Metal Wood, ordinary (4C1)
Receptacles: Plywood (4D)
Glass Reconstituted wood (4F)
Plastic
E-18................ Bags: Barrels:
Paper Wood, removable head (2C2)
Plastic Boxes:
Sheets: Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
Plywood (1D)
Steel, removable head
(1A2)
E-19(a)............. Not necessary Drums: 7.
Aluminum, removable head
(1B2)
Steel, removable head (1A2)
Plastic, removable head (1H2)
E-19(b)............. Bags: Barrels:
Plastic Wood, removable head (2C2)
Sheets: Boxes:
Plastic Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
E-20................ Receptacles: Boxes: 55.
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Fiber (1G)
E-21................ Boxes: Boxes: 2.
Fiberboard Wood, sift-proof (4C2)
Cans: Plywood (4D)
Metal Reconstituted wood (4F)
Receptacles:
Waterproof paper
Plastic
Note: Plastic used must not
be liable to generate static
electricity by contained
substances.
E-22(a)............. Bags: Barrels: 11 for UN 0411.
Paper, Kraft Wood, removable head (2C2)
Plastic Boxes:
Textile Fiberboard (4G)
Rubberized textile Wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Drums:
Fiber (1G)
Plywood (1D)
E-22(b)............. Receptacles: Boxes: 10.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
E-22(c)............. Not Necessary Drums: 8, 9, 10.
Steel, removable head (1A2)
Fiber (1G)
Plywood (1D)
Jerricans:
Steel (3A1)
Steel, removable head (3A2)
E-24(a)............. Bags: Boxes:
Rubber Fiberboard (4G)
Rubberized textile
Plastic
E-24(b)............. Bags: Drums:
Rubber Steel, removable head (1A2)
Rubberized textile with coating other than lead
Plastic
Intermediate:
Bags:
Rubber
Rubber textile
Plastic
E-25................ Bags: Drums:
Plastic Fiber (1G)
Steel, removable head (1A2)
E-26................ Bags: Barrels: 53.
Plastic Wood, removable head (2C2)
Paper Boxes:
Paper, multiwall, water Fiberboard (4G)
resistant Wood, ordinary (4C1)
Sheets: Plywood (4D)
Plastic Reconstituted wood (4F)
Receptacles: Drums:
Metal Fiber (1G)
Paper Bags:
Plastic Plastic, sift-proof (5H2)
E-102............... Optional Boxes: 13, 48, 49.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Expanded plastics (4H1)
Fiberboard (4G)
Plastics, solid (4H2)
Crates:
(For large articles)
Drums:
Steel, removable head (1A2)
Fiber (1G)
Aluminum, removable head
(1B2)
E103
(2) Must be
specifically
authorized by the
Associate
Administrator for
Hazardous Materials
Safety prior to
transportation. See
Secs. 173.57 and
173.58. For an
international
shipment, the
package must be
marked with
``Packaging
authorized by
competent authority
of the United
States of America
(USA).''
E-106............... Not necessary Boxes: 49 for all entries except UN
Wood, ordinary (4C1) 0434 and UN 0435.
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Steel, removable head (1A2)
E-107............... Not necessary Boxes: 57.
(a)................. Note: This packaging method Fiberboard (4G)
is to be used for boosters Wood, ordinary (4C1)
which are finished articles Plywood (4D)
consisting of closed metal, Reconstituted wood (4F)
plastic, or fiberboard Steel (4A)
receptacles that contain a Aluminum (4B)
detonating explosive, or Note: This packaging method
consisting of a plastic- is to be used for boosters
bonded detonating explosive. which are finished articles
consisting of closed metal,
plastic, or fiberboard
receptacles that contain a
detonating explosive, or
consisting of a plastic-
bonded, detonating
explosive.
E-107 (b)........... Receptacles: Boxes: 57.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Sheets: Reconstituted wood (4F)
Plastic Steel (4A)
Paper Aluminum (4B)
Note: This packaging method Note: This packaging method
is to be used for cast or is to be used for cast or
pressed boosters in tube or pressed boosters in tube or
capsules without end capsules without end
closures. closures.
E-108............... Receptacles Boxes 23
Metal Wooden, ordinary (4C1)
Plastic Plywood (4D)
Wooded Reconstituted wood (4F)
Note: Dividing partitions in Steel (4A)
the outer packaging may be Aluminum (4B)
used in place of inner
packagings.
E-109............... Receptacles: Boxes: 28
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Paper Steel (4A)
fiberboard Aluminum (4B)
E-113............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Metal Plywood (4D)
Reconstituted wood (4F)
Natural wood, with sift-proof
walls (4C2)
Steel (4A)
E-114............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Metal Plywood (4D)
Wood Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Natural wood, with sift-proof
walls (4C2)
Drums:
Steel, removable head (1A2)
E-115............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper, Kraft Plywood (4D)
(for cartridge of 1.4G and Reconstituted wood (4F)
1.4S) Steel (4A)
Plastic Aluminum (4B)
Wood Expanded plastics (4H1)
Plastics, solid (4H2)
E-116............... Bags: Boxes:
Plastic Fiberboard (4G)
Textile Wood, ordinary (4C1)
Boxes: Plywood (4D)
Fiberboard Reconstituted wood (4F)
Plastic Steel (4A)
Wood Aluminum (4B)
Note: (1) Bags are authorized
for small cases only. (2)
Dividing partitions in the
outer packaging may be used
in place of inner
packagings.
E-117............... Not necessary Boxes: 57.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
Drums:
Steel, removable head.
E-119............... Not necessary Boxes:
Wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
Plastics, solid (4H2)
Drums:
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Note: Packaging 4C1 is
authorized for cased charges
only
E-120............... Tubes: Boxes: 30, 31.
Fiberboard Fiberboard (4G)
Other materials Wood, ordinary (4C1)
Note: Dividing partitions in Plywood (4D)
the outer packaging may be Reconstituted wood (4F)
used in place of inner
packagings.
E-121............... Not necessary Boxes: 32, 57.
Fiberboard (4G1)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-122............... Boxes: Boxes: ............................
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-123............... Receptacles: Boxes: 35, 49.
Fiberboard Wood, ordinary (4C1), with
Metal metal liner
Plastics Plywood (4D)
Note: Dividing partitions in Reconstituted wood (4F)
the outer packaging may be Steel (4A)
used in place of inner Aluminum (4B)
packagings. Expanded plastics (4H1)
E-124............... Reels Boxes: 33
Receptacles: Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Aluminum (4B) Steel (4A)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
Fiber (1G)
E-125............... Bags: Boxes: 34
Plastic Fiberboard (4G)
Sheets: Wood, ordinary (4C1)
Paper, Kraft Plywood (4D)
Plastic Reconstituted wood (4F)
Note: Reels may be used in Steel (4A)
place of inner packagings. Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-126............... Receptacles: Boxes: ............................
Fiberboard Fiberboard (4G)
Note: Reels may be used in Wood, ordinary (4C1)
place of inner packagings. Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-127............... Receptacles: Boxes: ............................
Fiberboard Wood, ordinary (4C1)
Metals Plywood (4D)
Plastics Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
E-128............... Boxes: Boxes: 23, 36.
Fiberboard Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Trays: Steel (4A)
Fiberboard Aluminum (4B)
Plastic Fiberboard (4G)
Wood
Cans:
Metal
Note: All inner packagings
must be fitted with dividing
partitions.
E-129............... Receptacles: Boxes: ............................
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Sheets: Plywood (4D)
Paper Reconstituted wood (4F)
Drums:
Fiber (1G)
E-130............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1),
Metal Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper Steel (4A)
Aluminum (4B)
Expanded plastics (4H1)
Drums:
Fiber (1G)
Plastic, removable head (1H2)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-133............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper, Kraft Steel (4A)
Note: Dividing partitions in Aluminum (4B)
the outer package may be Expanded plastics (4H1)
used in place of inner Solid plastics (4H2)
packagings. Drums:
Fiber (1G)
Plastic, removable head (1H2)
Steel, removable head
Aluminum, removable head
(1B2)
E-134............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (4B)
E-135............... Bags: Boxes:
Plastic Reels Fiberboard (4G)
Sheets: Wood, ordinary (4C1)
Paper, Kraft Plywood (4D)
Plastic Reconstituted wood (4F)
E-136............... Not necessary Boxes: 32, 57
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Expanded solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-137............... Receptacles: Boxes: 56, 38 for UN 0106, 0107,
Fiberboard Wood, ordinary (4C1) 0257, 0367, 0408, 0409 and
Metal Plywood (4D) 0410 only.
Plastic Reconstituted wood (4F)
Wood Steel (4A)
Trays: Aluminum (4B)
Plastic Fiberboard (4G)
Wood Plastics, solid (4H2)
Note: Dividing partitions in Drums:
the outer packaging may be Steel, removable head (1A2)
used in place of inner
packagings.
E-138............... Optional Boxes:
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
E-139............... Receptacles: Boxes: 28 for UN 0121 only.
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Fiberboard Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
E-141............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Wood Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper Steel (4A)
Trays: Aluminum (4B)
Plastic
E-142............... Boxes: Boxes: 40, D11, D39.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Cans: Steel (4A)
Metal Aluminum (4B)
Trays:
Fiberboard, sleeved
Plastic, sleeved
Intermediate:
(Optional with inner boxes
but mandatory with trays.)
Boxes:
Fiberboard
E-143............... Boxes: Boxes:
Fiberboard Wood, ordinary (4C1)
Metal Plywood (4D)
Wood Reconstituted wood (4F)
Tubes: Steel (4A)
Fiberboard Aluminum (4B)
Trays:
Plastic
E-145............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal (for rivets, Wood, ordinary (4C1)
explosives) Plywood (4D)
Plastic Reconstituted wood (4F)
Wood Steel (4A)
Aluminum (4B)
E-146(a)............ Not necessary Boxes:
Fiberboard (4G)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Wood, ordinary (4C1)
E-146(b)............ Not necessary Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
E-146(c)............ Not necessary Boxes:
Steel (4A1)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
E-147............... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
E-149............... Optional Boxes: 42, 50.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Solid plastics (4H2)
Steel (4A)
Aluminum (4B)
E-150............... Boxes: Boxes: 12.
Fiberboard Fiberboard (4G)
metal Wood, ordinary (4C1)
Receptacles: Plywood (4D)
Metal Reconstituted wood (4F)
Plastic Steel (4A)
Sheets: Aluminum (4B)
Paper, Kraft Expanded plastics (4H1)
Plastics, solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Plastics, removable head
(1H2)
E-151............... Receptacles: Boxes: 43, 44, 45.
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Fiber (1G)
E-153............... Sheets: Boxes: 46.
Fiberboard, corrugated Wood, ordinary (4C1)
Tubes: Plywood (4D)
Fiberboard Reconstituted wood (4F)
Intermediate: Steel (4A)
Receptacles: Aluminum (4B)
Fiberboard
Metal
Plastic
E-156............... Bags: Boxes:
Plastic Fiberboard (4G)
Boxes: Wood, ordinary (4C1)
Fiberboard Plywood (4D)
Tubes: Reconstituted wood (4F)
Fiberboard Steel (4A)
Plastic Aluminum (4B)
Metal
Note: Dividing partitions in
the outer packaging may be
used in place of inner
packaging.
E-157............... Not necessary Boxes:
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-158(a)............ Bags: Boxes: 8, 10.
Paper, Kraft Fiberboard(4G)
Plastics Wood, ordinary(4C1)
Textile Wood, sift-proof(4C2)
Rubberized textile Plywood(4D)
Reconstituted wood(4F)
Solid plastics(4H2)
Drums:
Steel, removable head (1A2)
Fiber(1G)
Plywood(1D)
E-158(b)............ Receptacles: Boxes: 10
Fiberboard Fiberboard(4G)
Metal Wood, ordinary(4C1)
Plastics Wood, sift-proof(4C2)
Plywood(4D)
Reconstituted wood(4F)
Solid plastics(4H2)
E-158(c)............ Composite packagings:
Plastic receptacle with outer
solid plastic box (6HH2)
E-159(a)............ Receptacles: Boxes: 58.
Plastics Natural wood, ordinary (4C1)
Intermediate: Plywood (4D)
Bags Reconstituted wood (4F)
Plastic, in metal cans Note: DOT Spec. MC-200, motor
vehicle container may be
used as the outer packaging.
E-159(b)............ Receptacles: Drums: 59.
Plastics Steel, removable head (1A2)
Intermediate: Aluminum, removable head
Drums (1B2)
Metal Note: DOT Spec. MC-200, motor
vehicle container may be
used as the outer packaging.
US002............... Receptacles: Boxes: D2, D3.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
US003............... Receptacles: Boxes: D2, D3, D4, D10.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Intermediate: Reconstituted wood (4F)
Boxes: Steel (4A)
Fiberboard Aluminum (4B)
Wood
Sheets:
Paper, Kraft
Plastic
US004............... Receptacles: Boxes: D2, D5, D6, D7, D8.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
US005............... Boxes: Boxes: 13
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Note: Metal clips or dividing Steel (4A)
partitions in the outer Aluminum (4B)
packaging may be used in Drums:
place of inner packagings. Steel, removable head (1A2)
US006............... Jet perforating guns, charged, oiled well may be
transported under the following conditions:
a. Initiation devices carried on the same motor
vehicle or offshore supply vessel must be
segregated; each kind from every other kind, and
from the guns, tools or other supplies.
Initiation devices shall be carried in a
container having individual pockets for each such
device or in a fully enclosed steel container
lined with a non-sparking material. No more than
two initiation devices per gun shall be carried
on the same motor vehicle.
b. Each shaped charge affixed to the gun may not
contain more than 112 g (4 ounces) of explosives.
c. Each shaped charge if not completely enclosed
in glass or metal, must be fully protected by a
metal cover after installation in the gun.
d. Jet perforating guns classed as 1.1D or 1.4D
may be transported by highway by private or
contract carriers engaged in oil well operations.
1. Motor vehicles must have specially built racks
or carrying cases designed and constructed so
that guns are securely held in place during
transportation and are not subject to damage by
contact, one to the other or other articles or
materials carried in the vehicle, and;
2. The assembled gun or guns packed on the vehicle
may not extend beyond the body of the motor
vehicle.
e. Jet perforating guns classed as 1.4D may be
transported by private offshore supply vessels
only when the guns are carried in motor vehicles
as specified in paragraph (d) of this packing
method or on offshore down-hole tool pallets
provided that:
1. All the conditions specified in paragraphs (a),
(b), and (c) of this packing method are met;
2. The total explosive contents does not exceed
9.1 kg (20 pounds) per pallet;
3. Each cargo vessel compartment may contain up to
90.8 kg (200 pounds) of explosive content if the
segregation requirements in Sec. 176.83(b)(3) of
this subchapter are met; and
4. When more than one vehicle or pallet is stowed
``on deck'' a minimum horizontal separation of 3
m (9.8 feet) must be provided.
------------------------------------------------------------------------
(d) Table of particular packaging requirements or exceptions.
------------------------------------------------------------------------
Number
identifying
packaging Explanation of packaging requirement or exception
requirement or
exception
------------------------------------------------------------------------
1............... Water soluble substances must be packed in waterproof
receptacles.
2............... Packages must be lead-free.
3............... The barrels and drums must have a watertight seal.
4............... The intermediate and outer packagings must be filled
with water or an appropriate water saturated material
when the intermediate packaging is a rubber or
rubberized textile bag.
7............... Metal drums used for powder paste must be so
constructed that explosion is not possible by reason
of increase in internal pressure from internal or
external causes.
8............... The inside of drums and jerricans must be galvanized,
painted or otherwise protected. Bare steel must not
come into contact with smokeless powder.
9............... Drums or jerricans of steel must be constructed
without pockets or crevices in which smokeless powder
could be trapped or nipped.
10.............. Metal receptacles must be so constructed that the risk
of explosion, by reason of increase in internal
pressure from internal or external causes, is
reduced.
11.............. The inner packagings must be sealed.
12.............. Outer boxes of natural wood may be provided with tin-
plate liner having a sealed lid.
13.............. Open ends of inner packagings must be fitted with
padded end caps or the outer packaging must be
padded.
22.............. The inner packagings must be separated from the outer
packaging by a gap of not less than 25 mm (1 inch) of
cushioning material, e.g., sawdust, wood, wool.
28.............. Metal inner packagings must be padded with cushioning
material.
30.............. The shaped charges must be packed so that contact
between them is prevented.
31.............. The conical cavities of the shaped charges must face
inward in pairs or groups to minimize the shaped
charge (jetting) effect in the event of accidental
initiation.
32.............. The ends of the articles must be sealed or the use of
bags, plastics, as inner packaging is mandatory.
33.............. The ends of the detonating cord must be sealed and
tied fast.
34.............. The ends of the detonating cord must be sealed. Spaces
must be filled with packing material.
35.............. Packagings must be sealed against the ingress of
water.
36.............. The detonators must be cushioned to prevent
significant movement and contact between them.
38.............. The detonating fuses must be separated from each other
in the inner packaging.
41.............. The primers must be packed with shock absorbent layers
of felt, paper or plastic to prevent propagation
within the outer packaging.
42.............. The outer plastic packagings must be reinforced with
metal at corners and edge.
43.............. The signals must be separated to prevent contact with
one another and kept apart from the bottom, walls,
and lid of the outer packaging, e.g., by cushioning
material.
44.............. Where the signals are contained in magazines for
fitting into automatic units, the magazine may
replace the inner packaging provided adequate
cushioning material is used.
45.............. Tin-plate inner packagings must be sealed.
46.............. The sounding device must be wrapped individually in
corrugated fiberboard sheets or inserted in
fiberboard tubes.
47.............. Absorbent cushioning material must be inserted.
48.............. Large articles without propelling charge and without
means of ignition or initiation may be carried
unpacked.
49.............. Large articles without their means of initiation, or
with their means of initiation containing at least
two effective protective features, may be carried
unpackaged.
50.............. Large articles without their means of ignition may be
carried unpackaged.
53.............. Bags, sift-proof (5H2) recommended only for flake or
prilled TNT in the dry state and a maximum net mass
of 30 kg (66 pounds).
55.............. Not more than 50 g (1.8 ounces) of a substance shall
be packed in an inner packaging.
56.............. Fiberboard boxes (4G) are not authorized outer
packagings for UN0106 or UN0107.
57.............. Liner or inner coating required for metal outer
packagings unless another means, such as the use of
an inner packaging or cushing material protects the
explosive substance from contact with the metal outer
packaging during normal conditions of transport.
58.............. Plastic receptacles must have taped screw cap closures
and be of not more than 5 liters capacity each. Each
receptacle should be contained within an intermediate
packaging. Each plastic bag should be surrounded on
all sides with at least 50 mm of non-combustible
absorbent cushioning material: metal cans in the
outer packaging must also be cushioned from each
other in all directions. Net mass of propellent
should be limited to 30 kg for each package.
59.............. The intermediate drum must be surrounded on all sides
with at least 50 mm of non-combustible absorbent
cushioning material. A composite packaging consisting
of a plastic receptacle in a metal drum may be used
instead of the inner and intermediate packagings. The
net volume of propellent in each packaging must not
exceed 120 liters.
D1.............. The intermediate packaging must be entirely surrounded
by wetted cushioning material within the outer
packaging.
D2.............. Quantity limitations for all detonators are as follows
unless specifically defined for each type of
detonator:
(a) For detonators containing no more than 10 g of
explosive (excluding ignition and delay charges):
(i) No more than 50 detonators may be packed in one
inner packaging.
(ii) No more than 500 detonators may be packed in one
outer packaging.
(b) For detonators containing no more than 3 g of
explosive (excluding ignition and delay charges):
(i) No more than 100 detonators may be packed in one
inner packaging.
(ii) No more than 1000 detonators may be packed in one
outer packaging.
(c) There are no quantity limitations for detonators
classed as 1.4B or 1.4S. The number of detonators
that may be packed in each inner or outer (if inner
packaging is not required) packaging is determined
by:
(i) The ability for that package to pass certain tests
(see Sec. 173.57) that qualify the detonators to be
classed as 1.4B or 1.4S; or
(ii) The gross weight limitations of the packaging
used.
D3.............. Inner packaging is not required for electric blasting
caps when packed in pasteboard tubes, or when their
leg wires are wound on spools with the caps either
placed inside the spool or securely taped to the wire
on the spool, so as to restrict freedom of movement
of the caps and to protect them from impact forces.
No more than 500 electric blasting caps shall be
contained in one outer packaging.
D4.............. Intermediate packagings are required only for non-
electric detonators that are blasting caps or delay
connectors in metal tubes.
D5.............. Blasting caps are not required to be attached to the
safety fuse, metal clad mild detonating cord,
detonating cord, or shock tube.
D6.............. Inner packagings are not required if the packing
configuration restricts freedom of movement of the
caps and protects them from impact forces.
D7.............. Quantity limitations for detonator assemblies with
detonating cord are:
(a) No more than 50 detonator assemblies shall be
packed in one inner packaging.
(b) No more than 500 detonator assemblies shall be
packed in one outer packaging.
D8.............. Quantity limitations for detonator assemblies with
safety fuse or shock tube are:
(a) No more than 50 detonator assemblies shall be
packed in one inner packaging.
(b) No more than 1,000 detonator assemblies shall be
packed in one outer packaging.
D9.............. Primers fitted with anvil, composition not covered
with a disc of metal foil or other material
(varnished only).
(a) The primers must be packed in rows in single
layers in trays of fiberboard or plastic.
(b) Not more than 500 primers shall be packed in an
inner packaging.
D10............. Detonators that are blasting caps (including
percussion activated) or delay connectors in metal
tubes must be packed as follows:
(a) The detonators must be packed in an inner
packaging with the open end of any detonator covered
with appropriate cushioning material;
(b) Inner packagings must be snugly packed in an
intermediate packaging;
(c) Intermediate packagings must be separated from the
outside packaging by at least 25 mm (1 inch) of
cushioning material;
(d) Detonators containing no more than 10 g of
explosive (excluding ignition and delay charges) must
be packed as follows:
(i) No more than 50 detonators in one inner packaging.
(ii) No more than 500 detonators in one outer
packaging.
(e) Detonators containing no more than 3 g of
explosive (excluding ignition and delay charges) must
be packed as follows:
(i) No more than 110 detonators in one inner
packaging.
(ii) No more than 5,000 detonators in one outer
packaging.
D11............. Primers not fitted with an anvil, composition covered,
not more than 5,000 primers shall be packed in an
inner packaging.
D12............. Large articles may be carried unpackaged.
D13............. No inner packaging required for drums, fiber (1G).
D14............. Inner packaging is not required with fiberboard boxes
(4G) for packaging UN 0332.
D15............. Sheets, waterproof, when used, must also be impervious
to any liquid explosive ingredients of the substance.
------------------------------------------------------------------------
* * * * *
Sec. 173.62 [Amended]
45. In addition, in Sec. 173.62, in paragraph (e), the phrase
``January 1, 1988'' would be removed and replaced with the phrase
``January 1, 1990'' each place it appears.
46. In Sec. 173.115, paragraphs (b)(3) and (b)(4) would be added to
read as follows:
Sec. 173.115 Class 2, Divisions 2.1, 2.2, and 2.3--Definitions.
* * * * *
(b) * * *
(3) Is asphyxiant. An asphyxiant gas is a gas which dilutes or
replaces oxygen normally in the atmosphere; or
(4) Is oxidizing. An oxidizing gas is defined as a gas which may,
generally by providing oxygen, cause or contribute to the combustion of
other material more than air does.
* * * * *
Sec. 173.115 [Amended]
47. In addition, in Sec. 173.115, the wording ``, and'' at the end
of paragraph (b)(1) and the period at the end of paragraph (b)(2) would
be removed and replaced with a semicolon.
48. Section 173.120 would be amended by revising paragraph (a) and
adding a sentence at the end of paragraph (b)(2) to read as follows:
Sec. 173.120 Class 3--Definitions.
(a) Flammable liquid. For the purpose of this subchapter, a
flammable liquid (Class 3) means a liquid having a flash point of not
more than 60.5 deg.C (141 deg.F), or any material in a liquid phase
with a flash point at or above 37.8 deg.C (100 deg.F) that is
intentionally heated and offered for transportation or transported at
or above its flash point in a bulk packaging, with the following
exceptions:
(1) Any liquid meeting one of the definitions specified in
Sec. 173.115.
(2) Any mixture having one or more components with a flash point of
60.5 deg.C (141 deg.F) or higher, that make up at least 99 percent of
the total volume of the mixture, if the mixture is not offered for
transportation or transported at or above its flash point.
(3) Any liquid with a flash point greater than 35 deg.C (95
deg.F) which does not sustain combustion. A procedure for determining
if a material sustains combustion when heated under test conditions and
exposed to an external source of flame is provided in Appendix H of
this part.
(4) Any liquid with a flash point greater than 35 deg.C (95
deg.F) and with a fire point greater than 100 deg.C (212 deg.F)
according to ISO 2592-1973.
(5) Any liquid with a flash point greater than 35 deg.C (95
deg.F) which is in a water miscible solution with a water content of
more than 90 percent by mass.
(b) * * *
(2) * * * An elevated temperature material that meets the
definition of a Class 3 material because it is intentionally heated and
offered for transportation or transported at or above its flash point
may not be reclassed as a combustible liquid.
* * * * *
Sec. 173.120 [Amended]
49. In addition, in Sec. 173.120, the following changes would be
made:
a. In paragraph (c)(1)(i)(A), the wording ``ASTM D56-79'' would be
revised to read ``ASTM D 56-87''.
b. In paragraphs (c)(1)(i)(B) and (c)(1)(ii)(B), the wording ``ASTM
D3278-78'' would be revised to read ``ASTM D 3278-89''.
c. In paragraph (c)(1)(ii)(A), the wording ``ASTM D93-80'' would be
revised to read ``ASTM D 93-90''.
50. Section 173.121 would be amended by adding a parenthetical note
at the end of paragraph (b)(1)(ii) before the semicolon and revising
the paragraph (b)(1)(iv) table and paragraph (b)(2)(i) to read as
follows:
Sec. 173.121 Class 3--Assignment of packing group.
* * * * *
(b) * * *
(1) * * *
(ii) * * * (Note: The mixture is not necessarily required to bear a
POISON or CORROSIVE subsidiary risk label);
* * * * *
(iv) * * *
------------------------------------------------------------------------
Jet
Flow time t in seconds diameter Flash point c.c.
in mm
------------------------------------------------------------------------
2060............. 4 Above 17 deg.C (62.6 deg.F).
60100............ 4 Above 10 deg.C (50 deg.F).
2032............. 6 Above 5 deg.C (41 deg.F).
3244............. 6 Above -1 deg.C (31.2 deg.F).
44100............ 6 Above -5 deg.C (23 deg.F).
1005 minutes
for each mounting position (direction of vibrator) of the battery. The
battery must be tested in three mutually perpendicular positions (to
include testing with fill openings and vents, if any, in an inverted
position) for equal time periods.
(2) Pressure differential test. Following the vibration test, the
battery must be stored for six hours at 24 deg.Cplus-minuss>4
deg.C (75 deg.plus-minuss>7 deg.F) while subjected to a pressure
differential of at least 88 kPa (13 psi). The battery must be tested in
three mutually perpendicular positions (to include testing with fill
openings and vents, if any, in an inverted position) for at least six
hours in each position.
(b) Except as provided in Sec. 175.10(a)(19) of this subchapter, a
nonspillable battery is not subject to any other requirements of this
subchapter if--
(1) The battery is protected against short circuits and securely
packaged; and
(2) For a battery manufactured after September 30, 1995, the
battery and any outer packaging is plainly and durably marked
``NONSPILLABLE'' or ``NONSPILLABLE BATTERY''.
Sec. 173.171 [Amended]
65. In Sec. 173.171, in paragraph (a), the wording ``Division 1.3
classification'' would be revised to read ``Division 1.3 and Division
4.1 classification''.
66. Section 173.185 would be revised to read as follows:
Sec. 173.185 Lithium cells and batteries.
(a) Except as otherwise provided in this subpart, a lithium cell or
battery is authorized for transportation only if it conforms to the
provisions of this section.
(b) Exceptions. Cells and batteries are not subject to the
requirements of this subchapter if they meet the following
requirements:
(1) Each cell with a liquid cathode may contain no more than 0.5 g
(0.02 ounce) of lithium or lithium alloy, and each cell with a solid
cathode may contain no more than 1.0 g (0.04 ounce) lithium or lithium
alloy;
(2) Each battery with a liquid cathode may contain an aggregate
quantity of no more than 1.0 g (0.04 ounce) lithium or lithium alloy,
and each battery with a solid cathode may contain an aggregate quantity
of no more than 2.0 g (0.07 ounce) of lithium or lithium alloy;
(3) Each cell must be hermetically sealed;
(4) Cells and batteries must be separated so as to prevent short
circuits and must be packed in strong packagings, except when installed
in equipment; and
(5) If a liquid cathode battery contains more than 0.5 g (0.02
ounce) of lithium or lithium alloy or a solid cathode battery contains
more than 1.0 g (0.04 ounce) lithium or lithium alloy, it may not
contain a liquid or gas that is a hazardous material according to this
subchapter unless the liquid or gas, if free, would be completely
absorbed or neutralized by other materials in the battery.
(c) Cells and batteries also are not subject to this subchapter if
they meet the following requirements:
(1) Each cell contains not more than 5 g (0.18 ounces) of lithium
or lithium alloy;
(2) Each battery contains not more than 25 g (0.88 ounces) of
lithium or lithium alloy;
(3) Each cell or battery is of the type proved to be non-dangerous
by testing in accordance with tests in Part IV of the UN
Recommendations on the Transport of Dangerous Goods, Tests and
Criteria, Third Edition 1994; such testing should be carried out on
each type prior to the initial transport of that type; and
(4) Cells and batteries are designed or packed in such a way as to
prevent short circuits under conditions normally encountered in
transportation.
(d) Cells and batteries and equipment containing cells and
batteries which were first transported prior to January 1, 1995 and
were assigned to Class 9 on the basis of the requirements of this
subchapter in effect on October 1, 1993 may continue to be transported
in accordance with the applicable requirements in effect on October 1,
1993.
(e) Cells and batteries may be transported as items of Class 9 if
they meet the requirements in paragraphs (e)(1) through (e)(9) of this
section:
(1) Cells must not contain more than 12 g (0.42 ounce) of lithium
or lithium alloy. When transported by passenger aircraft, cells must
not contain more than 3 g (0.11 ounces) of lithium or lithium alloy.
(2) Batteries must not contain more than 500 g (17.6 ounces) of
lithium or lithium alloy. When transported by passenger aircraft,
batteries must not contain more than 125 g (4.4 ounces) of lithium or
lithium alloy.
(3) Each cell and battery must be equipped with an effective means
of preventing external short circuits.
(4) Each cell and battery must incorporate a safety venting device
or be designed in a manner that will preclude a violent rupture under
conditions normally incident to transportation.
(5) Batteries containing cells or series of cells connected in
parallel must be equipped with diodes to prevent reverse current flow.
(6) Cells and batteries must be packed in strong inner packagings
containing not more than 500 g (17.6 ounces) of lithium or lithium
alloy. When transported by passenger aircraft, inner packagings must
not contain more than 125 g (4.4 ounces) of lithium or lithium alloy.
(7) Cells and batteries must be packed in inner packagings in such
a manner as to effectively prevent short circuits and to prevent
movement which could lead to short circuits.
(8) Cells and batteries must be packaged in packagings conforming
to the requirements of part 178 of this subchapter at the Packing Group
II performance level:
(i) Inner packagings must be packed within a wooden box (4C1, 4C2,
4D, or 4F), fiberboard box (4G), fiber drum (1G), or metal drum (1A2 or
1B2);
(ii) Cells and batteries intended for air transportation must be
packaged in metal drums (1A1 or 1B2) fitted with gas-tight gaskets; and
(iii) When the outer packaging is metal, the inner packagings must
be separated from each other and from the outer packaging by at least
25 mm (1 inch) of non-combustible cushioning material.
(9) One of the following criteria must be met:
(i) Each cell or battery is of the type proven to meet the criteria
of Class 9 by testing in accordance with tests in Part IV of the UN
Recommendations on the Transport of Dangerous Goods, Tests and
Criteria, Third Edition 1994; or
(ii) Ten cells and one battery of each type taken from production
each week should be subjected to extreme temperature exposure and the
short circuit test procedures in Part IV of the UN Recommendations on
the Transport of Dangerous Goods, Tests and Criteria, Third Edition
1994, or, equivalent tests approved by the Associate Administrator for
Hazardous Materials Safety. There should be no evidence of distortion,
leakage or internal heating in conducting the extreme temperature
exposure test procedure. In conducting the short circuit test
procedure, if venting occurs, an open flame applied to venting fumes
should not produce an explosive condition; or
(iii) Cells and batteries that are hermetically sealed are excepted
from paragraphs (e)(8)(ii) and (e)(8)(iii) if the cells and batteries
are subjected to the altitude simulation, extreme temperature exposure,
vibration, and shock tests described in the UN Recommendations on the
Transport of Dangerous Goods, Tests and Criteria, Third Edition 1994,
or equivalent tests approved by the Associate Administrator for
Hazardous Materials Safety, and show no visible evidence of out-
gassing, leakage, loss of mass or distortion.
(10) Except as provided in paragraph (i) of this section, cells or
batteries may not be offered for transportation or transported if any
cell has been discharged to the extent that the open circuit voltage is
less than two volts or is less than 2/3 of the voltage of the fully
charged cell, whichever is less.
(f) Equipment containing or packed with cells and batteries meeting
the requirements of paragraph (b) or (c) of this section are excepted
from all other requirements of this subchapter.
(g) Equipment containing or packed with cells and batteries may be
transported as items of Class 9 if the batteries and cells meet all the
requirements of paragraph (e) of this section and are packaged as
follows:
(1) Equipment containing cells and batteries must be packed in a
strong outer packaging that is waterproof or is made waterproof through
the use of a liner. The equipment must be secured within the outer
packaging and be packed as to effectively prevent movement, short
circuits, and accidental operation during transport; and
(2) Cells and batteries packed with equipment should be packed in
inner packagings conforming to paragraph (e)(9) of this section in such
a manner as to effectively prevent movement and short circuits. Not
more than 5 kg of cells and batteries may be packed with each item of
equipment.
(h) Cells and batteries, for disposal, may be offered for
transportation or transported to a permitted storage facility and
disposal site by motor vehicle when they meet the following
requirements:
(1) Cells must not contain more than 12 g (0.42 ounce) and
batteries must not contain more than 500 g (17.6 ounces) of lithium or
lithium alloy;
(2) Be equipped with an effective means of preventing external
short circuits; and
(3) Are packed in a strong outer packaging conforming to the
requirements of Secs. 173.24 and 173.24a. The packaging need not
conform to performance requirements of part 178 of this subchapter.
(i) Cells and batteries and equipment containing or packed with
cells and batteries which do not comply with the provisions of this
section may be transported only if they are approved by the Associate
Administrator for Hazardous Materials Safety.
(j) For testing purposes, cells containing not more than 12 g (0.42
ounce) of lithium or lithium alloy and batteries containing not more
than 500 g (17.6 ounces) of lithium or lithium alloy may be offered for
transportation or transported by highway only as items of Class 9.
Packaging must conform with paragraphs (e)(8)(i) and (iii) of this
section with not more than 100 cells per package.
67. Section 173.189 would be added to read as follows:
Sec. 173.189 Batteries containing sodium or cells containing sodium.
(a) Batteries and cells may not contain any hazardous material
other than sulfur. Cells not forming a component of a completed battery
may not be offered for transportation at a temperature at which any
liquid sodium is present in the cell. Batteries may only be offered for
transportation, or transported, at a temperature at which any liquid
sodium present in the battery conforms to the conditions prescribed in
paragraph (d) of this section.
(b) Cells must consist of hermetically sealed metal casings which
fully enclose the hazardous materials and which are so constructed and
closed as to prevent the release of the hazardous materials under
normal conditions of transport. Cells must be placed in suitable outer
packagings with sufficient cushioning material to prevent contact
between cells and between cells and the internal surfaces of the outer
packaging, and to ensure that no dangerous movement of the cells within
the outer packaging occurs in transport. Cells must be packaged in 1A2,
1B2, 1D, 1G, 1H2, 4C, 4D, 4F, 4G or 4H2 outer packagings which meet the
requirements of part 178 of this subchapter at the Packing Group II
performance level.
(c) Batteries must consist of cells secured within, and fully
enclosed by a metal casing so constructed and closed as to prevent the
release of the hazardous materials under normal conditions of
transport. Batteries may be offered for transportation, and
transported, unpacked or in protective packagings that are not subject
to the requirements of part 178 of this subchapter.
(d) Batteries containing any liquid sodium may not be offered for
transportation, or transported, by aircraft. Batteries containing
liquid sodium may be transported by motor vehicle, rail car or vessel
under the following conditions:
(1) Batteries must be equipped with an effective means of
preventing external short circuits, such as by providing complete
electrical insulation of battery terminals or other external electrical
connectors. Battery terminals or other electrical connectors
penetrating the heat insulation fitted in battery casings must be
provided with thermal insulation sufficient to prevent the temperature
of the exposed surfaces of such devices from exceeding 55 deg.C (130
deg.F).
(2) No battery may be offered for transportation if the temperature
at any point on the external surface of the battery exceeds 55 deg.C
(130 deg.F).
(3) If any external source of heating is used during transportation
to maintain sodium in batteries in a molten state, means must be
provided to ensure that the internal temperature of the battery does
not reach or exceed 400 deg.C (752 deg.F).
(4) When loaded in a transport vehicle or freight container:
(i) Batteries must be secured so as to prevent significant movement
within the transport vehicle or freight container under conditions
normally incident to transportation;
(ii) Adequate ventilation and/or separation between batteries must
be provided to ensure that the temperature at any point on the external
surface of the battery casing will not exceed 240 deg.C (464 deg.F)
during transportation; and
(iii) No other hazardous materials, with the exception of cells
containing sodium, may be loaded in the same transport vehicle or
freight container. Batteries must be separated from all other freight
by a distance of not less than 0.5 meters (1.6 feet).
Sec. 173.196 [Amended]
68. In Sec. 173.196, in paragraph (f), the wording ``the primary
receptacle and secondary packaging'' would be revised to read ``the
primary receptacle or secondary packaging''.
Sec. 173.211 [Amended]
69. In Sec. 173.211, in paragraph (c), for the entry ``Steel box
with liner:'', the wording ``4A2'' would be revised to read ``4A''; and
for the entry ``Aluminum box with liner:'' the wording ``4B2'' would be
revised to read ``4B''.
Sec. 173.212 [Amended]
70. In Sec. 173.212, in paragraph (c), for the entry ``Steel box:''
the wording ``4A1'' would be revised to read ``4A''; for the entry
``Steel box with liner:'' the wording ``4A2'' would be revised to read
``4A''; for the entry ``Aluminum box:'' the wording ``4B1'' would be
revised to read ``4B''; and for the entry ``Aluminum box with liner:''
the wording ``4B2'' would be revised to read ``4B''.
Sec. 173.213 [Amended]
71. In Sec. 173.213, in paragraph (c), for the entry ``Steel box
with liner:'' the wording ``4A2'' would be revised to read ``4A''; for
the entry ``Steel box:'' the wording ``4A1'' would be revised to read
``4A''; and for the entry ``Aluminum box with liner:'' the wording
``4B2'' would be revised to read ``4B''.
72. Section 173.224 would be revised to read as follows:
Sec. 173.224 Packaging and control and emergency temperatures for
self-reactive materials.
(a) General. When the Sec. 172.101 Table of this subchapter
specifies that a Division 4.1 material be packaged in accordance with
this section, only packagings which conform to the provisions of this
section may be used. Each packaging must conform to the general
packaging requirements of subpart B of this part and the applicable
requirements of part 178 of this subchapter. Non-bulk packagings must
meet Packing Group II performance levels. To avoid unnecessary
confinement, metallic non-bulk packagings meeting Packing Group I are
not authorized. Self-reactive materials which require temperature
control are subject to the provisions of Sec. 173.21(f). Packagings
required to bear a Class 1 subsidiary label must conform to
Secs. 173.60 through 173.62.
(b) Self-Reactive Materials Table: The self-reactive materials
table specifies, by technical name, those self-reactive materials that
are authorized for transportation and not subject to the approval
provisions of Sec. 173.124(a)(2)(vii). A self-reactive material
identified by technical name in the following table is authorized for
transportation only if it conforms to all applicable provisions of the
table. The column headings of the Self-Reactive Materials Table are as
follows:
(1) Technical name. Column 1 specifies the technical name.
(2) ID number. Column 2 specifies the identification number which
is used to identify the proper shipping name in the Sec. 172.101 Table.
(3) Concentration of self-reactive material. Column 3 specifies the
concentration (percent) limitations, if any, in mixtures or solutions
for the self-reactive material. Limitations are given as minimums,
maximums, or a range, as appropriate. A range includes the lower and
upper limits (i.e., ``53-100'' means from, and including, 53 percent
to, and including 100 percent).
(4) Packing method. Column 4 species the highest packing method
which is authorized for the self-reactive material. A packing method
corresponding to a smaller package size may be used, but a packing
method corresponding to a larger package size may not be used. The
Table of Packing Methods in Sec. 173.225(d) defines the packing
methods. Additional bulk packagings are authorized in paragraph (d) of
this section for Type F self-reactive materials.
(5) Control temperature. Column 5 specifies the control temperature
in deg.C. Temperatures are specified only when temperature controls
are required (see Sec. 173.21(f)).
(6) Emergency temperature. Column 6 specifies the emergency
temperature in deg.C. Temperatures are specified only when temperature
controls are required (see Sec. 173.21(f)).
(7) Notes. Column 7 specifies other applicable provisions, as set
forth in notes following the table.
Self-Reactive Materials Table
Control Emergency
Self-reactive Identification Concentration Packing method temperature ( temperature ( Notes
substance number (%) deg.C) deg.C)
(1) (2) (3) (4) (5) (6) (7)
----------------------------------------------------------------------------------------------------------------
Azodicarbonamide 3232 <100 OP5B .............. .............. .......
formulation type B.
Azodicarbonamide 3234 <100 OP6A .............. .............. .......
formulation type C.
Azodicarbonamide 3236 <100 OP7B .............. .............. .......
formulation type D.
2,2'-Azodi(2,4- 3236 100 OP7B -5 +5 .......
dimethyl-4-
methoxyvaleronitrile
).
2,2'-Azodi(2,4- 3236 100 OP7B +10 +15 .......
dimethylvaleronitril
e).
2,2'-Azodi(ethyl 2- 3235 100 OP7A +20 +25 .......
methylpropionate).
1,1- 3236 100 OP7B .............. .............. .......
Azodi(hexahydrobenzo
nitrile).
2,2'- 3234 100 OP6B +40 +45 .......
Azodi(isobutyronitri
le).
2,2'-Azodi(2- 3236 100 OP7B +35 +40 .......
methylbutyronitrile).
Benzene-1,3- 3236 52 OP7B .............. .............. .......
disulphohydrazide,
as a paste.
Benzene 3236 100 OP7B .............. .............. .......
sulphohydrazide.
4- 3236 100 OP7B .............. .............. .......
(Benzyl(ethyl)amino)-
3-
ethoxybenzenediazoni
um zinc chloride.
4- 3236 100 OP7B +40 +45 .......
(Benzyl(methyl)amino
)-3-
ethoxybenzenediazoni
um zinc chloride.
3-Chloro-4- 3236 100 OP7B .............. .............. .......
Diethylamino-
benzenediazonium
zinc chloride.
2-Diazo-1-Naphthol-4- 3222 100 OP5B .............. .............. .......
sulphochloride.
2-Diazo-1-Naphthol-5- 3222 100 OP5B .............. .............. .......
sulphochloride.
2,5-Diethoxy-4- 3236 67-100 OP7B +35 +40 .......
morpholino-
benzenediazonium
zinc chloride.
2,5-Diethoxy-4- 3236 66 OP7B +40 +45 .......
morpholino-
benzenediazonium
zinc chloride.
2,5-Diethoxy-4- 3236 100 OP7B +30 +35 .......
morpholino-
benzenediazonium
tetrafluoroborate.
2,5-Diethoxy-4- 3236 67 OP7B +40 +45 .......
(phenylsulphonyl)ben
zenediazonium zinc
chloride.
2,5-Dimethoxy-4-(4- 3236 79 OP7B +40 +45 .......
methylphenylsulphony
)benzene-diazonium
zinc chloride.
4-Dimethylamino-6-(2- 3236 100 OP7B +40 +45 .......
dimethylaminoethoxy)
toluene-2-diazonium
zinc chloride.
N,N'-Dinitroso-N,N'- 3224 72 OP6B .............. .............. .......
dimethyl-
terephthalamide, as
a paste.
N,N'- 3224 82 OP6B .............. .............. 1
Dinitrosopentamethyl
enetetramine.
Diphenyloxide-4,4'- 3226 100 OP7B .............. .............. .......
Disulphohydrazide.
4- 3226 100 OP7B .............. .............. .......
Dipropylaminobenzene
diazonium zinc
chloride.
2-(N,N- 3236 63-92 OP7B +40 +45 .......
Ethoxycarbonylphenyl
amino)-3-methoxy-4-
(N-methyl-N-
cyclohexylamino)benz
enediazonium zinc
chloride.
2-(N,N- 3236 62 OP7B +35 +40 .......
Ethoxycarbonylphenyl
amino)-3-methoxy-4-
(N-methyl-N-
cyclohexylamino)benz
enediazonium zinc
chloride.
N-Formyl-2- 3236 100 OP7B +45 +50 .......
(nitromethylene)-1,3-
perhydrothiazine.
2-(2-Hydroxyethoxy)-1- 3236 100 OP7B +45 +50 .......
(pyrrolidin-1-
yl)benzene-4-
diazonium zinc
chloride.
3-(2-Hydroxyethoxy)-4- 3236 100 OP7B +40 +45 .......
(pyrrolidin-1-
yl)benzenediazonium
zinc chloride.
2-(N,N- 3236 96 OP7B +45 +50 .......
Methylaminoethylcarb
onyl)-4-(3,4-
dimethyl-
phenylsulphonyl)benz
ene-diazonium zinc
chloride.
4- 3226 100 OP7B +40 +45 .......
Methylbenzenesulphon
ylhydrazide.
3-Methyl-4- 3234 95 OP6B +45 +50 .......
(pyrrolidin-1-yl)
benzenediazonium
tetrafluoroborate.
4-Nitrosophenol...... 3236 100 OP7B +35 +40 .......
Self-reactive liquid, 3223 .............. OP2A .............. .............. 2
sample.
Self-reactive liquid, 3233 .............. OP2A .............. .............. 2
sample, temperature
control.
Self-reactive solid, 3224 .............. OP2B .............. .............. 2
sample.
Self-reactive solid, 3234 .............. OP2B .............. .............. 2
sample, temperature
control.
Sodium 2-diazo-1- 3226 100 OP7B .............. .............. .......
naphthol-4-
sulphonate.
Sodium 2-diazo-1- 3226 100 OP7B .............. .............. .......
naphthol-5-
sulphonate.
Tetramine palladium 3234 100 OP6B +30 +35 .......
(II) nitrate.
1. With a compatible diluent having a boiling point of not less than 150 C.
2. Samples may only be offered for transportation when all available data indicate that the sample is no more
dangerous than a self-reactive substance type C, and the sample is packaged using packaging method OP2A for
liquids or OP2B for solids, as appropriate, in quantities less than 10 kg per shipment, employing any
necessary temperature controls.
(c) New self-reactive materials, formulations and samples. (1)
Except as provided for samples in paragraph (c)(4) of this section, no
person may offer, accept for transportation, or transport a self-
reactive material which is not identified by technical name in the
Self-Reactive Materials Table of this section, or a formulation of one
or more self-reactive materials which are identified by technical name
in the table, unless the self-reactive material is assigned a generic
type and shipping description and is approved by the Associate
Administrator for Hazardous Materials Safety under the provisions of
Sec. 173.124(a)(2)(vii).
(2) Except as provided by an approval issued under
Sec. 173.124(a)(2)(vii), intermediate bulk and bulk packagings are not
authorized.
(3) Non-bulk packagings are authorized as specified in the Packing
Method Table for Generic Types, as follows. Column 1 of the table
specifies the generic type by identification number. Column 2 of the
table specifies the generic proper shipping name from the Sec. 172.101
Table. Column 3 of the table specifies the series of packing methods
authorized for use. The Table of Packing Methods in Sec. 173.225(d)
defines the packing methods. The Packing Method Table for Generic Types
is as follows:
Packing Method Table for Generic Types
Packing Method Table for Generic Types
Packing
UN No. Proper shipping name method
(1) (2)............................................ (3)
------------------------------------------------------------------------
3221.... Self-reactive liquid Type B.................... OP1A-OP5A
3222.... Self-reactive solid Type B..................... OP1B-OP5B
3223.... Self-reactive liquid Type C.................... OP1A-OP6A
3224.... Self-reactive solid Type C..................... OP1B-OP6B
3225.... Self-reactive liquid Type D.................... OP1A-OP7A
3226.... Self-reactive solid Type D..................... OP1B-OP7B
3227.... Self-reactive liquid Type E.................... OP1A-OP8A
3228.... Self-reactive solid Type E..................... OP1B-OP8B
3229.... Self-reactive liquid Type F.................... OP1A-OP8A
3230.... Self-reactive solid Type F..................... OP1B-OP8B
3231.... Self-reactive liquid Type B, temperature OP1A-OP5A
controlled.
3232.... Self-reactive solid Type B, temperature OP1B-OP6B
controlled.
3233.... Self-reactive liquid Type C, temperature OP1A-OP6A
controlled.
3234.... Self-reactive solid Type C, temperature OP1B-OP7B
controlled.
3235.... Self-reactive liquid Type D, temperature OP1A-OP7A
controlled.
3236.... Self-reactive solid Type D, temperature OP1B-OP8B
controlled.
3237.... Self-reactive liquid Type E, temperature OP1A-OP8A
controlled.
3238.... Self-reactive solid Type E, temperature OP1B-OP8B
controlled.
3239.... Self-reactive liquid Type F, temperature OP1A-OP8A
controlled.
3240.... Self-reactive solid Type F, temperature OP1B-OP8B
controlled.
(4) Samples. Samples of new self-reactive materials or new
formulations of self-reactive materials identified in the Self-Reactive
Materials Table in paragraph (b) of this section, for which complete
test data are not available, and which are to be transported for
further testing or evaluation, may be assigned an appropriate shipping
description for Self-reactive materials Type C, packaged and offered
for transportation under the following conditions:
(i) Data available to the person offering the material for
transportation must indicate that the sample would pose a level of
hazard no greater than that of a self-reactive material Type B and that
the control temperature, if any, is sufficiently low to prevent any
dangerous decomposition and sufficiently high to prevent any dangerous
phase separation;
(ii) The sample must be packaged in accordance with packing method
OP2A or OP2B, for a liquid or a solid, respectively;
(iii) Packages of the self-reactive material may be offered for
transportation and transported in a quantity not to exceed 10 kg (22
pounds) per transport vehicle; and
(iv) One of the following shipping descriptions must be assigned:
(A) Self-reactive, liquid, type C, 4.1, UN3223.
(B) Self-reactive, solid, type C, 4.1, UN3224.
(C) Self-reactive, liquid, type C, temperature controlled, 4.1,
UN3233.
(D) Self-reactive, solid, type C, temperature controlled, 4.1,
UN3234.
(d) Self-reactive substances of Type F may not be transported in
bulk or intermediate bulk containers except as approved, in writing, by
the Associate Administrator for Hazardous Materials Safety.
73. In Sec. 173.225, the fourth sentence of paragraph (a) and the
Organic Peroxides Table in paragraph (b) would be revised, and a new
paragraph (c)(5) would be added to read as follows:
Sec. 173.225 Packaging requirements and other provisions for organic
peroxides.
(a) * * * To avoid unnecessary confinement, metallic non-bulk
packagings meeting Packing Group I are not authorized. * * *
(b) * * *
Organic Peroxides Table
--------------------------------------------------------------------------------------------------------------------------------------------------------
Diluent (Mass %) Temperature( deg.C)
Technical Name ID Number Concentration --------------------- Water Packing ---------------------- Notes
(Mass %) A B I (Mass %) Method Control Emergency
(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)
--------------------------------------------------------------------------------------------------------------------------------------------------------
Acetyl acetone peroxide......................... UN3105 42 32 OP7B 21
................................................
Acetyl benzoyl peroxide......................... UN3105 45 82 32 88 62 96 100 OP7A +20 +25
tert-Amyl peroxy-2-ethylhexyl carbonate......... UN3103 92-100 OP5A
tert-Amyl peroxyneodecanoate.................... UN3115 77 77 100 OP5A
2,2-Bis(4,4-di(tert- UN3107 25 42 - 100 OP7A 1, 9
tert-Butyl cumyl peroxide....................... UN3106 42 52 - 100 OP5A
n-Butyl-4,4-di-(tert-butylperoxy)valerate....... UN3106 >42 - 52 42 79 - 90 80 79 >14 OP8A 13,
16
tert-Butyl hydroperoxide........................ UN3109 72 72 9 52 - 100 OP5B
tert-Butyl monoperoxymaleate.................... UN3103 52 52 42 OP8B 21
................................................
tert-Butyl monoperoxymaleate as a paste......... UN3108 52 OP8B 21
................................................
tert-Butyl monoperoxyphthalate.................. UN3102 100 OP5B
tert-Butyl peroxyacetate........................ UN3101 >52 - 77 32 - 52 32 32 77 - 100 52 - 77 52 52 77 100 OP5A +20 +25
tert-Butyl peroxydiethylacetate + tert-Butyl UN3105 33 33
tert-Butyl peroxy-2-ethylhexanoate.............. UN3113 >52 - 100 OP6A +20 +25
tert-Butyl peroxy-2-ethylhexanoate.............. UN3117 >32 - 52 52 32 32 32 32 12 >14 14
tert-Butyl peroxy-2-ethylhexanoate + 2,2-di- UN3115 31 36
tert-Butyl peroxy-2-ethylhexylcarbonate......... UN3105 100 OP7A
tert-Butyl peroxyisobutyrate.................... UN3111 >52 - 77 52 77 77 42 100 OP5A
tert-Butyl peroxyneodecanoate................... UN3115 77 77 - 100 OP7A -5 +5
tert-Butyl peroxyneodecanoate as a paste........ UN3117 42 OP8A 0 +10 21
................................................
tert-Butyl peroxyneodecanoate as a paste UN3118 42 OP8B 0 +10 21
(frozen).
................................................
3-tert-Butylperoxy-3-phenylphthalide............ UN3106 100 OP7B
tert-Butyl peroxypivalate....................... UN3113 >67 - 77 27 - 67 27 27 27 27 100 OP7B
tert-Butyl peroxy-3,5,5-trimethylhexanoate...... UN3105 >32 - 100 OP7A
tert-Butyl peroxy-3,5,5-trimethylhexanoate...... UN3109 32 32 57 - 86 57 72 90 - 98 90 90 77 77 91 72 32 72 OP7B 5, 21
................................................
Diacetone alcohol peroxides..................... UN3115 57 27 27 100 OP8A
1,1-Di-(tert-amylperoxy)cyclohexane............. UN3103 80 51 - 100 77 - 94 77 35 - 52 62 36 - 42 36 - 42 35 52 - 62 OP7B 21
................................................
Dibenzoyl peroxide as a paste................... UN3108 52 OP8B 21
................................................
Dibenzoyl peroxide as a paste................... UN3108 56 50 87 100 OP6B +30 +35
Di-(4-tert-butylcyclohexyl)peroxydicarbonate.... UN3114 100 OP6B +30 +35
Di-(4-tert-butylcyclohexyl)peroxydicarbonate as UN3119 42 OP8A +30 +35 10
a stable dispersion in water.
................................................
Di-tert-butyl peroxide.......................... UN3107 >32 - 100 OP8A
Di-tert-butyl peroxide.......................... UN3109 22 32 52 52 80 - 100 OP5A
1,1-Di-(tert-butylperoxy)cyclohexane............ UN3103 >52 - 80 52 42 27 13 25 27 - 52 27 52 - 100 OP4A -20 -10
Di-sec-butyl peroxydicarbonate.................. UN3115 52 42 - 100 42 42 - 52 42 52 OP7B 21
................................................
2,2-Di-(tert-butylperoxy)propane................ UN3105 52 42 90 - 100 OP5A
trimethylcyclohexane.
1,1-Di-(tert-butylperoxy)-3,3,5- UN3103 >57 - 90 57 32 57 100 OP7B +20 +25
Dicetyl peroxydicarbonate as a stable dispersion UN3119 42 OP8A +30 +35 10
in water.
................................................
Di-4-chlorobenzoyl peroxide..................... UN3102 77 32 52 OP7B 21
................................................
Dicumyl peroxide................................ UN3109 >42 - 100 OP8A 9, 14
Dicumyl peroxide................................ UN3110 >42 - 100 42 91 - 100 OP3B +5 +10
Dicyclohexyl peroxydicarbonate.................. UN3114 91 100 OP6B +30 +35
2,2-Di-(4,4-di(tert- UN3106 42 77 52 OP7B
silicon oil.
................................................
Di-(2-ethylhexyl) peroxydicarbonate............. UN3113 >77 - 100 OP5A -20 -10
Di-(2-ethylhexyl) peroxydicarbonate............. UN3115 77 OP7A -15 -5
Di-(2-ethylhexyl) peroxydicarbonate as a stable UN3117 42 OP8A -15 -5
dispersion in water.
................................................
Di-(2-ethylhexyl) peroxydicarbonate as a stable UN3118 42 OP8B -15 -5
dispersion in water (frozen).
................................................
Diethyl peroxydicarbonate....................... UN3115 27 27 100 OP7B
Diisobutyryl peroxide........................... UN3111 >32 - 52 32 82 52 - 100 OP2B -15 -5
Diisopropyl peroxydicarbonate................... UN3115 52 100 OP7A -10 0
Dilauroyl peroxide.............................. UN3106 100 OP7B
Dilauroyl peroxide as a stable dispersion in UN3109 42 OP8A 10
water.
................................................
Di-(2-methylbenzoyl) peroxide................... UN3112 87 52 OP7B
silicon oil.
................................................
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane....... UN3102 >82 - 100 OP5B
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane....... UN3104 82 82 52 - 100 OP7A
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane.... UN3106 70 52 52 47 OP8B
a paste.
................................................
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3.. UN3103 >52 - 100 OP5A
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3.. UN3106 52 100 OP7A +20 +25
ethylhexanoylperoxy)hexane.
2,5-Dimethyl-2,5-dihydroperoxyhexane............ UN3104 82 77 52 100 OP7B +20 +25
Dimyristyl peroxydicarbonate as a stable UN3119 42 OP8A +20 +25
dispersion in water.
................................................
Dimyristyl peroxydicarbonate as a stable UN3119 42 +15 +25 10
dispersion in water.
................................................
Di-(2-neodecanoylperoxyisopropyl) benzene....... UN3115 52 100 OP7B 0 +10
Di-n-octanoyl peroxide.......................... UN3114 100 OP5B +10 +15
Diperoxy azelaic acid........................... UN3116 27 13 - 42 13 85 - 100 OP5B
Di-(2-phenoxyethyl)peroxydicarbonate............ UN3106 85 27 100 OP4A -25 -15
Distearyl peroxydicarbonate..................... UN3106 87 72,100
Disuccinic acid peroxide........................ UN3102 >72 - 100 OP4B 18
Disuccinic acid peroxide........................ UN3116 72 52 OP7B +30 +35 21
as a paste.
................................................
Di-(3,5,5-trimethylhexanoyl)peroxide............ UN3115 >38 - 82 38 38 38 52 OP8A +10 +15
dispersion in water.
................................................
Ethyl 3,3-di-(tert-amylperoxy)butyrate.......... UN3105 67 77 - 100 OP5A
Ethyl 3,3-di-(tert-butylperoxy)butyrate......... UN3105 77 52 52 - 100 OP4B
tetraoxacyclononane.
3,3,6,6,9,9-Hexamethyl-1,2,4,5- UN3105 52 52 72 72 55 44 OP8A 14
Methylcyclohexanone peroxide(s)................. UN3115 67 52 45 40 62 5 36 43 OP7A 13,
20
Peroxyacetic acid, type E, stabilized........... UN3107 43 OP8A 13,
20
Peroxyacetic acid, type F, stabilized........... UN3109 43 OP8A 13,
20
Pinanyl hydroperoxide........................... UN3105 56 - 100 OP7A 13
Pinanyl hydroperoxide........................... UN3109 55 44 OP8A 14
Tetrahydronaphthyl hydroperoxide................ UN3106 100 OP7B
1,1,3,3-Tetramethylbutyl hydroperoxide.......... UN3105 100 OP7A
1,1,3,3-Tetramethylbutylperoxy-2-ethylhexanoate. UN3115 100 OP7A +20 +25
2,4,4-Trimethylpentyl-2-peroxyneodecanoate...... UN3115 72 37 19 percent, by mass, methyl isobutyl ketone.
(c) * * *
(5) Mixtures. Mixtures of organic peroxides individually identified
in the Organic Peroxides Table in paragraph (b) of this section may be
classified as the same type of organic peroxide as that of the most
dangerous component and be transported under the conditions for
transportation given for this type. If the stable components form a
thermally less stable mixture, the SADT of the mixture must be
determined and the new control and emergency temperature derived under
the provisions of Sec. 173.21(f).
* * * * *
Sec. 173.226 [Amended]
73a. In Sec. 173.226(c)(1), the wording ``4A1 or 4A2'' and ``4B1 or
4B2'' would be removed and the wording ``4A'' or ``4B'', respectively,
would be added in its place.
Sec. 173.304 [Amended]
74. In Sec. 173.304, in the paragraph (a)(2) table, for the entry
``Carbon dioxide'', in Column 3, ``DOT-311800'' would be removed and
replaced with ``DOT-3T1800''.
75. In Sec. 173.306, paragraph (a)(3)(v) would be revised to read
as follows:
Sec. 173.306 Limited quantities of compressed gases.
(a) * * *
(3) * * *
(v) Each container must be subjected to a test performed in a hot
water bath; the temperature of the bath and the duration of the test
must be such that the internal pressure reaches that which would be
reached at 55 deg.C (131 deg.F) (50 deg.C) (122 deg.F) if the
liquid phase does not exceed 95% of the capacity of the container at 50
deg.C (122 deg.F). If the contents are sensitive to heat or if the
containers are made of plastics material which softens at this test
temperature, the temperature of the bath must be set at between 20
deg.C (68 deg.F) and 30 deg.C (86 deg.F) but, in addition, one
container in 2000 must be tested at the higher temperature. No leakage
or permanent deformation of a container may occur, except that a
plastic container may be deformed through softening provided that it
does not leak.
* * * * *
Appendix A to Part 173 [Removed]
76. Appendix A to part 173 would be removed and reserved.
77. In Appendix E to part 173, paragraph 2.b.(4) would be
redesignated 2.b.(5) and a new 2.b.(4) would be added to read as
follows:
Appendix E to Part 173--Guidelines for the Classification and Packing
Group Assignment of Class 4 Materials
* * * * *
2. * * *
b. * * *
(4) A self-reactive material shall be regarded as possessing
explosive properties when, in laboratory testing, the formulation is
liable to detonate, to deflagrate rapidly or show a violent effect
when heated under confinement.
* * * * *
Appendix E to Part 173 [Amended]
78. In addition, in Appendix E to part 173, in paragraph
2.c.(3)(B), the wording ``Powders of metals or metal alloys are
classified when they can be ignited'' would be revised to read
``Powders of metals or metal alloys are classified in Division 4.1 when
they can be ignited''.
Appendix F to Part 173 [Amended]
79. In Appendix F to part 173, in paragraph 1., the phrase
``Division 4.1'' would be removed and replaced with ``Division 5.1''.
80. Appendix H would be added to part 173 to read as follows:
Appendix H to Part 173--Method of Testing for Sustained
Combustibility
1. Method. The method describes a procedure for determining if
the material when heated under the test conditions and exposed to an
external source of flame applied in a standard manner sustains
combustion.
2. Principle of the method. A metal block with a concave
depression (test portion well) is heated to a specified temperature.
A specified volume of the material under test is transferred to the
well and its ability to sustain combustion is noted after
application and subsequent removal of a standard flame under
specified conditions.
3. Apparatus. A combustibility tester consisting of a block of
aluminum alloy or other corrosion-resistant metal of high thermal
conductivity is used. The block has a concave well and a pocket
drilled to take a thermometer. A small gas jet assembly on a swivel
is attached to the block. The handle and gas inlet for the gas jet
may be fitted at any convenient angle to the gas jet. A suitable
apparatus is shown in Figure 5.1 of the UN Recommendations and the
essential dimensions are given in Figures 5.1 and 5.2 of the UN
Recommendations. The following equipment is needed:
(a) Gauge, for checking that the height of the center of the gas
jet above the top of the test portion well is 2.2 mm (see Figure
5.1);
(b) Thermometer, mercury in glass, for horizontal operation,
with a sensitivity not less than 1 mm/ deg.C, or other measuring
device of equivalent sensitivity permitting reading at 0.5 deg.C
intervals. When in position in the block, the thermometer bulb must
be surrounded with thermally conducting thermoplastic compound;
(c) Hotplate, fitted with a temperature-control device. (Other
types of apparatus with suitable temperature-control facilities may
be employed to heat the metal block);
(d) Stopwatch, or other suitable timing device;
(e) Syringe, capable of delivering 2 ml to an accuracy of
0.1 ml; and
(f) Fuel source, butane test fuel.
4. Sampling. The sample must be representative of the material
to be tested and must be supplied and kept in a tightly closed
container prior to test. Because of the possibility of loss of
volatile constituents, the sample must receive only the minimum
treatment necessary to ensure its homogeneity. After removing each
test portion, the sample container must be immediately closed
tightly to ensure that no volatile components escape from the
container; if this closure is incomplete, an entirely new sample
must be taken.
5. Procedure. Carry out the determination in triplicate.
WARNING--Do not carry out the test in a small confined area (for
example a glove box), because of the hazard of explosions.
(a) It is essential that the apparatus be set up in a completely
draft-free area (see warning) and in the absence of strong light to
facilitate observation of flash, flame, etc.
(b) Place the metal block on the hotplate or heat the metal
block by other suitable means so that its temperature, as indicated
by the thermometer placed in the metal block, is maintained at the
specified temperature within a tolerance of 1 deg.C.
The test temperature is 60.5 deg.C or 75 deg.C, (see (h)). Correct
this temperature for the difference in barometric pressure from the
standard atmospheric pressure (101.3 kPa) by raising the test
temperature for a higher pressure or lowering the test temperature
for a lower pressure by 1.0 deg.C for each 4 kPa difference. Ensure
that the top of the metal block is exactly horizontal. Use the gauge
to check that the jet is 2.2 mm above the top of the well when in
the test position.
(c) Light the butane test fuel with the jet away from the test
position (i.e. in the ``off'' position, away from the well). Adjust
the size of the flame so that it is 8 mm to 9 mm high and
approximately 5 mm wide.
(d) Using the syringe, take from the sample container at least 2
ml of the sample and rapidly transfer a test portion of 2 ml
0.1 ml to the well of the combustibility tester and
immediately start the timing device.
(e) After a heating time of 60 seconds (s), by which time the
test portion is deemed to have reached its equilibrium temperature,
and if the test fluid has not ignited, swing the test flame into the
test position over the edge of the pool of liquid. Maintain it in
this position for 15 s and then return it to the ``off'' position
while observing the behavior of the test portion. The test flame
must remain lighted throughout the test.
(f) For each test observe and record:
(i) whether there is ignition and sustained combustion or
flashing, or neither, of the test portion before the test flame is
moved into the test position;
(ii) whether the test portion ignites while the test flame is in
the test position, and, if so, how long combustion is sustained
after the test flame is returned to the ``off'' position.
(g) If sustained combustion interpreted in accordance with
paragraph 6. of this appendix is not found, repeat the complete
procedure with new test portions, but with a heating time of 30 s.
(h) If sustained combustion interpreted in accordance with
paragraph 6. of this appendix is not found at a test temperature of
60.5 deg.C (141 deg.F), repeat the complete procedure with new
test portions, but at a test temperature of 75 deg.C (167 deg.F).
6. Interpretation of observations.
The material must be assessed either as not sustaining
combustion or as sustaining combustion. Sustained combustion must be
reported at either of the heating times if one of the following
occurs with either of the test portions:
(a) When the test flame is in the ``off'' position, the test
portion ignites and sustains combustion;
(b) The test portion ignites while the test flame is in the test
position for 15 s, and sustains combustion for more than 15 s after
the test flame has been returned to the ``off'' position.
Note: Intermittent flashing may not be interpreted as sustained
combustion. Normally, at the end of 15 s, the combustion has either
clearly ceased or continues. In cases of doubt, the material must be
deemed to sustain combustion.
Secs. 173.201, 173.202, 173.203, 173.211, 173.212, 173.213,
173.226 [Amended]
81. In addition to the amendments set forth above, part 173 would
be amended by removing the wording ``4A1 or 4A2'' and inserting in its
place ``4A'' each place it appears; removing the wording ``4B1 or 4B2''
and inserting in its place ``4B'' each place it appears; and by
removing the wording ``6HH'' and inserting in its place ``6HH1'' each
place it appears in the following sections:
a. Section 173.201 (b) and (c);
b. Section 173.202 (b) and (c);
c. Section 173.203 (b) and (c);
d. Section 173.211 (b) and (c);
e. Section 173.212 (b) and (c); and
f. Section 173.213 (b) and (c).
PART 175--CARRIAGE BY AIRCRAFT
82. The authority citation for part 175 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1807, 1808; 49 CFR part 1.
83. In Sec. 175.10, paragraphs (a)(4) introductory text and (a)(13)
would be revised, paragraph (a)(17) would be removed and reserved, and
a new paragraph (a)(26) would be added to read as follows:
Sec. 175.10 Exceptions.
(a) * * *
(4) Non-radioactive medicinal and toilet articles carried by a crew
member or passenger in checked or carry-on baggage, and non-flammable
and non-toxic aerosols, with no subsidiary risk, for sporting or home
use, when carried in checked baggage only, when:
* * * * *
(13) Carbon dioxide, solid (dry ice) when:
(i) In quantities not exceeding 2.3 kg (5.07 pounds) per package
packed as prescribed by Sec. 173.217 of this subchapter and used as a
refrigerant for the contents of the package. The package must be marked
with the name of the contents being cooled, the net weight of the dry
ice or an indication that the net weight is 2.3 kg (5.07 pounds) or
less, and also marked ``Carbon Dioxide, Solid'' or ``Dry Ice'';
(ii) Intended for use in food and beverage service aboard aircraft;
or
(iii) In quantities not exceeding 2 kg (4.4 pounds) per passenger
when used to pack perishables in carry-on baggage provided the package
permits the release of carbon dioxide gas.
* * * * *
(26) A small medical or clinical mercury thermometer for personal use,
when carried in protective cases by passengers or crew members.
Sec. 175.10 [Amended]
84. In addition, in Sec. 175.10, in paragraph (a)(12) introductory
text, the wording ``environmental restoration or protection,'' would be
added immediately following ``weather control,'' and immediately
preceding ``forest preservation''.
85. In Sec. 175.33, a new sentence would be added in paragraph
(a)(1) introductory text after the first sentence, and a new paragraph
(a)(9) would be added to read as follows:
Sec. 175.33 Notification of pilot-in-command.
(a) * * *
(1) * * * In the case of Class 1 material, the compatibility group
letter also must be shown. * * *
* * * * *
(9) The air waybill number (when issued).
* * * * *
Sec. 175.33 [Amended]
86. In addition, in Sec. 175.33, in paragraph (a)(6), the word
``and'' at the end of the sentence would be removed; in paragraph
(a)(7), the period at the end of the sentence would be removed and
replaced with a semicolon; and in paragraph (a)(8), the period at the
end of the sentence would be removed and replaced with ``; and''.
PART 176--CARRIAGE BY VESSEL
87. The authority citation for part 176 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1805, 1808; 49 CFR part 1.
88. A new paragraph (c) would be added in Sec. 176.27 to read as
follows:
Sec. 176.27 Certificate.
* * * * *
(c) (1) A person responsible for packing or loading a freight
container or transport vehicle containing hazardous materials for
transportation by a manned vessel in ocean or coastwise service, must
provide the vessel operator with a signed container packing certificate
stating, at a minimum, that--
(i) The freight container or transport unit is serviceable for the
materials loaded therein, contains no incompatible goods, and is
properly marked, labeled or placarded, as applicable; and
(ii) When the freight container or transport unit contains
packages, those packages have been inspected prior to loading, are
properly marked, labeled or placarded, as applicable; are not damaged;
and are properly secured.
(2) The certificate may be either on a separate document or be
provided on the certificate required in Sec. 172.204 of this
subchapter.
89. In Sec. 176.76, a new paragraph (i) would be added to read as
follows:
Sec. 176.76 Transport vehicles, freight containers, and portable tanks
containing hazardous materials.
* * * * *
(i) A fumigated transport unit may only be transported on board a
vessel subject to the following conditions and limitations:
(1) The fumigated transport unit may be placed on board a vessel
only if at least 24 hours have elapsed since the unit was last
fumigated;
(2) The fumigated transport unit is accompanied by a document
showing the date of fumigation and the type and amount of fumigant
used;
(3) Prior to loading, the master is informed of the intended
placement of the fumigated transport unit on board the vessel and the
information provided on the accompanying document;
(4) Equipment that is capable of detecting the fumigant and
instructions for the equipment's use is provided on the vessel;
(5) The fumigated transport unit must be stowed at least five
meters from any opening to accommodation spaces;
(6) Fumigated transport units may only be transported on deck on
vessels carrying more than 25 passengers; and
(7) Fumigants may not be added to transport units while on board a
vessel.
PART 177--CARRIAGE BY PUBLIC HIGHWAY
90. The authority citation for part 177 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1805; 49 CFR part 1.
Sec. 177.841 [Amended]
91. In Sec. 177.841, in paragraph (e)(3), the wording ``is
separated as required in Sec. 177.848(e)(3) for classes identified with
the letter `O' in the Segregation Table for Hazardous Materials.''
would be revised to read ``is separated in a manner that, in the event
of leakage from packages under conditions normally incident to
transportation, commingling of hazardous materials with foodstuffs,
feed, or any other edible material would not occur.''
PART 178--SPECIFICATIONS FOR PACKAGINGS
92. The authority citation for part 178 would continue to read as
follows:
Authority: 49 App. U.S.C. 1803, 1804, 1805, 1806, 1808; 49 CFR
part 1.
93. In Sec. 178.2, paragraph (a) would be revised and paragraph (e)
would be added to read as follows:
Sec. 178.2 Applicability and responsibility.
(a) Applicability. (1) The requirements of this part apply to
packagings manufactured--
(i) To a DOT specification, regardless of country of manufacture;
or
(ii) To a UN standard, for packagings manufactured within the
United States. For UN standard packagings manufactured outside the
United States, see Sec. 173.24(d)(2) of this subchapter. For UN
standard packagings for which standards are not prescribed in this
part, see Sec. 178.3(b).
(2) A manufacturer of a packaging subject to the requirements of
this part is primarily responsible for compliance with the requirements
of this part. However, any person who performs a function prescribed in
this part shall perform that function in accordance with this part.
* * * * *
(e) Definitions. For the purpose of this part--
Manufacturer means the person whose name and address or symbol
appears as part of the specification markings required by this part or,
for a packaging marked with the symbol of an approval agency, the
person on whose behalf the approval agency certifies the packaging.
Specification markings mean the packaging identification markings
required by this part including, where applicable, the name and address
or symbol of the packaging manufacturer or approval agency.
94. In Sec. 178.3, paragraph (a) introductory text, the first
sentence of paragraph (a)(2) and paragraph (b) would be revised, a
sentence would be added at the end of paragraph (a)(4) and a new
paragraph (a)(5) would be added, to read as follows:
Sec. 178.3 Marking of packagings.
(a) Each packaging manufactured to a DOT specification or a UN
standard must be marked with specification markings conforming to the
applicable specification, and with the following:
(1) * * *
(2) Unless otherwise specified in this part, with the name and
address or symbol of the packaging manufacturer or, where specifically
authorized, the symbol of the approval agency certifying compliance
with a UN standard. * * *
* * * * *
(4) * * * For packagings having a capacity of 5 L (1 gallon) or 5
kg (11 pounds) or less, letters and numerals must be of an appropriate
size.
(5) For packages with a gross mass of more than 30 kg (66 pounds),
the markings or a duplicate thereof must appear on the top or on a side
of the packaging.
(b) A UN standard packaging for which the UN standard is set forth
in this part may be marked with the United Nations symbol and other
specification markings only if it fully conforms to the requirements of
this part. A UN standard packaging for which the UN standard is not set
forth in this part may be marked with the United Nations symbol and
other specification markings for that standard as provided in the ICAO
Technical Instructions or Annex 1 of the IMDG Code subject to the
following conditions:
(1) The U.S. manufacturer must establish that the packaging
conforms to the applicable provisions of the ICAO Technical
Instructions or Annex 1 of the IMDG Code, respectively.
(2) If an indication of the name of the manufacturer or other
identification of the packaging as specified by the competent authority
is required, the name and address or symbol of the manufacturer must be
entered. Symbols, if used, must be registered with the Associate
Administrator for Hazardous Materials Safety.
(3) The letters ``USA'' shall be used to indicate the State
authorizing the allocation of the specification marks if manufactured
in the United States.
* * * * *
Sec. 178.502 [Amended]
95. In Sec. 178.502, the following changes would be made:
a. In the paragraph (a) introductory text, the wording ``types''
would be revised to read ``kinds''.
b. In the paragraph (a)(1) introductory text and the first sentence
in paragraph (a)(3), the wording ``type'' would be revised to read
``kind''.
96. In Sec. 178.503, paragraph (d) would be redesignated paragraph
(e); new paragraphs (a)(11) and (d) would be added; paragraph (a)
introductory text, paragraph (a)(9), and paragraph (a)(10) would be
revised; and newly designated paragraph (e)(3) would be amended by
revising the illustration, to read as follows:
Sec. 178.503 Marking of packagings.
(a) The manufacturer must mark every packaging that is required to
meet a UN standard with the marks specified in this section. The
markings must be legible and placed in a location and of such a size
relative to the packaging as to be readily visible, as specified in
Sec. 178.3(a). For packages with a gross mass of more than 30 kg (66
pounds), the markings or a duplicate thereof must appear on the top or
on a side of the packaging. Except as otherwise provided in this
section, every reusable packaging liable to undergo a reconditioning
process which might obliterate the packaging marks must bear the marks
specified in paragraphs (a)(1) through (a)(6) and (a)(9) of this
section in a permanent form (e.g. embossed) able to withstand the
reconditioning process. A marking may be applied in a single line or in
multiple lines provided the correct sequence is respected. As
illustrated by the examples in paragraph (e) of this section, the
following information must be presented in the correct sequence. Slash
marks should be used to separate this information. A packaging
conforming to a UN standard must be marked as follows:
* * * * *
(9) For metal or plastic drums or jerricans intended for reuse or
reconditioning as single packagings or the outer packagings of a
composite packaging, the thickness of the packaging material, expressed
in millimeters, as follows:
(i) Metal drums or jerricans must be marked with the nominal
thickness of the metal used in the body. The marked nominal thickness
must not exceed the minimum thickness of the steel used by more than
the thickness tolerance stated in ISO Standard 3574. The unit of
measure is not required to be marked. When the nominal thickness of
either head of a metal drum is thinner than that of the body, the
nominal thickness of the top head, body, and bottom head must be marked
(eg., ``1.0-1.2-1.0'' or ``0.9-1.0-1.0'').
(ii) Plastic drums or jerricans must be marked with the minimum
thickness (in mm, rounded to the nearest 0.1 mm) of the packaging
material. Minimum thicknesses of plastic must be as determined in
accordance with Sec. 173.28(b)(4). The unit of measure is not required
to be marked.
(10) In addition to the markings prescribed in paragraphs (a)(1)
through (a)(9) of this section, every new metal or plastic drum having
a capacity greater than 100 L and intended for reuse or reconditioning
as a single packaging or the outer packaging of a composite packaging,
must bear the marks described in paragraphs (a)(1) through (a)(6), and
(a)(9) of this section, in a permanent form, on the bottom. For these
packagings, the markings on the top head or side of the packaging need
not be applied in a permanent form and need not include the thickness
mark described in paragraph (a)(9) of this section. This marking
describes a drum's characteristics at the time it was manufactured and
must be consistent with the original manufacturer's UN marking on the
top head or side. Subsequent remanufacture may render some of the
information provided in this bottom mark to be invalid (e.g., a 1A1
drum may be remanufactured into a 1A2 drum). This marking should not be
used to evaluate compliance with Sec. 173.24 of this subchapter.
(11) Rated capacity of the packaging expressed in liters may be
marked.
* * * * *
(d) When, after reconditioning, the markings required by paragraph
(a)(1) through (a)(6) of this section no longer appear on the top head
or the side of the metal drum, the reconditioner must apply them in a
durable form followed by the markings in paragraph (c) of this section.
These markings may identify a different performance capability than
that for which the original design type had been tested and marked, but
may not identify a greater performance capability. The markings applied
in accordance with this paragraph may be different from those which are
permanently marked on the bottom of a drum in accordance with paragraph
(a)(10) of this section.
(e) * * *
(3) * * *
BILLING CODE 4910-60-P
TP18JY94.000
BILLING CODE 4910-60-C
* * * * *
Sec. 178.503 [Amended]
97. In addition, in Sec. 178.503, the reference
``Sec. 178.503(a)(1) through (a)(10)'' following the illustration would
be revised to read ``Sec. 178.503(a)(1) through (a)(9)''.
Sec. 178.508 [Amended]
98. In Sec. 178.508, in paragraph (a)(2), the wording ``plywood or
plastic material'' would be revised to read ``plywood, plastics, or
other suitable material''.
99. In Sec. 178.512, paragraphs (a)(3) and (a)(4) would be removed
and paragraphs (a)(1), (a)(2), and (b)(2) would be revised to read as
follows:
Sec. 178.512 Standards for steel or aluminum boxes.
(a) * * *
(1) 4A for a steel box; and
(2) 4B for an aluminum box.
(b) * * *
(2) Boxes must be lined with fiberboard or felt packing pieces or
must have an inner liner or coating of suitable material in accordance
with subpart C of part 173 of this subchapter. If a double seamed metal
liner is used, steps must be taken to prevent the ingress of materials,
particularly explosives, into the recesses of the seams.
* * * * *
100. In Sec. 178.513, paragraphs (b)(2) and (b)(3) would be
redesignated (b)(3) and (b)(4), respectively, and a new paragraph
(b)(2) would be added to read as follows:
Sec. 178.513 Standards for boxes of natural wood.
* * * * *
(b) * * *
(2) Fastenings must be resistant to vibration experienced under
normal conditions of transportation. End grain nailing must be avoided
whenever practicable. Joints which are likely to be highly stressed
must be made using clenched or annular ring nails or equivalent
fastenings.
* * * * *
Sec. 178.516 [Amended]
101. In Sec. 178.516, the following changes would be made:
a. In paragraph (b)(1), at the end of the second sentence, the
wording ``ISO International Standard 535-1976(E)'' would be revised to
read ``ISO International Standard 535-1991(E)''.
b. In paragraph (b)(2), at the end of the first sentence, the
wording ``of wood.'' would be revised to read ``of wood or other
suitable material.''; and in the second sentence the wording ``or other
suitable material'' would be added immediately following the word
``battens''.
c. Paragraphs (b)(4) and (b)(5) would be redesignated as paragraphs
(b)(5) and (b)(6) and paragraph (b)(3)(iii) would be redesignated as
paragraph (b)(4).
Sec. 178.521 [Amended]
102. In Sec. 178.521, in paragraph (b)(2), in the penultimate
sentence, the wording ``water-resistant ply or barrier must also be
placed'' would be revised to read ``waterproof ply or barrier, such as
double-tarred kraft paper, plastics-coated kraft paper, plastics film
bonded to the inner surface of the bag, or one or more inner plastics
liners, must also be placed''.
103. In Sec. 178.522, paragraphs (a)(10) and (b)(3)(viii) would be
revised and paragraphs (a)(11) and (b)(3)(ix) would be added to read as
follows:
Sec. 178.522 Standards for composite packagings with inner plastic
receptacles.
(a) * * *
(10) 6HH1 for a plastic receptacle within a protective plastic
drum; and
(11) 6HH2 for a plastic receptacle within a protective plastic box.
(b) * * *
(3) * * *
(viii) 6HH1: Protective packaging must conform to the requirements
for plastic drums, in Sec. 178.509(b).
(ix) 6HH2: Protective packaging must conform to the requirements
for plastic boxes, in Sec. 178.517(b).
* * * * *
Sec. 178.522 [Amended]
104. In addition, in Sec. 178.522, the following changes would be
made:
a. In paragraph (a)(9), the word ``and'' at the end of the
paragraph would be removed.
b. In paragraph (b)(4), the wording ``6HH'' would be revised to
read ``6HH1''; and the wording ``, 6HH2'' would be added immediately
following ``6HG2''.
c. In paragraph (b)(5), the wording ``6HH'' would be revised to
read ``6HH1'', and the wording ``, 6HH2'' would be added immediately
following ``6HG2''.
105. In Sec. 178.601, paragraph (k) would be redesignated as
paragraph (l) and revised, a new paragraph (k) would be added, and
paragraphs (b), (g)(2)(i), and (g)(2)(vi) would be revised to read as
follows:
Sec. 178.601 General requirements.
* * * * *
(b) Responsibility. It is the responsibility of the packaging
manufacturer to assure that each package is capable of passing the
prescribed tests. To the extent that a package assembly function,
including final closure, is performed by the person who offers a
hazardous material for transportation, that person is responsible for
performing the function in accordance with Secs. 173.22 and 178.2 of
this subchapter.
* * * * *
(g) * * *
(2) * * *
(i) The outer packaging must have been successfully tested in
accordance with Sec. 178.603 with fragile (e.g. glass) inner packagings
containing liquids at the Packing Group I drop height;
* * * * *
(vi) When the outer packaging is intended to contain inner
packagings for liquids and is not leakproof, or is intended to contain
inner packagings for solids and is not siftproof, a means of containing
any liquid or solid contents in the event of leakage must be provided
in the form of a leakproof liner, plastic bag, or other equally
efficient means of containment. For packagings containing liquids, the
absorbent material required in paragraph (g)(2)(v) of this section must
be placed inside the means of containing liquid contents; and
* * * * *
(k) Number of test samples. Provided the validity of the test
results is not affected and with the approval of the Associate
Administrator for Hazardous Materials Safety, several tests may be
performed on one sample.
(l) Record retention. Following each design qualification test and
each periodic retest on a packaging, a test report must be prepared.
The test report must be maintained at each location where the packaging
is manufactured, at each location where the design qualification tests
are conducted for as long as the packaging is produced and for at least
two years thereafter, and at each location where the periodic retests
are conducted until such tests are successfully performed again and a
new test report produced. In addition, a copy of the test report must
be maintained by a person certifying compliance with this part. The
test report must be made available to users of a packaging or a
representative of the Department upon request. The test report must
contain the following information:
(1) Name and address of test facility;
(2) Name and address of applicant (where appropriate);
(3) A unique test report identification;
(4) Date of the test report;
(5) Manufacturer of the packaging;
(6) Description of the packaging design type (e.g. dimensions,
materials, closures, thickness, etc.), including methods of manufacture
(e.g. blow molding) and which may include drawing(s) and/or
photograph(s);
(7) Maximum capacity;
(8) Characteristics of test contents, e.g. viscosity and relative
density for liquids and particle size for solids;
(9) Test descriptions and results; and
(10) Signed with the name and address of signatory.
Sec. 178.601 [Amended]
106. In addition, in Sec. 178.601, the following changes would be
made:
a. In paragraph (g)(2) introductory text, the wording ``Inner
packagings'' would be revised to read ``Articles or inner packagings''.
b. In paragraph (g)(5)(i), the reference ``Sec. 178.602'' would be
revised to read ``Sec. 178.603''.
c. In paragraph (g)(5)(ii), the reference ``Sec. 178.603'' would be
revised to read ``Sec. 178.604''.
Sec. 178.602 [Amended]
107. In Sec. 178.602, in the second sentence of paragraph (c), the
reference ``Sec. 178.603(d)(2)'' would be revised to read
``Sec. 178.603(e)''.
108. In Sec. 178.603, in paragraph (a) introductory text, a
sentence would be added following the second sentence, the first
sentence in paragraph (c) would be revised, and paragraph (f)(1) would
be revised to read as follows:
Sec. 178.603 Drop test.
(a) * * * Where more than one orientation is possible for a given
drop test, the orientation most likely to result in failure of the
packaging must be used. * * *
* * * * *
(c) * * * Testing of plastic drums, plastic jerricans, plastic
boxes other than expanded polystyrene boxes, composite packagings
(plastic material), combination packagings with plastic inner
packagings, textile bags with inner plastic liners, woven plastic bags,
and plastic film bags must be carried out when the temperature of the
test sample and its contents has been reduced to -18 deg.C (0 deg.F)
or lower. * * *
* * * * *
(f) * * *
(1) For packagings containing liquid, each packaging does not leak
when equilibrium has been reached between the internal and external
pressures, except for inner packagings of combination packagings when
it is not necessary that the pressures be equalized;
* * * * *
Sec. 178.604 [Amended]
109. In Sec. 178.604, in paragraph (d), in the second sentence, the
wording ``for a period of time sufficient to pressurize the interior of
the packaging to the specified air pressure and to determine if there
is leakage of air from the packaging'' would be revised to read
``, for other than production testing, for a minimum time of five
minutes''.
Issued in Washington, DC on July 1, 1994 under authority
delegated in 49 CFR part 106, appendix A.
Alan I. Roberts,
Associate Administrator for Hazardous Materials Safety.
[FR Doc. 94-16542 Filed 7-15-94; 8:45 am]
BILLING CODE 4910-60-F,P