/1996 V.3. Appendices Malcolm PirnieEnvironmental Engineerrs, Scientists & Planners. Water quality management Erie, Lake. Water quality Erie, Lake. Volume 3 - Appendices Engineering Report PENNSYLVANIA COASTAL ZONE MANAGEMENT PROGRAM WATER QUALITY MONITORING STUDY FOR THE LAKE ERIE WATERSHED SEPTEMBER 1996 Project: 2758-001 CZM Project No.: CZ1:94.06PE A REPORT OF TBIE PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION TO THE NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION PURSUANT TO NOAA AWARD NO. - NA470ZO248 This project was financed through a Federal Coastal Zone Management Grant from the Pennsylvania Department of Environmental Protection with funds provided by the National Oceanic and Atmospheric Administration (NOAA). The views expressed herein are those of the author(s) and do not necessarily reflect the view of NOAA or any of its subagencies. m k om irms.n./gev Me of MAL03W PIRNIE ENVIRONMENTAL ENGINEERS, SCIENTISTS & PLANNERS Printed on Recycled Paper MALCOW PIRME APPENDIX A PRECIMATION DATA k \3 tn 114 (T@ 'In 111) -4 lzk q@k elt 4 2758-001 Printed on Recycled Paper ADS ENVIRONMENTAL SERVICES, INC. ERIE-RGI 0.400-- 0-320-- 0.240- 0.080- O.OOO_- Jon Feb Mar Apr May Jun Jul Aug Sep Oct Noy Dec 1995 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG2 2.000- 1.600 1.200- C= 0.800- 0.400- 0.000-- 1 L Jan Feb Mar Apr May Jun Jul Aug Sep Oct Noy Dec 1995 12/1 VE 1&1*17 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG3 1.000-- 0.800 0.600- 0.400- 0.200 0.000- LLI Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 W 104 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG4 2.000- 1.600 1.200- 0.800- 0.400 0.000 'tilid. I J 11 -LL IJL Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 12/1WZ itilm RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG5 1.000- 0.800- 0.600- 0.400- 0.200 0.000 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 1&12:40 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG6 1.000- 0.800- 0.600- 0.400- 0,200 0.000 .it Li Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 12/1 WN itim RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-RG7 1.000- 0.800 0.600- 0.400- 0.200 0.000- al LL Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 12/1Vm 1&14:M RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-01 1,000-- 0.800 0.600 .0 0.400- 0.200 0.000-- Jon Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 M/24/96 Imm RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-01 0.400- 0,320 0.240 0.160- 0.080 0.000 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 M/24/96 lts:15 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-02 2.000- 1.600- 1.200- 0.800- 0.400- 0.000- Jon Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-03 1.000- 0.800 0.600 G 0.400- 0.200 0.000- Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 M/24/96 12M,.'M RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-04 2.000- 1.600 1.200- 0.800- 0.40 0.000- J, Jon Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 0/24/% ImIll RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-05 1.000-- 0.800 0.600 0.400- 0.200 0.000 ba@ A., Lid A pr May Jon Feb Mar Jun Jul Aug Sep Oct Nov Dec 1996 M/24/96 MW2 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-06 1,000- 0.800 0.600 0.400- 0.200- 0.000- Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 0/24/% 12-V:27 RAIN ADS ENVIRONMENTAL SERVICES, INC. ERIE-07 1,000-- 0.800 0.600- 0.400- 0.200 0.000-1. Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 M/24/96 RAIN ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG1 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.11 05/10/95 0.23 05/11/95 0.23 05/12/95 0.02 05/13/95 05/14/95 0.20 05/15/95 05/16/95 05/17/95 0.15 05/18/95 0.01 05/19/95 0.02 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.72 05/25/95 05/26/95 0.13 05/27/95 05/28/95 05/29/95 0.24 05/30/95 0.03 05/31/95 TIME OF REPORT: 07/11/95 12;32:24 TOTAL RAIN FOR MONTH: 2.09 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 05/10/95 05/11/95 05/12/95 05/13/95 05/14/95 05/15/95 05/16/95 05/17/95 05/18/95 05/19/95 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 05/25/95 05/26/95 05/27/95 05/28/95 05/29/95 05/30/95 05/31/95 TIME OF REPORT: 07/11/95 12:58:59 TOTAL RAIN FOR MONTH: 0.00 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.13 05/10/95 0.42 05/11/95 0.50 05/12/95 0.01 05/13/95 0.01 05/14/95 0.37 05/15/95 05/16/95 05/17/95 0.35 05/18/95 0.04 05/19/95 0.02 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.75 05/25/95 05/26/95 0.16 05/27/95 05/28/95 0.01 05/29/95 0.19 05/30/95 0.11 05/31/95 0.01 TIME OF REPORT: 07/12/95 12:01:52 TOTAL RAIN FOR MONTH: 3.08 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.11 05/10/95 0.36 05/11/95 0.29 05/12/95 05/13/95 0.01 05/14/95 0.35 05/15/95 05/16/95 05/17/95 0.21 05/18/95 0.01 05/19/95 0.02 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.77 05/25/95 05/26/95 0.24 05/27/95 05/28/95 05/29/95 0.33 05/30/95 0.07 05/31/95 TIME OF REPORT: 07/11/95 12:59:02 TOTAL RAIN FOR MONTH: 2.77 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.08 05/10/95 0.40 05/11/95 0.45 05/12/95 0.03 05/13/95 05/14/95 0.27 05/15/95 05/16/95 05/17/95 0.35 05/18/95 0.02 05/19/95 0.03 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.73 05/25/95 05/26/95 0.10 05/27/95 05/28/95 05/29/95 0.17 05/30/95 0.16 05/31/95 TIME OF REPORT: 07/12/95 12:07:26 TOTAL RAIN FOR MONTH: 2.79 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.11 05/10/95 0.25 05/11/95 0.41 05/12/95 0.01 05/13/95 05/14/95 0.29 05/15/95 05/16/95 05/17/95 0.20 05/18/95 0.01 05/19/95 0.04 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.77 05/25/95 05/26/95 0.18 05/27/95 05/28/95 05/29/95 0.32 05/30/95 0.07 05/31/95 TIME OF REPORT: 07/12/95 12:01:54 TOTAL RAIN FOR MONTH: 2.66 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 05/01/95 05/02/95 05/03/95 05/04/95 05/05/95 05/06/95 05/07/95 05/08/95 05/09/95 0.10 05/10/95 0.38 05/11/95 0.43 05/12/95 0.01 05/13/95 05/14/95 0.40 05/15/95 05/16/95 05/17/95 0.39 05/18/95 0.04 05/19/95 0.02 05/20/95 05/21/95 05/22/95 05/23/95 05/24/95 0.67 05/25/95 0.09 05/26/95 05/27/95 05/28/95 05/29/95 0.20 05/30/95 0.09 05/31/95 TIME OF REPORT: 07/12/95 12:01:56 TOTAL RAIN FOR MONTH: 2.82 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERZE-RGI RAIN TOTAL RAIN (in) 06/01/95 0.02 06/02/95 0.40 06/03/95 0.02 06/04/95 06/05/95 06/06/95 06/07/95 0.23 06/08/95 0.01 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 '06/24/95 06/25/95 0.03 06/26/95 0.04 06/27/95 0.02 06/28/95 06/29/95 0.04 06/30/95 0.08 TIME OF REPORT: 07/12/95 12:01:58 TOTAL RAIN FOR MONTH: 0.89 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 06/01/95 0.02 06/02/95 0.37 06/03/95 0.01 06/04/95 06/05/95 06/06/95 06/07/95 0.21 06/08/95 0.01 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 06/24/95 06/25/95 0.02 06/26/95 0.05 06/27/95 06/28/95 06/29/95 0.04 06/30/95 0.10 TIME OF REPORT: 07/12/95 12:02:01 TOTAL RAIN FOR MONTH: 0.83 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 06/01/95 0.04 06/02/95 0.18 06/03/95 06/04/95 06/05/95 06/06/95 06/07/95 0.24 06/08/95 0.01 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06115/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 06/24/95 06/25/95 0.05 06/26/95 0.17 06/27/95 0.02 06/28/95 06/29/95 0.06 06/30/95 0.18 TIME OF REPORT: 07/12/95 12:02:03 TOTAL RAIN FOR MONTH: 0.95 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 06/01/95 0.02 06/02/95 0.45 06/03/95 0.04 06/04/95 0.01 06/05/95 06/06/95 06/07/95 0.17 06108/95 0.02 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 06/24/95 06/25/95 0.02 06/26/95 0.02 06/27/95 0.02 06/28/95 06/29/95 0.04 06/30/95 0.08 TIME OF REPORT: 07/12/95 12:02:04 TOTAL RAIN FOR MONTH: 0.89 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 06/01/95 O.Oz 06/02/95 0.18 06/03/95 06/04/95 06/05/95 06/06/95 06/07/95 0.22 06/08/95 0.03 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 06/24/95 06/25/95 0.03 06/26/95 0.03 06/27/95 0.01 06/28/95 06/29/95 0.09 06/30/95 0.12 TIME OF REPORT: 07/12/95 12:02:06 TOTAL RAIN FOR MONTH: 0.73 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 06/01/95 0.03 06/02/95 0.33 06/03/95 06/04/95 06/05/95 06/06/95 06/07/95 0.22 06/08/95 0.01 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 06/22/95 06/23/95 06/24/95 0.02 06/25/95 0.06 06/26/95 06/27/95 06/28/95 06/29/95 06/30/95 TIME OF REPORT: 07/12/95 08:04:54 TOTAL RAIN FOR MONTH: 0.67 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 06/01/95 0.03 06/02/95 0.23 06/03/95 06/04/95 06/05/95 06/06/95 06/07/95 0.18 06/08/95 0.01 06/09/95 06/10/95 06/11/95 06/12/95 06/13/95 06/14/95 06/15/95 06/16/95 06/17/95 06/18/95 06/19/95 06/20/95 06/21/95 0.14 06/22/95 0.24 06/23/95 06/24/95 0.01 06/25/95 0.06 06/26/95 0.18 06/27/95 0.01 06/28/95 0.43 06/29/95 06/30/95 TIME OF REPORT: 07/12/95 08:04:51 TOTAL RAIN FOR MONTH: 1.52 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG1 RAIN TOTAL RAIN (in) 07/01/95 07/02/95 07/03/95 07/04/95 07/05/95 07/06/95 0.73 07/07/95 0.05 07/08/95 0.03 07/09/95 0.01 07/10/95 07/11/95 07/12/95 07/13/95 0.24 07/14/95 07/15/95 07/16/95 0.01 07/17/95 0.01 07/18/95 07/19/95 07/20/95 0.01 07/21/95 0.14 07/22/95 07/23/95 0.22 07/24/95 0.01 07/25/95 0.12 07/26/95 07/27/95 0.22 07/28/95 0.01 07/29/95 0.04 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:25 TOTAL RAIN FOR MONTH: 1.85 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 07/01/95 07/02/95 07/03/95 07/04/95 07/05/95 07/06/95 0.56 07/07/95 0.01 07/08/95 0.04 07/09/95 0.01 07/10/95 07/11/95 07/12/95 07/13/95 0.20 07/14/95 07/15/95 0.01 07/16/95 0.01 07/17/95 07/18/95 07/19/95 07/20/95 0.01 07/21/95 0.09 07/22/95 07/23/95 0.22 07/24/95 07/25/95 0.14 07/26/95 07/27/95 0.22 07/28/95 07/29/95 0.06 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 10:38:38 TOTAL RAIN FOR MONTH: 1.58 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 07/01/95 0.01 07/02/95 07/03/95 07/04/95 07/05/95 07/06/95 0.30 07/07/95 0.32 07/08/95 0.09 07/09/95 0.02 07/10/95 07/11/95 07/12/95 07/13/95 0.18 07/14/95 07/15/95 0.02 07/16/95 0.05 07/17/95 07/18/95 07/19/95 07/20/95 0.02 07/21/95 0.07 07/22/95 07/23/95 0.22 07/24/95 07/25/95 0.13 07/26/95 07/27/95 0.20 07/28/95 07/29/95 0.07 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:27 TOTAL RAIN FOR MONTH: 1.70 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 07iOl/95 07/02/95 07/03/95 07/04/95 07/05/95 07/06/95 0.67 07/07/95 0.03 07/08/95 0.06 07/09/95 0.02 07/10/95 07/11/95 07/12/95 07/13/95 0.22 07/14/95 07/15/95 0.01 07/16/95 0.02 07/17/95 07/18/95 07/19/95 0.05 07/20/95 0.03 07/21/95 0.17 07/22/95 07/23/95 0.27 07/24/95 07/25/95 0.13 07/26/95 07/27/95 0.28 07/28/95 0.01 07/29/95 0.05 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:29 TOTAL RAIN FOR MONTH: 2.02 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 07/01/95 07/02/95 07/03/95 0.28 07/04/95 07/05/95 0.25 07/06/95 0.50 07/07/95 0.02 07/08/95 0.12 07/09/95 0.02 07/10/95 07/11/95 07/12/95 07/13/95 0.28 07/14/95 07/15/95 0.04 07/16/95 0.02 07/17/95 0.01 07/18/95 07/19/95 07/20/95 0.02 07/21/95 0.14 07/22/95 07/23/95 0.17 07/24/95 07/25/95 0.17 07/26/95 07/27/95 0.32 07/28/95 07/29/95 0.10 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:31 TOTAL RAIN FOR MONTH: 2.46 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 07/01/95 07/02/95 07/03/95 07/04/95 07/05/95 07/06/95 0.44 07/07/95 0.03 07/08/95 0.03 07/09/95 0.01 07/10/95 07/11/95 07/12/95 07/13/95 0.26 07/14/95 07/15/95 07/16/95 0.04 07/17/95 07/18/95 07/19/95 07/20/95 0.02 07/21/95 0.07 07/22/95 07/23/95 0.31 07/24/95 0.01 07/25/95 0.13 07/26/95 07/27/95 0.25 07/28/95 07/29/95 0.11 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:33 TOTAL RAIN FOR MONTH: 1.71 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 07/01/95 07/02/95 07/03/95 07104/95 07/05/95 07/06/95 0.24 07/07/95 0.15 07/08/95 0.11 07/09/95 0.01 07/10/95 07/11/95 07/12195 07/13/95 0.19 07/14/95 07/15195 0.03 07/16/95 0.11 07/17/95 07/18/95 07/19/95 07/20/95 0.03 07/21/95 0.05 07/22/95 07/23/95 0.21 07/24/95 0.01 07/25/95 0.15 07/26/95 07/27/95 0.20 07/28/95 07/29/95 0.04 07/30/95 07/31/95 TIME OF REPORT: 08/14/95 13:32:35 TOTAL RAIN FOR MOUTH: 1.53 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG1 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.01 08/03/95 0.02 08/04/95 08/05/95 1.40 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 0.93 08/12/95 0.23 08/13/95 0.08 08/14/95 0.11 08/15/95 08/16/95 08/17195 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 0.04 TIME OF REPORT: 12/16/95 17:35:45 TOTAL RAIN FOR MONTH: 2.82 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.05 08/03/95 08/04/95 08/05/95 1.21 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 0.98 08/12/95 0.38 08/13/95 0.07 08/14/95 0.21 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 0.03 TIME OF REPORT: 12/16/95 17:58:00 TOTAL RAIN FOR MONTH: 2.93 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.07 08/03/95 0.01 08/04/95 08/05/95 1.00 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 1.25 08/12/95 0.47 08/13/95 0.08 08/14/95 0.27 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 TIME OF REPORT: 12/16/95 17:58:02 TOTAL RAIN FOR 14ONTH: 3.15 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.01 08/03/95 08/04/95 08/05/95 1.74 08/06/95 0.01 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 0.94 08/12/95 0.09 08/13/95 0.14 08/14/95 0.23 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 TIME OF REPORT: 12/16/95 17:58:04 TOTAL RAIN FOR MONTH: 3.16 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.67 08/03/95 08/04/95 08/05/95 1.29 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 0.92 08/12/95 0.36 08/13/95 0.11 08/14/95 0.19 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 0.03 TIME OF REPORT: 12/16/95 17!58:06 TOTAL RAIN FOR MONTH: 2.97 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.03 08/03/95 0.04 08/04/95 08/05/95 1.23 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 1.13 08/12/95 0.38 08/13/95 0.11 08/14/95 0.32 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 0.03 TIME OF REPORT: 12/16/95 17:58:08 TOTAL RAIN FOR MONTH: 3.27 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 08/01/95 08/02/95 0.06 08/03/95 08/04/95 0.01 08/05/95 0.80 08/06/95 08/07/95 08/08/95 08/09/95 08/10/95 08/11/95 1.27 08/12/95 0.31 08/13/95 0.08 08/14/95 0.51 08/15/95 08/16/95 08/17/95 08/18/95 08/19/95 08/20/95 08/21/95 08/22/95 08/23/95 08/24/95 08/25/95 08/26/95 08/27/95 08/28/95 08/29/95 08/30/95 08/31/95 TIME OF REPORT: 12/16/95 17:58:10 TOTAL RAIN FOR MONTH: 3.04 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG1 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.21 09/08/95 0.06 09/09/95 0.01 09/10/95 09/11/95 09/12/95 0.01 09/13/95 0.10 09/14/95 0.05 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 0.47 09/21/95 0.02 09/22/95 0.20 09/23/95 09/24/95 09/25/95 09/26/95 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:12 TOTAL RAIN FOR MONTH: 1.13 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.03 09/08/95 0.05 09/09/95 09/10/95 09/11/95 09/12/95 0.01 09/13/95 0.19 09/14/95 0.06 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 0.43 09/21/95 0.03 09/22/95 0.34 09/23/95 09/24/95 09/25/95 09/26/95 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:14 TOTAL RAIN FOR MONTH: 1.14 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.04 09/08/95 0.06 09/09/95 0.01 09/10/95 09/11/95 09/12/95 0.03 09/13/95- 0.37 09/14/95 09/15/95 09/16/95 09/17/95 0.01 09/18/95 09/19/95 09/20/95 0.44 09/21/95 0.04 09/22/95 0.46 09/23/95 09/24/95 09/25/95 09/26/95 0.11 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:16 TOTAL RAIN FOR MONTH: 1.57 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 09/08/95 09/09/95 09/10/95 09/11/95 09/12/95 09/13/95 09/14/95 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 09/21/95 1.19 09/22/95 0.35 09/23/95 09/24/95 09/25/95 09/26/95 0.10 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:17 TOTAL RAIN FOR MONTH: 1.64 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.15 09/08/95 0.06 09/09/95 0.02 09/10/95 09/11195 09/12/95 0.02 09/13/95 0.30 09/14/95 0.04 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 0.37 09/21/95 0.05 09/22/95 0.43 09/23/95 09/24/95 09/25/95 09/26/95 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:19 TOTAL RAIN FOR MONTH: 1.44 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.02 09/08/95 0.06 09/09/95 09/10/95 09/11/95 09/12/95 0.02 09/13/95 0.17 09/14/95 0.03 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 0.49 09/21/95 0.02 09/22/95 0.36 09/23/95 09/24/95 09/25/95 09/26/95 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:21 TOTAL RAIN FOR MONTH: 1.17 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 09/01/95 09/02/95 09/03/95 09/04/95 09/05/95 09/06/95 09/07/95 0.04 09/08/95 0.06 09/09/95 0.02 09/10/95 09/11/05 09/12/95 0.02 09/13/95 0.38 09/14/95 09/15/95 09/16/95 09/17/95 09/18/95 09/19/95 09/20/95 0.43 09/21/95 0.04 09/22/95 0.46 09/23/95 09/24/95 09/25/95 09/26/95 09/27/95 09/28/95 09/29/95 09/30/95 TIME OF REPORT: 12/16/95 17:58:23 TOTAL RAIN FOR MONTH: 1.45 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RGI RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.62 10/04/95 0.35 10/05/95 1.67 10/06/95 0.03 10/07/95 0.02 10/08/95 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.69 10/15/95 0.32 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.69 10/21/95 10/22/95 0.04 10/23/95 10/24/95 10/25/95 10/26/95 10/27/95 0.09 10/28/95 0.19 10/29/95 0.15 10/30/95 0.05 10/31/95 0.07 TIME OF REPORT: 12/16/95 17;58:25 TOTAL RAIN FOR MONTH: 4.98 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.58 10/04/95 0.30 10/05/95 1." 10/06/95 0.15 10/07/95 0.14 10/08/95 0.04 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.73 10/15/95 0.35 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.85 10/21/95 10/22/95 0.06 10/23/95 10/24/95 10/25/95 10/26/95 10/27/95 0.12 10/28/95 0.33 10/29/95 0.10 10/30/95 0.08 10/31/95 0.09 TIME OF REPORT: 12/16/95 17:58:26 TOTAL RAIN FOR MONTH: 5.39 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.64 10/04/95 0.31 10/05/95 1.76 10/06/95 0.16 10/07/95 0.18 10/08/95 0.02 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.79 10/15/95 0.38 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.90 10/21/95 10/22/95 0.09 10/23/95 10/24/95 0.01 10/25/95 10/26/95 10/27/95 0.17 10/28/95 0.41 10/29/95 0.17 10/30/95 0.05 10/31/95 0.09 TIME OF REPORT: 12/16/95 17:58:28 TOTAL RAIN FOR MONTH: 6.13 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.63 10/04/95 0.38 10/05/95 1.76 10/06/95 0.23 10/07/95 0.17 10/08/95 0.06 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.92 10/15/95 0.51 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 1.18 10/21/95 10/22/95 0.07 10/23/95 10/24/95 10/25/95 10/26/95 10/27/95 0.12 10/28/95 0.30 10/29/95 0.28 10/30/95 0.08 10/31/95 0.09 TIME OF REPORT: 12/16/95 17:58:30 TOTAL RAIN FOR MONTH: 6.78 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RGS RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.57 10/04/95 0.32 10/05/95 1.64 10/06/95 0.17 10/07/95 0.12 io/08/95 0.04 10109/95- 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.80 10/15/95 0.38 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.91 10/21/95 10/22/95 0.09 10/23/95 10/24/95 0.01 10/25/95 10/26/95 10/27/95 0.16 10/28/95 0.34 10/29/95 0.25 10/30/95 0.07 10/31/95 0.08 TIME OF REPORT: 12/16/95 17:58:32 TOTAL RAIN FOR MONTH: 5.95 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.61 10/04/95 0.38 10/05/95 1.75 10/06/95 0.20 10/07/95 0.21 10/08/95 0.04 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.84 10/15/95 0.43 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.80 10/21/95 10/22/95 0.06 10/23/95 10/24/95 10/25/95 10/26/95 10/27/95 0.09 10/28/95 0.33 10/29/95 0.12 10/30/95 0.06 10/31/95 0.08 TIME OF REPORT: 12/16/95 17:58:34 TOTAL RAIN FOR MONTH: 6.00 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 10/01/95 10/02/95 10/03/95 0.67 10/04/95 0.31 10/05/95 1.67 10/06/95 0.15 10/07/95 0.20 10/08/95 0.03 10/09/95 10/10/95 10/11/95 10/12/95 10/13/95 10/14/95 0.80 10/15/95 0.34 10/16/95 10/17/95 10/18/95 10/19/95 10/20/95 0.76 10/21/95 10/22/95 0.09 10/23/95 10/24/95 10/25/95 10/26/95 10/27/95 0.15 10/28/95 0.40 10/29/95 0.12 10/30/95 0.03 10/31/95 0.09 TIME OF REPORT: 12/16/95 17:58:35 TOTAL RAIN FOR MONTH: 5.81 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RGI RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.52 11/03/95 0.01 11/04/95 0.05 11/05/95 11/06/95 11/07/95 0.51 11/08/95 0.01 11/09/95 11/10/95 0.65 11/11/95 0.96 11/12/95 11/13/95 0.02 11/14/95 0.27 li/15/95 0.31 11/16/95 0.02 11/17/95 0.06 11/19/95 0.12 11/19/95 11/20/95 11/21/95 0.32 11/22/95 11/23/95 11/24/95 0.01 11/25/95 11/26/95 11/27/95 11/28/95 11/29/95 11/30/95 TIME OF REPORT: 12/16/95 17:58:37 TOTAL RAIN FOR MONTH: 3.84 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG2 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.64 11/03/95 0.05 11/04/95 0.14 11/05/95 0.01 11/06/95 11/07/95 0.49 11/08/95 11/09/95 0.02 11/10/95 0.64 11/11/95 1.16 11/12/95 11/13/95 0.02 11/14/95 0.26 11/15/95 0.31 11/16/95 0.03 11/17/95 0.07 11/18/95 0.17 11/19/95 0.01 11/20/95 11/21/95 0.24 11/22/95 11/23/95 0.02 11/24/95 11/25/95 0.01 11/26/95 11/27/95 11/28/95 11/29/95 11/30/95 TIME OF REPORT: 12/16/95 17:58:39 TOTAL RAIN FOR MONTH: 4.29 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG3 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.71 11/03/95 0.06 11/04/95 0.21 11/05/95 0.09 11/06/95 11/07/95 0.50 11/08/95 0.03 11/09/95 0.05 11/10/95 0.69 11/11/95 1.43 11/12/95 11/13/95 0.04 11/14/95 0.34 11/15/95 0.14 11/16/95 0.16 11/17/95 0.47 11/18/95 0.26 11/19/95 0.01 11/20/95 11/21/95 0.22 11/22/95 0.10 11/23/95 0.07 11/24/95 0.04 11/25/95 0.13 11/26/95 11/27/95 11/28/95 0.01 11/29/95 0.07 11/30/95 0.02 TIME OF REPORT: 12/16/95 17:58:41 TOTAL RAIN FOR MONTH: 5.85 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG4 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.69 11/03/95 0.03 11/04/95 0.18 11/05/95 0.01 11/06/95 0.01 11/07/95 0.59 11/08/95 0.05 11/09/95 0.01 11/10/95 0.79 11/11/95 1.35 11/12/95 11/13/95 0.04 11/14/95 0.33 11/15/95 0.62 11/16/95 0.12 11/17/95 0.07 11/18/95 0.18 11/19/95 0.02 11/20/95 11/21/95 0.45 11/22/95 0.01 11/23/95 0.03 11/24/95 0.03 11/25/95 11/26/95 11/27/95 11/28/95 11/29/95 0.06 11/30/95 0.01 TIME OF REPORT: 12/16/95 17:58:43 TOTAL RAIN FOR MONTH: 5.68 ADS ENVIROW14ENTAL SERVICES, INC. LOCATION: ERIE-RG5 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.59 11/03/95 0.07 11/04/95 0.20 11/05/95 0.03 11/06/95 11/07/95 0.52 11/08/95 0.03 11/09/95 0.01 11/10/95 0.64 11/11/95 1.39 11/12/95 11/13/95 0.02 11/14/95 0.40 11/15/95 0.21 11/16/95 0.04 11/17/95 0.34 11/18/95 0.26 11/19/95 0.02 11/20/95 11/21/95 0.21 11/22/95 0.13 11/23/95 0.06 11/24/95 0.02 11/25/95 0.07 11/26/95 0.04 11/27/95 11/28/95 li/29/95 0.05 11/30/95 0.01 TIME OF REPORT: 12/16/95 17:58:45 TOTAL RAIN FOR MONTH: 5.36 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG6 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.64 11/03/95 0.02 11/04/95 0.16 11/05/95 0.02 11/06/95 11/07/95 0.54 11/08/95 0.02 11/09/95 0.02 11/10/95 0.71 11/11/95 1.16 11/12/95 11/13/95 0.05 11/14/95 0.33 11/15/95 0.34 11/16/95 0.07 11/17/95 0.24 11/18/95 0.24 11/19/95 0.01 11/20/95 11/21/95 0.23 11/22/95 0.08 11/23/95 0.06 11/24/95 0.03 11/25/95 0.12 11/26/95 11/27/95 11/28/95 11/29/95 0.07 11/30/95 TIME OF REPORT: 12/16/95 17:58:46 TOTAL RAIN FOR MONTH: 5.16 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-RG7 RAIN TOTAL RAIN (in) 11/01/95 11/02/95 0.68 11/03/95 0.05 11/04/95 0.08 11/05/95 0.03 11/06/95 11/07/95 0.49 11/08/95 0.02 11/09/95 0.01 11/10/95 0.63 11/11/95 1.26 11/12/95 11/13/95 0.02 11/14/95 0.37 11/15/95 0.45 11/16/95 0.04 11/17/95 0.03 11/18/95 0.16 11/19/95 0.01 11/20/95 11/21/95 0.31 11/22/95 0.03 11/23/95 0.02 11/24/95 11/25/95 11/26/95 11/27/95 11/28/95 0.01 11/29/95 0.07 11/30/95 0.01 TIME OF REPORT: 12/16/95 17:58:48 TOTAL RAIN FOR MONTH: 4.78 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-01 RAIN TOTAL RAIN (in) 12/01/95 12/02/95 12/03/95 12/04/95 12/05/95 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 12/15/95 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 12/22/95 12/23/95 12/24/95 12/25/95 12/26/95 12/27/95 12/28/95 12/29/95 12/30/95 12/31/95 TIME OF REPORT: 05/13/96 15:07:23 TOTAL RAIN FOR MONTH: 0.00 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) 12/01/95 0,02 12/02/95 12/03/95 0.07 12/04/95 12/05/95 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 12/15/95 12/16/95 12/17/95 12/18/95 12119/95 12/20/95 12/21/95 12/22/95 12/23/95 12/24/95 12/25/95 12/26/95 12/27/95 12/28/95 12/29/95 12/30/95 12/31/95 TIME OF REPORT: 05/13/96 15:18:38 TOTAL RAIN FOR MONTH: 0.09 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) ----------- 12/01/95 0.04 12/02/95 12/03/95 0.15 12/04/95 12/05/95 0.02 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 1.10 12/15/95 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 12/22/95 12/23/95 12/24/95 12/25/95 12/26/95 12/27/95 12/28/95 12/29/95 12/30/95 0.17 12/31/95 0.21 TIME OF REPORT: 05/13/96 15:19:04 TOTAL RAIN FOR MONTH: 1.69 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAIN (in) .12/01/95 0. 05 12/02/95 12/03/95 0.12 12/04/95 12/05/95 0.01 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 0.81 12/15/95 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 12/22/95 0.02 12/23/95 12/24/95 12/25/95 0.06 12/26/95 12/27/95 12/28/95 12/29/95 12/30/95 12/31/95 TIME OF REPORT: 05/13/96 15:22:20 TOTAL RAIN FOR MONTH: 1.07 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-05 RAIN TOTAL RAIN (in) ------------ 12/01/95 0 . 04 12/02/95 12/03/95 0.16 12/04/95 12/05/95 0.02 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 0.71 12/15/95 0.01 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 12/22/95 12/23/95 12/24/95 12/25/95 12/26/95 12/27/95 12/28/95 12/29/95 0.01 12/30/95 0.15 12/31/95 0.16 TIME OF REPORT: 05/13/96 15:24:27 TOTAL RAIN FOR MONTH: 1.26 - owl ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-06 RAIN TOTAL RAIN (in) 12/01/95 0.03 12/02/95 12/03/95 0.11 12/04/95 12/05/95 0.01 12/06/95 0.01 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95- 12/12/95 12/13/95 12/14/95 0.35 12/15/95 0.01 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 0.03 12/22/95 12/23/95 12/24/95 12/25/95 0.01 12/26/95 12/27/95 12/28/95 0.06 12/29/95 0.03 12/30/95 0.13 12/31/95 0.14 TIME OF REPORT: 05/13/96 15:20:04 TOTAL RAIN FOR MONTH: 0.92 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) 12/01/95 0.03 12/02/95 12/03/95 0.12 12/04/95 12/05/95 0.01 12/06/95 12/07/95 12/08/95 12/09/95 12/10/95 12/11/95 12/12/95 12/13/95 12/14/95 0.67 12/15/95 12/16/95 12/17/95 12/18/95 12/19/95 12/20/95 12/21/95 0.03 12/22/95 0.04 12/23/95 12/24/95, 12/25/95 12/26/95 12/27/95 0.01 12/28/95 0.07 12/29/95 12/30/95 0.02 12/31/95 0.08 TIME OF REPORT: 05/13/96 15:20:13 TOTAL RAIN FOR MONTH: 1.08 ET L :HiNOW IIOJ NIVII IVIOI EV:90:9 L 96/E USO :iNOd3ll JO 3WIi 96AE/LO 96/OE/LO Wo 96/6ZAO 96/9ZAO 90*0 96/LZAO 96/9Z/LO 96/SZ/LO zc*o 96/t7ZAO 9c*o 96/EZAO 96/ZZ/10 96AZAO 96/OZAO 99*0 96/6 L/ L 0 L L'o 96/9 L/ L 0 SO'O 96/Z U L 0 L 0'0 96/9 L/ L 0 96/9 L/ L 0 96/t, L/ L 0 96/E L/ L 0 LO*O 96/Z L/ L 0 96A LAO 96/OLAO 96/60AO 96/90AO 96/LOAO 96/90AO 96/SO/LO 96/tO/ L 0 96/EO/LO 96/ZOAO zo"o 96/LO/LO (Ul) NI Va IV-LU-L NI" LO 311H :NOIiVDOI *DNI 'S3DIAd3S IViN3WNO*dIAN3 SGV ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) 01/01/96 01/02/96 01/03/96 01/04/96 01/05/96 01/06/96 01/07/96 01/08/96 01/09/96 01/10/96 01/11/96 01/12/96 01/13/96 0.11 01/14/96 0.09 01/15/96 01/16/96 01/17/96 01/18/96 0.08 01/19/96 0.79 01/20/96 01/21/96 01/22/96 0.02 01/23/96 0.36 01/24/96 0.21 01/25/96 01/26/96 0.20 01/27/96 0.15 01/28/96 01/29/96 0.02 01/30/96 01/31/96 TIME OF REPORT: 05/13/96 15:25:36 TOTAL RAIN FOR MONTH: 2.03 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) 01/01/96 0.15 01/02/96 01/03/96 01/04/96 0.03 01/05/96 01/06/96 0.03 01/07/96 01/08/96 01/09/96 01/10/96 01/11/96 0.01 01/12/96 0.02 01/13/96 01/14/96 0.26 01/15/96 01/16/96 0.02 01/17/96 0.11 01/18/96 0.01 01/19/96 0.90 01/20/96 0.02 01/21/96 0.08 01/22/96 0.01 01/23/96 0.40 01/24/96 0.44 01/25/96 01/26/96 0.01 01/27/96 0.19 01/28/96 0.02 01/29/96 0.08 01/30/96 01/31/96 TIME OF REPORT: 05/13/96 15:26:24 TOTAL RAIN FOR MONTH: 2.79 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAIN (in) 01/01/96 0.03 01/02/96 01/03/96 01/04/96 0.01 01/05/96 01/06/96 01/07/96 01/08/96 01/09/96 01/10/96 01/11/96 01/12/96 0.03 01/13/96 01/14/96 0.02 01/15/96 01/16/96 0.01 01/17/96 0.07 01/18/96 01/19/96 0.98 01/20/96 01/21/96 01/22/96 01/23/96 0.48 01/24/96 0.41 01/25/96 01/26/96 01/27/96 0.19 01/28/96 0.01 01/29/96 0.07 01/30/96 01/31/96 TIME OF REPORT: 05/13/96 15:27:04 TOTAL RAIN FOR MONTH: 2.31 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-05 RAIN TOTAL RAIN (in) .01/01/96 0.04 01/02/96 01/03/96 01/04/96 01/05/96 01/06/96 0.01 01/07/96 01/08/96 01/09/96 01/10/96 01/11/96 01/12/96 0.01 01/13/96 01/14/96 0.04 01/15/96 01/16/96 0.02 01/17/96 0.08 01/18/96 01/19/96 0.91 01/20/96 01/21/96 01/22/96 01/23/96 0.37 01/24/96 0.38 01/25/96 01/26/96 0.01 01/27/96 0.15 01/28/96 0.01 01/29/96 0.04 01/30/96 01/31/96 TIME OF REPORT: 05/13/96 15:27:59 TOTAL RAIN FOR MONTH: 2.07 L*Z :HINOW @IOJ NMI IV10i 6E:OZ:S L 96/C USO :illOd3N JO 3WIi 96AEAO 96/OCAO 60*0 96/6ZAO ZO'O 96/9ZAO 90*0 96/ZZ/LO 96/9ZAO Lo*o 96/SZ/LO 9E*O 96/tZ/ L 0 EV,o 96/EZ/LO LO*O 96/ZZ/LO LO*O 96AZAO LO*O 96/OZ/LO V9,0 96/6 LAO LO'O 96/9LAO 90,0 96/Z LAO ZO'O 96/9LAO 96/S L/ L 0 EL'o 96/tL/LO 96/f L/ L 0 EO*O 96/Z L/ L 0 96A LAO 96/OLAO 96/60AO 96/80/LO 96/ZO/LO 96/90/LO LO*O 96/SO/LO LO*O 9 6/t7O/ L 0 96/EO/LO 96/ZO/LO ZO'O 96/LO/LO (Ul) NI" IVi( NIVN 90 3N3::NOI-LVDOI 'S3DIAN3S 1V-LN3WNO'dIAN3 SGV ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) 01/01/96 0.02 01/02/96 01/03/96 01/04/96 0.01 01/05/96 01/06/96 01/07/96 01/08/96 01/09/96 01/10/96 01/11/96- 01/12/96 0.03 01/13/96 01/14/96 01/15/96 01/16/96 0.02 01/17/96 0.08 01/18/96 0.02 01/19/96 0.84 01/20/96 0.01 01/21/96 01/22/96 01/23/96 0.38 01/24/96 0.41 01/25/96 01/26/96 01/27/96 0.12 01/28/96 01/29/96 0.06 01/30/96 01/31/96 TIME OF REPORT: 05/13/96 15:29:07 TOTAL RAIN FOR MONTH: 2.00 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-01 RAIN TOTAL RAIN (in) ------------ 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 02/07/96 0.05 02/08/96 0.36 02/09/96 02/10/96 02/11/96 0.02 02/12/96 02/13/96 02/14/96 0.06 02/15/96 02/16/96 02/17/96 02/18/96 02/19/96 0.02 02/20/96 0.31 02/21/96 0.12 02/22/96 02/23/96 02/24/96 02/25/96 02/26/96 02/27/96 0.45 02/28/96 0.03 02/29/96 TIME OF REPORT: 05il 3/96 15:08:01 TOTAL RAIN FOR MONTH: 1.42 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 02/07/96 02/08/96 02/09/96 02/10/96 02/11/96 02/12/96 02/13/96 02/14/96 02/15/96 02/16/96 02/17/96 02/18/96 02/19/96 02/20/96 02/21/96 02/22/96 02/23/96 02/24/96 1.26 02/25/96 02/26/96 02/27/96 0.05 02/28/96 02/29/96 TIME OF REPORT: 05/13/96 15:31:22 TOTAL RAIN FOR MONTH: 1.31 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 0.10 02/07/96 0.24 02/08/96 0.63 02/09/96 02/10/96 02/11/96 0.12 02/12/96 02/13/96 0.06 02/14/96 0.05 02/15/96 0.12 02/16/96 0.02 02/17/96 0.01 02/18/96 0.03 02/19/96 0.06 02/20/96 0.38 02/21/96 0.13 02/22/96 0.01 02/23/96 02/24/96 0.05 02/25/96 02/26/96 02/27/96 0.49 02/28/96 0.08 02/29/96 TIME OF REPORT: 05/13/96 15:32:01 TOTAL RAIN FOR MONTH: 2.58 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAI.N (in) ------------ 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 02/07/96 0.07 02/08/96 0.55 02/09/96 02/10/96 02/11/96 0.11 02/12/96 02/13/96 02/14/96 0.10 02/15/96 02/16/96 02/17/96 02/18/96 0.03 02/19/96 0.04 02/20/96 0.28 02/21/96 0.09 02/22/96 0.01 02/23/96 02/24/96 0.01 02/25/96 02/26/96 02/27/96 0.56 02/28/96 0.05 02/29/96 TIME OF REPORT: 05/13/96 15:33:53 TOTAL RAIN FOR MONTH: 1.90 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-05 RAIN TOTAL RAIN (in) 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 02/07/96 0.07 02/08/96 0.53 02/09/96 02/10/96 0.01 02/11/96 0.08 02/12/96 02/13/96 0.01 02/14/96 0.06 02/15/96 0.03 02/16/96 02/17/96 02/18/96 02/19/96 0.08 02/20/96 0.33 02/21/96 0.06 02/22/96 0.02 02/23/96 02/24/96 0.01 02/25/96 02/26/96 02/27/96 0.43 02/28/96 0.07 02/29/96 TIME OF REPORT: 05/13/96 17:01:33 TOTAL RAIN FOR MONTH: 1.79 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-06 RAIN TOTAL.RAIN (in) .02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 0.03 02/07/96 0.08 02/08/96 0.48 02/09/96 02/10/96 02/11/96 0.11 02/12/96 02/13/96 0.02 02/14/96 0.11 02/15/96 0.01 02/16/96 02/17/96 02/18/96 0.03 02/19/96 0.08 02/20/96 0.28 02/21/96 0.20 02/22/96 0.01 02/23/96 02/24/96 0.01 02/25/96 02/26/96 02/27/96 0.51 02/28/96 0.04 02/29/96 TIME OF REPORT: 05/13/96 15:32:48 TOTAL RAIN FOR MONTH: 2.00 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) 02/01/96 02/02/96 02/03/96 02/04/96 02/05/96 02/06/96 02/07/96 0.08 02/08/96 0.56 02/09/96 02/10/96 02/11/96 0.06 02/12/96 02/13/96 02/14/96 0.03 02/15/96 02/16/96 02/17/96 02/18/96 02/19/96 0.02 02/20/96 0.30 02/21/96 0.17 02/22/96 0.01 02/23/96 02/24/96 0.04 02/25/96 02/26/96 02/27/96 0.51 02/28/96 0.06 02/29/96 TIME OF REPORT: 05/13/96 17:02:05 TOTAL RAIN FOR MONTH: 1.84 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-01 RAIN TOTAL RAIN (in) .03/01/96 03/02/96 0.03 03/03/96 03/04/96 0.03 03/05/96 0.60 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.12 03/20/96 0.23 03/21/96 0.05 03/22/96 0.02 03/23/96 0.03 03/24/96 03/25/96 0.07 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TIME OF REPORT: 05/13/96 15:08:23 TOTAL RAIN FOR MONTH: 1.18 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) 03/01/96 03/02/96 03/03/96 03/04/96 03/05/96 1.07 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 0.01 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.10 03/20/96 0.18 03/21/96 0.01 03/22/96 03/23/96 0.13 03/24/96 03/25/96 0.10 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TIME OF REPORT: 05/13/96 17:03:48 TOTAL RAIN FOR MONTH: 1.60 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) ------------ 03/01/96 0. 02 03/02/96 0.03 03/03/96 03/04/96 0.36 03/05/96 0.73 03/06/96 03/07/96 03/08/96 03/09/96 0.01 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.13 03/20/96 0.10 03/21/96 0.07 03/22/96 0.13 03/23/96 0.45 03/24/96 03/25/96 0.14 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 0.01 03/31/96 TIME OF REPORT: 05/13/96 17:04:38 TOTAL RAIN FOR MONTH: 2.18 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAIN (in) 03/01/96 03/02/96 0.06 03/03/96 03/04/96 0.23 03/05/96 0.73 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.20 03/20/96 0.49 03/21/96 0.10 03/22/96 0.10 03/23/96 0.05 03/24/96 03/25/96 0.12 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TIME OF REPORT: 05/13/96 17:05:13 TOTAL RAIN FOR MONTH: 2.08 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-05 RAIN TOTAL RAIN (in) ---------- 03/01/96 03/02/96 0.03 03/03/96 03/04/96 0.14 03/05/96 0.44 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.20 03/20/96 0.09 03/21/96 0.01 03/22/96 0.10 03/23/96 0.29 03/24/96 0.01 03/25/96 0.11 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TWE OF REPORT: 05/13/96 17:05:41 TOTAL RAIN FOR MONTH: 1.42 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-06 RAIN TOTAL RAIN (in) 03/01/96 0. 01 03/02/96 0.05 03/03/96 03/04/96 0.24 03/05/96 0.50 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.13 03/20/96 0.20 03/21/96 0.08 03/22/96 0.20 03/23/96 0.22 03/24/96 03/25/96 0.10 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TIME OF REPORT: 05/13/96 17:07:22 TOTAL RAIN FOR MONTH: 1.73 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) .03/01/96 03/02/96 0.03 03/03/96 03/04/96 0.01 03/05/96 0.57 03/06/96 03/07/96 03/08/96 03/09/96 03/10/96 03/11/96 03/12/96 03/13/96 03/14/96 03/15/96 03/16/96 03/17/96 03/18/96 03/19/96 0.14 03/20/96 0.34 03/21/96 0.11 03/22/96 0.06 03/23/96 0.01 03/24/96 03/25/96 0.13 03/26/96 03/27/96 03/28/96 03/29/96 03/30/96 03/31/96 TIME OF REPORT: 05/13/96 17:06:12 TOTAL RAIN FOR MONTH: 1.40 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-01 RAIN TOTAL RAtN (in) 04/01/96 0.22 04/02/96 04/03/96 04/04/96, 0.11 04/05/96 0.02 04/06/96 04/07/96 0.01 04/08/96 04/09/96 04/10/96 04/11/96 04/12/96- 0.65 04/13/96 0.64 04/14/96 04/15/96 0.36 04/16/96 0.14 04/17/96 04/18/96 04/19/96 0.35 04/20/96 0.18 04/21/96 04/22/96 0.51 04/23/96 1.33 04/24/96 0.04 04/25/96 04/26/96 0.13 04/27/96 04/28/96 04/29/96 0.39 04/30/96 0.51 TIME OF REPORT: 05/13/96 15:08:49 TOTAL RAIN FOR MONTH: 5.59 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) .04/01/96 0 . 27 04/02/96 04/03/96 04/04/96 0.05 04/05/96 0.07 04/06/96 04/07/96 04/08/96 04/09/96 04/10/96 0.01 04/11/96 04/12/96- 0.87 04/13/96 0.59 04/14/96 04/15/96 0.36 04/16/96 0.23 04/17/96 04/18/96 04/19/96 0.26 04/20/96 0.17 04/21/96 04/22/96 0.58 04/23/96 1.39 04/24/96 0.05 04/25/96 04/26/96 0.15 04/27/96 04/28/96 04/29/96 0.33 04/30/96 0.67 TIME OF REPORT: 05/13/96 17:08:24 TOTAL RAIN FOR MONTH: 6.05 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) 04/01/96 0. 32 04/02/96 04/03/96 04/04/96 0.09 04/05/96- 0.06 04/06/96 04/07/96 04/08/96 04/09/96 04/10/96 0.02 04/11/96 0.01 04/12/96- 0.59 04/13/96 0.66 04/14/96 04/15/96 0.42 04/16/96 0.32 04/17/96 04/18/96 04/19/96 0.25 04/20/96 0.24 04/21/96 04/22/96 0.55 04/23/96 1.66 04/24/96 0.04 04/25/96 0.01 04/26/96 0.20 04/27/96 04/28/96 04/29/96 0.34 04/30/96 0.77 TIME OF REPORT: OV1 3/96 17:09:26 TOTAL RAIN FOR MONTH: 6.55 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAW (in) 04101/96 0. 31 04/02/96 04/03/96 04/04/96 0.16 04/05/96- 0.03 04/06/96 04/07/96 0.02 04/08/96 04/09/96 04/10/96 0.01 04/11/96- 04/12/96- 0.86 04Jl 3/96 0.79 04/14/96 04/15/96 0.39 04/16/96 0.21 04/17/96 04/18/96 04/19/96 0.33 04/20/96 0.21 04/21/96 04/22/96 0.72 04/23/96 1.49 04/24/96 0.03 04/25/96 04/26/96 0.16 04/27/96 04/28/96 0.01 04/29/96 0.49 04/30/96 0,73 TIME OF REPORT: 05/13/96 17:09:57 TOTAL RAIN FOR MONTH: 6.95 ADS ENVIRONMENTAL SERVICES, INC. LOCATION:: ERIE-05 RAIN TOTAL RAIN (in) 04/01/96 0 . 29 04/02/96 0.03 04/03/96 04/04/96 0.09 04/05/96- 0.03 04/06/96 04/07/96 04/08/96 04/09/96 04/10/96 0.02 04/11/96 0.01 04/12/96 0.59 04/13/96 0.62 04/14/96 04/15/96 0.39 04/16/96 0.27 04/17/96 0.01 04/18/96 04/19/96 0.24 04/20/96 0.21 04/21/96 04/22/96 0.49 04/23/96 1.79 04/24/96 0.05 04/25/96 04/26/96 0.15 04/27/96 04/28/96 04/29/96 0.07 04/30/96 0.92 TIME OF REPORT: 05/13/96 17:11:05 TOTAL RAIN FOR MONTH: 6.27 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-06 RAIN TOTAL RAIN (in) 04/01/96 0. 26 04/02/96 04/03/96 04/04/96 0.13 04/05/96- 0.07 04/06/96 04/07/96 04/08/96 04/09/96 04/10/96 0.03 04/11/96 04/12/96-- 0.63 04/13/96 0.67 04/14/96 04/15/96 0.38 04/16/96 0.23 04/17/96 04/18/96 04/19/96 0.36 04/20/96 0.21 04/21/96 04/22/96 0.64 04/23/96 1.63 04/24/96 0.03 04/25/96 04/26/96 0.22 04/27/96 04/28/96 0.01 04/29/96 0.36 04/30/96 0.68 TIME OF REPORT: 05/13/96 17:11:30 TOTAL RAIN FOR MONTH: 6.54 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) ------------ 04/01/96 0. 29 04/02/96 04/03/96 04/04/96 0.10 04/05/96 0.04 04/06/96 04/07/96 04/08/96 04/09/96 04/10/96 04/11/96 04/12/96 04/13/96 04/14/96 04/15/96 0.38 04/16/96 0.31 04/17/96 04/18/96 04/19/96 0.25 04/20/96 0.19 04/21/96 04/22/96 0.52 04/23/96 1.55 04/24/96 0.01 04/25/96 0.53 04/26/96 0.83 04/27/96 04/28/96 0.01 04/29/96 0.29 04/30/96 0.69 TIME OF REPORT: 05/13/96 17:12:02 TOTAL RAIN FOR MONTH: 5.99 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-01 RAIN TOTAL RAIN (in) 05/01/96 0.10 05/02/96 05/03/96 0.08 05/04/96 0.23 05/05/96 0.12 05/06/96 05/07/96 05/08/96 0.14 05/09/96 0.87 05/10/96 0.45 05/11/96 0.99 05/12/96 0.01 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 0.40 05/22/96 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:39: 11 TOTAL RAIN FOR MONTH: 3.39 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-02 RAIN TOTAL RAIN (in) ----------- .05/01/96 0. 17 05/02/96 05/03/96 0.08 05/04/96 0.20 05/05/96 0.10 05/06/96 05/07/96 05/08/96 05/09/96 05/10/96 05/11/96 05/12/96 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 05/22/96 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/14/96 10:45:07 TOTAL RAIN FOR MONTH: 0.55 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-03 RAIN TOTAL RAIN (in) 05/01/96 0.26 05/02/96 05/03/96 0.11 05/04/96 0.22 05/05/96 0.12 05/06/96 0.01 05/07/96 05/08/96 0.09 05/09/96 0.81 05/10/96 1.03 05/11/96 1.19 05/12/96 0.01 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 0.42 05/22/96 0.01 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:40:21 TOTAL RAIN FOR MONTH: 4.28 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-04 RAIN TOTAL RAIN (in) 05/01/96 0.17 05/02/96 05/03/96 0.09 05/04/96 0.23 05/05/96 0.14 05/06/96 0.01 05/07/96 05/08/96 0.23 05/09/96 0.64 05/10/96 0.57 05/11/96 1.21 05/12/96 0.02 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 0.52 05/22/96 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:41: 10 TOTAL RAIN FOR MONTH: 3.83 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-05 RAIN TOTAL RAIN (in) 05/01/96 0.20 05/02/96 05/03/96 0.11 05/04/96 0.23 05/05/96 0.13 05/06/96 0.01 05/07/96 05/08/96 0.08 05/09/96 0.62 05/10/96 0.86 05/11/96 1.32 05/12/96 0.03 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 0.44 05/22/96 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:42:07 TOTAL RAIN FOR MONTH: 4.03 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-06 RAIN TOTAL RAIN (in) 05/01/96 0.17 05/02/96 05/03/96 0.09 05/04/96 0.23 05/05/96 0.12 05/06/96 0.01 05/07/96 05/08/96 0.09 05/09/96 0.81 05/10/96 0.57 05/11/96 1.11 05/12/96 0.01 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 0.01 05/20/96 05/21/96 0.36 05/22/96 0.01 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:42:54 TOTAL RAIN FOR MONTH: 3.59 ADS ENVIRONMENTAL SERVICES, INC. LOCATION: ERIE-07 RAIN TOTAL RAIN (in) 05/01/96 -0.23 05/02/96 05/03/96 0.10 05/04/96 0.20 05/05/96 0.10 05/06/96 0.02 05/07/96 05/08/96 0.07 05/09/96 0.85 05/10/96 1.03 05/11/96 1.10 05/12/96 0.01 05/13/96 05/14/96 05/15/96 05/16/96 05/17/96 05/18/96 05/19/96 05/20/96 05/21/96 0.33 05/22/96 0.01 05/23/96 05/24/96 05/25/96 05/26/96 05/27/96 05/28/96 05/29/96 05/30/96 05/31/96 TIME OF REPORT: 05/24/96 12:44:01 TOTAL RAIN FOR MONTH: 4.05 MALCOLM PIRNIE APPENDIX B ANALYTICAL RESULTS 275"1 Printed on Recycled Paper PROJECT NAME: RA TER QUALITY MOA7TORING STUD Y FOR 7HE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TVELVEMILE CREEK EVENT: 01D PESTICI]DES/PCBs Date June 14,1995 June 14,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event OID OID CCC CIVIC TABLE3 @.it, I (pg/'-) (lb/day)* (PgtL) 61gL) (Pg/L) alpha-BHC <0.02 <0.0004 n/a n/a beta-BHC <0.02 <0.0004 n/a n/a delta-BHC <0.02 <0.0004 n/a n/a gamma-BHC (Lindane) <0.02 <0.0004 0.001 (X) Heptachlor <0.04 <0.0008 0.001 (X) Aldrin <0.4 <0.008 0.001 (X) Heptachlor epoxide <0.02 <0.0004 0.1 0.8 alpha-Endosulfan (1) <0.01 <0.0002 0.056 0.22 Dieldrin <03 <0.010 0.001 (X) 4,4'-DDE <0.01 <0.0002 0.001 1.1 Endrin <0.01 <0.0002 0.002 (X) beta-Endosulfm (11) <0.01 <0.0002 0.056 0.22 4,4'-DDD <0.01 <0.0002 0.001 1.1 Endosulfisn sulfate <0.01 <0.0002 n/a n/11 4,4'-DDT <0.01 <0.0002 0.001 1.1 alpha-Chlordane <0.2 <0.004 (X) gamma-Chlordane <0.2 <0.004 (X) Toxaphene <1.0 <0.020 0.008 (X) Endrin Aldehyde <0@01 <0.0002 n/a n/a NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS =Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 3.72 cfs - limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie 0-:9 PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENULE CREEK EVENT: 01D INORGANICS Date June 14, 1995 June 14, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS (P&/L) b/day)* -1 Event 01D 01D CCC CMC TABLE3 Cu junits (I I (pg/,-) (PS(L) Aluminum [total] <0.1 <2.01 0. ](96hrLC") (X) Antimony [total] <0.003 <0.060 219 1,095 Arsenic [total] <0.001 <0.0201 190(As3+) 360(As3+) Beryllium [total] <0.005 <0.100 0.01(96hrLC,) 0.05(96hrLC3a) Cadmium S [total] <0.0001 <0.0201 0.0l(96hrLC%)(X) Chromium Total S <0,05 <1.00 I l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(lnH)+3.688) Chromium VI (ugn) <0@01 <0.00020 11 16 Copper $ [total] <0.001 <0.0201 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) iron (total) 0.62 0.00 0.3 mSA--(X) I Lead $ [total) <0.001 <0.0201 EXP(l.266(lnH)-4.66l) FJ(P(l.266(lnH)-l.4l6) Manganese [total] <0@01 <0.00020 1 mgtl 2 Mercury [total] <0.0002 <0.0040 0.2 pgA***(X) Nickel S (total] <0@01 <0.00020 EXP(0.&46(lnH)+l.l645) EXP(0.g46(lnH)+3.36l2) Selenium [total] <0.002 <0.040 10 Pg/l (X) Silver $ [total] <0.0002 <0.0040 0.2 EXP(l.72(lnH)-6.52) Thallium [total] <0.001 <0.0201 0.018 0.09 Zinc $ [total] <0.012 <0.241 EXP(0.8473(lnH)+0.76l4) EXP(0.&473(lnH)+0.96D4) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 EP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 9:1.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flow of 3,72 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: W4 TER QUALITY MOA7TORING STVD Y FOR THE L4KE ERIE WATERSHED JOB NUMBER: 2759-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 01D ADDITIONAL PARAMETERS Date June 14, 1995 June 14,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event OID OID CCC CMC TABLE3 CU [Units (Mgt,) (lb/day)* I Alkalinity (mg1L CaCO3) 81 n1a minimum of 20 1 Chloride (mgtl) 38 0 250 2 Cyanide, free (pgA) <0.005 <0.100 5 22 Grease & Oil Grab (mgA) 1.2 0 2 2 Ammonia-Nitrogen 0.05 0.00 (NH3-N) x (log-I[pKT-pH]+I) Nitrite-Nitrogen (mg/l) <0.01 <0.200 N02+N03=10 2 Nitrate-Nitrogen (mg1l) 2.45 0.0 (as nitrogen) CBODs 3 n/a Chemical Oxygen Demand <10 n/a Fecal Coliform (#IIODmL) 141 n/a BACI (X) 3 Phosphorus, total <0.01 <0.200 (P) (X) Total Suspended Solids 2 0 Hardness (mg/L CaCO,) 157 11/a max. monthly mean of ISO PH (s.u.) **[fieldl 8.4 n1a 6.5 - 9.0 (X) I Temperature (*C) ** [field) 18.0 n/a I Conductivity (mv/cm) " [field] 413 n/a Dissolved Oxygen (mg/L 02) - [field] 5.37 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) MC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/ 1 00m) based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 3.72 cfs te - average of e 3 grab samples measured in the field (P)-Conrentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALI77 MOMITORING STVDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 01D PESTICIDES/PCBs Date June 14 ,1995 June 14, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 01D 01D CCC CIVIC TABLE3 [units (PgL) (lb/day). (pg/L) (Pg/L) (pg/L) alpha-BHC <0.02 <0.0056 n/a n/a beta-BHC <0.02 <0.0056 n/a n/a delta-BHC <0.02 <0.0056 n/a n/a gamma-BHC (Lindane) <0.02 <0.0056 0.001 (X) Heptachlor <0.04 <0.0111 0.001 (X) Aldrin <0.4 <0.111 0.001 (X) Heptachlor epoxide <0.02 <0.0056 0.1 0.8 alpha-Endosulfan (1) <0,01 <0.0028 0.056 0.22 Dieldrin <0.5 <0. 140 0.001 (X) 4,4'.DDE <0.01 <0.0028 0.001 1.1 Endrin <0.01 <0.0028 0.002 (X) eta-Endosulfan (11) <0.01 <0.0028 0.056 0.22 4,4'-DDD <0.01 <0.0028 0.001 1.1 Endosulfan sulfate <0.01 <0.0028 n1a n/a 4,4'-DDT <0.01 <0.0028 0.001 1.1 alpha-Chlordane <0.2 <0.056 (X) gamma-Chlordane <0.2 <0.056 (X) Toxaphene <1.0 <0.280 0.008 (X) Endfin Aldehyde <D.01 <0.0028 n1a n/a NOTES: EP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 51.82 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: WATER QUALITY MOA7TORING STVD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 01D INORGANICS Date June 14,1995 June 14, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event OID I) CCC CIVIC TABLE3 CU lUnits (pg/L) (lbo/dlay)* (pg/L) (pg/L) Aluminum [total] <0.1 <27.95 0. )(96hrLC%) (X) I Antimony [total] <0.003 <0.839 219 1,095 Arsenic [total] <0.001 <0.280 190(As3+) 360(As3+) Beryllium [total] <0.005 <1.40 0.01(96hrLC,) 0.05(96hrLc") Cadmium S [total] <0.0001 <0.0280 0.01(96hrLC,)(X) Chromium Total $ <0.05 <14.0 1 I+EXP(0.gI9-(InH)+I.56I) I6+EXP(0.8I9(InH)+3.688) Chromium VI (ugA) <0.01 <2.80 11 16 Copper $ [total] <0.001 <0.280 EXP(.8545(hdi)-l.465) EXP(0.9422(W1)-I.464) Iron [total] 0.39 0.00 0.3 mgA--(X) I Lead S [total] <0.001 <0.280 EXP(L266(InH)-4.66I) EXP(I.266(lnH)-I.4I6) Manganese [total) 0.01 0.00 1 mgtl 2 Mercury [total) <0.0002 <0.0560 0.2 PgA*.*(X) Nickel S [total] <0.01 <2.90 EXP(0.&46(lnH)+I.I645) EXP(0.WnH)+3.3612) Selenium [total] <0.002 <0.560 10 Pg/I (X) Silver $ [total) <0.0002 <0.0560 0.2 EXP(I.72(InH)-6.52) Thallium [total] <0.001 <0.280 0.018 0.09 Zinc $ [total] 0.048 0.00 EXP(0.8473(lnH)+0.76I4) EXP(0.9473(InH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpit 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for Iong-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 5(ft of test organisms over a specified time period. H = Hardness loading based on a flow of 51.82 cfa -This value or natural levels, Whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: WATER QUALITY MOWTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 01D ADDITIONAL PARAMETERS Date June 14, 1995 June 14, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 01D' 0113 CMC TABLE3 Pnits (M2/1) (lb/day)* ccc Alkalinity (mg/L CaCO,) 140 n/a minimum of 20 Chloride (mg/1) 59 0 250 2 Cyanide, free (glo) <0.005 <1.40 3 22 Grease & Oil Grab (mg/1) 1.33 0 2 2 Ammonia-Nitrogen 0.04 0.0 (NH3-N) x (log-l[pXT-pHj+l) Nitrite-Nitrogen (mg/l) <0.01 <2.80 N02 + N03- 10 2 Nitrate-Nitrogen (mg/1) 0.41 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand <10 n/a Fecal Coliform (#/l00mL) so n/a BACI (X) 3 Phosphorus, total <0.01 <2.80 (P) (X) Total Suspended Solids 2 0 Hardness (mg1L CaCO,) 209 n1a max. monthly mean of 150 pH (s.u.) ** [field] 8.7 n/a 6.5-9.0(X) I Temperature (C) ** [field] 21.5 n/a I Conductivity (mv/cm) ** [field) 553 n/a Dissolved Oxygen (mg/L 02) ** [field] 5.4 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. D. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term Protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than sk thirty-day period loading based on a flow of 51.82 cfs - [field - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 01D PESTICIDES/PCBs Date June 14,1995 June 14, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 01D 01D CCC CIVIC TABLE3 Pnits (ILSIL) (lb/day)* (pg/L) (pg/L) (pgL) alpha-BHC <0.02 <0.0020 n/a 1111 beta-BHC <0.02 <0.0020 n/a rda delta-BHC <0.02 <0.0020 n/a n/a gamma-BHC (Lindane) <0.02 <0.0020 0.001 (X) Heptachlor <0.04 <0.0040 0.001 (X) ldrin <0.4 <0.040 0.001 (X) Heptachlor epoxide <0.02 <0.0020 0.1 0.9 alpha-Endosulfan (1) <0.01 <0.0010 0.056 0.22 Dieldrin <0.5 <0@050 0.001 (X) 4,4'-DDE <0.01 <0.0010 0.001 1.1 Endrin <0.01 <0.0010 0.002 (X) beta-Endosulfan (H) <0.01 <0.0010 0.056 0.22 4,4'-DDD <0.01 <0.0010 0.001 1.1 Endosulfan sulfate <0.01 <0.0010 n1a n1a 4,4'.DDT <0.01 <0.0010 0.001 1.1 alpha-Chlordane <0.2 <0.020 Q0 gamma-Chlordane <0.2 <0.020 (X) Toxaphene <1 <0. 100 0.008 (X) Endrin Aldehyde <0.01 <0.0010 n/a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 18.47 cfs - limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITYMOA7TORINGS7UDY FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: OID INORGANICS Date June 14, 1995 June 14, 199 DEP CHPT 16 WQC DEP CHPT 93 WQS Event OID OID CCC CMC TABLE3 CU junits (mg/L) (lb/day)* (pg/L) (PgtL) Aluminum [total] <0.1 <9.96 0. )(96hrLC,) (X) I Antimony [total] <0.003 <0.299 219 1,095 Arsenic [total) <0.001 <0.0966 190(As3+) 360(As3+) Beryllium [total) <0.005 <0.498 0.01(96hrLC,) 0.05(96hrLcm) Cadmium S (total] <0.0001 <0.0100 0.01(96hrLC,.)(X) Chromium Total S <0.05 <4.98 1 I+EXP(0.8l9-(InH)+I.56l) l6+EXP(0.8l9(lnH)+3.688) Chromium VI (ugA) <0.01 <0.0010 11 16 Copper S [total] <0.001 <0.0966 EXP(.8545(lnH)-I.465) EXP(0.9422(lnH)-I.464) Iron [total] 0.47 0.0 0.3 mgA--(X) I Lead S [total] <0.001 <0.0966 EXP(I.266(InH)-4.661) EXP(I.266(lnH)-l.4I6) Manganese [total] <0.01 <0.0010 I mgfl 2 Mercury [total] 0.0002 <0.0199 0.2 pgA***(X) Nickel $ [total] <0.01 <0.0010 F_NP(0.WnH)+l.I645) EXP(0.&46(InH)+3.36I2) Selenium [total] 0.002 0.000 10 Pg/l (X) Silver S [total] <0.0002 <0.0199 0.2 EXP(I.72(InH)-6.52) Thalliurn [totall <0_00t <0.0966 O.Ots 0.09 Zinc S [total) 0.011 0.000 W(0.9473(lnH)+0.76l4) EXP(0.&473(InH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC,@ = The concentration of pollutant in test waters that is lethal to W1. of test organisms over a specified time period. H = Hardness loading based on a flow of 18.47 cfs -This value or natural levels, whichever is greater * - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: RA TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 01D ADDITIONAL PARAMETERS Date June 14, 1995 June 14 '1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 01D 01D CCC CMC TABLE3 CU [Units (mg/L) (lb/day)* Alkalinity (mg/L CaC03) too n1a minimum of 20 1 Chloride (mgfl) 35 0 250 2 Cyanide, free (pg1l) <0.005 <0.498 5 22 Grease & Oil Grab (mgfl) 1.6 0 2 2 Ammonia-Nitrogen 0@09 0.00 (N113-N) it (log- I [pKT-pHl+ I) Nitrite-Nitrogen (ing1l) <0.01 <1.00 N02 + N03-10 2 Nitrate-Nitrogen (mgfl) 0.97 0.0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 10 n/a Fecal Colifbrm (#/IOOmL) 28 n1a BACI (X) 3 Phosphorus, total 0.01 0.00 (P) (X) Total Suspended Solids 2 0 Hardness (mg/L CaC03) 154 n/a max. monthly mean of 150 PH (s.u.) ** [field] 9.0 n/a 6.5 - 9.0 (X) I Temperature (C) ** (field] 23.3 n/a I Conductivity (mv/cm) ** [field] 405 n1a Dissolved Oxygen (mg/L 02) 0* (field] 5.44 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHIPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-terin protection) Table 3 - located on pages 93.7 through 93. 15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 18.47 cfs - [field] - average of the 3 grab samples measured in the field (P)-Concentrations sho Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WA TER QUALITY MOIWTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 02W PESTICIDES/PCBs Aug. 11, 199 DEP Date Fu g-1 1, 5 Aug. 11, 1995 DEP CHPT 16 WQC CEPT 93 WQS Event 02W 02W CCC CIVIC TABLE3 junits (pg/L) b/day)* (pgL) (pg/L) (pg/L) alpha-BHC <0.02 <0.0137 n/a n/a beta-BHC <0.02 <0.0137 n/a n/a delta-BHC <0.02 <0.0137 n/a n/a gamma-BHC (Lindane) <0.02 <0.0137 0.001 (X) Heptachlor <0.04 <0.0275 0.001 (X) Aldrin <0.4 <0.275 0.001 (X) Heptachlor epoxide <0.02 <0.0137 0.1 0.8 alpha-Endosulfan (1) <0.01 <0.0069 0.056 0.22 Dieldrin <0.5 <0.343 0.001 (X) 4,4'-DDE <0.01 <0.0069 0.001 1.1 Endrin <0.01 <0.0069 0.002 (X) beta-Endosulfian (11) <0.01 <0.0069 0.056 0.22 4A-DDD <0.01 <0.0069 0.001 1.1 Endosulfan sulfate <0.01 <0.0069 n/a 11/9 4,4%DDT <0.01 <0.0069 0.001 1.1 alpha-Chlordane <0.2 <0.137 00 gamma-Chlordane <0.2 <0.137 (X) Toxaphene <1.0 <0.687 0.008 (X) Endrin Aldehyde <0.01 <0.0069 n/a n/a NOTES: DEP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CUPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 127.29 ds - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITY MOATTORING STUD Y FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 02W INORGANICS Date Aug. 1 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS CMC TABLE3 [Units (lb/day)* 61g/L) (pg/L) Event 02W 02W CCC :M,g/L) I T U Aluminum [total] 13.8 0 0. 1(96hrLC$.) (X) Antimony [total] <0.003 <2.060 219 1,095 Arsenic [total] 0.011 0.00 190(As3+) 360(As3+) Beryllium (total] <0.005 <3.433 0.0](96hrLC") 0.05(96hrLcm) Cadmium S (total] 0.0004 0.000 0.01(96hrLC,)(X) Chromium Total $ 0.13 0.0 II+EXP(0.8I9-(InH)+I.56l) I6+EXP(0.8I9(InH)+3.688) Chromium VI (ug/1) <0.01 <0.0069 11 16 Copper $ [total] 0.021 0.0 EXP(.8545(InH)-I.465) EXP(0.9422(lnH)-I.464) Iron [total) 19.5 0 0.3 mgA*-(X) I Lead $ [total] 0.018 0.0 EXP(l.266(InH)4.66l) EXP(I.266(InH)-l.4I6) Manganese [total] 1.34 0 1 MBA 2 Mercury [total] <0.0002 <0.1373 0.2 PBA***(X) Nickel $ [total] 0.04 0.0 EXP(0.846(lnH)+I.l645) EXP(O.946(InH)4-3.3612) Selenium [total] <0.002 <1.373 10 Pg/I (X) Silver S [total] 0.0003 0.000 0.2 EXP(I.72(InH)-6.52) Thallium [total] <0.001 <0.687 0.018 0.09 Zinc S [total] 0.2 0 EXP(0.8473(lnH)+0.76l4) E)(P(0.8473(lnH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Cbpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5@ = The concentration of pollutant in test waters that is lethal to 50116 of test organisms over a specified time period. H = Hardness loading based on a flow of 127.29 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR TME LAKE ERIE W4 TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 02W ADDITIONAL PARAMETERS Date Aug. 11, 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 02W 02W CCC CIVIC TABLE3 CU Junits (ingL) (lb/day). Alkalinity (mg/L CaCO,) 44 n1a minimum of 20 1 Chloride (mg/l) 35 0 250 2 Cyanide, free (lig/1) <0.005 <3.43 5 22 Grease & Oil Grab (mg/1) 0.5 0 2 2 Ammonia-Nitrogen 0.19 0 (NH3-N) x (log-l[pKT-pH)+l) Nitrite-Nitrogen (mg/1) 0.06 0.0 N02+NO3=10 2 Nitrate-Nitrogen (mg1l) 3.28 0 (as nitrogen) CBOD, 10 n/a Chemical Oxygen Demand 115 n1a Fecal Coliform (#/IOOmL) 13,100 n/a BAC I (X) 3 Phosphorus, total 0.89 0 (P) (X) Total Suspended Solids 680 0 Hardness (mg/L CaCO,) 112 n/a max. monthly mean of 150 PH (s.u.) **[field] 8.1 rim 6.5 - 9.0 (X) I Temperature (*C) ** [field) 20.8 n/a I Conductivity (mv/cm) 0* [field] 309 n/a Dissolved Oxygen (mg/L 02) ** (field] 4.58 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quatity Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 127.29 cfis **[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. IF) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: W4 TER QUALITY MOA'ITORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 02W PESTICIDES/PCBs Date Aug. 11, 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS CMC TARI (pg/L) (lb/day Event 02W 02W). CCC E 3 ju.its (Ag/L) (pg/L) 091L) alpha-BHC <0.02 <0.0237 n1a n/a beta-BHC <0.02 <0.0237 n/a n/a delta-BHC <0.02 <0.0237 n/a n/a gamma-BHC (Lindane) <0.02 <0.0237 0.001 (X) Heptachlor <0.04 <0.0474 0.001 (X) Aldrin <0.4 <0.474 0.001 (X) Heptachlor epoxidc <0.02 <0.0237 0.1 0.8 alpha-Endosulfan (1) <0.01 <0.0118 0.056 0.22 Dieldrin <0.5 <0.592 0.001 (X) 4,4'-DDE <0.01 <0.0118 0.001 1.1 Endrin <0.01 <0,0118 0.002 (X) beta-Fndosulfm (11) <0.01 <0.0118 0.056 0.22 4,4'-DDD <0.01 <0.0118 0.001 1.1 Endosulfan sulfate <0.01 <0.0118 n/a n/a 4,4'-DDT <0.01 <0.0118 0.001 1.1 alpha-Chlordane <0.2 <0.237 (X) gamma-Chlordane <0.2 <0.237 (X) Toxaphene <1.0 <1.18 0.008 (X) Endrin Aldehyde <0.01 <0.01 18 n/a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term prutection) n/a - not applicable loading based on a flow of 219.53cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITY MOA7TORING STUD Y FOR TUE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 02W INORGANICS Date Aug. 1 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS -g1L) (lb/day) MC TABLE3 Event 02W 02W CCC C Nnits I . I (Pg/L) (PgtL) Aluminum [total] 38.5 0 0. 1(96hrLC,) (X) Antimony [total] <0.003 <3.55 219 1,095 Arsenic [total] 0.010 0.0 190(As3+) 360(As3+) Beryllium [total] <0.005 <5.92 0.01(96htLC,) 0.05(96hrLC,) Cadmium $ [total] 0.0005 0.000 0.01(96hrlC@) (X) Chromium Total $ 0.29 0 1 I+EXP(0.8I9*(InH)+I.56I) l6+EXP(0.9l9(InH)+3.688) Chromium VI (ug1l) <0.01 <0.01 11 16 Copper S [total] 0.033 0.0 EXP(.8545(InH)-l.465) EXP(0.9422(InH)-l.464) Iron [total] 35.5 0 0.3 mSA--(X) Lead $ [total] 0.049 0.0 EXP(I.266(InH)-4.661) EXP(I.266(InH)-l.4l6) Manganese [total] 2.44 0 1 mgA 2 Mercury [total] <0.0002 <0.236 0.2 pg/l***(X) Nickel S [total] 0.10 0 EXP(0.846(InH)+I.l645) EXP(0.846(InH)+3.36I2) Selenium [total] <0.002 <2.36 10 Pg/I (X) Silver S [total) <0.0002 <0.236 0.2 EXP(I.72(lnH)-6.52) Thalliurn [total] <0.001 <1.19 0.018 0.09 Zinc S [total] 0.67 0 EXF(0.9473(InH)+0.76I4) EXP(O.8473(InH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effectiveMarch 11, 1989, 19 Pa. B. 1059 DEP CEPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards U = Critical Use: 1) Aquatic Life; 2) WaterSupply LC@ = The concentration of pollutant in test waters that is lethal to 500/a of test organisms over a specified time period. H = Hardness loading based on a flow of 219.53cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITYMOA7TORINGS7VDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 02W ADDITIONAL PARAMETERS Date Aug. 11, 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 02W 02W CCC CIVIC TABLE3 CU nits (mg/L) (lb/day)* Alkalinity (mg/L CaCO,) 165 n/a minimum of 20 1 Chloride (mg/1) 29 0 250 2 Cyanide, free (pgA) <0.005 <5.92 5 22 Grease & Oil Grab (mg/1) 2.0 0 2 2 Ammonia-Nitrogen 0.33 0 (NH3-N) x (log-] [pKT-pH]+I) Nitrite-Nitrogen (trign) 0.10 0 NO2+NO3=IO 2 Nitrate-Nitrogen (mgA) 0.59 0 (as nitrogen) CBOD, 15 n/a Chemical Oxygen Demand 125 n/a Fecal Coliform (#/IODmL) 11,500 n/a BACI (X) 3 Phosphorus, total 1.74 0 (P) (X) Total Suspended Solids 1,508 0 Hardness (mg/L CaCO3) 144 n/a max. monthly mean of ISO pH (s.u.) "[field] 7.9 n/a 6.5-9.0(X) I Temperature (*C) ** [field] 21.7 n/a I Conductivity (mvicm) -- [field) 332 n/a Dissolved Oxygen (mg/L 02) ** [field) 7.8 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March H, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 219,53 cfa IT "[field] - average of the 3 grab samples measured in the field 1(P)_ ricentrations a ould be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: W4 TER QUALITY MOATTORLNG STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 02W PESTICIDES/PCBs Date Aug. 11, 1995 Aug. 11, 1995 DEP, CHPT 16 WQC DEP CHPT 93 WQS Event 02W 02W CCC CMC TABLE3 nits (ILgIL) (lb/day)* (pg/L) (pg/L) (pg/L) alpha-BHC <0.02 <0.0107 n1a n/a beta-BHC <0.02 <0.0107 n/a n/a delta-BHC <0.02 <0.0107 n/a nil gamma-BHC (Lindane) <0.02 <0.0107 0.001 (X) Heptachlor <0.04 <0.0215 0.001 (X) Aldrin <0.4 <0.215 0.001 (X) Heptachlor epoxide <0.02 <0.0107 0.1 0.9 alpha-Endosulfan (1) <0.01 <0.0054 0.056 0.22 Dieldrin <0.5 <0.269 0.001 (X) 4,4'-DDE <0.01 <0.0054 0.001 1.1 Endrin <0.01 <0.0054 0.002 (X) beta-Endosulfan (11) <0.01 <0.0054 0.056 0.22 414'-DDD <0.01 <0.0054 0.001 1.1 Endosulfan sulfate <0.01 <0.0054 n/a 4,4'-DDT <0.01 <0.0054 0.001 alpha-Chlordane <0.2 <0. 107 (X) gamma-ChloTdane <0.2 <0.107 (X) Toxaphene <1.0 <0.537 0.008 (X) Endrin Aldehyde <0.01 <0.0054 n/a n/a NOTES: DEP CBPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CEPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 99.62 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: RA TER QUALITY MOAVTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 02W INORGANICS Date Aug. 11, 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS CMC TABLE3 nits mg/Ll (lb/day)* (ILg/L) 7 (pg/L) Event 02W 02W CCC Aluminum [total) 1.28 0 0. 1(96hrLC,) (X) Antimony [total) <0.003 <1.61 219 1,095 Arsenic [total] 0.003 0.00 190(As3+) 360(As3+) Beryllium [total] <0.005 <2.69 0,01(%hrLC30) 0.05(96hrLCSO) Cadmium S [total] <0.0001 <0.0537 0.01(96hrLcm) (X) Chromium Total S <0.05 <26.9 1 l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(lnH)+3.688) Chromium VI (ug/1) <0.01 <0.0054 11 16 Copper S [total) 0,0002 0.000 EXP(.8545(InH).1.465) EXP(0.9422(lnH)-l.464) Iron [total] 0.82 0 0.3 mgA**(X) I Lead S [total] <0.001 <0.537 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.4l6) Manganese [total] 0.06 0.0 1 mg/1 2 Mercury [total] <0.0002 <0. 107 0.2 pgA***(X) Nickel $ [total) 0.02 0.0 EXP(0."6(lnH)+l.l645) EXP(0.gWlnH)4-3.36l2) Selenium [total] <0.002 <1.07 10 pSA(X) Silver $ [total] 0.0008 0.000 0.2 EXP(l.72(lnH)-6.52) Thallium [total) <0.001 <0.537 0.018 0.09 Zinc $ (totall <0,005 <2.69 EXP(0.8473(lnH)+0.76l4) EXP(0.8473(tnH)+0.86G4) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 EP CEPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (forshort-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flo@ of 99.62 cfs -This value or natural levels, whichever is greater ** - in an unfiltered water sample II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUAUTY MOATITOR[NG STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 02W ADDITIONAL PARAMETERS Date Aug. 11, 1995 Aug. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 02W 02W CCC CMC TABLE3 CU JUnits (mg/L) (lb/day)* Alkalinity (mg/L CaCO3) 105 n/a minimum of 20 1 Chloride (mgA) 37 0 250 2 Cyanide, free (pg/1) <0.005 0 5 22 Grease & Oil Grab (mg/l) 0.4 0 2 2 Ammonia-Nitrogen 0.10 0 (NH3-N) x (log- I [pKT-pH]+I) itrite-Nitrogen (mg/1) O@03 0.0 N02+NO3=10 2 Nitrate-Nitrogen (mg/l) 1.27 0 (as nitrogen) CBOD, 6 n1a Chemical Oxygen Demand 10 n/a Fecal Coliform (#/IOOmL) 1,940 n/a BACI (X) 3 Phosphorus, total 0.04 0.0 (P) (X) Total Suspended Solids 24 0 Hardness (mg/L CaCO3) 184 n/a max. monthly mean of 150 pH(s.u.)**Jfield1 9.0 n1a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 24.5 n/a I Conductivity (mv/cm) -- [field] 468 n/a Dissolved Oxygen (mg/L 02) ** [field] 8.86 n/a minimum of 5.0 NOTES: n1a - not applicable DEP CEPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CEPT 93 WQS - Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 99.62 cfs 1"[field) - average ofthe 3 grab samples measured in the field P P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to my berieficial water use. ) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITY MONITORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 03W PESTICI]DES/PCBs Date Sept. 20, 1995 Sept. 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS (lb/day)* Event 03W 03W ccc CIVIC TABLE3 [units (RgL) (Kg/L) (pg/L) 01gL) ............. ................;........ alpha-BHC R/a n/a ............. beta-BHC n1a ............. ...... ............. ....... .................. delta-BHC fda n/a .................... ... ................ gamma-BHC (Lindane) ........................... ................................... . ............ 0.001 (X) . ........ . .. .... Heptachlor 0.001 (X) Aldrin O.D01 (X) ...................... ...... ....... ........ Heptachlor epoxide :X 0.1 0.8 alpha-Endosulfan (1) ..... 0.056 0.22 .......... ....................... -, ....................... ......... ... ................. .... Dieldrin .......................... 0.001 (X) ........................... ..................... ............ ... ........ 4,4'-DDE ............. 0.001 .... . ...... ..... ............. . . .......................... ........... .. ........ 0.002 (X) Endrin .......... ............... beta-Endosulfan (11) 0.056 0.22 ............ 4,4'-DDD ..... . ....... ...... 0.001 1.1 Endosulfan sulfate n/a n/a ..... .......................... ........................ 4,4'-DDT 1.1 ...................... . ... ............... 0.001 ...... .......................... ....... .......................... ...... ........................ ........... . .... ....................... (X) alpha-Chlordane ............ .................... . ........... * * ................. ......................... : ............... ...... . . . . ....X... (X) gamma-Chlordane ::::: ..................... .................. . ........ Toxaphene ..... X ...... 0.008 (X) ......... .... ............... ::::: ::::::::::::::::: :;:::: .................... ............. XXX Endrin Aldehyde ........ n/a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 19B9, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for shon-teffn protection) n/a - not applicable loading based on a flow of 4.96 cfs limit for Chlordane 0.06 pgfL (X) analyte eliminated from sampling program 11M - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUAL177MOA7TORING S7VDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 03W INORGANICS Date Sept. 20, 1995 Sept. 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W 03W CCC CMC TABLE3 CU junits (mgL) (lb/day)- (pg/L) (AgIL) Aluminum [total] 0.31 0.00 0. 1(96hrLC.) (X) I Antimony [total] <0.003 <0.0803 219 1,095 Arsenic [total] <0.001 <0.0268 190(As3+) 360(As3+) Beryllium [total] <0.005 <0.134 0.01(96hrLC,) 0.05(96hrLC5.) Cadmium $ [total] <0.0001 <0.0027 0.01(96hrLC5,) (X) Chromium Total S <0.05 <1.34 1 I+EXP(0.9l9-(InH)+I.56l) l6+EXP(0.8l9(InH)+3.688) Chromium VI (ugA) <0.01 <0.268 11 16 Copper $ [total] <0.001 <0.0268 EXP(.8545(lnH)-l.465) EXP(0.9422(InH)-l.464) Iron [total] 0.15 0.0 0.3 mgA--(X) I Lead S [total] <0.001 <0.0268 EXP(I.266(lnH)-4.66l) EXP(I.266(InH)-l.4l6) Manganese [total] 0.04 0.0 1 mg/l 2 Mercury [total] <0.0002 <0.0054 0.2 PgA*..(X) Nickel S [total] <0.01 <0.268 EXP(0.WlnH)4-l.l645) EXP(0.WnH)+3.3612) Selenium [total] <0.002 <0.054 10 pgA(X) silver S [total] <0.0002 <0.0054 0.2 EXP(I.72(lnH)-6.52) Thallium [total] <0.001 <0.0268 0.018 0.09 Zinc S [total] 1 <0.005 1 <0. 134 179.3 198.0 NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1939, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1939, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) @rrable 3 - located on pages 93.7 through 93.15 of 186 mg/L CU - Critical Use: 1) Aquatic Life; 2) Water Supply LC5,, = The concentration of pollutant in test waters that is lethal to W16 of test organisms over a specified time period. H = Hardness loading based on a flow of 4.96 cfis -This value or natural levels, whichever is greater 1* - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUALITY MONITORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 03W ADDITIONAL PARAMETERS Date Sept. 20, 1995 Sept 20,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W CCC CIVIC TABLE3 CU [Units (lb/day). Chloride(mgfi) Alkalinity (mg/L CaC03) 79 n/a minimum of 20 1 34 0 250 2 .............. 5 22 Cyanide, free (pg/1) ..... .... ........... ,rab (mg/1) 2 2 Cirease & Oil C ........... Ammonia-Nitrogen <0.01 <0.269 (NH3-N)x(log-l[pKT-pH)+l) Nitfite-Nitrogen (mg/l) 0.01 0.000 N02+NO3=10 2 Nitrate-Nitrogcn (mg/l) 2.85 0.0 (as nitrogen) CBOD, 7 n/a Chemical Oxygen Demand <10 n1a Fecal Coliform (#/IOOmL) 1,150 n/a BACI (X) 3 Phosphorus, total 0.01 0.000 (P) (X) Total Suspended Solids 4 0 Hardness (mg/L CaC03) 196 n/a max. monthly mean of 150 PH (s.u.) **[field] 8.2 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field) 15.8 n/a I Conductivity (mv/cm) ** [field] 426 n/a Dissolved Oxygen (mg1L 02) ** [field) 4.57 n1a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania DepartmLnt of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU - Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over riot more than a thirty-day period - - loading based on a flow of 4.96 cfis **[field] - average of the 3 grab samples measured in the field (P)-Concentrations s uld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ................. . ............ ................... - analyte eliminated from sampling program ........................ ...... PROJECT NAME: W4 TER QUALITY MONITORING SIUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 03W PESTICI]DES/PCBs Date Sept 20, 1995 Sept. 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W 03W CCC CMC TABLE3 Nnits filg/L) (lb/day)* (ILgIL) (Pg/L) (pg/L) alpha-BHC n/a n1a ....................... ................ ................... ............. ............ . ............ .............. .............. bcta-BHC n/a n/a . . . .................... delta-BHC ........................... n/a n/a .......................... .......................... 0.001 (X) .......................... garnma-BHC (Lindane) .............. .......................... 0.001 (X) Fleptachlor .... "..N. .............. ............. ...... Aldrin 0.001 (X) .................. ....... Fleptachlor epoxide ............... 0.1 0.8 ................. .......... alpha-Endosulfan (1) ........... . .............. 0.056 0.22 Dieldrin 0.001 (X) ................. ................. 4,4'-DDE 0.001 1A ........................ Endfin ......... 0.002 (X) ......................... ............ ........... ..... ...... eta-Endosulfan (11) 0.056 0.22 0.001 1.1 4,4'-DDD .......... ................. Endosulfim sulfate n/a n/a ....... ....... ........... ........ ........... 4,4'-DDT ........ 0.001 ... ........... ... ......... ........... .......................... alpha-Chlordane ......... 00 ............ gamma M -Chlordane . ..... . . . . . .... 0.008 (X) Toxaphene .... ...... Endrin Aldchyde n/a rt/a NOTES: DEP CBPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (forshort-term protection) n/a - not applicable loading based on a flow of 29.75 efs li mit for Chlordane - 0.06 pg/L (X) analyte eliminated from sampling program r(X-)Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: W4 TER QUALITY MOATTORING S TUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 03W INORGANICS Date Sept. 20, 1995 Sept. 20,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W 03W CCC CIVIC TABLE3 CU [units (MgtL) (lb/day)- (Ag/L) (Pg/L) Aluminum [total] <0.1 <16.0 0. 1(96hrLcs.) (X) I Antimony [total] <0.003 <0.481 219 1,095 Arsenic (total] <0.001 <0.160 190(As3+) 360(As3+) Beryllium [total] <0.005 <0.802 0.01(96hrLC,) 0.05(96hrLC,,) Cadmium $ [total] <0.0001 <0.016 0.0](96hrLC,) (X) Chromium Total S <0.05 <8.02 1 I+EXP(0.8I9-(lnH)+I.56I) I6+EXP(0.8I9(InH)+3.688) Chromium VI (ug/1) <0.01 <1.60 11 16 Copper S [total) <0.001 <0.160 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-I.464) Iron [total] 0.13 0.0 0.3 mg1l-(X) I Lead S [total] <0.001 <0. 160 EXP(1.266(1;6@4.661) EXP(I.266(lnH)-I.4l6) Manganese [total] 0.03 0.00 1 mg/l 2 Mercury [total] <0.0002 <0.032 0.2 AgA ... (X) Nickel S [total] <0.01 <1.60 EXP(0.946(InH)+I.I645) EXP(0.g46(lnH)+3.3612) Selenium [total] <0.002 <0.32 10 ILgIl M Silver $ [total] <0.0002 <0.032 0.2 EXP(I.72(lnH)-6.52) Thallium [total) <0.001 <0. 160 0.018 0.09 Zinc $ [total] <0.005 <0.802 12.7 14.0 NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Enviromnental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LCx, = The concentration of pollutant in test meters that is lethal to 5(r/o of test organisms over a specified time period. H = Hardness loading based on a flow of 29.75 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample I(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 03W ADDITIONAL PARAMETERS Date Sept. 20, 1995 Sept. 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W CCC CIVIC TABLE3 CU [Units (lb/day). Alkalinity (mg/L CaC03) 104 n/a minimum of 20 1 Chloride (mg1l) 42 0 250 2 Cyanide, free (pgtl) 5 22 ....................... .... ............ ... ........ :X-X-X-X-X-X ...... ........... 2 2 Grease & Oil Grab (mg/1) . ........................... Ammonia-Nitrogen 005 (NH3-N)x(Iog-I[pKT-pHI+I) @ itrite-Nitrogen (mg1l) 0.02 0.00 N02 + N03-10 2 Nitrate-Nitrogen (mg/l) 0.70 0 (as nitrogen) CBOD5 5 n/a Chemical Oxygen Demand 10 n1a Fecal Coliform (#/IOOmL) 2,140 n/a BAC I (X) 3 Phosphorus, total <0.014 <2.25 (P) (X) Total Suspended Solids 4 0 Hardness (mg/L CaCO3) 144 n/a max. monthly mean of ISO pH (s.u.) **[field] 8.19 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 16.0 n/a I Conductivity (mv/cm) ** [field] 487 n1a Dissolved Oxygen (mgtL %) ** [field) 11.3 n/a minimum of 5.0 NOTES: rila - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation JN # - colonies BAC I - MAX = geometric mean of 200/1 00m] based on not less than 5 samples taken over not more than a thirty-day period - - loading based on a flow of 29.75 cfs --[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ............ .. . ...... analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MOA7TOR17VG STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 03W PESTICIDES/PCBs Date SepL 20, 1995 Sept. 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W 03W CCC CMC TABLE3 jUnits (AgL) (lb/day)* (pgL) (pg/L) (pg/L) n/a ........... ... :::: . ........................... . ....... alpha-BHC nta ................ *........ .......................... ........................... .......................... beta-BHC n/a ........................... ................ delta-BHC n1a n/a ....... .. .. ... X, ....... .................. gamma-BHC (Lindane) 0.001 (X) ........................... .......................... ........................... ...... 0.001 (X) Heptachlor Aldrin 0.001 (X) ................. .......................... 0.1 0.9 Heptachlor epoxide ........................... alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 ...... .................. Endrin -:i*i:i:`X.X.X.X-: 0.002 (X) ......... "' ... .... ........................... eta-Endosulfan (11) 0.056 0.22 0.001 1.1 4,4'.DDD Endosulfim sulfate n/a via 4,4'.DDT 0.001 1.1 alpha-Chlordane (X) gamma-Chlordane (X) Toxaphene 0.008 (X) . .......... .................. ........... . .......... ......... ::: ...... n/a Endrin Aldehyde %X,X,X,A::::::%x n/a NOTES: DEP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 1), 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of - tda limit for Chlordane = 0.06 pg/L (X) -analyteeliminatedfroniswnplingpmgram 11(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie @jb PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUM13ER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 03W INORGANICS Date Sept. 20, 1995 Sept 20, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 03W 03W CCC CMC TABLE3 Cu junits (mg/L) (lb/day)* (pg/L) (Pg/L) Aluminum [total] <0.1 0. 1(96hrLcm) (X) Antimony [total] <0.003 219 1,095 Arsenic [total] <0.001 MAs3+) 360(As3+) Beryllium [total] <0.005 0.01(96hrLC,) 0.05(96hrLC,) Cadmium S [total] <0.0001 0.01(96hrLCM) (X) Chromium Total $ <0.05 I I+EXP(0.8l9'(InH)+l.56l) I6+EXP(0.8l9(InH)+3.689) Chromium VI (ugtl) <0.01 11 16 Copper S [total] <0.001 EXP(.8545(InH)-I.465) EXP(0.9422(lnH)-I.464) Iron [total] 0.09 0.3 mg1l**(X) I Lead S [total] <0.001 E%P(I.266(InH)-4.66l) EXP(I.266(]nH)- 1.416) Manganese [total] 0.03 1 mgfl 2 Mercury [total] <0.0002 0.2 PgA ... (X) Nickel S [total) <0.01 EXP(0.846(lnH)+I.l645) EXP(0.846(InH)+3.36l2) Selenium [total] <0.002 10 Pg/I (X) Silver S [total] <0.0002 0.2 EXP(I.72(InH)-6.52) Thallium [total] <0.001 0.018 0.09 Zinc $ [total] <0.005 12.6 1 14.0 1 NOTES: DEP CUPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93. 15 of Chapter 93 Water Quality Standards @ CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC,@ - The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness flow information not available -This value or natural levels, whichever is greater - - in an unfiltered water sample J(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WA TER QUALITY MOWORING STUD Y FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 03W ADDITIONAL PARAMETERS DEP CHPT 16 WQC DEP CHIPT 93 WQS Date Sept. 20, 1995 Sept. 20, 1995 Event 03W 03W CCC CMC TABLE3 CU junits (mg/L) (lb/dayy minimum of 20 1 Alkalinity (mg/L CaC03) 98 250 2 Chloride (mg/l) 46... .._11.-.-.".X.....::1-'::: . ........................ ............. . ........ .......... ............ ... 22 ............. X ............. 5 Cyanide, free (pg/1) .................. ............. ...... ... ........ 2 2 ............... Grease & Oil Grab (mgfl) ...... ................ ............. (NH3_N)x(log-l[pKT-pH)+l) Ammonia-Nitrogen 0.07 N02+NO3-10 2 Nitrite-Nitrogen (mg/1) 0.03 Nitrate-Nitrogen (mg/0 1.97 (as nitrogen) CBOD3 6 Chemical Oxygen Demand 10 BACI (X) 3 Fecal Coliform (#/IOOmL) 290 Phosphorus, total 0.06 (P) (X) Total Suspended Solids 2 Hardness (mg/L CaCO3) 222 max. monthly mean of 150 pH (s.u.) -[field) 8.1 6.5-9.0(X) I Temperature CC) ** [field) 17.2 Conductivity (mv/cm) ** [field] 544 Dissolved Oxygen (mg/L 02) ** [field] 2.4 minimum of 5.0 1 NOTES: rila - not applicable DEP CEPT 16 WQC = Pennsylvania Department of Environmental Protection Chpit 16 Water Quality Criteria for Toxic Substances effective March 11, 1989.19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX - geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - flow information not available **[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths; of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Wat Quality Criteria Designated Water Use Drainage List - Lake Erie .......... analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOATTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENULE CREEK EVENT: 04D PESTICIDES/PCBs Date OcL 3, 1995 Oct. 3,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC CMC TABLE3 Pnits 01gL) (lb/day). (40 (pg/L) 61g/L) ............. ............. alpha-BHC n/a n/a ...... ..... beta-BHC ................ n/a n1a .......... . ...... . .......... .......... delta-BHC ........... .......................... n/a n/a ............. gamma-BHC (Lindane) ........... 0.001 (X) ... .... ........ Heptachlor ............... 0.001 (X) ............. ....... . . ... .......... . . . . . . . . Aldrin ........... .......... ..... 0.001 (X) .............. . .................. Heptachlor epoxide .................... 0.1 0.9 alpha-Endosulfan (1) .............. 0.056 0.22 ...... .... :1 ...................... Dieldrin .. ........... X... ................ .. 0.001 (X) .......... .. .............. . ........ ............ . ... ...... X, ............ ............. 4,4'-DDE 0.001 1.1 ....................... ........................ Endrin 0.002 (X) 0.056 0.22 ............. beta-Endosulfm (11) ........ *...... X.. ............ ............. ........... 4,4'-DDD ............. ............. .. ............. ........ ............ 0.001 ............. ..... ..................... Endosulfan sulfate ............ n1a n/a 4,4'-DDT ......................... . .................. ...... 0.001 1.1 . ........... ... .. .. .... . (X) alpha-ChIOTdane ............. . ............ ................. ....... ......................... ......................... .......................... gamma-Chlordane ........ ............................. (X) ....................... .... ....... .. .......... V................ ......... ........................... .. . ...... .......................... . ....... ......... ....... %....... ........ %............ ......... . ... ... ..... .... .... ..................... Toxaphene 0.008 (X) Endfin Aldehyde n/a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 19 89,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection y Chapter 93 Water Qual it Standards effective Much 11, 19119,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable - analyte eliminated from sampling program loading based on a flow ofo.55 cf; - limit for Chlordane - 0.06 pg/L (X) II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: WATER QUALITYMOA71TORING STUDY FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 04D INORGANICS Date Oct. 3, 1995 Oct. 3, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC CMC TABLE3 CU junits (mg/L) (lb/day). L)_ ("g/L) I Aluminum [total] <0. 1 <0.297 0. 1(96hrLC,) (X) I Antimony [total] ............. 219 1,095 Arsenic [total] <0'001 <0 00297 190(As3+) 360(As3+) ........................... ........... .............. ................... .......................... .............. Beryllium [total] 0.01(96hrLC,) 0.05(96hrLC,,) .............. ...................... ...... ......................... Cadmium S [total] <0.0001 <0.000297 0.01(96hrLC50) (X) Chromium Total $ <0.05 <0.148 1 l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(1nH)+3.688) ............ ......... ........................... .......................... ............. Chromium VI (ugtl) 11 16 Copper S [total) 0.001 0.00000 EXP(.8545(tnH)-l.465) EXP(0.9422(lnH)-l.464) Iron [total) <0.03 <0.089 0.3 mgfl**(X) I Lead S [total] <0.001 <0.00297 EXP(I.266(id".661) EXP(l.266(lnH)-l.4l6) Manganese [total] 0.01 O.OODO I mg1l 2 .... ............. .... ............. .... ..... .. . . ...... ..... ..... .....................i.... ....... (X) .... ....... ....... .. ....... .:::: Mercury [total] ........................... .................. 0.2 Ag/l ...................... . ............ ............ ........................... ........................... Nickel S [total] 0.02 0.000 EXP(0.94WnH)+-l. 1645) EXP(0.946(lnH)+3.36l2) X Selenium [total] ............. 10 PSA (X) Silver $ [total] <0.0002 <0.00059 0.2 EXP(l.72(lnH)-6.52) Thallium [total) .............. .... . ..... . -:-X-:-X-X-X-:-: . ......... ........ 0.018 0.09 Zinc $ [total] <0.005 <0@0148 EXP(0.8473(lnH)+0.76l4) EXP(0.8473(lnH)+0.8604) NOTES: DEP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chpt 16'Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHFT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-terni protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC3@ = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 0.55 cf3 -This value or natural levels, whichever is greater *** - in an unfiltered water sample II(X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WA TER QUALITY MOAFITORING S TUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 04D ADDITIONAL PARAMETERS Date Oct. 3, 1995 Oct. 3, 1995 DEP CHPT 16 WQC DEP CEPT 93 WQS Event 04D 04D CCC CMC TABLE3 CU JUnits (-g/L) (lb/day). T Alkalinity (mg/L CaCO3) n/a minimum of 20 1 Chloride (mg/l) :11 0 250 2 Cyanide, free (lig/l) . . . ... 5 22 ... .. ........... ...... ... . ... ............ .................. Grease & Oil Grab (mg/1) 2 2 .............................. .......... ...... ..... Ammonia-Nitrogen <0.01 '0. (NID-N) x (109- 1 [pKT-pH]+ 1) Nitrite-Nitrogen (mg/1) <0.01 <0.0297 N02 + N03-10 2 Nitrate-Nitrogen (mg/1) 1.95 0.00 (as nitrogen) CBOD5 2 n/a Chemical Oxygen Demand <10 n/a Fecal Coliform (#/IOOmL) 29 n/a BAC I (X) 3 Phosphorus, total <0.01 <0.0297 (P) (X) Total Suspended Solids 2 0 Hardness (mg/L CaCO,) 198 n1a max. monthly mean of 150 pH (s.u.) **[field] 8.2 n/a 6.5 - 9.0 (X) I Temperature (C) ** [field] 13.7 n1a I Conductivity (mv/cin) 0* [field] 486 n1a Dissolved Oxygen (mg/L 0,) ** [field] 6.71 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1999, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) MC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93. 15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more thin a thirty-day period * - loading based on a flow of 0.55 cfs --[field) - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WA TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCAT1ON: WALNUT CREEK EVENT: 04D PESTICIDES/PCBs Date Oct. 3,1995 Oct. 3,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC CMC TABLE3 jUnits OgL) (lb/day)* 61g/L) (ItgL) (Ag/L) alpha-BHC n1a n/a . ................ :......... .............. ............. ............. beta-BHC . ................................ n/a n/a . .................. ................ delta-BHC .............. ............ n1a n/a ....................... ............................... gamma-BHC (Lindanc) ............. 0.001 (X) ............. ................. Heptachlor ............... .......... 0.001 (X) . .... ... ... .............. .............. Aldrin 0.001 (X) Heptachlor epoxide . ......... 0.1 0.9 ................. ...........*............. ............... alpha-Endosulfan (1) 0.056 0.22 Dieldrin ................... ....................X 0.001 (X) .......................... 4,4'-DDE 0.001 1.1 ......... ... .... ............. Endrin .................... 0.002 (X) beta-Endosulfan (H) ................. 0.056 0.22 ......................... ......................... ......................... ......................... .......... ............. 4,4'-DDD 0.001 . ..................... .......... Endosulfan sulfate .............. .... .. ................. ................. n/a via .............. .................... . . .................. 4,4'-DDT 0.001 1.1 ......................... ........................ alpha-Chlordane (X) ......................... .................... ........... garnma-Chlordane (X) . ... ....... :1.1 . . . . ... . ................. Toxaphene .............. 0.008 (X) ............. .. ........ .......... . . ::. Endfin Aldehyde .......... - .:" n/a n/a ........ .. .................... NOTES: DFP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 17.61 cfs - limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Erie ............... ..X n ...... analyte eliminated from sampling prograt PROJECT NAME: WATER QUALITY MOA17TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 04D INORGANICS Date Oct. 3 '1995 Oct. 3, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC _F CIVIC TABLE3 CU jUnits (mg/L) (lb/day)* (gg/L) (gg/L) Aluminum [total] <0.1 <9.50 0. l(96hrLC") (X) Antimony [total) 219 1,095 ............ Arsenic [total] <0.001 <0.095 190(As3+) 360(As3+) Beryllium [total) 0.01(96hrLc,) 0.05(96hrLC") Cadmium S (total] <0.0001 <0.0095 0.01(96hrLC9.) (X) Chromium Total S <0.05 <4.75 1 l+EXP(0.9l9-(lnH)+l.56l) l6+EXP(0.8l9(lnH)+3.688) ......... ... ............................ ........... .X ........................ ........ .. .................... ...... ... Chromium V1 (ug/1) 11 16 .............. ...... Copper $ [total] <0.001 <0.095 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) iron [total] <0.03 <2.85 0.3 mgA-*(X) I Lead $ [total] <0.001 <0.095 EXP(l.266(lnH)4.66l) EXP(l.266(lnH)-l.4l6) Manganese [total] 0.02 .... 0:00. 1 mgn 2 _-X ........ ............. ercury [total] 0.2 pgA***()() ........ . ................ ................. . . . ..... ... Nickel $ [total) 0.01 0.00 EXP(0.846(lnH)+l.l645) EXP(0.gWlnH)+3.36l2) Selenium [total] 10 Pg1l (X) ........................... ....... Silver $ [total] <0.0002 <0.019 0.2 EXP(l.72(lnH)-6.52) .................. .. .... ...... 0.018 0.09 Thallium [total] ........................... Zinc S [total) <0.005 <0.475 EXP(0.9473(lnH)+0.76l4) EXP(0.&473(lnH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1999,19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC3,, = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 17.61 cf; -This value or natural levels, whichever is greater ** - in an unfiltered water sample (X) - Chapter 93 Wat r Quality Criteria Designated Water Use Drainage List - Lake Erie .......... .. X X. :::::::::3 PROJECT NAME: W4 TER QUALITY MONITORING STUD Y FOR 7HE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 04D ADDITIONAL PARAMETERS Date Oct. 3,1995 Oct. 3, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC CIVIC TABLE3 CU nits (mg/L) (lb/day)* Alkalini (mg1L CaCO3) 122 n/a minimum of 20 1 Chloride (mg/1) 51 0 230 2 Cyanide, free (pg/1) ......... 5 22 ........... . 2 2 Grease Oil Grab (mg/1) Ammonia-Nitrogen 0.02 0.00 (NH3-N)x(log-l[pKT-pHj+l) Nitrite-Nitrogen (mg/1) <0.01 <0.95 N02 + N03=10 2 Nitrate-Nitrogen (mg/1) 0.10 0.00 (as nitrogen) CROD, 2 n/a Chemical Oxygen Demand <10 n/a Fecal Coliform (#/IGOmL) 45 n1a BACI (X) 3 Phosphorus, total <0.01 <0.95 (P) M Total Suspended Solids 4 0 Hardness (mg/L CaCO3) 220 n/a max. monthly mean of 150 pH (s.u.) **[field] 8.3 n/a 6.5-9.0(X) I Temperature (*C) ** [field) 13.5 n/a I Conductivity (mv/cm) ** [field] 559 n/a Dissolved Oxygen (mg/L 02) ** [field] 10.1 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-terin protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 17.61 cfs **[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that we or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Like Efie "XXXXX77:7....... ... . .analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOMTORINGSTUDY FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 04D PESTICIDES/PCBs Date Oct. 3, 1995 Oct, 3,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 041) CCC CIVIC TABLE3 [Units (pg/L) (lb/da (pg/L) (pgL) (pg/L) alpha-BHC ....... n1a n/a .............. ...... ............ ...... ............. ... .. .... .......................... beta-BHC .................. .................. n/a n/a .................... ........................... .......................... :X. delta-BHC .............................. .......................... ......................... gamma-BHC (Lindane) ................................ 0.001 (X) Heptachlor 0.001 (X) .......... %-.% ................. . .................... .......................... ..%....%......................................- ............ ........... .. ..... .......................... ..... . .... Aldrin ............ .. ....... ............ 0.001 (X) Heptachlor epoxide ............. 0.1 0.9 alpha-Endosulfan (1) ........ ......... ............ ::::: - .11 .............. 0.056 0.22 ................ Dieldrin ....... ........ 0-001 (X) ............. ............. ........................... .......................... .......................... .......................... ... . ............... . .............. .... ..................... 4,4'-DDE ............................ ... 0.001 1.1 ........................... ... . ..................... ........... .............. Endrin ......... 0.002 .... .............. X. ..... .... . ...... .................. ....... beta-Endosulfan (11) 0.056 0.22 . ......... . ......... ...... ......... ....... ......... ........ ......... ......... ......... .......... 4,4'-DDD 0.001 1.1 . ...................... . ......... ................ :.......... Endosulfan sulfate ................... ................. ........................... .......................... ............. .... ..... ............. n/a n/a ............... ............. ........... ": ............. .. 4,4@-DDT 0.001 .... ..................... ... ........... . ... ............................. alpha-Chlordane -XI.-N 1.1..:.:.:.:.:.:.:.:.::::.:.::.:.-I ....... ....... ....... ................. ............ ......... (X) ....... ... . .... ...... . ........... gamma-Chlordane 01) ............ 0.008 (X) Toxaphene Endrin Aldehyde ............... n1a n/a ......... ................ NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Envirommental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1999,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-tem protection) n/a - not applicable loading based on a flow of 29.46 cfs - limit for Chlordane = 0.06 Mg/L (X) (X) - Chapter 93 Wat r Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: W4 TER QUALITY MOAVTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 04D INORGANICS Date OcL 3, 1995 1 Oct. 3,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 04D 04D CCC CIVIC TABLE3 Cu junits (mgL) (lb/day). (pg/L) (ILg/L) Aluminum [total] <0.1 <15.9 0. 1(96hrLCO) I Antimony [total] ......... . ............ ......... ...............I............................ . 219 1,095 ...................................... ............................................ ... Arsenic [total] <0.001 <0.159 190(As3+) 360(As3+) Beryllium [total] ..... 0.01(96hTLC,) 0.05(96hrLC,) ............ XXXXX Cadmium S [total] 0.0l(96hrLC,) (X) Chromium Total S <0.05 <7.95 1 l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(lnH)+3.688) .. .......................... Chromium VI (ugA) 11 16 ................. ......... ..................... ............... ... Copper S [total] <0.001 <0. 159 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) Imn [total] 0.06 0.00 0.3 mSA-*(X) I Lead S [total] <0.001 <0. 159 EXP(l.266(lnH)-4.66l) EXP(l.266(hH)-1.416) Manganese [total] ......... 0.-0-3 ........... ....0 ,*00 .......... I mgA 2 ......... X. ........................... ...... Mercury [total] ........................... ...... . ........................ ................ X- 0.2 pgA*.*()C) Nickel S [total] 0. 01 0.00 EXP(0.&46(lnH)+l. 1645) EXP(0.WnH)+3.36l2) Selenium [total] 10 PgA (X) Silver S [total] <0.0318 0.2 EXP(l.72(lnH)-6.52) ... ....... --@-- ....... .. ....... Thaflium [total] ......... 0.018 0.09 ................ Zinc $ [total] <0.795 EXP(0.&473(lnH)+0.76l4) EXP(0.&473(1nH)+0.8604) NOTES: DEP CEPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 29.46 cfs -This value or natural levels, whichever is greater - - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric .. .............. : - ............. ....... . .................................. PROJECT NAME: WATER QUALITY M0AVT0RLlVG STUDY FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 04D ADDITIONAL PARAMETERS Date Oct. 3,1995 Oct. 3, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS CMC TABLE3 CU @.ita (mg/L) b/day)* _T Event 04D 04D CCC Alkalinity (mg/L CRC03) 109 n/a mininiumol'20 I Chloride (mg/1) 51 0 250 2 ... . .... .... ........... Cyanide, free (pgA) ........... 5 22 .............. Grease & Oil Grab (mgtl) ......... 2 2 ............. . ...................... Ammonia-Nitrogen 0. 11 0.0 (NH3-N) x (log-l[pKT-pH]+l) Nitrite-Nitrogen (mgA) 0.01 0.00 N02+NO3=10 2 Nitrate-Nitrogen (mg/1) 2.40 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand <10 F11a Fecal Colifinrin (#/IOOmL) 12 n/a BAC I (X) 3 Phosphorus, total 0.08 0.0 (P) (X) Total Suspended Solids 2 0 Hardness (mg/L CaCO,) 226 111a max. monthly mean of 150 pH (s.u.) **[field] 8.2 n1a 6.5 - 9.0 (X) I Temperature (1C) ** [field] 14.8 n/a I Conductivity (mv/cm) ** [field) 598 n1a Dissolved Oxygen (mg/L 0,) ** [field) 10.1 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHIPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 ofChapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 29.46 cfis **[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths ofalgae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ............. ............. . ........ analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOAVTORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENRLE CREEK EVENT: 05W PESTICIDES/PCBs Date Oct. 5,1995 Oct. 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CIVIC TABLE3 (pg/L) (lb/day)* 641-) (pg/L) (tigL) alpha-BHC n/a n/a beta.BHC n/a n/a delta-BHC n/a n/a gamma-BHC (Lindane) 0.001 (X) Heptachlor 0.001 (X) ldrin 0.001 (X) Heptachlor epoxide 0.1 0.9 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) beta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate ...... . . . . . .. . . . . .. . . . . .. . . . . .n/a n/8 4,4'-DDT 0.001 1.1 .......... .......... . . .... ........... ...... (X) -Chlordane ........... ... X.X.- alpha ........... ..... . ........... ........... (X) -Chlordane .. ........ gamma . ..... . . .............. Toxaphene ........... ... 0.008 (X) Endrin Aldehyde n1a ft/a NOTES: EP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much H, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 55.58 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric analyte eliminated from samplingprogram PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TVELVEMILE CREEK EVENT: 05W INORGANICS Date Oct. 5, 1995 Oct. 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS [Units (mg/L) (lb/day)- (119/L) E 3 CU Event 05W 05W cc CMC TABL (PS/Lc) I I Aluminum [total] 0.59 0 0. 1(96hrLC50) (X) Antimony [total) ..... .. X 219 1,095 . .......... . Arsenic [total] <0.001 <0.300 190(As3+) 360(As3+) Beryllium [total) 0.01(96hrLCN) 0.05(96hrLC,) ...... .... Cadmium S [total] <0.0001 <0.030 0.01(96hrLC@) (X) Chromium Total $ <0.05 <15.0 1 I+EXP(0.8I9-(InH)+I.56I) I6+EXP(0.8I9flnH)+3.689) Chromium VI (ugA) 16 ............. Copper S [total] 0.002 0.000 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-I.464) Iron [total] 3.14 0 0.3 mg/1--(X) I Lead S (total] 0.001 0.000 EXP(I.266flnH)-4.66I) EXP(I.266(InH)-I.4I6) Manganese [total] 0.49 0 1 mg/l 2 ................ . . . . . . . . . . . . . Mercury [total] ......................... ..... ..... 0.2 pgtl*'*(X) ... ....... ... Nickel $ [total) <0.01 <3.00 EXP(O.846(InH)+ 1. 1645) EXP(0.8460nH)4-3.36l2) Selenium [total] 10 Pg/I (X) Silver S [total] <0.0002 <01060 0.2 EXP(I.72(InH)-6.52) ................... Thallium [total] ............. ......... ..... .............. ............. ............... ............ . 0.018 0.09 Zinc S [total] <0.005 <1.50 EXP(0."73(lnH)+0.76l4) EXP(O. 8473(InH)4-0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, P )89,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93-7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC3@ = The concentration of pollutant in test waters that is lithal to 500/6 of test organisms over a specified time period. H = Hardness loading based on a flow of 55.58 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ..... ........ analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENBLE CREEK EVENT: 05W ADDITIONAL PARAMETERS Date Oct. 5,1995 Oct. 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS (mg/L) (lb/day)* T CMC TABLE Event 05W 05W CCC Prits I I Alkalinity (mg/L CaCO3) 53 n1a minimum of 20 1 Chloride (mgA) 37 0 250 2 ........................................ Cyanide, free (pgfl) 5 22 ....... ......... . ... ........................................ .... ... ......... ........... X-Xim ........................ Grewe & Oil Grab (nig/1) ................................................ 2 2 Ammonia-Nitrogen (NH3 -N) it (log- I [pKT-pFg+ 1) Nitrite-Nitrogen (mg/1) <0.01 <3.00 N02+NO3=10 2 Nitrate-Nitrogen (mgA) 1.37 0 (as nitrogen) CBOD, I I n/a Chemical Oxygen Demand 30 n/a Fecal Coliform (0/100mL) 940 n/a BACI (X) 3 Phosphorus, total 0.34 0 (P) (X) Total Suspended Solids 198 0 Hardness (mg/L CaCO3) 164 n/a max. monthly mean of 150 pH (s.u.) **[field) 8.7 n/a 6.5 - 9.0 (X) I Temperature (*C) -- [field] 15.2 n/a I Conductivity (mv/cm) ** [field] 319 n/a Dissolved Oxygen (mg/L 02) **.[field) 7.38 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHFT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU - Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period - - loading based on a flow of 55.58 cfi; **[field] - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the "tent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Wat r Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program ........................................... .......................................... .. ........... PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 05W PESTICIDES/PCBs Date Oct. 5,1995 Oct. 5,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CMC TABLE3 rnits (pg/L) (lb/day)- (PgtL) (pg/L) (PSIL) alpha-BHC .......... n/a n/a ........... . ...... ..... ... %...",'.... beta-BHC .. ........ ft/a n/a ........ ............... ............... ..... ... ......... ......... . ... ...... ..... ........................... delta-BHC n/a n/a .............. ................ ... gamma-BHC (Lindane) .... ........ 0.001 (X) .......... ... .................... i::: . . . . . . . . . . ................ Heptachlor 0.001 (X) ....................... ...................... Aldrin 0.001()() ................ . 0.1 0.8 Heptachlor epoxide .............. .. .......................... ............. *,:,: ......... ...................... alpha-Endosulfan (1) ......... 0.056 0.22 ..................... . ...... ......... ... . ....................... . .... . . ..... . . .......................... ... ..... ......... ... .......... ............ .. ........ ............. . Dieldrin ............... ...... .1'.1.'......"....,.............. :::::: 0.001 (X) ... .......................... 4,4'-DDE 0.001 1.1 ........................... : ...: - - ........................... .......................... .......................... .......................... Endrin .............. 0.002 (X) ............ ......... .......................... .......................... .......................... .... ............... ................... ...... 0.056 0.22 eta-Endosulfan (11) ........ ............... ixx: 4,4'-DDD xi.i.i.iii ................... 0.001 1.1 ...........%................ ........................... ...................... ... ............................... .......................%... ......................... n/a Endosulfan sulfate n1a .......................... .......................... ........................... ................ ................ *..... ................ ............ . ................ ............................ 4,4'-DDT 0.001 ........................... ................ (X) alpha-Chlordane ........................... ............... (X) gamma-Chlordane, ............ ................ .................... .. ......... ................... ..................... .... .. ................ ........... :: .... :.: ..................... 0.008 (X) ............ ............. . .............. ............ ................... ........... .............. ......... ............. Endrin Aldehyde n/a Iva Toxaphene NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CBPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 212.99 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Wat r Quality Criteria De signated Water Use Drainage List - Lake Erie ........... . ......... ............ .... analyte eliminated from sampling program PROJECT NAME: W4 TER QUAL17T MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 05W INORGANICS Date Oct. 5,1995 Oct. 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CIVIC TABLE3 CU Nnits (mgL) (lb/day)* (pg/L) (PgtL) Aluminum [total) <0.1 <115 0. 1(96hrLC") (X) Antimony [total) 219 1,095 Arsenic [total] 0.002 190(As3+) 360(As3+) ............ Beryllium [total] C") 0.05(96hrLC,) 001(96hrL Cadmium S [total] <0.0001 <0. 115 0.01(96hrLC") (X) Chromium Total S <0.05 <57.4 1 l+EXP(0.8l9-(lnH)+l.56l) lrY+EXP(0.8l9(lnH)+3.688) Chromium V1 (ug/l) 11 16 Copper $ [total] 0.008 0.00 EXP(.8545QnH)-l.465) EXP(0.9422(lnH)- 1.46-4) Iron [total] 14.40 0 0.3 mg/l**(X) I Lead $ [total] 0.014 0.0 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.4l6) Manganese [total) 0.80 0 1 mgA 2 .... X-X-X-X.,., 0.2 pgA..*(X) Mercury [total] .... Nickel $ [total] <0.01 <11.5 EXP(0. 846(InH)+ 1. 1645) EXP(0.g46(lnH)+3.36l2) ........... Selenium [total] ........ ................. 10 pgA (X) . . ...... ... Silver S (total] <0 0002 <0.230 0.2 EXP(l.72(lnH)-6.52) ...........:....... ........ -".:::::::::;:: .. ....... .......... . .......... Thallium [total] ....... 0.018 0.09 ............ . ............ :X Zinc S [total) <0.005 <5.74 EXP(0.8473(lnH)+0.76l4) EXP(0.8473(lnH)+0.86G4) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CUPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards @ U = Critical Use: 1) Aquatic Life; 2) Water Supply C3@ = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 212.99 cfs -This value or natural levels, whichever is greater in an unfiltered water sample @(X) Chapter 93 Wat r Quality Criteria Designated Water Use Drainage List - Lake Eric XX .. ........ .......... PROJECT NAME: WATER QUALITY MOATTORING STUDY FOR TUE LAKE ERIE W4 TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 05W ADDITIONAL PARAMETERS Date Oct. 31 1995 Oct. 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CIVIC TABLE3 CU Pnits I (mg/L) (lb/day), Alkalinity (mg/L CaC03) 122 n/a minimum of 20 1 Chloride (mg/1) 37 250 2 Cyanide, free (pg/1) ... .. 5 22 ... ...... .... .. ... . . ..... ...... ................ ...... .. . ........... ... ............... ........... . 2 2 Grease & Oil Grab (mg1l) Ammonia-Nitrogen 0.02 0.0 (NH3-N) x (log-l[pKT-pH]+l) Nitrite-Nitrogen (mg/l) 0.05 0.0 N02 + N03=1 0 2 Nitrate-Nitrogen (mg1l) 0.56 0 (as nitrogen) CBOD, 10 n/a Chemical Oxygen Demand so n/a Fecal Coliform (4/100mL) Z940 n/a BAC I (X) 3 Phosphorus, total 1.08 0 (P) (X) Total Suspended Solids 892 0 Hardness (nig/L CaCO3) W n/& inivi. monthly mean of 150 pH (s.u.) **[field] 7.4 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 15.2 n/a I Conductivity (mv/cm) *0 [field) 315 n/a Dissolved Oxygen (mg/L 0,) ** [field) 9.7 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection - Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. H. 1059 DEP CHPT 93 WQS =Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based an a flow of 212.99 cfs **[field] - average of the 3 grab smplw measured in the field (p)-Concentratiorissh Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to my beneficiall water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOATITORINGS7TJDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 05W PESTICIDES/PCBS Date Oct. 5 1995 Oct. 5,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CMC TABLE3 junits WIL) (lb/day)- 6LgL) (pg/L) (pg/L) ............ ....... ........................... alpha-BHC ................. ............... ............. n/a n/a ................ ........ ........ .............. .................... ........... beta-BHC -'.*-*-*.,-,.,..,....":::,:,:,:,:,:,::: . ...... n/a n/a .......... ..... ........ delta-BHC : n/a n1a ................................ ........ ............ ....... ................ . ................. gamma.BHC (Lindane) 0.001 (X) ............ Heptachlor 0.001 (X) ........ ...... Aldrin 0.001 (X) 0.1 0.8 Heptachlor epoxide 0.056 0.22 alpha-Endosulfan (1) Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) .......... ........... ............ ............. eta-Endosulfan (11) .............................. ': 0.22 ... .. ...... 0.056 4,4'-DDD 0.001 1.1 ........ ....... Endosulfan sulfate n/a ala ....... .................. ................... ................... 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) .......... gamma-Chlordane (X) .................. . ........ .. . .......... . . ........ 0.008 (X) Toxaphene . ..... ...... ............. .. ..... n/a Endrin Aldehyde ................ NOTES: DEP CEPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS =Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentrafion (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable - analyte eliminated from sampling program loading based on a flow of 162.19 cfs - limit for Chlordane - 0.06 gg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ...... .... PROJECT NAME: WATER QUALITY MOAFITORING S7VD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 05W INORGANICS Date Oct. 5,1995 OcL 5, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CIVIC TABLE3 jUnits (mgtL) (lb/day)* (pg/L) (WL) I _L@ Aluminum (total] 056 0 0.1(96hrLC, (X) I ........... i.............. ................. ............................................. X.:.X.X-:-X Antimony [total) .......... 219 1,095 Arsenic [total] <0001 190(As3+) 360(As3+) Beryllium [total] 0.01(96hrLC,) 0.05(96hrLC,) ...... .......... . Xx .......... Cadmium S [total] <0.0001 <0.0875 0.01(96hrLC,)(X) Chromium Total S <0.05 <43.7 1 I+EXP(O.819-(InH)+ 1.56 1) 16+EXP(0.8I9(lnH)+3.688) ......... . . ....... ..... . ... .. .................. ....... .................. ....................... .. Chromium VI (ugA) ........................... ........................ :..:j 11 16 .............. Copper S [total] 0.001 0.000 EXP(.8545(InH)-I.465) EXP(O.9422(InH)-l.464) Iron (total] 2.23 0 0.3 mgtl--(X) I Lead S [total] 0.003 0.00 EXP(1.266(InH)-4.66I) EXP(I.266(InH)-I.4I6) Manganese (total] 0.26 0 1 mg1I 2 ercury [total] .................... ...... .............. ................................... 0.2 pgA***(X) Nickel $ [total] <0.01 <8.75 EXP(0.846flnH)+l.l645) EXP(0.946(InH)+3.36I2) Selenium [total] ...... . .. . .. .......................... .......................... .......................... ........................... ........................... .. ........ .......................... 10 Pg(l (X) ............. .X.X-,:-:.X :.:.,: . . .............. . ' . `%.11*.-'.-.`- .... Silver$ [total] <0.0002 <0. 175 0.2 EXP(I.72(InH)-6.52) . . ......... Thallium [total) ................ ... 0.018 0.09 Zinc $ [total] '0.005 <4.37 EXP(0.&473(InH)+0.76l4) EXP(O.8473(ln".8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC50 = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 162.19 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Erie ......... ...... ... ... .......................... PROJECT NAME: WATER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 05W ADDITIONAL PARAMETERS Date Oct. 5, 1995 Oct. 5,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 05W 05W CCC CMC TABLE3 Cu [units (M (lb/day)- T Alkalinity (mg/L CaCO3) 75 n/a minimum of 20 1 Chloride (mg/1) 33 0 250 2 Cyanide, firee (pg1l) .. ........ 5 22 ............ . . . . . . . . . ... ....... ..... ...... ................ ........... -xxxx Grease & Oil Grab (mg/1) ......... X..... *. 2 2 Ammonia-Nitrogen 0.08 0.0 (NH3-N) x (log- I [pKT-pH]+I) Nitrite-Nitrogen (mgA) 0.01 0.00 N02 + N03=10 2 Nitrate-Nitrogen (mg1l) 0.88 0 (as nitrogen) CBOD, 5 n/a Chemical Oxygen Demand 20 n/a Fecal Colifinim (#/IOOmL) 1,410 n/a BAC I (X) 3 Phosphorus, total 0.17 0 (P) (X) Total Suspended Solids 142 0 Hardness (mg/L CaCO,) 200 n/a max. monthly mean of 150 pH (au.) **[field] 7.8 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 15.4 n/a I Conductivity (mv/cm) ** [field] 499 n/a Dissolved Oxygen (mg/L 02) ** [field] 10.0 n1a minimum of 5.0 NOTES: n1a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 162.19 cfi; **[field] - average of the 3 grab samples measured in the field (P)-Concentrations sh uld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. M - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie .............. . .................... analyte eliminated from sampling prograin PROJECT NAME: WATER QUALITY MOA7TORING STUD Y FOR THE L4KE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 06W PESTICIDES/PCBS Date Nov. 7,1995 Nov. 7, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CMC TABLE3 P.its (pg/L) (lb/day)* (pg/L) 64L) (pg/L) : @....... .......................... ............. ...... .......................... n1a :;XXXXXXXXX........... alpha-BHC .. ........ ....... .................... n/a beta-BHC n/a n/a X We n/a .............. delta-BHC . . ............... 0.001 (X) .... .................... ...... .... gamma-BHC (Lindane) ..................... . . . ... .... 0.001 (X) .... .................... .................. Heptachlor ......... . ........................... 0.001 (X) Aldrin .............. . ..... ................... Heptachlor epoxide ....... 0.1 0.8 .... .................... alpha-Endosulfan (1) 0.22 0.056 . ..... ................... .................. . ................................. Dieldrin 0.001 (X) . ............................... .-* 0.001 1.1 4,4'-DDE ...................... .................. ...... .............. . . 0.002 (X) Endrin ....... beta-Endosulf,an (11) 0.056 0.22 ... ......... . ............... .............. 0.001 4,4'-DDD .............. n/a Endosulfan sulfate ....... .. . n/a ........ ..... 4,4'-DDT ......... ....x........ 0.001 1.1 ................ . . . . . .............. ..... X"; (X) alpha-Chlordane ............. QQ . ............. .I........................... ........................ gamma-Chlordane .. ............ ......... X, 0.008 (X) Toxaphene .................. ..........I..... n/a n/a ......... ............. .... ........ Endrin Aldehyde ... ......................... . .......... NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989, 19 Pa. H. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 146.88cfs - limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Were Quality Criteria Designated Water Use Drainage List - Lake Erie E X"..;X -555 analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 06W INORGANICS Date '1995 Nov. 7,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CMC TABLE3 CU rnits (m./I.) (lb/day)- (11gL) T (PgtL) Aluminum [total] 0.76 0 0. 1(96hrLC50) (X) I ..................................................... Antimony (total] 219 1,095 Arsenic [total] 0.002 0.00 190(As3+) 360(As3+) . . ............................ Beryllium [total] ............. ................. 0.01(96hrLCSD) 0.05(96hrLC50) Cadmium $ (total] <0.0001 <0.080 0.01(96hrLcm) (X) Chromium Total S <0.05 <39.1 1 I+EXP(0.8l9-(InH)+l.56l) I6+EXP(0.8I9(lnH)+3.688) ..... ......... Chromium VI (ugA) 16 X . .... Copper $ [total] 0.004 0.00 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-I.464) Iron (total] 1.63 0 0.3 mgA*-(X) I Lead S [total) 0.004 0.00 EYP(I.266(InH)4661) EXP(I.266(InH)-I.4I6) Manganese [total] 0.20 0 1 M&A 2 .. ....................... ...... ............... ...... ............... .................... Mercury [total] ............................ 0.2 Pgfl-(X) ........ ................ ........................... ..... ............. ............. Nickel $ (total) <0.01 <7.92 EXP(0.WnH)+I.I645) EXP(0.g46(InH)4-3.36I2) Selenium (total] ........... ... ... . ................. .......................... 10 PgA (X) ................ ................. Silver S [total] <0.0002 <0 158 0.2 EXP(I.72(InH)-6.52) ........ ....... .............i............. ........... .. ....... ................ Thalliurn [total) .......................... ..........%...... 0.018 0.09 Zinc S [total] 0.008 EXP(0.8473(InH)+0.76I4) EXP(0.8473(InH)f0.86G4) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective Much 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 501/6 of test organisms over a specified time period. H = Hardness loading based on a flow of 146.88 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Efie ........ ....... . . ......................... X analyte eliminated from sampling program . ....... .... PROJECT NAME: WA TER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 06W ADDITIONAL PARAMETERS Date Nov. 7, 1995 Nov. 7, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CIVIC TABLE3 CU [Units (-9/L) (lb/day). Alkalinity (mg/L CaC03) 30 n1a minimum of 20 1 Chloride (mg/l) 38 0 250 2 Cyanide, free (RgfI) i 5 22 ............. . ... ............ ............. ............... ......... ..... .... ................. Grease & Oil Grab (mg/fl ....... 2 2 Ammonia-Nitrogen 0.01 0.00 (NH3-N) x (log-I[pKT-pHI+I) Nitrite-Nitrogen (mgA) 0.01 0.00 N02 + N03=10 2 Nitrate-Nitrogen (mg/1) 0.97 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 35 n/a Fecal Coliform (#/IOOmL) 1,200 n/a BACI (X) 3 Phosphorus, total 0.28 0 (P) (X) Total Suspended Solids 134 0 Hardness (mg1L CaCO,) 106 n/a max. monthly mean of ISO pH (s.u.) -(field] 8.9 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 7.1 n/a I Conductivity (mv/cm) ** [field] 291 n/a Dissolved Oxygen (mg/L 0,) ** (field] 10.65 n/a minimum of 5.0 1 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989.19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/100m] based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 146.88 cfs "[field] - average of the 3 grab samples measured in the field (P)-Concentrations sho Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie analyte eliminated from sampling program ................ ............. .............. . PROJECT NAME: WA TER QUALITY MOA7710RING S TUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 06W PESTICIDES/PCBS Date Nov. 7,1995 Nov. 7,1995 DEP CBPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CMC TABLE3 Pnits (pg/L) (lb/day)* (pg/L) (Pg'L) (pg/L) alpha-BHC n/a n/a .......... beta-BHC n/a n/a ................. . . . . . . ........ n1a n/a delta-BHC 0.001 (X) gamma-BHC (Lindane) ...... ........ .............. .............. ............... ............. .. ......... ......... . Heptachlor 0.001 (X) .................. .............. . . ........ ... .............. 0.001 (X) Aldrin Heptachlor epoxide 0.1 0.9 alpha-Endosulfm (1) 0.056 0.22 ............. .......... .... ........... ............... a001 (X) Dieldrin .................. 4,4'-DDE 0.001 1.1 0.002 (X) Endrin ............ ............ ............ ............ . ............ ... .......... beta-Endosulfan (11) 0.056 0.22 ............... .............. ...... . ........... ... .. . .......... . . .... 0.001 1.1 4,4'-DDD X n/a n/a Endosulfan sulfate .............. ............. .............. .. ......... ..... ............X 0.001 4,4'.DDT .. ......... .... ............................ PC) alpha-Chlordane . . . ... . .... .............. (X) gamma-Chlordane ..... . . ......... .... .......... Toxaphene 0.008 (X) ........... Endrin Aldehyde ...... n1a n/a ..... .....-. ....... NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards 19 Pa. 8. 1059 effective March 11, 1989, CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 146.96 cfs - limit for Chlordane - 0.06 lig/L (X) (X) - Chapter 93 Wat Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOA7TORING S TUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CWEK EVENT: 06W INORGANICS Date Nov. 7, 1995 Nov. 7, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CIVIC TABLE3 CU [Units (mg/l) (lb/day) (11gL) (pg/L) I Aluminum [total] 1.51 0 0. 1(96hrLC") (X) 1 Antimony [total] .............. ............ 219 1,095 Arsenic [total] 0.002 0.00 190(As3+) 360(As3+) Beryllium [total) hrLC5.) 0.05(96hrLcso) 0.01(96 Cadmium S [total) 1 <0.0973 0.01(96hrLC,) (X) Chromium Total S <0.05 <39.6 1 I+EXP(0.8I9-(lnH)+I.56I) l6+EXP(0.8I9(InH)+3.688) ......... . . . . ........................ .............. .. X. Chromium VI (ug/1) 16 Copper S [total] 0. 004 0.00 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-I.464) Iron [total] 2.54 0 0.3 mSA-*(X) I Lead S [total] 0.005 0.00 EXP(I.266(InH)-4.66I) EXP(I.266(InH)-l.4l6) Manganese (total] 0 1 mg/I 2 . ................. -a" [total] 0.2 pgA***(X) Nickel $ [total] <0.01 <7.93 EXP(O. 846(InH)+ 1. 1645) EXP(0.846(InH)+3.36I2) Selenium [total] ............ 10 PgA (X) Silver S [total] <0.0002 <0. 159 0.2 EYP(I.72(InH)-6.52) Thallium (total] ................ .............. . 0.019 0.09 ......... . . . . . . . ........... .. ....... ............. ........ ........... ........ Zinc S [total) 0.022 0.0 EXP(0.8473(InH)+0.76I4) EXP(0.8473(1nH)+0.9604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1939, 19 Pa. B. 1059 DEP CUPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March I 1, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) @ able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU Critical Use: 1) Aquatic Life; 2) Water Supply rr LC5@ The concentration of pollutant in test waters that is lethal to 508/a of test organisms over a specified time period. H = Hardness loading based on a flow of 146.96 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MONITORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 06W ADDITIONAL PARAMETERS Date Nov. 7, 1995 Nov. 7,1995 DEP CEPT 16 WQC DEP CHPT-93 WQS CIVIC [Units (mg/L) (lb/day)- Event 06W 06W CCC TABLE3 Alkalinity (mg/L CaCO,) 75 n/a minimum of 20 Chloride (mg/1) 62 0 250 2 Cyanide, free (pg/l) ....................... ... ... ...... . ..... ...... 5 22 .................... Grease & Oil Grab (mg/1) 2 2 ....................... Ammonia-Nitrogen 0.05 0 (NH3-N) x (log-l[pKT-pH]+l) Nitrite-Nitrogen (mg/l) 0.04 0 N02 + N03= 10 2 Nitrate-Nitrogen (mg1l) 0.95 0 (as nitrogen) CBOD, 3 n/a Chemical Oxygen Demand 20 n/a Fecal Coliform (#/IOOmL) 330 n1a BACI (X) 3 Phosphorus, total 0.31 0 (P) (X) Total Suspended Solids 212 0 Hardness (mg/L CaCO,) 176 111a max. monthly mean of 150 pH (s.u.) **[field] 7.73 n1a 6.5 - 9.0 (X) I Temperature (*C) ** [field) 5.0 n1a I Conductivity (mv/cm) ** [field] 516 n/a Dissolved Oxygen (mg/L 02) ** [field] 11.4 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC - Pennsylvania Deparunent of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHIPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 2001100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 146.96 cfs -[field] - average of the 3 grab samples measured in the field (P)-Concentrationssh ld be limited to the extent necessary to prevent nuisance growths of algae, weeds@ and slimes that are or may become injurious to any beneficial water use. (X) . Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie analyte eliminated from sampling program 7777.. PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATIOM ELK CREEK EVENT: 06W PESTICUDES/PCBs Date Nov. 7, 1995 Nov. 7, 199 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CIVIC TABLE3 Pnits (Ag/L) (lb/day)- (pg/L) (pg/L) (Pg/L) lalpha-BHC .......... n/a n/a . .. . ...... .. . . ... .. ........ ... ................ ........................... beta-BHC n/a n/a delta-BHC n/a ft/a gamma-BHC (Lindane) 0.001 (X) .......................... Heptachlor 0.001 (X) ........................ ............. ............. .. .. .. Aldrin 0.001 (X) .......... .......... . .. Heptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldfin ............................ 0.001 (X) .. .............. ............. 4,4'-DDE 0.001 1.1 Endfin 0.002 (X) beta-Endosulfan (11) 0.056 0.22 ,4'-DDD 0.001 1.1 Endosulfan sulfate n/a ntis 4,4'-DDT 0.001 alpha-Chlordane (X) gamma-Chlordme (X) Toxaphene ................ 0.008 (X) Endrin Aldehyde n1a ................ n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Departm ent of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1999,19 Pa. R. 1059 DEP CBPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 222.02 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie ............. ............ PROJECT NAME: W4 TER QUALITY MOATTORING S TUD Y FOR 7HE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 06W INORGANICS Date Nov. 7,1995 Nov. 7, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CIVIC TABLE3 FU_ [units (mg/L) (lb/day). (pg/L) (pg/L) Aluminum [total] 0.21 0 0. 1(96hrLc") (X) Antimony [total] 219 1,095 Arsenic [total] 0.002 0.00 190(As3+) 360(As3+) ... .............. .......................... ... ......... 0.0l(96hrLC30) Beryllium [total) 0.05(96hrLC,,) .... ............. ..............*........ Cadmium S [total] <0.0001 <0.120 0.01(96hrLc.) (X) Chromium Total S <0.05 <59.9 1 I+EXP(0.8I9-(InH)+l.56l) I6+EXP(0.8l9(InH)+3.688) -X-X-X-X-X-%X ...... . . . . ................................. ........................... .......................... .............. .. Chromium VI (ug1l) 16 ................ Copper S [total] <0.001 <1.20 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-l.464) Iron [total) 0.23 0 0.3 mg/l-*()Q I Lead $ [total) <0,001 <1.20 EXP(l.266(InH)-4.66I) EXP(I .266(]nH)- 1.416) Manganese [total] 0.05 0.0 1 mg/I 2 ........... ........ . .xxxxxxxx . ....... 0.2 pgA***(X) Mercury [total] ................ Nickel S [total] <0.01 <12.0 EXP(0.&46(InH)+I. 1645) EXP(0.g46(InH)+3.36l2) ..... .. ... .... Selenium [total] ..... .... ..........%....... 10 Pg/I (X) ........... *-.'.',.,,,.--.,--.%*, ........................ ............ . Silver S [total] <0.0002 <0.240 0.2 EXP(I_72(InH)-6.52) ..................... .. Thallium [total] 0.019 0.09 X.. .......................... .......................... Zinc S [total) <0.005 <5.99 EXP(0.8473(InH)+0.76l4) EXP(0.&473(InH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpit 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5o = The concentration of pollutant in test waters that is lethal to 509/6 of test organisms over a specified time period. H = Hardness loading based on a flow of 222.02 cfis -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Wine Quality Criteria Designated Water Use Drainage List - Lake Erie . ................... ........ .................... .analyte eliminated from sampling program .............. . PROJECT NAME: WATER QUALITY MOA7TOR17VG STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 06W ADDITIONAL PARAMETERS Date Nov. 7,1995 Nov. 7,1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 06W 06W CCC CIVIC TABLE3 Pnits (mg/L) (lb/day)* Alkalinity (mg/L CaC03) 55 n/a minimum of 20 Chloride (ing/1) 41 0 250 2 ............ Cyanide, free (pgA) 5 22 ....................... ... ....... X......................... .......... 2 2 Grease & Oil Grab (mgA) ....................... .... . Ammonia.Nitrogen 0.02 0 (NH3-N) x (log-I [pKT-pH]+]) Nitrite-Nitrogen (mgA) <0.01 <12.0 N02 + N03=1 0 2 Nitratc-Nitrogen (mgA) 1.22 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 15 n/a Fecal Coliform (#/IOOmL) 300 n/a BACI (X) 3 Phosphorus, total 0.10 0 (P) (X) Total Suspended Solids 24 0 Hardness (mg/L CaCO,) 156 n/a max. monthly mean of ISO PH (s.u.) -[field] 7.5 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 4.9 n1a I Conductivity (mv/cm) ** [field] 413 n/a Dissolved Oxygen (mg/L 02) ** [field] 11.3 n/a minimum of 5.0 1 1 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1939, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1939, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) C - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 222.02 cfis **[field) -average of e 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may heroine injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric 77-7 analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 07W PESTICIDES/PCBs Date Nov. 11, 1995 Nov. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CIVIC TABLE3 [units (pg/L) (lb/day)* (pg/L) Og/L) (pg/L) alpha-BHC n/a n1a beta-BHC n1a n/a delta-BHC n/a n/a gamma-BHC (Lindane) 0.001 (X) Heptachlor 0.001 (X) Aldrin 0.001 (X) keptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0,001 (X) 4,4*.DDE 0.001 1.1 Endrin 0.002 (X) beta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n/8 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) garnma-Chlordane (X) Toxaphene 0.008 (X) .. .. ....... .... ...... nta n/a Endrin Aldehyde . . ...... .... OTES: DEP CBPT 16 WOC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 830.28 cfs . limit or Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie .. ........ .... analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 07W INORGANICS Date Nov. 11, 1995 Nov. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CNIC TABLE3 CU [Units (mgtL) (lb/day)* (118,L) (pg1L) Aluminum [total] 8.59 0 0. 1(96hrLC50) (X) I ......................... .......................... ........................... Antimony [total] 'N .......... ................ .......... 219 1,095 ........................... .... Arsenic [total] 0.004 0.0 190(As3+) 360(As3+) .............. ............ ... ::%...........@............-.-.......-.- 0.01(96hrLC,) 0.05(96hrLC,) . .. .......... .. ........ ....... .. .... ................... Beryllium (total) .......... ........... ... ........ Cadmium S [total] 0.0004 0.00 0.0l(96hrLC")(X) Chromium Total S <0.05 <224 1 I+EXP(0.8l9-(InH)+l.56I) l6+EXP(0.8l9(lnH)+3.688) .......................... Chromium VI (ug(l) .......... ... ...... Mi., 11 16 Copper $ [total] 0.015 0.0 EXP(.8545(InH)-I.465) EXP(0.9422(InH)-l.464) Iron [total] 6.92 0 0.3 mgtl-*(X) I Lead $ [total] 0.015 0.0 EXP(l.266(lnH)-4.66I) EXP(I.266(lnH)-l.4l6) Manganese (total] 0.65 0 1 M84 2 .......... ...... ... .................. ercury [total] 0.2 pg/]***(X) Nickel $ [total] 0.01 0.0 EXP(0.9460nH)+l.I645) EXP(O.846(InH)4-3.3612) ...... ........................... .. .......... Selenium [total] 10 pgA (X) ........... .. ... ........... X. Silver $ [total] <0.0 002 <@.8;6 0.2 EXP(I.72(InH)-6.52) Thalliurn [total] ....... ............... ..... 0.019 0.09 ..... ....................... Zinc S [total] 0.050 0 ENP(0.8473(InH)+0.76I4) EXP(O.8473(InH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective Much 11, 1989,19 Pa. B. 1059 DEP CUPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-tem protection) CIVIC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 500/a of test organisms over a specified time Period. H = Hardness loading based on a flow of 830.28 cfs -This value or natural levels, whichever is greater m an un , ter water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WA TER QUALITY MOAVTORING STUD Y FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 07W ADDITIONAL PARAMETERS Date Nov. 11, 1995 Nov. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CMC TABLE3 CU nits (mg/L) (lb/day)* Alkalinity (mg/L CaCO,) 14 n/a minimum of 20 1 Chloride (mg/1) 21 0 250 2 Cyanide, free (pgn) 5 22 2 2 Grease & Oil Grab (mgtl) Em Arnmonia-Nitrogm 0.08 0 (NH3-N) x (log-] [pKT-pH]+I) Nitrite-Nitrogen (mg/l) 0.07 0 N02 + N03=10 2 Nitrate-Nitrogen (mg/l) 1.16 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 60 n/a Fecal Coliform (#/IOOmL) 10,400 n/a BACI (X) 3 Phosphorus, total 0.94 0 (P) (X) Total Suspended Solids 828 0 Hardness (mg/L CaC03) 72 n/a max. monthly mean of 150 pH (s.u.) **[field] 9.1 n/a 6.5 - 9.0 (X) I Temperature (*C) *0 [field) 7.5 n/a I Conductivity (mvlcm) ** [field] 182 n/a Dissolved Oxygen (mgtL 02) ** [field) 12.45 n/a min unum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CH" 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for tong-term protection) CIVIC - criterion maximum concentration (for short-term protection) able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 830.28 efis ield] - average o the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WA TER Q UALI TY MONITORING S YUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 07W PESTICI]DES/PCBs Date Nov. 11, 1995 Nov. 11, 1995 DEP CBPT 16 WQC DEP CHPT 93 WQS Event 07W 07W). (CCC CMC TABLE3 P.its 61gL) (lb/day Ag/L) (PgtL) (pg/L) ........ .......... alpha-BHC ........... . ..... ........ n1a n/a ... .. ..................... beta-BHC ... .. ....... n1a n/a .................. .. ......... ................... ............. ............. ....... ............ . ....... .... delta-BHC ........... ....... . n/a n/a .......... gamma-BHC (Lindane) ............. 0.001 (X) .......... ............... .......... ............... . . ... . .......... . . . . . . ................... ... ............... . . . . . . 0.001 (X) Heptachlor .. .......................... ............. ....... ..................... ............. ....... ............. ...... Aldrin 0.001 (X) ... ....... ::::::::::X: ...... ............. ............. ........... 0.1 0.8 Heptachlor epoxide .. .......... 0.22 ............ 0.056 alpha-Endosulfan (1) . .... . .......... ..... ............... ....... .............. Dieldrin 0.001 (X) .......... ...... ..... ...... .............. 4,4'-DDE ....... ............................. 0.001 1.1 ....... ....................... . ............ .......................... ..... .... .......................... Endrin 0.002 (X) .. .. ...... ... ........ ..... bcta-Endosulfan (11) .......... 0.056 0.22 ........... .. ......... -......... .......... 4,4'-DDD %-.-.-.-.-.-.-.% ................. ;-X; 1.1 .. ............ 0.001 n/a 11,18 .. ........... ........ ....... ............ X:X: ...... . . ................ ................ Endosulfut sulfate ........ ...................... . ......... .............. ..... ............ ........... X. 0.001 4,4'-DDT . ....... .......................... M alpha-Chlordane ........ ... .................... .... ...... .......... M ............... .. ................ gamma-Chlordane . ... .. ... ........ ......... ................. ................ ......... . . ............. .. . ............ . 0.008 (X) ........... Toxaphene, ............ :X. ........... . ............. ............. . . . . ........ . . . . ............. Endrin Aldehyde n/a n1a -.5 NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 1,107.59 cfs - limit for Chlordane = 0.06 pg/L (X) X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Efie ............ ............ analyte eliminated from sampling program PROJECT NAME: WA TER Q UALITY MONI TORING S TUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 07W INORGANICS Date Nov. I I ,1995 Nov. 11, 1995 DEP CEPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CMC TABLE3 CU [Units (mg/L) (lb/day 01g/L) (pg/L) Aluminum [total] 13.10 0 0. 1(96hrLCo) (X) I xx Antimony [total] 1,095 219 Arsenic [total] 0.006 0.0 190(As3+) 360(As,3+) .................. ""X ...... ........ .. ............. .V................. . .. ... . . .............. . ..................... ".. Beryllium [total] ...........:............... :.: . @ ..... . . I........ ... ....... 0.01(96hrLC,) 0.05(96hrLC,) .... ............... _.. ................ .... .......... ...... . ................. .. Cadmium S [total) 0.0004 0.00 0.0 1(96hrLC,) (X) Chromium Total S <0.05 <299 1 l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(lr"+3,688) 16 Chromium VI (ugA) ....... ............... Copper $ [total] -@0.016 <95.6 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) fron [total) 10.22 0 0.3 mgA--(X) I Lead $ [total] 0.025 0 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.4l6) Manganese [total] 0.79 0 1 mgtl 2 . ............. .. ... ... ........ ............................ . ... . ... ....... 0.2 pgA ... (X) ercury, [total] ..... . . . ........... Nickel $ [total) 0.02 0 EXP(0 846(inH)+1.1645) EXP(0.846(lnH)+3.36l2) ................ 10 VgA (X) Selenium [total] Silver $ [total] <0.0002 <1. 19 0.2 EXP(l.72(lnH)-6.52) .......... ........................... Thallium [total] .. .......................... 0.018 0.09 .... ......................... ................... .......................... .......... Zinc S [total] 0.089 0 EXP(0.8473(lnH)4-0.76l4) EYP(0.8473(lrtH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1939, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5@ = The concentration of pollutant in test waters that is lethal to 50% of t est organisms over a specified time period. H = Hardness loading based on a flow of 1, 107.59 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie .................... .... . ............ ... amalyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 07W ADDITIONAL PARAMETERS Date Nov. 11, 1995 Nov. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CMC TABLE3 CU rnits (mg/L) (lb/day)* T Alkalinity (mg/L CaC03) 40 n/a minimum of 20 Chloride (mg/1) 37 0 250 2 .. ............ ........... .............. ..... 5 22 Cyanide, free (pg1l) ............... Grease & Oil Grab (mg/l) ............... 2 2 .... .... . ...... ... Ammonia-Nitrogen 0.06 0 (NH3-N) x (log- I [pKT-pH]+]) itrite-Nitrogen (mg/l) 0.09 o N02 + N03=10 2 Nitrate-Nitrogen (mg/1) 1.17 0 (as nitrogen) CBOD, 3 n/a Chemical Oxygen Demand 60 n/a Fecal Coliform (#/IOOmL) 5,200 n1a BACI (X) 3 Phosphorus, total 0.95 0 (P) (X) Total Suspended Solids 892 0 Hardness (mg/L CaCO,) 104 n/a max. monthly mean of 150 PH (s.u.) **[field] 7.19 n1a 6.5 - 9.0 (X) I Temperature (C) ** [field) 7.5 ft/a I Conductivity (mv/cm) ** [field] 310 n/a Dissolved Oxygen (mg/L 02) ** [field] 11.0 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX - geometric mean of 200/1 00ml based on not less than 5 saimples taken over not more than a thirty-day period loading based on a flow of 1, 107.59 clis *[field] - average of the 3 grab samples measured in the field (P)-Concentrations sb Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use, (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: W4 TER QUALITY MONITORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 07W PESTICIDES/PCBs Date Nov.11,1995 Nov. 11, 1995 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CIVIC TABLE3 jUnits (Pglj-) (lb/day)* (pg/L) (pg/L) (VgL) alpha-BHC .......... n/a n/a .. .......... ...... ............. :- beta-BHC Imm n/a n/a .............. delta-BHC .. n/a n/a gamma-BHC (Lindanc) 0.001 (X) Heptachlor 0.001 (X) Aldrin 0.001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) eta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n1a ............. 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) .............. (X) gamma-Chtordane ............. X. Toxaphene 0.008 (X) ............ ... . ...... ... . ........ ....... n/a Endrin Aldehyde :. -N@X .... :-X,X... X. ............ NOTES: P CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. D. 1059 DEP CHPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards 19 Pa. B. 1059 effective March 11, 1989, CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 2,152.29 cfs - limit for Chlordane = 0.06 Vg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie PROJECT NAME: WATER QUALITY MOATTORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 07VV INORGANICS Date Nov. I Nov. 11, 1 5 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 07W 07W CCC CIVIC TABLE3 _T CU junits (mgL) (lb/day) (11gL) (Pg/L) Aluminum [total) 8.20 0 0. 1(96hrLCm) (X) I ....... . . . ...... *'** ....... Antimony [total] ........... ...... 219 1,095 ..................... ..... ........ .... Arsenic [total] 0004 0.0 190(As3+) 360(As3+) .............. .... .... .. .......... ............... ....... .......... 0.01(96hrLC,) 0.05(96hrLc,) Beryllium [total] .................. Cadmium $ (total] 0.0001 0.00 0.0](96hrLC,) (X) Chromium Total $ <0.05 <580 1 I+EXP(0.8I9-(InH)+I.56I) I6+EXP(0.8l9(InH)+3.688) XXXXXX. Chromium VI (ug/l) 16 xxxxxxxx ........... Copper $ [total] 0.010 0 EXP(.8545(InH)-l.465) EXP(0.9422(InH)-I.464) Iron [total] 7.49 0 0.3 mgtl**(X) I Lead $ [total] 0.013 0 EXP(I.266(lnH)-4.66I) EXP(I.266(InH)-I.4l6) Manganese [total] 0.50 0 1 mg/I 2 ...................... ........................ ercury [total] 0.2 pgn***(X) . ......................... .................. Nickel $ [total] 0.02 0 EXP(O.846(]nH)+ 1. 1645) EXP(0.946(InH)+3.36l2) .......... Selenium [total] 10 P8A (X) ....................... ............... . ................... Silver $ [total) <0.0002 <2.32 0.2 EXP(I.72(InH)-6.52) Thallium [total] ....... .. 0.018 0.09 ............. . ... .......................... Zinc S (total] 0.045 0 EXP(0.&473(lnH)+0.76l4) ENP(0.8473(InH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-tem protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5@ = The concentration of pollutant in test wat - analyte eliminated from sampling program H = Hardness loading based on a flow of 2,152.29 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Watc Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: W4 TER QUALITY MOA7TORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 07W ADDITIONAL PARAMETERS Date Nov. 11, 1995 Nov. 11, 1995 DEP CHFT 16 WQC DEP CUPT 93 WQS Event 07W 07W CCC CIVIC TABLE3 Cu [units (mgL) (lb/day)- Alkalinity (mg/L CaCO,) 31 n/a minimum of 20 1 Chloride (mg/l) 24 0 250 2 ... ......... .......................... . ..... ......... ... Cyanide, free (ligA) .. ....... ... .. ................ 5 22 X... ...................... . Grease & Oil Grab (mg/1) ......... . .......... 2 2 . . ............ ... Ammonia-Nitrogen 0.06 0 (NH3-N) x (log-l[pKT-pH]+l) Nitrite-Nitrogen (mg/1) 0.07 0 N02 + N03= 10 2 Nitratt-Nitrogen (mg1l) 1.36 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 50 n/a Fecal Coliform (#/IOOmL) 4,700 n/a BACI (X) 3 Phosphorus, total 0.79 0 (P) (X) Total Suspended Solids 768 0 Hardness (mg/L CaCO,) 102 n/a max. monthly mean of 150 pH (s.u.) **[field] 7.1 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 7.3 n/a I Conductivity (mv/cm) -* [field] 252 n/a Dissolved Oxygen (mg/L 02) ** [field) 10.9 n/a minimum of 5.0 NOTES: n1a - not applicable DEP CHPT 16 WQC = Pennsylvania Department ofEnvironmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU - Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period - - loading based on a flow of 2,152.29 cfs **[field) - average of the 3 grab samples measured in the field (P)-Concentrations should be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Eric ... . ...... *........ ............ ....... analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOAVTORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 08W PESTIC]nDES/PCBs Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 Nnits ("g/L) (lb/day)- (ILS/L) (pg/L) (RgL) alpha-BHC ........... .............. n/a n/a .............. ............................. beta-BHC 11/11 n/a ........... X1.,........... ........ ............ .... ...... ........:...%.............. ... %..................................... .......... .............. ....... delta-BHC ............... ............ n1a n/a .............. ....... . ............ gamma-BHC (Lindane) .......... . ..... .................... 0.001 (X) Heptachlor .......................... . ............ ** ........ ... ........ .............. .. ................... 0.001 (X) ............... Aldrin .. ................ :X, 0.001 (X) .............. Heptachlor epoxide 0.1 0.8 ....... ....... ................. alpha-Endosulfm (1) ................ 0.056 0.22 Dieldrin .... 0.001 (X) ............ . .............. ............. ............. ...... ... .. 4,4'-DDE ....................... . ........... 0.001 .............. . . ...................... .......... :................................ Endrin ..................... . .... .......... ........................... ......... X... ............ ............. 0.002 (X) .......... ................... ... ... ....................... ......... ... .... beta-Endosulfan (H) .................. ....... 0.056 0.22 ........ .. .. ........................... ............ .............. X. ............. 4,4'-DDD ................. 0.001 .......... ........ .... .......... ........... %.,.. ................... ........... ............. Endosulfan sulfate ..................%n/a n/a ........... . ... ........... ............... ................. ........... ...... ............................. . 4,4'-DDT .... @.,. .i. ............ .............. .......... 0.001 . . ........... .............. .......... .. ..... alpha-Chlordane (X) gamma-Chlordane . . . . . . . . . ............... ..... ................. (X) "'X: ::::::I Toxaphene . .......... ......... 0.008 (X) .. ............. X.: .......... ........... .. ............. . .... Endrin Aldehyde X ......... n/a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for shon-tenn protection) n/a - not applicable loading based on a flow of 136.67 cfs limit for Chlordane = 0.06 pg1l, (X) Chapter 93 Wa er Quality Criteria Designated Water Use Drainage List - Lake Erie . .......... analyte eliminated from sampling program .................. PROJECT NAME: WA TER QUALITY MOAVTORING STUD Y FOR 7HE LAKE ERIE WA 7ERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 08W INORGANICS Date April 12,1996 April 12, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 CU junits, (mgL) (lb/day)* OWL) (pg/L) Aluminum [total] 528 0 0. l(96hrLC") (X) I .. .................... ............ . ... ..................... 219 Antimony [total] 1,095 .......... X. .......... ... . . .. .... .. .. ..... ..... Arsenic (total] 0.001, 0.000 190(As3+) 360(As3+) .............. .. . .... ...................... ..... .. .. . ................ . ..... Beryllium [total] X. ......................... 0.01(96hrLc") ........ .. ..................... 0.05(96hrLC .... ........ :: .... ... Cadmium $ [total) <0.0001 <0.0737 0.01(96hrLC50) (X) Chromium Total $ <0.05 <36.9 1 l+FXP(0.8l9-(lnH)+l.56l) l6+EXP(0.8l9(lnH)+3.689) X. ... ::XXXXXXXXXXXX 1 16 Chromium VI (ug/1) X Copper $ [total] 0.004 0.000 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) Iron [total] &95 0 0.3 mgtl**(X) 1 Lead S [total] 0.008 0.00 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.416) Manganese [total] 0.15 0 1 mgn 2 Mercury [total] .................... .. ........ .... 0.2 pgA***(X) ........ ..... . ............. Nickel $ [total) 0.01 0.00 EXP(0.846(hiH)+l. 1645) EXP(0.846(lnH)+3.36l2) ........................ ...................... .................. 10 pgA (X) Selenium [total] .X .......................... .... .............. ............ ".. Silver S [total] <0.0002 <0. 147 0.2 EXP(l.72(lnH)-6.52) Thallium [total] 0.018 0.09 Zinc $ [total] IX EXI'(0.8473(hil".7614) ENP(0.8473(lnH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Clipt 93 Water Quality Standards effective Much 11, 1989,19 Pa. B. 1059 DEP CBPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located an pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC,@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flow of 136.67 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric `,X,X.:,X,X,: analyte eliminated from sampling program . .. ......... ...... PROJECT NAME: W4 TER QUAL17T MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENBLE CREEK EVENT: 08W ADDITIONAL PARAMETERS Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CMC TABLE3 CU JUnits (mgL) (lb/day)* Alkalinity (mg/L CaC03) 44 n/a minimum of 20 1 Chloride (mg/1) 42 0 250 2 ...................... ................. ............................... Cyanide, free (pg/l) 5 22 ....................... Grease & Oil Grab (mg/l) . ..... ............. Xi ................. 2 2 ........ . Ammonia-Nitrogen 0.2 0 (NH3-N) x (log- I [pKT-pH]+]) Nitrite-Nitrogen (mg1l) 0.05 0.0 N02 + N03=1 0 2 Nitrate-Nitrogen (mg/1) 2.05 0 (as nitrogen) CBOD, 3 n/a Chemical Oxygen Demand 20 n/a Fecal Coliform (#/IOOmL) 198 n/a BAC I (X) 3 Phosphorus, total 0.36 0 (P) (X) Total Suspended Solids 180 0 Hardness (mg/L CaCO,) 116 n/a max. monthly mean of 150 pH (s.u.) **[field) 7.8 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 7.7 n/a I Conductivity (mv/cm) * * [field] 331 n/a Dissolved Oxygen (mg/L 0,) ** [field) 12.75 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CUPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quadity Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93. 15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of200/100ml based on not less than 5 samples taken over not more than a thirty-day period loading based on a flow of 136.67 ch; **[field] - average ofthe 3 grab samples measured in the field (P)-Concentrmatiom a 0 Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric ............ .... ............. analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MOA17TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 08W PESTICIDES/PCBs Date April 12, 1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 jUnits (pgL) (lb/day)* (pg/L) (pgL) (pg/L) .. ..... .. . ... alpha-BHC . . ....... XXI", 111a n/a ............... ... ............................. beta-BHC ....... n/a n/a .................. delta-BHC .. .......................... n1a n/a .............. gamma-BHC (Lindane) ........... . ............. ....... 0.001 (X) .......... .. ..... . .. .. ..... ....... ... .. ... .. .... Heptachlor ... 0.001 (X) .................. Aldrin ...... 0.001 (X) .X, ......... ..... ......... 0.1 0.8 Heptachlor epoxide . . . . . . . . .......... alpha-Endosulfan (1) . . ... 0.056 0.22 Dieldrin .................... 0.001 (X) .............. .................. ........ . . . ............. X ............. .. ........... .............. ........ . 4,4'-DDE ... ...... . .. ........ 0.001 Endrin ........... 0.002 (X) ...... ...... eta-Endosulfan (H) ........... .. ........... ... 0.056 0.22 x* ............ ..... ..... 4,4 -DDD, 0.001 Endosulfan sulfate n/a n/a ....... .... . . . ..... .. . .. ......... ............. 4,4'-DDT 0.001 .......... .......... ............. (X) alpha-Chlordane (X) gamma-Chlordane .......... Toxaphene 0.008 (X) . .......... .................... .......... n/a Endrin Aldehyde n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1999,19 Pa. B. 1059 DEP CBPT 93 WQS = Pennsylvania Department of Envirorunental Protection Chapter 93 Water Quality Standards lb effective March 11, 1989 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 121.78 cfs - limit for Chlordane - 0.06 pg/L (X) X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Efie X analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 08W INORGANICS Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 CU Pnits (mg/L) (lb/day)* (lig/L) (pgL) Aluminum [total] 1.67 0 0. ](96hrLC,) (X) I ... . ...... ........................... ................ Antimony [total] ... 219 1,095 . ........ ........ ........ . ............ ....... Arsenic [total] <0.001 <0.657 190(As3+) 360(As3+) ..................... ....... ............ 0,01(96hrLC,) 0.05(96hrLCM) Beryllium [total] ......... .. ..... . Cadmium $ [total] <0.0001 <0.0657 0.01(96hrLCm) (X) Chromium Total S <0.05 -:32.8 1 I+EXP(0.8l9-(InH)+I.56I) 16+EXP(0.8l9(InH)+3.688) Chromium VI (ugA) 1 16 ..................... . Copper S [total) 0.003 0.00 EXP(.8545(InH)-l.465) EXP(O.9422(InH)-l.464) Iron (total] 2.16 0 0.3 mgfl-*(X) I Lead S [total] 0.003 0.00 EXP(I.266(InH)-4.66l) EXP(I.266(lnH)-I.4l6) Manganese [total] 0.07 0.0 1 mg/l 2 ................ ercury [total] 0-2 pgA***(X) X.................. ..... ..... .... .. ................. Nickel S [total] 0.01 0.00 EXP(0,946(ln"1.1645) EXP(0.&46(InH)+3.36I2) .. ..... ....... Selenium [total] ...... . ............ 10 Pg/I (X) ............... ................. Silver S (total) <0.0002 <0. 131 0.2 EXP(I.72(InH)-6.52) 0.018 0.09 Thallium (total] Zinc $ [total] 0032 . .. 0.0 EXP(0.&473(l.H)+0.76l4) EXF(0.8473(InH)+0.86G4) NOTES: DEP CHPT 16 WQC = Pemsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) @ able 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply rr LC,,@ = The concentration of pollutant in test waters that is lethal to 501% of test organisms over a specified time period. H = Hardness loading based on a flow of 121.78 cfs -This value or natural levels, whichever is greater in an unfiltered r ample in an unfiltered (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie eliminated from sampling program PROJECT NAME: WA TER QUALITY M01VITORING STUD Y FOR THE L4AE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 08W ADDITIONAL PARAMETERS Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 08W CCC CIVIC TABLE3 CU Units (mg/L) (lb/day)- Alkalinity (mg(L CaCO,) 97 n/a minimum of 20 1 Chloride (mgfi) 65 0 250 2 ..-Xx Cyanide, free (pg/1) 5 22 ............. ................. . ........... ............ . ........... ............ 2 2 Grease & Oil Grab (mgtl) ............ Ammonia-Nitrogen 0. 12 0.0 (NH3-N) x (log-l(pKT-pH]+l) Nitrit-Ni-gen (mg/1) 0.02 0.0 N02 + N03=10 2 Nitrate-Nitrogen (mg/1) 0.71 0 (as nitrogen) CBOD5 3 n/a Chemical Oxygen Demand 10 n/a Fecal Coliform (#/I 00mL) 143 n/a BACI (X) 3 Phosphorus, total 0.15 0.0 (P) (X) Total Suspended Solids 68 0 Hardness (mg/L CaCO,) 158 n/a max. monthly mean of 150 PH (s.u.) **Ifieldl 8.03 n/a 6.5 - 9.0 (X) I Temperature (*C) *' [field] 8.0 n/a I Conductivity (mv/cm) ** [field] 539 n/a Dissolved Oxygen (mg/L 01) ** [field] 10.6 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1999, 19 Pa. B. 1059 DEP CHPT 93 WQS - Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1999, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 121.78 efs --[field] - average of the 3 grab samples measured in the field )-Concentrations sho Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Like Efie analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOMITORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 08W PESTICIDES/PCBs Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 junits (mg/L) (lb/day)- (Pg/L) (0gL) (pg/L) .............. . . ..... ..... ............. alpha-BHC ............. n/a n/a ... ........ beta-BHC n1a n/a ... .............. .............. .............. . ........... ........ .............. ..... delta-BHC .............. n/a n/a .................... ................... gamma-BHC (Lindane) ....... 0.001 (X) ........... ...................... ......................... Heptachlor 0.001 (X) ....... .... .. ............... . ....................... Aldrin ............... ......................... ...... 0.001 (X) .......... . ......................... ......................... Heptachlor epoxide ... . . ... .. . ......................... 0@1 0.8 alpha-Endosulfan (1) . .......................... : 0.056 0.22 ........... % ---- -- - ............. ... ............ ............. . .................... Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 ................ ............. ..... ............. Endrin ....... 0.002 (X) .. ........ ......... ........... .... ........ . eta-Endosulfan (11) ........... .......... *..,:: 0.056 0.22 . ............. .. ............... 0 4,4'-DDD .001 1.1 .......... ...... :X. Endosulfan sulfate n/a n/a 4,4'-DDT . .... . ................ 0.001 1.1 ... ............ .......... ............. . .......... .............. .. alpha-Chlordane ............. . ........................ (X) ............. ........... .......... gamma-Chlordane 00 X: Toxaphene 0.008 (X) X Endfin Aldehyde . ... . ................... . ................... n/a n/a ............ .. . . . ..... ..... .. NOTES: EP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CUPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 160.06 efs - limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOA7TORING STUDY FOR THE LAKE ERIE RA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 08W INORGANICS Date April 12,1996 April 12,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CMC TABLE3 CU nits (ltg[L) (lb/day)* (ggtL) (VLgL) Aluminum [total] 1.35 0 0.1(%hrLC,)(X) I 1,095 219 ::., ......................... ......................... Antimony [total] Arsenic [total] -CO.001 <0.863 190(As3+) 360(As3+) .......... ... . . ..... ....... Beryllium [total] jxxxx 0.01(96hrLC30) 0.05(96hrLC,) Cadmium S (total] <0.0001 <0.0863 0.01(96hrlC0 (X) Chromium Total S <0.05 <43.2 1 I+ENP(0.8l9'(InH)+l.56I) I6+EXP(0.9I9(1nH)+3.688) khromium VI (ug/1) .......... 16 -X:::::::::X:X pper S [total] <0.001 <0.863 ENP(.8545(InH)-I.465) EXP(O.9422(InH)-l.464) Iron (total] 1.95 0 0.3 mSA--(X) I Lead $ [total] 0.002 0.00 EV(I.266(InH)-4.66l) EXP(I.266(InH)-I.4l6) Manganese [total) 0.05 0.0 1 mg/l 2 Mercury [total] 0-2 . ... . . .... ......... Nickel S (total) 0.01 0.00 EXP(0.946(htH)+I. 1645) EXP(0.846(InH)+3.36I2) ... . ...... 10 pgA (X) Selenium [total] ......... Silver $ (total] <0.0002 <0. 173 0.2 EXP(I.72(InH)-6.52) ................... ..... . ....... g--- X 0.018 0.09 ................... ... ....................... ... X Thalliurn [total] X ... .. Zinc $ [total) 1 <0.005 <4.32 EXP(0.8473(InH)+0.76I4) EXP(0.8473(lnH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards U = Critical Use; 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 501/6 oftest organisms over a specified time period. H = Hardness loading based on a flow of 160.06 efs -This value or natural levels, whichever is greater *** - in an unfiltered water sample X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOAIITORING STUDY FOR THE LA KE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 08W ADDITIONAL PARAMETERS Date April 12,1996 April 12, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 08W 08W CCC CIVIC TABLE3 Cu [Units (mg/L) (lb/day)- Alkalinity (mg/L CaCO3) 70 n/a minimum of 20 1 Chloride (mgfl) 30 0 250 2 ..................... 5 22 ........... Cyanide@ free (pg/1) ...... ............... ..... ..... ..... ..... 2 2 Grease & Oil Grab (mgtl) Ammonia-Nitrogen 0.11 0.0 (NH3-N) x (log-l[pKT-pH]+l) itfite-Nitrogen (mg/1) 0.02 0.0 N02+NO3=10 2 Nitrate-Nitrogen (mg/1) 1.16 0 (as nitrogen) CBOD, 4 n/a Chemical Oxygen Demand <10 n/a Fecal Coliform (#/IOGmL) 9 n/a BAC I (X) 3 Phosphorus, total 0.14 0 (P) (X) Total Suspended Solids 62 0 Hardness (mg/L CaCO3) 132 n/a max. monthly mean of 150 pH (s.u.) --[field] 7.9 n/a 6.5 - 9.0 (X) I Temperature (*C) ** [field] 9.2 n/a I Conductivity (mv/cm) ** [field] 347 n/a Dissolved Oxygen (mg/L 02) ** [field] 10.2 n/a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CUPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1999, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BAC I - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 160.06 ch; **[field) - average of the 3 grab samples measured in the field M-Concerumnationssh Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that arc or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric analyte eliminated from sampling program PROJECT NAME: WA TER Q UALITY MOAVTORING S YVD Y FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 09W PESTICIDES/PCBs Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 [Units (ILSIL) (lb/day)- 01gL) W/L) (Pg/L) alpha-BHC n/a wa . ......... beta-BHC n/a n/a OWN= delta-BHC n/a n/a ..................... ................... ............... gamma-BHC (Lindane) .......... ..I. . ..... 0.001 (X) ............................. Heptachlor ,............. ....... .............. 0.001 (X) ............. Aldrin .... ............ 0.001 (X) Heptachlor epoxide 0.1 0.8 ... . .............. .... . . ... ................ 0.056 0.22 alpha-Endosulfan (1) . : ... ;..: ........... ............. x Dieldrin ..................... 0.001 (X) 4,4'-DDE ...... ..... .... .. ........ ............. ....... ...... 0.001 .............. ........... X . . ..... . . .......... Endrin .......... .. .......... ..... . ..... 0.002 (X) ........... ............ ............. .............. eta-Endosulfan (11) 0.056 0.22 .......... . . . . . . . . .............. . ..... 4,4'-DDD .............. . ....... ..X 0.001 1.1 .............. Endosulfan sulfate ............ n/a n/a ...... ........... ................ 4,4'-DDT .............. 0.001 1.1 . ......... ..... ......... .............. . ................. ........... alpha-Chlordane (X) ............. ........ Chlordane . .................... .... ........... ............. .. (X) . .... .... 0 aphene 0.008 (X) ..... ..... X n/a n/a ndrin Aldehyde [nd % ..... ....... .......... NOTES- DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CIAPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable oa ng ased on a flo@ of 3 87.22 efs limit for Chlordane - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOATTORING STUDY FOR THE LAKE ERIE W4 TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: 09W INORGANICS Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 CU Pnits (mgL) (lb/day)- (PgtL) (pg/L) Aluminum [total] 5.07 0 0. 1(96hrLC") (X) Antimony [total] 219 1,095 ..... ..... Arsenic [total] 0.007 0.0 190(As3+) 360(As3+) ............... . Beryllium [total] 0.0 1 (96hrLCM) 0.05(96hrLC,,) .......... ... ........ Cadmium $ [total] <0.0001 <0.209 0.01(96hrLCm)(X) Chromium Total $ <0 0 <104 1 I+EXP(0.8I9-(InH)+I.56I) I6+EXP(0.8I9(InH)+3.689) . .. . ...... ........... ...... ................... Chromium VI (ug/1) 16 Copper $ [total] 0.002 0.00 EXP(.8545(InH)-I.465) EXP(0.9422(lnH)-I.464) Iron (total] 7.12 0 0.3mg/1"M I Lead S [total] <0.001 <2.09 EXP(I.266(lnH)-4.66I) EXP(I.266QnH)-I.4I6) Manganese [total] 0.13 0 1 mgfl 2 0.2 pgA***(X) Mercury [total] Nickel $ [total] 0.0 5 0 EXP(0.94WnH)+I.I645) EXP(0.846(InH)+3.36I2) . . ....... Selenium [total] ....................... .............. ......... 10 pgA (X) Silver S [total] <0.0002 <0.418 0.2 EXP(I.72(InH)-6.52) ...... 0.018 .... ......... .............. ....... ....... Thallium [total] ..... 0.09 ...... .... Zinc S [total] 0.023 0.0 EXP(G.9473(InH)+0.76I4) EXP(0.8473(InH)+0.86G4) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC,@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flow of 3 87.22 efs -This value or natural levels, whichever is greater *** - in an unfiltered water sample X)-Chapter93Wat Quality Criteria Designated Water Use Drainage List -Lake Eric analyte eliminated from sampling program PROJECT NAME: WA TER QUA LITY MOArITORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 ISAMPLE LOCATION: TWELVEMILE CREEK EVENT: 09W ADDITIONAL PARAMETERS Date April 30,1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 CU Units (nng/L) (lb/day)' Ikalinity (mg/L CaCO,) 33 n/a minimum of 20 1 hloride (mg/1) 24 0 250 2 yanide, firee (pg/l) 3 22 case & Oil Grab (mg/1) im sm 2 2 monia-Nitrogen 0.04 0 (NH3-N) x (log-l[pKT-pHJ+l) itrite-Nitrogen (mg/l) 0.01 0 N02+NO3=10 2 Nitrate-Nitrogen (mg/l) 1.02 0 (as nitrogen) CBOD' 2 n/a Chemical Oxygen Demand 25 n1a Fecal Coliform (#/IOOmL) 504 n/a BACI (X) 3 Phosphorus, total 0.32 0 (P) (X) Total Suspended Solids 180 0 Hardness (mg/L CaCO,) 70 m/a max. monthly mean of 150 pH (s.u.) --[field] 9.1 n/a 6.5 - 9.0 (X) I Temperature (*C) -- [field] 9.7 n1a I Conductivity (mv/cm) -- [field] 210 n/a Dissolved Oxygen (mg/L 02) ** [field) 10.80 n/a minimum of 5.0 1 NOTES: n/a - not applicable DEP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department ofEnvironmental Protection Chapter 93 Water Quality Standards effective March 11, 1999,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU - Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BAC I - MAX = geometric mean of 200/1 00ml based on not less than 5 samples taken over not mom than a thirty-day period * - loading based on a flow of 387.22 cfs **[field] - average of the 3 grab samples measured in the field ')-Concentrations sho ld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. -Chapter 93 Water Quality Criteria Desirated Water Use Drainage List - Lake Erie @:; @ @ - malyte eliminated from sampling program X: ............... PROJECT NAME: WATER QU4LI7`YM0A7T0R1NG STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 09W PESTICIDES/PCBs Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CNPT 93 WQS Event 09W 09W CCC CMC TABLE3 [Units (pg/L) (lb/day)* (Pg/L) (PgtL) (pg/L) ...................... alpha-BHC o/a n/a ......................... beta-BHC n/a n1a ................. n/a n/a delta-BHC ............. ....................... .......................... gamma.BHC (Lindane) ................ 0.001 (X) ............... . .. ................ Heptachlor 0.001 (X) ......... Aldrin ..................... 0.001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) @ eta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n/a 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) gamma-Chlordane (X) Toxaphene 0.008 (X) ............ Endrin Aldehyde n1a n/a NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective Much 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 875.19 cfs - limit for Chlordwe - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ......... .. ............ ............ analyte eliminated from sampling program ... .......... ... jb PROJECT NAME: WATER QUAL17TM0ATT0R1NGS7VDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 09W INORGANICS Date April 30,1996 April 30,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 CU [Units (mgL) (lb/day)* (ligL) (Pg/L) Aluminum [total] 17.48 0 0. 1(96hrLC,) (X) Antimony [total) 219 1,095 Arsenic [total] 0.003 0.0 190(As3+) 360(As3+) ............. ............................. 0.05(96hrLC,) ........... .......... 0.01(96hrLC50) Beryllium [total] ..... Cadmium S [total] <0.0001 472 0.01(96hrLC,) (X) hromiurn Total S <0.05 <236 1 l+EXP(0.8l9-(lnH)+l.56l) l6+EXP(0.9l9(lnH)+3.688) .......... 16 ............. .. . . . . . .... ......................... hmmium VI (ug/1) ....................... upper $ [total) 0.001 0.00 EXP(.8545(lnH)-l.465) EXP(0.9422(lnH)-l.464) Inon [total] 25.87 0 0.3 mgA--(X) I d S [total] 0.002 0.00 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.4l6) ganese [total] 0.45 0 1 mgtl 2 0.2 pg/]*..(X) ffcury [total] ......................... Nickel S [total] 0.07 0 EXP(O. 846(InH)+ 1. 1645) EXP(0.846(lnH)+3.36l2) ................ ...... ....... . ............................ ...... Selenium [total] 10 Pg1l (X) . ... ..... Silver$ [total] <0.0002 <944 0.2 EXP(l.72(lnH)-6.52) Thallium, [total] 0.018 0.09 ... ................ .................... Zinc $ [total] 0.084 0 EXP(0.8473(lnH)+0.76l4) EXP(0.8473(inH)+0.8604) NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flow of 875.19 cfs -This value or natural levels, whichever is greater *** - in an unfiltered water sample X) - Chapter 93 Wate Quality Criteria Designated Water Use Drainage List - Lake Eric analyte eliminated from sampling program @ X-:iX`; b" "PI mn en ROJECT NAME: WA TER QUAUTY MONITORING STUDY FOR THE L4KE ERIE WATERSHED OB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: 09W ADDITIONAL PARAMETERS Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CIVIC TABLE3 CU @hiits, I (mgL) (ib/day)- Alkalinity (mg/L CaCO3) 62 n/a minimum of 20 1 Chloride (mg/1) 43 0 250 2 Cyanide, free (pg/1) 5 22 ............ ............ ....... ............. ........... *1X'-'1.'..'-X . ............ ........... Grease & Oil Grab (mg/1) 2 2 ..................... . ............... Ammonia-Nitrogen 0.12 0 (NH3-N) x (log- I [pKT-pH]+l) Nitrite-Nitrogen (.g1l) 0.02 o N02 + N03=10 2 Nitrate-Nitrogen (mg/1) 0.47 0 (as nitrogen) CBOD, 2 n/a Chemical Oxygen Demand 40 n/a Fecal Coliform (#/IOOmL) 792 n1a BAC I (X) 3 Phosphorus, total 0.78 0 (P) M Total Suspended Solids 784 0 Hardness (mg/L CaC03) 100 n/a max. monthly mean of ISO PH (s.u.) -[field] 7.53 n/a 6.5 - 9.0 (X) I Temperature (*C) -- [field) 9.4 n/a I Conductivity (mv/cm) - - [field] 338 n/a Dissolved Oxygen (mg/L 02) ** J,fieldj 9.1 n/a minimum of 5.0 NOTES: m1a - not applicable DEP CUPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term pratection) CIVIC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of 2001100ml based on not less than 5 samples taken over not more than a thiny-day period * - loading based on a flow of 875.19 cfs **[field) - average of the 3 grab samples measured in the field M-Concentrations sho ld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any berieficiall water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie analyte eliminated from sampling program P PROJECT NAME: WATER QUALITY MOATTORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 09W PESTICIDES/PCBs Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 Units (Ag/L) (lb/day)* (n(L) (ggL) (pg(L) alpha-BHC fda R/a beta-BHC n/a n/a delta-BHC n/a n/a gamma-BHC (Lindane) 0.001 (X) Heptachlor 0.001 (X) Aldrin 0.001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) beta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n1a n/a 4,4'.DDT 0.001 1.1 alpha-Chlordane (X) garnma-Chlordane (X) Toxaphene 0.008 (X) Endrin Aldehyde ........ . n/a n/a . ........... .... ..... . NOTES: EP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n1a - not applicable loading based on a flow of 1,910.87 cf; - limit for Chlordane = 0.06 Vg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric PROJECT NAME: WATER QUALITY MONITORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 09W INORGANICS Date April 30, 1996 April 30, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CMC TABLE3 CU nits (mgL) (lb/day)- (Rg(L) (pg/L) Aluminum [total] 17.95 0 0. 1(96hrLCso) (X) .............. .......... .................. Antimony [total] .0 .......... 219 1,095 Arsenic [total] .0.002 0.0 190(A93+) 360(As3+) ......... ... ........ Beryllium [total] . .. ......... ... ..... . .. ........ 0.01(96hrLC,) 0.05(96hrLC,) -.:-:-X.X-:-X X.: ........................ Cadmium S [total) Z0001 <1.03 0.01(96hrLC50) (X) Chromium Total $ <0.05 <515 1 l+EXP(0.8l9-(lnH)4-l.56l) l6+EXP(0.8l9(lnH)+3.688) khromium V1 (ug1l) ................. 16 ........... pper S [total) 0.003 0.0 EXP(.8545(lnH)-l.465) EXP(0.9422(laH)-l.464) Imn [total] 35.64 0 0.3 mgn**(X) I Lead S [total] 0.001 0.0 EXP(l.266(lnH)-4.66l) EXP(l.266(lnH)-l.4l6) Manganese [total] 0.42 0 1 mg/l 2 Mercury [total] 0.2 ILg/]***(X) ickel S [total] 0.09 0 EXr(0.846(lnH)+l. 1645) EXP(0.&46(lnH)+3,36l2) .... ........ Selenium [total) ............... . ..... .... ....................... . ................ 10 pgA (X) .......... Silver S [total] <0.0002 <2.06 0.2 EXP(l.72(lnH)-6.52) hallium [total] ........ ......... .. .. ...... . .. ... X: 0.018 0-09 -X-X-X-X-X-:- ..... . ...... Zinc S [total) 0.079 0 E)T(0.&473(lnH)+0.76l4) ENP(O.9473(int".9604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 ID EP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5o = The concentration of pollutant in test waters that is lethal to 506/6 of test organisms over a specified time period. H = Hardness loading based on a flow of 1,910.87 cfs -This value or natural levels, whichever is greater **1 - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: W4 TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: 09W ADDITIONAL PARAMETERS Date April 30, 1996 April 30,1996 DEP CHFT 16 WQC DEP CHPT 93 WQS Event 09W 09W CCC CIVIC TABLE3 CU [Units (-g/L) (lb/day)* Alkalinity (mg/L CaCO,) 40 n/a minimum of 20 1 Chloride (mg/1) 15 0 250 2 ............... .......... ........... .............. :: - - - Cyanide, free (pg/1) ........ 5 22 .......................... ....... Grease & Oil Grab (mgA) .......................... 2 2 .......................... Ammonia-Nitrogen 0.16 0 (NH3-N) x (log-I [pKT-pH]+I) Nitrite-Nitrogen (mg1l) 0.03 0 N02+N03=10 2 Nitrate-Nitrogen (mg/1) 0.54 0 (as nitrogen) CBOD3 2 n/a Chemical Oxygen Demand 30 n1a Fecal Coliform (#/IoomL) 1,116 n/a BAC I (X) 3 Phosphorus, total 0.95 0 (P) (X) Total Suspended Solids 836 0 Hardness (mg/L CaCO,) 80 n/a max. monthly mean of 150 pH (s.u.) **[field) 7.4 n/a 6.5 - 9.0 (X) I Temperature (*C) - [field] 9.6 n/a I Conductivity (mv/cm) - (field] 194 ft/a Dissolved Oxygen (mg/L 02) ** (field] 8.9 n1a minimum of 5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March If, 1999, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1999,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-tem protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 1,910.87 cfs **[field] - average of the 3 grab samples measured in the field (p)-Concentrations sho Id be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program PROJECT NAME: WATER QU4LI7TM0A7T0R17VG STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVENULE CREEK EVENT: low PESTICIDES/PCBs Date May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CMC TABLE3 @ nits (ligL) (lb/day)* (PgtL) (pa(L) (pg/L) lpha-BHC n/a n/a eta-BHC n/a n/a elta-BHC n/a n/a amma-BHC (Lindane) 0.001 (X) eptachlor 0.001 (X) Aldrin 0.001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfm (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 drin 0.002 (X) beta-Endosulfan (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n1a 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) gamma-Chlordane (X) Toxaphene 0.008 (X) Endrin Aldehyde n/a n1a NOTES: EP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effccti@c Much 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 202.07 cfs - limit for Chlordane = 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Eric analyte eliminated from sampling program Iu @[En PROJECT NAME: WA TER QUALITY MOATTORING STUD Y FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: low INORGANICS Date May 9,1996 May9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CMC TABLE3 Cu jUnits (mgL) (lb/day). (Pg'L) (PgtL) Aluminum [total) 1.09 0 0. 1(96hrLC,) (X) Antimony [total] 1,095 219 Arsenic [total] 0.001 0.00 190(As3+) 360(As3+) Beryllium [total] . ..... xx ........ ........ 0.01(96hrLC,) 0.05(96hrLCm) .... ........ Cadmium $ [total) 0. 0001 0.000 0.0I(96hrLC")(X) Chromium Total $ <0.05 <54.5 1 I+EXP(0.819-(InH)+1.56I) I6+EXP(0.8I9(lnH)+3.689) .................... . . ....... Chromium VI (ug/1) 16 . ......... .............. ..X Copper $ [total) <0.001 <1.09 EXT(.8545(InH)-I.465) EXP(0.9422(InH)-I.464) Iron [total] 1.29 0 0.3 mgA--(X) I Lead S [total] 0.002 0.00 EXT(I.266(1nH)-4.66I) EXP(I.266(1nH)_j.416) Manganese [total] ... 0.05 0.0 1 ing/I 2 Mercury [total] 'X .............. X ...... . ................. 0.2 Pg/I ... W ... ....... S. ............. Nickel S [total] <0.01 <10.9 EXP(O 846([nH)+- 1. 1645) EXP(0.846(1nH)+3.36I2) Selenium [total] ...... ......... ......... 10 pgA (X) ...... .............. Silver S (total) <0.0002 <0.218 0.2 EXP(I.72(1nH)-6.52) Thallium [total] 0.018 0.09 Zinc S [total] 0.006 0.00 EXP(0.8473(InH)+0.76I4) EXP(0.8473(InH)+0.8604) NOTES: DEP CHPT 16 WQC = Pennsylvania Department ofEnvironmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use@ 1) Aquatic Life; 2) Water Supply LC,@ = The concentration of pollutant in test waters that is lethal to 50% of test organisms over a specified time period. H = Hardness loading based on a flow of 202.07 cfis -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Efie analyte eliminated from.sampling program .......... PROJECT NAME: W4 TER QUALITY MOArITORING STUDY FOR IHE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: TWELVEMILE CREEK EVENT: low ADDITIONAL PARAMETERS Date May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CIVIC TABLE3 CU Units (ingL) (lb/day)* Alkalinity (mg/L CaCO3) 43 n/a minimum of 20 1 Chloride (mg1l) 31 0 250 2 Cyanide, free (pg/i) 5 22 Grease & Oil Grab (mgA) 2 2 Ammonia-Nitrogen 0.42 0 (NH3-N) x (log-l[pKT-pH)+l) Nitrite-Nitrogen (mg/1) 0.02 0.0 N02 + N03-10 2 Nitrate-Ni"gen (mg/l) 2.98 0 (as nitrogen) CBOD, 2 n/a. Chemical Oxygen Demand 20 n/a Fecal Coliform (#/I OOmL) 700 n/a BACI (X) I Phosphorus, total 0.01 0.0 (P) (X) Total Suspended Solids 50 0 Hardness (mg/L C8C03) 90 m/a max. monthly mean of 150 pH (s.u.) **[field] 9.8 n/a 65 - 9.0 (X) I Temperature (*C) ** [field) 14.7 n/a I Conductivity (mv/cm) -- [field] 266 n/a Dissolved Oxygen (mg1L 02) ** [field] 7.56 n/a minimumof5.0 NOTES: n/a - not applicable DEP CHPT 16 WQC - Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation colonies BACI - MAX = geometric mean of 200/100ml based on not less than 5 samples taken ova not more than a thirty-day period loading based an a flow of 20107 cfs ie - average o the 3 grab samples measured in the field (P)-Concentrationssh ld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Like Efie PROJECT NAME: WA TER QUALITY MOA7TORING STUD Y FOR THE LAKE ERIE WA TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: low PESTICI]DES/PCBs Date May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CMC TABLE3 junks (pg/L) (lb/day)- (pg/L) (gg/L) (AstL) alpha-BHC n1a n/a beta-BHC n/a n/a delta-BHC n/a n/a gamma-BHC (Lindane) 0.001 (X) Heptachlor 0.001 (X) Aldrin 0,001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfan (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) beta-Endosulfan (H) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n1a 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) gamma-Chlordane (X) Toxaphene 0.008 (X) Endrin Aldehyde ........... . ....... ... . ............... .......... n/a 1118 NOTES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effcctive March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 1], 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n/a - not applicable loading based on a flow of 1,745.92 cfs - limit for Chl.rdane - 0.06 pg/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie . . .... analyte eliminated from sampling program PROJECT NAME: WATER QUALITY MOAVTORING STUDY FOR TUE LAKE ERIE W4 TERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: low INORGANICS Date May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CIVIC TABLE3 CU @nits (rng1L) (lb/day)* (pg/L) (pg/L) Aluminum [total] 19..03 0 0. ](96hrLC5.) (X) I ............ ....... ............ Antimony [total) 219 1,095 Arsenic [total) 0.002 0.0 190(As3+) 360(As3+) Beryllium [total] . . . ....... 0.01(96hrLcm) 0.05(96hrLC%) x: .X: ..... Cadmium S [total] 0.0002 0.00 0@01(96hrLc")(X) Chromium Total S 0.05 0 Il+E%P(0.9l9-(InH)+I.56I) I6+E)(P(0.&I9(InH)+3.689) ......... X. .......... ..... . ................ 16 VI ... Chromium (Ugll) .............. Copper S [total] 0.007 0.0 E3M(.8545(InH)-l.465) E3(P(0.9422flnH)-l.464) Iron [total) 20.22 0 0.3 mgA**(X) I Lead S [total] 0.014 0 E)X(l.266(InH)4.66I) ENP(I.266(InH)-l.416) Manganese [total] 0.30 0 1 mg/I 2 ercury [total] . . . . . . . . . . . . . . . . . 0.2 pgfl***(X) Nickel $ [total] 0.02 0 ENP(0.846(InH)+l.l645) EXP(0.WnH)+3.36I2) Selenium [total] gummomm 10 Pg/I (X) Silver $ [total] <0.0002 <L88 0.2 EXP(I.72(1nH)-6.52) Thallium [total) 0.019 0.09 Zinc $ [total] 0.076 0 EYP(0.8473(htH)+0.76I4) EXP(0.8473(1nH)+0.8604) 1,0TES: EP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CV = Critical Use: 1) Aquatic Life; 2) Water Supply e LC@ The concentration of pollutant in test waters that is lethal to 501/6 of test organisms o vr a specified time period. H Hardness loading based on a flow of 1,745.92 cfa -This value or natural levels, whichever is greater *** - in an unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie anatyte eliminated from sampling program PROJECT NAME: WATER QUALITYMOMITORING STUDY FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: WALNUT CREEK EVENT: low ADDITIONAL PARAMETERS Date may 9 '1996 1 May1g, 1996 DEP CHPT 16 WQC DEP CUPT 93 WQS Event low ow CCC CIVIC TABLE3 CU Junits (rng/L) (lb/day)- Alkalinity (mg/L CaCO3) 45 n/a minimum of 20 1 Chloride (mg/1) 22 0 250 2 .......................... ............. .......... ...... ...... .... ......... ....... .... ......... Cyanide, free (VgA) ................... ... 22 Grease & Oil Grab (mg/1) 2 2 Ammonia-Nitrogen 0.09 0 (NH3-N) x (log- I [pKT-pH]+ 1) Nitrite-Nitrogen (mg1l) 0.14 o N02+NO3=10 2 itrate-Nitrogen (mg1l) 0.44 0 (as nitrogen) BOD, 8 n/a hemical Oxygen Demand 20 n/a ecal Coliform (#/IOOmL) 10,100 n/a BAC I (X) 3 hosphorus, total 2.08 0 (P) (X) Total Suspended Solids 2,504 0 Hardness (mg/L CaCO3) 74 n/a max. monthly mean of 150 PH (s.u.) --[field] 7.43 n/a 6.5 - 9.0 (X) I Temperature (C) ** [field] 14.6 n/a I Conductivity (mv/cm) ** [field] 202 n/a Dissolved Oxygen (mg/L 0,) ** [field] 8.2 n/a minimum of 5.0 NOTES: n1a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-terin protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation 9 - colonies BACI - MAX = geometric mean of'200/100ml based on not less thin 5 samples taken over not more than a thirty-day period * - loading based on a flow of 1,745.92 cfs **[field] - average of the 3 grab samples measured in the field P)-Concentrations sho ld be limited to the extent necessary to prevent nuisance growths ofalgae, weeds, and slimes that are or may become injurious to any beneficial water use. X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie ............ analyte eliminated from sampling program PROJECT NAME: RA TER QUALITY MONITORING STUD Y FOR THE LAKE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: low PESTICIDES/PCBS Date May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CMC TABLE3 units (I'S(L) (lbiday)* 44L) 441-) (pg/L) alpha-BHC n/a n1a beta-BHC n/a n1a delta-BHC n/a n/a gamma-BHC (Lindane) 0.001 (X) Heptachlor 0.001 (X) Aldrin 0.001 (X) Heptachlor epoxide 0.1 0.8 alpha-Endosulfim (1) 0.056 0.22 Dieldrin 0.001 (X) 4,4'-DDE 0.001 1.1 Endrin 0.002 (X) beta-Endosulfm (11) 0.056 0.22 4,4'-DDD 0.001 1.1 Endosulfan sulfate n/a n/a 4,4'-DDT 0.001 1.1 alpha-Chlordane (X) gamma-Chlordane (X) Toxaphene 0.008 (X) ":X n1a Endrin Aldehyde ..... X.. n/a X ... ... NOTES: DEP CHPT 16 WQC Pennsylvania Department of Environmental Protection Chapter 16 Water Quality Criteria for Toxic Substances effective March 11, 1989, 19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective Much 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) n1a - not applicable loading based on a flow of 2,812.07 efs - limit for Chlordane = 0.06 p&/L (X) (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie .................. analyte eliminated from sampling program . ........... PROJECT NAME: WA TER QUALITY MOA7TORING STVD Y FOR THE L4KE ERIE WATERSHED JOB NUMBER: 2758-001 SAMPLE LOCATION: ELK CREEK EVENT: low INORGANICS Date May 9, 1996 May 9, 1996 DEP CHPT 16 WQC DEP CHPT 93 WQS Event low low CCC CIVIC TABLE3 CU Nnits (MgfL) (lb/day)* (tigL) (pg/L) Aluminum (total] 18.18 0 0. ](96hrLC") (X) I ......... . . ......... .... 1,095 .......... Antimony [total] 219 Arsenic [total] 0.003 0.0 190(As3+) 360(As3+) ........................ ................. Beryllium [total] ............................. .............................. .. 0.01(96hrLC,) 0.05(96hrLcm) ....................... ............ ............ Cadmium $ [total] <D.0001 <1.52 0.01(96hrLC,) (X) hromium Total $ 0.06 0 1 l+EXP(0.8l9-(InH)+I.56l) l6+EXP(0.8l9(lnH)+3.688) ........ 16 Chromium VI (ugfi) . .............. ... ......... Copper S [total] 0.003 0.0 EXP(.9545(lnH)-I.465) EXP(O.9422(hffl)-l.464) Iron [total] 19.87 0 0.3 mgA-*(X) I Lead S [total] 0.009 0 EXP(I.266(InH)-4.66I) EXP(l.266(InH)-l.4l6) Manganese [total] 0.25 0 1 mg/l 2 Mercury (total] 0.2 pgtl***(X) ..... ................. Nickel S [total) 0.02 0% EXP(0.846([nH)+ 1. 1645) EXP(0.WnH)+3.36l2) ........ XX... Selenium [total] ......... ............... 10 pSA (X) Silver $ [total) <0.0002 <3.03 0.2 EXP(I.72(InH)-6.52) . ....... .... Thallium [total) ....... ......... X X......... 0.018 0.09 xxxx .. .......... .. ......... Zinc $ [total] 0.079 1 0 EXP(0.8473(lnH)+0.76l4) EXP(0.8473(1nH)+0.8604) 1,0TES: DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Cbpt 16 Water Quality Criteria for Toxic Substances and Chpt 93 Water Quality Standards effective Much 11, 1999,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989,19 Pa. B. 1059 CC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-terrin protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply LC5,, = The concentration of pollutant in test waters that is lethal to 500/. of test organisms over a specified time period. H = Hardness loading based on a flow of 2,912.07 cfs -This value or natural levels, whichever is greater *** - in arit unfiltered water sample (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie PROJECT NAME: WATER QUALITY MOMITORINGSTUDY FOR THE LAKE ERIE WATERSHED OB NUMBER: 2758-001 SAMPLE LOCAT1ON: ELK CREEK EVENT: low DDITIONAL PARAMETERS ate May 9,1996 May 9,1996 DEP CHPT 16 WQC DEP CHPT 93 WQS vent low low CCC CIVIC TABLE3 CU nits (mg/L) (lb/day)* Alkalinity (mg1L CaCO,) 30 n/a minimum of 20 1 Chloride (mgfl) 8.4 0 250 2 Cyanide, free (pgf]) .......... :-XX-:-'-:-X 5 22 ............................ .......... . :: ........... 2 2 Grease & Oil Grab (mg/1) Ammonia-Nitrogen 0.07 0 (NH3-N) x (log-l(pKT-pHj+l) Nitrite-Nitrogen (mg/1) 0.2 0 N02 + N03=10 2 Nitrate-Nitrogen (mg1l) 0.47 0 (as nitrogen) CBOD5 6 n/a Chemical Oxygen Demand 30 n/a Fecal Coliform (#/IOOmL) 6,400 n/a BACI (X) 3 Phosphorus, total 2.30 0 (P) (X) Total Suspended Solids 3,428 0 Hardness (mg/L CaC03) 55 n/a max. monthly mean of 150 pH (s.u.) -[field] 6.9 n/a 6.5 - 9.0 (X) I Temperature (*C) -- [field] 14.6 n/a I Conductivity (mv/cm) ** [field] 125 n/a Dissolved Oxygen (mg/L 0,) ** (field] 8.6 n/a minimum of 5.0 NOTES: n1a - not applicable DEP CHPT 16 WQC = Pennsylvania Department of Environmental Protection Chpt 16 Water Quality Criteria for Toxic Substances effective March 11, 1989,19 Pa. B. 1059 DEP CHPT 93 WQS = Pennsylvania Department of Environmental Protection Chapter 93 Water Quality Standards effective March 11, 1989, 19 Pa. B. 1059 CCC - criterion continuous concentration (for long-term protection) CMC - criterion maximum concentration (for short-term protection) Table 3 - located on pages 93.7 through 93.15 of Chapter 93 Water Quality Standards CU = Critical Use: 1) Aquatic Life; 2) Water Supply; 3) Recreation # - colonies BACI - MAX = geometric mean of 200/100ml based on not Im than 5 samples taken over not more than a thirty-day period * - loading based on a flow of 2,812.07 cfs **[field] - average of the 3 grab samples measured in the field M-Concentratiom sho ld be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that are or may become injurious to any beneficial water use. (X) - Chapter 93 Water Quality Criteria Designated Water Use Drainage List - Lake Erie analyte eliminated from sampling program S MALCOLM PIRNIE APPENDIX C CREEK CROSS-SECTION SURVEY DATA 2758-001 Printed on Recycled Paper HENRY T. WELKA ASSOCIATES Ma "ST at" SrRw me, Px0sny"M fd"s SURVEYING - RINVOINERRING Pff. (SJ4) 833-S800 FAZ (8fg) AIM-W60 2 3 4 5 6 7 Mo I F F I I I am TOP Of LEM A' ffiro'Zi ROMM OF IEZDWW Wo V5 lot wo to f 1ENCHUNW: 12 MIL E CREEK CROSS SECTION st'ale ROOM 5 Blidge Over 7we"mim Creek. sVffe cut in Northeast corner LOOKING EAST of Arch ParOPOt. - 06v, @ 6W. 70 Et 10' HORIZ US.Gs. Disk stomped TTIBEFR 1955. SCALE. 25'Right of Stc- 557+14. SOUthw8st corner of intemecUon of L.R. 495 (S.R. 5' VERT 5) and L.R. 25070 (SA 1006) - Rev. 19 18 18 15 14 13 12 11 10 9 8 7 6 5 4 3 2 ow L -1 A. 1410M sm 7w ar mw J&VL so A. 575 wo WAI-JVU7' CREEK BRIDGE CROSS SEC77ON of MOWS" LOOKING NORTH C*M@r af SCALE: lo @ 20' HORIZ Dufth Read Wdf-t CAWk Ot 00 @N&Mwe to S070 Pat A=Opcmmtwf - 5' VERT zacr we& alov Dufth 20 01A @@@Cjjm of AARM"Ofm B d abd AM&A Rbat EAW. - =fso HENRY T WELKA ASSOCIATES am "AT $ad MAW im mxwft@ Mm in HEIVR Y T. WEL" ASSOCIATES 3200 NrST 38nd STAU7 EM. P"AWnVANU 086W SURMING - EXCINEEWNG PH. (814) 638-4900 VAX (814) 883-"Sa 10 9 8 5 4 0 an I J I I I I LA -A no 7- W5 sm am WNCtNAW. EL K CREEK CROSS SECTION hop of fl!vnns#vvniv Depariment of lfghways F-T I-1- I L C-1 Disk a 13, set of the northeast comer of LOOKING NORTH T, br*V* on North Creek Road fley @ 702.68 SHOTS TAKEN FROM EAST TO WEST' SCA L E.- 1 10' HORIZ 5' VER T BRIDGE 14- c; DETAIL OF BRIDGE NO SCALE FAX TRANSMITTAL COVER SHEET Irv Henry T. Welka Associates Swm"g - Engftwwft r 3200 West 32)sd SlYear -.&ig, Pavaylvania Phow.- (814) 833-3900 F= (8J4) 833-95SO Dam: mgy jo, 19% FAX No: /- 7) (* - 8ZO - 0431 T& nnoww CAD fnAWE61A 'WlfW%W6- Fro= ll@-- 7 -W&KA f'- sukdc= CRP% sp-C.-nomr--, 7()%?. CQ&-v-% Tb= we Trm==va& Q For y= um. ;( AS TaFegad. 0 For Ranew nd Cmm-m 0 . - Nualbw dplum (i=hwing Cava shado AddWang C4mnmm: 1P ANY C?UesmAj@ Pue-ASE Fal- F94F CAM, Ifyou do not readve aa of this transmiWon, Ptmu caa si4 -pn.3900. NOAA COASTAL SERVICES CTR LIBRARY 3 6668 141,11481 1 P"Int'd In R-Yeled Pape,