[From the U.S. Government Printing Office, www.gpo.gov]



                                                     Volume 4 - Raw Analytical Data
            Engineering Report






                        PENNSYLVANIA COASTAL ZONE MANAGEMENT PROGRAM


                                  WATER QUALITY MONITORING STUDY
                                     FOR THE LAKE ERIE WATERSHED



                                              SEPTEMBER 1996
                                               Project: 2758-001



                                        CZM Project No.: CZ1:94.06PE





                 A REPORT OF TBE PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTIOI@
                         TO TBE NATIONAL OCEANIC AND ATMOSPBERIC ADMINISTRATION
                                  PURSUANT TO NOAA AWARD NO. - NA470ZO248














             This project was financed through a Federal Coastal Zone Management Grant from the
             Pennsylvania Department of Environmental Protection with funds provided by the National
             Oceanic and Atmospheric Administration (NOAA). The views expressed herein are those of
             the author(s) and do not necessarily reflect the view of NOAA or any of its subagencies.
                           Or
                                  w






            MALODW                                   ENVIRONMENTAL ENGINEERS, SCIENTISTS & PLANNERS
              PIRNIE


                                                                                     Printed on Recycled Paper







                                                                                                                   (814) 474-2044
                         CHURCH laboratory,                         inc.

                                                                                              7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                  FAIRVIEW, PA. 16415







                                                         Water Analyses Report




              Customer:                 Malcolm Pirtfie, Inc.
                                        S. 3515 Abbott     Road
                                        Buffalo, NY 14219

              Pro ect:                  Erie County Water Quality Monitoring Study
                  j
                                        for Lake Erie Watershed             #2758-01
              Sample ID:                Dry Event #1, TWELVE XHLE CREEK                              Lab Log No: 49969
              Sample Date/Time:         June 14,1995/8:15AIVL 13:50PXt 17:30PM
              Sampler:                  N.A. Conaway


              PARAMETER                  EPA                      RESULTS/                   ANALYSIS             ANALYST
                                        METHOD                      UNITS                       DATE


              Antimony                   204.2                    <0.003    mg/l             06-20-95                  RJI
              Arsenic                    206.2                    <0.001    mg/l             06-15-95                  RJI
              Beryllium                  210.1                    <0.005    mg/I             06-16-95                  RJI
              Cadmium                    213.2                    <0.0001   mg/I             06-27-95                  RJI
              Chromium, Total            218.1                    <0.05     mg/I             06-19-95                  RJI
              Chromium, VI               218.4                    <0.01     mg/l             06-14-95                  NDA
              Copper                     220.2                    <0.001    mg/l             06-22-95                  RJI
              Lead                       239.2                    <0.001    mg/1             06-22-95                  RJI
              Mercury                    245.2                    <0.0002   mg/I             06-?7-95                  RJI
        i;S-- Nickel                     249.1                    <0.01     mg/1             06-16-95                  RJI
              Selenium                   270.2                    <0.002    mg/l             06-23-95                  RJI
              Silver                     272.2                    <0.0002   mg/I             06-27-95                  RJI
        \In   Thallium                   279.2                    <0.001    mg/l             06-27-95                  RJI
        M     Zinc                       289.1                      0.012   mg/I             06-20-95                  RE
              Cyanide, Free              DER   (White)            <0.005    mg/l             06-15-95                  LT

              Aduminum                   202.1                    <0. I     mg/I             06-16-95                  RJI
              Alkalinity                 310.1                      81      mg/I             06-19-95                  KW
              Ammonia Nitrogen           350.1                      0.05    mg/l             06-212-95                 LT
              Fecal Coliform
        \'P            Grrab@08:15AM     SM-16,909C                 141     col/ 100 ml      06-15-95                  LT
              Hardness                   130.1                      157     mg/I             06-15-95                  KW
              Iron                       236.1                      0. 621  mg/I             06-19-95                  RJI
              Manganese                  243.1                    <0.01     mg/I             06-16-95                  RJI
              Nitrite Nitrogen           353.2                    <0.01     mg/I             06-20-95                  LT
              Nitrate Nitrogen           353.2                      2.45    mg/I             06-20-95                  LT
              Chloride                   325.2                      38      mg;I             06-19-95                  LT


                                                                page I of 2




                           CHURCH laboratory, inc.                                                                     (814) 474-2044

                                                                                                  7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                      FAIRVIEW, PA. 16415







                Water Analyses Report
                Malcolm Pirnie, Inc.                                                                     Page 2 of 2

                Project:                  Erie County Water Quafity TvIonitoring Study
                                          for Lake Erie Watershed              #2758-01
                Sample ID:                Dry Event #1, TWELVE MILE CREEK                                Lab Log No: 49969
                Sample Date/Time:         June 14, 1995/8:15AN4,13:50PM, 17:30PM
                Sampler:                  N.A. Conaway


                PARAMETER                   EPA                      RESULTS/                   ANALYSIS              ANALYST
                                          METHOD                       UNITS                       DATE


                Oil& Grease Grab
                           @08:05AM         413.1                      1.2     Mg/l             06-19-95                   KW
                           0,14:50PM        413.1                      2.0     M-0              06-19-95                   KIW
                           jl7:30PM         413.1                    <0.4      Mg/l             06-19-95                   KW
                CBOD,                       405.1                      3       Mg/I             06-19-95                   KW
                Total Suspended Solids      160.2                      2       M-0              06-19-95                   KW
                Phosphorus                  365.4                    <0,01     Mg/l             06-16-95                   LT
                COD                         410.4                    <10       1n9q             06-20-95                   NDA

                Aldrin                      508                      <0.4      uo               06-23-95                   NDA
                aphaBHC                     508                      <0.02     ugA              06-23-95                   NDA
                beta-BHC                    508                      <0,02     u9n              06-23-95                   NDA
                gamma-BHC(Lindane)          508                      <0.02     u9/1             06-23-95                   NDA
                delta-BHC                   508                      <0.02     ug/l             06-23-95                   NDA
                alpha-Chlordane             508                      <0.2      U-94             06-23-95                   NDA
                gwnma-Chlordane             508                      <0.2      u9/1             06-23-95                   NDA
                4,4'-DDT                    508                      <0.01     U94              06-23-95                   NDA
                4,4'DDE                     508                      <0@01     u9A              06-23-95                   NDA
                4,4'-DDD                    508                      <0.01     ug/l             06-23-95                   NDA
                Dieldrin                    508                      <0.5      u9A              06-23-95                   NDA
                alpha-Endosulfan            508                      <0.01     USA              06-23-95                   NDA
                beta-Endosulfan             508                      <0.01     U911             06-23-95                   NDA
                endosulfan Sulfate          101,                     <0.01     UO               06-23-95                   NDA
                Endrin                      508                      <0.01     u9n              06-23-95                   NDA
                Endrin Aldehyde             508                      <0@01     ugA              06-23-95                   NDA
                Heptachlor                  508                      <0.04     u9/1             06-23-95                   NDA
                HeptacWor Epoxide           508                      <0.02     ug/l             06-23-95                   NDA
                Toxaphene                   508                      <1.0      UFA              06-23-95                   NDA






                Robert W. S    a    Jr.
                President


                Reported: June 28, 1995








                                                                                                                             (814) 474-2044
                            CHURCH laboratory, inc.

                                                                                                       7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                            FAIRVIEW, PA. 16415







                                                              Water Analyses Report




                 Customer:                   Malcolm Pirnie, Inc.
                                             S. 3515 Abbott Road
                                             Buffalo, NY 14219

                 Project:                    Elie County Water Quality Monitoring Study
                                             for Lake Ene Watershed                #2758-01
                 Sample H):                  Dry Event #1, WALNUT CREEK                                        Lab Log No: 49968
                 Sample Date/Time:           June 14, 1995/10:25AA4, 15:00PNt 18:16PM
                 Sampler:                    N.A. Conawky

                 PARAMETER                    EPA                        RESULTS/                   ANALYSIS                 ANALYST
                                             METHOD                        UNITS                         DATE


                 Antimony                     204.2                      <0.003    mg/l               06-20-95                    RJI
                 Arsenic                      206.2                      <0.001    mg/l               06-15-95                    RR
                 Bervlhum                     210.1                      <0.005    mg/l               06-16-95                    RJI
                 Ca(irmurn                    213.2                      <0.0001   mg/I               06-217-95                   RJI
                 Chromium, Total              218.1                      <0.05     mg/l               06-19-95                    RJI
                 Chromium, VI                 2111,4                     <0.01     mg/l               06-14-95                    NDA
                 Copper                       2 2 0.2                    <0.001    mg/l               06-22-95                    RJI
                 Lead                         239.2                      <0.001    mg/l               06-22-95                    RJI
                 Mercury                      245.2                      <0.0002   mg/l               06-27-95                    RE
                 Nickel                       249.1                      <0.01     mg/l               06-16-95                    RJI
                 Selenium                     270.2                      <0.002    mg/l               06-23-95                    RJI
                 Silver                       1. 7 2. 2                  <0.0002   mg/l               06-2-1-95                   RE
                 Thalhurn                     279.2                      <0.001    mg@q               06-27-95                    RJI
                 Zinc                         289.1                        0,048   mg/l               06-20-95                    RE
                 Cyanide, Free                DER   (White)              <0.005    mg/l               06-15-95                    LT

                 Aluminum                     202,1                      <0. 1     mg/l               06-16-95                    RE
                 Alkalinity                   310.1                        140     mg/l               06-19-95                    KW
                 Ammonia Nitrogen             350.1                        0.04    mizIl              06-22-95                    LT
                 Fecal Coliform
                          Grab@10:25AM        SM- 16, 909C                 80      col/100 ml         06-15-95                    LT
                 Hardness                     130.1                        209     mg/l               06-15-95                    KW
                 Iron                         236.1                        0.38    mg/1               06-19-95                    RJI
                 Manganese                    241,1                        0.01    mgn                06-16-95                    RJI
                 Nitrite Nitrogen             353.2                      <0.01     mg/1               06-20-95                    LT
                 Nitrate Nitrogen             353.2                        0.41    mg/l               06-20-95                    LT
                 Chloride                     325.2                        59      mg;1               06-19-95                    LT

                                                                       page 1 of 2




                              CHURCH laboratory, inc.                                                                                   (814) 474-2044

                                                                                                               7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                                       FAIRVIEW, PA. 16415








                Water Analyses Report
                Malcolm Pirnie, Inc.                                                                                   Page 2 of 2

                Project:                       Efie County Water Quality Monitoring Study
                                               for Lake Erie Watershed                   #2758-01
                Sample ID:                     Dry Event #1, WALNUT CREEK                                              Lab Log No: 49968
                Sample Date/Time:              June 14,1995/10:25AK 15:00PM, 18:16PM
                Sampler:                       N.A. Conaway

                PARAMETER                        EPA                          RESULTS/                     ANALYSIS                   ANALYST
                                               METHOD                            UNITS                           DATE


                Oil & Grease Grab
                             @10:25AM            413.1                           3.2     Mg/l                 06-19-95                      KW
                             @15:OOPM            413.1                           0.4     mg/l                 06-19-95                      K-W
                             @18:16PM            413.1                        <0.4       Mg/1                 06-19-95                      KIAT
                CBOD,                            405.1                           2       Mg1l                 06-19-95                      KW
                Total Suspended Solids           160.2                           2       Mg/l                 06-19-95                      KW
                Phosphorus                       365.4                        <0.01      Mg/1                 06-16-95                      LT
                COD                              410.4                        <10        Mg1l                 06-20-95                      NDA

                Aldrin                           508                          <0.4       ug/l                 06-23-95                      NDA
                aphaBHC                          508                          <0.02      ug/l                 06-23-95                      NDA
                beta-BHC                         508                          <0.02      qX1                  06-23-95                      NDA
                gamma-BHC(Lindane)               508                          <0.02      ug
                                                                                            A                 06-23-95                      NDA
                delta-BHC                        508                          <0.02      ug/l                 06-23-95                      NDA
                alpha-Chlordane                  508                          <0.2       ug/l                 06-23-95                      NDA
                ganima-Chlordane                 508                          <0.2       ug/1                 06-23-95                      NDA
                4,41-DDT                         508                          <0.01      ug/l                 06-23-95                      NDA
                4,4'DDE                          508                          <0.01      uqA                  06-23-95                      NDA
                4,4'-DDD                         508                          <0.01      ug/l                 06-23-95                      NDA
                Dieldrin                         508                          <0.5       ug/l                 06-23-95                      NDA
                alpha-Endosulfan                 508                          <0.01      u9n                  06-23-95                      NDA
                beta-Endosulfan                  508                          <0.01      ug/l                 06-23-95                      NDA
                endo8ulfan Sulfate               508                          <0.01      ug/l                 06-23-95                      NDA
                Endrin                           508                          <0.01      ug/l                 06-23-95                      NDA
                Endrin Aldehyde                  508                          <0.01      ug/l                 06-23-95                      NDA
                Heptachlor                       508                          <0.04      ug/l                 06-23-95                      NDA
                Heptachlor Epo-,ude              508                          <0.02      ug/l                 06-23-95                      NDA
                Toxaphene                        508                          < 1,0      110                  06-23-95                      NDA






                Robert W. Stallbaum, Jr.                .01
                President


                Reported: June 28, 1995








                                                                                                                                                 (814) 474-2044
                                 CHURCH laboratory,                                   inc.

                                                                                                                       7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                                FAIRVIEW, PA. 16415







                                                                       Water Analyses Report




                  Customer:                        Malcolm Pirnie, Inc.
                                                   S. 3515 Abbott Road
                                                   Buffalo, NY 14219

                  Project:                         Erie County Water Quality Monitoring Study
                                                   for Lake Erie Watershed                     #2758-01
                  Sample ID:                       Dry Event #1, ELK CREEK                                                     Lab Log No: 49970
                  Sample Date/Time:                June 14, 1995/11:18 AM, 15:30PK 18:40PM
                  Sampler:                         N.A. Conaway


                  PARAMETER                          EPA                            RESULTS/                      ANALYSIS                     ANALYST
                                                   METHOD                             UNITS                             DATE


                  Antimony                           204.2                          <0.003     mg/I                 06-20-95                         RJI
                  Arsenic                            206.2                          <0.001     mg/I                 06-15-95                         RE
                  Beryllium                          210.1                          <0.005     mg/I                 06-16-95                         RJI
                  Cadmium                            213.2                          <0.000 I   mg/I                 06-27-95                         RJI
                  Chromium, Total                    218. 1                         <0.05      mg/I                 06-19-95                         RE
                  Chromium, VI                       218*1                          <0.01      mpq                  06-14-95                         NDA
                  Copper                             '120.2                         <0.001     M-0                  06-22-95                         RE
                  Lead                               239.2                          <0.001     mg/I                 06-22-95                         RJI
                  Mercury                            245.2                          <0.0002    mg/l                 06-27-95                         RE
                  Nickel                             249.1                          <0.01      mg/I                 06-16-95                         RJI
                  Selenium                           270.2                          <0.002     mg/I                 06-23-95                         RJI
                  Silver                             2 7 2.2                        <0.0002    mg/l                 06-27-95                         RE
                  Thallium                           279.2                          <0.001     mg/I                 06-27-95                         RE
                  Zinc                               289.1                            0.011    mg/l                 06-20-95                         RJI
                  Cyaruide, Free                     DER    (White)                 <0.005     mg/l                 06-15-95                         LT

                  Aluminum                           202,1                          <0. 1      mg/I                 06-16-95                         RJI
                  Alkalinity                         310.1                            100      mg/1                 06-19-95                         KW
                  Ammonia Nitrogen                   350.1                            0.09     mg/I                 06-22-95                         LT
                  Fecal Coliform
                               Grab@ 11: 18AM        SM-16,909C                       28       col/ 100 ml          06-15-95                         LT
                  Hardness                           130.1                            154      mg/I                 06-15-95                         KW
                  Iron                               236.1                            0.47     mpA                  06-19-95                         RJI
                  Manganese                          243.1                          <0.01      mg/1                 06-16-95                         RJI
                  Nitrite Nitrogen                   353.2                          <0.01      mg/I                 06-20-95                         LT
                  Nitrate Nitrogen                   353.2                            0.97     mg/I                 06-20-95                         LT
                  Chloride                           325.2                            35       mg;I                 06-19-95                         LT


                                                                                 page I of 2








                                                                                                                                       (814) 474-2044
                               CHURCH laboratory,                                inc.

                                                                                                               7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                      FAIRVIEW, PA. 16415







                  Water Analyses Report
                  Malcolm Pirnie, Inc.                                                                                 Page 2 of 2

                  Project:                      Erie County Water Quality Monitoring Study
                                                for Lake Erie Watershed                  #2758-01
                  Sample ID:                    Dry Event# 1, ELK CREEK                                                Lab Log No: 49970
                  Sample Date/Time:             June 14, 1995/11:18K 15:30PM, 18:40PM
                  Sampler:                      N.A. Conaway

                  PARAMETER                       EPA                          RESULTS/                     ANALYSIS                  ANALYST
                                                METHOD                           UNITS                           DATE


                  Oil & Grease Grab
                            @ 11: 18AM            413.1                          1.2     Mg/l                06-19-95                       KW
                            @15:30PM              413.1                          2.4     Mg/l                06-19-95                       KW
                            @18:40PM              413.1                          1.2     Mg/l                06-19-95                       KW
                  CBOD,                           405.1                          2       Mg/l                06-19-95                       KIW
                  Total Suspended Solids          160.2                          2       Mg/l                06-19-95                       KW
                  Phosphorus                      365.4                          0.01    mgn                 06-16-95                       LT
                  COD                             410.4                          10      MgA                 06-20-95                       NDA

                  Aldrin                          508                          <0.4      ug/l                06-23-95                       NDA
                  aphaBHC                         508                          <0.02     ug/1                06-23-95                       NDA
                  bela-BHC                        508                          <0.02     ugA                 06-23-95                       NDA
                  gamma-1311C(Lmidane)            508                          <0.02     ug/l                06-23-95                       NDA
                  delta-BHC                       508                          < 0. 021  u9/1                06-23-95                       NDA
                  alpha-Chlordane                 508                          <0.2      ug/l                06-23-95                       NDA
                  gainma-Chlordane                508                          <0.2      u9/1                06-23-95                       NDA
                  4,4'-DDT                        508                          <0.01     u9/1                06-23-95                       NDA
                  4,41DDE                         508                          <0.01     u9A                 06-23-95                       NDA
                  4,4'-DDD                        508                          <0.01     ug/l                06-23-95                       NDA
                  Dieldrin                        508                          <05       ug/l                06-23-95                       NDA
                  alpha-Endosulfan                508                          <0.01     u9A                 06-23-95                       NDA
                  beta-Endosulfan                 508                          <0.01     u&q                 06-23-95                       NDA
                  endosulfan Sulfate              501                          <0.01     ug/l                06-23-95                       NDA
                  Endrin                          508                          <0.01     ug/l                06-23-95                       NDA
                  Endrin Aldehyde                 508                          <0.01     ug/l                06-23-95                       NDA
                  Heptachlor                      508                          <0.04     ugA                 06-23-95                       NDA
                  Heptachlor Epoxide              508                          <0.02     ug/l                06-23-95                       NDA
                  Toxaphene                       508                          <1.0      U94                 06-23-95                       NDA






                  Ro     W. S      a      r.
                  President


                  Reported: June 28, 1995








                                                                                                                                             (814) 474-2044
                                CHURCH laboratory, inc.

                                                                                                                   7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                           FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                 Customer:                       Malcolm Pirnie, Inc.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                 Project:                        Erie County Water Quality Monitoring Study
                                                 for Lake Erie Watershed                      #2758-01
                 Sample ID:                      Dry Event #1, TRIP BLANK                                                  Lab Log No: 49984
                 Sample Date/Time:               June 14, 1995
                 Sampler:                        N.A. Conaway


                 PARAMETER                         EPA                           RESULTS/                      ANALYSIS                   ANALYST
                                                 METHOD                            UNITS                        DATE


                 Antimony                          204.2                         <0.003     mg/l                06-2 '0-95                      RJI
                 Arsenic                           206.2                         <0.001     Ing/l               06-15-95                        RJI
                 Beryllium                         210.1                         <0.005     mg/I                06-16-95                        RE
                 Cadmium                           213.2                         <0.0001    mg/1                06-27-95                        RE
                 Chromium, Total                   218.1                         <0.05      mg/1                06-19-95                        RE
                 Chromium, VI                      218.4                         <0.01      MgA                 06-14-95                        NDA
                 Copper                            220.2                         <0.001     mg/1                06-22-95                        RE
                 Lead                              239.2                         <0.001     mg/1                06-22-95                        RJ1
                 Mercury                           245.2                         <0.0002    mg/1                06-27-95                        RE
                 Nickel                            249.1                         <0.01      mg/1                06-16-95                        RE
                 Selenium                          270.2                         <0.002     mg/l                06-23-95                        RE
                 Silver                            272.2                         <0.0002    mg/1                06-27-95                        RJ1
                 Thalliurn                         279.2                         <0.001     mg/1                06-27-95                        RJI
                 Zinc                              289.1                           0.012    mg/1                06-20-95                        RE
                 Cyanide, Free                     DER   (White)                 <0.005     mg/1                06-15-95                        LT

                 Aluminum                          202.1                         <0. I      mg/1                06-16-95                        RE
                 Alkalinity                        310.1                           0.2      mg/1                06-19-95                        KW
                 Ammonia Nitrogen                  350.1                         <0.01      mg/1                06-22-95                        LT
                 Fecal Coliform                    SM-16,909C                      0        col/ 100 ml         06-15-95                        LT
                 Hardness                          130.1                           2        mg/l                06-15-95                        KW
                 Iron                              236.1                           0.87     mg/l                06-19-95                        RE
                 Manganese                         243.1                         <0.01      mg/1                06-16-95                        RJ1
                 Nitrite Nitrogen                  353.2                         <0.01      mg/l                06-20-95                        LT
                 Nitrate Nitrogen                  353.2                         <0.01      mg/1                06-20-95                        LT
                 Chloride                          325.2                         <')        mg;l                06-19-95                        LT


                                                                              page I of 2








                                                                                                                                          (814) 474-2044
                               CHURCH laboratory,                                inc.

                                                                                                                 7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                         FAIRVIEW, PA. 16415







                  Water Analyses Report
                  Malcolm Pirnie, Inc.                                                                                   Page 2 of 2

                  Project:                       Efie County Water Quality Monitoring Study
                                                 for Lake Erie Watershed                   #2758-01
                  Sample ID:                     Dry Event #1, TRIP BLANK                                                Lab Log No: 49984
                  Sample Date/Time:              June 14, 1995
                  Sampler:                       N.A. Conaway

                  PARAMETER                        EPA                          RESULTS/                     ANALYSIS                   ANALYST
                                                 METHOD                            UNITS                        DATE


                  oil & Grease                     111*1                        <0.4       M94                 06-22-95                       KW
                  CBOD,                            405.1                                   mg/l                06-19-95
                  Total Suspended Solids           160.2                         2         mg/l                06-19-95                       KW
                  Phosphorus                       365.4                        <0.01      Mg/l                06-16-95                       LT
                  COD                              410.4                        <10        Mg/l                06-20-95                       NDA

                  Aldrin                           508                          <0.4       u9/1                06-23-95                       NDA
                  aphaBHC                          508                          < 0. 02    ug/l                06-23-95                       NDA
                  beta-BHC                         508                          <0.02      UO                  06-23-95                       NDA
                  gaxnma-BHC(LM'dane)              508                          <0.02      ug/l                06-23-95                       NDA
                  delta-BHC                        508                          <0.02      ug/l                66-23-95                       NDA
                  alpha-Chlordane                  508                          <0.2       ug/l                06-23-95                       NDA
                  gamma-Chlordane                  508                          <0.2       ug/l                06-23-95                       NDA
                  4,4'-DDT                         508                          <0.01      ug/l                06-23-95                       NDA
                  4,4'DDE                          508                          <0-01      UEA                 06-23-95                       NDA
                  4 4'-DDD                         508                          <0.01      ug/l                06-23-95                       NDA
                  Dieldrin                         508                          <0.5       U&I                 06-23-95                       NDA
                  alpha-Endosulfan                 508                          <0.01      UgA                 06-23-95                       NDA
                  beta-Endosulfan                  508                          <0.01      ug/l                06-23-95                       NDA
                  endogulfan Sulfate               508                          <0.01      U94                 06-23-95                       NDA
                  Endrin                           508                          ---0.01    ug/l                06-23-95                       NDA
                  Endrin.Aldehyde                  508                          <0.0 I     ug/l                06-23-95                       NDA
                  Heptacblor                       5011                         <0.04      u9n                 06-23-95                       NDA
                  Heptacblor Epoxide               508                          <0.02      ug/l                06-23-95                       NDA
                  Toxaphene                        508                          <1.0       ug/l                06-23-95                       NDA





                  Robert W. S baum, Jr.
                  President     tall

                  Reported: June 28, 1995




          SEP-19-96 THU 02:18 PM CHURCH LABORATORY, INC. 814 474 2044                                                        P.04




                                                                                                            (914) 474-2044
                          CHURCH laboratory, inc.

                                                                                         7397 CHESTNUT GTR6fiT     P,O, VQX 04
                                                                                                           PAIRVIEW, PA, 1641 S







                                                        Field Analyses Report




                Customer:                Malcolm Pirnie. Inc.
                                         S. 3515 Abbott Road
                                         Buffalo, NY 14219

                Project:                 Bric County Water Quality Mordtorbig Study
                                         for Lake Erie Watershed          92758-01
                Sample ID:               Dry Event #1, TWELVENULE CREEK
                Sample Date/Time:        June 14, 1995
                Sampler-                 N.A. Conaway

                TIME                     PARAMETER              RESULTS/                 ANALYST
                                                                   UNITS

                08: 15 AM                pH                     8.3                        NAC
                13:50 PM                 PH                                                NAC
                17:30 PM                 PH                     9.4                        NAC

                08: 15 Abl               Mssolved OxyM          5.72    mg4                NAC
                13:11, PM                Dissolved Oxygen       5,0     nIZ4               NAC
                17:30PM                  Dissolved oxygen       5.33    u44                NAC
                08:15 AM                 Temperature            10      0 C                NAC
                13:50 PM                 Temperature            19.4      C                NAC
                17:30 PNI                Tiunperature           20.2    0 C                NAC
                08:15 AM                 conductiY4             411     us/eni             NAC
                13-50 PM                 Conductivity           413     U&fm               NAC
                1730 PM                  Conductivity           416     US/=               NAC
                08.15 AM                 Velocity
                                                                0.5     fps                NAC
                *Plesult is an avelagg Of three biab U-ing stop watch RRd C46ng0S.



                  bert W.     aump Jr.
                @
                PkeaddentI
                   9







                4b?2a 21: @@Jr

                ROported: Julio 28, 1995
                Revised: Sept IS, 1996
                                                              page I of I




            SEP-19-96 THU 02:18 PM CHURCH LABORATORY, INC. 814 474 2044                                                                               P.03




                                                                                                                                  (814) 474-2044
                               CHURCH laboratory, ina.

                                                                                                           7397 CHG,9TNtJT STROF.T - P,Q, IROX 03
                                                                                                                                 FAIRVIEW, PA. 16415






                                                                    Field Analyses Report



                    Customer:                    Malcolm Piniie, ine.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                    Project.,                    F-rie County Water Quality Monitoring Study
                                                 for Lake Erie Watershed                  #2758-01
                    Sample ID:                   Dry Event #1, WALNUr CREEK
                    Sample Date/Time*            June 14, 1995
                    Sampler:                     N.A. Conaway

                    TIME                         PARAMETER                    RESULTS/                     ANALYST
                                                                                UNITS

                    10;25 AM                     pH                           8.6                            NAC
                    15:00 PM                     pH                           8.7                            NAC
                    13;16 PM                     PH                           83                             NAC


                    10:25 AM                     Dis3clved Oxygen             5.62     mg1l                  NAC
                    15:00 PM                     DiS6Q1V6d Oxygen             5,38     ImS4                  NAC
                    18: 16 PM                    Dissolved Oxygen             5.22     mg4                   NAC
                    10:15 AM                     Teripgratme                  17.5     a C                   NAC
                    15:00 PM                     Tempentwe                    23.6     IC                    NAC
                    19: 16 PM                    Ternpenture                  23.4       C                   NAC
                    10:25 A.M                    Conductivity                 554      USICM                 NAC
                    15:00 PM                     conduct-vity                 553      uslem                 NAC
                    18:16 PM                     L70ndUctiVity                552      us/cm                 NAC
                    10:15 AM                     Velocity *                   2.47     fps                   NAC
                    *Rem@t iq    avermse ofthree triais u#h18 stop watch and orarseo,



                    Robert W. Stan     M, Jr.
                  ZA@





                    @2@
                    Phsident


                    Reported: June 28, 1993
                    Revised,   sept is, 19945
                                                                            page I of I





      SEP-19-96 THU 02:17 PM CHURCH LABORATORY, INC. 814 474 2044                       P.02




                                                                             (61-4) 474-2044
                   CHURCHIaboratory,         inc.

                                                               73970He8TNuTaTREF-T - P.0.80X83
                                                                            FAIRViEW. PA. 1 e4l 5






                                       Field Analyses Report



            Customer:       Malcohn Pirnie, Inc.
                            S. 3 515 Abbott Road
                            Buffalo, NY 14219

            Project:        Erie County Water Quality Mordtorin Study
                            for Lake Eno Watershed   92758-01
            Sample ID:      Dry Event #1, ELK CREEK
            Sample Date/Time: June 14, 1995
            Sampler:        N.A. Conaway

            TIME            PAPANIETER       RXSULTS/          ANALYST
                                                UNITS

            11:18AM         PH               8.9                NAC
            15:30 PM        PH               9.2                WAC
            18:40 PM        PH               9.0                NAC


            11:18AM         Dissolved Oxygen 6,23  mgA          NAC
            '5:,o  PM       Dissolved oxygen 5.03  rngd         NAC
            18:40 PM        Dinolved Oxygen  5.03  mgl          NAC
            11:18AM         Temperature      20.7  OC           NAC
            15:3 0 PM       Tanperature      25.2  *C           NAC
            18:40 PM        Tempeyetwe       24.1   C           NAC
            11:18AM         Conductivity     419   us/cnl       NAC
            15:30 PM        Coaduofivity     402   u3/cIn       NAC
            18:40 PM        conduc&4         393   uwrtm        NAC
            11:19AM         VekcitY *        1,41  fps          NAC
            *Re&Wt is WX average -of thma UWN using stop watch mid orViges.



             ert W. S baum, Jr.
            Pmidonl

            Reported: June 28, 1995
            ReNixed: Sept 19, 1996
            @9
























































                                            page I of I








                                                                                                                                  (814) 474-2044
                               CHURCH laboratory,                            inc.

                                                                                                          7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                FAIRVIEW, PA. 16415







                                                                   Water Anakyses Report




                    Customer:                    Malcolm Pirnie, Inc.
                                                 S. 3 515 Abbott Road
                                                 Buffalo, NY 14219

                    Project:                     Erie County Water Quality Monitoring Study
                                                 for Lake Eric Watershed                #2758-01
                    Sample H):                   Event #02W, TWELVE ARLE CREEK                                       Lab Log No: 50759
                    Sample Date/Time:            August 11, 1995/10:30W 12:20PM, 14:27PM
                    Sampler:                     N.A. Conaway


                    PARAMETER                     EPA                         RESULTS/                    ANALYSIS                  ANALYST
                                                 METHOD                         UNITS                          DATE


                    Antimony                      204.2                       <0.003    mg/l               08-23-95                      RJI
                    Arsenic                       206.2                         0.011   mg/l               08-22-95                      RJI
                    Beryllium                     210.1                       <0.005    mo                 08-23-95                      RJI
                    Cadmium                       213.2                         0.0004  mg/I               08-17-95                      NAC
                    Chromium, Total               218.1                         0.13    mg/I               08-22-95                      RJI
                    Chromium, VI                  218.4                       <0.01     mg/I               08-11-95                      NDA
                    Copper                        220.2                         0.021   mg/1               08-22-95                      RJI
                    Lead                          239.2                         0.018   mg/l               08-15-95                      NAC
                    Mercury                       245.1                       <0.0002   mg/l               08-24-95                      RJI
                    Nickel                        249.1                         0.04    mgA                09-22-95                      RJI
                    Selenium                      270.2                       <0.002    mg/I               08-21-95                      RJ1
                    Silver                        272.2                         0.0003  mg/1               08-22-95                      RJI
                    Thallium                      279.2                       <0.001    mg/l               08-21-95                      RJI
                    Zinc                          289.1                         0.2     mg/l               08-18-95                      NAC
                    Cyanide, Free                 DER   (White)               <0.005    mg/I               08-15-95                      LT

                    Aluminum                      202.1                         13.8    mg/1               08-18-95                      NAC
                    Alkalinity                    310.1                         44      mg/1               08-16-95                      KW
                    Ammonia Nitrogen              350.1                         0.19    mg/1               08-18-95                      LT
                    Fecal Coliform
                               Grab@12:20PM       SM-16,909C                    13,100  col/100 ml         08-12-95                      LT
                    Hardness                      130.1                         112     mg/1               08-11-95                      KW
                    iron                          236.1                         19.5    mg/1               08-18-95                      NAC
                    Manganese                     243.1                         1.34    mg/1               08-22-95                      RJI
                    Nitrite Nitrogen              353.2                         0.06    mW1                08-17-95                      LT
                    Nitrate Nitrogen              353.2                         3.28    mg/1               08-17-95                      LT
                    Chloride                      325.2                         35      mg;;1              08-15-95                      LT


                                                                           page I of 2







                                                                                                                  (814) 474-2044
                          CHURCH laboratory, inc.

                                                                                              7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                 FAIRVIEW, PA. 16415







                  Water Analyses Report
                  Malcolm Pirnie, Inc.                                                                 Page 2 of 2)

                  Project:                 Erie County Water Quality Monitoring Study
                                           for Lake Erie Watershed            #2758-01
                  Sample ID:               Event #02W, TWELVE MILE CREEK                               Lab Log No: 50759
                  Sample Date/Time:        August 11, 1995/10:30AK 12:20PK 14:27PM
                  Sampler:                 N.A. Conaway

                  PARAMETER                  EPA                     RESULTS/                 ANALYSIS             ANALYST
                                           METHOD                      UNITS                      DATE


                  oil & Grease Grab
                          @10:30AM           413.1                   <0.4     mg/l            08-22-95                  KW
                          @12:20PM           413.1                   <0.4     Mg/l            08-22-95                  KW
                          @14:27PM           413.1                     0.8    mg/l            08-22-95                  KIN
                  CBOD,                      405.1                     10     mg/1            08-16-95                  KW
                  Total Suspended Solids     160.2                     680    mg/l            08-16-95                  KW
                  Phosphorus                 365.4                     0.89   Mg/l            08-22-95                  LT
                  COD                        410.4                     115    mg1l            08-22-95                  NDA

                  Aldrin                     508                     <0.4     ug/l            08-24-95                  NDA
                  aphaBHC                    508                     <0.02    ug/l            08-24-95                  NDA
                  beta-BHC                   508                     <0.02    ug/l            08-24-95                  NDA
                  gwnma-BHC(Lindane)         508                     <0.02    ug/l            08-24-95                  NDA
                  delta-BHC                  508                     <0.02    ug/l            08-24-95                  NDA
                  alpha-Chlordane            508                     <0.2     UgA             08-24-95                  NDA
                  gamma-Cidordane            508                     <0.2     ug/l            08-24-95                  NDA
                  4,4'-DDT                   508                     <0.01    U94             08-24-95                  NDA
                  4,4'DDE                    508                     <0.01    Ug/l            08-24-95                  NDA
                  4,4'-DDD                   508                     <0.01    ug/l            08-24-95                  NDA
                  Dieldrin                   508                     <0.5     ug/l            08-24-95                  NDA
                  alpha-Endosulfim           508                     <0.01    ug/l            08-24-95                  NDA
                  beta-Endoaffan             508                     <0.01    U10             08-24-95                  NDA
                  endosul@ Sulfate           5011                    <0.01    u8A             08-24-95                  NDA
                  Endrin                     508                     <0.01    ug/l            08-24-95                  NDA
                  Endrin Aldehyde            508                     <0.01    ug/l            08-24-95                  NDA
                  Heptachlor                 508                     <0.04    ug/l            08-24-95                  NDA
                  Heptachlor Epoxide         508                     <0.02    ug/l            08-24-95                  NDA
                  Toxaphene                  508                     <1.0     ug/l            08-24-95                  NDA






                  Ro         tallba   Jr.
                    b6@@taUb      , Air7?--
                  President


                  Reported: August 24, 1995








                                                                                                                                  (814) 474-2044
                                CHURCH laboratory, inc.

                                                                                                          7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                FAIRVIEW, PA. 16415






                                                                    Water Analyses Report




                    Customer:                    Malcolm Pirnie, Inc.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                    Project:                     Erie County Water Quality Monitoring Study
                                                 for Lake Erie Watershed                 #2759-01
                    Sample ID:                   Event #02W. WALNUT CREEK                                             Lab Log No: 50760
                    Sample Date/Time:            August 11, 1995/10:25AK 12:45PK 14:45PM
                    Sampler:                     R.W. Stallbaurn


                    PARAMETER                      EPA                         RESULTS/                    ANALYSIS                 ANALYST
                                                 METHOD                          UNITS                          DATE


                    Antimony                       204.2                       <0.003    mg/1               08-23-95                      RJI
                    Arsenic                        206.2                         0.010   mg/l               08-22-95                      RJI
                    Beryllium                      210.1                       <0.005    mg/1               08-23-95                      RJ1
                    Cadmium                        213.2                         0.0005  mg/1               08-17-95                      NAC
                    Chromium, Total                218.1                         0.29    mg/1               08-22-95                      RJI
                    Chromium, VI                   218.4                       <0.01     mg/1               08-11-95                      NDA
                    Copper                         220.2                         0.033   mg/1               08-22-95                      RJI
                    Lead                           239.2                         0.049   mg/1               08-15-95                      NAC
                    Mercury                        245.1                       <0.0002   mg/1               08-24-95                      RJI
                    Nickel                         249.1                         0.10    mg/1               08-22-95                      RE
                    Selenium.                      270.2                       <0.002    mg/1               08-21-95                      RJ1
                    Silver                         272.2                       <0.0002   mg/1               08-22-95                      RJ1
                    Thallium                       279.2                       <0.001    mg/1               08-21-95                      RJI
                    Zinc                           289.1                         0.67    mgA                08-18-95                      NAC
                    Cyanide, Free                  DER   (White)               <0.005    mg/1               08-15-95                      LT

                    Aluminum                       202.1                         38.5    mg/1               08-18-95                      NAC
                    Alkalinity                     310.1                         165     mg/1               08-16-95                      KW
                    Ammonia Nitrogen               350.1                         0.33    mg/1               08-18-95                      LT
                    Fecal Coliform
                                Grab@ 12:45 PM     SM-16,909C                    11,500  col/100 ml         08-12-95                      LT
                    Hardness                       130.1                         144     mg/1               08-11-95                      k1w
                    Iron                           236.1                         35.5    mg/1               08-18-95                      NAC
                    Manganese                      243.1                         2.44    mg/1               08-22-95                      RJ1
                    Nitrite Nitrogen               353.2                         0.10    mg/1               08-17-95                      LT
                    Nitrate Nitrogen               353.2                         0.59    mg/1               08-17-95                      LT
                    Chloride                       325.2                         29      mg;'1              08-15-95                      LT

                                                                            page I of 2




                              CHURCH laboratory, inc.                                                                                  (814) 474-2044

                                                                                                                7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                     FAIRVIEW, PA. 16415







                    Water Analyses Report
                    Malcohn Pirnie, Inc.                                                                                  Page 2 of 2

                    Project:                       Erie County Water Quality Monitoring Study
                                                   for Lake Erie Watershed                  #2758-01
                    Sample ID:                     Event #02WWALNUT CREEK                                                 Lab Log No: 50760
                    Sample Date/Time:              August 11, 1995/10:25AK 12:45PK 14:45PM
                    Sampler:                       R. W. Stallbaum

                    PARAMETER                       EPA                          RESULTS/                       ANALYSIS                 ANALYST
                                                   METHOD                          UNITS                           DATE


                    Oil & Grease Grab
                               @10:25AM             413.1                          L6       mg/l                08-22-95                      KW
                               @12:45PM             413.1                          3.2      mgn                 08-22-95                      KW
                               @14:45PM             413.1                          1.2      M911                08-22-95                      k1w
                    CBOD5                           405.1                          15       mg/1                08-16-95                      KW
                    Total Suspended Solids          160.2                          1508     mg/I                08-16-95                      KW
                    Phosphorus                      365.4                          1.74     mg/l                08-22-95                      LT
                    COD                             410.4                          125      mg/l                08-22-95                      NDA

                    Aldrin                          508                          <0.4       ug/1                08-24-95                      NDA
                    aphaBHC                         508                          <0.02      ug/1                08-24-95                      NDA
                    beta-BHC                        508                          <0.02      ug/l                08-24-95                      NDA
                    ganuna-BHC(Lindane)             508                          <0.02      ug/l                08-24-95                      NDA
                    delta-BHC                       508                          <0.02      ug/l                08-24-95                      NDA
                    alpha-Chlordane                 508                          <0.2       U-QA                08-24-95                      NDA
                    gamma-Chlordane                 508                          <0.2       U0                  08-24-95                      NDA
                    4,4'-DDT                        508                          <0.01      u9/1                08-24-95                      NDA
                    4,4'DDE                         508                          <0.01      ug/l                08-24-95                      NDA
                    4,4'-DDD                        508                          <0.01      ug/1                08-24-95                      NDA
                    Dieldrin                        508                          <0.5       U94                 08-24-95                      NDA
                    alpha-Endosulfan                508                          <0.01      ugA                 08-24-95                      NDA
                    beta-Endosulfan                 508                          <0.01      U9/1                08-24-95                      NDA
                    endosulfan Sulfate              508                          <0.01      1*4                 08-24-95                      NDA
                    Endrin                          508                          <0.01      UFA                 08-24-95                      NDA
                    Endrin Aldehyde                 508                          <0.01      1194                08-24-95                      NDA
                    Heptachlor                      508                          <0.04      ugn                 08-24-95                      NDA
                    Heptachlor Epo)dde              508                          <0.02      ug/1                08-24-95                      NDA
                    Toxaphene                       508                          <1.0       ug/1                08-24-95                      NDA


                                             /17
                    Robert W, S            T
                    President


                    Reported: August 24, 1995








                                                                                                                      (814) 474-2044
                            CHURCH laboratory, inc.

                                                                                                 7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                     FAIRVIEW. PA. 16415







                                                             Water Analyses Report




                  Customer:                  Malcolm Pirnie, Inc.
                                             S. 3515 Abboft Road
                                             Buffalo, NY 14219

                  Project:                   Eric County Water Quality Mor@toring Study
                                             for Lake Erie Watershed             #2758-01
                  Sample ID:                 Event #02W, ELK CREEK                                         Lab Log No: 50758
                  Sample Date/Time:          August 11, 1995/11:00 AK 13:30PNt 15:15PM
                  Sampler:                   R. W. Stallbaum


                  PARAMETER                   EPA                         RESULTS/               ANALYSIS               ANALYST
                                             METHOD                       UNITS                       DATE


                  Antimony                    204.2                       <0.003 mg/I             08-23-95                   RJI
                  Arsenic                     206.2                       0.003  mg/1             08-22-95                   RJI
                  Beryllium                   210.1                       <0.005 mgA              08-23-95                   RJI
                  Cadmium                     213.2                       <0.0001 mg/I            08-17-95                   NAC
                  Chromium, Total             218.1                       <0.05  mg/1             08-22-95                   RE
                  Chromium, VI                218.4                       <0.01  mg/I             08-11-95                   NDA
                  Copper                      220.2                       0.0002 mg/l             08-22-95                   RJI
                  Lead                        239.2                       <0.001 mg/1             08-15-95                   NAC
                  Mercury                     245.1                       <0.0002 mg/1            08-24-95                   RJI
                  Nickel                      249.1                       0.02   mg/I             08-22-95                   RJI
                  Selenium                    270.2                       <0.002 mg/I             08-21-95                   RJI
                  Silver                      272.2                       0.0008 mg/1             08-22-95                   RJI
                  Thallium                    279.2                       <0.001 mg/1             08-21-95                   RJI
                  Zinc                        289.1                       <0.005 mg/I             08-18-95                   NAC
                  Cyanide, Free               DER   (White)               <0.005 mg/1             08-15-95                   LT

                  Aluminurn                   202.1                       1.28   mg4              08-18-95                   NAC
                  Alkalinity                  310.1                       105    nign             08-16-95                   KW
                  Ammonia Nitrogen            350.1                       0.10   mg/1             08-18-95                   LT
                  Fecal Coliform
                            Grab@13:30PM      SM-16,909C                  1940   col/100 ml       08-12-95                   LT
                  Hardness                    130.1                       184    mg;A             08-11-95                   KW
                  Iron                        236.1                       0.82   mg/1             08-16-95                   NAC
                  Manganese                   243.1                       0.06   mgA              08-22-95                   RE
                  Nitrite Nitrogen            353.2                       0.03   mgA              08-17-95                   LT
                  Nitrate Nitrogen            353.2                       1.27   mg/1             08-17-95                   LT
                  Chloride                    325.2                       37     mg;'1            08-15-95                   LT


                                                                     page 1 of 2




                              CHURCH laboratory, inc.                                                                                    (814) 474-2044

                                                                                                                7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                        FAIRVIEW, PA. 16415







                     Water Analyses Report
                     Malcolm Pirnie, Inc.                                                                                   Page 2 of 2

                     Project:                       Eric County Water Quality Monitoring Study
                                                    for Lake Erie Watershed                   #2758-01
                     Sample ID:                     Event #02W, ELK CREEK                                                   Lab Log No: 50758
                     Sample Date/Time:              August 11, 1995/11:OOK 13:30PK 15:15PM
                     Sampler:                       R. W. Stallbaurn

                     PARAMETER                       EPA                           RESULTS/                     ANALYSIS                   ANALYST
                                                    METHOD                           UNITS                           DATE


                     oil & Grease Grab
                               @I 1:00AM             413.1                         <0.4       Mg/l                08-22-95                       KW
                               @13:30PM              413.1                         <0.4       Mg/l                08-22-95                       KW
                               @15:15PM              413.1                         <0.4       Mg/1                08-22-95                       KW
                     CBOD,                           405.1                           6        mg/l                08-16-95                       KW
                     Total Suspended Solids          160.2                           24       Mg/l                08-16-95                       KW
                     Phosphorus                      365.4                           0.04     mg/1                06-22-95                       LT
                     COD                             410.4                           10       Mg/l                06-22-95                       NDA

                     Aldrin                          508                           <0.4       ug/l                08-24-95                       NDA
                     aphaBHC                         508                           <0.02      ug/1                08-24-95                       NDA
                     beta-BHC                        508                           <0.02      ug/1                08-24-95                       NDA
                     gamma-BHC(Lindane)              508                           <0.02      ug/l                08-24-95                       NDA
                     delta-BHC                       508                           <0.02      ug/l                08-24-95                       NDA
                     alpha-Chlordane                 508                           <0.2       ug/l                08-24-95                       NDA
                     gannna-Cblordane                508                           <0.2       u9A                 08-24-95                       NDA
                     4,4'-DDT                        508                           <0.01      ug/l                08-24-95                       NDA
                     4,4'DDE                         508                           <0.01      ug/1                08-24-95                       NDA
                     4,4'-DDD                        508                           <0.01      ug/l                08-24-95                       NDA
                     Dieldrin                        508                           <0.5       ug/1                08-24-95                       NDA
                     alpha-Endosulfan                508                           <0.01      UEA                 08-24-95                       NDA
                     beta-Endosulfwi                 508                           <0.01      ug/l                08-24-95                       NDA
                     endosulfan Sulfate              5011                          <0.01      ug/1                08-24-95                       NDA
                     Endrin                          508                           <0.01      ug/l                08-24-95                       NDA
                     Endrin Aldehyde                 508                           <0.01      ug/1                08-24-95                       NDA
                     Heptachlor                      508                           <0.04      ug/l                08-24-95                       NDA
                     Heptachlor Epo)dde              508                           <0.02      ug/l                08-24-95                       NDA
                     Toxaphene                       508                           <1.0       ug/l                08-24-95                       NDA
                     Ro @ert@ EtAllba , Jr.
                     President


                     Reported: August 24,1995







                                                                                                                                             (814) 474-2044
                              CHURCH laboratory, inc.

                                                                                                                   7397 CHESTNUT STREET - P.O. SOX 83
                                                                                                                                           FAIRVIEW, PA. 16415







                                                                         Water Analyses Report




                       Customer:                      Malcolm Pirnie, Inc.
                                                      S. 3515 Abbott Road
                                                      Buffalo, NY 14219
                       Project:                       Erie County Water Quality Monitoring Study
                                                      for Lake Efie Watershed                      #2758-01
                       Sample ID:                     Event #02W, TREP BLANK                                                     Lab Log No: 50758B
                       Sample Date/Time:              August 11, 1995
                       Sampler:                       N.A. Conaway
                       PARAMETER                        EPA                            RESULTS/                     ANALYSIS                     ANALYST
                                                      METHOD                            UNITS                          DATE
                       Antimony                         204.2                          <0.003      mg/l                08-23-95                        RJI
                       Arsenic                          206.2                          <0.001      mgd                 08-22-95                        RJI
                       Berylliwn                        2103                           <0.005      mo                  08-23-95                        RJI
                       Cadmium                          213.2                          <0 *000 1   mg/l                08-17-95                        NAC
                       Chromium, Total                  218.1                          <0*05       mg/I                08-22-95                        RJI
                       Chromium, V1                     218.4                          <0.01       mg/l.               08-11-95                        NDA
                       Copper                           220.2                          <0.001      mo                  08-22-95                        RJI
                       Lead                             239.2                          <0.001      mg4                 08-15-95                        NAC
                       Mercury                          245.1                          <0@0002     mg/1                08-24-95                        RJI
                       Nickel                           249.1                          <0.01       mg/1                08-22-95                        R11
                       Selenium                         270.2                          <0.002      mg/1                08-21-95                        RJI
                       Silver                           272.2                          <0.0002     mg/l                09-22-95                        RJI
                       Thallium                         279.2                          <0.001      mg4                 08-21-95                        RR
                       Zinc                             289.1                          <0.005      mg/1                08-18-95                        NAC
                       Cyanide, Free                    DER    (White)                 <0.005      mg/1                08-15-95                        LT
                       Aluminum                         202.1                          <0. I       mg/1                08-18-95                        NAC
                       Alkalinity                       310.1                           0.2        m8A                 08-16-95                        KW
                       Ammonia Nitrogen                 350.1                          <0.01       M911                08-18-95                        LT
                       Fecal Coliform                   SM-16,909C                      0          col/100 mi          08-12-95                        LT
                       Hardness                         130.1                           2          mg/l                08-11-95                        KW
                       Iron                             236.1                          <0.03       mg;/1               08-18-95                        NAC
                       Manganese                        243A                           <0.01       mg/1                08-22-95                        RA
                       Nitrite Nitrogen                 353@2                          <0.01       mg/1                08-17-95                        LT
                       Nitrate Nitrogen                 353.2                          <0.01       mg/l                08-17-95                        LT
                       Chloride                         325.2                          <2          mg;1                08-15-95                        LT


                                                                                    page I of 2








                                                                                                                                           (814) 474-2044
                              CHURCH laboratory, inc.

                                                                                                                  7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                          FAIRVIEW, PA. 16415







                     Water Analyses Report
                     Malcolm Pirnie, Inc.                                                                                     Page 2 of 2

                     Project:                       Eric County Water Quality Monitoring Study
                                                    for Lake Erie Watershed                    #2758-01
                     Sample ID:                     Event #02W, TRIP BLANK                                                    Lab Log No: 50758B
                     Sample Date/Time:              August 11, 1995
                     Sampler:                       N.A. Conaway

                     PARAMETER                        EPA                           RESULTS/                      ANALYSIS                    ANALYST
                                                    METHOD                            UNITS                          DATE


                     oil 8,, Grease                   411*1                         --0.4      Mg/l                 08-22-95                       KW
                     CBOD,                            405.1                           2        Mg/l                 08-16-95                       KW
                     Total Suspended Solids           160-2                           2        Mg/l                 08-16-95                       KW
                     Phosphorus                       365.4                         --0.01     rug/l                08-22-95                       LT
                     COD                              410.4                         <10        rug/l                08-22-95                       NDA

                     Aldrin                           508                           <0.4       ug/l                 08-24-95                       NDA
                     aphaBHC                          508                           <0.02      ug/l                 08-24-95                       NDA
                     beta-BHC                         508                           <0.02      ug/l                 08-24-95                       NDA
                     gamma-BHC(Lindane)               508                           <0.02      ug/l                 08-24-95                       NDA
                     delta-BHC                        508                           <0.02      ug/l                 08-24-95                       NDA
                     alpha-Cldordane                  508                           <0.2       ug/l                 08-24-95                       NDA
                     gamzna-Chlordane                 508                           <0.2       ug/l                 08-24-95                       NDA
                     4,4'-DDT                         508                           <0.01      ug/l                 08-24-95                       NDA
                     4,4@DDE                          508                           <0.01      ug/l                 08-24-95                       NDA
                     4,4'-DDD                         508                           <0.01      ug/l                 08-24-95                       NDA
                     Dieldrin                         508                           <0.5       ug/l                 08-24-95                       NDA
                     alpha-Endosulfan                 508                           <0.01      ug/l                 08-24-95                       NDA
                     beta-Endosulfan                  508                           <0.01      ug/l                 08-24-95                       NDA
                     endogulfan Sulfate               509                           <0.01      ug/l                 08-24-95                       NDA
                     Endrin                           508                           <0.01      ug/l                 08-24-95                       NDA
                     Endrin Aldehyde                  508                           <0.01      UPI                  08-24-95                       NDA
                     Heptachlor '                     508                           <0.04      UPA                  08-24-95                       NDA
                     Heptachlor Epoxide               508                           <0.02      ug/l                 08-24-95                       NDA
                     Toxaphene                        508                           <1.0       ug/l                 08-24-95                       NDA
                     @
                      o ert W. S       aum, Jr.
                     President
                      o @@@W. Stamm, Jr.
                     Reported: August 24, 1995





          SEP-L9-96 THU 02:19 PM CHURCH LABORATORY, INC. 814 474 2044                                                                   P.06




                                                                                                                      (9 14) 474-2D44
                           CHURCH laboratory, inc.

                                                                                                 7327 CHiSTNUT STREI!T - P.O. BOX 83
                                                                                                                     FAIRVISW. PA. 10415






                                                             Field Analyses Report


                  Customer:                 Malcolm Pirwe, Inc.
                                            S. 3515 Abbott Road
                                            Buffalo, NY 14219

                  Project:                  Erie County Water QuOty Monitoring Study
                                            for Lake Eric Watershed              #2758-01
                  Sample ID:                Event #02W, TWELVE MILE CREEK
                  Sample Date/Time:         Augugst 11, 1995
                  Sampl@v                   N.A, Conaway
                  Site Observations:        In rowd one all of the flow *-as near the cement w.* covetilig roughly 213 of the total bed.
                                            In founds two and three the flow had spread over the en*e bed. Water was leas turbid in
                                            rourld thres. There was no noticable change in turbidity between rounds one and two.

                  TIME                      PAR"IETER                 RESULTS/                  ANALYST
                                                                          uNirs
                  10:30 AA1                 PH                        9.2                          NAC
                  12:20 PNI                 pit                       8.0                          NAC
                  14.27 I'M                 pH                        8.0                          NAC

                  10.30 AM                  Diosolved Oxygen          4.68       mgA               NAC
                  ,2:", "M                  Dinolved Oxygen           4.70       Ingil             NAC
                  14:27 PM                  Diewlved Oxygen           4.36       m&4               NAC
                  10:30 AM                  Tempetature               190         C                NAC
                  12:20 PM                  Temperature               20.5       PC                NAC
                  14:27 PM                  Temperature               22.1       PC                NAC
                  1030 AM                   Conductivity              241.'      us/cm             NAC
                  12:20 PM                  Conductivity              324        U&01@             NAC
                  14;27 PM                  Conductivity              361        US/VM             'NAC
                  10:30 AM                  Velocity *                4.9        fps               NAC
                  12:20 PNf                 Velocity *                4.9        fps               NAC
                  14,27 PM                  Velocity *                3.67       fps               NAC
                  111:30 AM                 Depth                     1.75       R                 NAC
                  12:20 PM                  Dep th                    2.0        ft                NAC
                  4-                        Depth                     1.3        ft                NAC
                  *Re    is  avemoofthrea, triOll ulinS irtop watch and oranges.
                    27 PAI.N
                  4r           baum, Jr.
                  Awt W. st,
                  Preeident
                  Reported: Aupost:24,1995
                  Revised; Sept IS, 1996





        SEP-19-96 THU 02:20 PM CHURCH LABORATORY, INC. 814 474 2044                                             P.07




                                                                                                 (914) 474-2044
                      CHURCH laboratory, inc,

                                                                                7-497 CHESTNUT STREET I P.O.BOX83
                                                                                                FAIAVIEW, PA. 16416







                                                  Field AnaJyses Report



              Customer:             Malcolm Pin&, Inc.
                                    S. 3515 Abbott Road
                                    Buffalo, NY 14219

              Project:              Erie County Water Quality Monitodng Study
                                    for IAe Erie Watershed        #2759-01
              Sample ID:            Event #02W, WALNUT CREEK
              Sample Date/Time:     August 11, 1995
              Sanipler:             R. W. Stallbaum
              Site Observation:     lNuing round one the water was slightly turbid. During round two the water turned black,
                                    the# Wto a lot of floatim branches and debris. By the Wfd round the water had spread all
                                    tke way across the ftewn bed.


              TIME                  PARAMETER            RESULTS/              ANALYST
                                                            UNITS
              10,25 AM              PH                   8.26                    PIWS
              12:45 PM              PH                   7.76                    RWS
              14:45 PM              PH                   7AL                     RWS
              10:25 AM              Diasolved Oxygen     8.4      IngA           RWS
              12:45 PM              Dissolved Oxygen     7,7      me             RWS
              14!45 PM              Dissolved oxygen     7.4      me             RWS
              10:25 AM              Temperature          21.0     CC             RWS
              12:45 PM              Temperature          210        C            RWS
              14;45 PM              Temperature          22.1       C            RWS
              10:25 AM              Conductivity         276      as/cm          RWS
              12:45 PM              Conductivity         416      us/cIn         RWS
              14:45 PM              Conductivity         301      us/cm          RWS
              10:25 AM              Velocity *           2.6      fps           RWS
              11.45 PM              Velocity *           2.86     fps           RWS
              14:45 PM              velocity             733      An            RWS





                                                       page 1 of 2




            SEP-19-96 THU 02:20 PM CHURCH LABORATORY, INC. 814 474 2044                                                                                  P.08




                                                                                                                                   (814) 474-2044
                               CHURCH laboratory, inc.

                                                                                                             7397CHESTNUTSTREST - P0.80XI33
                                                                                                                                  FAIRVIEW. PA. 16415





                   Field Analyses Report
                   Malcolm Pin-lie, Inc.                                                                             Page 2 of 2

                   Projern:                       Efle County Water Quafity Monitoling Study
                                                  for Lake Efie Watershed                  #2758-01
                   Sample. ID:                    Event #02W,WALNUT CREEK
                   Sample Datetrime:              August 11, 1995
                   Sampler:                       R. W. Stallbaum



                      ME                          PARAMETER                   RUSULTS/                     ANALYST
                                                                                UNITS

                   10:25 AM- St I                 Dirtance                    18.69        ft                RWS
                               St2                froin bridge                19.03        ft                RWS
                               St 3               to                          19.27        ft                RWS
                               St 4               water mrface                19.18        ft                PIWS
                               St 8                                           19-15        ft                RWS
                   12:45PM     -St I              Distance                    18.08        ft                RWS
                               St 2               from bridge                 IS-70        ft                P-WS
                               St3                to                          18.77        fk                RWS
                               St4                water suface                10.67        ft                RWS
                               St 5                                           18.70        ft                RWS
                               sts                                            18.56        ft                RWS
                   14:45 PI.J. St I               Distance                    18.11        ft                RWS
                             -St2                 from bridge                 17.97        R                 RWS
                             - St 3               to                          18.01        ft                RWS
                             - St 4               water owface                18.03        ft                RWS
                             - St 5                                           17.94        ift               RWS
                               St. 7                                          18.52        ft                RWS
                               St 8                                           18.44        ft                RWS








                  .R0 ert W, S     aum, Jr.
                  President
                  RePotted: Aupat 24, 1995
                  Revised: Sept Is, 1996




             SEP-19-96 THU 02:19 PM CHURCH LnBORATORY, INC. 814 474 2044                                                                                              P.05




                                                                                                                                               (814) 474-2044
                                  CHURCH laboratory, inc.

                                                                                                                      7397 CHESTNUT STRCET - P.O.BOX83
                                                                                                                                              FAIRVIEW. PA. 10415







                                                                          Field Anal)ses Report


                     Customer:                       Malcolm Pirnic, Inc.
                                                     S. 3 515 Abbott Road
                                                     BuffAo, W 14219

                     P r oj c,.- t:                  Eric County Water Quahty Mordtoring Study
                                                     for Lake Brie Watershed                       #2759-01
                     Sample ID:                      Event #02W, ELK CREEK
                     Sample Date/Titne:              August 11, 1995
                     Sampler:                        &W. Stallbaum
                     Site Observations:              During rounds one " two the w2ter stayed clear. During round thsee the water was 0otly
                                                     turbid with what looked like algae.


                     TIME                            PARAAMTER                       RESULTS/                         ANALYST
                     11:00 AM                        PH                                   VNITS
                                                                                     713                                 RWS
                     13:30 FM                        PH                              8.3                                 RWS
                     15:15 PM                        P11                             8.4                                 RWS

                     12:00 AM                        Dissolved Oxygen                7,871      mgA                      RWS
                     ":,o PM                         Dissolved oxy8on                9.3        WS/1                     RWS
                     15:15 PM                        Dievolved oxygen                9.4        ing/l                    RWS
                     11:00 AM                        Teniperature                    22,2       0 C                      RWS
                     13:30 PM                        Temperature                     24A        OC                       RWS
                     15:15 PM                        Tempelature                     26.8       ac                       RWS

                     11:00 AM                        Conductivity                    469        usfcm                    RWS
                     13:30 PM                        Conductivity                    462        US/01n                   PIWS
                     15:15 PM                        Conductivity                    473        USICITI                  RWS
                     11:00 AM                        Velocity                        1.33       fps                      RWS
                     13:30 PM                        Velocity                        1.43       fps                      RWS
                     15:15 PM                        VelOcit3r                       1.63       fps                      RWS
                     *Result is  an BMW Of three trilds using sWp w8tch and oranges.



                     R
                      obert W. S batimm,
                       A@@
                     President
                     Reported; August 24, 1995
                     Revised:     Sept IS. 1996
                                                                          Pagel oF2








                                                                                                                                  (814) 474-2044
                             CHURCH laboratory, inc.

                                                                                                          7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                 FAIRVIEW, PA. 16415







                                                                    Water Anakyses Report



                    Customer:                     Malcohn Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                    Project:                      Ene County Water Quably Momtormg Study
                                                  for Lake Eric Watershed                #2758-01
                    Swnple ID:                    Event #03W, TWELVE NULE CREEK                                       Lab Log No: 51224
                    Sample Date/Time:             September 20, 1995/13:40PK 15:38PK 17:28PM
                    Sampler:                      N.A. Conaway

                    PARAMETER                      EPA                         RESULTS/                    ANALYSIS                 ANALYST
                                                  METHOD                         UNITS                          DATE


                    Antimony                       204.2                       <0.003    mg/l                09-28-95                     RJI
                    Arsenic                        206.2                       <0.001    mg/1                09-22-95                     RJI
                    Beryllium                      210.1                       <0.005    mg/l                09-26-95                     RE
                    Cadmium                        213.2                       <0.0001   mg/l                09-27-95                     RJI
                    Chromium, Total                218.1                       <0.05     M94                 09-21-95                     RJI
                    Chromium, VI                   218.4                       <0.01     mg/1                09-21-95                     RA
                    Copper                         220.2                       <0.001    Mg/l                09-27-95                     RJI
                    Lead                           239.2                       <0.001    MgA                 09-25-95                     RJI
                    Mercury                        245.1                       <0.0002   mg/l                09-29-95                     RE
                    Nickel                         249.1                       <0.01     149/1               09-21-95                     RJI
                    Selenium                       270.2                       <0.002    mg/1                09-26-95                     RJI
                    Silver                         272.2                       <0.0002   mg/l                09-27-95                     RJI
                    Thallium                       279.2                       <0.001    mg/1                09-26-95                     RE
                    Zinc                           289.1                       <0.005    mgA                 09-21-95                     RJI

                    Aluminum                       202.1                         0.31    mg/1                09-26-95                     RJI
                    Alkalinity                     310.1                         79      mg/l                09-25-95                     KW
                    Ammonia Nitrogen               350.1                       <0.01     mg/1                09-22-95                     LT
                    Fecal Coliform
                              Gmb@15:38PM          SM-16,909C                    1,150   col/100 ml          09-21-95                     LT
                    Hardness                       130.1                         186     mg/1                09-21-95                     KW
                    Iron                           236.1                         0.15    mg/1                09-21-95                     RJI
                    Manganese                      243.1                         0.04    mg/l                10-02-95                     RJI
                    Nitrite Nitrogen               353.2                         0.01    mg/l                09-26-95                     LT
                    Nitrate Nitrogen               353.2                         2.85    mg/l                09-26-95                     LT
                    Chloride                       325.2                         34      mg;1                09-26-95                     LT


                                                                             page 1 of 2




                            CHURCH laboratory, inc.                                                                          (814) 474-2044

                                                                                                      7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                           FAIRVIEW. PA. 16415







                    Water Analyses Report
                    Malcolm Pirnie, Inc.                                                                         Page 2 of 2

                    Project:                    Erie County Water Quality Monitoring Study
                                                for Lake Exie Watershed               #2758-01
                    Sample ID:                  Event #03W, TWELVE ABLE CREEK                                    Lab Log No: 51224
                    Sample Date/Time:           September 20, 1995/13:40PK 15:38PK 17:28PM
                    Sampler:                    N.A. Conaway


                    PARAMETER                    EPA                        RESULTSt                  ANALYSIS                 ANALYST
                                                METHOD                        UNITS                        DATE


                    CBOD,                        405.1                        7       mg/l              09-25-95                    KW
                    Total Suspended Solids       160.2                        4       M911              09-21-95                    KW
                    Phosphorus                   365.4                        0.01    Mg/l              09-21-95                    LT
                    COD                          410.4                      <10       M9/l              09-22-95                    NAC








                    RAobertW. Slum, Jr.
                    President


                    Reported: October 2, 199595








                                                                                                                                   (814) 474-2044
                             CHURCH laboratory, inc.

                                                                                                            7397 CHESTNUT STREET - P.0.80X83
                                                                                                                                  FAIRVIEW, PA. 16415






                                                                     Water Analyses Report




                     Customer:                    Malcohn Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitoring Study
                                                  for Lake Erie Watershed                  #2758-01
                     Sample ID:                   Event #03W. WALNUT CREEK                                              Lab Log No: 51225
                     Sample Date/Time:            September 20, 1995/13:40 PK 15:40PK 17:45PM
                     Sampler:                     R.W. Stallbaum

                     PARAMETER                      EPA                         RESULTS/                    ANALYSIS                  ANALYST
                                                  METHOD                          UNITS                          DATE


                     Antimony                       204.2                       <0.003     mg/1               09-28-95                      RJ1
                     Arsenic                        206.2                       <0.001     mg/l               09-22-95                      RJI
                     Beryllium                      210.1                       <0.005     mg/l               09-26-95                      RJI
                     Cadmium                        213.2                       <0.0001    mg/1               09-27-95                      RJI
                     Chromium, Total                218.1                       <0.05      mg11               09-21-95                      RJI
                     Chromium, VI                   218.4                       <0.01      mg/1               09-21-95                      NDA
                     Copper                         220.2                       <0.001     mg/1               09-27-95                      RE
                     Lead                           239.2                       <0.001     mg/1               09-25-95                      RE
                     Mercury                        245.1                       <0.0002    mg/l               09-29-95                      RJI
                     Nickel                         249.1                       <0.01      mg/1               09-21-95                      RJI
                     Selenium                       270.2                       <0.002     mg/l               09-26-95                      RE
                     Silver                         272.2                       <0.0002    mg1l               09-27-95                      RE
                     Thallium                       279.2                       <0.001     mg/l               09-26-95                      RJI
                     Zinc                           289.1                       <0.005     mg/l               09-21-95                      RE

                     Aluminum                       202.1                       <0. I      mg/l               09-26-95                      RJI
                     Alkalinity                     310.1                         104      mg/l               08-16-95                      KW
                     Ammonia Nitrogen               350.1                         0.05     Mg/1               08-18-95                      LT
                     Fecal Coliform
                               Grab@ 15:40 PM       SM-16,909C                    2,140    col/100 ml         09-21-95                      LT
                     Hardness                       130.1                         144      mg/l               09-21-95                      KW
                     Iron                           236.1                         0.13     mg/l               09-21-95                      RJI
                     Manganese                      243.1                         0.03     mg/l               10-02-95                      RJI
                     Nitrite Nitrogen               353.2                         0.02     mg/1               09-26-95                      LT
                     Nitrate Nitrogen               353.2                         0.70     mg/1               09-26-95                      LT
                     Chloride                       325.2                         42       m.&I               09-26-95                      LT

                                                                              page 1 of 2








                                                                                                                      (814) 474-2044
                           CHURCH laboratory, inc.

                                                                                                 7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                     FAIRVIEW, PA. 16415







                   Water Analyses Report
                   Malcolm Pirnie, Inc.                                                                     Page 2 of 2

                   Project:                   Erie County Water Quality Monitoring Study
                                              for Lake Erie Watershed             #2758-01
                   Sample ID:                 Event #03WWALNUT CREEK                                        Lab Log No: 51225
                   Sample Date/Time:          September 20, 1995/1340PK 15:40PK 17:45PM
                   Sampler:                   R. W. Stallbaum

                   PARAMETER                   EPA                       RESULTS/                 ANALYSIS               ANALYST
                                              METHOD                       UNITS                       DATE


                   CBOD,                       405.1                       5      11119/1          09-25-95                   KW
                   Total Suspended Solids      160.2                       4      M84              09-21-95                   KW
                   Phosphorus                  365.4                    <0.014    ing/l            09-21-95                   LT
                   COD                         410.4                       10     1119/1           09-22-95                   NAC





























                   R
                    @ert W.
                     ob@stal@sg tir
                   President


                   Reported: October2, 1995








                                                                                                                                  (814) 474-2044
                             CHURCH laboratory, inc.

                                                                                                          7397 CHESTNUT STREET - P.O@ BOX 83
                                                                                                                                FAIRVIEW, PA. 16415







                                                                    Water Analyses Report




                     Customer:                    Malcohn Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitoring Study
                                                  for Lake Erie Watershed                 #2758-01
                     Sample ID:                   Event #03W, ELK CREEK                                               Lab Log No: 51226
                     Sample Date/Tirne:           September 20, 1995/14:15PK 16:15PK 18:20PM
                     Sampler: -                   R. W. Stallbaumn

                     PARAMETER                     EPA                         RESULTS/                    ANALYSIS                  ANALYST
                                                  METHOD                          UNITS                         DATE


                     Anfimony                      204.2                       <0.003     mg/1               09-28-95                     RJI
                     Arsenic                       206.2                       <0.001     mg/1               09-22-95                     RA
                     Beryllium                     210.1                       <0.005     mg/1               09-26-95                     RII
                     Cadmium                       213.2                       <0.0001    mg/l               09-27-95                     RJI
                     Chromium, Total               218.1                       <0.05      mg/l               09-21-95                     RJI
                     Chromium, VI                  218.4                       <0.01      mg/1               09-21-95                     NDA
                     Copper                        220.2                       <0.001     mg/1               09-27-95                     RJI
                     Lead                          239.2                       <0.001     mg/1               09-25-95                     M
                     Mercury                       245.1                       <0.0002    mg/l               09-29-95                     RJI
                     Nickel                        249.1                       <0.01      M94                09-21-95                     RE
                     Selenium                      270.2                       <0.002     mg/1               09-26-95                     RJI
                     Silver                        272.2                       <0.0002    mg/l               09-27-95                     RJ1
                     Thallium                      279.2                       <0.001     mg/1               09-26-95                     RE
                     zinc                          289.1                       <0.005     Mg/l               09-21-95                     RJI

                     Aluminum                      202.1                       <0.1       mg/1               09-26-95                     RJI
                     Alkalinity                    310.1                          98      mg/1               09-25-95                     KW
                     Ammonia Nitrogen              350.1                          0.07    mg/1               09-22-95                     LT
                     Fecal Coliform
                               Grab@16:15PM        SM-16,909C                     290     col/100 ml         09-21-95                     LT
                     Hardness                      130.1                          222     mg/l               09-21-95                     KW
                     Iron                          236.1                          0.09    mg/1               09-21-95                     RJI
                     Manganese                     243.1                          0.03    mg/l               10-02-95                     RJI
                     Nitrite Nitrogen              353.2                          0.03    mg/l               09-26-95                     LT
                     Nitrate Nitrogen              353.2                          1.87    mg/l               09-26-95                     LT
                     Chloride                      325.2                          46      m9J                09-2&95                      LT


                                                                             page I of 2








                                                                                                                       (814) 474-2044
                          CHURCH laboratory, inc.                                                7397 CHESTNUT STREET o P.O. BOX 83
                                                                                                                     FAIRVIEW, PA. 16415







                  Water Analyses Report
                  Malcolm Pirnie, Inc.                                                                      Page 2 of 2

                  Project:                   Erie County Water Quality Monitoring Study
                                             for Lake Erie Watemhed              #2758-01
                  Sample ID:                 Event #03W, ELK CREEK                                          Lab Log No: 51226
                  Sample Date/Titne:         September 20, 1995/14:15PK 16:15PK 18:20PM
                  Sampler:                   R. W. Stallbaum

                  PARAMETER                    EPA                      RESULTS/                  ANALYSIS               ANALYST
                                             METHOD                       UNITS                       DATE


                  CBOD3                        405.1                      6      Jn9/1              09-16-95                  KW
                  Total Suspended Solids       160.2                      2      mg/l               09-16-95                  KW
                  Phosphorus                   365.4                      0.06   mg/I               09-21-95                  LT
                  COD                          410.4                      10     H19/1              09-22-95                  NAC










                  Robert W. Stallbawn, Akio@
                  President


                  Reported: October 2, 1995








                                                                                                                 (814) 474-2044
                         CHURCH laboratory, inc.

                                                                                             7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                FAIRVIEW, PA. 16415







                                                           Water Analyses Report




                  Customer:                Malcohn Pirnie, Inc.
                                           S. 3 515 Abbott Road
                                           Buffalo, NY 14219

                  Project:                 Erie County Water Quahty Monitonng Study
                                           for Lake Erie Watershed              #2758-01
                  Sample ID:               Event #03W, TRIP BLANK                                      Lab Log No: 51223
                  Sample Date/Time:        September 20, 1995
                  Sampler:                 N.A. Conaway

                  PARAMETER                  EPA                     RESULTS/                ANALYSIS               ANALYST
                                           METHOD                      UNITS                   DATE


                  Antimony                   204.2                   <0.003   mg/l             09-28-95                 RJI
                  Arsenic                    206.2                   <0.001   mg/l             09-22-95                 RJI
                  Beryllium                  210.1                   <0.005   mg/l             09-26-95                 RJI
                  Cadmium                    213.2                   <0.0001  mg/l             09-27-95                 RJI
                  Chromium, Total            218.1                   <0.05    mg/l             09-21-95                 RJ1
                  Chromium, VI               218.4                   <0.01    mg/l             09-21-95                 NDA
                  Copper                     220.2                   <0.001   mg/l             09-27-95                 RJI
                  Lead                       239.2                   <0.001   mg/l             09-25-95                 RE
                  Mercury                    245.1                   <0.0002  mg/l             09-29-95                 RJI
                  Nickel                     249.1                   <0.01    mg/l             09-21-95                 RJI
                  Selenium                   270.2                   <0.002   mg/1             09-26-95                 RJI
                  Silver                     272.2                   <0.0002  mg/l             09-27-95                 RJI
                  Thallium                   279.2                   <0.001   mg/l             09-26-95                 RE
                  zinc                       289.1                   <0.005   mg/l             09-21-95                 RJI

                  Aluminum                   202.1                   <0.1     mg/1             09-26-95                 RJI
                  Alkalinity                 310.1                   <0.02    mg/1             09-25-95                 KW
                  Ammonia Nitrogen           350.1                   <0.01    mg/l             09-22-95                 LT
                  Fecal Coliform             SM-16,909C                0      col/I 00 ml      09-21-95                 LT
                  Hardness                   130.1                     2      mg/l             09-21-95                 KW
                  Iron                       236.1                   <0.03    mg/l             09-21-95                 RJI
                  Manganese                  243.1                   <0.01    mg/l             10-02-95                 RE
                  Nitrite Nitrogen           353.2                   <0.01    mg/l             09-26-95                 LT
                  Nitrate Nitrogen           353.2                   <0.01    mg/l             09-26-95                 LT
                  Chloride                   325.2                   <2       mg;1             09-26-95                 LT


                                                                   page I of 2








                                                                                                               (814) 474-2044
                         CHURCH laboratory, inc.

                                                                                           7397 CHESTNUT STREET       P.O. BOX 83
                                                                                                              FAIRVIEW, PA. 16415







                  Water Analyses Report
                  Malcolm Pinfie, Inc.                                                               Page 2 of 2

                  Project:                Ene County Water Quality Momtormg Study
                                          for Lake Eric Watershed           #2758-01
                  Sample ID:              Event #03W, TRIP BLANK                                     Lab Log No: 51223
                  Sample Date/Time:       September 20, 1995
                  Sampler:                N.A. Conaway

                  PARAMETER                 EPA                    RESULTS/                ANALYSIS              ANALYST
                                          METHOD                     UNITS                   DATE


                  CBOD3                     405.1                    2       Mg/l           09-25-95                  KW
                  Total Suspended Solids    160.2                    2       Mg/l           08-21-95                  KW
                  Phosphorus                365.4                  <0.01     mg/l           08-21-95                  LT
                  COD                       410.4                  <10       Mg/l           08-22-95                  NAC






























                  Robert W. Stallbauumn, Jr.
                  President


                  Reported: October 2, 1995




           SEP-19-96 THU 02:22 PM CHURCH LABORATORY, INC. 814 474 2044                                                                            P.12


                              CHURCHIaboratory, inc.                                                                         (814) 474-2044

                                                                                                       7007 QHEï¿½TNVT 5TR9f;T - P,O. JJ0X 03
                                                                                                                            PAIR VIEW, PA. 184 15





 IL

                                                                 Field Anitlyses Report


                   Customer:                   Malcobn Miic, Inc.
                                               S, 3 515 Abbott Road
                                               Buffalo, NY 14219

                   Project:                    Elio CountY Water Quality Monitoring Study
                                               for Lako Eric Watershed                 #2758-01
                   Sample ID;                  Event #03W, IRVELVE MILE CREEK
                   Sample Date/Time:           September 20, 1995
                   Sampler:                    N.A. Conaway


                   TIME                        PAPLAMETER                 RMULTS/                      ANALYST
                                                                              UNITS
                   13:40 PM                    VH                         8.2                            NAC
                   15:38 PM                    pH                         8.2                            NAC
                   17"23 FM                    PH                         8.2                            NAC
                   13:40 FM                    Movolved Oxygm             4.6          ing/l             NAC
                   15:33 FM                    Moohred Oxygen             4.63         Ine               NAC
                   17:28 PM                    Mssohred Oxygen            4.47         M84               NAC
                   11:40 FM                    Temperature                15.6         0C                NAC
                   15:38 FM                    Temperature                15.7         C                 NAC
                   17:28 FM                    Temperature                16           C                 NAC
                   13:40 PM                    Conduo6vity                417          uskm              NAC.
                   15:38 PM                    Conductivity               434          USIOM             NAC
                   17:28 FM                    Conductivity               428          us/em             NAC
                   13:40 PM                    Velocity *                 0.84         fps               NAC
                   15:38 PM                    Velocity *                 0.78         fps               NAC
                   17:28 PM                    Velocity -                 0.58         fps               NAC
                   13:40 PM                    Depth                      O@75         ft                NAC
                   15:38 PM                    Depth                      0.75         ft                NAC
                   17-28 PM                    Dvpth                      0.57         ft                NAC
                   *Remlt is an Mrs9e Ofthree bials wing gtopA%tC)1 ond orw4es,


                   Robert W. stallbaum, Jr.
                       @M





























                   President    aba=, Jr.
                   Reported- October 2, 1995
                   Revissed: Sept 18, 1996




            SEP-19-96 THU 02:21 I'M CHURCH LABORATORY, INC. 814 474 2044                                                                                              P.11a




                                                                                                                                               (814) 474-2044
                                 CHURCH laboratory,                                 inc.

                                                                                                                     '1327 CHESTNUT STREET I P.O. BOX 53
                                                                                                                                             FAIRVIEW. PA. 10415









                                                                         Field Analyses Report



                     Customer:                       Malcohn Pirnie, Inc.
                                                     S. 3515 Abbott Road
                                                     Buftalo, NTY 14219

                     Projmt:                         Erie County Water Quality Monitoring Study
                                                     for Lake Erie Watershed                      #2758-01
                     Sample, ID:                     Event #03W, WALNUT CREEK
                     Sample Date/Timo:               September 20, 1995
                     Sampler:                        R. W. Stallbaum



                     TIME                            PARAMETER                      MULTS/                           ANALYST
                                                                                       UNITS
                     13.40 PM                        PH                             8.05                                RWS
                     15:40 PM                        PH                             8.23                                Rws
                     17:45 PM                        PH                             8.29                                RIVS
                     13:40 PM                        Wwlved Oxygen                  10.2          mSA                   RWS
                     15.40 PM                        Dissolved Oxygen               10.4          Pisa                  RWS
                     17:45 PM                        Dissolved oxygen               13.2          rno                   RWS
                     13;40 PM                        Temperatwe                     15.7            C                   RwS
                                                                                                  .r
                     15;40 PM                        Tempentae                      16.1                                Rws
                     17:45 PM                        Temp"ture                      16.3          cc                    RWS
                     13:40 PM                        Conductivity                   44.1          us/cm                RwS
                     15:40 PM                        Conductivity                   476           US/=                 RWS
                     11,45 PM                        Conductivit3t                  5424          USIC111              RWS
                     15;40 PM                        Velocity *                     1.72          f@a                  RVS
                     15:40 PM                        Velocity *                     2.24          f@s                  RWS
                     17:45 PM                        Velocity 0                     2.46          los                  RWS
                     *Result is an ayelage Ofor" t"W8 Ugitlg StOP WfItCh 2nd 0fqjjge$.




                                                                                    page I of 2




      SEP-19-96 THU 02:22 PM CHURCH LABORATORY, INC. 814 474 2044         P.11




                                                                (814) 474-2044
               CHURCH laboratory, inc.

                                                     7390? CHESTNUT STREET - P.O.BOX83
                                                               FAIRVIEW. PA. 10415









         Field Analyses Report
         Malwhn Pirrie, Inc.                             Page 2 of 2

         Project:       Eirie County Water Quality h1ordtofing Study
                        for Lake Eric Watershed 42758-01
         Sample H):     E-v=t #03WWALNUT CREEK
         Sample, Date/Time: September 20, 1995
         Sampler        R. W. Stallbaum



         TIME           PARAMETER     RESULTS/       ANALYST
                                       UNITS

         11:40 PM, S, I Digalice      19.18 ft       RWS
              -St2      from bridge   19.31 ft       RWS
              - St 3    to            19.56 ft       RWS
              - St 4    water jn=face 19.53 R        RWS

         15:40 PM- St I Distanoe      19.14 R        RWS
              - St 2    &m bndge      19-26 R        RV8
              -St3      to            19.51 R        RWS
              -St4      water owfacs  19,50 ft       RWS
         17:45 AM- St I Diswme        19,23 ft       RIA'S
               St 2     fiom bridge   19,30 R        RWS
               St 3     to            19-159 ft      RWS
              -St4      water swface, 19.53 R        RWS









        Ro eit W, Stall 11m, Jr.
        President
        A






         0(e@i t w @St a I I /MJ,*
        Repojiv& October2,1995
        Revised: Sept IS, 1996




            SEP-19-96 THU 02:21 PM CHURCH LABORATORY, INC. 814 474 2044




                                                                                                                                   (814) 474-2044
                               CHURCH laboratory,                             inc.

                                                                                                            7397 CHESTNUT STRGET I P-O BOX 53
                                                                                                                                  FAIRVIr;W. PA. 18415








                                                                    Field Analyses Report


                    Customer:                    Xlalcohn Pimie, Inc.
                                                 S. 3 515 Abbott Road
                                                 Buffalo, NY 14219

                    Project:                     Elie County Water Quality Monitoring Stu4
                                                 for Lake Me Watershed                    #2758-01
                    Sample ID:                   Event #03AV, ELK CREEK
                    Sample Date/Time:            September 20, 1995
                    Sampler:                     R.W. Stallbawn



                    TIME                         PARAMETER                    RESULTS]                     ANALYST
                                                                                  UMTS
                    14:15 P11                    PH                           8,2                             RNVS
                    16:15 PM                     pH                           8.1                             RWS
                    18:20 PM                     PH                           8.1                             RWS
                    14:15 PM                     Diesolved Oxygen             11A      mo                     RNVS
                    16:15 PM                     Dioeolved Cb.,)-gen          11.2     mg/1                   RAIS
                    18:20 FM                     Woolved Oxygen               14.5     mio                    RNVS
                    14:15 PM                     Temperabm                    169      'C                     RwS
                    16,13 PM                     Temperature                  17.1     a C                    RWS
                    18:20 PM                     Temperature                  17.3     *C                     RWS
                    14:15 PM                     Conducti%ity                 544      USIVCM                 RWS
                    16:15 PM                     Condwtivi@r                  536      us/on                  RWS
                    18:20 PM                     conducti-vity                551      us/cm                  RWS
                    14:15 PM                     WlOcit3r *                   0.94     fp@                    RWS
                    16:15 PM                     Volor
                                                     'ity *                   1.08     fps                    RWS
                    18:20 PM                     Velocity *                   1.04     fps                    RWS
                    Result is an average Oftluee tri8h using stop watch and orangeo.




                       9tt W. Stallbaum, Jr.
                  President
                  R@Oert W;st.

                  Reported., October 2, 1995
                  Regived: Sept 18,1996








                                                                                                                                            (814) 474-2044
                               CHURCH laboratory, inc.

                                                                                                                   7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                           FAIRVIEW, PA. 16415







                                                                         Water Analyses Report




                      Customer:                       Malcolm Phiie, Inc.
                                                      S. 3515 Abbott Road
                                                      Buffalo, NY 14219

                      Project:                        Ene County Water Quality Monitoring Study
                                                      for Lake Erie Watershed                   #2758-01
                      Sample ID:                      Event #04D, TWELVE XHLE CREEK                                            Lab Log No: 51449
                      Sample Date/Time:               October 3, 1995/ 07:30AK 09:30AK 11:33AM
                      Sampler:                        N.A. Conaway

                      PARAMETER                        EPA                           RESULTS/                      ANALYSIS                    ANALYST
                                                      METHOD                            UNITS                            DATE


                      Arsenic                          206.2                         <0.001     Mg/l                 10-11-95                        RJI
                      Cadmium                          213.2                         <0.0001    m&4                  10-12-95                        RJI
                      Chromium, Total                  218.1                         <0.05      mg/l                 10-05-95                        RJI
                      Copper                           220.2                            0.001   mg/l                 10-06-95                        RJI
                      Lead                             239.2                         <0.001     mg/l                 10-03-95                        RJ1
                      Nickel                           249.1                            0.02    mg1l                 10-06-95                        RJI
                      Silver                           272.2                         <0.0002    mg1l                 10-11-95                        RJI
                      Zinc                             289.1                         <0.005     mg/l                 10-06-95                        RJ1

                      Aluminurn                        202.1                         <0. 1      M&4                  10-11-95                        RJI
                      Alkalinity                       310.1                            88      mg/l                 10-06-95                        KW
                      Ammonia Nitrogen                 350.1                         <0.01      m&4                  10-03-95                        LT
                      Fecal Coliform
                                Omb@09:30AM            SM-16,909C                       29      col/100 ml           10-04-95                        LT
                      Hardness                         130.1                            198     mg/l                 10-03-95                        KW
                      Iron                             236.1                         <0.03      mg/l                 10-06-95                        RJI
                      Manganese                        243.1                            0.01    mg/l                 10-12-95                        RJI
                      Nitrite Nitrogen                 353.2                         <0.01      rng/l                10-10-95                        LT
                      Nitrate Nitrogen                 353.2                            1.95    mg/l                 10-10-95                        LT
                      Chloride                         325.2                            40      mg;l                 10-06-95                        LT
                      CBOD,                            405.1                            2       mg,/l                10-09-95                        KW
                      Total Suspended Solids           160.2                            2       mg/l                 10-05-95                        KW
                      Phosphorus                       365.4                         <0.01      M911                 10-04-95                        LT
                      COD                              410.4                         <10        1111911              10-11-95                        NDA


                      R e W.S            aum, Jr.
                 AA











                                   Sta@@410*4
                          ert @W               Jr.
                      President


                      Reported: October 16,1995








                                                                                                                                  (814) 474-2044
                             CHURCH laboratory, inc.

                                                                                                          7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                FAIRVIEW, PA. 16415







                                                                    Water Analyses Report



                     Customer:                    Malcohn Pinfie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitoring Study
                                                  for Lake Erie Watershed                 #275"1
                     Sample ID:                   Event #04D, WALNUT CREEK                                            Lab Log No: 51450
                     Sample Date/Tinte:           October 3, 1995/ 07:45AK 09:50AK 11:50AM
                     Sampler:                     R.W. Stallbaum

                     PARAMETER                     EPA                            RESULTS/                 ANALYSIS                  ANALYST
                                                  METHOD                          UNITS                         DATE


                     Arsenic                       206.2                          <0.001  M94                10-11-95                     RA
                     Cadmium                       213.2                          <0.0001 mgn                10-12-95                     RR
                     Chromium, Total               218.1                          <0.05   m&4                10-05-95                     RJI
                     Copper                        220.2                          <0.001  M&4                10-06-95                     RJI
                     Lead                          239.2                          <0.001  mg/l               10-03-95                     RJI
                     Nickel                        249.1                          0.01    Mg/1               10-06-95                     RJI
                     Silver                        272.2                          <0.0002 mg/l               10-11-95                     RJI
                     zinc                          289.1                          <0.005  mg/l               10-06-95                     RJI

                     Aluminum                      202.1                          <0.1    mg/1               10-11-95                     RJI
                     Alkalinity                    310.1                          122     mg/l               10-06-95                     KW
                     Ammonia Nitrogen              350.1                          0.02    m&4                10-03-95                     LT
                     Fecal Coliform
                              Grab@09:50AM         SM-16,909C                     45      col/100 ml         10-04-95                     LT
                     Hardness                      130.1                          .220    mg/1               10-03-95                     KW
                     Iron                          236.1                          <0.03   mg/l               10-06-95                     RE
                     Manganese                     243.1                          0.02    mg/l               10-12-95                     RJI
                     Nitrite Nitrogen              353.2                          <0.01   mg/l               10-10-95                     LT
                     Nit-ate Nitrogen              353.2                          0.10    mg4                10-10-95                     LT
                     Chloride                      325.2                          51      mg;'I              10-06-95                     LT
                     CBOD,                         405.1                          2       mg/l               10-09-95                     KW
                     Total Suspended Solids        160.2                          4       mg/l               10-05-95                     KW
                     Phosph To--'                  365.4                          <0.01   M94                10-04-95                     LT
                     COD                           410.4                          <10     mg/l               10-11-95                     NDA


                     R
                         ert W. S     aum, Jr.
                      o A449@@
                     President


                     Reported: October 16, 1995




                             CHURCH laboratory, inc.                                                                              (814) 474-2044

                                                                                                           7397 CHESTNUT STREET . P.O. BOX 83
                                                                                                                                 FAIRVI EW, PA. 16415






                                                                    Water Analyses Report




                     Customer:-                   Malcolm. Pfimie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quahty Monitoring Study
                                                  for Lake Erie Watershed                 #2758-01
                     Swnple ID:                   Event #04D, ELK CREEK                                               Lab Log No: 51451
                     Sample Date/Time:            October 3, 1995/ 08:15AK 10:20AK 12:20PM
                     Sampler:                     K W. Stallbaurn

                     PARAMETER                     EPA                            RESULTS/                 ANALYSIS                  ANALYST
                                                  METHOD                          UNITS                         DATE


                     Arsenic                       206.2                          <0.001  Mg/l               10-11-95                     RE
                     Cadmium                       213.2                          <0.0001 m&4                10-12-95                     RJI
                     Chromium, Total               218.1                          <0.05   mg/l               10-05-95                     RJI
                     Copper                        220.2                          <0.001  M&4                10-06-95                     RJI
                     Lead                          239.2                          <0.001  mg/l               10-03-95                     RJI
                     Nickel                        249.1                          0.01    mg/l               10-06-95                     RJI
                     Silver                        272.2                          <0.0002 mg/l               10-11-95                     RJI
                     Zinc                          289.1                          <0.005  m&4                10-06-95                     RJI

                     Aluminum                      202.1                          <0.1    mg/I               10-11-95                     RJI
                     Alkalinity                    310.1                          108     mg/l               10-06-95                     KW
                     Ammonia Nitrogen              350.1                          0.11    mg/l               10-03-95                     LT
                     Fecal Coliform
                              Grab@10:20AM         SM-16,909C                     12      col/100 ml         10-04-95                     LT
                     Hardness                      130.1                          226     mg/l               10-03-95                     KW
                     Iron                          236.1                          0.06    mg/l               10-06-95                     RJI
                     Manganese                     243.1                          0.03    mg/l               10-12-95                     RJI
                     Nitrite Nitrogen              353.2                          0.01    mg/l               10-10-95                     LT
                     Nitrate Nitrogen              353.2                          2.40    mg/l               10-10-95                     LT
                     Chloride                      325.2                          51      mg;l               10-06-95                     LT
                     CBOD,                         405.1                          2       mg/l               10-09-95                     KW
                     Total Suspended Solids        160.2                          2       mg/l               10-05-95                     KW
                     Ph  sp ho                     365.4                          0.08    mg/I               10-04-95                     LT
                       "o
                     COD                           410.4                          <10     Ing/I              10-11-95                     NDA


                                            Jr
                     Robert W. Stan aurn, Jr.
                     President


                     Reported. October 16, 1995








                                                                                                                                 (814) 474-2044
                            CHURCH laboratory, inc.

                                                                                                          7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                FAIRVIEW, PA. 16415







                                                                    Water Analyses Report




                    Customer:                     Malcolm. Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                    Project:                      Ene County Water Quality Monitoring Study
                                                  for Like Erie Watershed                #275M1
                    Sample H):                    Event #04D, TRIP BLANK                                              No: 51448
                    Sample Date/Time:             October 3, 1995
                    Sampler:                      N.A. Conaway


                    PARAMETER                      EPA                         RESULTS/                   ANALYSIS                  ANALYST
                                                  METHOD                         UNITS                          DATE


                    Arsenic                        206.2                       <0.001    mg4                10-11-95                      RA
                    Cadmium                        213.2                       <0.0001   m8a                10-12-95                      RJI
                    Chromium, Total                218.1                       <0.05     mg/l               10-05-95                      RJI
                    Copper                         220.2                         0.001   mg/1               10-06-95                      RJI
                    Lead                           239.2                       <0.001    mg/l               10-03-95                      RJI
                    Nickel                         249.1                       < 0.01    mg/l               10-06-95                      RJI
                    Silver                         272.2                       <0.0002   mg/l               10-11-95                      RE
                    Zinc                           289.1                       <0.005    mg/l               10-06-95                      RJI

                    Aluminum                       202.1                       <01       mg/l               10-11-95                      RJI
                    Alkalinity                     310.1                       <0.02     mg/l               10-06-95                      KW
                    Ammonia Nitrogen               350.1                       <0.01     mg/l               10-03-95                      LT
                    Fecal Coliform                 SM-16,909C                    0       col/ 100 ml        10-04-95                      LT
                    Hardness                       130.1                       <2        mg/1               10-03-95                      KW
                    Iron                           236.1                       <0.031    mg/1               10-06-95                      RJI
                    Mwiganese                      243.1                       <0.014    mg/1               10-12-95                      RE
                    Nitrite Nitrogen               353.2                       < 0.01    mg/l               10-10-95                      LT
                    Nitrute Nitrogen               353.2                       <0.01     mg/l               10-10-95                      LT
                    Cldoride                       325.2                       <2        mg;1               10-06-95                      LT
                    CBOD,                          405.1                       <2        Mg/l               10-09-95                      KW
                    Total Suspended Solids         160.2                       <2        mg/1               10-05-95                      KW
                    Phosphorus                     365.4                       <0.01     mg/1               10-04-95                      LT
                    COD                            410.4                       <10       mg/l               10-11-95                      NDA
                            4i;
                                46.    -OA
                    Robert W. Stallbaum, Jr.
                    President


                    Reported: October 16, 1995




                                                                                                     P. 05
       SEP-19-96 THU 02:41 PM CHURCH LABORATORY, INC. _g.44 474 2044

                     CHURCH laboratory, inc.                                             (814) 474-2044

                                                                         7397 CHESTNUT STREET - P.O.E10)(83
                                                                                        FAIRVIEW, PA. 10416






                                              Field Analyses Report


              Customer-,         Malcolm PirWe, Inc.
                                 S. 3515 Abbott Road
                                 Buffalo, NY 14219

              Project:           Erie County Water Quality Monitoring Study
                                 for Like Erie Watershed     #2738-01
              Sample ID.         Event #04D, TWELVE XULE CREEK
              Sample. Date/The:  October 3, 1995
              Sampler:           N.A. Conaway




              TIME               PARAMETER           RESULTS/            ANALYST
                                                      UNITS
              07:30 AM           PH                  8.3                  NAC
              09:30 AM           P11                 8.2                  NAC
              11:33AM            PH                  8.2                  NAC

              07:30 AM           Dissolved oxygen    6.67    mg4          NAC
              09:30 AM           Dissolved oxygen    6.72    In4          NAC
              11:33 AM           Disbolved OX)wn     6.75    me           NAC

              07.30 AM           Tempmtm             13.3      C
              0930 AM            Temperature         13.9    oc           NAC
              11.33 AM           Tempemtue           13.9    be           NAC
                                                                          NAC
              07:30 AM           Conductivity        487     us@cln       N4C
              09:30 AM           Conductivity        481     13SIcnk      NAC
              11:33 AM           Conductivity        489     uslem        NAC
              07:30 AM           Velocity            0.22                 NAC
              09:30 AM           Velocity
              1133 AM            Velocity            0.21                 NAC
                                                     0.21    fps          NAC
              07:30 AM           Depth               0.42    ft           NAC
              0930 AM            Depth               0.42    ft           NAC
              11., 3             Dept)i              0.42
              *Res w average qf2iee triab UsIng stop Watch and oranses,   NAC

                eft W. 5 um, Jr.
              A3                 D p1ju
              *R      av ge      Z

                             Jr.
              Pregident
              Reported: October 1,5, 1995
              Revised; Sept 18, 199.6




                                                                                                                                                         P. 03
           SEP-19-96 THU 02:40 PM CHURCH LABORATORY, INC...,81-4 474 2044

                                 CHURCH laboratory, inc,                                                                              (81 4@ 474-2044

                                                                                                              7397 CHESTNOT STREET - P.Q,8GX63
                                                                                                                                     FAIRVIEW, PA. 16415






                                                                      Field Analyses Report



                     Customer:                     Malwhn Pimie, Inc.
                                                   S. 3515 Abbon Road
                                                   Buffalo, NY 14219

                     Project:                      Erie County Water Qwfily Monitoring Study
                                                   for Lake Eric watershed                  #2758-01
                     Sample ID:                    EVent #04D, WALNUT CREE X
                     Sample Datcaime:              October 3, 1995
                     SafnPlef:                     R. W. Staftbauni




                     TIME                          PARAMETER                    RZSVLTS/                      ANALYST
                                                                                    UNITS
                     07:45 AM                      pH                           83                               RWS
                     09;50 AM                      PH                           8.3                              RWS
                     11:50 AAI                     PH                           8.4                              RWS

                     07:45 AM                      Dimlyed Oxygen               10115       111VI                RWS
                     09:50 AM                      Dissolved 0)qgen             9.6         mg/1                 RWS
                     11:50 AM                      Dmolved OXY8031              10.1        Inga                 PIWS

                     0745 AM                       Temperatmv                   13.7        mc
                     09:50 AM                      Tempemtm                     13.3        0 C                  RWS
                     11!55 AM                      Tempmturc                    13.9        0 C                  RWS
                                                                                                                 RWS
                     07:45 AM                      Conductivity                 562         US/=                 RWS
                     0:50 AM                       Conduc&4                     560         uslem                k%VS
                     11:50 AM                      Conducti-,*                  $54         uls/om               RWS
                     07:45 AM                      VelQcity *                   1.72        fps                  RWS
                     09:50 AM                      Velocity *                   1.2         fps                  RWS
                     11:50 AM                      Velocity *                   1.25        fps                  RWS
                     *P'*Fu" is an average of ft*e tlials usiAS IrtcP watch and oranges,




                                                                              Page I of2




                                                                                                                                                                           P
            SEP-19-         96 THU 02:40 PM CHURCH LABORATORY, INC. eLI!4- 474 2044-                                                                                          .04

                                     CHURCHIaborc-                                                                                                     (8141474-2044
                                                                          itory, inc.

                                                                                                                            ':3Q7GWE6TNVTF,TFIEET 0 P-O-50X63
                                                                                                                                                     FAIRVIEW, PA 18415






                        Field Analyses Report
                        Malcolm Pirnle, Inc.                                                                                          Page 2 of 2

                        Project:                        Erie County Water Quality Molfitoring Study
                                                        for Lake Brie Watershed                        #2758-01
                        Sample ID:                      Event #04D,I#VALNUT CREEK
                        SOMP10 DaWTime:                 Octobet 3, 1995
                        Sampler:                        K W. Stabaum




                                                        PARAMETER                         RESULTS/                         ANALYST
                                                                                            UNITS

                        07:45 AM- St 1                  Digtance                          19-31        ift                   RWS
                                     St2                  fiom bridge                     19.38        ft                    RWS
                                     St 3                 to                              19.49        ft                    RWS
                                     St 4                 water surface                   19.56        R                     RWS


                        09:30 AM- St I                  DiAmce                            19.29        ft                    RWS
                                   -St2                   from bridge                     19-35        ft                    RWS
                                     St 3                 to                              19-48        R                     RWS
                                     St 4                 WOW ourⅇ                      19.53        ft                    RW5

                        11:50 AM- St I                  Distance                          19-29        ft                    RIVS
                                   - St 2                 frm bridge                      19.37        R                     RWS
                                   - St 3                 to                              19,49        it                    RWS
                                   - St 4                 water surface                   19.52        A                     RWS













                      R        W. St belum, Jr,
                      President
                             @m
                      49







                        '6e@n W @.Sta ez--- @J'.

                      Repoiled: October 16,1995
                      Reviyed: Sepf is, 1996



                                                                                                                                                         P. 02
           SEP-19-96 THU 02:39 PM CHURCH LABORATORY, INC                                                .._P14-474            2044



                                                                                                                                       (814) 474-2044
                                 CHURCHIaboratory,                               inc.

                                                                                                               7397CHESTNUTSTRFET              P0.GOX@$
                                                                                                                                     FAIRVIEW, PA. 115415






                                                                      Field Anal)ses Report


                     Customer:                     Afalcohn Pirrde, Inc,
                                                   S. 3 515 Abbott Road
                                                   Buffalo, NY 14219

                     Project:                      Eric County Water Quality Nionitoring Study
                                                   for Lake Efie Watershed                   #2758-01
                     Sple ID:                      Event #04D, ELK CREEK
                     Sample Date/Time:             October 3, 1995
                     Sampler:                      R.W. Stallbaunt



                     TIME                          PARA-METER                    MULTS/                       ANALYST
                                                                                    UNITS
                     08:15AM                       P14                           s,2                             RwS
                     10:20 AM                      pff                           8.2                             RWS
                     12:20 PNf                     PH                            93                              Rws

                     08; 15 AM                     DiSSOlVed Oxygen              9.8      MR11                   RWS
                     10:20AM                       Dissolved Oxygen              10.2     ine                    RWS
                     12:20 PM                      Dissolved Ox@sen              10.4     Ingil                  RWS

                     08:15 AM                      Temperature                   1412       C                    RWS
                     10:20 AM                      Temperature                   15         C                    RwS
                     12:20 PM                      Temperature                   15.3     OC                     RWS

                     DS; 15 AM                     Conductivity                  606      us/cm                  RwS
                     10:20 AM                      Conductivity                  600      US&M                   RWS
                     12:20 PM                      Conductivity                  587      us/cm                  RIVS

                     08:15AM                       Velocity                      0.73     fps                    RWS
                     10:20 AM                      Velocity                      0.72     fps                    RWS
                     12:20 PM                      'Velocity                     0,72     f@r.                   RWS
                     *Result is an averqe offtes triab using gtop watch and oranges.
                     08:15 AM                      Deptli                        1.93     ft                     RWS
                     10:20 AM                      Deptit                        1.94     ft                     RWS
                     12:20 P                       DeA                           1.92     ft                     RWS
                     Ro ed W. 8 - Aauijr, tF
                   @9
































































                       "0 P
                       )@ell awste.

                     Reported: October 16, 995
                     Revised. sept is, 1996








                                                                                                                     (814) 474-2044
                          CHURCH laboratory, inc.

                                                                                                7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                    FAIRVIEW, PA. 16415







                                                             Water Analyses Report




                  Customer:                  Malcolm Phiie, Inc.
                                             S. 3515 Abbott Road
                                             Buffalo, NY 14219

                  Project:                   Ene County Water Quality Monitoring Study
                                             for Lake Exie Watershed             #2758-01
                  Swnple ID:                 Event #05W, TWELVE ABLE CREEK                                Lab Log No: 51489
                  Sample Date/Time:          October 5, 1995/ 16:40PNt 18:30PNt 20:30PNt 22:30PM
                  Sampler:                   N.A. Conaway


                  PARAMETER                   EPA                      RESULTS/                 ANALYSIS                ANALYST
                                             METHOD                      UNITS                       DATE


                  Arsenic                     206.2                    <0.001    mg/I             10-11-95                  RJI
                  Cadmium                     213.2                    <0.0001   mg/1             10-12-95                  RE
                  Chromium, Total             218.1                    <0.05     mg`4             10-12-95                  RJI
                  Copper                      220.2                      0.002   mg/l             10-09-95                  RJI
                  Lead                        239.2                      0.001   mg/I             10-09-95                  RJI
                  Nickel                      249.1                    <0.01     mg/1             10-06-95                  RJI
                  Silver                      272.2                    <0.0002   mg/I             10-11-95                  RJI
                  zinc                        289.1                    <0.005    mg/l             10-06-95                  RJI

                  Aluminum                    202.1                      0.59    mg/l             10-11-95                  RJI
                  Alkalinity                  310.1                      53      mg/1             10-06-95                  KW
                  Ammonia Nitrogen            350.1                      0.02    me               10-12-95                  LT
                  Fecal Coliform
                           Grab@18:30PM       SM-16,909C                 940     col/100 ml       10-07-95                  LT
                  Hardness                    130.1                      164     mg/l             10-06-95                  KW
                  Iron                        236.1                      3.14    mg/I             10-12-95                  RE
                  Manganese                   243.1                      0.49    mg/I             10-12-95                  RJI
                  Nitrite Nitrogen            353.2                    <0.01     mg/l             10-10-95                  LT
                  Nitrate Nitrogen            353.2                      1.37    mg/l             10-10-95                  LT
                  Chloride                    325.2                      37      M&I              10-06-95                  LT
                  CBOD,                       405.1                      11      mg/I             10-11-95                  KW
                  Total Suspended Solids      160.2                      198     mg/1             10-12-95                  KW
                  Phosphorus                  365.4                      0.34    mg/I             10-09-95                  LT
                  COD/"                       410.4                      30      mg/1             10-11-95                  NDA


                  R      W. S     aum, Jr.
                         WAS     baum- @Jr
                  President
                  Reported: October 16,1995








                                                                                                                                    (814) 474-2044
                              CHURCH laboratory, inc.

                                                                                                            7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                   FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                      Customer:                    Malcolm Pirnie, Inc.
                                                   S. 3515 Abbott Road
                                                   Buffalo, NY 14219

                      Project:                     Ene County Water Quality Monitoring Study
                                                   for Lake Erie Watershed                 #2758-01
                      Sample ID:                   Event #05W, WALNUT CREEK                                             Lab Log No: 51490
                      Sample Date/Time:            October 5, 1995/ 17:05PK 19:15PK 21:20PK 23: 1OPM
                      Sampler:                     R.W. Stallbaurn


                      PARAMETER                      EPA                         RESULTS/                    ANALYSIS                  ANALYST
                                                   METHOD                          UNITS                          DATE


                      Arsenic                        206.2                         0.002   mg/l                10-11-95                      RJI
                      Cadmium                        213.2                       <0.0001   mg/l                10-12-95                      RE
                      Chromium, Total                218.1                       <0.05     mg/l                10-12-95                      RE
                      Copper                         220.2                         0.008   mg/l                10-09-95                      RJI
                      Lead                           239.2                         0.014   mg/l                10-09-95                      RJI
                      Nickel                         249.1                       <0.01     mg/l                10-06-95                      RJI
                      Silver                         272.2                       <0.0002   mg/l                10-11-95                      RJI
                      Zinc                           289.1                       <0.005    mg/l                10-06-95                      RE

                      Aluminum                       202.1                       <0. I     mg/l                10-11-95                      RJI
                      Alkalinity                     310.1                         122     mg/l                10-06-95                      KW
                      Ammonia Nitrogen               350.1                         0.02    mg/l                10-12-95                      LT
                      Fecal Coliform
                               Grab@19:15PM          SM-16,909C                    2940    col/100 ml          10-07-95                      LT
                      Hardness                       130.1                         144     mg/l                10-06-95                      KW
                      Iron                           236.1                         14.40   mg/l                10-12-95                      RJI
                      Manganese                      243.1                         0.80    mg/l                10-12-95                      RJI
                      Nitrite Nitrogen               353.2                         0.05    mg/l                10-10-95                      LT
                      Nitrate Nitrogen               353.2                         0.56    mg/l                10-10-95                      LT
                      Chloride                       325.2                         37      mg;l                10-06-95                      LT
                      CBOD,                          405.1                         10      mg/l                10-11-95                      KW
                      Total Suspended Solids         160.2                         892     mg/l                10-12-95                      KW
                      Phosphorus                     365.4                         1.08    mg/l                10-09-95                      LT
                      COD                            410.4                         50      mg/l                10-11-95                      NDA
                                                     410A




                                                   Jr
                                      b ^ni,
                      Ro       W. S         aum,
                      President
                      Reported: October 16,995








                                                                                                                      (814) 474-2044
                           CHURCH laboratory, inc.                                              7397 CHESTNUT STREET o P.O.BOX83
                                                                                                                    FAIRVIEW, PA. 16415







                                                              Water Analyses Report




                   Customer:                 Malcolm Pinfie, Inc.
                                             S. 3515 Abbott Road
                                             Buffalo, NY 14219

                   Project:                  Ene County Water Quality Monitoring Study
                                             for Lake Erie Watershed             #2758-01
                   Sample ID:                Event #05W, ELK CREEK                                         Lab Log No: 51491
                   Sample Date/Time:         October 5, 1995/ 16:40PK 18:40PNt 20:45PK 22:40PM
                   Sampler:                  R. W. Stallbaurn

                   PARAMETER                   EPA                      RESULTS/                 ANALYSIS               ANALYST
                                             METHOD                       UNITS                      DATE


                   Arsenic                     206.2                    <0.001   Mg/l             10-11-95                   RJ1
                   Cadmium                     213.2                    <0.0001  mg/l             10-12-95                   RE
                   Chromium, Total             218.1                    <0.05    mg/l             10-05-95                   RJI
                   Copper                      220.2                      0.001  mg/l             10-09-95                   RE
                   Lead                        239.2                      0.003  mg/l             10-09-95                   RJI
                   Nickel                      249.1                    <0.01    mg/l             10-06-95                   RJI
                   Silver                      272.2                    <0.0002  mg/I             10-11-95                   RJI
                   zinc                        289.1                    <0.005   mg/l             10-06-95                   RJI

                   Aluminum                    202.1                      0.56   mg/l             10-11-95                   RJI
                   Alkalinity                  310.1                      75     mg/l             10-06-95                   KW
                   Ammonia Nitrogen            350.1                      0.08   mg/l             10-12-95                   LT
                   Fecal Coliform
                           Grab@18:40PM        SM-16,909C                 1410   col/100 ml       10-07-95                   LT
                   Hardness                    130.1                      200    mg/1             10-06-95                   KW
                   Iron                        236.1                      2.23   mg/l             10-12-95                   RJI
                   Manganese                   243.1                      0.26   mg/l             10-12-95                   RJI
                   Nitrite Nitrogen            353.2                      0.01   mg/l             10-10-95                   LT
                   Nitrate Nitrogen            353.2                      0.88   mg/l             10-10-95                   LT
                   Chloride                    325.2                      33     mg;l             10-06-95                   LT
                   CBOD,                       405.1                      5      mg/l             10-11-95                   KW
                   Total Suspended Solids      160.2                      142    mg/l             10-12-95                   KW
                                               365.4                      0.17   mg/l             10-09-95                   LT
                   COD                         410.4                      20     mg/l             10-11-95                   NDA
                      spho
                                       4    VJ410*40o-
                     obert W. S a'aurn, J
                   President


                   Reported: October 16, 1995








                                                                                                                                   (814) 474-2044
                              CHURCH laboratory,                             inc.

                                                                                                           7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                 FAIRVIEW, PA. 16415







                                                                     Water Analysft Report




                     Customer:                    Malcohn Pimie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Erie County Water Quality Monitoxing Study
                                                  for Lake Erie Watershed                 #2758-01
                     Sample ID:                   Event #05W, TRIP BLANK                                               No: 51488
                     Sample Date/Titne:           October 5, 1995
                     Sampler:                     N.A. Conaway

                     PARAMETER                      EPA                         RESULTS/                    ANALYSIS                 ANALYST
                                                  METHOD                          UNITS                          DATE


                     Arsenic                        206.2                       --0.001   mo                 10-11-95                      RJ1
                     Cadmium                        213.2                       <0.0001   mg4                10-12-95                      RJI
                     Chromium, Total                218.1                       <0.05     m&4                10-12-95                      RJI
                     Copper                         220.2                       <0.001    mg/l               10-09-95                      RA
                     Lead                           239.2                       <0.001    Mg/1               10-12-95                      RJI
                     Nickel                         249.1                       < 0.01    mg/l               10-06-95                      RJI
                     Silver                         272.2                       <0.0002   mg/l               10-11-95                      RJI
                     Zinc                           289.1                       <0.005    mg/l               10-06-95                      RJI

                     Aluminum                       202.1                       <0. I     mg/l               10-11-95                      RJI
                     Alkalinity                     310.1                       <0.02     mg/l               10-06-95                      KW
                     Ammonia Nitrogen               350.1                       <0.01     Mg/l               10-12-95                      LT
                     Fecal Coliform                 SM-16,909C                    0       col/100 ml         10-07-95                      LT
                     Hardness                       130.1                       <2        mg4                10-06-95                      KW
                     Iron                           236.1                       <0.03     mg/l               10-12-95                      RJI
                     Manganese                      243.1                       <0.01     mg/1               10-12-95                      RJI
                     Nitrite Nitrogen               353.2                       <0.01     mg/1               10-10-95                      LT
                     Nitmte Nitrogen                353.2                       <0.01     mg/1               10-10-95                      LT
                     Chloride                       325.2                       <2        mg;1               10-06-95                      LT
                     CBOD,                          405.1                       <2        mg/l               10-11-95                      KW
                     Total Suspended Solids         160.2                       <2        mg/1               10-12-95                      KW
                     Phosphorus                     365.4                       <0.01     mg/l               10-09-95                      LT
                     COD                            410.4                       <10       mg/l               10-11-95                      NDA
                                                    410A





                     Robe W. S              Jr.
                     President


                     Reported: October 16, 1995



                                                                                                                                                                   10
           SEP-19-96 THU 02:43 PM CHURCH LABORATORY,.T.NC. 814 474 2044



                                                                                                                                           (814) 474-2044
                                  CHURCH laboratory,                               inc.

                                                                                                                  73070HESrNUTSTFROET - P.Q.gOX83
                                                                                                                                          FAIRVIFEW, PA. 16415






                                                                         Field Analyses Report


                      Customer:                      Malcolm Pirnle, Inc.
                                                     S. 3515 Abbott Road
                                                     Buffalo, NY 14219

                      Project:                       Eric County Water QUafitY N10AU'Drin& StUdy
                                                     for Lake Efie Watershed                    42758-01
                      Sample ID:                     Event 405W, TWELVE MILE CREEK
                      Sample Date/Time:              October 5, 1995
                      Sampler:                       N.A. Conaway



                      TIME                           PARAMETER                     RESLTI,TS/                     ANALYST
                                                                                       UNITS
                      16:40 PM                       PH                            8.3                               NAC
                      1810 PM                        PH                            8.8                               NAC
                      2013 0 PM                      PH                            9.0                               NAC
                      22:30 PM                       Ph                            8.8                               NAC

                      16:40 Phl                      Disfolved oxygen              7,52         MgA                  NAC
                      18:30 PM                       Diaeoh-ed c@xygen             6.49         ingA                 NAC
                      20:30 PM                       Dissolved oxygell             7.2          Mg/l                 NAC
                      22:30 PM                       Dissolved Oxygen              9.3          mg/l                 NAC
                      16:40 PAI                      Temperature                   15.1           C
                      18:30 PM                       Temperature                   15.2           C                  NAC.
                      20,30 PM                       Temperature                   15@ 1        0 C                  NAC
                      22:30 IN                       Tomporeture                   15.2           C                  NAC
                                                                                                                     NAC
                      16:40 PM                       Conductivity                  455          Wom                  NAC
                      19:30 PM                       Conductivity                  439          us(cm                NAC
                      2030 PM                        conductivity                  383          us/cm                NAC
                      22:30PM                        Conductivity                  410          UsIcim               NAC
                      16;40 PM                       Velocity *                    0.82         fps                  NAC
                      18:30 R1                       Velocity *                    1.46         fP-9                 NAC
                      20:30 PM                       'Velocity *                   3.95         fps                  NAC
                      2230 PM                        Velocity *                    6.64         fps                  NAC





                                                                         pap I of 2



                                                                                          P. 11
      SEP-19-96 THU 02:44 PM CHURCH [email protected], INC. 814 474 2044

                   CHURCH laboratory, inc.                                     (814) 474-2044

                                                                 7397 CHESTNUT STREET - P.O.BOX53
                                                                              rAIRVIEW. PA. 16415






            Field Ana@yses Report
            Malcolm Pimic, Inc.                                       Page 2 of 2

            Project:         Erie County Water QuAty Mordtc6ng Study
                             for Lake Eric Watershed  #2759-01
            Samplo ID:       Event #051VTWELVE ARLE CRFEK
            Sample Date/Time: October 5, 1995
            Sampler:         R. W. Staftaum




            TIME             PARAMETER         RESULTSi          ANALYST
                                                 UNITS

            16:40 PNI        Depth             1.0    ft           NAC
            18;30PM          Dept              1.0    R            NAC
            20:30 PNI        Depth             1.5    ft           NAC
            2230 PM          Depth             1.5    ft           NAC
            *ResWt ii an average of ftge triab sirq Stop watch and oranges.





















           Robert W. St baum, Jr.
           President
           ,A










































           Reported* OctObey 16,1995
           Revieed: Sept IS, 199,5



           SEP-19-96 THU 02:42 PM CHURCH LABORATORYI.-INP.. 814 474 2044


                                CHURCH laboratory, inc.                                                                               (81 4@ 474-2044

                                                                                                               7397 CHESTNUT STREET - P.0 BOX IB3
                                                                                                                                     FAIPVIEW PA. 16415






                                                                      Field Analyses Report



                     Customer:                     Malcolm Philie, Inc.
                                                   S. 3515 Abbott Road
                                                   Buffalo, NY 14219

                     Project:                      Eric County Water Quality Monitoring Study
                                                   for Lake Eric Watershod                  #2758-01
                     Sample ID:                    Event #05W, WALNUT CREEK
                     Sample Date/Time:             October 5, 1995
                     SamPlef:                      R. W. Staflbaum




                     TIME                          PARAMETER                    RESVLTS/                      ANALYST
                                                                                    UNITS
                     17:05 PM                      PH                           8.0                              RwS
                     19:15 PM                      pH                           7.4                              RWS
                     21,20 FM                      PH                           7.1                              RWS
                     23:10 PM                      PH                           6,9                              RWS
                     17:05 PM                      Dis,,;olved Oxygen           9.8         "191                 RWS
                     19.- 13 PU                    Dissolved Oxygen             9.7         rng/l                RWS
                     21:20 PM                      Dissolved Oxygen             10.0        MVI                  RWS
                     23:10 PM                      Dissolved Oxygell            9.3         Ing/I                RwS
                     17:05 pM                      Tompenture                   15.1        a C
                     19@ 15 PNI                    Temperature                  15.2        cc                   RwS
                     21:20 PM                      Tempemture                   151         0 C                  PIW3
                     23:10 PM                      Temperature                  15.4        0 C                  PINVS
                                                                                                                 RWS
                     1-T05 PM                      Conductivity                 43:2        us/cm                RWS
                     19:15 PM                      Conductivity                 401         us/cm                RWS
                     21:20 PM                      Conductivity                 428         U'S/=
                     2310 FM                       Conductivity                                                  RWS
                                                                                109         US/=                 RWS
                       :05 P&I                     Velocity *
                     19:15 PM                      velocity *                   2.62        fps                 RWS
                                                                                3.13        fps                 RWS
                     21.20 PM                      Velocity -
                     23:1 D PM                                                  4.53        fps                 RWS
                                                   Velocity *                   7.5         fps                 RW6




                                                                                page I of2



                                                                                                              814 47a '2044                                   k3
         SEP- 19-96 THU 02 :4 3 PM CHURCH LRBQRATQFY


                                                                                                                                       (814) 474-2044
                                CHURCHIaboratory,                                inc.

                                                                                                               7397 CHESTNUT STREET * P.O.BoXfia
                                                                                                                                      FAIRVIEW, PA 16415







                     Field Analyses Report
                     Malcolm Pirrdo, Inc.                                                                               Page 2 of 2
                     project:                        Efie County Water QualityMonltodng Study
                                                     for Lake Erie Watmhed                    42758-01
                     Sample JD-                      Event -#05%VVVALNlJT CREEK
                     Sample Date/Tixnc:              October 5, 1995
                     Sampler:                        R. W. Stafta=



                     TIME                            PARANIETER                   RESULTS/                      ANALYST
                                                                                   UNITS

                     17:05 PM- St I                  D6tance                      19.11       R                   RWS
                                - St 2               from bfidge                  19.23       ft                  RWS
                                - St 3               to                           1942        R                   RWS
                                - St 4               water surface                19.37       R                   RWS


                     19:13 PM- St I                  rAotance                     19.84       ft                  RWS
                                -St2                 froin btidge                 19.18       ft                  RWS
                                - St 3               to                           19.29       ft                  RWS
                                - St 4               water "face                  19.3        ft                  RWS
                                - St 5                                            19.24       ft                  RWS
                                 St 8                                             19.62       ft                  RWS

                     ":'o PM- St                                                  11,91       11                  RWS
                                 St 2                frora Mdge                   19.55       ft                  PIWS
                                -St3                 to                           18.79       ft                  RWS
                                 St:4                water x"face                 18.18       R                   RWS
                                 St 5                                             18.58       ft                  RWS
                                -Sto                                              18,11,      ft                  RWS

                     23:10 ?M- St I                  Distance                     17.44       ft                  RWS
                                - St 2               floin bridge                 0.71        ft                  RWS
                                -St3                 to                           18.65       R                   RWS
                                - St 4               water surface                17,49       ft                  RWS
                                . St 5                                            17.93       ft                  RWS
                                     7                                            18.23       ft                  RW$
                                     8                                            1828        ft                  RWS


                     Roberat w.        auln, jr.
                                       , @jr
                     President
                     RePorted, October 16,1995
                     Resived: Sept 18, 1996



          sEp-ig-96 THU 02:41 PM CHURCH LABORATORY, INC9. 8.14 474 2044 - --                                                            tl.k0t@

                             CHURCHIaboratory, inc.                                                                     (814) 474-2044

                                                                                                   7397 CHESTNVT STREET - P.O. BOX a3
                                                                                                                       FAIRVIEW PA. 16415






                                                               Field Anal)ses Report


                   Customer:                 Malcolm Pitnie, Inc.
                                             S. 3515 Abbott Road
                                             Buffalo, NY 14219

                   Project:                  Erie County Water Quality Monitozing study
                                             for Lake Fxie Wateished               #2758-01
                   Sample ID:                Event #05W, ELK CREEK
                   Sample Datc/Timo:         October 5, 1995
                   Sampler;                  R.W. Stallbaum



                   TIME                      PARANIETER                 RESULTS/                  ANALYST
                                                                           UNITS
                   16:40 PNI                 PH                         7.9                          RWS
                   18:4 0 PAI                PH                         8.0                          R%VS
                   20:45 PM                  PH                         7.6                          RwS
                   21:40PM                   PH                         7.8                          RWS

                   16:49 FIM                 Disoolved Oxygen           9.8      tng/l               RWS
                   18,-.40PM                 Dissolved Oxygen           10.4     mjo                 RWS
                   20:45 FXf                 I)Lssolved Oxygen          9,9      m gA                RWS
                   22:40 Pkf                 Disooh-ed Oxygen           9.8      DIM                 RWS
                   16-40 PM                  Temperature                15.5     *C                  RWS
                   18:40 FM                  Tempomture                 15.3     a C                 RW3
                   20:45 PM                  Temperature                15,4     u C                 RWS
                   22:40 Phl                 Temperetwe                 15.5     Ic                  RwS
                   16-.40 PM                 Cwductivity                540      US/=                RWS
                   18:40 PM                  conductil'ity              520      uWcjn               RWS
                   20@45 PM                  condctivity                482      uSkin               RWS
                   22:40 PM                  coftductivi@-              403      us/cm               RWS
                   16:40 PM                  velocity *                 1.16     fps                 RNVS
                   19:40 PM                  velodty *                  2.17     f
                   20-45 PM                  Velocity *                          ps                  RwS
                                                                        3.52     f@s                 RWS
                   22:40 PM                  'Velocity 0                4.17     fp a                Rsw





                                                               P89e  of 2



                                                                                                        __P14 474 2044
           SEP-19-96 THU 02:42 PM CHURCH LABORATORY, INC

                                CHURCH laboratory, inc.                                                                            (814) 474-2044

                                                                                                            73917CHESTNUTTMEET - P.Q.SOX83
                                                                                                                                 FAIRVIEW, PA. 1641 S







                     Field Analyses Report
                     Malcolm Ph-we, Inv,                                                                   Page 2 of 2

                     Project:                    Efie, COuntY Watef Qwlity Mojitoring Study
                     Sample ID:                  for Lake Efie Watershed                #2758-01
                                                 Event #05W, ELK CREEK
                     Sample Date/Time:           October 5, 1995
                     Sampler:                    R. W. Staltbaum.




                                                 PARAMETER                    RESULTS/                     ANALYST
                                                                                 UNITS

                     16:40PM                     Depth                        2.14      ft                     RWS
                     19:4 0 PM                   Depth                        2.44      ft                     IMS
                     2D:45 PM                    Depth                        2.73      R                      RWS
                     22:40 P?vf                  Depth                        2.83      ft                     RWS
                     *Re"It is gn average oftilree tijals using stop watch an(,























                     Robeirtw.
                     President

                     Vorted; October 16,1995
                     Revilyvd-' SePt 18. 1996
                         10
                   IA@






























































                                stau




                            CHURCH laboratory, inc.                                                                     (814) 474-2044

                                                                                                  7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                       FAIRVIEW, PA. 16415







                                                               Water Analyses Report




                    Customer:                 Malcolm Pirrfie, Inc.
                                              S. 3515 Abbott     Road
                                              Buffalo, NY 14219

                    Project:                  Erie County Water Quality Monitoring Study
                                              for Lake Erie Watershed              #2758-01
                    Sample ID:                Event #06W, TWELVE NHLE CREEK                                  Lab Log No: 51884
                    Sample Date/Time:         November 7, 1995/ 10:00AM, 12:OON, 14:OOPM
                    Sampler:                  N.A. Conaway


                    PARAMETER                   EPA                      RESULTS/                  ANALYSIS               ANALYST
                                              METHOD                       UNITS                       DATE


                    Arsenic                     206.2                      0.002   mg/l             11-08-95                   RJI
                    Cadmium                     213.2                    <0.0001   mg/l             11-09-95                   RJI
                    Cluornium, Total            218.1                    <0.05     MO               11-09-95                   RE
                    Copper                      220.2                      0.004   mg/l             11-09-95                   RJI
                    Lead                        239.2                      0.004   mg/l             11-08-95                   RJ1
                    Nickel                      249.1                    <0.01     mg/1             10-09-95                   RE
                    Silver                      272.2                    <0.0002   mg/1             11-09-95                   RE
                    Zinc                        289.1                      0.008   mg/1             11-09-95                   RJI

                    Alunfinum                   202.1                      0.76    mg;A             11-08-95                   RJI
                    Alkalinity                  310.1                      30      mg/1             11-08-95                   KW
                    Ammori a Nitrogen           350.1                      0.01    mg/1             11-09-95                   LT
                    Fecal Coliform
                            Grab@12:OON         SM-16,909C                 1200    col/ 100 ml      11-08-95                   LT
                    Hardness                    130.1                      106     mg/l             11-08-95                   k1w
                    Iron                        236.1                      1.63    mg/l             11-09-95                   RJI
                    Manganese                   243.1                      0.20    mg(l             11-09-95                   RJI
                    Nitrite Nitrogen            353.2                      0.01    mg/l             11-08-95                   LT
                    Nitrate Nitrogen            353.2                      0.97    mg/l             11-08-95                   LT
                    Cldon*de                    325.2                      38      mw
                                                                                      @1            11-08-95                   LT
                    CBOD,                       405.1                      2       mg/1             11-13-95                   KW
                    Total Suspended Solids      160.2                      134     mg/1             11-10-95                   KW
                    PhWhorus                    365.4                      0.28    mg/l             11-14-95                   LT
                    COD                         410.4                      35      mg/1             11-10-95                   NDA



                                         H.
                    Ro @ert W. Stallbaurn, r.
                    President
                    Reported: November 15, 1995








                                                                                                                                                (814) 474-2044
                                 CHURCH laboratory, inc.

                                                                                                                        7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                                              FAIRVIEW, PA. 16415







                                                                           Water Analyses Report




                       Customer:                       Malcolm Pirnie, Inc.
                                                       S. 3515 Abbott Road
                                                       Buffalo, NY 14219

                       Project:                        Erie County Water Quality Monitoring Study
                                                       for Lake Erie Watershed                     #2758-01
                       Sample ID:                      Event #06W, WALNUT CREEK                                                   LabLogNo: 31885
                       Sample Date/Time:               November 7, 1995/ 10:00AM, 12:00 N, 14:OOPM
                       Sampler:                        R.W. Stallbaum


                       PARAMETER                         EPA                           RESULTS/                         ANALYSIS                  ANALYST
                                                       METHOD                             UNITS                            DATE


                       Arsenic                           206.2                            0.002    mgA                  11-08-95                        RJI
                       Cadmium                           213.2                         <0.0001     mg/l                 11-09-95                        RJI
                       Chromium, Total                   218.1                         <0.05       mgn                  11-09-95                        RE
                       Copper                            220.2                            0.004    mg,11                11-09-95                        RJI
                       Lead                              239.2                            0.005    mg/l                 11-08-95                        RJI
                       Nickel                            249.1                         <0.01       m9A                  11-09-95                        RJ1
                       Silver                            272.2                         <0.0002     mg/l                 11-09-95                        RJI
                       Zinc                              289.1                            0.022    mg/l                 11-09-95                        RJI

                       .4durninuin                       202* 1                           1.51     mg;1                 11-08-95                        RE
                       Alkalinity                        310.1                            75       mg/l                 11-08-95                        k1w
                       Ammonia Nitrogen                  350.1                            0.05     mg/1                 11-09-95                        LT
                       Fecal Coliform
                                 Grab@12:OON             SM-16,909C                       330      col/ 100 nil         11-08-95                        LT
                       Hardness                          130.1                            176      mg,4                 11-08-95                        KW
                       Iron                              236.1                            2.54     mg/l                 11-09-95                        RE
                       Manganese                         243*1                            0.21     mg/l                 11-09-95                        RE
                       Nitrite Nitrogen                  353.2                            0.04     mg/l                 11-08-95                        LT
                       Nitrate Nitrogen                  353.2                            0.95     mg/l                 11-08-95                        LT
                       Chloride                          325.1                            62       mgl                  11-08-95                        LT
                       CBOD,                             405.1                            3        mg/l                 11-13-95                        KW
                       Total Suspended Solids            160.2                            212      mg/l                 11-10-95                        KW
                       Phosphorus                        365.4                            0.31     mgq                  11-14-95                        LT
                       COD                               410.4                            20       mg/l                 11-10-95                        NDA



                       Robertt W.. Stallbawn, Jr.
                       President
                       Reported: November 15, 1995








                                                                                                                                              (814) 474-2044
                                 CHURCH laboratory, inc.

                                                                                                                     7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                             FAIRVIEW, PA. 16415







                                                                          Water Analyses Report




                       Customer:                       Malcohn Pirnie, Inc.
                                                       S. 3515 Abbott Road
                                                       Buffalo, NY 14219

                       Project:                        Erie County Water Quality Monitoring Study
                                                       for Lake Erie Watershed                    #2758-01
                       Sample ID:                      Event #06W, ELK CREEK                                                     Lab Log No: 51886
                       Sample Date/Time:               November 7, 1995/ 10:30AK 12:30PM, 14:30PM
                       Sampler:                        R. W. Stallbaum

                       PARAMETER                        EPA                           RESULTS/                       ANALYSIS                   ANALYST
                                                       METHOD                            UNITS                            DATE


                       Arsenic                          206.2                            0.002    mg/1                 11-08-95                       RJI
                       Cadmium                          213.2                         <0.0001     mg/1                 11-09-95                       RJI
                       Chromium, Total                  218.1                         <0.05       mg/1                 11-09-95                       RE
                       Copper                           2 2 0.21                      <0.001      mg/l                 11-09-95                       RE
                       Lead                             239.2                         <0.001      mg/1                 11-08-95                       RE
                       Nickel                           249.1                         <0.01       mg/1                 11-09-95                       RJI
                       Silver                           27 2.2                        <0.0002     mg/1                 11-09-95                       RJI
                       Zinc                             289.1                         <0.005      mg/1                 11-09-95                       RH

                       Aluminum                         202.1                            0.21     mg/l                 11-08-95                       RJI
                       Alkalinity                       310.1                            55       mg/1                 11-08-95                       K1w
                       Ammonia Nitrogen                 350.1                            0.02     mg/1                 11-09-95                       LT
                       Fecal Coliform
                                  Grab@ I 2:30PM        SM-16,909C                       300      col/ 100 ml          11-08-95                       LT
                       Hardness                         130.1                            156      mg/l                 11-08-95                       KW
                       Iron                             236.1                            0.23     mg/1                 11-09-95                       RJI
                       Manganese                        243,1                            0.05     mg/1                 11-09-95                       RJ1
                       Nitrite Nitrogen                 353.2                         <0.01       mg/1                 11-08-95                       LT
                       Nitrate Nitrogen                 353.2                            1.22     mg/1                 11-08-95                       LT
                       Chloride                         325.2                            41       mg;'1                11-08-95                       LT
                       CBOD,                            405.1                            2        mg/1                 11-13-95                       KW
                       Total Suspended Solids           160.2                            24       mg11                 11-10-95                       k1w
                       Phosphorus                       365.4                            0.10     mg/1                 11-14-95                       LT
                       COD                              410.4                            15       mg/1                 11-10-95                       NDA
                       Robert W. Stallbau,?,Jie@
                       President


                       Reported: November 15, 1995








                                                                                                                                   (814) 474-2044
                               CHURCH laboratory, inc.                                                      7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                  FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                      Customer:                     X4alcohn Pirnie, Inc.
                                                    S. 3515 Abbott Road
                                                    Buffalo, NY 14219

                      Project:                      Ene County Water Quality MOMtOnng Study
                                                    for Lake Erie Watershed                #2758-01
                      Sarnple ID:                   Event #06W, TRIP BLANK                                              No: 51883
                      Sample Date/Time:             November 7, 1995
                      Sampler:                      N.A. Conaway                 RESULTS/                    ANALYSIS                 ANALYST
                      PARAMETER                      EPA
                                                    METHOD                         UNITS                         DATE


                      Arsenic                        206.2                       <0.001    mg/l               11-08-95                      RJI
                      Cadmium                        213.2                       <0.0001   mg/l               11-09-95                      RE
                      Chromium, Total                218.1                       <0.05     mg/I               11-09-95                      RE
                      Copper                         220.2                       <0.001    mg/I               11-09-95                      RJI
                      Lead                           239.2                       <0.001    mg/1               11-08-95                      RJI
                      Nickel                         249.1                       < 0.01    mg/l               11-09-95                      RE
                      Silver                         272.2                       <0.0002   mg/l               11-09-95                      RE
                      Zinc                           289.1                       <0.005    mg/I               11-09-95                      RJI

                      Aluminum                       202.1                       <0.1      mg/1               11-08-95                      RJI
                      Alkalinity                     310.1                       <0.02     mg/1               11-08-95                      KW
                      Ammonia Nitrogen               350.1                       <0.01     mg/l               11-09-95                      LT
                      Fecal Coliform                 SM-16,909C                    0       col/100 ml         11-08-95                      LT
                      Hardness                       130.1                       <2        mg/l               11-08-95                      KW
                      Iron                           236.1                       <0.03     mg/I               11-09-95                      RE
                      Mangatiese                     243.1                       <0.01     MgA                11-09-95                      RJI
                      Nitrite Nitrogen               353.2                       <0.01     mg/I               11-08-95                      LT
                      Nitrate Nitrogen               353.2                       <0.01     mgq                11-08-95                      LT
                      Chloride                       31-5.2                      <2        M&I                11-08-95                      LT
                      CBOD,                          405.1                       <2        mg/1               11-13-95                      KW
                      Total Suspended Solids         160.2                       <2        mg/1               11-10-95                      KW
                      Phosphorus                     365.4                       <0.01     mg/1               11-14-95                      LT
                      COD                            410.4                       <10       mg/I               11-10-95                      NDA
                 @9








                         @2tall                     Z51-
                      Ro T. S @a, dJr
                      President


                      Reported: November 15, 1995



         SEP-19-96 THU 02:44 PM CHURCH LABORATORY, INC. --814 4"14

                             CHURCH laboratory, inc.                                                                    (814) 474-2044

                                                                                                   7307 004ESTNUT STPEET - P.O. SOX 93
                                                                                                                       FAIPVIEW. PA. 16415






                                                               Field Analyses Report


                   Customer:                 h1alcohn Pirnie, Inc,
                                             S. 3515 Abbott Road
                                             Buffalo, NY 14219

                   Project:                  Erie County Water Quality Monitofin Study
                                             for Lake Efle Watershed                #2758-01
                   Sample ID:                Evemt 406W, TWELVE MILE CREEK
                   Sample Date/Time:         Novembc.T7,1995
                   Sampler:                  N.A. Conaway

                   TIME                      PARAMETER                  RESULTS/                   ANALYST
                                                                           VNITS
                   10-00AM                   PH                         8.9                          NAC
                   11,00N                    PH                         8.9                          NAC
                   14:00 PM                  pH                         8.9                          NAC
                   10:00 AM                  Diisolved Oxygen           10.36       m6n              NAAC
                   12:00 N                   Dieffolved oxygen          10.83       mg/I             NAC
                   14:00 PM                  MFolved O)qgen             10.75       nig/l            NAC
                   10:40 AM                  Temperature                9.4         C                NAC
                   12:00 N                   Temperature                6.6         CC
                   14; 00 PM                 Temperature                6.3         OC               NAC
                                                                                                     NAC
                   111:411 All,              Conduotivity               305         us/cm            NAC
                   12@00 N                   Conductivity               296         US/=             NAC
                   14:00 F&I                 Conductivity               272         US,=             NAC
                   10@40 AM                  Velocity *                 3.42        fps              NAC
                   12@00 N                   Velocity *                 6.96        fP3              NIAC
                   14:00 PXI                 Velocity                   5.83        fps              NAC
                    :00 AM                   Depffi                     1.25        ft               NAC
                   12:00 N                   Depdx
                   10                                                   2.0                          NAC
                   14:00 PM                  Depth                      1.75        ft
                   *ReeW '  an verage Of tlhftg trials Wins stop watch and omSes.                    NAC


                   Robert W St ba-wn, Jr.
                   President
                   Reported: November 15.1995
                   Revieed: Sept 18, 1996
                                                               page I of I




                                                                                                               814 4
           SEP-19-96 THU 02:45 PM CHURCH LABORATOR-Y, INC-_                                                               74 2044-

                                 CHURCH laboratory, inc.                                                                                (1914) 474,2044

                                                                                                                7307 CHESTNUT STREET - P.O. BOX a,3
                                                                                                                                       FAIRVPEW, PA 16415







                                                                       Field Analyses Report




                     Customer                       NWcolm Pirrde, Inc.
                                                    S. 3515 Abbott Road
                                                    Buffalo, NY 14219

                     Project-                       Efie CoLmty'%Vater QuaUty Motdtoring Stwly
                                                    for Lake Erie Watershed                   #2758-01
                     Sample ID:                     Event #06W, WAJ.,NTjT CR.EFK
                     Sample Date/Time:              November 7, 1995
                     Sampler:                       R. W. Stallbaum



                     TIME                           PARAMETER                     RESULTS/                      ANALYST
                                                                                    UNITS
                     10;00 AM                       PH                            7.75                             RWS
                       20 N                         PH                            7.87                             JzwS
                     14;00 PM                       Pff                           7,58                             RWS
                     ':0


                     10-00AM                        Dissolved Oxygen              11.6        flign                P.WS
                     12:00 N                        Distolved Oxygen              11.6        n1&4                 RwS
                     1410 PM                        Dissolved Oxygen              11.1        M&I                  RWS
                     10:00 AM                       Tompersture                   4.7         0 C
                     12:00 N                        Temperabire                   4.9         0 C                  RWS
                     14:00 PM                       Tempel-atme                               9 C                  RWS
                                                                                  5.4                              P"%VS
                     10:00 AM                       conducthity                   512         tweim                RWS
                     12:00 N                        ConducUvity                   547         u'Sion)              RWS
                     14:00 PM                       CoAducti-fity                 490         w9l/crn              RWS
                     10-00 AM                       Velocit_y .                   3.13        fps                  RWS
                     12:00 ff                       Velocity *                    3.68        ts                   Rws
                     14:00 PM                       velocity                      4,62        fpa                  RWS







                                                                                page I of 2




                                                                                                                                                        P. 14
          SEP-19-96 THU 02:45 PM CHURCH LA20RATORY, INC __814-474 2044



                                                                                                                                      (814) 474-2044
                                 CHURCH laboratory,                             inc.

                                                                                                              7397 CHESTNUT STAMOT - P,O.BOXB3
                                                                                                                                     FAMVIEW. PA I BA1 6






                     Field Analyses Report
                     Malcolm Pirrde, Ine.                                                                              Page 2 of 2

                     Projcct:                      Erie County WAteff Quaty Mor&ofing Study
                                                   for Lake Me Watershed                    #2758-01
                     Sample ID:                    Evcnt #06WWALNLTT CREEK
                     Sample Date/Timc:             November 7, 199 5
                     Sampler:                      R. W. Stallbaurn



                     TIME                          PARAMETER                    RESULTS/                      ANALYST
                                                                                  UNITS

                     I (WO AM- St I                Mtance                       18.97                           RWS
                               -St2                froni bridge                 19.05       ft                  RWS
                               -St3                to                           19.29       ft                  RWS.
                                 St 4              wa ter Furface               19.09       ft                  RwS
                                 St 8                                           19.51       ft                  RAIS

                     12:00 N     St I              Distance                     18.71       ft                  RwS
                                 St 2              from bridge                  18.95       ft                  RWS
                                 St 3              to                           19.07       ft                  RAVS
                                 St4               water guface                 19.03       ft                  RWS
                                 sts                                            19-51       R                   RWS
                     14:00 PM- St I                Distance                     18.36       R                   RwS
                               - St 2              VOM bjidge                   18-14       ft                  RUIS
                               - St 3              to                           18.32       ft                  RVS
                               - St 4              Vrater Rudace                18.44       ft                  RW3
                               -St 5                                            18-32       ft                  RwS
                                 St 8                                           18.94       R                   RWS










                   Robert w. st            Jr-
                   President

                   Re,orte,: November 11,
                   Revised: Sept 1g, 1996



           SEP-19-96 THU 02:46 PM CHURCH LABORRTORY, INC.. 814 474 20-44                                                                                               FI.1!5

                                   CHURCH laboratory, inc,                                                                                        (814) 474-2044

                                                                                                                        7307 CHGSTNUT STRFET , P.Q BOX a3
                                                                                                                                                 FAIAVIEW, PA. 16415






                                                                            Field Analyses Report


                      Customer:                        Malcolm pimle, Inc.
                                                       S. 3515 Abbott Road
                                                       BuffAo, NY 14219

                      Project:                         Ede County Water QuAhfY Monitoring Study
                                                       for Lake Efle Watershed                      42758-01
                      Sample ID:                       Event 406W, ELK CREEK
                      Sample DatdTime:                 Novembor 7,1995
                      Sampler:                         RM. StaRbaurn



                      TIN119                           PARAMETER                      RESULTS/                         ANALYST
                      10:30 AM                                                             UNITS
                                                       PH                             7,5                                 RWS
                      12:30 PM                         PH                             7.5                                 RWS
                      14:30 PM                         PH                             74                                  RWS
                      10;30 AM                         Dissolved oxygei,              11.3       mgq                      RWS
                      12:30 P?*f                       Dissolved Oxygen               11.3       nig/l                    RWS
                      14:30 PM                         Dissolved Oxygen               11.2       m14                      RWS
                      10:30 AM                         Tempewtire                     4,6          C
                      12:30 PM                         Tsmpelat=                      4.9          C                      RWS
                      14;30 PM                         Temperature                    5.2          C                      RWS
                                                                                                                          RWS
                      10:30 AM                         conductivity                   409       I-SicIn                   RWS
                      1210 PM                          Conductvity                    412       lalcin                    RWS
                      14:30 FM                         Conductivity                   419       us/cm                     RWS
                      10:30 ANI                        Velocity                       3.42       fps                      RWS
                      1230 PM                          Velocity                       3.79       fpg                      RWS
                      14:30 PM                         Velocity                       4-171                               RWS
                      10:30 AM                         Depth                          2159
                      12:30 P1v1                                                                                          RWS
                                                       Depth                          2.75                                RWS
                      14;3 0 PAI                       Depth                          2.93      ff                        RWS
                      *Reo@Wt **      ' rage of three trials us@V zt0P watch and


                      Robeit'Vv. Sta.
                      President
                                    Ub

                      Reporte& NOvem@er 15, 1995
                          0.         t
                      Revis & ""P "" '9'6
                                                                         P2.80 1 of 2








                                                                                                                                                (814) 474-2044
                                  CHURCH laboratory, inc.

                                                                                                                      7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                               FAIRVIEW. PA. 16415







                                                                     Water Analyses Report




                 Customer:                       Malcolm Pirnie, Inc.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                 Project:                        Erie County Water Quality Monitoring- Study
                                                 for Lake Erie Watershed                     #2758-01
                 Sample ID:                      Event #07W, TWELVE MILE CREEK                                              Lab Log No: 51951
                 Sample Date/Time:               November 11, 1995/ 7:00AM, 9:00AM, 1 1:OOAM
                 Sampler:                        N.A. Conaway


                 PARAMETER                         EPA                           RESULTS/                       ANALYSIS                    ANALYST
                                                 METHOD                             UNITS                             DATE


                 Arsenic                           206.2                            0.004    mg/1                 11-13-95                        RE
                 Cadmium                           213.2                            0.0004   intO                 11-14-95                        RJI
                 Chromium, Total                   218.1                          <0.05      mg/l                 11-14-95                        RE
                 Copper                            220.2                            0.015    mg/l                 11-13-95                        RE
                 Lead                              239.2                            0.015    mg/I                 11-14-95                        Ril
                 Nickel                            249.1                            0.01     mgJ1                 11-14-95                        RE
                 Silver                            272.2                         <0.000'?    mg1l                 11-14-95                        RJI
                 Zinc                              289.1                            0.050    mgA                  11-14-95                        RJI

                 Aluminum                          2 021. 1                         8.59     mg/I                 11-13-95                        RJI
                 Alkalinity                        310.1                            14       mgJ'I                11-20-95                        KW
                 Ammonia Nitrogen                  350.1                            0.08     mg/1                 11-16-95                        LT
                 Fecal Coliform
                            Grab@9:00AM            SM- 16, 909C                     10,400   col/ 100 ml          11-12-95                        RWS/LT
                 Hardness                          130.1                            72       mg/l                 11-12-95                        KW
                 Iron                              236.1                            6.92     m_wl                 11-14-95                        RJI
                 Manganese                         243.1                            0.65     m vA                 11-16-95                        RJI
                 Nitrite Nitrogen                  353.2                            0.07     mgtl                 11-15-95                        LT
                 Nitrate Nitrogen                  353.2                            1.16     mg/l                 11-15-95                        LT
                 Chloride                          325.2                              1      mg;l                 11-20-95                        LT
                 CBOD,                             405.1                                     mg/I                 11-16-95                        KW
                 Total Suspended Solids            160.2                            828      mg/I                 11-15-95                        KIN
                 Phosphorus                        365.4                            0.84     mg/I                 11-14-95                        LT
                 COD                               410.4                            60       mg/l                 11-14-95                        NDA
                   @9





                    OD
                 R45bert. Stall aum, Jr.
                 President
                 Reported: November 22, 1995








                                                                                                                                       (814) 474-2044
                                CHURCH laboratory, inc.

                                                                                                               7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                     FAIRVIEW, PA. 16415







                                                                 Water Analyses Report




                Customer:                     Malcolm Pirnie, Inc.
                                              S. 3515 Abbott Road
                                              Buffalo, NY 14219

                Project:                      Erie County Water Quality Monitoring Study
                                              for Lake Erie Watershed                  #2758-01
                Sample ID:                    Event #07W, WALNUT CREEK                                              Lab Log No: 51953
                Sample Date/Time:             November 11, 1995/ 7:20AK 10:35 AM, 13:20PM
                Sampler:                      R.W. Stallbaum


                PARAMETER                       EPA                         RESULTS/                     ANALYSIS                  ANALYST
                                              METHOD                           UNITS                          DATE


                Arsenic                         206.2                          0.006   m2A                 11-13-95                      RJI
                Cadmium                         213.2                          0.0004  mg/l                11-14-95                      RJI
                (.1romium, Total                218.1                        <0.05     mg/1                11-14-95                      RJI
                Copper                          220.2                          0.016   mg/I                11-13-95                      RJ1
                Lead                            239.2                          0.025   mg/1                11-14-95                      RJI
                Nickel                          249.1                          0.02    mg/1                11-14-95                      RE
                Silver                          272.2                       <0.0002    mg/I                11-14-95                      RJI
                Zinc                            289.1                          0.089   ing/I               11-14-95                      RJI

                .'Uuminuin                      202.1                          13.10   mg/1                11-13-95                      RJI
                Alkahnity                       310.1                          40      mg/l                11-20-95                      KW
                Ammoni'a Nitrogen               350.1                          0.06    mgl                 11-16-95                      LT
                Fecal Coliform
                          Grabra,10:35AM        SM-16,909C                     5200    col/100 ml          11-12-95                      RWS/LT
                Hardness                        130.1                          104     mg/l                11-12-95                      k1w
                Iron                            236.1                          10.22   mg/I                11-14-95                      RJI
                Manganese                       243.1                          0.79    mg/I                11-16-95                      RJI
                Nitrite Nitrogen                353.2                          0.09    mgil                11-15-95                      LT
                Nitrate Nitrogen                353.2                          1.17    mgA                 11-15-95                      LT
                Chloride                        325.2                          3-7     mg;l                11-20-95                      LT
                C1301),                         405.1                          3       mg/1                11-16-95                      k-1A1
                Total Suspended Solids          160.2                          892     m&q                 11-15-95                      KVI
                Phosphorus                      365.4                          0.95    mivl                11-14-95                      LT
                CO@@                            410.4                          60      mi/I                11-14-95                      NDA
                Robert W. Stallbaum, Jr.
                President
                Reported: November 22, 1995








                                                                                                                                                              (814) 474-2044
                                     CHURCH laboratory, inc.

                                                                                                                                  7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                                                            FAIRVIEW, PA. 16415







                                                                            Water Analyses Report




                   Customer:                          Malcolm Pirnie, Inc.
                                                      S. 3515 Abbott Road
                                                      Buffalo, NY 14219

                   Project:                           Erie County Water Quality Monitoring Study
                                                      for Lake Erie Watershed                         #2758-01
                   Sample ID:                         Event #07W, ELK CREEK                                                             Lab Log No: 51952
                   Sample Date/Time:                  November 11, 1995/7:45AM, 10:00AM, 13:OOPM
                   Sampler:                           R. W. Stallbaurn

                   PARAMETER                            EPA                              RESULTS/                          ANALYSIS                       ANALYST
                                                      METHOD                                UNITS                                DATE


                   Arsenic                              206.2                               0.004     mg(l                   11-13-95                           RJI
                   Cadmium                              213.2                               0.0001    mg/1                   11-14-95                           RJI
                   Chromium, Total                      218.1                             <0.05       mg/1                   11-14-95                           RE
                   Copper                               220.2                               0.010     mg,11                  11-13-95                           RJI
                   Lead                                 2 3 9.2)                            0.013     mg/1                   11-14-95                           RJI
                   Nickel                               249.1                               0.02      mgl                    11-14-95                           RE
                   Silver                               2 721. 2                          <0.0002     mg/1                   11-14-95                           RE
                   Zinc                                 289.1                               0.045     ma/1                   11-14-95                           RJI


                   Aluminum                             202. 1                              8.20      mg
                                                                                                          A                  11-13-95                           RE
                   Alkalinity                           310.1                               31        mg/1                   11-20-95                           KIV?
                   Ammonia Nitrogen                     350.1                               0.06      Mg/1                   11-16-95                           LT
                   Fecal Coliform
                               Grab@10:OOAM             SM-16,909C                          4700      col/ 100 ml            11-12-95                           RWS/LT
                   Hardness                             130.1                               10111-    mg/1                   11-12-95                           K-VNI
                   Iron                                 236.1                               7.49      mg/l                   11-14-95                           RJI
                   Manganese                            243.1                               0.50      mg/l                   11-16-95                           RJI
                   Nitrite Nitrogen                     353.2                               0.07      mg/1                   11-15-95                           LT
                   Nitrate Nitrogen                     353.2                               1.36      nigil                  11-15-95                           LT
                   Chloride                             325@2                               24        mg;1                   11-20-95                           LT
                   CBOD,                                405.1                               2         mgA                    11-16-95                           K1w
                   Total Suspended Solids               160.2                               7.68      mg/l                   11-15-95                           KIW
                   Phosphorus                           365.4                               0.79      mg/l                   11-14-95                           LT
                   COD                                  410.4                               50        mp@l                   11-14-95                           NDA



                   Rob rt W. Stallba , Jr.
                   President


                   Reported: November 1-2, 1995








                                                                                                                                                  (814) 474-2044
                                CHURCH laboratory, inc.

                                                                                                                        7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                                 FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                Customer:                       Malcohn Pirnie, Inc.
                                                S. 3515 Abbott Road
                                                Buffalo, NY 14219

                Project:                        Ene County Water Quality Monitoring Study
                                                for Lake Erie Watershed                       #2758-01
                Sample ID:                      Event #07W, TRIEP BLANK                                                       No: 51950
                Sample Date/Time:               November 11, 1995
                Sampler:                        N.A. Conaway

                PARAMETER                         EPA                             RESULTS/                       ANALYSIS                     ANALYST
                                                METHOD                              UNITS                              DATE


                Axsenic                           206.2                           <0.001      mg/l                 11-13-95                         RJI
                Cadmium                           213.21                          <0. 000 1   mg/1                 11-14-95                         RJI
                Chromium, Total                   12 18. 1                        <0.05       mg/l                 11-14-95                         RJI
                Copper                            220-1                           <0.001      mirA                 11-13-95                         RJI
                Lead                              239.2                           <0.001      M;A                  11-14-95                         RJI
                Nickel                            249.1                           < 0.01      mg/1                 11-14-95                         RJI
                Silver                            272.2                           <0.000"     mg/l                 11-14-95                         RJI
                Zinc                              289.1                           <0,005      mg)l                 11-14-95                         RJI

                Alumininn                         202. 1                          <0. I       m vA                 11-13-95                         RJI
                Alkalinity                        310.1                           <1          mg/l                 11-1-0-95                        KW
                Ammonia Nitrogen                  350.1                           <0.01       M&I                  11-16-95                         LT
                Fecal Coliform                    SM- 16, 909C                      0         col/ 100 nil         11-12-95                         RWS/LT
                Hardness                          130.1                           <2          mg/l                 11-12-95                         KW
                Iron                              1-36.1                          <:0.03      mg,1                 11-14-95                         RJI
                Manmmese                          243.1                           <0.01       mzq                  11-16-95                         RJI
                Nitrite Nitrogen                  353.2                           <0.01       mz/1                 11-15-95                         LT
                Nitrate Nitrogen                  353.2                           <0.01       nl@i                 11-15-95                         LT
                Cldoride                          325.2                           <2          ing;J                11-20-95                         LT
                CBOD,                             405.1                           <2          mg/l                 11-16-95                         KW
                Total Suspended Solids            160.2                           <2          M&I                  11-15-95                         NCW
                Phosphonis                        365.4                           <0.01       MQA                  11-14-95                         LT
 'A             COD                               410.4                           <10         mg,11                11-14-95                         NDA


                                          Jr.
                Ro ert W. S
                President


                Reported: November 22,1995



           SEP-19-96 THU 02:50 PM CHURCH LABORATORY, INC. 814 474 2044                                                                        P.05

                             CHURCH laboratory, inc.                                                                       (814) 474-2044

                                                                                                     73970HESTNUTGTREET - P.0.80X83
                                                                                                                          FAtRVIEW, PA. 18415






                                                                Field Analyses Report


                   Customer:                  Malcolm Pinlie, inc.
                                              S. 3 515 Abbott Road
                                              Buffalo, NY 14219

                   Projec.t.                  Erie County Water Quality Monitoft Study
                                              for Lake, Eric Watershed               #2759-01
                   Sample ID:                 Event #07W, TWEVU MILE CREEK
                   Sample Date/Time:          November 11, 1995
                   Sampler:                   N.A. Conaway


                   TIME                       PARAMETER                   RESULTS/                   ANALYST
                                                                             UNITS
                   7:00 A.M                   pH                          9.5                           NAC
                   9;00 AM                    pH                          8.9                           NAC
                   11:00 AW                   jP14                        8.8                           NAC

                   7;00 AM                    Dissolvid QAygen            12.32      M&q                NAC
                   9.00 ANI                   Dissolved Oxypn             12-75      MgA                NAC
                   I L00 AM                   Dissolved Oxygen            12.29      MSA                NAC

                   7:011 AM                   Temperattire                7.2        1C                 NAC
                   9:00 AM                    Temperature                 7A         CC                 NAC
                   I 1 -100 AM                Temperatuxe                 8          OC                 NAC

                   7:00 All                   Cojiductivity               199        us/cm              NAC
                   9;00 AM                    Conductivity                186        11SICIn            NAC
                   11:00 AM                   Conductivity                170        US/CM              NAC.

                   7:00 AM                    Velocity *                  11,7       fpq                NAC
                   9:00 AM                    Velocity *                  10.6       fps                NAC
                   11:00 AM                   velocity *                  9.3        rp a               NAC
                   7:00 AM                    Depth                       3.25       ft                 NAC
                   9:00 AM                    Depth                       3.5        ft                 NAC
                   11:00 AM                   Depth                       2,75       ft                 NAC
                   *Result'     verage Of three tTials usiAg VtOP watch and oranges.


                   Rolert W, S          Jr.
                   President
                   Reported; November 22,1995
                   Revised, sept ig, 1996
                                                                pap i of I





           SEP-19-96 THU 02:49 PM CHURCH LABORATORY, INC. 814 474 2044                                                                       P.03




                                                                                                                         (814) 474-2044
                            CHURCH laboratory, inc.

                                                                                                    7327 CHEStNuT StREET - P.0 BOX 9.3
                                                                                                                        FAIR VI 6W. PA. 16415






                                                               Field Analyses Report



                  Customer:                  Malcolm Pirniv, Inc.
                                             S. 3515 Abbott Road
                                             Buffido, NY 14219

                  Project:                   Erie County Water Quality Mor@toring Study
                                             for Lake Ene Watershed                #2758-01
                  Sample ID:                 Event #07W, WALNUT CREEK
                  Sample- Date/Time:         November 11, 1995
                  Sampler:                   R. W. Stfibawn




                  TIME                       PARAMVER                   RESULTS/                   ANALYST
                                                                           UNITS

                  7.                         PH                         7.36                          RwS
                  10:35 AM                   PH                         7.09                          RWs
                  13"2"O"PMM                 PH                         7,12                          RWS
                  7:20AM                     Dissolved Oxygen           11.2       rne                RWS
                  10:35 Alt                  Disoolved oxygen           10.9       M94                RWS
                  13:20 PM                   woolved oxygen             11.0       inZ4               RWS
                  7.10 AM                    Temperature                7.1        or                 RWS
                  10:35 AM                   Temperatuiv                7.5        ac                 RwS
                  13:20 P14                  Temperature                7.8        a C                RwS
                  7:20 AM                    Conduetivity               345        wvcm               RWS
                  1015 AM                    Conduotivity               303        us/con             RWS
                  13;20 PM                   conduchvity                282        US/=               RWS
                  7:20 AM                    velooity *                 7.1        fps                RWS
                  10:35 AM                   Velocity *                 7.5        fps                RWS
                  13:20 PM                   Velocity                   6.6        fpa                RWS







                                                                      page I of 2



            SEP-19-96 THU 02:50 PM CHURCH LABORATORY, INC. 814 474 2044                                                                                                 P.04

                                   CHURCH laboratory, inc.                                                                                       (014) 474-2044

                                                                                                                       7397 CHESTNUT STREET - P.0,80X&3
                                                                                                                                                rAIRVIEW, PA 18415






                      Field Analyses Report
                      Malcolm Pirnic, Inc.                                                                                       Page 2 of 2

                      Project:                        Eric County Water Quality Monitoring Study
                                                      for Lake Eric Watenhe,1                       #2758-01
                      Sample ff):                     Event #07WIVALNUT CREEK
                      Sample Date/Titne:              November 11, 1995
                      Sampler:                        P, W. Stallbawn




                      TINIE                           PARAMETER                        RESULTS/                        ANALYST
                                                                                         UNITS


                      7:20 AM- St 1                   Distmwe                          17.38        ft                    RWS
                                   -5t2                 from bridge                    17.61        ft                    Plkvs
                                   -St3                 to                             17-68        ft                    RWS
                                   -St4                 Water nuface                   17. 7 4      ft                    RWS
                                   . SO                                                18.02        ft                    Rws
                                   -St7                                                18-11        ft                    RWS
                                   - St 8                                              18.31        ft                    Rws
                                   - St 9                                              18.29        ft                    RWS
                                   - St 10                                             18.28        ft                    RWI

                      10:35 AM@ St I                  Distance                         17.07        R                     RNVS
                                   St 2                 ftom bridge                    17,14        ft                    RWS
                                   St 3                 to                             17.31        ft                    RWS
                                   St4                  water furface                  17.42        ft                    RWS
                                   St 5                                                17.91        R                     RWS
                                   St 7                                                17.76        ft                    RWS
                                   St 8                                                17.92        R                     RNVS
                                   -St9                                                18.05        ft                    RwS
                                   - St 10                                             18,43        ft                    RWS
                      13:20 ?N1- St I                 Difftance                        16,08        ft                    RWS
                                   St 2                 frorn bridge                   16.31        ft                    RWS
                                   SO                   to                             17,22        R                     RWS
                                   St 4                 water stirface                 173          R                     RWS
                                   St 5                                                IT73         ft                    RWS
                                   St 7                                                17.63        ft                    RAVS
                                   -St8                                                17.81        ft                    RWS
                                11-W)                                                  17.96        R                     Rws
                           /11 V      10                                               18.07        ft                    RWS

                      RoberltW. S              Jr.
                      Piesident
                      Repoitod: NaVember 22,1915
                      Revised; Sept IS, 1996



      SEP-19-96 THU 02:49 PM CHURCH LABORATORY, INC.           814 474 2044            P-02


                  CHURCH laboratory, inc.                                   (a14) 474-2044

                                                               7397 CHESTNOT STREET - FF,O, BOX 6;3
                                                                            FAIRVIEW PA. 1641f)






                                       Field Analyses Report


            Customer:       Malcohn Pirnie, Jnc.
                            S. 3515 Abbott Road
                            Buffalo, NY 14219

            Project:        Eric County Water Quality Monitoring study
                            for Lake Efie Wateished  #2758-01
            Sample ID:      Event #07W, ELK CREEK
            Sample DatefTime: November 11, 1995
            Sampler:        R.W. Stallbawn



            TIME            PARAMETER        RESULTS/         ANALYST
                                                UNITS
            7:45AM          PH               73                 RWS
            WkO AM          pH               7.2                RWS
            13;00 FM        PH               6.9                RWIS

            7:45 AM         Dies olved Oxygen 11'1 Insl         RWS
            10:00 AM        Dissolved Oxygen 10.9  MVi          RWS
            13:00 PM        Digoolved Oxygen 10.6  ing(I        RWS

            7:45 ANJ        Temperature      6.8   4C           RWS
            10.,00 AM       TOMperature      7.2   DC           RWS
            13.00 PM        Temperatwe       7.8   a C          RWS
            7:45 AM         Conductivity     280   us/cm        RWS
            10:00 PM        Conductivity     236   uslem.       RWS
            13:00 PM        Conductivity     221   us/cnl       RWS
            7:45 AM         Velocity *       7.9   fps          RWS
            10:00 AM        velocity *       9.4   fps          RWS
            13:00 P&f       velocity -       8.2   fps          RWS
            7:45 AM         Depth            5.0   ft           RNVS
            10:00 AM        Depth            5.67  R            RWS
            13:11           Dmal             6.25  ift          RWS
            *R  tis 'average of three " using gop -watch and orangea.


            Rob W. S baum, it.
              0
              0 Pp"





              ert t
            President

            RePOfted: November 22,1995
            R-eviced-, Sept 18,1996




                               CHURCH laboratory, inc.                                                                             (814) 474-2044

                                                                                                           7397 CHESTNUT STREET - P-0-BOX83
                                                                                                                                 FAIRVIEW, PA. 16415







                                                                    Water Analyses Report



                    Customer:                     Malcolm Pirtie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                    Project:                      Ene County Water Quality Monitoring Study
                                                  for Lake Erie Watershed               #2758-01
                    Sample ID:                    Event #08W, TWELVE ABLE CREEK                                      Lab Log No: 53864
                    Sample Date/Time:             April. 12, 1996/ 19:40PNt 21:40 PK 23:35PM
                    Sampler:                      N. C. Whiteman

                    PARAMETER                     EPA                         RESULTS/                    ANALYSIS                 ANALYST
                                                  METHOD                        UNITS                          DATE

                    Arsenic                       206.2                         0.001   Mg/l               04-15-96                     RJ1
                    Cadmium                       213.2                       <0.0001   mg/1               05-01-96                     RJI
                    Chromium, Total               218.1                       <0.05     mg/1               04-16-96                     RJI
                    Copper                        220.2                         0.004   mg/l               05-07-96                     RJI
                    Lead                          239.2                         0.008   mg/l               04-15-96                     RA
                    Nickel                        249.1                         0.01    mg/1               04-16-96                     RJI
                    Silver                        272.2                       <0.0002   mg/l               05-07-96                     RJI
                    Zinc                          289.1                         0.028   mg/l               04-15-96                     RJI
                    Aluminum                      202.1                         5.28    mg/1               04-16-96                     RJI
                    Alkalinity                    310.1                         44      m9/1               04-16-96                     KW
                    Ammonia Nitrogen              350.1                         0.20    mg/l               04-22-96                     LT
                    Fecal Coliform
                             Grab@21:40PM         SM-16,909C                    198     col/100 ml         04-13-96                     NCW
                    Hardness                      130.1                         116     mg/l               04-15-96                     KW
                    Iron                          236.1                         6.95    mg/l               04-16-96                     RJI
                    Manganese                     243.1                         0.15    mg/1               04-16-96                     RJI
                    Nitrite Nitrogen              353.2                         0.05    mg/l               04-19-96                     LT
                    Nitrate Nitrogen              353.2                         2.05    mg/l               04-19-96                     LT
                    Chloride                      325.2                         42      mg;l               04-24-96                     LT
                    CBOD,                         405.1                         3       M911               04-18-96                     KW
                    Total Suspended Solids        160.2                         180     mg/1               04-22-96                     KW
                    Phosphorus                    365.4                         0.36    mg/l               04-16-96                     LT
                    COD                           44 110;4                      20      mg/1               04-25-96                     NDA
                        J
                    Robert W. S U, &Jr
                    President
                    Reported: May 7, 1996








                                                                                                                                  (814) 474-2044
                              CHURCH laboratory,                              inc.

                                                                                                           7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                 FAIRVIEW, PA. 16415







                                                                   Water Analyses Report



                    Customer:                    Malcolm Pirnie, h1c.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                    Project:                     Ene County Water Quality Monitoring Stt*
                                                 for Lake Erie Watershed                #2758-01
                    Sample ID:                   Event #08W, WALNUT CREEK                                            Lab Log No: 53864
                    Sample Date/Titne:           Aprfl 12,1996/ 20:30PK 22:30PK 00:30AM
                    Sampler:                     R.W. Stallbaum


                    PARAMETER                      EPA                        RESULTS/                    ANALYSIS                 ANALYST
                                                 METHOD                         UNITS                          DATE

                    Arsenic                        206.2                      <0.001    mg/I               04-16-96                     RJI
                    Cadmiwn                        213.2                      <0.0001   mg/l               05-01-96                     RJI
                    Chromium, Total                218.1                      <0.05     mg/I               04-16-96                     RJI
                    Copper                         220.2                        0.003   mg/l               05-07-96                     RJI
                    Lead                           239.2                        0.003   mg/l               04-15-96                     RJI
                    Nickel                         249.1                        0.01    mg/1               04-16-96                     FJI
                    Silver                         272.2                      <0.0002   mg/1               05-07-%                      RJI
                    Zinc                           289.1                        0.032   mg/1               04-15-96                     RJI

                    Aluminum                       202.1                        1.67    mg/1               04-16-96                     RJI
                    Alkalinity                     310.1                        97      mg/1               04-16-96                     KW
                    Ammonia Nitrogen               350.1                        0.12    mg/1               04-22-96                     LT
                    Fecal Coliform
                              Omb@22:30PM          SM-16,909C                   143     col/100 ml         04-13-96                     NCW
                    Hardness                       130.1                        158     mg/l               04-15-96                     KW
                    Iron                           236.1                        2.16    mg/l               04-16-96                     RJI
                    Manganese                      243.1                        0.07    mg/l               04-16-96                     RJI
                    Nitrite Nitrogen               353.2                        0.02    mg11               04-19-96                     LT
                    Nitrate Nitrogen               353.2                        0.71    mg/l               04-19-96                     LT
                    Chloride                       325.2                        65      mg;'l              04-24-96                     LT
                    CBOD,                          405.1                        3       mg/I               04-18-96                     KW
                    Total Suspended Solids         160.2                        68      mg/1               04-22-96                     KW
                    Phosphorus                     365.4                        0.15    mg/l               04-16-96                     LT
                    COD
                                                   410.4                        10      mg/l               04-25-96                     NDA



                                           Jr.
                    Robert W. Si;@@@
                    President
                    Reported:- May 7, 1996








                                                                                                                                    (814) 474-2044
                               CHURCH laboratory, inc.

                                                                                                             7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                   FAIRVIEW, PA. 16415







                                                                    Water Analyses Report




                     Customer:                    Malcolm Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitoring Study
                                                  for Lake Eric Watershed                 #2758-01
                     Sample ID:                   Event #08W, ELK CREEK                                                Lab Log No: 53865
                     Sample Date/Time:            April 12, 1996/ 19:55PK 22:00 PNt 24:00M
                     Sampler:                     P- W. Stallbaurn

                     PARAMETER                      EPA                         RESULTS/                   ANALYSIS                  ANALYST
                                                  METHOD                          UNITS                         DATE


                     Arsenic                        206.2                       <0.001    mg/l               04-15-96                     RJI
                     Cadmium                        213.2                       <0.0001   mg/l               05-01-96                     RJI
                     Chromium, Total                218.1                       <0.05     mg/l               04-16-96                     RJI
                     Copper                         220.2                       <0.001    mg/l               05-07-96                     RJI
                     Lead                           239.2                         0.002   mg/l               04-15-96                     RE
                     Nickel                         249.1                         0.01    mg/l               04-16-96                     RJI
                     Silver                         272.2                       <0.0002   mg/l               05-07-96                     RE
                     Zinc                           289.1                       <0.005    mg/1               04-15-96                     RJI

                     Aluminum                       202.1                         1.35    mg/l               04-16-96                     RJI
                     Alkalinity                     310.1                         70      mg/l               04-16-96                     KW
                     Ammonia Nitrogen               350.1                         0.11    mg/l               04-22-96                     LT
                     Fecal Coliform
                               Grab@22:OOPM         SM-16,909C                    9       col/100 ml         04-13-96                     NCW
                     Hardness                       130.1                         132     mg/l               04-15-96                     KW
                     Iron                           236.1                         1.95    m&4                04-16-96                     RJI
                     Manganese                      243.1                         0.05    mg/l               04-16-96                     RJI
                     Nitrite Nitrogen               353.2                         0.02    mg/l               04-19-%                      LT
                     Nitrate Nitrogen               353.2                         1.16    mg/l               04-19-96                     LT
                     Chloride                       325.2                         30      mg;l               04-24-96                     LT
                     CBOD,                          405.1                         4       mg/l               04-18-96                     KW
                     Total Suspended Solids         160.2                         62      mg/l               04-22-96                     KW
                     Phosphorus                     365.4                         0.14    mg/l.              04-16-96                     LT
                     COD                            410.4                       <10       mg/l               04-25-96                     NDA



                     Robert W. Stallbawn, Jr,
                     President
                     Reported: May 7,1996




                               CHURCH laboratory, inc.                                                                              (814) 474-2044

                                                                                                             7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                  FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                     Customer:                    Malcohn Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitorag Study
                                                  for LAe Eno Watershed                   #2758-01
                     Sample Il):                  Event #08W, TREP BLANK                                               No: 53867
                     Sample Date/Time:            April 12, 1996
                     Sampler:                     N.C. Whiteman

                     PARAMETER                      EPA                         RESULTS/                     ANALYSIS                ANALYST
                                                  METHOD                          UNITS                          DATE


                     Arsenic                        206.2                       <0.001    mg/l               04-15-96                      RJI
                     Cadmium                        213.2                       <0.0001   mg/l               05-03-96                      RJI
                     Chromium, Total                218*1                       <0.05     mg/l               04-16-96                      RJI
                     Copper                         220.2                       <0.001    mg/l               05-03-96                      RJI
                     Lead                           239.2                       <0.001    mg/l               04-15-96                      RE
                     Nickel                         249.1                       < 0.01    mg/l               04-16-96                      RE
                     Silver                         272.2                       <0.0002   mg/l               05-03-96                      RE
                     Zinc                           289.1                       <0.005    mg/l               04-15-96                      RJI

                     Aluminum                       202*1                       <0.1      mg/l               04-16-96                      RJI
                     Alkalinity                     310.1                       <1        mg/l               04-16-96                      KW
                     Ammonia Nitrogen               350.1                       <0.01     mg/l               04-22-96                      LT
                     Fecal Coliform       SM-16,909C                            0         col/100 ml         04-13-96                      NC`W
                     Hardness                       130.1                       <2        mg/l               04-15-96                      KW
                     Iron                           236.1                       <0.03     mg/l               04-16-96                      RJI
                     Manganese                      243.1                       <0.01     mg/l               04-16-96                      RJI
                     Nitrite Nitrogen               353.2                       <0.01     mg/l               04-19-96                      LT
                     Nitrate Nitrogen               353.2                       <0.01     M94                04-19-96                      LT
                     Chloride                       325.2                       <2        mg;l               04-24-96                      LT
                     CBOD.,                         405.1                         2       mg/l               04-18-96                      KW
                     Total Suspended Solids         160.2                       <2        mg/l               04-22-96                      KW
                     Phosphorus                     365.4                       <0.01     mg/l               04-16-96                      LT
                     COD                            410.4                       <10       mg/l               04-25-96                      NDA
                     Ro6 2WASW@aum, AJr.
                     President


                     Reported: May 7,1996



            SEP-19-96 THU 02:52 PM CHURCH LABORATORY, INC.                                                 &I.+ '+   74 2044            ---- --      r- k-1 _r


                                CHURCH laboratory, inc.                                                                           (814) 474-2044

                                                                                                           7897 CHOSTNUT STREET - P.Q. IDOX Ba
                                                                                                                                 FAIRVIEW, PA. 16415






                                                                    Field Analyses RepiDrt


                     Customer:                   Ivulcohn Ph-rdc' Jnr'.
                                                 S. 3515 Abbott Road
                                                 Buffalo, NY 14219

                     Project:                    Erie County Water Quality Monitoli% Study
                     Sam* ID:                    for Lake Eric Watershed                 #2758-01
                                                 Event 408W, TWELVE MILE CREEK
                     Sample Date/Time:           April 12,1996
                     Sampler:                    N. C. Whitmun

                     TIME                        PARAMETER                    RESULTS/                    ANALYST
                                                                                 UNITS
                     19:40 PM                    P14                          8.2                            NCW
                     21:40 PM                    pH                           7.6                            NCW
                     23:35 PM                    pH                           7.6                            NCV
                     19:40 PM                    Msolved Oxygen               12.55      ing/l               NC-Uf
                     21,40 PM                    Dissolved Oxygen             12-71      mgn                 NCW
                     2335 FM                     Disiohvd Oxygen              13.        me                  NCW
                     19:40 PM                    Temperature                  85         0 C
                     21:40 PM                    Temperature                  7.6        VC                  NCW
                     23:35 PM                    Tempoisture                             0 C                 NCV
                                                                              7                              NCW
                     19*3 PM                     COnductivitY                 354        VS/Cm               NMI
                     21:40 PM                    Conductivity                 333        UJI/Cin             NCW
                     23:33 PM                    Conductivity                 306        usiom               NCW
                     19:40 PM                    Velocity *
                     21,40 FW                                                 2.6        fps                 NCW
                                                 velocity *                   4
                     23;35 PM                    veloaty *                               fps                 NCW
                                                                              7          fpii                NCW
                     19;49 PM                    Depth
                     21:40 PM                    Depth                        1,5                            NCW
                     23:35 PM                                                 1,75                           NCW
                                                 Depth                        2.1                            Nr-V
                     *Re, o an vmge of tilree, trials a_
                                                          inS stop watch and Oranges,


                     Ro ett W. StFW aum, Jr,
                     President
                     @k












































                        *5-2-N
                     t(oert "W/sw eAaum'
                     Repoited., April 30, 1996
                     Revited- Sept 18, 1996
                                                                  page I of I




                                                                           .07
      SEP-19-96 THU 02:51 PM CHURCH LABORATORY, INC. 814 474 2044          P



                                                                (814) 474-2044
               CHURCH laboratory,     ina.

                                                     7307 CHr:STNUT STREET . p.Q. 13OX 83
                                                                FAIRVIEW PA. 16415





A&


                                 Field Analyses Report



          Customer:     Nblcohn Pirrde, Inc.
                        S. 3 515 Abbott Road
                        Buffalo, NY 14219

          Project:      Elie County Water Quality Mordtoring Study
                        for Lako Me Watenhod #2758-01
          Sample ID:    Event #09W, WALNUT CREEK
          Sample DaWTfiiic: Aptil 12,1996
          Sampler:      R. W. Stallbaum



          TIME          PARAMETER     RESULTS/       ANALYST
                                        UNITS


                                      7.9             RWS
          22:30 FM      pH            8.2             RWS
          00:30 AM      PH
                                      8.0             RWS
          20:30 PM      Difsolved Oxygen 10-68 MO     RWS
          22:30 PM      Dissolved OMen 10.3 V%4       RW3
          00:30 AM      Disgohed Oxygen 10.7 M0       P111VS
          20:30 PM      Tempe=we      8.0   VC
          22:30 PM      Tavaiatm      8.2   0 C       RWS
          0030 AM       Trinperatuxe  7.7   'C        RWS
                                                      Rws
          20:30 PM      Conductivity  463   uskrn     R'%VS
          22:30 PM      Conductivity  526   US/cm     RWS
          0030 AM       Conductivity  628   uskin     RWS
          20:30 PM      Velocity *    2.7   fps       RWS
          22:30 PM      Velooity *    3.6   fps       RNYS
          0030 AM       Velocity      4.1   f@s       RWS







                                      page I Of 2



           SEP-19-96 THU 02:52 PM CHURCH LABORATORY, INC. 814 474 2044
                                 CHURCH laboratory, inc.                                                                                 (8140 474-2044
                                                                                                                 ?3Q70H6%TNUTSTF4EffT - P.O.BOX@3
                                                                                                                                        FAIRVIew, PA, 16415






                      Field Analyses Report
                      Malcolm Firnie, Inr,.                                                                                page 2 Of 2

                      Project:                        Erie County Water Quality Monitofing Study
                                                      for I-Ike. E lie Watershed                #2759-01
                      Sasnple ID:                     Event #08w,%VALNUT CRFEX
                      Sample Date/V=:                 Aptil 12,1996
                      Sampler:                        R. W. Staftaum



                      TIME                            PARAMETER                     RESULTS1                      ANALYST
                                                                                     LNITS

                      20,.30 P11- St I                DLOmwe                        18-86       11                   RWS
                                 . St2                from blidge                   18.97       ft                   RWS
                                 -St3                 to                            19.14       ft                   R%VS
                                 - St4                  ater aurface                19.59       ft                   RWS
                                 - sts                                              19.43       ft                   RWS
                                 -St9                                               19,31       ft                   RWS


                      21,10 PM, 1, 1                  D@#taftce                     18-92       ft                   RIVS
                                   St2                from bridge                   1914        ft                   RWS
                                   St 3               to                            19,25       ft                   RWS
                                   St 4               water awfa0v                  19.37       ft                   RIVS
                                 -9t9                                               20.07       ft                   RwS
                                   St 10                                            19-28       R                    Rws

                      003 0 AM- St I                  DiAxnce                       18.62       ft                   RwS
                                   St 2               from bridge                   18.97       :R                   RWS
                                   St 3               to                            19.23       ft                   Rws
                                 -St4                 water yahoo                   ISS4        ft                   RWS
                                   St 5                                             18.61       ft                   RWS
                                      9                                             19-12       ft                   R\VS



                      Robert W. S       auni, Jr,
                      pleaident
                      Reported: AW 30, 1996
                      Revited: Sept 18, 1 g_Q,6
                                        auni, Jr,



        SEP-19-96 THU 02:51 PM CHURCH LABORATORY, INC. 814 474 2044                                -


                      CHURCH laboratory, inc.                                             (614) 474-2044

                                                                          7397 OWESTNVT STREET - P.O. BOX aa
                                                                                         PAIRVIGW, PA. 16415






                                               Field Analyses Report


              Customer:           Malcolm Pirnie, Inc..
                                  S. 3 515 Abbott Read
                                  Buffalo, NY 14219

              Project:            Efic County Water Quality Monitoring Study
                                  for Lake Erie Watershed     #2759-01
              Sample tD:          Event:908W, ELK CREEK
              Sample Date/Time:   Aprd 12, 1996
              Sampler:            R.W. Stallbaum



              TIME                PARAMETER           RESULTS/            ANALYST
                                                        UNITS
              19:55 PM            PH                                       RWS
              22:00 PM            PH                                       RWS
              24 00 M             PH                  7.9                  RWS
              19.55 Phi           Dirsolved Oxygen    10.47 1n&1           RwS
              22:00 PM            Disoolvgd oxygen    10.0  nlgll          RWS
              24:00 M             Dipwlved Oxygen     10,0  Irkwi          RWS
              19:55 PM            Temperature         9.7   a C            RWS
              22:00 PM            Temperature         9.2    C             RWS
              24:00 M             Temperahm           8.6   a C            RWS
              19;55 Phl           conduclivity        329   us/an          RwS
              22:00 PM            Conductivity        341   usion          RWS
              24:00 M             Conductivity        372   us/cm          RWS
              19:53 PM            Velocity *          2.6   fps            RWS
              2'2:00 PM           Velocity *          16    fps            RWS
              24:00 M             Velocity *          2.9   fps            PIWS
              19:55 PM            Depth               2.5   ft             RWS
              22,00 PM            Depal               2.61  ft             RWS
              24:00 M             Depth               2.65  ft             RWS
              'Reou  T 11verage of fluce triolq uvi218 Stop Watch suid oranges,


              Robert W.
              President
              Reported; Apti130,19!P6
              @9





              R






              Revised: Sept IS, 1996








                                                                                                                                            (814) 474-2044
                                 CHURCH laboratory, inc.                                                            7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                           FAIRVIEW, PA. 16415







                                                                         Water Analyses Report




                      Customer:                      Malcolm Pirnie, Inc.
                                                     S. 3515 Abbott Road
                                                     Buffalo, NY 14219

                      Project:                       Ene County Water Quality Monitoring Stucly
                                                     for Lake Ene Watershed                     #2758-01
                      Sample H):                     Event #09W, TWELVE ABLE CREEK                                            Lab Log No: 54116
                      Sample Date/Time:              April 30, 1996/ 11:40AK 13:40 PK 15:40PM
                      Sampler:                       N. C. Whiteman

                      PARAMETER                        EPA                           RESULTS/                     ANALYSIS                   ANALYST
                                                     METHOD                            UNITS                            DATE


                      Arsenic                          206.2                           0.007    nig/l               05-02-96                       RA
                      Cadmium                          213.2                         <0.0001    mg/1                05-01-96                       RA
                      Chromium, Total                  218.1                         <0.05      mg/l                05-02-96                       RJI
                      Copper                           220.2                           0.002    mg/1                05-07-96                       RJI
                      Lead                             239.2                         <0.001     mg/l                05-01-96                       RJI
                      Nickel                           249.1                           0.05     mg/1                05-03-96                       RJI
                      Silver                           272.2                         <0.0002    mg/1                05-07-96                       RJI
                      Zinc                             289.1                           0.023    mg/1                05-03-96                       RJI

                      Aluminum                         202.1                           5.07     mg/1                05-02-96                       RE
                      Alkalinity                       310.1                           33       m8A                 05-10-%                        KW
                      Ammonia Nitrogen                 350.1                           0.04     mg/l                05-06-96                       LT
                      Fecal Coliform
                                 Gmb@13:40PM           SM-16,909C                      504      col/100 ml          05-01-96                       LT
                      Hardness                         130.1                           70       mg/l                05-01-96                       KW
                      Iron                             236.1                           7.12     mg/l                05-03-96                       RJI
                      Manganese                        243.1                           0.13     mg/l                05-06-96                       RJI
                      Nitrite Nitrogen                 353.2                           0.01     mg/1                05-14-%                        LT
                      Nitrate Nitrogen                 353.2                           1.02     mg/1                05-14-%                        LT
                      Chloride                         325.2                           24       mg;'l               05-10-96                       LT
                      CBOD,                            405.1                           2        mg/l                05-06-96                       KW
                      Total Suspended Solids           160.2                           180      mg/l                05-03-%                        KW
                      Phosphorus                       365.4                           0.32     mg/l                05-03-96                       LT
                      COD                              410.4                           25       mg/l                05-03-96                       NDA
                   4@9














                      Robert W. S@taiflba , @Jr.
                      President
                      Reported: May 17,1996








                                                                                                                                    (814) 474-2044
                              CHURCH laboratory, inc.                                                        7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                   FAIRVIEW, PA. 16415







                                                                    Water Analyses Report




                    Customer:                     Malcohn Pinfie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                    Project:                      Ene County Water Quality Monitoring Sh*
                                                  for LAe Eric Watershed                  #2758-01
                    Sample ID:                    Event #09W, WALNUT CREEK                                             Lab Log No: 54117
                    Sample Daterlime:             April 12, 1996/ 11:40AK 13:40PK 15:40PM
                    Sampler:                      R.W. Stallbaurn


                    PARAMETER                       EPA                         RESULTS/                     ANALYSIS                 ANALYST
                                                  METHOD                          UNITS                          DATE


                    Arsenic                         206.2                         0.003   mg/l               05-02-96                      RJI
                    Cadmium                         213.2                       <0.0001   mg/l               05-01-96                      RJ1
                    Chromium, Total                 218.1                       <0.05     mg/l               05-02-96                      RJI
                    Copper                          220.2                         0.001   mg/l               05-07-96                      RJI
                    Lead                            239.2                         0.002   mg/1               05-01-96                      RJI
                    Nickel                          249.1                         0.07    mg/l               05-03-96                      RR
                    Silver                          272.2                       <0.0002   mg/l               05-07-96                      RJI
                    Zinc                            289.1                         0.084   mg/1               05-03-96                      RJI

                    Ahuninum                        202.1                         17.48   mg/l               05-02-96                      RJI
                    Alkalinity                      310.1                         62      mg/l               05-10-96                      KW
                    Ammonia Nitrogen                350.1                         0.12    mg/1               05-06-96                      LT
                    Fecal Cohfbim
                              Grab@13:40PM          SM-16,909C                    792     col/100 ml         05-01-96                      LT
                    Hardness                        130.1                         100     M84                05-01-96                      KW
                    Iron                            236.1                         25.87   mg/l               05-03-96                      RK
                    Manganese                       243.1                         0.45    mg/l               05-06-96                      RJI
                    Nitrite Nitrogen                353.2                         0.02    mg/l               05-14-96                      LT
                    Nitrate Nitrogen                353.2                         0.47    mg/l               05-14-96                      LT
                    Chloride                        325.2                         43      mg;l               05-10-96                      LT
                    CBOD,                           405.1                         2       mgtl               05-06-96                      KW
                    Total Suspended Solids          160.2                         784     mg/l               05-03-96                      KW
                    Phosphonn                       365.4                         0.78    mg/l               05-03-96                      LT
                    COD                             410.4                         40      mg/l               05-03-96                      NDA
                    Robert W.              dir@@
                    President
                    Reported:   May 17,1996







                                                                                                                         (814) 474-2044
                            CHURCH laboratory, inc.

                                                                                                   7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                       FAIRVIEW, PA. 16415







                                                               Water Analyses Report




                   Customer:                  Malcolm Pirnie, Inc.
                                              S. 3515 Abbott Road
                                              Buffalo, NY 14219

                   Project:                   Erie County Water Quality Monimring Study
                                              for Lake Erie Watershed              #2758-01
                   Sample ID:                 Event #09W, ELK CREEK                                          Lab Log No: 54118
                   Sample Date/Time:          April 30, 1996/ 12:00N, 14:10 PK 16:10PM
                   Sampler:                   R. W. Stallbaum.

                   PARAMETER                    EPA                      RESULTS/                  ANALYSIS               ANALYST
                                              METHOD                       UNITS                        DATE


                   Arsenic                      206.2                      0.002   me                05-02-96                   RJI
                   Cadmium                      213.2                    <0.0001   mg/1              05-01-96                   RJI
                   Chromium, Total              218.1                    <0.05     mg/1              05-02-96                   RJI
                   Copper                       220.2                      0.003   me                05-07-96                   RE
                   Lead                         239.2                      0.001   mg/1              05-01-96                   RJI
                   Nickel                       249.1                      0.09    mg/1              05-03-96                   RE
                   Silver                       272.2                    <0.0002   mg/1              05-07-96                   RJI
                   Zinc                         289.1                      0.079   me                05-03-96                   RE

                   Aluminum                     202*1                      17.95   mg/l              05-02-96                   RJI
                   Alkalinity                   310.1                      40      mg/l              05-10-96                   KW
                   Ammonia Nitrogen             350.1                      0.16    mg/l              05-06-96                   LT
                   Fecal Coliform
                            Grab@14:10PM        SM-16,909C                 1116    col/100 ml        05-01-96                   LT
                   Hardness                     130.1                      so      mg/l              05-01-96                   KW
                   Iron                         236.1                      35.64   mg/l              05-03-96                   RJI
                   Manganese                    243.1                      0.42    mg/1              05-06-96                   RJI
                   Nitrite Nitrogen             353.2                      0.03    me                05-14-96                   LT
                   Nitrate Nitrogen             353.2                      0.54    mg/1              05-14-96                   LT
                   Chloride                     325.2                      15      mg;1              05-10-96                   LT
                   CBOD,                        405.1                      2       me                05-06-96                   KW
                   Total Suspended Solids       160.2                      936     me                05-03-96                   KW
                   Phosphorus                   365.4                      0.95    mg/1              05-03-96                   LT
                   COD                          410.4                      30      M94               05-03-96                   NDA




                   Robert w. tallba      Jr.
                   President
                   Reported: May 17, 1996








                                                                                                                                   (814) 474-2044
                               CHURCH laboratory, inc.                                                       7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                  FAIRVIEW, PA. 16415







                                                                    Water Analyses Report




                     Customer:                    Malcolm Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Erie County Water Quality Monitoring Study
                                                  for L*e Elie Watershed                  #2758-01
                     Sample ID:                   Event #09W, TRIP BLANK                                               No: 54116A
                     Sample Date/Time:            Apn130,1996
                     Sampler:                     N.C. Whiteman                                                                      ANALYST
                     PARAMETER                      EPA                         RESULTS/                     ANALYSIS
                                                  METHOD                          UNITS                          DATE


                     Arsenic                        206.2                       <0.001    mg4                05-02-96                      RJI
                     Cadmium                        213.2                       <0.0001   mg/l               05-01-96                      RA
                     Chromiwn, Total                218.1                       <0.05     mg/l               05-02-96                      RJI
                     Copper                         220.2                       <0.001    mg/l               05-07-96                      RJI
                     Lead                           239.2                       <0.001    mg/l               05-01-96                      RJI
                     Nickel                         249.1                       < 0.01    mg/l               05-03-96                      RJI
                     Silver                         272.2                       <0.0002   mg/l               05-07-96                      RE
                     Zinc                           289.1                       <0.005    mg/1               05-03-96                      RJI

                     Aluminum                       202.1                       <0. I     mg/l               05-02-96                      RJI
                     Alkalinity                     310.1                       < I       mg/1               05-10-96                      KW
                     Ammonia Nitrogen               350.1                       <0.01     mg/l               05-06-96                      LT
                     Fecal Coliform       SM-16,909C                            0         col/100 ml         05-01-96                      LT
                     Hardness                       130.1                       <2        mg/l               05-01-96                      KW
                     Iron                           236.1                       <0.03     mg/l               05-03-96                      RJI
                     Manganese                      243.1                       <0.01     mg/l               05-06-96                      RE
                     Nitrite Nitrogen               353.2                       <0.01     mg                 05-14-96                      LT
                     Nitrate Nitrogen               353.2                       <0.01     M&4                05-14-96                      LT
                     Chloride                       325.2                       <2        mg;l               05-10-96                      LT
                     CBOD,                          405.1                         2       mg/1               05-06-96                      KW
                     Total Suspended Solids         160.2                         2       mg/l               05-03-96                      KW
                     Phosphorus                     365.4                       <0.01     mg/l               05-03-96                      LT
                     COD                            410.4                       <10       mg/l               05-15-96                      NDA
                                 2

                     Robert W. Stallbsum, Jr.
                     President


                     Reported: May 17,1996




                                                                                                                                           P
         SEP-19-96 THU 02:54 PM CHURCH LABORATORY, INC. 814 474 2044...                                                                     .13

                            CHURCH laboratory, inc.                                                                      (814) 474-2044

                                                                                                   73970HESTNUTSTREET * P.O.SQX@2
                                                                                                                       FAIRVIEW, PA. 10415







                                                              Field Analyses Report


                  Customer:                 Malcolm Pirnie, Inc.
                                            S. 3515 Abbott Road
                                            BufWo, NY 14219

                  Project:                  Eric County Water Quality 10ordtoring Study
                                            for Lake Erie Watershed               #2758-01
                  SamPle ID:                EveAt #09W, TWELVE MILE CREEK
                  Sample Date/Tirne:        Aprff 30, 1996
                  Sampler:                  N. C. Mdteman

                  TIME                      PAR"ETER                   RESULTS/                   ANALYST
                                                                           'UNITS
                  11:40 Ph4                 PH                         8.1                           NCW
                  11:40 PM                  PH                         8.1                           NCW
                  15:40 PM                  PH                         8.1                           NCW
                  11:4o Pm                  Wsolvcd oxygen             11.13      Vgf1               NCW
                  1):40 PM                  Dissolved oxysen           11-34      311gl              NCW
                  15:40 PM                  Dissolved oxygen           9.94       mg1l               NCW

                  11:40 FM                  Temperatme                 10A         C
                  13:40 PM                  TeInperatUrg               9.3        'r                 NCW
                  15:40 PM                                                                           NCW
                                            Ternpenture                9.4         C                 NCW
                  11;40 PM                  Conductivity               249        USI'm              NCW
                  13:40 P?-J                Conductivity               213        usico              NCW
                  15:40 FM                  Coliductivity              168        usicm              NC`W
                  11:40 PM                  Velocity *                 5.8        fps                NCW
                  13:40 PA4                 Velocity *                 8.3        ipa                NCW
                  15AG PM                   velocity *                 7.4        f@z                NCW
                  11:40 Phl                 Dq-,th                     1,75       R                  NCW
                  13:40 PM                  Depth                      2.75       ft                 NCW
                  15:40 PM                  Depth                      3          ft                 NCW
                  Result is 2n average of tilzee trials u',,ing tstop watch and orwWo.


                  Ro ert . S    aum. yr.
                  President
                  Repoited: May 17,1906
                  Revised: Sept 18, 1996
                                                             page I of I



         SEP-19-96 THU 02:53 PM CHURCH LABORATORY, INC. 814 474 2044                                                      P.11


                          CHURCH laboratory, inc.                                                          (814) 414-20414

                                                                                        7397 CHESTNUT STRF-IET - P-0-EOXQ3
                                                                                                          PAIRVIEW.PA 16415






                                                        Field Analyses Report



                Customer:               Malcolm Pirnie, jnc,.
                                        S - 3515 Abbott Road
                                        Buffalo, NY 14219

                Project-                Erie County Water QwUly Monitoling Stucly
                                        for Lake Eric Watershed          #2758-01
                S ample ID:             Event #09W, WALNUT CRET.K
                Sample Date/Time:       Apfi130@1996
                Sampler.                R. W. Stallbaum



                TIME                    PARAMETER               RESULTS/               ANALYST
                                                                  UNITS

                11:40 AM                PH                      7.4                       RWS
                1330 PM                 pH                      7.6                       RWS
                15A PM                  pH                      7,6                       RwS
                11:40 AM                Dissolved Oxygeu        @.2      m&4              RWS
                13:40 PM                DL"olved Oxygen         9.2      -Yn&l            RwS
                15:40PM                 Dissolved oxygen        9.0      11184            RWS
                11.40 AM                Temperature             9.6      a C              RWS
                13:40 PM                Tempei-sture            9.3        C              RWS
                15:40 PM                Tempetahm               9.3      0 C              RNVS
                11:40 AM                Conductivity            410      u-s1cm           RWS
                13-40 PM                conduatiNity            343      us/w             PIWS
                15:40 PM                Conductivity            261      us/cm            RWS
                11:40 AM                Velocity                4.9      fps            RWS
                13:40 PN5               Velocity                6.5      fp 9           RWS
                15:40 PAJ               Velocity                6.9      fps            RWS






                                                              page 1 of 2



            SEP-19-96 THU 02:54 PM CHURCH LABORATORY, INC. 814 474 2044

                                    CHURCH laboratory, inc.                                                                                       (814) 474-2044

                                                                                                                        7307 CHF-6TNUT STRIEE"r - P.O. 5ox $a
                                                                                                                                                PAIRVIEW, PA. 16415






                       Field Analyses Report
                       Malcolm Pirrie, Inc.                                                                                       Page 2 of 2

                       Project:                         Efie County Water Quality Monitoring Study
                                                        for Lake Erie Watershed                      #2758-01
                       Samplv ID:                       Evont #09WWALNUT CREEK
                       Sample, DatcfTime.;              April 30, 1996
                       Sampler:                         R. W. Stallbaura

                       TIME                             PARANIETER                     RESULTSV                         ANALYST
                                                                                         UNITS


                       11AD AM- St I                    Distance                       17-76         ft                   RWS
                                    -St2                fromblidge                     18.72         ft                   RWS
                                    -SO                 to                             18.14         ft                   RWS
                                    - St 4              water ffwface                  18.45         ft                   RW3
                                    _St5                                               18.58         ft                   RWS
                                    - St 7                                             18-54         R                    RWS
                                    - St a                                             18.56         ft                   RWS
                                    St 9                                               18.69         ft                   P.WS

                       13:40 PAI- St I                  Distance                       16.71         ft                   RWS
                                    - St 2              from bridge                    11,28         R                    RWS
                                    - St 3              to                             17.96         ft                   RWS
                                    -St4                water surface                  17.76         ft                   RWS
                                    -St5                                               17.96         ft                   RWS
                                    - St 6                                             18-22         ft                   RWS
                                    - St 7                                             1811          ft                   RWS
                                    sts                                                17,74         ft                   RWS
                                    St9                                                19.13         :R                   RWS
                                    St 10                                              19.29         ft                   RWS

                       15;40 PM- St I                   Di9tance                       16.72         ft                   R*%VS
                                    - St 2              fivin bridge                   16-48         it                   RWS
                                    _St3                to                             17.11         ft                   RWS
                                    - St 4              water surface                  17-56         fk                   RWS
                                    -st5                                               17.6          ft                   RWS
                                    -St6                                               17.14         ft                   RWS
                                    St 7                                               17,26         ft                   R%VS
                                    -%s                                                17,48         ft                   RWS
                                    St 9                                               17-35         ft                   RWS
                                        10                                             1794          ft                   RWS
                       Ro@rt 2WS@n aum, &Jr@
                       President
                     @9
























































                       Reported: May 17,1996
                       Roised: Sept 18, 1996



            SEP-19-96 THu e2:53 PM CHURCH LABORATORY, INC. 814 474                                                                                          P.10

                                 CHURCH laboratory, inc.                                                                                 (814) 474-2044

                                                                                                                1397 CHESTNUT STPWeT - P.O.BOY63
                                                                                                                                       FAIRVIEW PA. 16415







                                                                       Field Analyses Report


                      Customer:                     Malcolin Pimie, Inc.
                                                    S. 3515 Abbott Road
                                                    Buffalo, NY 14219

                      Project:                      Eric County Water Quality Mordtoring Study
                                                    fo.r Lake Erie watershed                  #2758-01
                      S ample ID:                   EVent #09W, ELK CREEK
                      Sample Date/Thne:             Apiil 3 0, 1996
                      Sampler.-                     R.W. StAffbaum



                      TIME                          PARAAMTER                     RESULT&                       ANALYST
                                                                                     UNITS
                      12;00 N                       p14                           7.5                              RWS
                      14,10PM                       PH                            7.5                              RWS
                      16 10 PM                      pli                           7.3                              RWS
                      12:00 N                       Dissolved oxnen               8.9      n1vi                    RWS
                      14:10 PM                      Di.--"Vod Oxygen              8.9      Mg/1                    RWS
                      16:10 PU                      Dissolved Oxygvn              8.9      mg/L                    RWS
                      12:00 N                       Temperature                   9.7      oc
                      14; 10 FAI                    'rejuperature                 9.6      9C                      RWS
                      16:10PM                       Temperature                   9.5      6C                      RWS
                      12:00 N                       Conductivity                  227      VNCM                    RWS
                      14: 10 Phl                    Conducdvity                                                    RWS
                      16; 10 PRI                    Conductivity                  195      us/cm                   RWS
                                                                                  161      US/Gyn                  RWS
                      12;00 N                       Velocity *                    5.3      fps                     RWS
                      ":", Pm                       Velocity *                    7A       fps                     RWS
                      16: 10 Phl                    Velocity -                    6.8      fps                     RWS
                      12:00 N                       DeptlL at east woul           4.75     A                       RW3
                      14:10 FM                      nepth         n
                      16: 10 P                      Depth         of              6.25     ti                      RWS
                      *Re t is                                                    7.5      It                      RWS
                                   averag346=11` bial's QS* 8t0p watch and orWes,

                      Ro itws         aum. Jr.
                            P
                      a,             -2
                       be        aaum5.Jr.Z/
                      President

                      Reported: May 17,,1996
                      Reviged: Sept 18, lg!;6








                                                                                                                                   (814) 474-2044
                              CHURCH laboratory, inc.

                                                                                                             7397 CHESTNUT STREET - P.O.BOX83
                                                                                                                                  FAIRVIEW, PA. 16415







                                                                     Water Analyses Report



                     Customer:                    Malcohn Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219

                     Project:                     Ene County Water Quality Monitoring Su*
                                                  for Like Erie Watershed                 #2758-01
                     Sample ID:                   Event #10W, TWELVE ABLE CREEK                                        Lab Log No: 54293
                     Sample DatefIlme:            May 9-10,1996/ 21:30PNt 23:30 PNt 01:30AM
                     Sampler:                     N. C. Whiteman


                     PARAMETER                      EPA                         RESULTS/                     ANALYSIS                ANALYST
                                                  METHOD                          UNITS                          DATE


                     Arsenic                        206.2                         0.001   mg/1               05-14-96                      RJ1
                     Cadmium                        213.2                         0.0001  mgA                05-10-96                      RJI
                     Chromium, Total                218.1                       <0.05     mg11               05-16-96                      RJl
                     Copper                         220.2                       <0.001    mg/1               05-10-%                       RJI
                     Lead                           239.2                         0.002   me                 05-14-96                      RJI
                     Nickel                         249.1                       <0.01     Mg/1               05-16-96                      RJ1
                     Silver                         272.2                       <0.0002   mg/1               05-14-96                      RE
                     Zinc                           289.1                         0.006   mg/l               05-16-96                      RJI

                     Alwninum                       202.1                         1.09    mg/l               05-17-96                      RA
                     Alkalinity                     310.1                         43      mg/1               05-10-96                      KW
                     Ammonia Nitrogen               350.1                         0.42    mg/l               05-13-96                      LT
                     Fecal Coliform
                               Gmb@23:30PM          SM-16,909C                    700     col/100 ml         05-11-96                      LT
                     Hardness                       130.1                         90      mg/1               05-10-96                      KW
                     Iron                           236.1                         1.29    mg/l               05-16-96                      RJI
                     Manganese                      243.1                         0.05    mg/l               05-10-96                      RJI
                     Nitrite Nitrogen               353.2                         0.02    mg/l               05-14-96                      LT
                     Nitrate Nitrogen               353.2                         2.98    mg/l               05-14-96                      LT
                     Chloride                       325.2                         31      mg;1               05-10-96                      LT
                     CBOD,                          405.1                         2       mg/l               05-15-96                      KW
                     Total Suspended Solids         160.2                         50      mg/1               05-17-96                      KW
                     Phosphorus                     365.4                         0.01    mg/l               05-16-96                      LT
                     CO;                            410.4                         20      mg/1               05-15-96                      NDA


                     Robert W. Stallbaum, Jr.
                     President
                     Reported: May 17,1996








                                                                                                                                   (814) 474-2044
                               CHURCH laboratory,                              inc.

                                                                                                             7397 CHESTNUT STREET o P.O. BOX 83
                                                                                                                                  FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                     Customer:                    Malcolm Pirnie, Inc.
                                                  S. 3515 Abbott Road
                                                  Buffalo, NY 14219.

                     Project:                     Ene County Water Quality Monitonng Sh*
                                                  for Lake Eno Watershed                  #2758-01
                     Sample ID:                   Event #10W, WALNUT CREEK                                             Lab Log No: 54294
                     Sample Date/Time:            May 9-10,1996/ 23:30PK 01:30AK 03:30AM
                     Sampler:                     P-W. Stallbawn

                     PARAMETER                      EPA                         RESULTS/                     ANALYSIS                ANALYST
                                                  METHOD                          UNITS                          DATE


                     Arsenic                        206.2                         0.002   mg/l               05-14-96                      RJI
                     Cadmium                        213.2                         0.0002  mg/1               05-10-96                      RJI
                     Chromium, Total                218.1                         0.05    mg/l               05-16-96                      RJI
                     Copper                         220.2                         0.007   mg/l               05-10-96                      RJI
                     Lead                           239.2                         0.014   mg/1               05-14-96                      RJI
                     Nickel                         249.1                         0.02    mg/l               05-16-96                      RJI
                     Silver                         272.2                       <0.0002   mg/l               05-14-96                      RJI
                     zinc                           289.1                         0.076   mg/I               05-16-96                      RA

                     Aluminum                       202.1                         19.03   mg/l               05-17-96                      RE
                     Alkalinity                     310.1                         45      M94                05-10-96                      KW
                     Ammonia Nitrogen               350.1                         0.09    mg/l               05-13-96                      LT
                     Fecal Coliform
                               (hub@01:30AM         SM-16,909C                    10100   col/100 ml         05-11-96                      LT
                     Hardness                       130.1                         74      mg/l               05-10-96                      KW
                     Iron                           236.1                         20.22   mg/1               05-16-96                      RJI
                     Manganese                      243.1                         0.30    mg/l               05-16-96                      RJI
                     Nitrite Nitrogen               353.2                         0.14    mg/l               05-14-96                      LT
                     Nitrate Nitrogen               353.2                         0.44    mg/l               05-14-96                      LT
                     Chloride                       325.2                         22      mg;l               05-10-96                      LT
                     CBOD.,                         405.1                         8       mg/l               05-15-96                      KW
                     Total Suspended Solids         160.2                         2504    mg/1               05-17-96                      KW
                     Phosphorus                     365.4                         2.08    mg/l               05-16-96                      LT
                                                    410.4
                     Co@@.                                                        20      mg/l               05-15-96                      NDA
                     Robert W.Stallbaum,
                     President
                     Reported: May 17,1996







                                                                                                                                    (814) 474-2044
                               CHURCH laboratory, inc.

                                                                                                             7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                                   FAIRVIEW, PA. 16415







                                                                     Water Analyses Report




                      Customer:                    Malcohn Phide, Inc.
                                                   S. 3515 Abbott Road
                                                   Buffalo, NY 14219

                      Project:                     Ene County Water Quafity Monitoring Study
                                                   for Lake Eric Watershed                #2758-01
                      Sample ID:                   Event #10W, ELK CREEK                                               Lab Log No: 54295
                      Sample Date/Tirne:           May 9-10, 1996/ 23:00PK 01:00AK 03:00AM
                      Sampler:                     P- W. Stallbawn

                      PARAMETER                     EPA                         RESULTS/                     ANALYSIS                 ANALYST
                                                   METHOD                          UNITS                         DATE


                      Arsenic                       206.2                          0.003  mg/l               05-14-96                      RJI
                      Cadmium                       213.2                        <0.0001  mg/1               05-10-96                      RR
                      Chromium, Total               218.1                          0.06   mg/1               05-11-96                      RJI
                      Copper                        220.2                          0.003  mg/1               05-10-96                      RJI
                      Lead                          239.2                          0.009  mg/l               05-14-96                      RH
                      Nickel                        249.1                          0.02   mg/1               05-16-96                      RJI
                      Silver                        272.2                        <0.0002  mg/l               05-14-96                      RJI
                      Zinc                          289.1                          0.079  mg1l               05-16-96                      RJI

                      Almninum                      202.1                          18.18  mg/l               05-17-96                      RJI
                      Alkalinity                    310.1                          30     mg/1               05-10-96                      KW
                      Ammonia Nitrogen              350.1                          0.07   mg/l               05-13-96                      LT
                      Fecal Colifozm
                               Gmb@01:00AM          SM-16,909C                     6400   col/100 ml         05-11-96                      LT
                      Hardness                      130.1                          55     mg/l               05-10-96                      KW
                      Iron                          236.1                          19.87  mg/l               05-16-96                      RJI
                      Manganese                     243.1                          0.25   mg/1               05-16-96                      RJI
                      Nitrite Nitrogen              353.2                          0.20   mg/1               05-14-96                      LT
                      Nitrate Nitrogen              353.2                          0.47   mg/l               05-14-96                      LT
                      Chloride                      325.2                          8.4    mg;1               05-10-96                      LT
                      CBOD,                         405.1                          6      mg/I               05-15-96                      KW
                      Total Suspended Solids        160.2                          3428   mg/l               05-17-96                      KW
                      Phosphorus                    365.4                          2.30   m&4                05-16-96                      LT
                      COD                           410.4                          30     m9ti               05-15-96                      NDA



                      Robert W, Stallbaurn,  'r.
                      President
                      Reported: May 17, 1996







                                                                                                                              (814) 474-2044
                             CHURCH laboratory,                            inc.

                                                                                                        7397 CHESTNUT STREET - P.O. BOX 83
                                                                                                                             FAIRVIEW, PA. 16415







                                                                  Water Analyses Report




                    Customer:                   Malcolm Pirnie, Inc.
                                                S. 3515 Abbott Road
                                                Buffalo, NY 14219

                    Project:                    Ene County Water Quality Monamng Study
                                                for Lake Eric Watershed                #2758-01
                    Sample ID:                  Event #10W, TREP BLANK                                            No: 54298A
                    Sample Date/Tinte:          May 9-10, 1996
                    Sampler:                    N.C. Whiteman

                    PARAMETER                     EPA                        RESULTS/                   ANALYSIS                ANALYST
                                                METHOD                         UNITS                         DATE


                    Arsenic                       206.2                      <0.001    mg/l              05-14-%                      RJI
                    Cadmium                       213.2                      <0.0001   mg/l              05-10-96                     RJI
                    Chromium, Total               218.1                      <0.05     mg/l              05-16-96                     RJI
                    Copper                        220.2                      <0.001    mg/l              05-10-96                     RJI
                    Lead                          239.2                      <0.001    mg/l              05-14-96                     RJI
                    Nickel                        249.1                      < 0.01    mg/l              05-16-96                     RJI
                    Silver                        272.2                      <0.0002   mg/l              05-14-96                     RJI
                    Zinc                          289.1                      <0.005    mg1l              05-16-96                     RR

                    Aluminum                      202.1                      <0.1      1119/1            05-17-96                     RJI
                    Alkabnity                     310.1                      <1        mg/l              05-10-96                     KW
                    Ammonia Nitrogen              350.1                      <0.01     mg/l              05-13-96                     LT
                    Fecal Coliforin     SM-16,909C                           0         col/100 ml        05-11-96                     LT
                    Hardness                      130.1                      <2        mg/l              05-10-96                     KW
                    Iron                          236.1                      <0.03     mg/l              05-16-96                     RJI
                    Manganese                     243.1                      <0.01     mg/l              05-16-96                     RJI
                    Nitrite Nitrogen              353.2                      <0.01     mg/l              05-14-96                     LT
                    Nitrate Nitrogen              353.2                      <0.01     1119/1            05-14-96                     LT
                    Chloride                      325.2                      <2        mg;l              05-10-96                     LT
                    CBOD_,                        405.1                        2       mg/1              05-15-96                     KW
                          Suspended Solids        160.2                        2       11119/1           05-17-96                     KW
                    Phosphorus                    365.4                      <0.01     M94               05-16-96                     LT
                    TOW

                    CO                                                       <10       mg/l              05-15-96                     NDA
                                                  410.4
                    Robert W. Stallb  41F@
                                     am, Jr.
                    President


                    Reported: May 17, 1996



          SEP-19-96 THU 02:55 PM CHURCH LABORATORY, INC. 814 474 2044                                                                            P.14

                              CHURCH laboratory, inc.                                                                         (814) 474-2044

                                                                                                        73R7CHEGTNkJr.5TF3Er&T - PO.SOXa3
                                                                                                                             FAIRVIEvv, PA. 164-15







                                                                  Field Analyses Report



                    Customer:                  Malcolm Pink Inc.
                                               S. 3515 Abbott Road
                                               Buffalo, NY 14219

                    Project:                   Erie County Water Quality Monitoring Study
                                               fO.r Lake Me Watcrshed                  #2758-01
                    Sample ID:                 EVCnt #10W, TWELVEMILE CREEK
                    Sample Date/Time.          MaY 9-10, 1996
                    samplof:                   N. C. Wmemn

                    Tim E                      PAP-MMETER                   RESULT&                     ANALYST
                    21 -30 Pm                  PH                             UNITS
                    2330 PM                    PH                           8.9                           NCW
                    0130 AM                    pH                           8.1                           NCW
                                                                                                          NCW
                    21:30 PM                   Dissolved oxygen             7,57       MgA                N17CW
                    23:30 FM                   Dissolved Oxyrn              7.58
                    01.30AM                                                            me                 NCW
                                               DiSOOlVed OVgen              7.54       mg/l               NCW
                    21:30 PNI                  Temperut"t                   14.9       *C
                    23:30 PXI                  Temperature                  143        2C                 NCW
                    01!30 AM                   Tempemturs                              . C                NCW
                                                                            14.8                          NCW
                    21:30.PM                   Conductivity                 273        Wcm                NCW
                    23:30 PM                   Conductivity                 271        usfem              WCW
                    01:30 Pm                   Conductivity                 253        Lis/am             NCW
                    2 130 rM                   Velocity *                   2.8        fps                NCW
                    23:30 PM                   Velocity *                   6.2
                    01:30 AM                   Velocity *                              fp                 NCW
                                                                            7-5        fps                NC.W
                    21:30 PNJ                  Depth
                    23:30 PM                   Dept3i                       1.5                           NCW
                    01:30 AM                   Depth                        2                             NCW
                    *Result is an &verage offtee triels U8,14 stop watch an 2.5                           NCW
                                                                            d oranⅇ,

                    Robed W, StabaWn, jr.
                    President
                 ZA@














































                    Reported: May 17, IM
                    Revised: SePt 19, 19961                                 page I of I



          SEP-19-96 THU 02:55 PM CHURCH LABORATORY, INC. 814 4T4 2044                                                                        -.P.

                              CHURCH laboratory, inr,.                                                                       (814) 474-2044

                                                                                                        7397 CHESTNUT STREET - P.O.OQX63
                                                                                                                            FAinviEw.PA 40415





                                                                 Field Analyses Report



                   Customer:                   Malcolm Pirwe' Inc.
                                               S. 3515 Abbott Road
                                               DuffalO, NY 14219

                   project:                    Eric County Water Quality moWtoling Study
                                               for Lake F-ric NVatetshed              #2758-01
                   SHnPle 113:                 Event #IONV, WALNUT CREEK
                   Sample Dato/Timc:           may 9-10, 1996
                   Sampler:                    R. W. Stallbaurn



                   TIME                        PARAMETER                   RESULTS/                     ANALYST
                                                                             UNITS
                   23:30PM                     PH                          7.2                           RWS
                   01:30 AM                    PH                          7.6                           Pw$
                   0330 AM                     PH                          7.5                           RWS
                   23:30 Phi                   Dissolved Oxygen            7.8        n)34               Rws
                   0130 AM                     DiqWved Oxygen              8.3        nie                RW3
                   0330 AM                     Dissolved Oxygen            8.4        Mg/l               RWS
                   23:30 PM                    Temperature                 14.9       0 C
                   01:30AM                     Temperature                 14.6       a C                RWS
                   03:30 AM                    Temperattja                 14.4       ac                 RWS
                                                                                                         RwS
                   23:30 PM                    CcMductivity                2129       ustem             RW6
                   01:30 AM                    Conductivity                199        uskjn             RV/S
                   03--30 AM                   Candiwtivity                180        us/cm             RVIS
                   23:30 PM                    Alelocity *
                   01:30 AM                    Velocity *                  8.7        fps               RAVS
                   0330 AM                     Velocity                    7A         f@a               RW3
                                                                           8.6        fps               RWS








                                                                        page I ofz



          SEP-19-96 THU 02:56 PM CHURCH LABORATORY, INC. 814 474 2044

                                CHURCH laboratory, inc.                                                                          (814) 474-2044

                                                                                                          73970HESTNUTSTOREF-7 - PQ,90X83
                                                                                                                                FAfRVISW, PA. 16415





                    FleW Analyses Report
                    Malcohn Pimle, Inc.                                                                            Page 2 of 2

                                                Elie County Water Quality Mon1toring Study
                                                for LAW Efic Watmhed                     42758-01
                    Saniple ID:                 ENVnt #10NVVVALNUT CREEK
                    Sample Date/Titne:          May 9-10, 1996
                    Sampler:                    R. W. Stallbaurn

                    TIME                        PARAMETER                    RESULTS/                     ANALYST
                                                                               UNITS


                    23:30 PM- St I              Distance                     16.7        ft                 RWS
                                -St2              from bzidge                16.64       ft                 RWS
                                -St3              to                         16,91       ft                 RWS
                                -St4              watei MArface              17.03       it                 AWS
                                - St 5                                       17.35       ft                 RWS
                                -st6                                         16.6        ft                 RWS
                                -50                                          16.7        ft                 RWS
                                - St 8                                       17.25       ft                 RW;S
                                -St9                                         Z7.41       ft                 RWS
                                -stio                                        18-21       ft                 RWS

                    0130 AM- St I               Dislance                     16.74       11                 RWS
                                -St2              fronj bridge               16.65       R                  RWS
                                - St 3            to                         17.17       R                  RWS
                                - st 4            water suiface              17-48       ft                 RWS
                                -St5                                         17A2        R                  RNVS
                                St 6                                         16.79       ft                 RWS
                                St 7                                         16.86       R                  RWS
                                St 8                                         17.01       R                  RWS
                                St 9                                         17.27       ft                 RWS
                                                                             17.58       ft                 RWS
                    03:30 AM- St I              DistaAce                     17.18       ft                 RWS
                                .St2              fim bridge                 16.74       ft                 RWS
                                -SO               to                         16.92       ft                 RWS
                                - St 4            water surface              16.88       ft                 RWS
                                -St5                                         17.43       ft                 RWS
                                St 6                                         16.63       ft                 RWS
                                -St7                                         16.87       ft                 RWS
                                - St 8                                       17.07       ft                 RWS
                                - St 9                                       17,2        A                  RWS
                                tio                                          17.83       ft                 RWS


                    Ro ert W. S
                    President
                    Reported: MaY 17,1996
                   @A@











                                -S- 10    Ir
                           'W S*
                     e@d@ent
                    Revised; Sept 18,1996



         SEP-19-96 THU 02:56 PM CHURCH LABORATORY, INC. 814 474 2044                                                          -J"17-

                           CHURCH laboratory, inc.                                                               (814) 474-2044

                                                                                             7397 0HESTNUT STREET - P.0,00Xan
                                                                                                                FAIRVIEW. PA. 1 B41 5







                                                           Field Analyses Report


                  Customer:               Malcolm Piff&, Inc.
                                          S. 3515 Abbott Road
                                          Buffalo, NY 14219

                  Project:                Lie County Water Quality Monitoling Study
                                          for Lake Eric Watershed             #2758-01
                  Sample ID:              Event #10W, FELK ME EK
                  Sample Datc/Time:       May 9-10, 1996
                  Sampler:                R.W. Stallbaurn


                  TIME                    PARAXWER                 RESULTSt                  ANALYST
                                                                       UNITS
                  23,00 Phi               pli                      6.5                         RWS
                  01:30 AM                P11                      7.0                         RWS
                  03 00 AM                P11                      7.3                         RNYS
                  23:00,PM                Dissolvedoxyzen          8.5     zng4                RWS
                  01:00 AM                moolved oxy8pli          8.6     Mg11                RWS
                  03 100 AM               Dissolved oxygen         8.7     M94                 RWS
                   :00 PM                 Temperature              14.6    *C                  RWS
                  01:010 AM               Temperature
                                                                   14,9    'C                  RWS
                  03:00 AM                T102niperature           14.3    -C                  RWS
                  23:00 PM                Conductivity             127     uSlcin              RWS
                  0 1:00 AM               Conductivity             127     uS/cim              RWS
                  03:00 AM                Conductivity             120     US/On               P.WS
                  23 -00 Rf               velocity *               6.6     fps                 RAIS
                  01;00 AM                Velocity *
                  0100 AM                 Velocity *               5.2     fps                 RWS
                                                                   5.7     40                  aws
                  23:00 PM                Depth    at eas-t wan    8,      ft
                  01 '00 AM               Depth                    9.25    ft                  RWS
                  03! 00 AM                                                                    RWS
                  0                       Depth                    7,75
                  Re      an average of tbxgg trials u0itIS stopwatch elld GrO4'as.            RWS

                  Ro eitW,St&U
                  President
                  Reported: May 17,,1996
                  Rcvi3vd: Sept IS, 1996








                                                                                                                          MOAA COASTAL SERVICES CTR UBRAR



                                                                                                                          3 6668 14111476 1