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EXHIBIT 10 -PIL NAR -7o -7-o 3LI-i-o i wvq5 Nonpoint-Source Po ution at -the Fajardo River Basin, Puerto Rico Fe'lix A. Grana-Raffucci LE 0 Mayra T. Garcia-Pe'rez JI, 1993 Ceiba Fajardo City State Forest CIO C-< 3 .0*4 1; 6 8 Vieques Passage MunicipaLity of Fajardo TD 2311 .PS G73 Final Report Task 7.2 1993 Coastal Zone Management Program Scientific Research Area Department of Natural Resources San Juan, Puerto Rico A report of Puerto Rico Department of Natural Resources to the National Oceanic and Atmospheric Administration pursuant to NOAA Award No. - - NA270ZO347-01 D R S.C Un informe del Departamento de Recursos Naturales de Puerto Rico a la Administracio'n Ocea'nica yAtmosf6rica Nacional conducente al Fondo NOAA No. NA270Z0347-01 AV:\ Nonpoint-Source Pollution at the Fajardo River Basin, Puerto Rico Fe'lix A. Grana-Raffucci Mayra T. Gard'a-Pe'rez 1993 Final Report Task 7.2 Coastal Zone Management Program Scientific Research Area Department of Natural Resources San Juan, Puerto Rico EXECUTIVE SUMMARY During the last thirty years, at least, surface and ground water resources in Puerto Rico have been impacted by large quantities of various kinds of pollutants of both the point-source and nonpoint-source varieties. Nonpoint source pollutants are diffuse, both in terms of origins and in the ways they reach water bodies. These pollutants originates mostly from different human activities: landfills, crop and animal farms, urban and rural communities' runoff and waste leakage, soil movement and extraction, construction projects, deforestation, marinas, etc. The Fajardo River basin, though relatively small, is representative of the development of hydrological basins in Puerto Rico and the impact this development brought. Geology and soil type, land use, water management practices, biodiversity, and water quality history for the basin were researched and are discussed. Field interviews to parties involved in one way or another in nonpoint source pollution in the basin were done. Based on the information presented, a series of recommendations leading to control nonpoint source pollution at the basin is offered. 2 ACKNOWLEDGEMENTS We wish to thank the following persons whose help resulted indispensable for the succesful completion of this project: Ms. Ileana P6rez and the staff from DNR Laboratory; Mr. Carlos Padfn (CZMP), Mr. Paulino Laguna (DNR-Water Resources), Mr. Eric Morales (EQB-Water Quality), Ms. Nitza Massini (DNR- Scientific Inventory), Mr. Israel Diaz, Mr. James Timber, Mr. Miguel Miranda, Mr. Jos6 Col6n, (DNR-Marine Resources) and the staff of Consultations and Endorsements (DNR). 3 LIST OF CONTENTS Executive summary ...............................................................................................1 Acknowledgements ...............................................................................................2 List of contents ....................... ...... ...........................................................3 List of figures ...........................................................................................................6 List of tables ............................................................................................................. 10 I. Introduction ........................................................................................................ 11 II. Overview of existing government efforts in Puerto Rico to control nonpoint source pollution ............................................................................. 14 1. Federal level ................................................................................ 14 2. Commonwealth level ............................................................... 20 111. The Fajardo River basin ................................................................................ 26 Land use ........................................................................................... 29 Geology, hydrology, geogrphy and soils .................................. 30 Water management at the river basin ...................................... 31 Natural biota and biodiversity .................................................... 36 4 IV. Water quality history of the Fajardo River ............................................... 46 Sampling stations ........................................................................... 46 Water discharge .............................................................................. 51 Tempeiature .... ..................*...................................... .................... 51 Conductance, salinity, dissolved solids ..................................... 56 Fecal bacteria .................................................................................... 56 Turbidity, color, suspended material ......................................... 61 Oxygen requirements .................................................................... 67 Hardness and alkalinity ................................................................ 73 Substances reactive to Methylene Blue ..................................... 88 Chlorine and fluoride ................................................................... 88 Nitrogen and phosphorus ............................................................ 88 Phenolic substances ........... ;*****'* ....... 106 The carbon system and pH ........................................................... 106 Metals, silica and toxic substances .............................................. 114 Pesticides .......................................................................................... 114 Field sampling at the Fajardo River .......................................... 120 Summarized review of historical water data ........................... 149 V. Field interviews ............................................................................................... 150 Agricultural activities ................................................................... 150 Marinas ............................................................................................. 151 Hydromodifications ....................................................................... 152 Wetlands ............................. ............................................................ 152 5 Waste disposal systems ................................................................. 153 Construction and soil extraction activities ............................... 153 VI. Conclusion and recommendations ............................................................ 154 VH. References ....................................................................................................... 156 Appendix 1: Field interview questionnaires ................................................... 160 Appendix 2: Field photographs .......................................................................... 171 6 LIST OF FIGURES Figure 1 - The Fajardo River basin .................................................................. 27 Figure 2: DNR-approved permits and endorsements; municipalities of Fajardo and Ceiba (1989-1993) ......................................................... 28 Figure 3: EQB's schematic description of nonpoint-source pollution at the Fajardo River ..................................................................................... 32 Figure 4: Phytoplankton standing crop from the Fajardo River ............. 42 Figure 5: Phytoplankton biodiversity at the Fajardo River ...................... 44 Figure 6: Benthic invertebrate biodiversity at the Fajardo River ............ 45 Figure 7: Water quality monitoring st4ions and nonpoint sources, as identified by EQB, along the Fajardo River ................................ 47 Figure 8: Water quality monitoring station and nonpoint sources, as identified by EQB, along the Fajardo River ................................ 49 Figure 9: Instantaneous water discharge ....................................................... 52 Figure 10: Annual water discharge ................................................................. 53 Figure 11: Temperature ..................................................................................... 54 Figure 12: Conductance ..................................................................................... 57 Figure 13: Salinity ............................................................................................... 58 Figure 14: Dissolved solids ............................................................................... 59 Figure 15: Sum of dissolved solids ................................................................. 60 Figure 16: Fecal coliforms ................................................................................. 62 Figure 17: Fecal streptococci ............................................................................. 64 Figure 18: Turbidity ............................................................................................ 65 Figure 19: Suspended solids ............................................................................. 68 Figure 20: Residue of suspended solids ......................................................... 69 Figure 21: Color ................................................................................................... 71 Figure 22: Suspended oils and greases ........................................................... 72 Figure 23: Dissolved oxygen' ............................................................................. 74 Figure 24: Percent of oxygen saturation ......................................................... 76 Figure 25: Biochemical oxygen demand ........................................................ 78 Figure 26: Chemical oxygen demand ............................................................. 79 Figure 27: Hardness ............................................................................................ 80 Figure 28: Noncarbonate hardness ................................................................. 81 Figure 29: Alkalinity .......................................................................................... 82 Figure 30: Dissolved sodium ........................................................................... 83 Figure 31: Dissolved calcium ........................................................................... 84 Figure 32: Dissolved potassium ...................................................................... 85 Figure 33: Dissolved magnessium .................................................................. 86 Figure 34: Dissolved sulfate ............................................................................. 87 Figure 35: Substances reactive to Methylene Blue ...................................... 89 Figure 36: Dissolved chloride .......................................................................... 90 Figure 37: Dissolved fluoride ........................................................................... 91 8 Figure 38: Nitrates .............................................................................................. 93 Figure 39: Nitrites .....................................b ......................................................... 95 Figure 40: Sum of nitrates and nitrites .......................................................... 96 Figure 42: Ammonia ......................................................................................... 98 Figure 43: Total organic nitrogen .................................................................... 99 Figure 44: Total nitrogen .................................................................................. 101 Figure 45: Sum of total nitrogen, ammonia and organic nitrogen ......... 102 Figure 46: Phosphorus ....................................................................................... 103 Figure 47: Phosphates ........................................................................................ 105 Figure 48- Phenolic substances ........................................................................ 107 Figure 49: Bicarbonates ...................................................................................... 108 Figure 50: Carbonat6s ......................................................................................... 109 Figure 51: Carbon dioxide ................................................................................. 110 Figure 52: Organic carbon ................................................................................. 111 Figure 53: Hydrogen potential (pH) ................................................................ 112 Figure 54: Silicates .............................................................................................. 121 Figure 55: Total iron .......................................................................................... 122 Figure 56: Dissolved iron .................................................................................. 124 Figure 57: Total copper ...................................................................................... 125 Figure 58: Total arsenic ..................................................................................... 127 Figure 59: Total barium ........................... 128 Figure 60: Total boron ....................................................................................... 129 Figure 61: Total cadmium ................................................................................ 131 9 Figure 62: Total chromium .............................................................................. 133 Figure 63: Total lead ........................................................................................... 134 Figure 64: Total manganese ............................................................................. 136 Figure 65: Total cyanide .................................................................................... 138 Figure 66: Total cobalt ................................ .......................................................... 139 Figure 67: Total mercury ................................................................................... 140 Figure 68: Total nickel ....................................................................................... 141 Figure 69: Total selenium ................................................................................. 142 Figure 70: Total zinc ........................................................................................... 143 Figure 71: Sampling stations established for this project (indicated by stars) ............................................................................................................................. 145 Figure 72: Upstream station established for this project (as indicated by a star) ................................................................................................................................ 146 6 10 LIST OF TABLES Table 1: Comparison of land zoning categories for 1971 and 1979 at the Fajardo River basin ............................................................................. 30 Table 2: EQB's use classification of the Fajardo River ................................ 33 Table 3: EQB's use description of the estuary segment of the Fajardo River .............................................................................................................................. 33 Table 4: NPDES permit limits imposed by EQB on ASA's wastewater plant filter backwash discharges unto the Fajardo R . ............................ 34 Table 5: Phytoplankton identified from, samples taken at station USGS 710, Fajardo River ....................................................................................... 37 Table 6: Benthic invertebrates identified from samples taken from station USGS 710, Fajardo River ................................................................... 39 Table 7: Water quality monitoring stations located at the Fajardo River basin ................................................................................................................................. 46 Table 8: Macro- and micronutrients essential for aquatic biota ............... 92 Table 9: Summarized analysis of historical water quality data gathered at monitoring stations USGS 710, USGS 720, USGS 725, and EQB 78B (1958-1992) .............................................................................................. 114 Table 10: Water quality field stations established by this project at the Fajardo River system ...................................................................................... 147 Table 11: Water quality data from this project's field samples ................. 147 I. INTRODUCTION Point-source pollution is clearly identified with a well-defined location or place. Gross pollution of this kind have, in large part, been brought under control. Government, by requiring permits and impact evaluations, has created mechanisms whereby technology to treat these polluters can be mandated, and the effect of such technology can be monitored. This success is at best a partial one; water pollution remains a serious problems. Sediment, nutrients, pathogenic organisms, and, toxins still find their way into our waters, where thy degrade the ecosystem, pose health hazards, and impair the full use of aquatic resources. Nonpoint-source pollution or NPSP (unlike pollution from point sources) is diffuse, both in terms of its origin and in the manner in which it enters ground and surface waters. It results from a variety of human activities that take place over a wide geographic area. Pollutants from nonpoint sources usually find their way into water bodies in sudden surges associated with rainfall, in addition to constant slow percolation from other sources. The most significant sources of NPSP are: 1. Ag1icultural activities: Including sediments from eroded croplands and overgrazed pastures, fertilizers, animal wastes, pesticides, etc. 2. Runoff: From roads, sewers, and urban areas. Industrial stormwater discharges and runoff from sewers serving populations of 400,000 or more are considered point sources. 3. Hydromodification: Reservoir or dam construction, stream channelization, flood prevention projects, etc. 12 4. Abandoned mines and other resource-extraction ol2erations: Active mines are considered point sources. 5. Forestry operations 6. Construction: Produces toxic materials and huge sediment loads. Construction activities disturbing five acres or more are considered point sources. 7. Waste disl2osal on land: Largely leakage form septic tanks and the spreading of sewage sludge. 8. Marinas: Responsible for important spills of oils, greases, paints, metals, wastewaters, and others. Often, the full effect of NPSP cannot be measured in terms of water contamination alone: loss of topsoil due to erosion has a negative impact on agricultural productivity and damages structures, roads and ditches. Sediments can destroy breeding grounds for fish and other wildlife. Carried all the way to the sea, sediments kill entire marine communities, such as coral reefs and seagrass prairies. Increased levels of sediment mean increased costs for dredging harbors and treating wastewaters. Unfortunately, there is no practical way to write a permit for every agricultural field because NPSP is not affected by discharge controls of individual pipes or outfalls. Further, NPSP occurs as a direct result of land use planning and zoning. Control strategies for NPSP proceed from two basic principles involving land use practices: 1. Measures can b*e taken to lhcrease the ability of land to retain water, thereby reducing runoff to streams, lakes, and the sea. 2. The kinds and amounts of pollutants swept away in runoff can be minimized. Puerto Rico has 100 hydrological basins, all showing signs of NPSP. In fact, the Environmental Quality Board of Puerto Rico (EQB) considers that NPSP currently presents "a serious threat to the quality of surface and groundwaters, risking human health and the environment". As a result of these and other human activities, EQB recently determined that impairment of designated uses in rivers amounts to 73% of total area for aquatic life, 71% for swimming, 69% for drinking water, and 63% for secondary contact recreation. At estuaries, impairment for designated uses were determined as 64% of total area for aquatic life, 66% for swimming, and 58% for secondary contact recreation. The main sources to which these results were related 13 included for rivers: land disposal, agriculture, urban runoff, and natural sources (intermittence of streams, soil types, rains, etc.); and for estuaries: urban runoff, storm sewer discharges, and land disposal. This document reports on the Fajardo River Basin, a small basin chosen because it was considered representative, at a small scale, of problems with NPSP throughout Puerto Rico. 14 11. OVERVIEW OF E)CISTING GOVERNMENT EFFORTS IN PUERTO RICO TO CONTROL NONPOINT SOURCE POLLUTION 1. Federal level Federal agencies expect that state nonpoint source programs build on and complement, rather than duplicate and conflict with, other Federal statutory requirements and state imRIemented programs. State nonpoint source agencies are encouraged to work with these programs in implementing their programs. Environmental Protection Agency (EPA) 1. Clean Water Act Section 319 - Nonpoint Source Program A number of local, state and Federal programs have been implemented over time to address nonpoint source pollution. However, the first national program to authorize Federal funding for the control of nonpoint sources began in 1987 when Congress passed the Water Quality Act of 1987, enacting section 319 of the Clean Water Act., which established a national program to control nonpoint sources of water pollution. Section 319 requires that, in order to be eligible for federal funding, states develop an assessment report detailing the extent of nonpoint pollution, and a management program specifying nonpoint source. controls. Section 319 authorizes EPA to issue grants to states to assist them in implementing their nonpoint source management programs or portions of management programs that have been approved by EPA. 15 2. Clean Water Act Section 320 - National Estuary Program EPA also administers the National Estuary Program under section 320 of the Clean Water Act. This program focuses on point and nonpoint pollution in geographically targeted, high-priority estuarine waters. Under this program, EPA assists state, regional and local governments in developing estuary-specific comprehensive conservation and management plans that recommend corrective actiocs to restore and maintain estuarine water quality and to protect fish populations and other designated uses of these targeted waters. In Puerto Rico, one estuarine system (San Juan Bay) has been designated as part of the National Estuary Program. 3. Near Coastal Waters Program The Near Coastal Waters (NCW) Program serves as a primary vehicle for implementing environmental protection in coastal areas under a variety of programs and authorities. It is also the framework for coastal regions for carrying-out Agency directives, strategic themes, and other initiatives not specifically related to distinct program issues. Examples of these cross-cutting themes include geographic targeting for management attention; pollution prevention; and setting priorities based on the expected efficacy of preventive measures as well as the magnitude of ecological or human health risks. 4. Ground-Water Protection -Programs - EPA has a number of programs, in addition to section 319, to control nonpoint source pollution of ground-water. Since at least 1984, ground-water protection programs have provided technical and financial assistance to states for the development of state ground-water strategies and, more recently, Groundwater Protection Programs. Under the Safe Drinking Water Act, EPA may designate sole source aquifers. These are aquifers that are the sole or principal of drinking water source for an area. At EPA's discretion, no commitment for federal funds can be made for projects that will contaminate these aquifers. In addition, the 1986 amendments to the Safe Drinking Water Act established a Wellhead Protection program. This program was created to protect ground waters that supply wells and wellfields that contribute to public drinking water supply systems. USDA and EPA are also cooperating under a program to assess private drinking water wells on farmsteads. 5. Pesticides Program EPA's pesticides program under the Federal Insecticide, Fungicide, and Rodenticide Act addresses some forms of nonpoint pollution. Among other things, this statute authorizes EPA to control pesticides that may threaten ground water and surface waters. Pesticide State Management Plans will be developed by state agriculture, water/ environment, and health agencies and will prescribe pesticide application measures to protect ground water that is vulnerable to pesticide contamination. Required components of these Plans will include: state philosophy and goals, state roles and responsibilities, legal authority, resources, assessment and planning, monitoring, prevention, response, enforcement, public awareness and participation,information dissemination, and records and reportifig. 6. Wetlands Protection Program EPA's wetlands program also has undertaken a number of projects to increase awareness of the relationship between the protection and restoration of wetlands and nonpoint source control. In 1990, the agency developed guidance to encourage coordination of nonpoint sources and wetlands programs, both within EPA and the states, to attain water quality goals shared by the two programs. In addition, EPA has released technical guidance on how to ensure effective application of water quality standards to wetlands. The Wetlands Division is working with several agencies to develop methods and transfer information on protecting and restoring wetlands in ways which can be expected to provide nonpoint source abatement benefits. EPA is providing support for the development of criteria to address the many types of nonpoint source pollutants including nutrients, clean sediment, and organic contaminants (e.g., @esticides) *The Wetlands Division is assisting in the development of wildlife criteria applicable to all waterbody types and biological criteria for wetlands. National Oceanic and Atmospheric Administration (NOAA) Coastal Zone Management Program The Coastal Zone Management Act of 1972 established a program for states and territories to voluntarily develop comprehensive programs to protect and manage coastal resources. In order to receive Federal approval 17 and implementation funding, states and territories must demonstrate that they have progrards, incldding enfo!rceable policies that are sufficiently comprehensive and specific to regulate land uses, water uses, and coastal development; and to resolve conflicts among competing uses. In addition, they must have the authority to implement the enforceable policies. The programs operates within a coastal zone bound any which includes coastal waters and those which have a direct one significant impact on coastal waters. This program must protect and manage important coastal resources, including: wetlands, estuaries, beaches, dunes, barrier islands, coral reefs, and fish and wildlife and their habitats. Resource management and protection is accomplished in a number of ways through state laws, regulations, permits, and local plans and zoning ordinances. While water quality protection is integral to the management of many coastal resources, it was not specifically cited as a purpose or policy of the original statute. The Coastal Zone Act Reauthorization Amendments of 1990 specifically charged state coastal programs, as well as state nonpoint source programs, with addressing nonpoint source pollution alfecting coastal water quality. United States Department of Agriculture (USDA) USDA's Agricultural Stabilization and Conservation Service (ASCS), Soil Conservation Service (SCS) and Extension Service administer a number of programs that contribute to reducing nonpoint pollution from agricultural production. 1. Agricultural Conservation Program The Agricultural Conservation Program, administered by ASCS, provides cost-share funds to farmers and ranchers to install conservation practices. The program has several goals including: conserving soil and water, improving water quality, protecting and maintaining productive farm and ranch land, and preservin@ and developing wildlife habitat. ASCS also administers the Conservation Reserve Program (CRP), designed to protect the most highly erodible land and to protect and improve water quality. Under the CRP, farmers are reimbursed for retiring highly erodible and environmentally sensitive croplands from production under ten year contracts. Water quality improvements occur as lands are taken out of 18 production because of-lower fertilizer and pesticide applications and because reductions in soil erosion decrease sediment loadings to water. Land enrolled in the reserve program also provides habitat and other environmental benefits. Criteria for the conservation reserve program have been expanded to include environmentally sensitive lands such as filter strips, wetlands and wellhead protection areas. . & 2. Soil Conservation Service The Soil Conservation Services (SCS) is the technical arm of USDA. SCS provides technical assistance to conservation districts throughout the U. S. and Puerto Rico. Under the President's Water Quality Initiative, started in 1989, SCS is focusing some of its technical assistance on a number of demonstration projects to address water quality problems. SCS staff are also located in many of EPA's Regional Offices to provide technical assistance and support to the States and EPA. SCS is also providing accelerated technical assistance to multi-state, regional projects such as the National Estuary Program. 3. Nonpoint Source Hydrologic Unit Areas In selected agricultural watersheds and aquifer recharge areas, SCS, Extension Service, and co9perating federal, state and local agencies will provide technical assistance and conservation planning to help farmers and ranchers meet state water quality goals without undue economic hardship. These hydrologic units are selected based on: significance of the agricultural sources of pollution, relative predominance of pollutants such as pesticides, nutrients, and animal wastes; and conformance with other water quality efforts. Findings on the water quality effects of selected conservation practices will provide a basis for expanding applications of -such practices to other areas with similar water quality problems. 4. Forest Service In Puerto Rico, the Forest Se rvice manages approximately 14,400 acres of public lands at the Caribbean National Forest, part of the National Forest System. This agency shows increased concern regarding the potential impacts of sediment production from forest management activities on water quality and aquatic life. . It currently requires the implementation of Best 19 Management Practices Plans (BMPs) to any project carried out or proposed within Forest boundaries. These BMPs include provisions to prevent possible sources of NPSP. 5. President's Water Quality Initiative In 1989, President Bush launched an initiative to protect ground and surface water from contamination of fertilizers and pesticides. Congress has funded the initiative in the past several years. USDA, EPA, USGS, and NOAA are all working together on this initiative through a series of work groups. Through this initiative, a number of watershed projects have begun to address fertilizer and pesticides problems. The agencies are tracking the implementation progress in these watersheds. United States Geological Survey (USGS) EPA and the U.S. Geological Survey have signed a memorandum of understanding (MOU) pledging cooperation and collaboration on water quality monitoring and assessment activities. Both agencies expend much effort on monitoring and assessment activities and the MOU is a tool to coordinate these efforts. USGS has a similar agreement with Puerto Rico's Environmental Quality Board. Related Federal laws and regulations a. The Clean Water Act (CWA) (33 USC 1251, et seq.) b. The Rivers and Harbours Act (RHA) (33 USC 401 et seq.). c. Endangered Species Act (ESA) - 1973 d. Act for the Protection of Marine Mammals (1972) (16 USC 1361 et seq.). e. Food Security Act, 1986 (16 USC 3821, et seq.). f. Emergency Wetlands Resources Act of 1986 (PL-99-645). 20 g. Executive order Num. 11990, emitte& by President J. Carter on May 24, 1977 (42 CFR 26961). h. Coastal Areas Management Act (1972) (16 USC 1451 et seq.). 2. Commonwealth level Environmental Quality Board (EQB) EQB is the local government agency with the legal responsibility to implement federal and state laws and regulations concerning pollution in Puerto Rico, it is the local "Lead Agency" concerning all types of pollution. It has designated a Nonpoint Source Division under the Water Quality Area with the main objective of controlling nonpoint source pollution from livestock farms, and from sewage disposal in small communities. They address the first by'requirinj@ livestock'farms to implement Best Management Plans (BMPs). By agreement with Puerto Rico's Department of Agriculture (PRDA) and the federal Department of Agriculture (USDA), farms found in violation of their BMPs can loose subsidies and services offered by PRDA and USDA. The implementation of these Plans is monitored by both EQB and PRDA personnel. To address the second, EQB may provide financial assistance for the construction of wastewater treatment works in rural communities. Estuaries and wetlands conservation and management is another concern of this Division, and EQB may also provide financial assistance to deal with these problems. As part of this Division tasks, EQB collects surf ace and ground water quality data both from its own Water Quality Monitoring Network and from monitoring stations operated by the United States Geological Survey (USGS). This data, together with information provided by BMPs and other permits applications (like is analyzed to pinpoint probable sources of NPSP in Puerto Rico's major river basins. Certain EQB programs related to point-source pollution, like requiring Erosion and Sedimentation Control Plans to major construction projects, and the emission of National Pollutant Discharge and Emission System (NPDES) permits, are a source of useful data for evaluating the impact of non-point source pollution at specific areas. 21 Related laws and regulations: -Act 9 of 1970 (Environmental Public Policy Act) Established the Environmental Quality Board as the agency in charge of the surveillance, management and conservation of the quality of air, waters and soils in Puerto Rico.' -Regulation of Environmental Impact Statements (1984). EQB fulfill this mandate through the evaluation of Environmental Impact Statements and other environmental documents. - Water Quality Standards Regulation (1990). Based on current EPA water quality standards, this regulation established similar standards for Puerto Rico. Currently it does not include standards or use classifications for wetlands, but includes an anti-degradation statement applicable to wetlands. - Regulation for Hazardous and Non-Hazardous Solid Waste Control (1983). Department of Natural Resources (DNR) The Department of Natural Resources is responsible for regulating the extraction of water, soil and minerals through the emission of corresponding permits. It evaluates any project which includes the above-mentioned activities, and potential for non-point source pollution is one of the elements considered. DNR is also responsible for ensuring the conservation of natural aquatic and terrestrial ecosystems. Extraordinary episodes , like fuel spills and fish kills, are monitored by DNR. Though not an integral part of DNR, the Coastal Zone Management Program of Puerto Rico (CZMP) is ascribed to this agency. CZMP regulates development activities within the coastal zone of Puerto Rico by proposing to the Planning Board the designation of natural reserves and areas "of special planning", in which certain human activities are restricted. 22 Related laws and regulations: -Act 23 of 1972 (Organic Act of the Department of Natural Resources) Established the Department of Natural Resources as the state agency in charge of the protection, surveillance and conservation of all natural resources of Puerto Rico, including water resources and aquatic biota. -Act 83 of 1936, as amended (Fishing Act) For fishing conservation; conservation of aquatic habitats is required since they are fundamental for the'life cycle 9f many fish species. -Act 6 of 1968 (pursuant to flood prevention and conservation of beaches and rivers). DNR is responsible for providing surveillance and protection to swamps, beaches, and rivers of the Commonwealth of Puerto Rico. -Act 133 of 1975 (Forests Act). DNR is responsible for the conservation, protection, and management of the forests of the Commonwealth of Puerto Rico. -Act 70 of 1976 (Wildlife Act). For the protection of wildlife and its habitats. -Act 1 of 1977 (DNR Corps of Rangers Act). Establishes the Corps of Rangers as the law-enforcement division of PRDNR and its statutes. -Act 6 of 1961, as amended. Stipulates that PRDNR is responsible for the surveillance and conservation of the Commonwealth's mangrove swamps. 23 -Act 144 of 1976 (Act for the Control of Excavation and Extraction of Land). -Spanish Act of Harbors and Rivers of 1896. Established the maritime-terrestrial zone as a public domain, including mangrove swamps. -Regulation for the Protection of Endangered Species and Critical Wildlife Management Areas in the Commonwealth of Puerto Rico (1985). -Regulation for the Development, Use, Conservation and Management of the Waters of Puerto Rico (1992). Regulates the extraction of ground and surface water in Puerto Rico. -Regulation for the Development, Surveillance, Conservation and Management of the Territorial Wate-rs, the Lands Under Them and the Maritime-TeTrestrial Zone (1992). It establishes zones of special concern or value in the maritime-terrestrial zone and territorial waters and regulates construction and extraction projects within those areas. Planning Board (PB) PB is in charge of establishing land zoning and designating corresponding planning objectives. As such, it is the PB the lead agency in the evaluation of development projects. It is also the state organism with legal power to designate state forests and reserves and other areas of special planning. Related laws and regulations: -Act 75 of 1975, as- amendLed (Organi@ Act of the Planning Board of Puerto Rico) Established the Planning Board as the agency in charge of preparing public policies and objectives regarding land use and zonification. 24 -Act 9 of 1970 (Environmental Public Policy Act) Designated the Planning Board as the agency in charge of preparing public policies regarding environmental protection. -Land Use Plan of Puerto Rico (1977) ' -Integral Development Plan of Puerto Rico (1979) Regulation 17, Regulation of Coastal Area Zonification and Beach and Coast Entrance. Regulation 13, Regulation for Floodable Areas. Regulation 4, Zoning Regulation (1989) Regulation for Special Zoning of Non-urban Areas for the Municipalities Surrounding the Caribbean National Forest (1983). Resolution Nurn. 74-21 (1974) to Preserve, Protect and Restore Mangrove Swamps in Puerto Rico. a 0 Puerto Rico Department of Agriculture (PRDA) PRDA is the local agency in charge of the development of agriculture and commercial fishing in Puerto Rico, including assignment of state and federal subsidies for agricultural production and other support services for farmers. Agreements signed by PRDA, USDA, and EQB give PRDA the joint responsibility (with EQB) of monitoring the implementation of Best Management Plans (BMPs) for livestock farms and for the suspension of all financial and technical support to farms found in violation of BMPs. PRDA is also in charge of the application in Puerto Rico of all USDA programs. 25 Aqueducts and Sewers Authority (ASA) ASA is in charge of developing sources of drinking and irrigation waters, of delivering these waters and of treating and disposing wastewaters according to federal and state laws and regulations. ASA is required NPDES permit for discharges from its wastewater and drinking water treatment plants and has been found in violation of these permits repeatedly by EPA. As a result, it has not only been forced to pay heavy fines, but also several of its plants had been temporarily arrested. Regulations and Permits Administration (REPA) -Act 76 of 1975, as amended. Established REPA as the agency in charge of the enforcement of planning regulations promulgated by the Planning Board by reviewing applications for the necessary permits for regulated activities, land use and construction projects. Solid Wastes Management Administration (SWMA) -Act 70 of 1978, as amended. Established SWMA as the agency in charge of assisting Commonwealth and local (municipal) governments in the development of infrastructure at the local and intermunicipal. levels for the disposal and recycling of solid wastes. Other applicable local legislation: Article IV of the Constitution of the Commonwealth of Puerto Rico (1952) Established the use and conservation of Puerto Rico's natural resources as a constitutional right. 26 III. THE FAJARDO RIVER BASIN The Fajardo River basin, located in northeastern Puerto Rico, covers some 118 km2 mostly within the municipalities of Fajardo and Ceiba, from the Luquillo Sierra. to the Vieques PAssage, an arm of the Caribbean Sea (Figure 1). This is the definition of the basin used by the United States Geological Survey (USGS); the Department of Natural Resources WNR) has used traditionally a wider definition which we did not agree with. The Basin, (as defined by USGS) contains the southern part of a small city (Fajardo; 40,000 people), rural neighborhoods, farms, a small local airport, one marina and a significant portion of the Caribbean National Forest, one of the few tropical montane rainforests within the National Forest Service system. The southern shoreline at the river mouth is covered by a small mangrove forest which is part of the Ceiba State Forest, managed by DNR. Although development in the area concentrates immediately north of the basin. government and private interest in the basin per se is growing, as evidenced by projects under way for flood control measures at the Fajardo River mouth, enlargement of the local airport, an increasing number of commercial farms, and residential and road construction projects. Between 1989 and 1993, DNR approved 99 -development projects' permits and endorsements (Figure 2) for the municipalities of Fajardo and Ceiba. 38.38% of them were for the reconstruction of public infrastructure, such as roads, docks and sewers. The Fajardo River has even been mentioned as the site of a possible new reservoir. There is already significant concern among environmentalists and community groups for the increase in silting of the River estuary and flooding along the river shore, and a reduction of fish stocks, allegedly due to past and current development within the basin. List of ruraL communities in the Fajardo River Basin: 7. Fortuna Ceiba 1. Puerto ReaL Fajardo City State 2. Santa Rita 8. Vapor Forest 3. FLorencio 9. SaLdafia 4. San Pedro 10. PeA6n rr2 5. Mabi 11. Paraiso 6. Josefa 12. Rio Abajo 3 Vieques Caribbean NationaL Passage Forest MunicipaLity of Fajardo MunicipaLity of Ceiba Map 01*0 ruraL communities Rio Fajardo main FIGURE 1: The Fajardo River Basin. municipaL Limits FIGURE DNR-approved permits and indorsements, municipalities of Fajardo and Ceiba (1989-1993). 2 23.23% 17,17% Housing Reconstruction Dredging Filling Land Segregation Commercial 9.09% W&PON.,400 00 38.38% 29 Goenaga and Cintr6n (1979), and Goenaga et al. (1990) cited possible increased discharge of freshwater and sediment from the Fajardo River as one cause for degradation of coral reefs and seagrass communities located off the Fajardo coast and at the nearby Cordillera Keys.. The Fajardo River Basin is a typical Antillean mountain river basin. In its headwater it flows in narrow valleys, have steep gradients, and tTansport and deposit coarse sediments. The rural areas of the basin are forested in its western third, the Caribbean National Forest having most of this. The rest is used mainly by farms with a splash of growing rural communities. Cow farms are present throughout the basin. In the lowlands, multiple channels and depositional surfaces occur within the valley floor. Sugar cane is still heavily planted in the alluvial valley next to the city of Fajardo. Throughout the basin, there are many small plantain (a fruit closely related to bananas) farms, and also a few small farms dedicated to pigs, chicken, fruits (limes, papayas, grapefruits, oranges) or cassavas. Land use Available data on land use at the Fajardo River basin, obtained at the Scientific Inventory Division of DNR, came from aerial photographs on the area dating from 1971 and 1979, and was organized in thirteen zoning categories and compared (see Table 1). Categories that showed the largest increases in percentage of change during that period were: transportation (+67.00%), communications (+50.00%), and forests (+38.39%). In terms of absolute measurements, though, only the category of forests presented considerable increase (+8.76 km2). On the other hand, the largest decreases in percentage of change corresponded to agriculture (-36.09%), and wetlands (- 31.03%), while the largest decrease in area was also in agriculture 09.62 km2). From this data one would expect that during the period 1971-1979, due to a reduction in agricultural lands and increases in forest area, and construction of transportation and communications projects, the generation of pollutants related to agricultural activities (fecal streptococci and coliforms, phosphates and nitrates, among others) would have decreased. An increase in forests would mean a' larger carpacity of soils to retain water, so measurements of water discharge would show diminished amounts. Finally, an increase in construction projects could have generated larger sediment 30 loads in the river. While visiting the area working on this project (1992), the authors received the impression that significant portions of land were being cleared to be used for rural and urban construction, and for livestock farming. TABLE 1: Comparison of land zoning categories for 1971 and 1979 at the Fajardo River Basin. LAND AREA PERCEN- AREA PERCEN- NET % OF USE 1971 TAGE 1979 TAGE CHANGE CHANGE (km2) M (km2) M (km2) Agriculture 54.46 46.15 34.84 F53 -19.62 -36.07 Forests 52.85 44.79 72.70 61.61 +8.76 +38.39 Wetlands 0.68 0.58 0.47 0.40 -0.28 -31-03 Non- 0.78 0.66 0.78 0.66 none none productive Residential, 4.12 3.49 4.00 3.38 -0.74 -3.15 Urban Residential, 3.46 2.93 3.U 2.83 -0.63 -3.41 Rural Recreational 0.58 0.49 0.50 0.42 -0.26 -2.00 Public Uses 0.40 0.31 0.44 0.37 -0.03 -8.38 Commercial 0.21 0.18 0.120 0.17 -0.04 -5.66 Industrial 0.28 0.24 0.30 0.25 +0.01 -4.00 Extractions 0.07 0.06 0.08 0.07 +0.01 +14.29 Transport 0.10 0.08 0.28 0.24 +0.14 +67.00 Communica- 0.01 0.01 0.02 0.02 +0.01 +50.00 tions TOTAL 118.00 100-00 118.00 100.00 ----- ----- Geology, hydrology, geography and soils More than a dozen geological faults cross the area of the Fajardo River basin. Most of them have a northwest-southeast orientation, although many also run from east to west. The western third of the basin, part of the Luquillo Sierra, comprises mostly mountains (some of them more than 670 m high) with steep slopes, and formed basicly from poorly cemented volcanic rock, sandstone and mudstone. Formations in these areas include cupric minerals and ferruginous @Iays. Soils here are thin, highly erodible, and highly acidic. 31 The other two thirds comprise of and alluvial plain of sand, clays and rock-and-pebble fields that broadens towards the river mouth, and then nears the mouth narrows again. To the west, north and south, this plain is bordered by hills formed of sandstone and mudstone. The alluvial plain is separated from the sea by mangrove swamp deposits. As one goes from west to east, soils gradually turn from thin to thick, from highly acidic to slightly acidic, and from highly erodible to erodible. The area is within the "rain mantle" of the Luquillo Mountains, the first geographical sttucture in Puerto tco, that encounters moist-ladden trade winds blowing in a northeast-to-southwest direction from the Atlantic Ocean most of the year. When trade winds make contact with the warm surface of the mountains, most of their humidity condenses into rain. As a result, the Sierra receives an annual rainfall that ranges from 70 to 500 cm. Sudden, heavy rains has been held responsible for constant bleaching of soil minerals, frequent natural landslides and sudden large increases of water discharge of the Fajardo River and its tributary creeks which causes, among other things, significant erosion of riverbanks in periodic episodes. It is possible that these episodes of sudden, large water discharges serve as a flushing mechanism for, at least, some of the pollutants that percolates or fall into the Fajardo River. However, this mechanism's action probably stops at the very moment that freshwater coming down the river meets the saltier, denser water mass at the estuary. Water management -at the b@sin: The Environmental Quality Board maintains a database of possible sources of NPSP in Puerto Rican rivers (we found, that for the Fajardo River, it needed updating). EQB, throughout its 1992 monitoring of point and nonpoint source pollution on Puert *o Rican surface waters, found in the Fajardo River Basin high levels of pesticides, metals, and phenolic substances and attributed them to the Fajardo Drinking Water Plant, the Fajardo Wastewater Treatment Plant, the Ceiba Municipal Landfill, urban runoff, road construction, soil extraction operations, and local produce and livestock farms, as well as to natural causes (Figures 3, 7 & 8). In terms of use potential, EQB divides the river into five segments: estuary segment, recharge area segment, unclassified area segment, drinking water area segment, and ;X1 Yin )-wer 32 V cite *10 CrCet *7 creer-*V fee yet 710 Cree c ree re e IL AL sQb jig o Krn LEr-eAD Mver A V,,,V%l+brnS at Sc.%t r-11 ko 14 G ATSPL F Ep wT IN(. PLAMT FIGURE 3: EQB's schematic description of FA9A POND -Drinv-i"c- L-jhT'C'P nonpoint-source polltion at the I fvT,&Kw- Fajardo River. 33 ecologically sensitive area segment (Table 2). An EQB description of the estuary segment (the only segment description available) is shown in Table 3. TABLE 2: EQB's use clasification of the Fajardo River. SEGMENT CLASSIFICATION TRIBUTARIES INCLUDED 1. From the river mouthto 2.2 Esiuary km upstream (Fajardo). 2. From the river mouth to Recharge area Redonda Creek Km 10.8 HW 976 upstream (Fajardo). 3. From the end of segment #2 Unclassified segment upstream to Km 11.4 HW 976 (Fajardo). 4. From the end of segment #3 Drinking water area Aguas Buenas Creek, Rinc6n (Fajardo) upstream to river's Creek, Juan Diego Creek, birthplace (Ceiba). Sonadora Creek 5. From Km 18.0 HW 976 Ecologically sensitive area (Fajardo) upstream to river's birthplace (Ceiba). TABLE 3: EQB's use description of the estuary segment of the Fajardo River. Water body name Fajardo River Water body segment type Estuary Water body segment size 2.0 miles Segment evaluation Estuarine Aquatic life support Partially supporting Swimming Partially supporting Secondary contact 2.0 miles. Threatened by wastewaters. Drinking Water Supply Unfit for drinking Overall Partially supporting Comments Presence of urban runoff. In terms of water properties and water quality parameters, EQB divides the river in two categories: "SC" (coastal-estuarine segment), and "SD" (all other surface waters). The Aqueducts and Sewers Authority has a Drinking Water Plant at , and a Wastewater Treatment Plant (Figures 7 & 8). This last plant discharges filter backwash to the river under a NPDES (National Pollutant Discharge and Elimination System) permit issued by EQB. Frequently, it has been found in violation of permit specifications (Table 4) 6 0 34 TABLE 4: NPDES permit limits imposedby EQB on ASA's wastewater Plant filter backwash discharges unto the Fajardo R. Clows Parameters NPIDES Limits Jan 1991 Feb 1991 Mar 1991 Apr 1991 May 1991 1 M >5 mg/l 2 Total Coliforms 10,000/100 ml 3 Fecal Coliforms 4,000/100 ml 4 Color lo STU 5 Surfactants 100 mg/I 6 Flow 2.2 MGD 7 TSS 30-45 mg/I 8 Residual Chlorine 0.5 ma/I 1.2 1.2 9 Turbidity 50 NTU 1300 750 0 0 10 Phosphorus, total 1 mg1l 0 2.39 1.91 1.96 11 Copp2r 40 ug/l 80 60 12 Lead- 50 --uq/l 13 Zinc 50 I&g/I 70 14 Fluoride 700 IA /1 0 15 Iron, total 300 Igg/I 27000- 25001 38001 38001 89 Rows Jul 1991 Aug 1991 Sep 1991 Oct 1991 Nov 1991 Dic 1991 Jan 1992 2 230000 3 230000 4 30 5 0 6 2.8 7 8 1.9 1.7 3 1.3 1.3 2.5 9 390 10 0 0 3.5@ 11 0 0 12 70 13 90 14 90001 590L+- 1 151 12001 60001 0 64501 68001 10000 M 50 39 35 Rows Fab 1992 Mar 1992 Abr 1992 May 1992 Jun 1992 Jul 1992 Aug 1992 1 - 0 0 0 . 1 2 11000 70000 50000 23000000 13000000 3 30000 30000 13000000 3000000 4, 25 50 45 35 30 45 30 5 1640 0 9 800 1000 6 2.54 3.25 4.g6 2.91 3.09 7 8@ 79 35 40 8 2.6 3 2.8 2 2 4 8 9 - -0 0 315 850 55 10 2.87 5.45 5.09 4.46 3.35 4.41 11 125 70 70 12 .1 0 13 701 2201 1301 1401 14 0 .1 -1 9855 26001 200001 7001 15 38000 400 Rows Sep 1992 Oct 1992 Nov 1992 Doc 102 1 4.9 4 4.4 2 210QOOO 3 170QOOO 5000000 300000 41 50 40 30 30 5 3750 950 1000 @200 6 3.68_ 3.6 4.97 4.05 7 0. 48 35 35 8 2.2 2.2 3 4 9. 600 0 0 10 4.18 --4.22 4.66 3.04 12 13 14 79001 6100 3100 5800 36 creating a point-source pollution (turbidity, fecal bacteria, metals, nitrogen, phosphorus, etc.) that is difficult to pinpoint as separate from NPSP in the Fajardo River. Natural biota and biodiversity: USGS assessed phytoplankton populations in the Fajardo River from 1977 to 1981 at monitoring station #USGS 710. It also monitored, at the same station, benthic invertebrates from 1980 to 1982. During those periods, 39 species of microalgae (Table 5), and 37 species of benthic invertebrates (Table 6) were collected and identified. Ananalyses of the river's phytoplankton standing crop, defined as the amount of microalgal cells per milliliter of sampled water, is shown on Figure 4. It fluctuated from 0 to 2,000 cells/ml with an extraordinary peak in 1978 of around 11,000 cells/ml. While the number of different species compares favorably with similar, nearby rivers like the Mameyes, species diversity was very low, as demonstrated by the fact that only two or three species of phytoplankton or invertebrates were dominant on any single sampling day (Figures 5 & 6). Low biodiversity may be induced by the frequent entrance to the river system of external tensors, such as pollutants. It has been reported that the Fajardo River is frequently visited by recreational fishermen looking for tarpon (Megalops atlantica), and snooks (Centropomus sp.). In addition, the authors of this report observed green macroalgae of the genus Chara growing in some sections of the river passing through the city of Fajardo, as well as needlefishes (Belonidae) and mullets (Mugilidae) swimming in the estuary segment. ROWS DIVISION CLASS ORDER FAMILY GENUS COMMENTS I Chlorophyta** Chlorophyceae Chlorococcales Ooscystaceae Ankistrodesmus Common in pools & ponds. 2 Chlorella Widespread in organically rich & polluted waters. 3 Gloeoactinium 4 Kirchneriella Usually an open-water group. 5 00cystl .S Common. 6 Selenastrum Common in shallow waters. 7 Scenedesmaceae Scenedesmus Corm-non in pools & ponds. 8 Cledogoniales Oedogoniaceae Oedogonium 9 Volvocales Chlamydomonadaceae Chlamydomonas Very common, specially in barnyard pools and water throughs. 10 Zygnematales Desmidiaceae Closterium Found in soft-water habitats. I I Cosmarium Found in soft-water habitats. 12 Staurastrum Usually found in acid or soft- water habitats. 13 Chrysophyta Bacillariophyceae Achnantales Achnantaceae Achnantes 14 Cocconeis 15 Bacillariales Nitzchiaceae Denticula 16 Nitzchi .a 17 Surirellaceae Surirella 18 Eupodiscales Coscinodiscaceae Cyclotella Found on hard or alkaline water habitats. 19 Melosira Common. 20 Naviculales Cymbellaceae Cymbella 21 Diatomaceae Diatoma 22 Eunotiaceae Eunotia Found in soft or acid water habitats. 23 Fragilariaceae Fragilart .a 24 Synedra 25 Gomphonemataceae Gomphonema 26 Naviculaceae Frustulia 27 1 Gyrosigma Common. TABLE 5: Phytoplankton identified from samples taken at station USGS 710, Fajardo River. 28 Navicula 29 Pinnularia 30 Cyanophyta** Cyanophyaceae Chroococcales Chroococcaceae Anacystis 31 Hormo onales Nostocaceae Anabaena 32 Anabaenopsts Found only in nitrogen-rich waters. 33 Aphanizomenon 34 Oscillatoriaceae Lyngbya Common in lakes & streams. 35 Oscillatoria 36 Schizothrix 37 Spirulina 38 Rivulariaceae Rachidiopsis 39 Euglenophyta** Euglenophyceae EuLdenales I r-1--aceae Trachelomonas NOTES: Row numbers are the same as those used in Figure 5 Usually, Chlorophyta is more abundant in freshwater habitats than all other algal groups combined. Cya4ophyta is most abundant in lotic waters rich in organic matter. Euglenophyta are almost always found in ponds rich in organic matter. W Co ROWS PHYLUM CLASS ORDER FAMILY GENUS COMMENTS 1 Annefida Oligochaeta Plesiopora Tubificidae unknown 2 Prosopora unknown unknown 3 Arthropoda Crustacea Decapoda Palaemonidae Macrobrachium 4 Palaemonetes 5 Insecta Coleoptera Elmidae Stenelmis 6 Diptera Chironomidae Ablabesmya 7 Chironomus 8 Conchapelopia 9 Cricotopus 10 Eukiefferiella 11 Labrundinia 12 Larsia 13 Limnochironomus 14 Paramert'na 15 Pentaneura 16 Polypedilum 17 Tanytarsus 18 Thienemanniella 19 Empididae unkn6wn 20 Ephemenoptera Baefidae Baetis 21 unknown 22 Caenidae Caenis 23 Ephemerelfidae Ephemerella 24 Heptagenfidae Stenonema 25 Leptophlebiidae Hermanellopsis 26 Leptop lebia 27 unknown 28 Lepidoptera Pyralididae Paragyactis 29 Odonata Coenagrionidae Emallagma 30 unknown 31 Tricho tera Calanoceratidae Phylloicus 32 Hydroptilid22__@Hydroptila 33 Oxyethira TABLE 6: Benthic invertebrates identified from samples taken from station USGs 710, Fajardo River. 34 Mollusca Gastropoda Basommatophora Ancylidae Ferrissia 35 Mesogastropoda Pleuroceridae Goniobasis 36 Pleurocera 37_ Platyhelminthes Turbellaria Tricladida Planariidae unknown 39 Row numbers are the same as those used in Figure 7. 0 Plot 42 12000- 10000- 8000- 0 0 6000- a 49 U) 4000- 2000- 0 7/7/77 2/24/78 10/13/78 6/2/79 1/19/80 9/7/80 4/26/81 12/14/81 Date Stan Crop FIGURE 4: Phytoplankton standing crop from the Fajardo River. N J@A 44 population 7000.00 6000.00 !;000.00 4000.00 3000.00 200.00 1000. 00 0.00 sampling days -------------------- species FIGURE 5: Phytoplankton, biodiversity at the Fajardo River. 45 PIO'Rulation 150.00 100.00 50.00 0.00 species sampling days FIGURE 6: Benthic invertebrate biodiversity at the Fajardo River. 46 IV. WATER QUALITY HISTORY OF THE FAJARDO RIVER Sampling stations EQB only established one monitoring station on the Fajardo River Basin (EQB 78B). It is a c6astal marihe station located in estuarine waters immediately north of the Fajardo River mouth that receive freshwater aport from the river (EQB classification "SC"). EQB has contracted USGS to monitor the river per se (EQB classification "SD"). USGS has three stations along the river: USGS 710, 720 and 725. The locations of these stations is described in Table *7 and sliown in Figures 7 & 8. An analysis of relevant historical data gathered by EQB and USGS is presented in Table 9. Figures 9-70 are plots of this data for each station. TABLE 7: Water quality monitoring stations located at the Fajardo River Basin. Station Monitoring Agency Location Period Monitored USGS 710 U. S. Geological Survey On left bank, HW 976, 1960-1992 5.3 krn sw of Fajardo. USGS 720 U. S. Geological Syrvey At bridge on HW 3, 1958-1967,1974 0.8 km south of Fajardo. USGS 725 U. S. Geological Survey 1.9 krn sw of Playa Fajardo. 1974-1992 EQB 78B P. R. Environmental Quality Coastal marine station loca- 1986-1990 Board ted at Isleta Marina dock, 1.5 krn nw of river mouth. --------------------------- ---------- --------------------------------------------------------------------- 47 SARDINERA PLAYA SARDINERA PTA.BATERIA BAHIA BELTRAN DE FAJARDO P, PLAYA, DE FAJARDO -PUERTO NOR REAL EQB 78B PTA FAJARDO P EBLO RIO FAJARDO ESTE A USGS 725 A -N- SANTARLTA EST It VERTEDERO ESCALA APROXIMADA USGS 720 120,000 1KM FIGuRE 7: water quality monitoring stations and nonpoint sources, as identified by EQB, along the Fajardo River. MAPA AREAS IDENTTFICADAS DE FUENTES DE CONTAMINACION NO PRECISADAS 48 LEYENDA LEGEM FOR FIGURE 7 Mapa 1. Areas identificadas de fuentes de contaminaci' on no precisadas. 4D Estaciones de Bombas - Autoridad de Acueductos y Alcantarillados. Pump stations-ASA 0 Estaci6n de Monitoreo - Servicio Geol6gico de E.U. USGS water quality monitoring stations Sistema de Uso Nacional de Eliminacion de Descargas Contaminantes (Privadas). Private NPDES discharge systems Sistema de Uso Nacional de Eliminacion de Descargas Contaminantes (Nblicas). Public NPDES discharge systems 'All Estaci On de'Monitoreo Junta de Calidad Ambiental. EQB water quality monitoring station Estaciones de Muestreo Departamento de Recursos Naturales. 49 G) CARR. USGS 710 ESTAGION DE VERTEDERO ESGUELA PERON RIO ARRIBA RIO ARRIBA Ceiba Land- f ill 01 PARAISO Fajardo Landfill Ah RIO ABAJO CARR 971 FAJARDO ESCALA APROXIMADA Fo-1 1:20, 000 FIGURE 8: Water quality monitoring station and nonpoint I KM sources, as identified by EQB, along the Fajardo River. MAPA AREAS IDENTIFICADAS DE FUENTES DE CONTAMINACION N - NO PRECISADAS 50 LEYENDA LEGEND FOR FIGURE 8 lapa 2. Areas identificadas de fuentes de contaminacion noprecisadas. Vertederos de relleno sanitarios Municipal landfills Pozos de oxidacion oxydation ponds Estacion de monitoreo (JCA) Sistema de uso nacional de eliminacion de descargas contaminantes. NPDES discharge system ------ Fajardo River main course 51 Table 4 shows data from the monitoring of backwash discharges during 1991-1992 from the Fajardo Water Treatment Plant into the Fajardo River. Though a point-source type of pollution that requires a NPDES, since these discharges goes directly into the river, such data is needed to compare with water quality data from the river's monitoring stations as an attempt to separe pollution froin poinesources fr;m pollution from non-point sources. Water discharge Water discharges from the Fajardo River are typical (in volume and behavior) of northeastern Puerto Rico mountain rivers born at the Luquillo Sierra (Table 9: parameters #1 & 2; Figures 9 & 10). The fact that these parameter has not shown significant change over time indicates that those factors which may affect water retention capabilities of the basin's soils (like significant vegetation cover loss, excessive water extraction from the river, channelization, construction of dame, dikes or some other sort of flood- control or water-retention project) are still absent from the basin. Temperature Temperature is a measure of heat. The physical properties of water are dependant to a large degree on heat, since cool waters are capable of dissolving more gases, salts, and minerals than warm waters. Aquatic organisms adapt themselves to the natural heat fluctuations of the body of water which they inhabit. Sudden extreme temperature changes can kill these organisms as well as cause significant changes in the physical and chemical properties of water. Temperatures in surface waters in Puerto Rico usually fluctuate at around 300C. Abnormally high temperatures may be due to warm water discharges or decomposition of huge amounts of organic matter. Temperature 'surges feflected in7data from the Fajardo River (Table 9: parameter #3; Figure 11) coincide with peaks in other parameters like BOD (parameter #17; USGS 725: 1973, 1977), total organic nitrogen (parameter #37; USGS 725: 1973, 1974), and valleys in DO (parameter #15; USGS 710 & 725: 1973-1974), suggesting that * decomposjtion of abnormally high amounts of organic matter throughout the river is the likely cause. 52 Plot FIGURE 9: Instantaneous water discharge 700- - USGS 710 600- 500- 400- 300- 200- 100- 0 11/13/57 1/14/61 3/16/64 5/18/67 7118no 9117n3 11118n6 1/19/90 3/22183 5/22/86 7/23/89 9/22/92 Date Plot 1100- 500- 1000- 900- USGS 725 USGS 720 400- 800- 700- CD 300- 600- 21 500- 200- 400- 300- 100- 200- loo- 0 r---r-7 9/17/73 1/19/80 5/22/86 9/22/92 11/13/57 3/16/64 7/18/70 Date Date 53 Line Chart 60000- 50000- USGS 710 40000- 30000- 20000- 10000- 0- 1966 1971 1976 1981 1986 1991 FIGURE 10: Annual water discharge Line Chart 40000- USGS 720 30000- 20000- 10000- 0 1961 1962 1963 1964 1965 54 Plot FIGURE 11: Temperature 32- 31- USGS 710 30- 29- 28- 27- 26- 25- 24- 23- 22- 21-, 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date Temp. 32- USGS 720 31- 30- 29- 28- cz 27- E 26- 25- 24- 23- 22 11/13/57 1/14/61 3/16/64 5/18/67 7/18/70 9/17/73 55 Line Chart 35 EQB 78B 3o- 25- 20- E 15- 10 5- 0 09/24/87 01/1@/89 09/210/90 Plot 38- 36- USGS 725 34- 32- E 30- 28- 26- 24- 22 9/17/73 1/19/80 5/22/86 9/22/92 Date 56 Conductance, salinity, dissolved solids Conductance is a measure of the speed with which an electric current is transported through water (conductivity of water). As the concentration of ions in water increases, so does conductance. Marine waters show conductance values of more than 200 gs/cm, freshwaters usually show less than 100 gs/cm, and estuarine waters has values anywhere in between. Conductance is sometimes used as indirect measurements of water salinity and amount of dissolved solids. Salinity, to use the simplest pqssible definition, is a measure of the amount of dissolved salts in water. Marine waters have salinity values of 30- 40 ppt. Freshwaters have a value of 0 ppt. Estuarine waters measure anywhere in between. Dissolved solids is a measurement somewhat similar to salinity but it is more general because it includes any solids in water that can precipitate, not just salts. All three parameters vary with freshwater inputs, sea water intrusions, droughts, temperature chAnges, sedImentation, and inputs of any ion- producing substance. Conductance level fluctuations of over 150 gm/cm. on stations USGS 720 & 725 may reflect periodic saltwater intrusions from the river estuary (Table 9: parameter #4; Figure 12). However, peaks in 1973 and 1980 appearing also at station USGS 710 (upriver) may signal episodes of NPSP occurring along the river. Salinity, measured at station EQB 78B, is normal for coastal estuarine situations (Table 9; parameter #5; Figure 13). Dissolved solids show a declining tendency (Table 9: parameters #10 & 11; Figures 14 &15). Fecal bacteria Bacteria are microscopic, unicellular, autotrophic organisms assigned by biologists to the Kingdom Monera. Typically they are either spherical (cocci), rodlike (bacilli) or threadlike (;pirilli). They often clump together to form colonies. Many bacteria are found naturally in the soil or in surface waters. However, bacteria that transmit waterborne diseases do not multiply in natural waters or even in heavily polluted waters. Water and wastewaters are not good media for their growth. Water serves primarily as a mechanical 57 Plot FIGURE 12: Conductance 300- USGS 710 250- 200- 79 - 8 150- 100- so -7 ......... 1-... .7r- 11/13/57 3/16/64 -5118/67 7/18no- 9117n3 -iiiiim 3/=? 5/22/86 7/23/89 9/22/92 Date Plot 4000- 11000- 3500- 10000- USGS 725 USGS 720 9000- 3000- 8000- 2500- 7000- 0 6000- Z 2000- 5000- 0 1500- 4000- 3000- 1000- 2060- 500- 1000- 0 0- 9/17/73 1/19/80 5/22/86 9/22/92 11/13/57 3/16/64 7/18/70 Date Date Conductance 58 FIGURE 13: Salinity Line Chart 40- EQB 78B 35- a 0 30- 25- -=1 '9 Z% 20- A ,a co 15- 10- 5- 0- 1 1 1 09/24/87 01/19/89 09/20/90 q vv 6 0 59 Plot FIGURE 14: Dissolved solids 60 USGS 710 50- 40- V = 30 0 Cl) 20- 10- 0*1 1 1 1 1 1 1 1 1 1 1 11/13/57 3/16/64 7/18/70 .11/18/76 3/22/83 7/23/89 Date P I o t 40- 0 USGS 725 35- 3o- 25- co 20- C/) 15- 10- 5- 0 9/17/73 1/19/80 5/22/86 9/22/92 . Dale 0 60 P1 ot FIGURE 15: Sm of dissolved solids 170- 160- USGS 710 150- 140- 130- 120- 110- 100- -6 go- so- 70- 60- so- 40- 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date P I o t 120- Plot 110- USGs 720 170 USGS 725 100- 160- 150- 90- 140- E 130 80- CO E 120- 110- 70- cn 100 go- 6o- 80- q 50- 70- 60-1 1 7-1 40- 9/17/73 1/19/80 5/22/86 9/22/92 6/15/59 8/16/62 10/16/65 Date Date 61 medium for transmission of disease organisms, and most of the natural processes that go in water decrease the likelihood of transmittance. Pathogenic bacteria usually originates in the intestines and feces of warm- blooded animals. Consequently, water borne outbreaks are associated with recent, gross pollution. One of the measures used as an indicator of possible sewage pollution is Total Coliform Bacteria Count. Coliform bacteria are a kind of aerobic or facultative anaerobic bacillus. However,general bacterial counts, such as this are not the best indicators because natural microbial flora is also present. As a result, Fecal Coliforms are fr;quently separated and censused. Fecal coliforms are mostly associated to human fecal material. Fecal Streptococci, bacteria usually associated with farm animals' fecal material, are also commonly counted in surface waters. The Fajardo River Basin has a history of coliforms outbreaks (Table 9: parameters #42 & 43; Figures 16 & 17). Its many cattle farms allow their animals free access to the river, there are many rural houses that still spill their wastewater to the river and the Fajardo Wastewater Treatment Plant discharges its filters backwash into the river. From a high peak in 1973, reflected at all stations, the situation has gotten better but its still unsatisfactory. Turbidity, color, suspended materials Turbidity is a measure of the cpncentration of suspended material in water. Color is an estimate of the amount of organic matter in water whose decomposition process produces dark-colored substances. Suspended sediments is a measure of the amount of suspended material in water. An excess of suspended materials in water produces a significant reduction in light penetration, which affects photosynthetic organisms and, eventually, their production of oxygen and coitsumption of carbon dioxide (C02). Sediments also clog the gills of aquatic animals, asphyxiating them. Except for a peak in 1981 (USGS 710 & 725), turbidity fluctuations appear to be localized episodes (Table 9: parameter #8 ; Figure 18). Suspended sediments may be able to precipitate or settle between stations. Sediment fluctuations at station EQB 78B are high and may be due to the vicinity of this 62 Plot FIGURE 16: Fecal Coliforms 60000- USGS 710 50000- 40000- 30000- 20000- 10000- 0 -T- 11/13/57 1/14/61 3/16/64 5/18/67 7/18/70 9/17f73 11/18t76 1/19/80 3/2Z/83 5/22/86 7/23/89 9/2Zt92 Date 7-1 Plot 50000- EQB 78B 40000- 30000- 20000- 10000- 0- 7- 5/22186 12/22/87 7/23/89 2/21/91 Date 63 p I o t 20000000- USGS 725 15000000- 10000000- 5000000- 0 9/17/73 1/1 9/8Q 6/22186 9/22/92 Date 64 Plot FIGURE 17: Fecal streptococci 50000- - USGS 710 40000- 30000- 04 20000- 10000- 0- 011 &A4 6- 11/13/57 1/14/61 3/16/64 5/18/67 7/18f7O 9/17f73 11/18/76 1/19/80 3/22/83 5/22186 7/23/89 9/22/92 Date Plot 2000000- USGS 725 1500000- Q CL (D 1000000- 500000- 0-7 9/17/73 1/19/80 5/22/86 9/22/92 Date 65 Plot FIGURE 18: Turbidity 200- USGS 710 loo- 0 11/13/57 1/14/61 3/16/64 5/18/67 7/18170 9/17/73 11/18fl6 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date Plot 2000- USGS 725 1500- 1000- 500 9/17/73 1/19/80 5/22/86 9/22/92 Date 66 Plot 30.00- EQB 78B 25.00- 20.00- 15.00- :9 .0 I a 0 10.00-- -- - - - - - - -- - - - - --- 5.00- 0.00 1 1 1. 1 1 1 5/22/86 - IZ=7 7/23/89 2/21/91 Daw v 6 station to a marina whose boat motors lift bottom sediments continually (Table 9: parameters #7 & 9; Figures 19, 20 & 21). Suspended oils and greases, measured at EQB 78B, show frequent peaks which may be due to frequent small spills from boats at the marina (Table 9: parameter #14; Figure 22). Oxygen requirements Oxygen conc6ntratioiis determir@e the kinds of living activities that can go on in water. It is determined mostly by water temperature, salinity, pressure, and the interaLiion between water and atmosphere. Cool, clear, fast- moving, over-oxygenated mountains streams support a small variety of specialized organisms. As water slows and organic matter accumulates, these organisms are replaced by d larger variety of more tolerant types. However, if the concentration of organic wastes continue increasing, it could reach the level in which oxygen is completely depleted by decomposition (water turns anaerobic). Most organisms will be wiped out, bacteria will begin obtaining oxygen from nitrite, nitrate, or sulfate in that order. Nitrite and nitrate will be reduced to nitrogen gas which will show as bubbles. Sulfate will be reduced to hydrogeh sulfidb. Sulfideg react with metals in water to form a black suspension that darken polluted waters. Metals will also be reduced. Soluble ferric and manganic compounds will turn into insoluble ferrous and manganous ones. Organic matter decomposition will grind to a halt without oxygen, leaving in the wate; organic ajids, alcohols, and aldehydes, as well as C02, that normally are just transitional products in the breakdown of organic matter. Chemical Oxygen Demand (COD) is a measurement of the amount of dissolved oxygen required to convert organic waste compounds in the water to stable, inoffensive, and harmless compounds (preferably, water and carbon dioxide). As such, it is an indirect measurement of the amount of organic and reducing material present. Determined values may correlate with water color or organic pollution. Biochemical Oxygen Demand (BOD) is the most popular measurement of the likely behavior of organic wastes as oxygen consumers. It measures the oxygen levels need@d for tl@e biochemLl oxidation of organic matter. 68 P 10 t FIGURE 19: Suspended solids USGS 710 2000- CL 1000 - - - - --r- 1-7 r- lt/13/57 3716/64 7/18/70 1 T/18/76 3/22/83 7/23/89 Date P 10 t USGS 725 2000- 1500- CL - U) D (n -(OD 1000- 500- 9/17/73 1/19/80 5/22/86 9/22/92 Date 69 P10 t FIGURE 20: Residue of suspended solids 200- USGS 710 CL loo- 11/13/57 3/16/64 7/1-8/70 1111 8_/766 V22@/83 7123189 Date Plot 110- 100- EQB 78B 90- 80- 70- E co 60- 2 j2 50- 40- 30- 20- 10 5/22/86 12/22/87 7/23/89 2/21/91 Date 70 P I o t 700 - USGS 725 600- 500- 400- CD cc 300- 200- 100- - I I 1@ - - @ 0 9117/73 1/19/80 5/22/86 9'/22/92 Date Plot 110- - USGS 720 100- go- CD cc 0 U) 80- 70- 60 6/15/59 8/16/62 10/16/65 Date 71 Plot FIGURE 21: Color 10- USGS 710 9- 8- 7- 6- 0 0 4- 3- L 2- 0 11/13/57 1/14/61 3/16/64 5/18/67 7/18170 9/17fl3 11/18f76 1/19/80 3/22/83 5/22/86 7/23/89 9/2.' Date 40- Line Chart 35- 20- EQB 78B 30- USGS 720 15- 25- 0 0 20- 10- u 15- 10- 5- 5- 0.- T- 09/24/87 01/19/89 09/20/90 0 1 6/15/59 8/16/6210/16/65 Date 72 Plot 8.00- FIGURE 22: Suspended oils and greases EQB 78B 7.00- 6.00- 5.00- 4.00- 3.00- 2.00- 1.00- 0.00- 5/22/86 12/22/87 7/23/89 2/21/91 Date A 73 One way of estimating the requirements for oxygen in a body of water is to study the pattern of oxygen uptake in the water itself using various oxygen measurements along with COD and BOD over time. Several conditions combine together to determine oxygen requirement: First, oxygen is more soluble in cold water than in warm water, and in clear water than in water with high levels of suspended sediments. Second, organic matter consumes oxygen slower in cold water than in warm water. Third, decomposition of organic matter in water increases C02 content and reduces pH. Fourth, some'aquatic animals (like fish), cannot take up oxygen as fast in low pH waters withhigh Cd2 as in higK pH waters with low C02. Data from the Fajardo River show critical oxygen situations for 1973-74 (DO valley in 1974 at USGS 725; BOD peaks in 1973-74 at USGS 710). Although such problem levels fell significantly to normal fluctuations, BOD, COD and % of oxygen saturation data signals to an descending tendency in available oxygen (Table 9: parameters # 15, 16, 17 &18; Figures 23, 24, 25 & 26). Hardness and alkalinity Hardness is the amount of dissolved alkaline metals in water. "Hard" waters are waters high in such materials, particularly calcium and magnesium; these waters are present in areas of limestone or other alkaline type of soils. "Soft" waters, like those of the Fajardo River, are low in such components. Historical data from the Fajardo River show a declining tendency in hardness, though periodical peaks occur. These peaks may be due to intensive use of fertilizers, which tend to be alkaline (Table 9: parameters #19 & 20; Figures 27 & 28). Alkalinity is an estimate of the amount of negative ions (anions) dissolved in water (anions react with water to form alkaline materials). In the Fajardo basin, alkalinity as such shows a decrease, but amounts of alkaline materials: sodium (Na), calcium (Ca), magnesium (Mg), potassium (K), and sulfates (S04-2), all show increasing tendencies (Table 9: parameters #21, 22, 23, 24, 25 & 32; Figures 29, 30, 31, 32, 33 & 34). S04-2 besides its alkaline properties, is a nutrient formed by decomposition of organic matter. 74 Plot FIGURE 23: Dissolved oxygen 13- USGS 710 12- 11- 10- 9- 8- ,a E 7- 0 6- 5- 4- 3- 2 1 11/13/57 1/14/61 3/16164 5/18/67 7/18f7O 9/17f73 11118f76 1/19/80 3/2Z'83 5/2Z'86 7/23/89 9/22/92 Date p 10 t 12- USGS 725 11- 10- 9- 8- 7- 6- C\1 0 5- 4- 3- 2- 0- 9/17/73 1/19/80 5/22/86 9/22/92 Dale 75 Line Chart 10- EQB 78B 8- 6 0 6- 9 8 4 - 2- 0 09/2@/87 01/6/89 09/26/90 DO (mg/1) 0 0 VAN 0 76 Plot FIGURE 24: Percent of oxygen 150- saturation USGS 710 140- 130- 120 - 110- 0 100- 90- go- 11/13/57 J/14/61 3/16/64 5/18/67 7/18/70 9/17/73 11/18/76 1/19/80 3=3 5/22/86 7/23/89 9/22/92 Date p 10 t 150- USGS 725 140- 130- 120- An Cli 110- 0 100- go- 80- 70 9/17/73 1/19/80 5/22/86 9/22/92 Date 77 Line Chart 125 EQB 78B 100- a. 0 75- 9 V t? 8 50- 25- 0 1 09/2@/87 01/1@fflq 09[26/90 a 0 V/@ 0 78 Plot FIGURE 25: Biochemical oxygen demand USGS 710 4- 3- 2- 0 1 1 f I 1 1 11/13/57 1/14/61 3/16/64 5/18/67 7118nO 9/17n3 11118n6 1/19/80 3122183 5/22/86 7/23/89 9/22/92 Date Plot 1000- 900- 800- USGS 725 700- 600- 500- 400- 300- 200- 100- 0- 9/17/73 1/19/80 5/22/ 86 9122192 Date 79 Plot 80- FIGURE 26: Chemical oxygen demand USGS 710 70- 60- 50- 40- 0 L) 30- 20- 10- 0 11/13/57 1114/61 3/16/64 5/18/67 7118nO 9/17/73 1111.8n6 1/19/80 312;M3 5/22/86 7/23189 9/22192, Date p 10 t 110- 100- USGS 725 90- 80- 70- 60- so- 40- 30- 20- 10- 0 9/22/92 9/17/73 1/19/80 5/22/86 L Date 80 Plot Figure 27: Hardness USGS 710 60- 50- 40- 30- 20 11/13/57 1/14/61 3/16/64 5/18/67 7118nO 9117n3 11118n6 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date Hard CaC03 p 10 t 55- p 10 t 50- USGS 720 80- USGS 725 45- 70- 40- 60- 35- 50- 30- 40- 25- 30- 1 20- 20 1 54@ 9/17/73 1/19/80 5/22/86 9/22/92 6/15/59 3/16/6 4 5/18 /6 7 Date Date Hardness Hard (CaC03) P lot FIGURE 28: Noncarbonate hardness 20- USGS 710 10- 0-- 11/13/57 1/14/61 3/16/64 5/18/67 7/18/70 9/17f73 11/18/76 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date 7- Plot 6- 25- USGS 725 USGS 720 5- 20- 4- is- '2 16 cu 3- 2 10- 2- Li 0 0 -L-r@@ 9/17/73 1/19/80 5/22/86 9/22/92 6/15/59 8/16/62 10/16/65 Dale Date p I o FIGURE 29: Alkalinity 60- USGS 710 40- 0 < 30- 20- 10- 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date p I o t 130- 120- 110- USGS 725 100- 90- 80- 70- Ag 60- 50- 40- 3o- 2o- 10 9117173 1119180 5/22/86 9/22192 Date Plot FIGURE 30: Dissolved sodium 60- USGS 710 50- 40- cc Z 30- 20- 10- 11/13/57 1/14/61 3/16/64 5/18/67 7118nO 9/17f73 11118n6 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Dam 14- Plot 13- 12- 2000- USGS 725 USGS 720 11- 10- 1500- M z E :5 :6 1000- 0 8- U) 7- 500- 6- 0 5 9/17/73 1/19/80 5/22/86 9/22/92 6/15/59 8/16/62 10/16/65 Date Date 84 Plot 14- FIGURE 31: Dissolved calcium USGS 710 13- 12- 11- 10- M 9- 8- U 7- 6- 5- 4- 3 11/13/57 1/14/61 3/16/64 5/18/67 7/18no 9/17fl3 11/18fl6 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date -7 12- p 10 t 11- 25- 10- - USGS 725 USGS 9- 720 20- 8- 7- 15- Cz 6- 10- 5- 4- 5 3-1 --- r- 9/17/73 1/19/80 5/22/86 9/22/92 6/15/59 3/16/64 Date Date Ca dis Ca P 10 t FIGURE 32: Dissolved potassium USGs 710 3.5- 3.0- 2.5- CA 2.0- 1.0- 0.5 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/-89 Date P 10 t go- 80- 70- USGS 725 60- 50- 40- 30- 20- 10- 0 8 9/17/73 1/19/ 0 5/22 86 9/22/92 Date 86 Plot 9- FIGURE 33: Dissolved magnessium USGS 710 8- 7- 6- 5- 4- 3- 2- 11/13/57 1/14/61 3/16/64 5/18/67 7/18/70 9/17/73 11/18fl6 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date 7- p 10 t USGS 6.5- 6- 720 USGS 725 6.0- 5- 5.0- CY) 4- 4.5- 4.0- 3- 3.5- 3.0- 2 2.5 i - 1@111 9/17/73 1/19/80 5/22/86 9/22/92 6115/59 8/1616210/16/65 Date Date 87 p 10 FiGURE 34: Dissolved sulfate 14 13 USGs 710 12 11 10 8- 7- 0 6- 5- 4- 3- 2- 1- 0 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7123/89 Date 10 1 9 USGS 720 500- 8 USGS 725 7- 400- 5- 300- 4- 200- 3- 2- 100- 0 0 9/17/73 1/19/80 5122/86 9/22/92 6/15/59 8/16/62 10/16/65 Date Date Suliale Substances reactive to Methylene Blue Methylene Blue is a chemical dye which changes color in the presence of anions dissolved in water. So, the dye is used as an indirect method of estimating alkalinity and hardness. In the data from the Fajardo River it shows a declining tendency (Table 9: p4rameter #61; Figure 35). Chlorine and Fluoride Chlorine and fluoride are cheap, effective disinfectants added to treated waters. Their presence in natural water bodies indicates waste water discharges. Chlorine is also illegally used, in concentrated form, by fishermen to kill and capture freshwater shrimp. Chlorine showed a very high peak in the Fajardo River data foK 1973-74 4t station USGS 725 and an increase tendency at USGS 720. Fluoride has fluctuated within acceptable levels (Table 9: parameters #26 & 27; Figures 36 & 37). Anions formed from both elements also contribute to water's hardness and alkalinity. Nitrogen and phosphorus Nitrogen, ph6sphoru4 and solAe materials composed of them are the most important sources of nutrients in aquatic systems (see Table 8). What we call organic nitrogen is the sum of the amounts of nitrates (N03), nitrites (N02) and ammonia (NI-14) in water. Clean natural waters rarely contain more than a tenth of a milligram of ammonia nitrogen per liter (0.1 ppm N), while community sewages commonly contain 15-50 ppm N. Most of this ammonia rises from the hydrolysis of urea in urine, but additional ammonia is generated by decomposition of other nitrogenous materials in sewage. Sudden increases in the concentrations of ammonia found in streams indicates that sewage, barnyard wastes, or other high energy nitrogen additions are being added. Other changes commonly accompanies added nitrogen from sewage: slime growth in shallow surfaces of the stream, algal blooms, turbidity due to bacteria and colloids, fish kills, and sewage odors. Ammonia measurements are used because they afford a rough quantitative measurement of the relative concentration of sewage in the water, even at very low levels of pollutioL If dissolved oxygen is available in the water, 89 p 10 t FIGURE 35: Substances restive to 0.10- Methylene Blue USGS 710 0.09- 0.08- 0.07- 0.06- 0.05- 0.04- 0.03- 0.02- 0.01- 0.00 1/144/61 @5/1 8/67 9/17/73 1/19/80 -5/22/86 9/22/92 Date Met i p 10 t 0.10- 0.09- 0.08- USGS 725 0.07- CO 0 0.06- C 0.05- 0.04- 0.03- 0.02- 0.01- 9/17/73 1/19/80 5/22/86 9/22/92 Date MethyleneB 90 P1 Ot FIGURE 36: Dissolved Chloride go- - USGS 710 80- 7o- 60- 50- 40- 30- 20- 10- 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date p 10 t 25- 4000- 3500- USGS 725 20- USGS 3000- 720 2500- CD 15- 2000- 0 0 1500- 1000- 10- 500- - 0 5 1-T---- 9/17/73 1/19/80 5/22/86 9/22192 11/13/57 5/18/6 7 9/17/7 3 Date- Date 9-1 p 10 t FIGURE 37: Dissolved Fluoride 0.40- USCS 710 0.30- rn LL 0.20- 0.10- 0.00- 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 1.4- p 10 t 1.2- 0.5- 1.0- - USGS 725 USGS 720 0.4- 0.8- LL CD 0.3- 0.6- U- 0.2- L 0.4- 0.1- 0.2- 0,0 0. 9/17/73 1/19/80 5/22/86 9122192 6/15/59 8/16/62 10/1 6/65 Date Date Fluoride F 92 highly toxic ammonia, is eventually oxidized by some bacteria into nitrites, which are, in turn, oxidized into nitrates (which are fertilizers for aquatic plants). The presence of significant concentration of nitrites and nitrates is an indicator of older waste or pollution further up stream. It is also an indirect way of determining the presence of adequate amounts of dissolved oxygen in the water. Ammorvia, nitrife, and nitrate. can also enter water from sources other than sewage, like fertilizers and industrial wastes. Reported cases in scientific literature have revealed that nitrates in concentrations above 10 mg/I can be fatal to small infants and to the elderly. TABLE 8: Macro- and micronutrients essential for aquatic biota. Macronutrients Micronutrients carbon, hydrogen, oxygen, calcium (for algae), iron, manganese, phosphorus, sulfur, potassium, copper, zinc, molibdenum, magnessium, calcium (except for vanadium, boron, chloride, cobalt, algae) silica From the data gathdred from 1he Fajardo River, it is obvious that periodic episodes of peak levels of organic nitrogen in all its from have been happening since 19i3 and co'ntinue (Table 9: parameters #33, 34, 35, 36, 37, 38 & 39; Figures 38, 39, 40, 41, 42, 43, 44 & 45). Phosphates, which are soluble phosphorus derivatives, like nitrogenous materials, are a normal component of sewage, but inclusion of phosphates from detergents has multiplied phosphate coming from treatment plants. Intensive fertilization of farm lands with fertilizers containing high phosphorus' concentrations also raises the phosphate contents of runoff waters. High phosphate levels in water produces heavy algal blooms which disrupts the oxygen content of the water as well as the balance of the food chain. Phosphorus levels reached a high peak in 1973 at USGS 710 but have been showing a declining tendency since 1975 at USCS 725 (Table 9: parameters #40 & 41; Figures 46 & 47). 93 Plot FIGURE 38: Nitrates 1.4- USGS 710 1.3- 0.8- 0.7- 0.6- 0.5- 0.4- 0.3- 0.2- 0.1 0. C)j T 11/13/57 3/16/64 7/18/70 11/18176 3/22/83 7/23/89 Date Plot 3.5- 3.0- USGS 720 2.5- 2.0- 1.0- 0 .5- 0. cr 6/15/59 8/1616210/16/65 Date 94 Plot USGS 725 0.9- 0.8- 0.7- 0.6- CD 0.5- z 0.4- 0.3- 0.2- 0.1- 0.0- 9/17/73 1/19/80 5/22/86 9/22/92 Date Plot 0.10- 0.10.- EQB 78B z 0.09- cl@ 0 z 0.09- 0.08- 5/22/86 12/22/87 7/23/89 2/21/91 Date 95 P I o t FIGURE 39: Nitrites 0.06- - USGS 710 0.05- 0.04- ,7, 0.03- 0 z 0.02- 0.01 0.00 f 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date Plot 0.14- 0.12- USGS 725 0.10- 0.08- z 0.06- 0.04- 0.02 - LLIa 0.00 9/17/73 1/19/80 5/22/86 9/22/92 Date p 0 t FIGURE 40: Sum of nitrates and 1.1- nitrites 1.0- USGS 710 0.9- 0.8- o.7- 0 CO 0.6- 0 z c,-,j 0.5- 0 z 0.4- 0.3- 0.2- 0.1- 0. 11/13/57 3/16/64 7/18/70 111*18/76 3/22/83 7/23/89 Date p 10 t 0.8- 0.7- USGS 725 0.6- 0.5- Z+ 0.4- 8 z 0.3- 0.2- 0.1- 0.0- 9/17/73 1/19/80 5/22/86 9/22/92 Date 9 7 Plot 0.30- EQB 78B 0.25- 0.20- ,a s 0 en . 0 0.15- z as S z 0.10- 4,*"*\ 0.05- 1 1 1 1 - 0.00 1 1 1 v I I I 5/2Z'86 IZ=7 7/23/89 2/21/91 D= 0 a 98 p 10 t 5- FIGURE 42: Ammonia USGS 710 4- 3- z 2- p r P. P1 40 d"T". ll-/13/57 3/16/64 //18/70 11/18/76 3@/22/83 7/23/89 Date p 10 t 6- 5- 4- USGS 725 .E 0 3- E E 2- 0 L F 9/17/73 1/19/80 5/22/86 9/22/92 Date 99 Plot 2- FIGURE 43: Total organic nitrogen USGS 710 0 z 0 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date 10C Plot 1-000- Total kiel N EQB 78B 0.900- 0.800- 0.700- 0.600- E 0.500- 0 0.400- 0.300- Olm- 0.100- 0.000 5/22/86 12/=7 7/23/89 Zf21/91 Date Plot 5- Tot org Nitrogen USGS 725 4- 3- c CD cm 0 0 9/17/73 1/19/80 5/22/86 9122/92 Date 101 p 10 t FIGURE 44: Total nitrogen 7- USGS 710 6- 5- 4- z 3- 2- 4 ICA 0 1 9/17/73 11/18/76 1/19/80 3/22/83 5/2@/86 7/23/89 9/22/92 Date N tot p 10 t 9- 8- 7- USGS 725 6- c 5- (D 0) 0 4- 3- 2 9/17/73 1/19/80 5/22/86 9/22/92 Date Nitrogen 102 p I o t 7- FIGJRE 4:@-. Sum of total nitrogen, ammonia and organic nitrogen 6- USGS 710 5- '6 4- E? 0 z 3 z 2- AA 0- 1 9/17/73 11/18176 1119180 3/22/83 5122186 7123/89 9/22192 Date Plot 9- 8- 7- 6- 0 z 5- C 0 4- USGS 725 E E < 3- 2- 1 0@ 9/17/73 1/19/80 5/22/86 9/22/92 Date 103 P 10 t 2.0- FIGURE 46: Phosphorus USGS 710 B i.o- 0.5- 0.0- 9/17/73 11/18/76 1/19/80. 3/22/83 5/22/86 7/23/89 9/22/92 Date 104 plot 0.400- 0.350- EQB 78B 0.300- 0.250- 0.2m - 90.150- 0.100- 0.050- 0.000-- 5/22/86 12=7 W23/89 2121/91 Dm Plot 1.6- 1.4- USGS '725 1.2- 0 -C CL 0.6- 0.4- 0.2- 0.0-- 9/17/73 1/19/80 5f22/86 9/22/92 Date 1 OS FIGURE 47: Phosphates Plot 0.10- 0.09- USGS 710 0.08- o.o7- 0.06- 0.05- 0.04- 0.03- 0.02- 0.01- 0.00 1 1 1 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date 106 Phenolic substances Phenols are by-products of organic matter in decomposition. Thus, phenolic levels are used mostly as an indication of sewage and wastewater pollution. In the Fajardo River, phenolics peaked in 1986 at USGS 710, perhaps reflecting wastewater influx from a nearby landfill (Table 9: parameter #60; Figure 48). The carbon system and pH Carbon dioxide (CO2) is the most important material in a body of water, besides water itself. It is picked up from the atmosphere, from the soil, from decomposition of organic matter, and from the respiration of aquatic organisms. In water, C02 produces carbonic acid (H2CO3), bicarbonate (HCOY), carbonate (C03-2), and hydrogen ions (H+) turning the water slightly acidic, and increasing the water's ability to carry alkaline compounds. Waters that flow through soils that cor@tain no al;aline materials will remain acidic and will be slightly corrosive. Such waters are low in mineral content and are called "soft". Aquatic plant life depends upon C02 and HC03 to survive, using it (in the presence of sunlight) in photosynthesis (Renn, 1968). They excrete oxygen. In the absence of sufficient sunlight, the process reverses, and plants consume oxygen to produce C02. Aquatic animals always consume oxygen to produce C02-. The pH me`asurem@nt estim;tes the relative concentrations of hydrogen (H+) and hydroxyl (OH-) ions in water; the proportions of acids and bases. To a large extent, pH in water bodies is determined by those chemical processes of the carbon system. As plants remove C02 from the water, the oxygen content, pH, and alkalinity increases. Plants will also take from the water dissolved salts, minerals, and metals. Data from the Fajardo River shows a decreasing tendency of bicarbonate at USGS 725 and of organic carbon at both USGS 725 &710. However, it shows an increasing tendency for bicarbonate at USGS 720 (Table 9: parameters #28, 29, 30, 31; Figures 49, 50, 51 & 52). This may be due to localized discharges of organic matter at stations USGS 710 and 725 that do not reach station USGS 720. 107/ p 10 50- FIGURE 48: Phenolic substances - USGS 710 40- 30 B -6 C (D LL 20- 10 0- 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Pate Fenol tot p 10 t 10- 9- 8- 7- USGS 725 In 0 C 6- CL 5- 4- 3- 2- 9/1 7/73 1/19/80 5/22/86 9/22/92 Date Phenols 108 p 10 t FIGURE 49: Bicarbonates USGS 710 70- 60- 50- 40- 30- 20 1 11/13/57 3/16/64 7/18170 1.1/18/76 .3/22/83 7/23/89 Date 65- p 10 t 6 0 - USGS 720 150- 55- 140- 130- USGS 725 50- 120- 110- 45- 100- 40- 90- 80- 35- 70- 60- 30- 50- 25- 40- 30-1 20 9/17/73 1/19/80 5/22/86 9/22/92 11/13/57 3/16/64 7/18/70 Date Date HCO3 109 FIGUIZE 50: Carlbonates p I o t 5- 4- USGS 710 3- 2- 0 1 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date p 10 t FIGURE 51: Carbon dioxide 40- USGS 710 30- 20- 10- 0 11/13/57 3/16/64 7/18/70 11/18/76 3/22/83 7/23/89 Date 002 p 10 t 250- 2oo- 150- USGS 725 100- 50- 0 9/17/73 1/19/80 5/22/86 9/22/92 4-@ Date C02 P I o t FIGURE 52: Organic carbon 25- USGS 710 2o- 15- LM 0 10- 5- 0- 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date Plot 200- USGS 725 150- C 0 -2 loo- 50- L 0 ___T__I I I I I I I -I 9/17/73 1/19/80 5/22/86 9/22/92 Dale 112 Plot 9.5- FIGURE 53: Hydrogen potential (pH) 9.0- - USGS 710 8.5- 8.0- 7.5- 7.0- 6.5- 6.0 11/13/57 1/14/61 3/16/64 5/18/67 7118nO. 9/17/73 1108M V19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date pH 010t 8.0- USGS 720 7.5- 7.0- 6.5- 6.0- 5.5 11/13/57 5/18/67 9/17/73 Date p I o t 8.0- USGS 725 7.5- 7.0- 6.5- 6.0- 5.5 9/17/73 1/19/80 5/22/86 9/22/92 Date Line Chart 10- EQB 78B 8- 6- 4- 2- 0- 09/24/87 01/19/89 09/20190 114 pH peaked in 1973 at USGS 710, while showing valleys for the same period at USGS 720 & 725 (Table 9: parameter #6; Figure 53). It may be due to influx of organic matter at st. 720 which reached st. 725. Station EQB 78B shows more recent high fluctuations. Metals, silica and toxic substances Metals, silica (which are micronutrients) and toxic substances like cyanide, can come from soils, metallic pipes in contact or near the river, wastewater, landfills or solid wastes thrown directly onto the river. Silica, another micronutrient, comes mostly from the soil. Data from the Fajardo River shows an increase tendency in silica, decreasing tendencies of copper, chromium and cobalt and siable fluctuations for the other components (Table 9: parameters #13, 44, 45, 4@, 47, 48 , 44, 50 , 51, 52 53, 54, 55, 56, 57, 58 & 59; Figures 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69 & 70). Amounts of toxic substances have been low. Pesticides Samples for pesticides are taken once a year from station USGS 710. It has never found significant traces of pesticides. However, since EQB has established that pesticides is one of the most important types of NPSP at the Fajardo River, it is possible that USGS sampling methods are inadequate for this group of parameters. TABLE 9: Summarized analysis of historical water quality data gathered at monitoring stations USGS 710, USGS 720, USGS 725, and EQB 78B (1958-1992). Parameter Station H L Comments 1. InstantaneousUSGS 710 Fluctuations: 10-200. Peaks: 1961, 1975, 1979, Discharge 1980,1982,1990. YO / s) USGS 720 Fluctuations: 10-100. Peaks: 1961, 1962, 1963. USGS 725 Fluctuations: 10-180. Peaks: 1973,1975,1990. 2. Total VolurneUSGS 710 Fluctuations: 10,000-35,000. Peaks: 1968, 1969, (ft3) 1986. USGS 720 Fluctuations: 15,000-30,000. Peak: 1962. ------------------------------------------------------------------------------------------------------------ Parameter Station H L Comments 3. TemperatureUSGS 710 32.2 (00 USGS 720 32.2 USGS 725 32!2 huctuations: 24-33. Peaks: 1974, 1975, 1977, 1981. EQB 78B 32.2 Fluctuations: 25-33. Peak; 1988. 4. Conductance USGS 710 Fluctuations: 75-150. Valleys: 1962, 1972, 1980, 1981, (gs/cm) 1985. Peaks: 1973, 1980, 1984. USGS 720 Fluctuations around 100. Very high peak in 1973. USGS 725 Fluctuations: 100-500. Very high peaks in 1973- 1974. 5. Salinity EQB 78B Fluctuations: 25-40. Very low valley in 1988. (ppt) 6. pH USGS 710 9.0 6.0 Fluctuations: 7.0-8.0 from 1961-1971 and (standard units) afterwards from 6.0-9.0. Peak: 1973. USGS 720 9.0 6.0 Fluctuations: 6.0-8.0. Valley: 1973. USGS 725 9.0 6.0 Fluctuations: 6.0-8.0. Valley: 1973. EQB 78B 8.5 7.3 Fluctuations: 7.3-8.5. Peak: 1987. Valley: 1989. 7. Color USGS 710 Fluctuations: 2-7. Peaks in 1967; valley in 1966. (standard units)USGS 725 Fluctuations: 3-15. Peaks: 1962, 1966, Valleys: 1965,1966. EQB 78B Fluctuations: 0-5. Peaks: 1987, 1989, 1990. 8. Turbidity USGS 710 50 Fluctuations: 0-20. Peaks: 1977,1978,1980,1981, (NTU) 1989,1990. USGS 725 50 Fluctuations: 0-10. Peaks: 1979, 1981, 1985 (very high), 1986, 1990. EQB 78B 10 Fluctuations: 0-20. Peaks: 1986, 1987, 1988-1989. 9.Suspended USGS 710 Fluctuations: 0-600. Peaks: 1962, 1974, 1977, Sediments 1980. (mg/D USGS 725 Fluctuations: 0-600. Peaks: 1974, 1975. 10. Dissolved USGS 710 fluctuations: 0-25. Peaks: 1977, 1978, 1979. Solids Decrease tendency. (tons/day) USGS 725 Fluctuations: 0-25. Peaks: 1979, 1986. Decrease tendency. 11. Total Sum USGS 710 500 Fluctuations: 40-100. Peaks in 1964 and 1979 Diss. Solids were within acceptable levels. (nig/1) USGS 720 500 Fluctuations: 40-100. Peaks in 1962 and 1963 were within acceptable levels. USGS 725 500 Fluctuations: 60-130. Peak in 1983 was within acceptable levels. ------------------------------------------------------------------------------------------------------------ Para eter Station H L Comments 12. Residue of USGS 710 Fluctuations between 1963 and 1979 were 50-120. Susp.Solids From 1980 on, fluctuations are 0-50. Peaks: 1977, (Mg/1) 1979,1981, 1989. Increase tendency. USGS 720 Fluctuations: 60-95. Peak in 1966. Increase tendency. USGS 725 Fluctuations: 0-50. Peaks: 1980, 1982, 1986. EQB 78B Fluctuations: 10-80. Peaks: 1987, 1988. 13. Silica, diss USGS 710 Fluctuations: 10-30. (mg/1) USGS 720 Muctuations: 16-27. Peak in 1962. USGS 725 Fluctuations: 12-26. Increase tendency. 14. Oil/grease EQB 78B Fluctuations 0-3. Peaks: 1988, 1989-1990. (Mg/1) 15. Dissolved USGS 71.0 5.0 Fluctuations: 7.0-11.0. Very low valley in 1974. Oxygen USGS 725 5.0 Fluctuations: 6.0-11.0. Valleys: 1973-1974, 1976. (mg/1) EQB 78B 4.0 Fluctuations: 5.0-7.0. 16. % Saturation USGS 710 Fluctuations- 90-120. Decrease tendency. Diss. OxygenUSGS 725 Fluctuations: 80-120. Decrease tendency. EQB 78B Fluctuations: 50-100. 17. BOD (mg/I)USGS 710 Fluctuations: 0-3. Peaks: 1968, 1971, 1973, 1979. Increase tendency. USGS 725 Fluctuations: 0-200. Peaks: 1973-1974, 1977. 18. COD (mg/I)USGS 710 Fluctuations: 0-30, increasing since 1983. Peaks: 1983,1987,1988,1990,1992. USGS 725 Fluctuations: 040. Peaks: 1983, 1986, 1988, 1989. 19. Hardness, USGS 710 fluctuations: 0-5. Peaks: 1962,1966,1967,1980. Total (mg/1) Decrease tendency. USGS 720 Fluctuations: 04. Peaks in 1966. USGS 725 Fluctuations: 0-7. Peaks: 1981, 1984, 1985. Decrease tendency. 20. Hardness, USGS 710 Fluctuations: 15-45. Peaks: 1962, 1966, 1972, Noncarbonate 1980. (mg/1) USGS 720 Fluctuations: 15-45. Peak in 1966. Increase tendency USGS 725 Fluctuations: 35-60. Peak in 1984. Valleys: 1978, 1979. 21. Alkalinity USGS 710 Fluctuations: 10-50. Peaks: 1973,1991. (mg/1) USGS 725 Fluctuations: 10-70. Peaks: 1973, 1974. Decrease tendency. 22. Sodium, dissUSGS 710 Fluctuations: 5-15. Peaks: 1974,1980. (mg/1) USGS 720 Fluctuations: 5-14. USGS 725 Fluctuations; 0-50. Very high peaks in 1974. 117 Parameter --Station H L Comments 23. Calcium, USGS 710 Fluctuations: 4-10. Peaks: 1968, 1970. diss (mg/1) USGS 725 Fluctuation: 5-9. Peak in 1966. Increase tendency. USGS 720 Fluctuations: 5-15. Peak in 1984. 24. Potassium, USGS 710 Fluctuations: 0.5-2.0. Peaks: 1974, 1980, 1989- diss (mg/1) 1990, 1991. Increase tendency. USGS 725 Fluctuations: 0-5.0. High peaks: 1973-1975, 1978. 25. MagnessiumUSGS 710 Fluctuations: 1.5-5-5. Peaks: 1962, 1967, 1980. diss (mg/1) USGS 720 Fluctuations: 13-6.0. Peaks: 1963, 1967. USGS 725 Fluctuations: 3.0-5.0. Peaks: 1984, 1985, 1990. 26. Chloride, USGS 710 250 Fluctuations: 5-15. Peaks within acceptable diss (Mg/1) 0 fevels: 1962, 1974, 1976, 1978, 1979. USGS 720 250 nuctuations: 5-15. Peak in 1962 within acceptable levels. Increase tendency. USGS 725 250 Fluctuations: 0-100. Very high peaks in 1973- 1974. 27. Fluoride, USGS 710 0.7 Fluctuations: 0-0.3. Peak in 1973 within diss (mg/1) acceptable levels. USGS 720 0.7 Fluctuations: 0-0.4. Peak in 1962. USGS 725 0.7 Fluctuations: 0-0.3. Peak in 1973 within acceptable levels. 28. Bicarbonate,USGS 710 Fluctuations: 20-60. Peak in 1973. diss (mg/1) USGS 720 Fluctuations: 20-60. Peaks: 1966,1973. Increase tendency. USGS 725 Fluctuations: 30-80. Peaks; 1973, 1974. Decrease tendency. 29. Carbonate, USGS 710 Around 0, except in 1971, 1974, 1978. diss (mg/1) 30. Carbon USGS 710 Fluctuations: 0-10. Peaks: 1973,1980,1981. dioxide, diss USGS 725 Fluctuations: 0-40. Peaks: 1973, 1977. (mg/1) a 31. Carbon, USGS 710 Fluctuations: 0-15. Peaks: 1975, 1977. Decrease organic total tendency. (Mg/1) USGS 725 Fluctuations: 0-25. Peaks: 1973, 1975, 1976, 1977. Decrease tendency. 32. Sulfate, USGS 710 250 Fluctuations: 0-10. Peaks (1973, 1974) are diss (mg/1) within acceptable levels. Increase tendency. USGS 720 250 Fluctuations: 0-10. USGS 725 250 Fluctuations: 0-10. Peaks: 1973-1974. ------------------------------------------------------------------------------------------------------------ 118 Parameter Station H L Comments 33. Nitrate, USGS 710 Fluctuations of 0-1.0 between 1962 and 1967, of total (mg/1) 0-1.5 in 1968-1973, and of 0-0.5 in 1974 on. USGS 720 Fluctuations: 0-1.5. Peaks: 1960, 1961. USGS 725 Fluctuations: 0-0.5. Peaks: 1981, 1990. EQB 78B A single peak in 1990 (0.1-0). 34. Nitrite, USGS 710 Fluctuations: 0-0.3. Peaks: 1976,1980. total (mg/1) USGS 725 Fluctuations: 0-0.8. Peak in 1980. 35. N03 + N02,USGS 710 relative* Fluctuations: 0-0.4. Peaks: 1981, 1985. total (mg/1) USGS 725 relative* Fluctuations: 0-0.5. Peak in 1981. EQB 78B Fluctuations: 0-0.2. Peaks: 1988,1989. 36. Ammonia, USGS 710 1.0** Fluctuations: 0-0.3. Peak in 1974. total (mg/1) USGS 725 1.0** Fluctuations: 0-1.0. Peaks: 1973, 1978, 1982. 37. Nitrogen, USGS 710 Fluctuations: 1.0-2.0. organic, total USGS 725 Fluctuations: 1.0-2.0. Peaks 1973, 1974, 1975, (Mg/1) 1976. 38. Nitrogen USGS 710 Fluctuations: 0-2. Peaks in 1973. (NO3), total USGS 725 Fluctuations: 0-2. Peaks: 1973, 1974, 1975, 1976. (Mg/1) 39. Amonnia + USGS 710 Fluctuations: 0-2. Peak in 1973. Norg + N USGS 725 Fluctuations: 0-2. Peaks: 1973, 1974, 1975, 1976. (mg/1) EQB 78B Fluctuations: 0-1. 40. Phosphorus,USGS 710 1 Fluctuations: 0-1. Significant peak in 1973. total (mg/1) USGS 725 1 Fluctuations over 1.0 in 1973, 1974, 1975 & 1976. Descending tendency since. EQB 78B Fluctuations: 0-0.4. Peak in 1987. 41. Phosphate,USGS 710 Fluctuations: 0-0.1. total (mg/1) 42. Fecal Coli- USGS 710 2,000... Fluctuations: 0-10,000. Very high peaks: 1973, forms (colonies/ 1974, 1978, 1980, 1981, 1989, 1991. Decrease 100 n-d) tendency. USGS 725 2,000"-- From an extremely high count of near 20,000,000 in 1973, situation has normalized since 1983. EQB 785 2,000' From a very high count in 1973, situation normalized. 43. Fecal Strep-USGS 710 Fluctuation: 0-10,000. High peaks in 1973, 1978, tococci (colonies/ 1980,1981,1982,1988,1989. 100 n-fl) USGS 725 Fluctuations: 0-10,000. Peaks: 1973, 1974, 1975, 1976,1978. ------------------------------------------------------------------------------------------------------------ 9 Parameter Station H L Comments 44. Iron, total USGS 710 Fluctuations: 0-250. Peaks: 1978, 1980, 1990. (pg/1) USGS 725 Fluctuations: 0-2,000. Peaks: 1979, 1986. EQB 78B Fluctuations: 0-500. Peaks: 1987, 1988. 45. Iron, diss USGS 720 Values at 0, except peak in 1970. (Mg/1) 46. Copper, USGS 710 relative* Fluctuations: 0-10. Peaks: 1977, 1981, 1987, 1990. total (4g/1) USGS 7215 relative* huctuations: 0-25 after 1980. Peaks: 1975, 1976, 1977. Decrease tendency. EQB 78B 50 Fluctuations: 0-10. Peak in 1987 within acceptable levels. 47. Arsenic, USGS 710 50 Peaks in 1974, 1983 within acceptable levels. total (pg/1) USGS 725 50 Peaks in 1974, 1983 within acceptable levels. 48. Barium, USGS 710 1,000 Fluctuations between 0-100. total (gg/1) 49. Boron, USGS 710 1,000 Fluctuations between 10-30. total (gg/1) USGS 725 1,000 Fluctuations between 10-50. EQB 78B 4,800 Fluctuations between 2,000-4,500. Peak in 1987. 50. Cadn-dun, USGS 710 relative* Fluctuations between 0-5. Peaks in 1978,1980. total (gg/1) USGS 725 relative* Fluctuations between 0-3. Peaks in 1973,1982. EQB 78B 5 Fluctuations: 0-5. Decrease tendency. 51. Chromium, USGS 710 50 Fluctuations: 0-20. Peak in 1980 within total, (gg/1) acceptable levels. Decrease tendency. USGS 725 50 Fluctuations: 0-20. Peak in 1975 within 5cceptable levels. Decrease tendency. EQB 78B 300 Values at 0, except peak in 1987 within acceptable levels. 52. Lead, total USGS 710 relative* Fluctuations: 0-20. Peaks: 1978, 1981, 1989. (jig/P USGS 725 relative* Fluctuations: 0-10. Peaks: 1974, 1975, 1976, 1977. EQB 78B 15 Values at 0 except peak in 1986. 53. Manganese,USGS 710 50 Fluctuations: 0-50. Peaks: 1974, 1975,1977,1979, total (gg/1) 1981,1987,1989. USGS 725 50 Fluctuations over acceptable levels: 0-250. High peaks in 1975, 1976, 1977. EQB 78B 100 Fluctuations: 0-100. Peaks: 1986,1987, 54. Cyanide, USGS 710 0.02 Values at 0, except high peak in 1978. total (mg/1) 55. Cobalt, USGS 710 Fluctuations: 0-2. Peaks: 1978, 1980. total (gg/1) a 9 ------------------------------------------------------------------------------------------------------------ 120 Parameter Station H L Comments 56. Mercury, USGS 725 1 Fluctuations: 0-0.5. Peaks: 1979, 1986. total (gg/1) 57. Nickel, USGS 710 relative* Fluctuations: 04. Peaks: 1974, 1980. total (gg/1) USGS 725 relative* Fluctuations: 0-25. 58. Selenium, USGS 725 10 Fluctuations: 0-1. Peak in 1976 within total (4g/1) acceptable levels. 59. Zinc, total USGS 710 50 Fluctuations: 0-50. Peaks: 1980, 1988. (Jig/1) USGS 725 50 Fluctuations after 1980: 0-50. Peaks: 1973-1974, 1975,1976,1977,1978,1979. Decrease tendency. EQB 78B 50 Fluctuations over acceptable levels: 0-100. High peaks 1986, 1987. 60. Phenols, USGS 710 Fluctuations: 0-10, except peak in 1986. total (gg/1) W 61. Methylene USGS 710 0.1 Fluctuations: 0-0.05 except peak in 1989 within Blue Active acceptable levels. Substance, USGS 725 0.1 Fluctuations: 0-0.4 except peak in 1986 within total (4g/1) acceptable levels. ------------------------------------------------------------------------------------------------------------ H and L refer to the highest and lowest limits allowed by EQB. Limit values depends on values for hardness obtained from the same sample. Ammonia levels are restricted in specific water bodies which do not include the Fajardo River. Fecal bacteria levels are calculated as the geometric mean in a series of samples taken sequentially. Field sampling at the Fajardo River For the purpose of confirming historical data, this projects personnel, established two water sampling stations at the river and two additional stations at the coast, just outside the river mouth (See Table 10; Figures 71 & 72). Samples were taken three times in- 1992-1993. Results are summarized in Table 11. Laboratory analyses results of our field water samples were consistent with recent water quality data from USGS monitoring stations. They show that, during sampling periods, levels of pollutants were relatively low. 12 2 P I o t FIGURE 54: Silicates 30- USGS 710 25- CO 2o- 0 15- to- 11/13/57 3/16/64 7/18/70 11/18/76 3122/83 7/23/89 Date Si02 dis P I 30- USGS Plot 28- 720 26- USGS 725 26- 24- 22- 24- 0 Cd 20- U) 22- .C.) 18- 20- 16- 18- 14- 12 16- 1 - Ll 9/17/73 1/19/80 5/22/86 9/22/92 6/15/5 9 8/16/62 10/16/65 Date Date Silica Si02 122 P I o t FIGURE 55: Total iron 40000- - USGS 710 30000- 16 20000- CD LL - 10000- 0- 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date Plot 16000- 14000- 12000- USGS 725 10000- -6 8000- c 6000- 4000- 2000- 0 9/17/73 1/19/80 5/22/86 9/22/92 Date 123 a 0 Plot 4000- 3500- 3000- EQB 78B 2500- 1 2000- 92 9 1500- 1000- 0 0 500- 0 1 1 1 1 1 -- - - 1 8/6/85 5/22/86 3/7/87 12/22/87 10/6/88 7/23/89 Date a a 124 a 0 FIGuRE 56: Dissolved iron p 10 t 80- 70- USGs 710 60- 50- 0 0 "D 40- W 6 U - 30- 20- 10- 0 - 11/13/57 5/18/6 7 9/1 7/73 Date 0 0 12 P 10 t go- USGS 710 FIGURE 57: Total copper 80- 70 60- 50- B 40- 3o- 20- 10- 0 9/17/73 11/18/76 1/19/80 3/22/83 5/22/86 -7/23/89 9/22/92- Date 126 Plot EQB 78B 5- 0 8/6/85 5/22/86 3n187 12/22/87 10/6/88 7/23/89 Date p 10 t 250- 200- USGS 725 150- 100 50- 9/17/73 1/19/80 5/22186 9122192 p 10 t FIGURE 58: Total arssenic 6- USGS 710 5- 4- B 3- 2- 9/17/73 11/18/76 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date As tot p 10 t 5- 4- - USGS 725 3- 0- 9/17/73 1/19/80 5/22/86 9/22/92 Date Arsenic 128 FIGURE 59: Total barium Plot 100- go- 80- USGS 710 70- 60- 50- 40- 30- 20- 10- 0 9/17/73 11/18/76 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date 129 p I o t FIGURE 60: Total boron 30- USGS 710 25- Z 20- 15- 10- 9/17/73 11/18/76 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 Date Plot 50- 45- 40- USGS 725 35- c 9 30- 0 m 25- 20- 15- 10 9/17/73 1/19/80 5/22/86 9/22/92 Date 130 0 Plot 5000- EQB 78B 4500- 4000- c % 3500- CQ 9 3000- 2500- a a f -2000 i -. I I I I 1 1 8/6/85 5/22/86 3/7/87 12/22/87 10/6/88 7/23/89 Date a 0 p I O't FIGURE 61: OTotalcadmium 131 25- USGS 710 20- 15- 10- 5- 0- 9/17/73 11/1 t76 3/22183 5122/86 7/23/89 9/22/92 Date Plot 20- is- USGS 725 E E 10- 5- 0 T I f I 9/17/73 1/19/80 5/22186 9122/92 Date 'L 32 p I Ot 9 0 5- EQB 78B 1 4- 3- =L a 9 2- 1 - 0 0 0- 1- I - - I - - 1 8/6/85 5/22/86 3f7/87 12=7 10/6/88 7/23/89 - Date 0 0 133 Plot FIGURE 6;,. Total chromium 40- USGS 710 35- 30- 25- 36 20- 15- 10- 5- 0 9/17/73 11/18/76 1/19/80 3/22/83 5/22/86 7/23/89 9/22/92 r Date - - 134 10 t FIGURE 63: Total lead 120- 110- 100- USGS 710 go- 80- 70- *6 .z 60- (L 50- 40- 30- 20- 10- 0- 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date 135 p 10 t 50- USGS 725 40- 3o- 20- to- 0 9/17/73 1/19/80 5/22/86 9/22/92 Date Plot 15- EQB 78B 10- =L 0 5- 0- 5/22/86 12/22/87 7/23/89 2/21/91 Date 136 p 10 t 700- FIGURE 64: Total manganese - USGS 710 600- 500- 400- 16 c 300- 200- 100- 0- A/\ 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date Mn tot 137 Plot 700.00- EQB 78B 600.00- 500.00- 400.00- 9300.00- 200.00- 100.00- 0.00- 1 5/22/86 1=@87 7/23/89 2/21/91 Date Plot 3500- USGS 725 3000- 2500- ton 2000- cu m C: 1500- 1000- 500- 0 9/17/73 1/19/80 5/22/86 9/22/92 Date 138 FIGURE 65: Total cianide p 10 t 0.10 0.09- USGS 710 0.08- 0.07 0.06- z 0 0.05- 0.04- 0.03- 0.02- 0.01 -T - - I - I I I - - T-- - 1 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date 139 FIGURE 66: Total cobalt p 10 t 18- 16- USGS 710 14- 12- 10- 8- 6- 4- 2- 0-1 1/14161 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date 140 FIGURE 67: Total mercury p 10 t 4.5- 4.0- 3.5- 3.0- USGS 710 2.5- 2 CD 2.0- 1.0- 0.5- 0.0+ 9/17/73 1/19/80 5/22/86 9/22/92 Date Mercury 141 p 10 t FIGURE 68: Total nickel 14- 13- usGS 710 12- 11- 10- 9- 8- B 7- z 6- 5- 4- 3- 2- 1- 0 r I 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date Ni lot p 10 t 25- USGS 725 20- 15- z 10- 5- 0 9/17/73 1/19/80 5/22/86 9/22/92 Date Nickel 142 FIWRE 69: Selenium p 10 t 2.0- USGS 710 E :3 2 1.0- p 2 M U) 0.5- 0.0 9/17/73 1/19/80 5/22/86 9/22/92 Date 14 3) p 10 t FIGURE 70: Total zinc 400- 300 USGS 710 200- 100- 0 1/14/61 5/18/67 9/17/73 1/19/80 5/22/86 9/22/92 Date p 10 t 200- 150- USGS 725 S 100- N 50- 0 9/17/73 1/19/80 5/22/86 9/22/92 Date 144 Plot 600- I h 500- 1.II EQB 78B 400- I i I i 300- 4 11. 9 200- 100- 1 1\ I 0- 1 1 1 1 5/22/86 12/2@M 7/23/89 2/21/91 Date - I - A. a 0 14 5 FIGURE 71: Sampling stations established for this project (indicated by stars) SARDINERA PLAYA SARDINERA PTA-BATERIA BAHIA BELTRAN DE FAJARDO R PLAYA DE FAJARDO PUERTO* NOR REAL PTA FAJARDO PUEBLO, *#3 RIO FAJARDO -tt #4 ESTE A -N- SANTA RITA EST VERTEDERO ESCALA APROXIMADA I 2qOOO 1KM MAPA ESTACIONES DE MUE-STREC) DPN 146 FIGURE 72: Upstream station established for this project (as indicated by a star). CARR. ESTAGION DE VERTEDERO ESGUELA PERON RIO ARRIBA RIO ARRIBA PARAISO v Fajardo River RIO ABAJO FAJARDO CARR 971 ESCALA APROXIMADA 1: 20, 000 47[1 1 KM At -N- MAPA ESTACIONES DE MUESTREO DRN 147 TABLE 10: Water quality field stations established by this project at the Fajardo River system. Station Location --Type of site 1. HWY 971,3km upriver freshwater, river from USGS 710. 2. Bridge at HWY 194, estuarine, river 0.5 km downriver from USGS 725. 3. Coast, 200m off coastal estuarine rivermouth. 4. Coast, 200 m south of coastal estuarine StItion #3. 0 - ------------------ -------------------------------- TABLE 11: Water quality data from this project's field samples*. Station 1: 0 0 Parameter D;c. 17,1992 Mar. 24,1993 Jul. 14. 1993 NH3 Mg/l NA 0.06 0.03 N02 n-g/l 0.001 0.001 0.002 N03 mg/l 0.43 0.19 0.262 P total mg/l 0.02 0.02 0.02 P04 Mg/l 0.01 0.01 0.01 Susp. Solids mg/l 1.6 7.1 9.3 Hardness mg/l 20 29 30 Fecal coliforms (colonies/100 n-d) NA 210 Fecal streptococci (colonies/ 100 ml) NA 220 Lead gg/l 5 Copper 4g/l 1 Zinc gg/I 12.5 Cadmium lig/l 0.5 Manganese pg/l 1 Iron gg/l 1 Cobalt lig/l 1 Nickel gg/l 1.5 Chron-dum 4g/l 1 1 ---------------------------------------------- ------------------------------------------------------------- 146 Station 2: Parametel Dec. 17.1992 Mar, 24,1993 Jul, 14.1993 NH3 mg/l NA 0.03 0.03 N02 mg/l 0.001 0.001 0.006 N03 mg/l 0.188 0.592 0.241 P total mg/l 0.01 0.02 0.01 P04 mo 0.01 0.01 0.01 Susp. Solids mg/I 2.3p 0 Hardness mg/l 45 42 38 Fecal coliforms (colonies/100 n-d) NA 200 Fecal streptococci (colonies/100 n-d) NA 110 Lead gg/l 5 Copper gg/l 1 Zinc gg/l 12.5 Cadmium 4g/I o.5 Manganese pg/l 35 Iron jig/l 1 Cobalt gg/l 1 Nickel gg/l 1.5 Chromium lig/l 1 Station 3: Parameter Dec. 10, 1992 ME jr. 23, 1993 Jul. 2, 199a NH3 mg/l NA 0.06 N02 mg/l 0.001 0.001 0.006 N03 mg/l NA 0.020 0.226 P total mg1l 0.03 0.03 0.029 P04 Mg/l - 0.01 0.01 0.01 Susp. Solids mg/l 58 85.8 Hardness mg/l 6098 5920 Calcium mg/l 375 Magnesium mg/l 1300 Fecal coliforms (colonies/100 ml) NA 20 Fecal streptococci (colonies/100 ml) NA 1300 Lead gg/l 5 Copper jig/ 1 Zinc @tg/l 22.5 Cadmium gg/l 0.5 Manganese pg/l 90 Iron jig/l 1015 Cobalt gg/l 1 Nickel pg1l 3 Chromium gg/l 1 ------------------------------------------------------------------------------------------------------------ 149 Station 4: Parameter Dgc. 10. 1222 Max, 23,1993 Jul, 2. 1993 NH3 mg/l NA 0.18 NO@ mig/l 0.001 0.001 0.001 N03 n-CA NA 0.30 0.033 P total mg/l 0.02 0.29 P04 mg/l 0.06 0.01 0.01 Susp. Solids mg/l 43.8 96.8 Hardness mg/l 7207 6370 Calcium mg/l 399 Magnesium mg/I 1300 Fecal coliforms (colonies/100 n-d) NA 10 Fecal streptococci (colonies/100 n-d) NA 2 Lead gg/I 5 Copper @Lg/l 1 Zinc gg/l 62.5 Cadmium gg/l 1 Manganese pg/l 85 Iron lig/I 525 Cobalt gg/l 1 Nickel gg/l 2.2 Chron-dumpg/l 1 ------------------------------------------------------------------------------------------------------------ * Ammonia, nitrate, and fecal bacterial tests could not be done for the first sample. Laboratory analyses are yet to be completed for some samples. They will be added to this Table as soon as we have them. Summarized review of historical water quality data When historical water quality data from the Fajardo River is reviewed together, a pattern can be discerned: -there is some gradual increase in the level of pollutants in the river during the late sixties; then, during 1973-1975 there is an outburst of growth in most parameters. This explosion ends around 1975-1976, and then parameters' levels has very gradually been decreasing since. Maybe pollution levels were reduced as a result of a growth in forested lands and, consequently, in the water retention capability of the soil; most probably, however, graphs* reflect the effect on the basin of the implementation of point-source pollution controls beginning in the mid- seventies. However, occasional peaks continue to appear in almost all graphs, and some parameters involving oxygen requirements (% of dissolved oxygen and COD) do show a slight worsening. V. FIELD INTERVIEWS To check in the field what impact, if any, government actions have had over local activities suspected of producing non-point source pollution (NPSP), a series of interviews were done along the basin. Questionnaires were produced based on EPA's Guidance Specifying Management Measures For Sources Of Nonpoint Pollution In Cbastal Waters (1993) (see Appendix 1). Agricultural activities Four cattle farms and a pig farm were visited. Cattle farms ranged from 20 to 300 acres each. All their owners were aware in one way or another of nonpoint source pollution caused by soil erosion, wastewater, runoff, pesticides and fertilizers. Only the largest one had a holding pond for wastewater (cleaned once every five to six years), runoff ditches, vegetated. filter strips, and critical area planting. All had their lands tested for pH, but again, only the larger farm had tested for nutrient and runoff potential and planned fertilizer application using such information. None had water troughs. Their animals were taken to the river or some tributary creek to drink. All had identified surface water bodies within their farms but none took this into account when planning any of the farms' activities. Pesticides and fertilizers and @orresp6nding equIpment were supplied to them by the Department of Ag;iculture (PRDA) along with instructions on their use. Equipment maintenance was the minimum necessary to maintain them operational. Two of the farms also planted plantains on a commercial scale. Pesticides and fertilizers were used on those crops according to PRDA instructions. 15-1 The pig farm had some 20 acres and about 200 pigs in a confined facility built according to Environmental Quality Board (EQB) and PRIDA guidance. Animal wastes wer 'e washqd daily in@o a functional oxidation pond. The farm included a plantain plantation to which pesticides and fertilizer were applied according to PRDA instructions. The owner was aware of low pH and erodibility potential'of her land. 0 We tried, unsuccessfully to interview other farmers, including the owner of a crop farm planting cassava, limes, and papaya. We noticed that plantain was a favorite crop because of generous subsidies and services offered by PRDA. There was some oranges and grapefruits planted. We also noticed that stripping the land of vegetation and topsoil with machines is a common practices before planting crops or to let grasses grow for cattle. That was being done even in very steep terrains. Sugar cane still dominates agriculture in the lowlands. No commercial silviculture activity is currently under way within the Fajardo River Basin. Marinas Though the coasts of the municipalities of Fajardo and Ceiba are home to seven marinas, only one of them (Villa Marina), is within the Fajardo River Basin per se. -The ma;ina includ;s a fueling station and has a capacity for harboring as many as 870 boats (including 70 on land). Facilities were designed and built without taking into account water quality or any kind of waste or spill management. In fact, there is no water quality assessment program run by Villa Marina management (although government monitoring station EQB 78B was functioning here from 1986 to 1990). The marina has a revegetation program, but it is a beautification program, not a sediment-control one. Allegedly, the marina have implemented effective runoff control strategies, boat cleaning programs, and installed dumpstation, and restroom facilities to reduce release of sewage to surface waters. There are no sewage pumpout facilities. Solid wastes from boats are collected on docking and disposed by the municipal government. Absorbing pads are used to collect oils, greases, and fuel from su"rface waters. There are no restrictions, management or orientation regarding fish waste. There is no educational strategy regarding pollution and wastes in the marina, although occasional recordatories are offered via the marina's own monthly periodical and office memos. Management established a speed limit within the marina to reduce probabilities of boating accidents and turbidity in the water. Hydromodifications The Fajardo River is one of the very few rivers in Puerto Rico that, so far, has not been channelized or dammed. However, there is a current proposal in the hands of the*U. S. Arm@ Corps of Engineers for a flood control program in the river which includes the construction of a dike to divert water from the river directly into the mangrove forest that lies at the southern shore of the river mouth. It is hoped that the mangrove will be able to absorb this increased influx of freshwater and will act as a filtering system for pollutants as well. The project is in the stage of gathering permits and endorsements and its still collecting preliminary information for a future preparation of an Environmental Impact Statement. The river has also been mentioned by the Aqueducts and Sewers Authority as a probable site for a new dam and reservoir. Wetlands The Department of Natural Resources (DNR), administrator of Ceiba State Forest, and the Federal Forest Service (USFS), in charge of the Caribbean National Forest, administe; almost all wetlands in the basin classified as ecologically sensitive or important. USFS has adopted a program for the protection of its lands, which include asking of all projects within the Forest to submit Best Management Practices Plans. Ceiba Forest is still lacking a similar DNR program. Protection of mangroves, and other wetlands, is pursued in Puerto Rico mostly through EQB's Regulation of Environmental Impact Statements, the Environmental Public Policy Act, Planning Board's Resolution Num. 74- 21, and Section 401 of the Federal Clean Water Act. In addition, through the Coastal Zone Management Program, certain construction and waste disposal activities are restricted in wetlands of special concern within the Maritime- Terrestrial Zone. Wate disposal systems The municipal landfills of both Fajardo and Ceiba are located within the Fajardo River Basin. Until very recently, there were no government controls on the production of non-point source pollutants from these sites. As a result, neither of them had any mechanisms or plans to deal with this problem. Farmers living near the landfills reported that it was usual to see a dense, blackish muck going Zlown neargy creeks instead of water. However, since the beginning of 1993, the Commonwealth and the Municipal governments were instructed by the Federal Environmental Protection Agency that they had to comply with the new regulations under the Clean Water Act. There are plans to close one of the landfills and turn the other into a regional system, and-recyclable materials are being identified to try to reduce the load coming in. Construction and soil extraction activities Control of pollutants originating from construction and soil extraction activities is pursued mostly by requiring Control of Erosion and Sedimentation (CES) Plans at EQB and Soil Extraction Permits at DNR. CES Plans submitted to EQB during 1992 were reviewed for this project. Most of the measures they contain involves maintaining soil wet and compacted to inhibit clouds of p@rticula@es, establAing hay barriers and sedimentation ponds to capture runoff, dispositions on equipment washing and solid waste disposal, and mandating revegetation or pavimentation of open spaces remaining after completion of project. 154 VI. CONCLUSION ANEY RECOMMENDATIONS All the information collected for this report presents a river system and its basin which has been significantly impacted by non-point source pollution (NPSP), at least since the early sixties. There are, for sure, natural causes responsible for some pollutants, some of the time: sudden, heavy rains common in the area, erodibility and acidity of the soils, valleys with steep gradients, small natural deposits of metal-containing minerals, etc. However, it is obvious that human activities are responsible for most NPS pollutants. Data confirm that the Environmental Quality Board correctly assessed the possible causes of NPSP at'the river: Agricultural activities, runoff, landfills, construction activities, waste disposal, and soil extraction operations. The existing marina is an NPSP source on the coastal region of the basin. Although the situ@tion a * ears to @ave significantly improved since an pp upsurge in the early seventies, this improvement seems to reflect the imposition of point-source pollution control, more than anything else. There are some government controls on NPSP, but it is obvious that they are insufficient at the present moment. Since development pressure is growing along the basin, we can expect a future increase of pollutant production in the area, and if this is not addressed now, maybe water quality data in the late nineties will show a repetition of the crisis of the seventies. The following are our short and mid-term recommendations in respect to NPSP in the Fajardo River Basin: 1. DNR should adopt a Management Plan or Program for the Ceiba State Forest with strict guidelines and requirements for all types of development 'propos@ls. 2. There such be a concerted effort between the Federal, Commonwealth and Municip@l gover@ments to avoid further destruction of wetlands and explore the possibility of creating new ones. 3. There such be a concerted effort between the Federal, Commonwealth and Municipal governments to maintain current levels of forested lands as one way to sustain soils' water retention capability. 4. The Environmental Quality Board should reopen monitoring station EQB 78B and establish at least one additional station on the river per se. 5. Pesticides should be monitored at least four times a year, instead, of just once. 6. EQB's Best Management Practices Plans should be required to all commercial (animal or crops) farms. This plans should require an increase used of anti-erosion practices. 7. All direct wastewater discharges to the river should be closed. 8. Cattle should not be given direct access to surface waters. Drinking troughs should be mqndatory for all animal farms. 9. All construction permits should include dispositions for revegetation and mitigation of natural areas. 10. All soil extraction permits should include dispositions to revegetate abandoned extraction areas. 11. There should be concerted efforts by the Federal, Commonwealth and Municipal governments to increase public education on NPSP and public participation in NSPS programs, as well as development projects' permits evaluation process. 12. Government'@ assessm* ent of waste disposal in marinas should be done in a systematic, frequent way. Fish waste disposal should be better managed as well as current dispositions on boat fuels, oils, greases, paints and human wastes. 13. Being one of the few rivers left in Puerto Rico without hydromodifications, any such project should be considered with extreme care in respect to its impact on the river's (and estuary) hydrology, chemistry and biota, and effects on local community, particularly in terms of hidden costs of pollution, erosion, loss of farm and forest lands, etc. 6 VIL REFERENCES Ahmad, R., F. N. Scatena & A. Gupta. 1993. Morphology and sedimentation in Caribbean montane streams: Examples from Jamaica and Puerto Rico. Sediment. Geof. 85:157-169. Anonymous. 1973a. Water Resources Data For Puerto Rico, 1968. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 53. ---------------- 1973b. Water Resources Data For Puerto Rico, 1968-1972. Part 2a. Water Quality Records. USGS. San Juan, P. R. p. 253-259. ---------- - ---- 1973c. Water Resources Data For Puerto Rico, 1969. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 46. --------- - ----- 1973d. Water Resources Data For Puerto Rico, 1970. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 48. ---------------- 1973e. Water Resources Data For Puerto Rico, 1971. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 37. ---------------- 1973f. Water Resources Data For Puerto Rico, 1972. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 35. ---------------- 1975a. Water Repources Data For Puerto Rico, 1973. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 37. ---------------- 1975b. Water Resources Data For Puerto Rico, 1973. Part 2. Water Quality Records. USGS. San Juan, P. R. p. 74-75. ---------------- 1976a. Water Resources Data For Puerto Rico, 1974. Part 1. Surface Water Records. USGS. San Juan, P. R. p. 34. 157 ---------------- 1976b. Water Resources Data For Puerto Rico, 1974. Part 2. Water Quality Records. USGS. San Juan, P. R. p. 100-103. ---------------- 1977. Soil Survey of Humacao Area of Eastern Puerto Rico. USDA..San Juali, P. R. pp..105. 1978. Water Resources Data For Puerto Rico. Water Years 1973-76. USGS. San Juan, P. R. p. 206-214. ------------ - -- 1979. Geologic Map of the Fajardo and Cayo Icacos Quadrangles, Puerto.Rico. U@GS- San Jujan, P. R. ----------- 1980. Geologic Map of the Naguabo and Part of Punta Puerca Quadrangles, Puerto Rico. USGS. San Juan, P. R. 1982. Inventario de los cuerpos de agua superficiales de Puerto Rico. EQB. San Juan, P. R. 1990. Reglamento de estindares de calidad de agua de Puerto Rico. EQB. San Juan, P.- R. 105 pp. ----- - --- - ---- 1992. Goals and Progress Of Statewide Water Quality Management Planning: Puerto Rico 1990-1991. Rev. Ed. EQB- San Juan, P. R. 194 pp.. 0 ---------------- 1993. Guidance Specifying Management Measures For Sources Of Nonpoint Pollution In Coastal Waters. EPA. Washington, D. C. 909 pp. Col6n-Dieppa, E., P. L. Diaz & R. G4rcia. 1986. Water Resources Data for Puerto Rico. W@ter Year 1985. USGS. San Juan, P. R. p. 195-202. Curtis, R. E., Jr., Z. Aquino, P. L. Diaz & R. Garcia. 1987. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1986. USGS. San Juan, P. R. p. 201-210. Curtis, R. E., Jr., Z. Aquino, P. L. Diaz & R. J. Vachier. 1988. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1987. USGS. San Juan, P. R. p. 195-199. ---------------- 1989. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1988. USGS. San Juan, P. R. p. 293-297. ---------------- 1990. Water R@sources D@ta-. Puerto Rico and the U. S. Virgin Islands: Water Year 1989. USGS. San Juan, P. R. p. 223-227. 158 --------- - ----- 1991. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1990. USCS. San Juan, P. R. p. 301-304. 1992. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1991. USGS. San Juan, P. R. p. 303-307. Curtis, R. E., Jr., S. GuzmAn-Rios & P. L. Diaz. 1980a. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1977. USGS. San Juan, P. R. p. 101-104. -- - ---- -. 1980b. Water Rqsources D4ta: Puerto Rico and the Virgin Islands: Water @ear 1978. USGS. San Juan, P. R. p. 124-131. ---------------- 1981. Water Resources Data: Puerto Rico and the U. S. Virgin Islands@ Water @ears 1979-80. USGS. San Juan, P. R. p. 198-211. ------------ - -- 1982. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Years 1981-82. USGS. San Juan, P. R. p. 182-203. ---------------- 1984. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1983. USGS. San Juan, P. R. p. 124-131. ---------------- 1985. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1984. USGS. San Juan, P. R. p. 172-179. Cintr6n, B. 1993. Interagency field visit observations, Rio Fajardo, Puerto Rico. Section 205 Study. Unpublished Memorandum. US Army CoE. Jacksonville, Fla. pp. 3. Diaz, P. L. , Z. Aq@ino, C..Figueroa-41amo, R. J. Vachier & A. V. Sdnchez. 1993. Water Resources Data: Puerto Rico and the U. S. Virgin Islands: Water Year 1992. USGS. San Juan, P. R. p. 357-361. Goenaga, C., & G. Cintr6n.o 1979. Invintory of the Puerto Rican coral reefs. DNR. San Juan, P. R. pp. 190. Goenaga, C., V. Mestey, V. Vicente, J. Berrios, J. Caballero, 0. DAvila, D. Delgado, 1. Diaz, M. Rivera & V. Quevedo. 1990. Suplemento t6cnico para el Plan de Manejo de la Reserva Natural La Cordillera, Fajardo, Puerto Rico. P. M. Gonzdlez, M. T. Garcia & R. F. Martinez (Eds.). DNR. San Juan, P. R. pp. 156. Kipple, F. P. 1968. Water Records of Puerto Rico, 1958-63. USGS. San Juan, P. R. p. 165-176. i59 Lugo, A. E. 1993. Rio Marneyes and the water intake project of PRASA. Unpublished document. USDA Forest Serv. San Juan, P. R. 17 PP. Margalef, R. 1978. Diversity. In: Phytoplankton Manual. A. Sournia (Ed.). UNESCO. Paris, France. p. 251-260. Renn, C. E. 1968. A Study Of Water Quality. La Motte Chem. Prod. Co. Chestertown, Mar. pp. 46. 1969. Our Envitonment Bgttles Water Pollution. La Motte Chem. Prod. Co. Chestertown, Mar. pp. 32. Rickher, J. G. 1970. Water Records of Puerto Rico, 1964-67. Vol. 1: North and Northeast Slopes. USGS. San Juan, P. R. p. 248-261. Riley, J. P., & R. Chester. 1@71. IntrodVction to Marine Chemistry. Academic Press. &ew York, N. Y, p. 105-218. Zayas, E. 1993. Gold rush! Business booms in Puerto Rico's eastern region. Caribbean Business 21(4):1-2; 32-33. 160 APPENDIX 1: Field interviews' questionnaires. 161 AGRICULTURAL LANDS 1. Farm size: - acres (total). Estimate of acreage in active use: acres. 2. Farm use: a. Crops _. What crops? Plantains/bananas _ Sugar cane Others (explain): b. Animals Cattle Horses Pigs Others (explain): 3. Farm location: Is it adjacent to surface waterbodies? Yes No 4. Type(s) of soil in farm, if known: Has the soil been classified as highly erodible? Yes No Do not know: 5. Erosion management: a. Does activities in this farm include the following: Conservation tillage Contour strip-cropping Sediment retention pond Water control basin Terraces Sediment control basin Critical area planting Filter strip _ Field borders Grade stabilization structure Reforestation None b. Other erosion control activities (explain): 6. Confined animal facility wastewater and runoff management: a. Is wastewater/runoff routed through holding pond, treatment lagoon or other settling structure/ debris basin? Yes No b. If Yes, How frequently are fh-ese structures cleaned/maintained? c. For small facilities: Do you maintain vegetated filter strips or any other mitigation area vegetation? Yes No 7. Nutrient and Pesticide management- a. Do you use nutrients? Natural Artif icial - None b. Do you use pesticides? Natural Artificial None c. Have you evaluated soil for: pH phosphorus nitrogen potassium leaching/runoff potential? d. Do you calibrate and maintain application equipment? Yes No e. Do you determine yield expectations through yield history or soil series information? Yes No f. Do you apply nutrients and pesticides after determination of real economic benefit? Yes No g. Do you plan type of pesticide/nutrient application and timing, amount and frequency taking into account: weather stage of crop development type of crop soil type pest problem toxicity - previous pest control methods used _ persistence h. Have you identified environmental concerns (sinkholes, surface water, shallow aquifer,) highly erodible soil) in or near your farm? Yes No There are none i. It yes, Do you plan nutrient/pesticide application taking this into account? Yes-No-. 16 2 8. Grazing Management: a.To protect sensitive.areas (strpambanks, wptlands, surface waters, riparian zones), do you: Exclude livestock from these areas Alternate grazing areas within farm Provide alternate drinking location Provide stream crossings or hardened access for drinking Locate saft and shade away from sensitive areas b. Grazing is not carded out in this farm 9. Irrigation water management: a. Do you use irrigation water? Yes No b. If yes, Do you irrigate unfformly? Yes - No c. Have you prepared an irrigation schedule? Yes No d. If yes, have you taken into account the following: rainfall and temperature soil properties type of crop and its resistance to stress stage of crop development availability of water supply 16 13 URBAN RUNOFF 1. New development management: a. Type of development: b. Area covered: Total: Within the Fajardo River Basin: c. Have you designed or constructed development to be able to reduce average annual Total Suspended Solids (TSS) loadings by, at least, 80% after project completion'? Yes No d. Have you designed or constructed development to be able to reduce postdevelopment TSS loadings so that average annual loadings are no greater than predevelopment loadings? Yes No 2. Watershed protection management: Have you developed-a Watershed Protection' Program: a. To protect areas particularly susceptible to erosion? b. To protect areas that provide important water quality benefits? c. To protect areas necessary to maintain riparian/aquatic biota? d. To site development to protect natural integrity of waterbodies and natural drainage systems? e. Have not prepared Program. f. Program not necdssary 3. Site development management: Do you plan, design or develop sites to be able to: a. Protect areas that provide important water quality benefits or are susceptible to erosion b. Limit increases of impervious areas c. Limit land disturbance activities to reduce erosion d. Limit disturbances on natural drainages and vegetation 164 URBAN CONSTRUCTION ACTIVITIES 1. Site size: 2. Site location: 3. Construction site erosion and sediment control management: a. Have you prepared a plan to control erosion? Yes No b. If yes, have you taken into account: soil type(s) site grading and present or future contours topsoil preservation design for structural controls stabilization measures revegetation description of sequence of construction mitigation areas near waterbodies or drainage systems others (explain) 4. Construction she chemical control management: a. How and where do you store chemicals? b. Do you have a plan for their application? Yes No c. If yes, explain: d. How do you dispose of chemicals? e. Have you established fuel and vehicle/equipment maintenance and washing areas away from all drainage courses? Yes No f. Do you cover and isolate construction materials and chemicals to prevent runoff ? Yes No g. Have you prepare a spill r ention and control plan? Yes No h. Do you provide proper sanitary facilities for construction workers? Yes No EXISTING DEVELOPMENT MANAGEMENT a. Do you have a watershed management program to reduce runoff pollutants? Yes No b. If yes, does it include: Identif ication of priority local/regional watershed pollutant reduction opportunities A schedule for implementation of appropriate controls Limits for destruction of natural conveyance systems Preservation, enhancement or establishment of buffers along surface waterbodies c. Location of development:* d. Site size: POLLUTION PREVENTION MANAGEMENT a. Agency: b. Is there a pollution prevention and education program to reduce nonpoint source pollutants generated from the following activities: Improper storage, use, and disposal of household hazardous chemicals, including automobile fluids, pesticides, paints, solvents, etc. Application and disposal of garden care products, and improper disposal of leaves and yard trimmings. Turf management of golf courses, parks and recreational areas. Discharge of pollutants into storm drains,, including floatables, oil and litter. Commercial activitiev including 'parking lots, das stations, and other entities not under NPDES purview. Improper disposal of pet excrement. Others (explain) ONSITE DISPOSAL SYSTEMS MANAGEMENT 1. New onsite disposal systems (OSDS) management: a. Do your agency has policies, regulations or plans to ensure that new OSDS are located, designed, installed, operated, inspected and maintained to prevent the discharge of pollutants to the ground, to ground waters and to surface waters? Yes No b. It yes, do you: Discourage the installation of garbage disposal to reduce hydraulic and nutrient loadings? Reduced total hydraulic loadings to the OSDS by 25% in new developments or redevelopments where low-volume plumbing fixtures have not been installed? Direct placement of O@DS away from' unsuitable areas including poorly or excessively drained soils, areas with shallow water tables or with high seasonal water tables, areas over fractured bedrock, floodplains, and areas where nutrient or pathogen concentrations in the effluent can not be reduced? Establish protective setbacks from surface waters, wetlands, and floodplains? Establish protective separation distahces between OSDS and groundwaters?_ Require installation of OSDS that reduce total nitrogen loadings by 50% to groundwaters, where conditions indicate that surface waters may be adversely affected by excess nitrogen loadings from groundwaters? c. System location: d. System capacity: 2. Agency: 3. Operating onsite disposal systems (OSDS) management: a. Do your agency has policies, regulations or plans to ensure that existing OSDS are operated and maintained to prevent discharge of pollutants to the ground, groundwaters or surface waters? Yes No b. If yes, do you: Discourage the reduced use of garbage disposals? Encourage the use of low-volume plumbing fixtures? Reduce total phosphorus loadings by 15%? Require an OSDS to be repaired, replaced, or modified when it fails or threaten or impairs surface waters? Inspect OSDS at a frequency adequate to ascertain whether OSDS are failing?_ Consider replacing or upgrading OSDS to treat influent so that total nitrogen loadings in the effluent are reduced by 50%, if surface waters may be adversely affected by groundwater nitrogen loading from OSDS? c. System location: d. System capacity: 6 C ROADS, HIGHWAYS AND BRIDGES 1. Agency: 2. Planning, siting, and developing roads and highways management: Do your agency plan, site and develop roadsthighways taking into account: Protection of areas that provide important water quality benefits or are susceptible to erosion? Limits to land disturbance (clearing and grading, cut and fill, etc.) to reduce erosion? Limits to disturbance of natural drainage features and vegetation? 3. Bridges management: Do your agency site, design, and maintain bridges so that sensitive and valuable aquatic ecosystems and areas providing important water quality benefits are protected from adverse effects? Yes No 4. Construction projects (roads, highways, bridges) management: Do you: Reduce erosion in construction projects? Retain sediment onsite during and after construction? Prior to land disturbance, prepare and implement an approved erosion control plan? 5. Construction site chemical control management: Do you Limit application, generation, and migration of toxic substances? Ensure proper storage and disposal of toxic materials? Apply nutrients at rates necessary to establish and maintain vegetation without causing significant nutrient runoff? 6. Operation and maintenance management: Do you incorporate pollution prevention procedures into the operation and maintenance of roads, highways and bridges to reduce pollutant loadings to surface waters? 7. Runoff systems management: a. Have you developed runoff management systems for existing roads, highways and bridges to reduce runoff pollutant concentration and volumes entering surface waters? Yes No b. If yes, have you: Identified priority and watershed pollutant reduction opportunities?_ Established schedules for implementing appropriate controls? 167 MARINAS AND RECREATIONAL BOATING 1. Marinas flushing management: a. Have you designed and site this marina such that tides or currents will aid in flushing of site or renew water regularly? Yes No 2. Water quality assessment management: a. Do you assessed water quality as part of marina siting and design? Yes No b. If yes, do you tested for: Dissolved oxygen? Pathogens? c. Do you currently run a regular water quality assessment program? Yes No d. If yes, what do you test for? 3. Shoreline stabilization management: a. Do you reforest/revegetate as a regular shoreline stabilization procedure? b. If you use other procedures, did you take into account their cost effectiveness against revegetation, prior to construction or implementation? Yes No c. What are/were those other procedures? 4. Storm water runoff management: a. Do you implement effective runoff control strategies? Yes No b. If yes, do they include the following: Use of pollution prevention activities. Proper design of hull maintenance areas to reduce annual loadings of total suspended solids by 80%? 5. Fueling station design managementi A Have you designed iOeling stations to allow for ease in spills cleanups? Yes No 6. Sewage facility management: Have you installed pumpout, dump station and restroom facilities to reduce release of sewage to surface waters? Yes No 7. Solid waste management: a. Do you propedy dispose of solid wastes from boats to limit their entry to surface waters? Yes No b. If yes, how (explain): 8. Fish waste management: a. Do you apply any kind of fish cleaning restrictions? Yes - No b. Do you implement some kind of public education regarding fish waste disposal? Yes No c. Do you implement proper disposal procedures for fish waste? Yes No d. If yes, explain which ones: 9. Petroleum control management: a. Have you implemented measures to reduce amount of fuel and oil entering surface waters? Yes No b. If yes, explain: 10. Boat cleaning management: a. Do you perform boat cleaning operations such that the release to surface waters of cleaners, solvents, and paints is minimized? Yes No b. If yes, explain how: 168 11. Public education management: a. Do you implement any public education, oLoreach or training program dealing with proper disposal of polluting maeerial? Yes No b. If yes, describe: 12. Maintenance of sewage facilities management: a. Do you have sewage pumpout facilities? Yes No b. If yes,: Do you encourage their use? Yes No Do ybu ensurethat they are Fnaintained in operational conditions? Yes No 13. Marina: 14. Marina location: 15. Marina size and capacity: BOAT OPERATION MANAGEMENT 1. Do you restrict boating activities where necessary to decrease turbidity and physical destruction of shallow-water habitat? Yes.- No 2. If facility is not a marina, identify source of information: 3. Source size/capacity and location, if apply: 169 CHANNELIZATION AND CHANNEL MODIFICATION 1. Physical and chemical characteristics of surface waters management: a. Has there been an evaluation of chemical and physical charactedstics of surface waters previous to construction? Yes No b. Have you evaluated the potential effects of proposed channel modif ication on the chemical and physical charactedstics of surface waters? Yes No c. Have you planned and designed channel modification to reduce negative impact? Yes No d. Do you have an operation/maintenance program for existing modified channels? Yes No e. If yes, does it includes measures to improve chemical and physical characteristics of surface waters? Yes No 2. Instream and riparian habitat restoration management: a. Has there been an.evaluation of instream and riparian habitats previous to construction? Yes No b. Have you evaluated the potential eff ects of proposed channel modif ication to instream and dparian habitats? Yes No c. Have you planned and designed channel modification to reduce negative impact? Yes No d. If you do have an operation/maintenance program for existing modif ied channels, does it includes measures to restore instream and hpadan habitats in those channels? Yes No ERODING STREAMBANKS AND SHORELINES MANAGEMENT 1. Have you identified areas of streambank and shorline erosion which represents a nonpoint pollution problem? Yes No 2. If yes, are you taking measures to protect these areas? Yes No a. What measures are you implementing? 170 WETLANDS AND RIPARIAN AREAS 1. Wetlands and riparian areas protection management: a. Have you identif ied wetlands and riparian areas which serve a signif icant nonpoint source pollution abatement? Yes No b. Do you have a program for the protection of these areas? c. If yes, does it include maintenance of the following: non point source pollution abatement species composition vegetative cover hydrology of surface water hydrology of ground water substrate geochemistry 2. Wetlands and riparian areas restoration management: Do you promote the restoration of preexisting functions in damaged and destroyed wetlands and riparian systems? Yes No 3. Vegetated treatment systems management: Do you promote the use of engineered vegetated treatment systems, such as: constructed wetlands vegetated filter strips 17 1 APPENDIX 2: Field photographs. 172 OF "ova Author F A. Grana-Raffucci overLooking the Fajardo River at bridge over HeCd Station Pl. I= OL Vik AL E7 m JIM r -@4r !6 FieLd Station #P, 173 7 je. @WO 4t .. f- 7? '4 77 _47 p4r 4* PLantain pLantation adjacent to FieLd Station #1. it 4, q@ 44. 40- - 110* AA v@. Author F. A. Grana-Raffucci taking water sampLes at FieLd Station #1.