[From the U.S. Government Printing Office, www.gpo.gov]


                                NOAA NATioN-AL STATUS& TRENDS
                                                          MUSSEL WATCH PRO-GRAM
                                                Analytical Data Report
                                                                                                   Year IX


                                                                                                 The Geochemical &
                                                                                                 Environmental Research Group

                                   ,@D ATMOSp
                                    'D P.TMOSp




                           0





                                   -NeAff of


                                                                                                                                                                                           a ii
                                                                                                            TN


                                                                                                                                                                                                           lg,  ,
                                                                                                                  W.
                                                                                                                                                      MNW,"              @Mi, "mom
                                                                                                                                                                                           S

                                             7i.*!




                                                          M,                                                             ......
                                                 .-W
                                                                       -4
                                                                                                                                                                   IWNR B"m
                                                                                                                                                                                        'go,
                                                                                                                                               T'
                                                                    ill, 'R
                                                                                                                                  4    MEN J"
                                                                                                                              w                                        j  ig                 14
                                   MM     1@                                                                                                                           _"J"
                                                                                                                                                                M',
                                                                                                                                                                            M
                                                                                                                                                                            -M
                                                                                                                                                                                         S-1
                                                         I ia



                            . ... . . .
                            ... . ... .


                                   ,W                                                                                                                                                            'EN @88
                                                                                                                                                                                           R40

                                                                                        GULF OF MEXICO


                         IMP




                         QH
                         541.5
                            C65
                         A63
                         year        9
                         (199
                                95)
                                                                                                SEPTEMBER 1995












                                                                     NOAA Status and Trends
                                                                  Mussel Watch Project - Year 9
                                                                            Analytical Data


                                                                           Table of Contents
                                                                                                                                   Page


                         MUSSEL WATCH PROJECT                       .................................................................. I


                                    Field Station Data          ...................................................................... 2
                                    Hydrocarbon Results            ................................................................... 4a

                                              PAH Data (Tissue)           ............................................................ 5
                                              PAH QC Data (Tissue)              ...................................................... 39
                                              PAH Data (Sediment)             ........................................................ 56
                                              PAH QC Data (Sediment)                .................................................. 58


                                    Pesticide and PCB Results              ........................................................... 64


                                              Pesticides and PCBs Data (Tissue)                 ...................................... 65
                                              Pesticides and PCBs QC Data (Tissue)                    ................................ 88
                                              Pesticides and PCBs Data (Sediment)                   .................................. 101
                                              Pesticides and PCBs QC Data (Sediment)                      ............................. 104


                                    Trace Metal Results           .................................................................... Ill


                                              Trace Metal Data (Tissue)              ................................................. 112
                                              Trace Metal QC Data (Tissue)                ............................................ 117
                                              Trace Metal Data (Sediment)               .............................................  122
                                              Trace Metal QC Data (Sediment)                  ........................................ 124

                                    Butylin Results        ..........................................................................  127

                                              Butyltin Data (Tissue)           ....................................................... 128
                                              Butyltin QC Data (Tissue)              ................................................. 135
                                              Butyltin Data (Sediment)             ................................................... 140
                                              Butyltin QC Data (Sediment)               .............................................  144


                                    Method Detection Limits              ............................................................. 146


                                              PAH Method Detection Limits                 ............................................ 147
                                              Pesticides and PCBs Method Detection Limits                        ...................... 149
                                              Trace Metal Method Detection Limits                   .................................. 151
                 AP                           Butyltin Metal Method Detection Limits                    .............................. 153

            Nf\                                                                                         PrOPe-rtY Of CSC Li.brary
           1-z
                  co                                                                                U - S - DEPARTMENT OF COMMERCE NOAA
                                                                                                    COASTAL SERVICES CENTER
                                                                                                    2234 SOUTH HOBSON AVENUE
                                                                                                    CHARLESTON , SC 29405-2413




 I
 I
 I
 I
 I
 I
 I
 I
 I
           MUSSEL WATCH PROJECT
 I
 I
 I
 I
 I
 I
 I
 I
 I @
 I                       I




 I
 I
 I
 I
 I
 I
 I

m
 I
 I             Field Station Data
 I
 I
 I
 I
 I
 I
 I
 I
 1
                        2
 1






                                                                                  Mussel Watch Project Year 9 - Field Station Data


                                                                                                                                                                                                                         High      Low
                        Rep.                                                                                                Date        Collect. Bottom                                   Depth Temp Salinity            Water Water           Tidal         Tidal
                 Site   No.   Location Name                                         Latitude       Longitude     1Xpe     (M/D/Y)       Method Type           Scientist      Species        (m)      (C)     (0/00)      (Local Time)          Reference   Horizon

                LMSB       I  South Bay, Lower Laguna Madre                         26*02'46"      97010'29"       B      12/9/93          H          N         Fay       C. virginica      0.3      19          31      15:27     6:00        Pt. Isabel    0.34
                LMPI       I  Port Isabel, Lower Laguna Madre                       26004'37"      97012'03"       B      12/8/93          H          N         Fay       C. virginica      0.5      21          29      14:09     5:13        Pt. Isabel    0.34
                LMAC       I  Arroyo Colorado, Lower Laguna Madre                   2601648"       97017'18"       B      12/8/93          H          HNG       Fay       C. virginica      0.3      22          30      22:49     4:10        Padre Is.     0.34
                CCNB       I  Nueces Bay, Corpus Christi                            27051'10"      9702 1'33"      B      12/14/93         H          SM      Wilson      C. virginica      0.2      13          32      18:50     10:38       Aransas P.    0.65
                ABLR       I  Long Ree@ Aransas Bay                                 28"02'58"      96*5646"        B      12/16/93         D       MNSG       Jobling     C virginica       0.5      16          23      20:06     12:07       Aransas P.    0.50
                MBAR       I  Ayres Reet Mesquite Bay                               28010'09"      96049'57"       B      12/15/93         H                  Wilson      C. virginica      0.1      13          24      19:30     11:23       Aransas P.    0.58
                SAPP       I  Panther Point Rce@ San Antonio Bay                    28014'00"      96042'33"       8      12/15/93         D          S       Jobling     C. virginica      1.5      15          24      19:30     11:23       Pt. O'Con.    0.20
                ESSP       I  South Pass Reef, Espiritu Santo                       28017'54"      96@37'20"       B      12/16/93         HD         R       Wilson      C. virginica      0.5      17          24      20:06     12:07       Pt. O'Con.    0.17
                ESBD       I  Bill Day's Reef, Espiritu Santo                       29@24'5 1"     96026'16"       B      12/16/93         H          SNA     Wilson      C virginica       0.3      16          30      20:06     12:07       Pt. O'Con.    0.17
                MBGP       I  Gallinipper Point@ Matagorda Bay                      28035'15"      96034'10"       B      12/14/93         D          SMH     Jobling     C. virginica      2.0      15          25      18:50     10:38       Pt. Lavaca    0.32
                MBCB       I  Carancahua Bay, Matagorda Bay                         2839'24"       96023'11 "      B      12/14/93         H          SR      Jobling     C. virginica      0.3      15          25      18:50     10:38       Pt. Lavaca    0.32
                BRCL       I  Cedar Lakes, Brazos River                             2805 1'30"     95027'50"       B      12/7/93          H          R       Wilson      C. virginica      0.3      18          22      22:01     4:06        Freeport      0.34
                GBID       I  Todd!s Dump, Galveston Bay                            29030'04"      94053'49"       B      12/8/93          D          SM      Jobling     C. virginica      1.5      16          13      23:46     6:36        Texas City    0.35
                GBOB       I  Offats Bayou, Galveston Bay                           2rl7'05"       94050'09"       B      12/8/93          H          B       Wilson      C. virginica      0.5      17          21      23:13     5.55        Galveston     0.35
                GBSC       I  Ship Channel, Galveston Bay                           29042'16"      9405935"        B      12/7/93          D          SM      Jobling     C. virginica      1.5      16          12      23:16     5:49        Texas City    0.25
                SLBB       I  Blue Buck Point, Sabine Lake                          29047'30"      9305425"        B      12/9/93          D          SM      Wilson      C. virginica      1.5      16          11      13:25     5:27        Sabine        0.64
                CLLC       I  Lake Charles, Calcasieu Lake                          30003'25"      93018'25"       B      12/9/93          H          SM      Wilson      C. virginica      0.5      18          12      12:31     5:43        Mermentau     0.85
              CA
                VBSP       I  Southwest Pass, Vermillion Bay                        2903436"       92002'45"       B      1/11/94          D          SMH     Jobling     C. virginica      2.0      8           3       17:09     9:09        SW Pass       0.71
                CLCL       I  Caillou Lake, Caillou Lake                            29*15'15"      90055'48"       B      1/12/94          D          SM      Jobling     C. virginica      2.0      10          10      22:11     9:31        Caillou       0.55
                TBLF       I  Lake Felicity, Terrebonne Bay                         29015'48"      90@2424"        B      1/11/94          H          SM      Wilson      C. virginica      0.5      15          15      21:07     8:26        Timbalier     0.55
                MRPL       I  Pass a Loutre, Mississippi River                      29004'52"      89005'32"       B      1/14/94          D          MS      Jobling     C. virginica      1.5      8           2       19:40     7:49        P-a-Loutre    0.34
                BSSI       I  Sable Island, Breton Sound                            29024'07"      Sn9'06"         B      1113194          D          MS      Jobling     C virginica       1.0      10          1       23:33     9:50        Breton S.     0.42
                LBMP       I  Malheureux Point, Lake Borgne                         29052'01"      89040'42"       8      1/14/94          H          SM      Wilson      C virginica       0.4      10          6       20:40     9:36        N. Orleans    0.22
                LBNO       I  New Orleans, Lake Borgne                              29056'36"      89050'06"       B      1/14/94          H          SNP     Wilson      C. virginica      0.2      9           7       20:40     9:36        N. Orleans    0.22
                MSPC       I  Pass Christian, Mississippi Sound                     30018'07"      89019'40"       B      1/15/94          D          NSH     Jobling     C virginica       2.5      6           18      11:02     22:09       Bay,S. Lou    0.46
                MSPB       I  Pascagoula Bay, Mississippi Sound                     30*20'02"      88136'06"       B      1/15/94          D          SR      Jobling     C. virginica      1.5      11          18      9:29      19:57       Pascagoula    0.42
                MBCP       I  Cedar Point Reef, Mobile Bay                          30*18'42"      88008'00"       B      1/15/94          H          NS      Wilson      C. virginica      1.2      11          20      1:59      11:28       Mobile        0.30
                MBHI       I  Hollingers Is. Channel, Mobile Bay                    3003348"       88004'30"       B      1/15/94          D          MSN     Wilson      C virginica       2.0      9           7       1:59      11:28       Mobile        0.30
                PBPH       I  Public Harbor, Pensacola Bay                          30'24'38"      87*11'25"       B      1/16/94          H          N       Wilson      C. virginica      0.5      10          24      0:52      10:07       Pensacola     0.52
                PBIB       I  Indian Bayou, Pensacola Bay                           30031'00"      87006'42"       B      1/16/94          D          SM      Wilson      C. virginica      2.0      11          23      0:52      10:07       Pensacola     0.52
                CBJB       I  Joe's Bayou, Choctawhatchee Bay                       3002437"       8602927"        B      1/17/94          H       SBRM       Wilson      C. virginica      0.5      11          24      16:54     10:26       Destin        0.13
                CBBL       I  Ben!s Lake, Choctawhatchce Bay                        30027'09"      8602844"        B    . 1/17/94          H          CB      Wilson      C. virginica      0.5      13          25      16:54     10:26       Destin        0.13
                CBPP       I  Postil Point Choctawhatchee Bay                       30*28'51"      8602844"        B      1/16/94          H          B       Jobling     C. virginica      0.3      6           24      0:25      11:27       Destin        0.24
                CBB13      I  Boggy Bayou, Choctawhatchec Bay                       30*30'11"      86029'39"       B      1/16/94          H          E       Jobling     C. virginica      0.5      7           17      0:25      11:27       Destin        0.24
                PCLO       I  Little Oyster Bar, Panama City                        30015'11"      85*40'57-       B      1/17/94          H          M       Jobling     C. virginica      0.2      12          10      17:15     9:26        Lyn Haven     0.34


                 Bottom Type: A=Algae, B-Rubble, C-Clay, E--Concrete, G--Grass, H=Hash, K=Kelp, M=Mud, N=Sand, P--Peat, R=Reef, S=Shell, TuRoots
                 Collection Method: DoDredge, H=Kand, R=Rake, T-Tongs
                 Sample Type: B=Bivalve, S-Sediment






                                                                                     Mussel Watch Project Year 9 - Field Station Data


                                                                                                                                                                                                                                 High      Low
                         Rep.                                                                                                   Date        Collect. Bottom                                     Depth Temp Salinity              Water Water           Tidal          Tidal
                  Site   No.    Location Name                                          Latitude        Longitude    Type       (M/D/Y)      Method Type             Scientist     Species         (m)      ('C)     (0/00)       (Local Time)          Reference    Horizon

                AESP         I  Spring Creek, Apalachee Bay                            30P0345"        84019'22"       B       1/18/94          H          SR       Wilson      C virginica       0.5       15         13        17:58     0:15        Bald Pt.       0.57
                CKBP         I  Black Point, Cedar Key                                 29012'17"       8300420'        B       1/19/94          H          MSR      Wilson      C. virginica      1.0       4          19        17:47     0:20        Cedar Key      0.69
                TBOT         I  Old Tampa Bay, Tampa Bay                               28001'29"       82037'57"       B       1/20/94          H          NSR      Wilson      C virginica       0.2       13         2         21:33     4:45        Safety H.      0.67
                TBPB         I  Papys Bayou, Tampa Bay                                 27050'32"       82@36'37"       B       1/20/94          H          SR       Wilson      C virginica       0.5       14         28        19:55     2:50        St. Peters.    0.55
                TBHB         I  Hillsborough, Tampa Bay                                2705 I'l 7"     8202345-        B       1/21/94          H                   Wilson      C virginica       0.6       15         15        20:53     4:30        Hillsbrgh.     0.75
                TBMK         1  Mullet Key Bayou, Tampa Bay                            27037'17"       82043'37-       B       1/21/94          H                   Wilson      C virginica       0.5       15         33        18:37     3:20        St. Pete B.    0.52
                TBKA         I  Knights Airport, Tampa Bay                             27054'31"       82027'16"       B       1/20/94          H          NBH        Fay       C. virginica      0.2       14         30        20:02     3:16        Hillsbrgh.     0.67
                TBNP         I  Navarez Park, Tampa Bay                                2747'17"        82*45'17'       B       1/20/94          H          N        Wilson      C virginica       0.3       12         32        18:15     1:32        Madeira B.     0.55
                CBBI         I  Bird Island, Charlotte Harbor                          26030'44"       82002'11"       B       1/21/94          D          SR         Fay       C virginica       0.8       16         26        20:27     4:30        Pineland       0.50
                RBHC         I  Henderson Creek, Rookery Bay                           26001'30"       81044'12"       B       1/21/94          H          SN         Fay       C virginica       0.4       18         34        19:23     2:34        Marco          0.51
                FBFO         I  Flamingo, Florida Bay                                  25008'16"       80055'15"       SB      1/25/94          H          N        Wilson      C virginica       1.0       20         35        1:02      9:49        Flamingo       0.88
                FBFO         2  Flamingo, Florida Bay                                  25008'16"       80055'15"       SB      1/25/94          H          N        Wilson      C virginica       1.0       20         35        1:02      9:49        Flamingo       0.88
                FBFO         3  Flamingo, Florida Bay                                  25*08'16"       80*55'15"       SB      1/25/94          H          N        Wilson      C virginica       1.0       20         35        1:02      9:49        Flamingo       0.88
                FBJB         I  Joe Bay, Florida Bay                                   25012'32"@      ff32'00"        SB      1/25/94          H          NO       Wilson      C. virginica      1.0       23         30        1:02      9:49        Flamingo       0.88
                FBJB         2  Joe Bay, Florida Bay                                   25012'32"       80032'00"       SB      1/25/94          H          NO       Wilson      C virginica       1.0       23         30        1:02      9:49        Flamingo       0.88
                FBJB         3  Joe Bay, Florida Bay                                   2501232"        80032'00"       SB      1/25/94          H          NO       Wilson      C. virginica      1.0       23         30        1:02      9:49        Flamingo       0.88
              4BHKF          I  Bahia Honda, Florida                                   2439'31"        81016'26"       B       1/19/94          H          NGP        Fay       C virginica       0.5       20         35        14:00     7:42        B.Honda K      0.29
                PRBB         I  Bahia de Boqueron, Puerto Rico                         18000'26"       67010'43"       B       2/14/94          H          M        Wilson      C virginica       0.3       25         35        10:50     17:16       San Juan       0.33
                PRBM         1  Bahia Montalva, Puerto Rico                            17058'14"       66059'26"       B       2/13/94          H          TB;      Wilson      C virginica       0.3       26         36        2:58      6:57        San Juan       0.37
                PRBJ         I  Bahia de Jobos, Puerto Rico                            17656'20"       66010'57"       B       2/15/94          H          TN       Wilson      C virginica       0.3       26         36        0:23      7:56        San Juan       0.30

















                  Bottom Type: A-Algae, BoRubble, C-Clay, E=Conerete, G--Grasa, H=Hash, X=Kelp, M=Mud, N=Sand, P--Peat, R=Reef, S=Shell, T=Roots
                  Collection Method: D=Dredge, H=Hand, R-Rake, T=Tonge
                  Sample Type: B=Bivalve, S-Sediment




 I
 I
 I
 I
 I
 I
 I
 I          Hydrocarbon Results
 I
 'I
 -I
 I
 I
 I
 I
 I
 I.
 -I
                      4a
.I




 I
 I
 I
 I
 I
 I
 I
 I                  PAH Data
 I                   (Tissue)
 I
 I
 I
 11
 I
 I
 I
 I
 1                       5
 1





                                                          Mussel Watch Project Year 9 - PAH Data (Tissue)

                                 INVEST#                LMSB                             LWI                               LMAC                             CCNB                         ABLR
                                          ID    L. Laguna Madre                   L. Laguna Madre                  L. Laguna Madre                   Corpus Christi                 Aransas Bay
                                       SITE         South Bay                         Port Isabel                  Arroyo Colorado                     Nueces Bay                    Long Reef
                             LABSAMNO                   K8008                            K8016                             K8012                            K8018                        K8032
                          SAMPLE TYPE                   SAW                              SANT                              SAW                              SAMP                         SAMP
                                      UNIT              11919                            ng/g                              ng1g                             ng/g                         ng/g
                             PNA Analyte                Conc          DB QUAL            Conc          DBQUAL              Conc          DB QUAL            Conc        DB QUAL          Conc        MQUAL

                         RECEIPT DATE                   12/10/93                         12/10/93                          12/10/93                         12/16/93                     12/17/93
                                QCBATCH                 M1410                            M1410                             M1410                            M1410                        M1410
                  EXTRACTION DATE                       07/21/94                         07/21/94                          07/21/94                         07/21/94                     07/21/94
                                 METHOD                 GCMS                             GCMS                              GCMS                             GCMS                         GCMS
                      ANALYSIS DATE                     09/04/94                         09/04/94                          09/04/94                         09/04/94                     09/04/94
                                 MATRDC                 TISSUE                           TISSUE                            TISSUE                           TISSUE                       TISSUE
                                 SUBMAT
                                   WETWT                10.23                            10.02                             10.15                            10.03                        10.05
                                   DRYWT                1.06                             1.32                              1.70                             2.21                         1.65
                                 WTUNITS                GRAMS           DRY              GRAMS            DRY              GRAMS           DRY              GRAMS          DRY           GRAMS         DRY
         0)                  PCTSOLIDS                  10.3%                            13.2%                             16.7%                            22.0%                        16.4%
                             Lipid Weight
                                 % LIPIDS               4.11                             3.28                              10.92                            2.04                         18.74
                     Surrogate Recoveries
                                 NAPHD8                 50.8                             48.7                              48.1                             54.3                         55.4
                                 ACEND10                54.9                             51.3                              53.6                             60.4                         60.2
                                 PHEND10                59.7                             55.4                              58.9                             65.7                         58.0
                                 CHRYD12                65.5                             60.1                              66.0                             75.7                         67.3
                                 PERYD12                21.9                             20.3                              12.1              Q              10.6            Q            9.6              Q
                      NAPHTHALENE *                     20.3                             18.9                              54.4                             14.0                         14.2
                  Cl-NAPHTHALENES                       15.9               J             15.7                              30.4                             13.0                         10.9
                  C2-NAPHTHALENES                       18.2                             21.1                              20.3                             16.4                         29.0
                  C3-NAPHTHALENES                       35.9                             51.1                              48.6                             33.7                         91.4
                  C4-NAPHTHALENES                       17.9               J             56.1                              51.4                             28.9                         110.9
                             BIPHENYL                   5.9                J             4.9                J              26.8                             4.1             J            6.8              J
                  ACENAPHTHYLENE                        1.3                J             2.2                J              2.9               J              2.6             J            2.4              J
                     ACENAPHTHENE*                      1.3                J             13.1                              8.9                              5.5                          1.6              J




                                                           mmmmm m mm m m m
                                                           Mussel Watch Project Year 9 - PAH Data (Tissue)

                                 INVEST#              LMSB                             LMPI                            LMAC                            CCNB                        ABLR
                                         ID    L. Laguna Madre                  L. Laguna Madre                 L. Laguna Madre                  Corpus Christi               Aransas Bay
                                      SITE        South Bay                        Port Isabel                  Arroyo Colorado                   Nueces Bay                    Long Reef
                             LABSAMNO                 K8008                            K8016                           K8012                           K8018                       K8032
                         SAWLE TYPE                   SAW                              SAW                             SAW                             SAW                         SAW
                                     UNIT             ng/g                             ng/g                            ng/g                            ng/g                        ng/g
                            PNA Analyte               Conc          DB QUAL            Conc         DB QUAL            Conc          DB QUAL           Conc        DB QUAL         Conc        DB QUAL

                           FLUORENE*                  2.7                J             13.1                            13.8                            7.9                         4.8               J
                         Cl-FLUORENES                 18.2               J             23.9                            24.1                            20.1                        35.2
                         C2-FLUORENES                                  ND                              ND              86.7                                           ND                          ND
                         C3-FLUORENES                                  ND                              ND              136.1                                          ND                          ND
                     PHENANTHRENE*                    14.6                             85.8                            88.7                            52.2                        33.3
                         .ANTHRACENE*                 2.3                J             9.8                             6.7                             6.8                         4.4               J
                     Cl-PHEN-ANTHR                    16.5                             66.8                            59.8                            29.1                        82.1
                     C2-PHEN-ANTHR                    27.4                             87.3                            41.4                            31.0                        114.0
                     C3-PHEN-ANTHR                    29.2                             111.5                           55.6                            37.6                        78.9
                     C4-PBEN ANTHR                    12.8               J             39.0                            17.5                            15.4
                         DIBENZOTHIO                  0.9                J             6.1                             4.2                             3.4                         2.8
                               Cl-DIBEN               4.2                J             13.3                            7.6                             10.3                        18.7
                               C2-DIBEN               9.9                              33.5                            23.6                            17.1                        41.6
                               C3-DIBEN               13.3                             42.8                            16.4                            22.1                        28.1
                    FLUORANTHENE *                    19.8                             513.9                           249.5                           88.9                        7.0
                               PYRENE*                10.9                             207.5                           140.7                           52.0                        8.0
                    Cl-FLUORAN PYR                    10.2                             134.5                           74.6                            48.8                        14.8
                    BENaANTHRACENE*                   2.7                J             95.2                            24.7                            13.0                        1.2               J
                           CHRYSENE *              .  7.8                              95.0                            52.8                            36.5                        3.6               J
                         Cl-CHRYSENES                 3.1                J             16.6                            6.9               J             7.3                         3.2               J
                         C2-CHRYSENES                 3.3                J             4.0              J              2.6               J             5.1               J         4.4               J
                         C3-CHRYSENES                                  ND                              ND              1.2               J                            ND                          ND
                         C4-CHRYSENES                                  ND                              ND              2.1               J                            ND                          ND_.
               I BENb/BEN1cFLUORAN                    6.7                              42.4                            18.9                            16.0                        2.9
                         BENePYRENE *                 3.3                              17.6                            11.3                            8.6                         1.7
                         BENaPYRENE *                 1.1                J             2.2              J              2.4               J             1.2               J         0.5               J
                           PERYLENE*                  2.0                J             3.7              J              4.7                             3.7                         4.0
                         I123cdPYRENE                 1.4                J             3.3                             2.0                             1.3                         0.6               J
                         DBahANTHRA *                 0.7                J             0.9              J              0.8               J             0.6               J         0.4               J
                         BghiPERYLENE                 1.8                J             4.1                             2.2                             1.9                         0.9               J
                           TOTALPAHs                  343.3            0.0             1856.7          0.0             1423.1          0.0             655.9          0.0          795.0          0.0
                     S&T Total PAHs                   125.0                            1125.6                          741.5                           326.7                       153.7





                                                        Mussel Watch Project Year 9 - PAH Data (Tissue)

                                 INVEST#             LMSB                            LMPI                          LMAC                           CCNB                         ABLR
                                        ID    L. Laguna Madre                 L. Laguna Madre                 L. Laguna Madre                 Corpus Christi                Aransas Bay
                                      SITE        South Bay                       Port Isabel                 Arroyo Colorado                   Nueces Bay                   Long Reef
                            LABSAMNO                 K8008                           K8016                          K8012                         K8018                        K8032
                         SAMPLE TYPE                 SAM?                            SAMP                           SAMP                           SAMP                        SAMP
                                     UNIT            ng/g                            ng/g                            ng/g                           ng/g                        ng/g
                            PNA Analyte              Conc          DB QUAL           Conc          DD QUAL           Conc         DB QUAL           Conc        DB QUAL         Conc       DB QUAL



                    2-METHYLNAPH *                   8.8                             8.7                             16.8                           8.5                         6.5
                    1 -METHYLNAPH *                  7.1                             7.0                             13.6                           4.5                         4.5
                  2,6-DRvfETHNAPH *                  10.1                            10.9                            10.6                           9.2                         18.0
                  1,6,7-TRR,4ETHNAPH *               1.7               J             4.7               J             4.2               J            3.1             J           16.4
                    I-METHYLPHEN *                   2.1               J             12.7                            10.1                           6.6                         17.0







        00





                                                         Mussel Watch Project Year 9 - PAH Data (Tissue)

                                  INVEST#           ABLR                       MBAR                           SAPP                            ESSP                          ESBD
                                         ID    Aransas Bay                Mesquite Bay                 San Antonio Bay                   Espiritu Santo                Espiritu Santo
                                       SITE     Long Reef                  Ayres Reef                 Panther Point Reef                South Pass Reef               Bill Day's Reef
                              LABSAMNO              K8032                      K8020                          K8026                           K8030                         K8028
                          SAMPLE TYPE               SAMP                       SAMP                           SAMP                            SAW                           SAMP
                                      UNIT          ng1g                       ng/g                           ng/g                            ng/g                          ng/g
                             PNA Analyte            Cone       DB QUAL         Conc       DB QUAL             Conc          DB QUAL           Cone         DB QUAL          Conc        DB QUAL

                         RECEIPT DATE               12/17/93                   12/16/93                       12/16/93                        12/17/93                      12/17/93
                                QCBATCH             M1410                      M1410                          M1410                           M1410                         M1410
                   EXTRACTION DATE                  07/21/94                   07/21/94                       07/21/94                        07/21/94                      07/21/94
                                  METHOD            GCMS                       GCMS                           GCMS                            GCMS                          GCMS
                       ANALYSIS DATE                09/04/94                   09/04/94                       09/04/94                        09/04/94                      09/04/94
                                  MATRIX            TISSUE                     TISSUE                         TISSUE                          TISSUE                        TISSUE
                                  SUBMAT
                                  WETWT             10.05                      10.02                          10.02                           10.02                         10.04
                                  DRYWT             1.65                       1.37                           1.81                            1.90                          1.28
                                  WTUNITS           GRAMS        DRY           GRAMS         DRY              GRAMS            DRY            GRAMS          DRY            GRAMS         DRY
                              PCTSOLD:)S            16.4%                      13.7%                          18.0%                           18.9%                         12.8%
                             Lipid Weight
                                  % LIPIDS          18.74                      10.87                          15.31                           14.93.                        6.24
                     Surrogate Recoveries
                                  NAPHD8            55.4                       57.9                           51.0                            54.9                          52.3
                                  ACENDIO           60.2                       57.6                           54.8                            63.7                          57.9
                                  PHEND10           58.0                       .59.2                          55.2                            61.4                          60.4
                                  CHRYD12           67.3                       59.0                           64.6                            70.3                          72.5
                                  PERYD12           9.6             Q          16.1           Q               11.2              Q             8.1              Q            22.6
                      NAPHTHALENE *                 14.2                       23.4                           16.6                            14.7                          14.4
                   CI-NAPHTHALENES                  10.9                       15.9                           19.7                            11.3                          11.9            J
                   C2-NAPHTHALENES                  29.0                       30.9                           15.6                            11.6                          11.5            J
                   C3-NAPHTHALENES                  91.4                       52.4                           26.8                            24.4                          31.6
                   C4-NAPHTHALENES,                 110.9                      61.2                           9.9               J             21.4                          18.3
                            BIPHENYL *              6.8             J          9.5            J               7.2               J             4.6              J            4.0             J
                   ACENAPHTHYLENE                   2.4             J          2.9            J               2.4               J             2.3              J            1.5             J
                     ACENAPHTHENE*                  1.6             J          1.4            J               0.9               J             1.5              J            0.8             J




               mmmm m mm@m m man m1m m m m m
                                                         Mussel Watch Project Year 9 - PAH Data (Tissue)

                                 INVEST#           ABLR                        MBAR                           SAPP                            ESSP                          ESBD
                                         ID    Aransas Bay                Mesquite Bay                 San Antonio Bay                   Espiritu Santo               Espiritu Santo
                                      SITE      Long Reef                  Ayres Reef                 Panther Point Reef                South Pass Reef               Bill Day's Reef
                             LABSAMNO              K8032                       K8020                          K8026                           K8030                         K8028
                          SAMPLE TYPE              SAMP                        SAMP                           SAMP                            SAMP                          SAMP
                                      UNIT         ng/g                        ng/g                           ng/g                            ng/g                          ng/g
                             PNA   Analyte         Cone       DB QUAL          Cone       DB QUAL             Cone          DB QUAL           Cone         DB QUAL          Cone       DB QUAL

                            FLUORENE*              4.8             J           6.1             J              4.6                 J           3.6                J          2.1              J
                         Cl-FLUORENES              35.2                        32.1                           17.1                            17.7                          17.3             J
                         C2-FLUORENES              173.4                                     ND                                ND                             ND                           ND
                         C3-FLUORENES              216.9                                     ND                                ND                             ND                           ND
                                                                                                                                                                                 . . ..... . ............ .
                    PHENANTHRENE                   33.3                        37.9                           23.3                            16.3                          13.7
                         ANTHRACENE*               4.4             J           4.1             J              2.3                 J           1.7                J          1.8              J
                      Cl-P]HEN-ANTHR               82.1                        25.5                           14.2                            11.8                          10.1             J
                      C2-PBEN-ANTBR                114.0                       33.4                           23.1                            25.0                          21.6
                      C3-PHEN-ANTHR                78.9                        43.0                           21.8                            33.9                          17.9
                      C4-PBEN ANITHR               31.1                        11.2            1              11.4                            11.3                                         ND
                          DIBENZOTFHO              2.8                         1.8             J              1.2                 J           0.9                J          0.9              J
        0                      Cl-DIBEN            18.7                        10.9                           3.7                 J           3.4                J          4.7              J
                               C2-DIBEN            41.6                        25.0                           7.5                             8.3                           8.5
                               C3-DIBEN            28.1                        20.3                           10.1                            10.6                          7.4
                     FLUORANTHENE*                 7.0                         42.5                           6.2                             5.2                           5.7
                               PYR.ENE*            8.0                         24.6                           5.3                             4.6                           4.3
                     Cl-FLUORAN PYR                14.8                        21.1                           5.2                             4.3                           4.0              J
                    BENaANTHRAC                    1.2             J           8.5                            0.7                 J           0.6                J          0.9              J
                            CHRYSENE*              3.6             J           16.3                           3.1                 J           3.0                J          2.8              J
                         Cl-CHRYSENES              3.2             J           6.1             J              1.6                 J           1.5                J          1.9              J
                         C2-CHRYSENES              4.4             J           9.0             J              3.1                 J           2.9                J          3.7              J
                         C3-CHRYSENES                            ND                          ND                                ND                             ND                           ND
                         C4-CHRYSENES                            ND                          ND                                ND                             ND                           ND
                I BENb/BENULUORAN                  2.9                         16.6                           3.3                             2.3                           2.7
                         BENePYRENE *              1.7                         8.4                            2.1                             1.3                           1.7              J
                         BENaPYRENE *              0.5             J           2.9             J              0.6                 J           0.4                J          0.5              J
                            PERYLENE*              4.0                         10.9                           4.5                             4.4                           1.6              J
                           I123cdPYRENE            0.6             J           3.2                            0.7                 J           0.4                J          0.6              J
                         DBahANTHRA *              0.4             J           2.6             J              0.4                 J           0.3                J          0.4              J
                         BghiPERYLENE              0.9             J           3.4                            1.2                 J           0.7                J          1.0              J
                            TOTAL PAHs             1185.3        0.0           608.0         0.0              277.4            0.0            268.3           0.0           231.9          0.0
                     S&T Total PA14s (*2           153.7                       244.2                          109.7                           86.0                          76.9





                                                   Mussel Watch Project Year 9 - PAH Data (Tissue)

                               INVEST#         ABLR                     MEBAR                          SAPP                          ESSP                         ESBD
                                      ID    Aransas Bay              Mesquite Bay               San Antonio Bay                 Espiritu Santo              Espiritu Santo
                                    SITE     Long Reef                Ayres Reef                Panther Point Reef             South Pass Reef              Bill Day's Reef
                           LABSAMNO            K8032.                    K8020                         K8026                         K8030                        K8028
                        SAMPLE TYPE            SANT                      SAMP                          SAMP                          SAMP                         SAMP
                                   UNIT         ng/g                      ng/g                         ng/g                          ng/g                         ng/g
                           PNA Analyte          Conc       DB QUAL        Conc       MQUAL             Conc         DB QUAL          Conc        DB QUAL          Conc      DB QUAL



                   2-METHYLNAPH *               6.5                       9.7                          13.0                          6.8                          6.9            J
                     I-METHYLNAPH*              4.5                       6.1                          6.8                           4.5                          5.0            J
                  2,6-DIMETHNAPH *              18.0                      15.2                         8.2                           8.3                          6.8
                  1,6,7-TRINETHNAPH *           16.4                      8.2                          1.9              J            2.0             J            1.7            J
                    I -METHYLPHEN *             17.0                      5.9                          2.1              J            2.2             J            1.7            J




                                                m-m mm m m m ml@ m m m Im m m
                                                        Mussel Watch Project Year 9 - PAH Data (Tissue)

                                   INVEST#              MBGP                             MBCB                          BRCL                        GBTD                          GBOB
                                          11)     Matagorda Bay                    Matagorda Bay                  Brazos River               Galveston Bay                 Galveston Bay
                                        SITE     Gallinipper Point                Carancahua Bay                  Cedar Lakes                 Todd!s Dump                   Offats Bayou
                              LABSAMNO                  K8024                            K8022                         K8004                       K8000                         K8006
                          SAMPLE TYPE                   SANT                             SAW                           SAW                         SAMP                          SAMP
                                       UNIT             ng/g                             ng/g                          ng/g                        ng/g                          ng/g
                              PNA Analyte               Conc          DB QUAL            Conc         DB QUAL          Conc       MQUAL            Conc        DB QUAL           Conc        DB QUAL


                          RECEIPT DATE                  12/16/93                         12/16/93                      12/09/93                    12/09/93                      12/09/93
                                 QCBATCH                M1410                            M1410                         M1410                       M1410                         M1410
                    EXTRACTION DATE                     07/21/94                         07/21/94                      07/21/94                    07/21/94                      07/21/94
                                   METTIOD              GCMS                             GCMS                          GCMS                        GCMS                          GCMS
                       ANALYSIS DATE                    09/04/94                         09/04/94,                     09/03/94                    09/03/94                      09/04/94
                                   MATRIX               TISSUE                           TISSUE                        TISSUE                      TISSUE                        TISSUE
                                   SUBMAT
                                   WETWT                10.04                            10.05                         10.31                       10.38                         10.22
                                   DRYWT                1.65                             1.30                          1.43                        2.06                          2.03
                                   WTUNITS              GRAMS           DRY              GRAMS           DRY           GRAMS        DRY            GRAMS          DRY            GRAMS         DRY
         N)                    PCTSOLIDS                16.4%                            13.0%                         13.8%                       19.9%                         19.9%
                              Lipid Weight
                                   % LIPIDS             14.69                            11.50                         4.41                        13.00                         12.13
                      Surrogate Recoveries
                                   NAPHD8               50.1                             54.6                          47.3                        54.9                          47.5
                                   ACEND10              57.9                             60.1                          58.6                        60.5                          53.2
                                   PHEND10              59.1                             52.6                          58.4                        65.6                          55.7
                                   CHRYD12              69.8                             67.1                          67.6                        72.8                          66.3
                                   PERYD12              11.4              Q              17.1              Q           14.9           Q            18.7              Q           16.2            Q
                        NAPHTHALENE*                    13.8                             13.9                          17.4                        12.4                          12.5
                    Cl-NAPHTHALENES                     9.7               J              12.2              J           15.8                        14.5                          10.8
                    C2-NAPHTHALENES                     10.8                             27.2                          18.8                        22.2                          22.5
                    C3-NAPHTHALENES                     34.8                             154.0                         60.8                        111.9                         47.8
                    C4-NAPHTHALENES                     28.5                             252.1                         77.8                        134.9                         59.3
                             BIPHENYL                   4.7               J              4.5               J           6.2            J            5.9               J           3.7             J
                    ACENAPHTHYLENE                      1.6               J              10.3                          15.9                        3.5               J           7.7
                      ACENAPHTHENE*                     3.1               J              2.2               J           1.4            J            0.7               J           20.8





                                                       Mussel Watch Project Year 9 - PAH Data (Tissue)

                                  INVEST#              MBGP                             MBCB                         BRCL                        GBTD                         GBOB
                                          ID     Matagorda Bay                   Matagorda Bay                  Brazos River               Galveston Bay                Galveston Bay
                                       SITE     Gallinipper Point                Carancahua Bay                 Cedar Lakes                 Todd!s Dump                  Offats Bayou
                              LABSAMNO                 K8024                            K8022                        K8004                       K8000                        K8006
                          SAMPLE TYPE                  SAMP                             SANT                         SAMP                        SAMP                         SAMP
                                      UNIT             ng/g                             ng/g                         ng/g                        ng/g                         ng/g
                             PNA Analyte               Conc          DB QUAL            Cone         DB QUAL         Conc       DB QUAL          Conc        DB QUAL          Conc        DB QUAL

                            FLUORENE*                  3.1               J              6.1              J           4.2             J           5.4             J            11.8
                         Cl-FLUORENES                  24.1                             42.0                         27.0                        38.7                         37.6
                         C2-FLUORENES                                   ND              124.3                        88.8                        154.7                        117.9
                         C3-FLUORENES                                   ND              216.4                        185.4                       161.0                        144.3
                                                                                                                                                                                           . ....... . .........
                      PHENANTHRENE*                    23.2                             51.3                         20.4                        15.5                         55.7
                         ANTHRACENE*                   6.8                              7.0                          5.9                         9.3                          18.2
                       Cl-PHEN-ANTBR                   23.0                             48.3                         37.9                        81.9                         75.9
                       C2-PHEN-ANTHR                   53.6                             100.6                        74.1                        144.8                        98.6
                       C3-PHEN-ANTHR                   65.4                             93.6                         121.2                       154.3                        115.8
                       C4-PHEN ANTHR                   35.9                             48.4                         64.0                        60.7                         56.0
                           DI13ENZOTHIO                1.6               J              5.9                          2.3             J           2.6                          4.4
                                Cl-DIBEN               4.0               J              19.1                         8.9                         16.0                         7.7
                                C2-DIBEN               24.7                             53.1                         39.0                        49.9                         43.7
                                C3-DIBEN               25.0                             67.7                         60.9                        62.2                         53.5
                      FLUORANTHENE*                    34.6                             78.9                         29.7                        4.5                          165.8
                                PYRENE*                18.2                             45.2                         41.8                        5.9                          117.0
                     Cl-FLUORAN PYR                    21.2                             41.9                         46.8                        21.1                         115.6
                    BENaANTHRACENE *                   5.6                              10.6                         6.6                         1.5                          47.0
                            CHRYSENE *                 13.1                             28.6                         16.0                        9.7                          74.6
                         CI-CIHRYSENES,                5.4               J              7.7              J           22.9                        9.3                          26.9
                         C2-CIHRYSENES                 3.0               J              4.4              J           11.5                        8.3                          16.7
                         C3-CHRYSENES                                   ND                               ND          2.8             J                          ND            2.0             J
                         C4-CHRYSENES                                   ND                               ND          3.2             J                          ND            7.0             J
                I BENb/BENkFLUORAN                     13.9                             15.5                         15.9                        4.3                          69.3
                         BENePYRENE *                  6.3                              7.8                          11.0                        3.7                          31.9
                         BENaPYRENE *                  1.0               J              1.0              J           2.9             J           0.9             J            7.4
                            .PERYLENE*                 23.8                             5.2                          8.0                         2.2             J            5.7
                           1123cdPYRENE                2.2                              1.5                          3.3                         0.9                          9.1
                         DBahANTHRA *                  0.6               J              0.8              J           1.3             J           0.6             J            2.9
                         BghiPERYLENE                  2.8                              1.8              J           7.6                         1.6                          13.0
                            TOTAL PA14s                549.0            0.0             1610.8          0.0          1185.3        0.0           1337.4        0.0            1738.2        0.0
                      S&T Total PAHs (*)               182.7                            326.0                        213.0                       143.4                        617.4





                                                    Mussel Watch Project Year 9 - PAH Data (Tissue)

                                INVEST#           MBGP                            MBCB                         BRCL                      GBTD                       GBOB
                                        ID    Matagorda Bay                   Matagorda Bay                Brazos River              Galveston Bay              Galveston Bay
                                     SITE    Gallinipper Point               Carancahua Bay                Cedar Lakes               Todd's Dump                 Offats Bayou
                            LABSAMNO               K8024                          K8022                        K8004                     K8000                      K8006
                          SAMPLETYPE               SAW                            SAW                          SANT                      SAW                        SAW
                                    UNIT            ng/g                           ng/9                        ng/g                       ng/g                        ng/g
                            PNA Analyte             Conc          DB QUAL          Conc         DBQUAL         Conc       DB QUAL         Conc       DB QUAL          Cone       DB QUAL



                    2-METHYLNAPH                    5.6               J            7.1              J          9.9                        10.8                        6.9
                      I-METHYLNAPH*                 4.1               J            5.1              J          5.9                        3.7                         3.9
                   2,6-DIMETHNAPH *                 7.6                            12.4                        10.4                       12.6                        12.0
                   1,6,7-TRUviETHNAPH *             2.9               J            25.6                        6.5            J           21.0                        6.1
                     1 -METHYLPHEN *                4.5               J            12.8                        7.6                        17.2                        13.5





                                                      Mussel Watch Project Year 9 - PAK Data (Tissue)

                                 INVEST#            GBSC                          SLBB                           CLLC                          VBSP                         CLCL
                                         ID    Galveston Bay                  Sabine Lake                  Calcasieu Lake                Vermillion Bay                Caillou Lake
                                      SITE     Ship Channel                 Blue Buck Point                 Lake Charles                 Southwest Pass                Caillou Lake
                             LABSAMNO               K8002                         K8010                          K8014                         K8040                        K8034
                          SAMPLE TYPE               SAW                           SAMP                           SAW                           SAMP                         SAMP
                                      UNIT          ng1g                          ng/g                           ng1g                          ng/g                         ng/g
                             PNA Analyte            Conc        DB QUAL           Conc         DB QUAL           Conc        DB QUAL           Conc         DB QUAL         Conc      DB QUAL


                         RECEIPT DATE               12/09/93                      12/10/93                       12/10/93                      01/13/94                  01/13/94
                                QCBATCH             M1410                         M1410                          M1410                         M1411                        M1410
                   EXTRACTION DATE                  07/21/94                      07/21/94                       07/21/94                      07/25/94                  07/21/94
                                 METHOD             GCMS                          GCMS                           GCMS                          GCMS                         GCMS
                       ANALYSIS DATE                09/03/94                      09/04/94                       09/04/94                      09/05/94                  09/04/94
                                  MATRIX            TISSUE                        TISSUE                         TISSUE                        TISSUE                    TISSUE
                                 SUBMAT
                                                                                                                                                                                        .. . ...........
                                  WETWT             5.04                          10.06                          10.01                         10.02                        10.04
                                   DRYWT            0.90                          1.54                           2.06                          0.96                         1.33
                                WTUNITS             GRAMS          DRY            GRAMS          DRY             GRAMS          DRY            GRAMS          DRY        GRAMS           DRY
                              PCTSOLIDS             17.8%                         15.3%                          20.6%                         9.5%                         13.2%
                             Lipid Weight
                                % LIPIDS            9.44                          9.66                           12.43                         15.05                        15.01
                     Surrogate Recoveries
                                  NAPHD8            54.7                          47.3                           46.5                          64.2                         54.8
                                ACEND10             61.8                          57.0                           53.6                          60.4                         62.2
                                 PHEND10            54.4                          54.0                           54.8                          55.0                         61.7
                                CHRYD12             69.7                          65.5                           68.4                          61.6                         68.4
                                 PERYD12            12.4            Q             15.7             Q             12.9            Q             25.3                         16.5          Q
                      NAPHTHALENE                   31.1                          16.9                           12.6                          14.9                         19.2
                   CI-NAPHTHALENES                  28.5                          18.1                           18.5                          12.4             J           23.2
                   C2-NAPHTHALENES                  65.3                          25.7                           60.6                          18.6                         32.6
                   C3-NAPHTHALENES                  381.1                         95.7                           315.5                         47.5                         72.9
                   C4-NAPHTTIALENES                 988.2                         198.3                          626.8                         73.4                         81.1
                            BIPHENYL                11.6             J            6.7              J             8.6                           9.4              J           5.7           J
                   ACENAPHTHYLENE                   27.6                          7.5                            6.4                           1.4              J           1.2           J
                     ACENAPHTHENE*                  8.4              J            3.3              J             10.4                          2.3              J           2.9           J



                                     mmm mmm M,mm M M M M M M M
                                                        Mussel Watch Project Year 9 - PAH Data (Tissue)

                                  RqVEST#             GBSC                           SLBB                           CLLC                            VBSP                         CLCL
                                          ID    Galveston Bay                   Sabine Lake                   Calcasieu Lake                 Vermillion Bay                 Caillou Lake
                                        SITE     Ship Channel                 Blue Buck Point                  Lake Charles                  Southwest Pass                 Caillou Lake
                              LABSAMNO                K8002                          K801 0                         K8014                           K8040                        K8034
                          SAMPLE TYPE                 SANT                           SAW                            SAMP                            SAW                          SAW
                                       UNIT           ng/9                           ng/g                           ng/g                            ngIg                         ng/g
                              PNA Analyte             Conc        DB QUAL            Conc         DD QUAL           Conc         DB QUAL            Conc         DB QUAL         Conc       DB QUAL

                             FLUORENE*                7.6              J             4.4               J            14.9                            4.7                J         5.7             J
                         CI-FLUORENES                 121.1                          35.1                           87.1                            33.3                         40.5
                         C2-FLUORENES                 555.7                          156.0                          450.1                           85.5                                        ND
                         C3-FLUORENES                 1103.1                         241.2                          555.0                           211.2                                       ND
                     PHENANTHRENE                     49.6                           27.9                           43.4                            25.2                         22.9
                         ANTHRACENE*                  31.5                           16.0                           25.4                            1.8                          2.6
                       CI-PHEN-ANTUR                  197.1                          77.7                           191.3                           24.4                         34.0
                       C2-PHEN-ANTHR                  700.0                          186.7                          606.1                           54.5                         62.9
                       C3-PHEN-ANTHR                  2296.9                         260.0                          775.6                           55.4                         63.6
                       C4-PBEN ANTHR                  2063.8                         112.8                          394.5                           34.8                         24.7
                           DIBENZOTFHO                11.1                           2.4               J            13.7                            3.7                J         1.9             J
                                CI-DIBEN              102.4                          25.4                           65.2                            14.5                         10.9
                                C2-DIBEN              274.2                          108.6                          277.7                           32.5                         31.3
                                C3-DIBEN              1011.0                         152.6                          390.1                           40.9.                        26.9
                      FLUORANTBENE*                   164.3                          37.5                           201.8                           13.6                         11.9
                                PYRENE*               453.2                          44.6                           291.8                           16.4                         14.0
                     CI-FLUORAN PYR                   1008.9                         67.4                           300.0                           27.7                         14.8
                     BENaANTHRACENE*                  65.0                           5.8                            19.6                            1.2                J         2.2             J
                             CHRYSENE*                238.2                          17.9                           90.1                            4.9                J         4.2
                         Cl-CHRYSENES                 466.8                          19.1                           83.1                            4.2                J         3.7             J
                         C2-CHRYSENES                 394.6                          20.7                           58.6                            10.4               J         5.6             J
                         C3-CHRYSENES                 23.5                           3.5               J            3.2               J                              ND                         ND
                         C4-CHRYSENES                 12.0             J             3.7               J            4.3              J                               ND                         ND
                I BENb/BENkFLIJORAN                   219.2                          9.8                            26.1                            2.4                          3.4
                         BENePYRENE *                 207.8                          10.0                           27.2                            2.1                J         2.4
                         BENaPYRENE *                 22.4                           1.3               J            5.4                             0.4                J         0.7
                             'PERYLENE*               66.5                           21.8                           27.4                            6.7                          8.4
                           1123cdPYRENE               10.1                           1.2                            4.5                             0.3                J         0.6
                         DBahANTHRA *                 7.4                            1.2               J            3.8                             0.1                J         0.4
                         BghiPERYLENE                 39.9                           2.9                            6.2                             0.5                1         1.2
                             TOTALPAHs                13466.4        0.0             21047.2         0.0            6102.7          0.0             892.8           0.0          640.0          0.0
                      S&T Total PAHs (*)              1477.3                         275.1                          931.6                           145.7                        160.3





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                                  INVEST#           GBSC                           SLBB                          CLLC                          VBSP                         CLCL
                                         ID    Galveston Bay                  Sabine Lake                  Calcasieu Lake                Vermillion Bay                Caillou Lake
                                       SITE     Ship Channel                Blue Buck Point                 Lake Charles                 Southwest Pass                Caillou Lake
                              LABSAMNO              K8002                          K8010                         K8014                         K8040                        K8034
                          SAMPLE TYPE               SAMP                           SAMP                          SAMP                          SAMP                         SAMP
                                      UNIT          ng/9                           ng/g                          ng/g                          ng/9                         ng/g
                             PNA Analyte            Conc         DB QUAL           Conc        DB QUAL           Conc         DB QUAL          Conc         DB QUAL         Conc       DB QUAL



                     2-METHYLNAPH                   15.5                           11.9                          10.1                          7.5               J          14.9
                       I-METHYLNAPH*                13.0                           6.2                           8.5                           4.9               J          8.4
                    2,6-DIMET14NAPH *               17.8                           10.2                          22.1                          11.6                         16.0
                    1,6,7-TRMETHNAPH *              32.1                           14.2                          54.6                          13.0                         10.7
                      I-METHYLPHEN *                34.5                           17.4                          54.0                          5.0               J          7.2




                                                          mmm mmm m1m mm m m m m
                                                          Mussel Watch Project Year 9 - PAH Data (Tissue)

                               INVEST#              TBLF                            MRPL                          BSSI                        BSSI                           LBMP
                                        ID   Terrebonne Bay                  Mississippi River               Breton Sound                Breton Sound                   Lake Borgne
                                     SITE      Lake Felicity                   Pass a Loutre                  Sable Island                Sable Island                Matheureux Point
                            LABSAMNO                K8036                           K8042                         K8038                       K8038                          K8044
                        SAMPLE TYPE                 SAW                             SAMP                          SAMP                        SAMP                           SAMP
                                    UNIT            n919                            ng/g                          ng/9                        ng/g                           ng/g
                           PNA Analyte              Cone         DBQUAL             Cone         DB QUAL          Cone        DB QUAL         Cone        DB QUAL            Cone          DB QUAL


                       RECEIPT DATE                 01/13/94                        01/15/93                      01/15/93                    01/15/93                       01/15/93
                              QCBATCH               M1410                           M1411                         M1411                       M1411                          M1411
                 EXTRACTION DATE                    07/21/94                        07/25/94                      07/25/94                    07/25/94                       07/25/94
                               METHOD               GCMS                            GCMS                          GCMS                        GCMS                           GCMS
                     ANALYSIS DATE                  09/04/94                        09/05/94                      09/05/94                    09/05/94                       09/05/94
                               MATRIX               T`ISSUE                         TISSUE                        TISSUE                      TISSUE                         TISSUE
                               SUBMAT
                                 WETWT              10.01                           10.05                         10.03                       10.03                          10.03
                                 DRYWT              1.82                            0.46                          0.75                        0.75                           0.87
                               WTUNITS              GRAMS           DRY             GRAMS           DRY           GRAMS         DRY           GRAMS         DRY              GRAMS            DRY
        00                   PCTSOLIDS              18.2%                           4.5%                          7.4%                        7.4%                           8.6%
                            Lipid Weight
                               % LIPIDS             13.19                           11.53                         17.40                       17.40                          15-57
                    Surrogate Recoveries
                               NAPHD8               62.1                            63.8                          63.8                        63.8                           61.4
                               ACEND10              65.5                            60.5                          57.7                        57.7                           63.5
                               PHEND10              63.8                            61.5                          61.1                        61.1                           59.8
                               CHRYD12              66.5                            59.6                          56.9                        56.9                           63.4
                               PERYD12              5.4              Q              18.9              Q           19.1             Q          19.1            Q              21.2
                    NA,PHTIIALENE *                 12.1                            29.3                          26.2                        26.2                           21.6
                 Cl-NAPHTHALENES                    10.3                            39.0                          27.3                        27.3                           14.4
                 C2-NAPHTHALENES                    9.9                             72.9                          83.2                        83.2                           13.7
                 C3-NAPHTHALENES                    18.2                            192.0                         282.3                       282.3                          44.2
                 C4-NAPHTHALENES                    21.8                            278.7                         468.4                       468.4                          47.6
                           BIPHENYL                 4.5              J              9.0               J           15.5             J          15.5            J              8.2
                 ACENAPHTHYLENE                     0.9              1              5.6               J           3.6              J          3.6             J              1.0               J
                   ACENAPHTHENE                     3.0              J              1.1               J           5.0              J          5.0             J              1.6               J--J





                                                         Mussel Watch Project Year 9 - PAH Data (Tissue)

                                INVEST#             TBLF                            MRPL                          BSSI                        BSSI                           LBMP
                                        ED   Terrebonne Bay                  Mississippi River               Breton Sound                Breton Sound                   Lake Borgne
                                     SITE      Lake Felicity                   Pass a Loutre                  Sable Island                Sable Island                Malheureux Point
                            LABSAMNO                K8036                           K8042                         K8038                       K8038                          K8044
                        SAMPLE TYPE                 SAW                             SAMP                          SAMP                        SAMP                           SAMP
                                    UNIT            ng/g                            ng/g                          ng/g                        ng/g                           ng/g
                           PNA Analyte              Conc         DB QUAL            Conc         DB QUAL          Conc       DB QUAL          Conc        DB QUAL            Conc          DB QUAL

                          FLUORENE*                 3.5              J              10.5              J           16.5                        16.5                           6.0                 J
                       Cl-FLUORENES                 12.7             J              87.1                          106.6                       106.6                                              ND
                       C2-FLUORENES                                 NI)             230.7                         251.9                       251.9                                              ND
                       0-FLUORENES                                  ND              551.7                         502.0                       502.0                                              ND
                                                                                                                                                                                   . . . ...... .
                  PBENANTFRENE                      27.8                            30.3                          67.6                        67.6                           11.6
                       ANTHRACENE*                  2.7              J              4.7               J           6.8              J          6.8               J            1.3                 J
                    CI-PHEN-ANTHR                   10.9                            97.9                          183.9                       183.9                          28.2
                    C2-PHEN-ANTBR                   30.9                            549.1                         627.1                       627.1                          39.7
                    C3-PHEN-ANTHR                   25.9                            801.4                         464.8                       464.8                          49.8
                    C4-PHEN ANTHR                   11.0                            612.3                         297.7                       297.7                          31.5
                         DIBENZOTFHO,               1.3              J              4.6               J           9.5                         9.5                            5.6
        @0                    CI-DIBEN              4.4                             53.0                          54.6                        54.6                           6.6                 J
                              C2-DlBEN              12.7                            306.4                         261.2                       261.2                          19.5
                              C3-DIBEN              13.1                            633.0                         347.6                       347.6                          20.8
                   FLUORANTHENE *                   10.7                            58.0                          59.9                        59.9                           7.0
                              PYRENE*               7.8                             125.9                         82.1                        82A                            5.8
                   Cl-FLUORAN PYR                   8.4                             168.4                         119.3                       119.3                          16.1
                   BENaANTHRACENE*                  2.1                             23.5                          11.5                        11.5                           1.1                 J
                          CHRYSENE*                 6.5                             72.0                          63.2                        63.2                           4.5                 J
                       CI-CHRYSENES,                2.9              J              82.4                          63.0                        63.0                           2.7                 J
                       C2-CHRYSENES                 3.4              J              86.0                          36.1                        36.1                           6.2                 J
                       C3-CHRYSENES                                 ND                              ND                           ND                           ND                                 ND
                       C4-CHRYSENES                                 ND                              ND                           ND                           ND                                 ND
              I BENb/BET-ULUORAN                    4.5                             58.3                          19.7                        19.7                           1.9
                       BENePYRENE *                 2.3                             48.1                          20.1                        20.1                           2.0                 1
                       BENaPYRENE, *                0.5              J              4.5               J           2.0              J          2.0               J            0.3                 J
                          PERYLENE*                 10.3                            191.5                         43.0                        43.0                           4.6                 J
                         1123cdPYRENE               0.5              J              7.2                           1.8              J          1.8               J            0.2                 J
                       DBahANTHRA                   0.4              J              2.6               J           0.8              J          0.8               J            0.1                 J
                       BghiPERYLENE                 1.0              J              14.5                          2.7              J          2.7               J            0.6                 J
                          TOTAL PAHs                299.2           0.0             5543.0          0.0           4634.5         0.0          4634.5         0.0             425.8           [email protected]
                    S&T Total PAHs                  115.3                           747.0                         592.3                       592.3                          104.4




                                                        mmmimm mmm mm m " m m
                                                     Mussel Watch Project Year 9 - PAH Data (Tissue)

                               INVEST#            TBLF                         MRPL                           BSSI                       BSSI                         LBMP
                                      ID    Terrebonne Bay                Mississippi River              Breton Sound               Breton Sound                   Lake Borgne
                                    SITE     Lake Felicity                  Pass a Loutre                 Sable Island               Sable Island               Malheureux Point
                           LABSAMNO               K8036                        K8042                          K8038                      K8038                        K8044
                       SAMPLE TYPE                SAW                          SAW                            SAW                        SANT                         SAMP
                                   UNIT           ng/g                          ng/g                          ng/g                       ng/g                          ng/g
                          PNA Analyte             Cone        DB QUAL           Conc          DB QUAL         ConC       DB QUAL         Conc       DB QUAL            Conc          DB QUAL



                  2-METHYLNAPH                    5.7                           23.5                          16.4                       16.4                          7.8                J
                    I-METHYLNAPH*                 4.7                           15.5                          10.9                       10.9                          6.6                J
                 2,6-DIMETHNAPH *                 6.7                           34.3                          43.3                       43.3                          5.4                J
                1,6,7-TPJMETHNAPH *               1.9              J            36.9                          47.0                       47.0                          5.8                J
                   I-METHYLPHEN *                 2.0              J            26.0                          54.5                       54.5                          3.2                J





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                             INVEST#           LBNO                          MSPC                           MSPB                           MBCP                              MBHI
                                     ID   Lake Borgne                Mississippi Sound              Mississippi Sound                  Mobile Bay                        Mobile Bay
                                  SITE    New Orleans                  Pass Christian                 Pascagoula Bay                Cedar Point Reef                Hollingers Is. Channel
                         LABSAMNO              K8046                         K8052                          K8054                          K8048                             K8050
                     SAMPLE TYPE               SAW                           SAMP                           SAMP                           SANT                              SAMP
                                 UNIT          ng1g                          ng/g                           ng/g                           ng/g                              ng/g
                        PNA Analyte            Conc       DB QUAL            Conc         DB QUAL           Conc         DB QUAL           Conc         DB QUAL              Conc             DB QUAL


                    RECEIPT DATE             01/15/93                        01/16/94                    01/16/94                          01/16/94                        01/16/94
                           QCBATCH             M1411                         M1411                          M1411                          M1411                             M1411
              EXTRACTION DATE                07/25/94                        07/25/94                    07/25/94                                                          07/25/94
                            METHOD             GCMS                          GCMS                           GCMS                           GCMS                              GCMS
                  ANALYSIS DATE              09/05/94                        09/05/94                    09/05/94                          09/05/94                        09/05/94
                             MATRIX          TISSUE                          TISSUE                      TISSUE                            TISSUE                          TISSUE
                             SUBMAT                                                                                                                                                       . ............. . ...... .
                              WETWT            10.02                         10.01                          10.02                          10.02                             10.03
                              DRYWT            0.92                          1.29                           0.83                           1.64                              1.26
       tQ                   W1`UNITS         GRAMS           DRY             GRAMS          DRY          GRAMS             DRY             GRAMS           DRY             GRAMS                DRY
                         PCTSOLIDS             9.2%                          12.9%                          8.2%                           16.4%                             12.6%
                        Lipid Weight
                           % LIPIDS            17.06                         12.58                          11.65                          20.34                             14.78 . . ......
                 Surrogate Recoveries
                             NAPHD8            46.1                          64.2                           51.7                           59.6                              48.2
                            ACEND10            49.2                          61.1                           59.9                           56.4                              54.6
                            PHEND10            44.6                          53.4                           55.1                           54.2                              52.0
                            CHRYD12            44.7                          62.1                           66.6                           64.8                              63.8
                            PERYD12            16.4             Q            25.8                           22.2                           27.6                              21.5         . ...... . .......
                  NAPHTHALENE*                 28.5                          20.4                           134.0                          28.5                              19.1
              Cl-NAPHTHALENES                  17.0             J            15.7                           186.2                          36.7                              19.9
              C2-NAPHTHALENES                  23.7                          10.7             J             142.9                          39.8                              52.7
              C3-NAPHTHALENES                  40.1                          30.1                           210.2                          54.8                              112.3
              C4-NAPHTHALENES                  51.5                          28.2                           239.9                          49.4                              122.7
                       BIPHENYL                6.9              J            7.4              J             11.4             J             7.8               J               6.3
              ACENAPHTHYLENE                   0.9              J            3.0              J             8.5              J             2.6               J               2.9                  J
                 ACENAPHTHENE*                 4.4              J            7.6                            16.9                           4.8               J               5.2                  J





                                                       Mussel Watch Project Year 9 - PAH Data (Tissue)

                             INVEST#           LBNO                          MSPC                           MSPB                           MBCP                               MBHI
                                     DD   Lake Borgne                Mississippi Sound              Mississippi Sound                  Mobile Bay                        Mobile Bay
                                  SITE    New Orleans                  Pass Christian                 Pascagoula Bay                Cedar Point Reef                Hollingers Is. Channel
                         LABSAMNO              K8046                         K8052                          K8054                          K8048                              K8050
                     SAMPLE TYPE               SAMP                          SANT                           SAMP                           SAMP                               SAMP
                                 UNIT          ng/g                          ng/g                           ng1g                           ng/g                               ng/g
                        PNA Analyte            Conc        DB QUAL           Conc         DB QUAL           Conc         DB QUAL           Conc         DB QUAL               Conc            DB QUAL

                       FLUORENE*               7.1              J            11.4                           25.9                           12.0                               9.2                   J
                    Cl-FLUORENES                              ND             18.8                           56.3                           31.9                               40.8
                    C2-FLUORENES                              ND             49.1                           159.0                          62.0                               115.4
                    C3-FLUORENES                              ND             115.6                          381.3                          183.9                              296.7     . ... . ........... . ...... . .........
                PHENANTHUNE *                  21.0                          53.7                           126.1                          41.0                               54.9
                    ANTHRACENE*                2.7              J            5.7              J             10.3                           5.1                                8.9
                 Cl-PHEN-ANTBR                 34.7                          41.6                           186.9                          64.3                               87.9
                 C2-PHEN-ANTHR                 69.0                          48.9                           405.4                          91.3                               208.2
                 C3-PHEN-ANTHR                 61.8                          52.4                           368.2                          85.2                               141.3
                 C4-PHEN ANT14R                34.2                          57.6                           255.7                          49.4                               174.9                 ....... .. . ........
                      DIBENZOTHIO              5.2                           6.9                            16.0                           4.9                                8.6
                           Cl-DIBEN            9.3                           14.0                           23.5                           12.1                               36.1
                           C2-DIBEN            22.5                          42.4                           135.0                          56.5                               204.6
                           C3-DIBEN            20.1                          45.8                           143.0                          51.8                               162.4
                 FLUORANTHENE*                 16.4                          47.4                           227.3                          38.3                               170.8
                           PYRENE*             19.2                          34.4                           177.2                          24.9                               157.1
                Cl-FLUORAN PYR                 21.5                          37.2                           168.1                          36.2                               123.4
               BENaANTHRACENE *                1.8              J            7.5                            31.4                           2.4                                15.6
                       CHRYSENE*               6.3              J            22.7                           58.1                           11.8                               53.4
                    Cl-CHRYSENES.              3.8              J            7.3              1             22.8                           4.4                J               17.1
                    C2-CHRYSENES               7.9              J            7.4              J             13.8             J             9.1                J               18.2
                    C3-CHRYSENES                              ND                              ND                            ND                              ND                1.5                   J
                    C4-CHRYSENES                              ND                              ND                            ND                              ND                4.0                   J
           I BENb/13ENkFLUORAN                 3.0                           9.3                            24.9                           3.6                                23.3
                    BENePYRENE *               2.9                           5.7                            12.7                           3.5                                18.4
                    BENaPYRENE *               0.2              J            0.9              J             2.1              J             0.2                J               1.5                   J
                       PERYLENE*               2.3              J            2.7              J             9.2                            1.8                J               9.1
                      I123cdPYRENE             0.9              J            1.0              J             2.3                            0.4                J               1.4                   J
                    DBahANTHRA *               0.2              J            0.3              J             0.5              J             0.1                J               0.6                   J
                    BghiPERYLENE               1.1              1            1.6              J             3.3              J             1.0                J               3.2
                       TOTALPAHs               548.0          0.0            872.6           0.0            3996.1         0.0             1113.2           0.0             2509.8               0.0
                 S&T Total PAHs (*)            155.0                         265.4                          1175.7                         267.8                              615.5




    M@m @.Om@mml mom mewww'" mmmm
                                                    Mussel Watch Project Year 9 - PAH Data (Tissue)

                            INVEST#         LBNO                          MSPC                          MSPB                         MBCP                               MBHI
                                   ID   Lake Borgne               Mississippi Sound              Mississippi Sound                Mobile Bay                        Mobile Bay
                                 SITE   New Orleans                  Pass Christian               Pascagoula Bay                Cedar Point Reef              Hollingers Is. Channel
                        LABSAMNO            K8046                         K8052                         K8054                        K8048                              K8050
                    SAMPLE TYPE             SAW                           SAMP                          SAMP                         SAMP                               SAMP
                                UNIT         ng/g                         ng/9                          ng/g                          ng/g                              ng/g
                       PNA Analyte           Conc       DB QUAL           Conc        DB QUAL           Conc         DB QUAL          Conc         DB QUAL              Conc           DB QUAI



               2-METHYLNAPH *                9.7             J            9.6                           121.6                         24.6                              11.7
                 I-METHYLNAPH*               7.4             J            6.1                           64.6                          12.0                              8.3
              2,6-DUvETHNAPH *               10.3                         6.9                           57.5                          25.6                              21.6
              1,6,7-TTUNETHNAPH *            4.6             J            4.9              J            40.7                          10.6                              20.0
                I-METHYLPHEN *               3.3             J            10.0                          48.3                          12.9                              23.8




                                                          m m m m m-m m m1m @ M,
                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                           INVEST#            PBPH                          PBIB                           CBJB                             CBBL                               CBPP
                                   ID,  Pensacola Day                 Pensacola Bay               Choctawhatchee Bay               Choctawhatchee Bay                 Choctawhatchee Bay
                                SITE     Public Harbor                 Indian Bayou                    Joe's Bayou                      Ben's Lake                         Postil Point
                       LABSAMNO               K8058                         K8056                          K8066                            K8064                              K8060
                   SAMPLE TYPE                SAMP                          SAMP                           SANT                             SAMP                               SAMP
                               UNIT           ng/g                          ng/g                           ng/g                             ng/g                               ng/g
                      PNA Analyte             Conc         DB QUAL          Conc        DB QUAL            Conc          DB QUAL            Conc          DB QUAL              Conc            DB QUAL

                  RECEIPT DATE                01A7/94                       01/17/94                       01/19/94                         01/19/94                         01/17/94
                         QCBATCH              M1411                         M1411                          M1411                            M1411                              M1411
            EXTRACTION DATE                   07/25/94                      07/25/94                       07/25/94                         07/25/94                         07/25/94
                           METHOD             GCMS                          GCMS                           GCMS                             GCMS                               GCMS
                ANALYSIS DATE                 09/06/94                      09/05/94                       09/06/94                         09/06/94                         09/06/94
                           MATRIX             TISSUE                        TISSUE                         TISSUE                           TISSUE                           TISSUE
                           SUBMAT
                           WETWT              10.05                         10.01                          10.04                            10.03                              10.03
                           DRYWT              1.41                          0.67                           0.84                             0.94                               1.14
                           WTUNITS,           GRAMS          DRY            GRAMS         DRY              GRAMS            DRY             GRAMS            DRY             GRAMS               DRY
                        PCTSOLD:)S            14.1%                         6.7%                           8.4%                             9.4%                               11.4%
                      Lipid Weight
                           % LIPIDS           1920                          12.90                          9.42                             5.87                               12.23
               Surrogate Recoveries
                           NAPHD8             45.1                          56.1                           50.3                             57.6                               45.7
                           ACEND10            47.0                          60.3                           58.7                             61.1                               56.9
                           PHEND10            46.1                          61.8                           58.1                             57.4                               56.4
                           CHRYD12            53.7                          70.1                           65.7                             61.3                               60.2
                           PERYD12            22.4                          22.9                           24.0                             27.9                               18.1                Q
                NAPHTHALENE*                  20.6                          35.0                           55.0                             27.4                               27.4
            Cl-NAPHTHALENES                   22.0                          40.8                           72.9                             28.2                               36.1
            C2-NAPHTHALENES,                  26.3                          29.2                           76.7                             29.7                               49.5
            C3-NAPHTHALENES                   48.2                          55.8                           118.5                            38.5                               88.0
            C4-NAPHTHALENES                   56.4                          41.6                           123.0                            15.7                               120.4
                     BIPHENYL                 8.5                           11.1                           10.7                             6.8                                6.1
            ACENAPHTHYLENE                    3.0                           2.7                            7.5                              1.3                                3.2
              ACENAPHTHENE*                   7.9                           4.9                            62.3                             14.9                               11.3




    M MM M MM M M M Mao MM am m;m M M M
                                                      Mussel Watc                h Project Year 9 - PAH Data (Tissue)

                           INVEST#             PBPH                         PBIB                           CBJB                              CBBL                              CBPP
                                   ID    Pensacola Bay                Pensacola Bay               Choctawhatchee Bay               Choctawhatchee Bay                 Choctawhatchee Bay
                                SITE     Public Harbor                 Indian Bayou                    Joe's Bayou                       Ben's Lake                        Postil Point
                       LABSAMNO                K8058                        K8056                          K8066                             K8064                             K8060
                   SAMPLE TYPE                 SANT                         SANT                           SAMP                              SAMP                              SAMP
                               UNIT            ng/g                         ng/g                           ng/g                              ng/g                              ng/g
                      PNA Analyte              Conc        DB QUAL          Conc        DB QUAL            Conc          DB QUAL             Conc         DB QUAL              Conc            DB QUAL

                      FLUORENE*                12.2                         12.0             J             58.1                              14.1                              13.2
                   Cl-FLUORENES                26.8                                        ND              44.3                              12.7               J              39.1
                   C2-FLUORENES                89.3                                        ND              104.9                             35.9                              175.3
                   O-FLUORENES                 158.0                                       ND              263.6                                             ND                575.9
                                                                                                                                                                                              ...........
              PHENANTHRENE                     55.4                         35.6                           134.8                             46.9                              61.9
                   ANTHRACENE*                 7.3                          4.6              J             21.1                              4.7                J              14.6
                Cl-PHEN-ANTHR                  44.1                         29.5                           117.1                             31.2                              187.5
                C2-PHEN-ANTHR                  74.6                         49.1                           211.3                             49.3                              746.2
                C3-PHEN-ANTHR                  71.8                         51.2                           231.2                             63.2                              688.8
                C4-PHEN ANTHR                  75.8                         30.8                           160.7                             123.6                             439.8
                   DIBENZOTHIO                 4.2                          3.1              J             15.9                              3.9                J              7.6
                         Cl-DIBEN              10.7                         8.0              J             24.6                              5.6                J              31.8
                         C2-DIBEN              38.9                         14.3                           118.2                             21.3                              437.1
                         O-DIBEN               53.9                         18.2                           159.1                             25.9                              681.4
               FLUORANTHENE*                   99.1                         47.0                           458.6                             98.7                              101.2
                         PYRENE*               51.7                         27.5                           382.0                             55.6                              86.1
              Cl-FLUORAN PYR                   62.9                         37.3                           236.5                             41.3                              197.4
             BENaANTHRACENE *                  13.3                         5.4                            88.1                              11.1                              21.5
                      CHRYSENE*                44.2                         18.0                           268.9                             34.3                              61.0
                   Cl-CHRYSENES                11.5                         7.0              J             65.0                              13.3               J              60.0
                   C2-CHRYSENES                8.5             J            8.2              J             26.1                              8.1                J              44.5
                   O-CHRYSENES                                ND                           ND              4.4                J                              ND                4.0                  J
                   C4-CHRYSENES                               ND                           ND              12.9               J                              ND                5.9
         I BENb/BENkFLUORAN                    2.72                         16.4                           227.9                             2.92                              24
                   BENePYRENE *                11.2                         7.9                            94.3                              11.1                              19.1
                   BENaPYRENE *                1.0             J            1.9              J             17.8                              1.8                J              3.5                  J
                      PERYLENE*                2.9             J            4.0              J             15.9                              2.6                J              8.6
                   1123cdPYRENE                1.0             J            3.0                            30.2                              3.0                               3.2
                   DBahANTHRA                  0.4             J            0.5              J             7.0                               0.6                J              1.5                  J
                   BghiPERYLENE                1.8             J            4.1              J             43.1                              5.1                               7.2
                      TOTALPAHs                1225.2        0.0            665.3          0.0             4170.3           0.0              887.3           0.0              5066.8             0.0
                S&T Total PAHs                 390.3                        283.6                          1825.7                            382.5                             545.2





                                                    Mussel Watch Project Year 9 -1 PAH Data (Tissue)

                          INVEST#            PBPH                        PBIB,                         CBJB                             CBBL                              CBPP
                                  ID   Pensacola Bay                Pensacola Bay              Choctawhatchee Bay              Choctawhatchee Bay                Choctawhatchee Bay
                               SITE    Public Harbor                Indian Bayou                    Joe's Bayou                     Ben's Lake                        Postil Point
                      LABSAMNO               K8058                       K8056                         K8066                            K8064                             K8060
                  SAMPLE TYPE                SAMP                        SAMP                          SAMP                             SAND                              SAMP
                              UNIT           ng/9                        ng/g                          ng/g                             ng/g                              ng/g
                     PNA Analyte             Conc        DB QUAL         Conc        DB QUAL           Conc          DB QUAL            Conc         DBQUAL               Conc           DB QUAL



              2-MEETHYLNAPH *                12.8                        21.5                          41.8                             15.6                              20.9
               I-METHYLNAPH*                 9.2                         19.4                          31.1                             12.6                              15.2
             2,6-DINET'HNAPH *               11.8                        13.3                          29.4                             9.7                               15.7
            1,6,7-TRIMETHNAPH *              7.4             J           7.8             J             17.5                             6.5               J               10.2
              I-METHYLPHEN *                 13.7                        6.5             J             31.1                             7.6              J                46.3




                                               M M MM M MAW @ M M MIM M M M
                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                              INVEST#                 CBBB                               PCLO                           AESP                       CKBP                        TBOT
                                       ID    Choctawhatchee Bay                      Panama City                  Apalachee Bay                 Cedar Key                  Tampa Bay
                                    SITE         Boggy Bayou                      Little Oyster Bar                Spring Creek                Black Point               Old Tampa Bay
                           LABSAMNO,                  K8062                              K8068                          K8070                      K8072                       K8080
                       SAMPLE TYPE                    SAW                                SAMP                           SAMP                       SAMP                        SAMP
                                   UNIT               ng/g                               ng/g                           ng/g                       ng/g                        ng/g
                          PNA Analyte                 Conc             DB QUAL           Conc         DB QUAL           Conc        DB QUAL        Conc      DB QUAL           Conc        DB QUAL


                      RECEIPT DATE                    01/17/94                           01/19/94                       01/20/94                   01/20/94                  01/21/94
                              QCBATCH                 M1411                              M1411                          M1411                      M1411                       M1412
                EXTRACTION DATE                       07/25/94                           07/25/94                       07/25/94                   07/25/94                  08/01/94
                              METHOD                  GCMS                               GCMS                           GCMS                       GCMS                        GCMS
                    ANALYSIS DATE                     09/06/94                           09/06/94                       09/06/94                   09/06/94                  09/05/94
                              MATRIX                  TISSUE                             TISSUE                         TISSUE                     TISSUE                    TISSUE
                              SUBMAT
                                WETWT                 10.02                              10.42                          10.00                      10.00                       10.27
                                DRYWT                 1.11                               0.71                           0.71                       0.79                        0.80
       ND                     WTUNITS                 GRAMS              DRY             GRAMS          DRY             GRAMS         DRY          GRAMS        DRY          GRAMS           DRY
                            PCTSOLIDS                 11.1%                              6.8%                           7.0%                       7.9%                        7.8%
                          Lipid Weight.
                              % LIPIDS                14.70                              32.15                          12.17                      9.04                        3.77
                                                                                                                                                                                           .. . .......
                   Surrogate Recoveries
                              NAPHD8                  57.6                               56.3                           43.9                       58.4                        47.3
                              ACENDIO                 61.8                               60.4                           52.6                       57.7                        52.1
                              PHENDIO                 68.3                               60.2                           49.1                       60.5                        56.6
                              CHRYD12                 74.0                               73.9                           59.9                       63.1                        62.6
                              PERYD12                 16.1                 Q             27.8                           23.3                       30.1                        22.5
                   NAPHTHALENE *                      31.6                               35.5                           71.8                       50.9                        28.6
                Cl-NAPHTHALENES                       36.7                               32.4                           63.7                       37.1                        31.8
                C2-NAPHTHALENES                       42.0                               30.4                           34.1                       28.1                        31.6
                C3-NAPHTHALENES                       59.3                               47.5                           46.4                       44.7                        59.0
              _C4-NAPHTHALENES                        60.1                               56.7                           54.1                       26.3           J            35.0
                          BIPHENYL *                  8.0                  J             10.5             J             11.5            J          11.8           J            8.2              J
                ACENAPHTHYLENE,                       8.6                  J             4.4              J             1.4             J          0.5            J            1.6              J
                  ACENAPHTHENE                        26.1                               4.8              J             1.7             J          2.3            J            3.9              J





                                                    Mussel Watch Project Year 9 - PAH Data (Tissue)

                             INVEST#                CBBB                             PCLO                         AESP                       CKBP                      TBOT
                                     ID    Choctawhatchee Bay                   Panama City                 Apalachee Bay                Cedar Key                 Tampa Bay
                                  SITE        Boggy Bayou                     Little Oyster Bar              Spring Creek               Black Point              Old Tampa Bay
                         LABSAMNO                   K8062                            K8068                        K8070                      K8072                     K8080
                      SANTLE, TYPE                  SAMP                             SANT                         SANT                       SAMP                      SAMP
                                 UNIT               ng/g                             ng/g                         ng/g                       ng/g                      ng/g
                         PNA Analyte                Conc           DB QUAL           Conc         DB QUAL         Conc        DB QUAL        Conc     DB QUAL          Conc       DB QUAL


                        FLUORENE*                   27.7                             17.2                         9.4               J        6.6           J           8.1              J
                      Cl.-FLUORENES                 30.7                             32.5             J                         ND           13.4          J           23.2             J
                      C2-FLUORENES                  76.0                             92.9                                       ND           46.6                                    ND
                      C3-FLUORENES                  165.4                            264.3                                      ND           75.7                                    ND
                  PHENANTHRENE*                     98.7                             114.3                        21.2                       17.9                      39.7
                      ANTHRACENE*                   15.4                             11.4             J           2.1               J        1.4           J           4.2              J
                  Cl-PHEN-ANTHR                     82.5                             78.5                                       ND           15.9          J           50.3
                  C2-PHEN-ANTBR                     111.0                            87.6                                       ND           30.4                      49.0
                  C3-PHEN-ANTHR                     94.2                             108.4                                      ND           22.7                      80.3
                  C4-PHEN ANTHR                     107.3                            94.8                                       ND           14.8          1           31.5
                      DIBENZOTHIO                   7.9                              7.2                          2.4               J        1.8           J           2.6              J
                           Cl-DIBEN                 15.8                             11.5                                       ND                       ND            4.9              J
                           C2-DIBEN                 44.0                             60.2                                       ND                       ND            16.8
                           C3-DIBEN                 54.6                             41.5                                       ND                       ND            21.0
                 FLUORANTHENE *                     194.8                            246.8                        26.0                       12.9                      87.6
                           PYREM *                  128.3                            116.4                        11.9                       7.3                       57.2
                 Cl-FLUORAN PYR                     105.7                            72.1                         18.6                       12.5                      24.4
                 BENaANTHRACENE*                    32.6                             10.9                         3.3               J        1.5           J           7.1
                        CHRYSENE*                   83.2                             100.0                        8.3               J        5.1           J           28.8
                      Cl-CBRYSENES                  34.6                             22.0                         9.6               J                    ND            7.0              J
                      C2-CHRYSENES                  15.6                             11.3             J           11.5              J                    ND            6.5              J
                      C3-CHRYSENES                  2.2                J                             ND                         ND                       ND                          ND
                      C4-CHRYSENES                  10.7               J                             ND                         ND                       ND                          ND
            I BENb/BENkFLUORAN                      49.4                             51.5                         8.2                        3.1                       19.9
                      BENePYRENE *                  25.6                             24.9                         4.5                        2.4           J           11.4
                      BENaPYRENE, *                 6.0                              2.0              J           1.2               J        0.5           J           1.3              J
                        PERYLENE*                   12.0                             2.6              J           2.9               J        2.4           J           2.3              J
                      1123cdPYRENE                  7.4                              4.5                          1.4               J        0.6           J           1.4              J
                      DBahANTHRA *                  2.5                J             1.0              J           1.0               J        0.2           J           0.4              J
                      BghiPERYLENE                  10.0                             5.8                          2.1               J        1.4           J           3.3              J
                        TOTALPAHs                   1923.8            0.0            1915.9          0.0          421.9         0.0          498.6       0.0           789.6         0.0
                  S&T Total PAHs (*)                772.9                            781.1                        269.6                      177.9                     348.5





                                                    Mussel Watch Project Year 9 - PAH Data (Tissue)

                              INVEST#              CBBB                               PCLO                          AESP                     CKBP                        TBOT
                                     ID     Choctawhatchee Bay                    Panama City                 Apalachee Bay                Cedar Key                 Tampa Bay
                                   SITE        Boggy Bayou                      Little Oyster Bar              Spring Creek               Black Point              Old Tampa Bay
                          LABSAMNO                 K8062                              K8068                         K8070                    K8072                       K8080
                      SAMPLE TYPE                  SAMP                               SAMP                          SAW                      SAMP                        SAMP
                                  UNIT              ng/g                              ng/9                          ng/g                       ng/g                      ng/g
                         PNA Analyte                Conc            DB QUAL           Conc         DB.QUAL          Conc        DB QUAL        Conc     DB QUAL          Conc        DB QUAL


                  2-METHYLNAPH *                    23.2                              18.0                          34.0                       20.8                      18.2
                  I-METHYLNAPH *                    13.5                              14.3                          29.7                       16.4                      13.6
                2,6-I)MIETHNAPH *                   18.6                              11.2             J            13.8                       9.8          J            15.8
                1,6,7-TRIMETHNAPH *                 4.6                  J            3.3              J            3.9             J          4.4           J           4.0              J
                  i -METHYLPHEN *                   20.9                              36.0                          11.4            J          3.8           J           8.2              J





                                                    Mussel Watch Project Year 9 - PAH Data (Tissue)

                                   INVEST#          TBPB                      TBHB                         TBMK                          TBKA                        TBNP
                                          11)   Tampa Bay                 Tampa Bay                    Tampa Bay                     Tampa Bay                   Tampa Bay
                                        SITE   Papys Bayou               Hillsborough              Mullet Key Bayou                Knights Airport              Navarez Park
                               LA13SAMNO            K8078                     K8084                        K8088                         K8074                       K8082
                           SAMPLE TYPE              SAW                       SANT                         SANT                          SAND                        SAMP
                                       UNIT         ng/g                      ng/g                         ng/g                          ng/g                        ng/g
                              PNA Analyte           Conc       DB QUAL        Conc       DB QUAL           Cone         DB QUAL          Cone        DB QUAL         Conc       DB QUAL


                          RECEIPT DATE              01/21/94                  01/23/94                     01/23/94                      01/21/94                    01/21/94
                                 QCBATCH            M1412                     M1412                        M1412                         M1411                       M1412
                    EXTRACTION DATE                 08/01/94                  08/01/94                     08/01/94                      07/25/94                    08/01/94
                                   METHOD           GCMS                      GCMS                         GCMS                          GCMS                        GCMS
                        ANALYSIS DATE               09/05/94                  09/06/94                     09/06/94                      09/06/94                    0.9/05/94
                                   MATRIX           TISSUE                    TISSUE                       TISSUE                        TISSUE                      TISSUE
                                   SUBMAT
                                   WETWT            10.36                     10.34                        10.25                         10.00                       10.20
                                   DRYWT            1.37                      1.66                         1.75                          1.25                        1.64
                                   WTUNITS          GRAMS        DRY          GRAMS        DRY             GRAMS          DRY            GRAMS         DRY           GRAMS        DRY
                               PCTSOLH)S            13.2%                     16.1%                        17.1%                         12.5%                       16.1%
                              Lipid Weight
                                   % LIPIDS         7.75                      8.20                         8.99                          14.91                       6.85
                       Surrogate Recoveries
                                   NAPHD8           54.4                      96.7                         50.6                          43.6                        50.0
                                   ACEND10          58.6                      94.5                         51.5                          50.3                        50.4
                                   PHEND10          55.3                      88.3                         55.6                          53.6                        57.8
                                   CHRYD12          54.8                      99.5                         55.5                          59.7                        58.2
                                   PERYD12          16.0                      91.0                         22.8                          19.5            Q           17.9
                       NAPHITIALENE *               17.4                      14.5                         29.2                          41.7                        28.9
                    Cl-NAPHTHALENES                 15.7                      44.5                         15.0                          36.0                        67.0
                    C2-NAPHTHALENES                 16.5                      28.3                         14.8                          42.5                        61.0
                    C3-NAPHTHALENES                 34.7                      97.9                         32.6                          90.6                        106.2
                    C4-NAPHTHALENES                 36.4                      67.7                         27.4                          155.4
                             BIPHENYL *             4.2            J          7.3           J              3.9              J            7.3             J           7.1            J
                    ACENAPHT11YLENE                 2.8            J          19.7                         1.5              J            6.8             J           4.8            J
                      ACENAPHTHENE*                 4.1            J          13.2                         3.6              J            11.0                        3.7            J





                                                     Mussel Watch Project Year 9 - PAH Data (Tissue)

                                   INVEST#           TBPB                       TBHB                         TBMK                           TBKA                         TBNP
                                           ID    Tampa Bay                  Tampa Bay                    Tampa Bay                      Tampa Bay                    Tampa Bay
                                        SITE    Papys Bayou                Hillsborough              Mullet Key Bayou                 Knights Airport              Navarez Park
                               LABSAMNO              K8078                      K8084                        K8088                          K8074                        K8082
                           SAMPLE TYPE               SAW                        SAMP                         SAW                            SAMP                         SAMP
                                        UNIT         ng/g                       ng/g                         ng/g                           ng/g                         ng/g
                               PNA Analyte           Conc       DB QUAL         Conc      MQUAL              Conc          DBQUAL           Conc        DB QUAL          Conc       DB QUAL

                              FLUORENE*              5.5            J           19.9                         6.2               J            13.4                         8.9
                           Cl-FLUORENES              17.7                       23.5                         10.3              J            34.5                         38.2
                           C2-FLUORENES              64.8                       67.8                         38.3                           106.4                        204.3
                           O-FLUORENES               101.6                      261.3                        98.4                           242.9                        459.7
                       PHENANTHRENE*                 37.4                       258.5                        27.5                           61.9                         41.5
                           ANTHRACENE*               7.2                        60.4                         3.7                            12.9                         11.8
                        Cl-PHEN-ANTTIR               55.5                       180.4                        29.6                           77.8                         145.5
                        C2-PHEN-ANTHR                62.6                       173.7                        38.3                           208.6                        789.1
                        O-PHEN-ANTHR                 79.2                       136.6                        41.8                           178.1                        1726.0
                        C4-P,HEN ANTER               30.0                       76.3                         21.9                           57.4                         1213.3
                           DIBENZOTHIO               3.1                        15.5                         1.8                            8.4                          4.4
                                 Cl-DIBEN            6.4                        37.4                         4.5                            18.2                         29.1
                                 C2-DIBEN            24.9                       107.4                        12.5                           98.9                         217.9
                                 C3-DIBEN            26.5                       124.6                        11.3                           126.8                        522.6
                       FLUORANTHENE*                 210.2                      1327.7                       44.6                           216.1                        232.5
                                 PYREIC *            106.2                      953.0                        20.4                           213.8                        187.2
                      Cl-FLUORAN PYR                 52.0                       418.5                        14.1                           125.5                        583.4
                       BENaANTHRACENE*               26.2                       245.6                        3.1                            18.0                         93.8
                              CHRYSENE*              89.6                       285.7                        20.9                           80.1                         470.1
                           Cl-CHRYSENES              14.3                       102.0                        7.3               J            33.3                         1189.9
                           C2-CHRYSENES              11.0           J           23.1                         11.0                           20.1                         1112.3
                           C3-CHRYSENES                            ND                        ND                               ND            5.5             J            17.0
                           C4-CHRYSENES                            ND                        ND                               ND            8.5             J            23.8
                  I BENb/BENkFLUORAN                 63.4                       153.8                        8.4                            56.8                         175.7
                           BENePYRENE *              30.2                       73.9                         5.3                            40.3                         192.9
                           BENaPYRENE *              3.0            J           13.9                         1.0               J            4.3             J            21.9
                               PERYLENE*             2.9                        5.1                          1.1               J            4.4             J            40.1
                           1123cdPYRENE              5.1                        5.3                          1.5                            6.2                          8.5
                           DBabANTHRA *              1.3                        1.7                          0.3               J            1.8             J            9.7
                           BghiPERYLENE              7.2                        9.3                          2.1                            13.0                         28.5
                               TOTALPAHs             1277.1        0.0          5455.0       0.0             615.0            0.0           2484.9          0.0          10237.5      0.0
                       S&T Total PAHS M              584.2                      3390.1                       200.7                          804.5                        1491.1





                                                     Mussel Watch Project Year 9 - PAH Data (Tissue)

                                   R4VEST#           TBPB                     TBHB                         TBMK                             TBKA                        TBNP
                                           ID    Tampa Bay                  Tampa Bay                    Tampa Bay                      Tampa Bay                    Tampa Bay
                                        SITE    Papys Bayou                Hillsborough              Mullet Key Bayou                 Knights Airport              Navarez Park
                               LABSAMNO              K8078                    K8084                        K8088                           K8074                        K8082
                            SAMPLE TYPE              SAW                      SAW                           SAW                             SAW                         SAW
                                        UNIT         ng/g                       ng/g                         ng/g                           ng/g                        ng/g
                               PNA Analyte           Conc       DB QUAL         Conc      DB QUAL            Conc          DB QUAL          Conc        DB QUAL         Conc   ------- DB-QUAL


                       2-METHYLNAPH *                9.3                        24.6                         8.7                            19.9                        44.4
                       I-METHYLNAPH *                6.4                        20.0                         6.3                            16.1                        22.6
                      2,6-DRAETHNAPH *               8.7                        17.2                         6.4                            15.3                        29.2
                     1,6,7-TRINIIETHNAPH *           4.7            J           7.5                          4.1               J            12.7                        16.7
                        I-METHYLPHEN *               9.6                        40.4                         4.4               J            13.7                        28.2





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                            INVEST#             CBBI                           RBHC                      FBFO                    FBFO                   FBFO                   FBFO
                                    ID,   Charlotte Harbor                Rookery Bay                Florida Bay             Florida Bay            Florida Bay            Florida Bay
                                 SITE       Bird Island                 Henderson Creek                  Flamingo                Flamingo               Flamingo               Flamingo
                        LABSAMNO                K8086                          K8090                     K8092                   K8093                  K8094                  K8093
                    SAMPLE TYPE                 SANIP                          SAW                       SAMP                    SAMP                   SAMP                   SAMP
                                UNIT            ng/g                           ng/g                      ng/g                    n9/9                   ng/g                   ng/g
                        PNA Analyte,            Conc          DB QUAL          Conc        DB QUAL       ConC      DD QUAL       ConC     DB QUAL       ConC     DB QUAL       ConC     DB QUAL


                    RECEIPT DATE                01/23/94                       01/23/94                  01/27/94                01/27/94               01/27/94               01/27/94
                          QCBATCH               M1412                          M1412                     M1412                   M1412                  M1412                  M1412
              EXTRACTION DATE                   08/01/94                       08/01/94                  08/01/94                08/01/94               08/01/94               08/01/94
                            METHOD              GCMS                           GCMS                      GCMS                    GCMS                   GCMS                   GCMS
                 ANALYSIS DATE                  09/05/94                       09/06/94                  09/06/94                09/05/94               09/06/94               09/05/94
                            MATRIX              TISSUE                         TISSUE                    TISSUE                  TISSUE                 TISSUE                 TISSUE
                            SUBMAT
                             VvrETWT            10.31                          10.15                     10.19                   10.03                  10.35                  10.03
                             DRYWT              1.33                           1.21                      1.60                    1.04                   1.18                   1.04
       W                   W`TUNITS             GRAMS           DRY            GRAMS         DRY         GRAMS       DRY GRAMS DRY                      GRAMS      DRY GRAMS DRY
       p                 PCTSOLIDS              12.9%                          11.9%                     15.7%                   10.4%                  11.4%                  10.4%
                        Lipid Weight
                           % LIPIDS             5.92                           4.33                      9.25                    6.25                   7.40                   6.25
                Surrogate Recoveries
                            NAPHD8              47.5                           42.8                      54.2                    58.3                   44.2                   58.3
                           ACEND10              50.1                           49.7                      57.6                    57.5                   47.1                   57.5
                           PHENDIO              49.8                           55.9                      56.1                    65.9                   55.7                   65.9
                           CHRYD12              47.1                           63.4                      65.6                    63.8                   60.3                   63.8
                           PERYD12              21.3                           28.4                      21.3                    21.4                   30.2                   21.4
                 NAPHTHALENE                    14.3                           22.2                      35.5                    25.4                   26.9                   25.4
              Cl-NAPHTHALENES                   11.6              J            28.0                      167.1                   56.7                   48.9                   56.7
              C2-NAPHTHALENES                   14.5                           25.9                      386.7                   70.5                   559.8                  70.5
              C3-NAPHTHALENES                   33.8                           40.9                      966.2                   122.0                  939.2                  122.0
              C4-NAPHTHALENES                   23.3                           33.7                      1512.0                  98.9                   794.7                  98.9
                       BIPHENYL *               3.2               J            6.1             J         24.8                    9.3         J          7.5          J         9.3           J
              ACENAPHTHYLENE                    1.2               J            0.9             J         48.7                    2.8         J          2.4          J         2.8           J
                ACENAPHTHENE*                   0.7               J            1.5             J         28.3                    1.8         J          0.8          J         1.8           J





                                                       Mussel Watch Project Year 9 - PAH Data (Tissue)

                             INVEST#              CBBI                           RBHC                       FBFO,                    FBFO,                  FBFO                     FBFO
                                     ID    Charlotte Harbor                 Rookery Bay                 Florida Bay             Florida Bay             Florida Bay             Florida Bay
                                  SITE        Bird Island                 Henderson Creek                Flamingo                Flamingo                   Flamingo              Flamingo
                         LABSAMNO                 K8086                          K8090                      K8092                    K8093                  K8094                    K8093
                     SANTLE TYPE                  SANT                           SANT                       SAMP                     SAMP                   SAMP                     SAMP
                                 UNIT             ng/g                           ng/g                       ng/9                     ng/g                   ng/g                     ng/g
                        PNA Analyte               Conc         DB QUAL           Conc         DB QUAL       ConC      DB QUAL        ConC     DB QUAL       ConC      DB QUAL        ConC     DB QUAL

                        FLUORENE*                 2.2                 J          4.3                J       59.5                     8.4            J       7.4            J         8.4           J
                    Cl-FLUORENES                  10.9                J          12.0               J       354.1                    36.9                   31.8                     36.9
                    C2-FLUORENES                  36.4                           41.8                       1409.5                   114.9                  98.5                     114.9
                    C3-FLUORENES                  89.8                           101.4                      1870.8                   135.8                  150.6                    135.8
                PHENANTHRENE*                     8.4                            7.0                        236.0                    20.5                   13.9                     20.5
                    ANTHRACENE*                   2.5                 J          1.8                J       124.6                    3.9            J       3.9            J         3.9           J
                 CI-PHEN-ANTHR                    16.7                           11.1               J       933.0                    49.7                   32.1                     49.7
                 C2-PHEN-ANTHR                    26.1                           26.4                       2134.1                   91.5                   73.6                     91.5
                 C3-PHEN-ANTHR                    43.5                           27.6                       1795.3                   80.5                   65.3                     80.5
                 C4-PHEN ANTHR                    15.7                           11.1               J       508.2                    31.0                   18.2                     31.0
                      DIBENZOTHIO                 0.6                 J          0.7                J       19.2                     2.0            J       1.6            J         2.0           J
       v                   -CI-DIBEN              2.7                 J          2.3                J       120.8                    5.7            J       4.9            J         5.7           J
                           C2-DIBEN               10.1                           6.8                        477.2                    16.9                   16.7                     16.9
                           C3-DIBEN               12.6                           8.7                        656.3                    17.8                   13.9                     17.8
                FLUORANTHENE*                     15.1                           9.5                        1626.2                   39.7                   30.7                     39.7
                       1. PYRENE*                 11.6                           8.0                        1376.7                   38.3                   29.4                     38.3
                Cl-FLUORAN PYR                    10.3                           10.7                       1868.1                   49.7                   38.3                     49.7
                                                                                                                                                                                           ... . ... ........
               BENaANTHRACENE                     1.5                 J          0.9                J       540.4                    9.0                    6.4                      9.0
                       CHRYSENE*                  5.8                 J          2.6                J       650.5                    13.9                   10.1                     13.9
                    CI-CHRYSENES,                 1.6                 J          2.4                J       326.1                    13.3                   7.2            J         13.3
                    C2-CHRYSENES                  7.8                 J          3.9                J       100.1                    9.9                    10.3           J         9.9
                    C3-CHRYSENES                                   ND                            ND         3.3           J                      ND                      ND                      ND
                    C4-CHRYSENES                                   ND                            ND         5.9           J                      ND                      ND                      ND
           I BENbJBENkFLUORAN                     3.5                            2.6                        455.7                    11.2                   6.7                      11.2
                    BENePYRENE *                  2.5                            2.0                        222.2                    8.4                    5.7                      8.4
                    BENaPYRENE *                  0.1                 J          0.2                J       33.5                     0.8            J       0.6            J         0.8           J
                        PERYLENE*                 0.7                 1          0.5                J       32.7                     1.7            J       0.7            J         1.7           J
                      1123cdPYRENE                0.7                 J          0.3                J       16.6                     2.7                    0.6            J         2.7
                    DBahANTHRA                    0.2                 J          0.2                J       4.1                      0.3            J       0.2            J         0.3           J
                    BghiPERYLENE                  1.1                 J          1.1                J       60.6                     9.1                    3.2                      9.1
                       TOTAL PAHs                 443.2            0.0           467.0           0.0       21190.1      0.0          1210.4      0.0        3062.8       0.0         1210.4      0.0
                S&T Total PAHs (*)                89.2                           109.8                      5637.5                   298.7                  234.0                    298.7





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                            INVEST#              CBBI                          RBHC                        FBFO                   FBFO                    FBFO                    FBFO
                                    ID    Charlotte Harbor                 Rookery Bay                 Florida Bay            Florida Bay             Florida Bay             Florida Bay
                                  SITE       Bird Island                 Henderson Creek                Flamingo                Flamingo               Flamingo                Flamingo
                        LABSAMNO                 K8086                         K8090                       K8092                  K8093                   K8094                   K8093
                     SAWLE TYPE                  SAW                           SAW                         SAND                   SAMP                    SAMP                    SAMP
                                 UNIT            ngig                           ng/g                       ng/g                   ng/g                    ng/g                    ng/g
                        PNA Analyte              Conc          DB QUAL          Conc        DB QUAL        Conc     DB QUAL       Conc      DB QUAL       Conc     DB QUAL        ConC     DB QUAL



                2-METHYLNAPH                     7.2               J            16.1                       112.4                  39.6                    30.4                    39.6
                 1-METHYLNAPH*                   4.4               J            11.9                       54.8                   17.1                    18.4                    17.1
               2,6-DR,4ETHNAPH *                 4.2               J            8.3                        147.6                  32.3                    19.7                    32.3
              1,6,7-TRINETHNAPH *                1.1               J            3.6             J          144.2                  18.7                    11.8                    18.7
                 I -NETHYLPHEN *                 3.5               J            3.1             J          183.8                  9.7                     9.5                     9.7






       CIO





                                                     Mussel Watch Project Year 9 - PAH Data (Tissue)

                                                   INVEST#             FBJB                        FBJB                     FBJB                      BHKF
                                                           ID      Florida Bay                 Florida Bay              Florida Bay              Bahia Honda
                                                         SITE          Joe Bay                     Joe Bay                  Joe Bay               Key Florida
                                                LABSAMNO               K8107                       K8108                    K8109                     K8076
                                            SAMPLE TYPE                SANT                        SAMP                     SAMP                      SAMP
                                                        UNIT           ng/g                        ng/g                     ng/g                      ng/g
                                               PNA Analyte             Conc         DB QUAL        Conc      DB QUAL        Conc      DB QUAL         Conc       DB QUAL


                                           RECEIPT DATE                01/27/94                    01/27/94                 01/27/94                  01/21/94
                                                   QCBATCH             M1412                       M1412                    M1412                     M1412
                                     EXTRACTION DATE                   08/01/94                    08/01/94                 08/01/94                  08/01/94
                                                   METHOD              GCMS                        GCMS                     GCMS                      GCMS
                                         ANALYSIS DATE                 09/06/94                    09/06/94                 09/06/94                  09/06/94
                                                   MATRIX              TISSUE                      TISSUE                   TISSUE                    TISSUE
                                                   SUBMAT
                                                     WETWT             5.50                        10.41                    10.38                     10.26
                                                     DRYWT             0.60                        1.00                     1.09                      1.82
                                                   WTUNITS             GRAMS          DRY          GRAMS       DRY          GRAMS       DRY           GRAMS        DRY
                                                 PCTSOLIDS             11.0%                       9.6%                     10.5%                     17.7%
                                               Lipid Weight
                                                   % LIPIDS            4.46                        4.47                     7.09                      10.88
                                        Surrogate Recoveries
                                                   NAPHD8              38.0                        37.8                     44.5                      41.9
                                                   ACENDIO             43.1                        45.7                     53.5                      48.6
                                                   PHEND10             46.4                        53.5                     52.1                      52.4
                                                   CHRYD12             54.7                        64.1                     51.3                      49.4
                                                   PERYD12             33.9                        31.7                     33.4                      33.5
                                         NAPHTHALENE*                  50.5                        40.9                     28.9                      17.3
                                     Cl-NAPHTHALENES                   50.9                        40.1                     36.3                      22.0
                                     C2-NAPHTHALENES                   53.8                        37.4                     29.1                      27.2
                                     C3-NAPHTHALENES                   98.0                        69.5                     39.7                      39.2
                                     C4-NAPHTHALENES                   27.3             1          19.8          1          37.9                      27.1
                                               BIPHENYL *              14.9             1          6.8           J          7.1           1           4.5
                                     ACENAPHTHYLENE                    2.1              1          1.6           J          0.3           1           0.5
                                        ACENAPHTHENE*                  3.6                         3.2                      1.7           1           0.8





                                                        Mussel Watch Project Year 9 - PAH Data (Tissue)

                                                      INVEST#              FBJB                         FBJB                       FBJB                       BHKF
                                                              M       Florida Bay                   Florida Bay               Florida Bay                Bahia Honda
                                                            SITE           Joe Bay                      Joe Bay                    Joe Bay               Key Florida
                                                  LABSAMNO                 K8107                        K8108                      K8109                      K8076
                                              SANDLE TYPE                  SAMP                         SAMP                       SAMP                       SAMP
                                                           UNIT            ng/g                         ng/g                       ng/g                       ng/g
                                                  PNA Analyte              Conc         DB QUAL         Conc       DB QUAL         Conc      DB QUAL          Conc       DB QUAL

                                                 FLUORENE*                 8.5                1         5.2              1         4.4                        3.6
                                              CI-FLUORENES                 20.7               1         16.2                       14.5                       10.0
                                              C2-FLUORENES                 51.5                         32.8                       24.5                       30.0
                                              O-FLUORENES                  102.4                        86.1                       83.6                       81.4
                                         PHENANTHRENE *                    23.9                         16.1                       13.9                       8.6
                                              ANTHRACENE*                  2.8                1         1.3              J         2.5             J          1.5             J
                                           Cl-PHEN-ANTBR                   21.7               1         17.6                       13.7            1          14.0
                                           C2-PHEN-ANTHR                   26.3               J         18.1                       14.3            1          24.8
                                           O-PHEN-ANTUR                    19.1                         27.5                       17.9                       20.7
                                           C4-PHEN ANTHR                   20.1                         14.9             1         10.5            1          8.6             1
                                              DIBENZOTHIO                  2.1                1         1.6              J         1.4             1          1.0             1
                                                    CI-DIBEN               4.6                1         3.2              J         3.1             1          2.5             1
                                                    C2-DIBEN               10.7               1         7.2              1         7.6                        7.0
                                                    C3-DIBEN               5.8                1         6.7              1         6.6             1          11.7
                                          FLUORANTHENE*                    14.8                         10.1                       8.5                        14.6
                                                    PYRENE*                9.5                          7.3                        5.4                        10.0
                                         CI-FLUORAN PYR                    14.3                         10.2                       7.8                        10.9
                                         BENaANTHRACENE*                   1.4                1         1.3              J         1.4             1          3.4
                                                 CHRYSENE*                 5.9                1         3.8              1         3.6             1          7.5
                                              Cl-CHRYSENES                 3.6                1         2.3                        2.8             1          4.0             1
                                              C2-CHRYSENES                 3.6                1         3.7                        3.3             1          7.2             1
                                              C3-CHRYSENES                                  ND                         ND                        ND                         ND
                                              C4-CHRYSENES,                                 ND                         ND                        ND                         ND
                                    I BENb/BENkFLUORAN                     2.7                          2.2                        2.0                        3.4
                                              BENePYRENE *                 2.9                          1.8              J         1.9             1          2.8
                                              BENaPYRENE *                 0.7                          0.4              1         0.5             1          1.1             1
                                                 PERYLENE*                 1.1                          0.7              J         0.4             1          0.2             1
                                              1123cdPYRENE                 0.9                J         0.5              1         0.6             1          0.6
                                              DBahANTHRA                   0.3                1         0.1                        0.1             1          0.2
                                              BghiPERYLENE                 1.4                1         1.2                        1.2             1          1.4             1
                                                 TOTALPAHs                 684.4            0.0         519.2         0.0          438.8         0.0          430.9         0.0
                                           S&T Total PAHs (*)              215.3                        158.3                      135.3                      109.4





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                                                    INVEST#            FBJB                         FBJB                     FBJB                      BHKF
                                                            ID      Florida Bay                 Florida Bay               Florida Bay              Bahia Honda
                                                          SITE        Joe Bay                     Joe Bay                   Joe Bay                 Key Florida
                                                LABSAMNO               K8107                       K8108                     K8109                     K8076
                                             SAMPLE TYPE               SAMP                        SAMP                      SAW                       SAMP
                                                         UNIT           ng/g                        ng/g                      ng/g                       ng/g
                                                PNA Analyte            Conc          DB QUAL        Conc       DB QUAL        Conc      DB QUAL          Conc      DB QUAL



                                        2-METHYLNAPH                   26.5                         21.7                      19.5                       12.6
                                         I-METHYLNAPH*                 24.3                         18.3                      16.8                       9.4
                                       2,6-DIMETHNAPH *                 10.0             1           9.3                      9.2                        5.0
                                      1,6,7-TRB4ETHNAPH *               8.2              1           7.0           1          5.9                        3.5
                                         I-METHYLPHEN *                 5.5              1           2.9           1          3.7                        3.0







        U1






                                                          Mussel Watch Project Year 9 - PAH Data (Tissue)

                                                          INVEST#                    PRBB;                                 PRBM[                             PRBJ
                                                                I ID,            Puerto Rico                           Puerto Rico                       Puerto Rico
                                                                SITE        Bahia De Boqueron                        Bahia Montalva.                   Bahia De Jobos
                                                      LABSAMNO                       K8122                                 K8124                             K8126
                                                  SAWLE TYPE                         SAW                                   SAW                               SAW
                                                               UNIT                  119/9                                 ng/g                              ng/g
                                                     PNA Analyte                     Conc                DB QUAL           Conc          DB QUAL             Conc           DB QUAL


                                                 RECEIPT DATE                        02/16/94                            02/16/94                            02/16/94
                                                        QCBATCH                      M1412                                 M1412                             M1412
                                           EXTRACTION DATE                           08/01/94                            08/01/94                            08/01/94
                                                          METHOD                     GCMS                                  GCMS                              GCMS
                                               ANALYSIS DATE                         09/06/94                            09/06/94                            09/06/94
                                                          MATRIX                     TISSUE                              TISSUE                              TISSUE
                                                          SUBMAT
                                                          WETWT                      10.02                                 10.06                             10.19
                                                          DRYWT                      1.62                                  1.66                              1.65
                                                          WTUNITS                    GRAMS                 DRY           GRAMS             DRY               GRAMS            DRY
                                                       PCTSOLIDS                     16.2%                                 16.5%                             16.1%
                                                      Lipid Weight
                                                          % LIPIDS                   4.98                                  5.79                              6.11
                                             Surrogate Recoveries
                                                          NAPHD8                     36.6                                  41.6                              47.9
                                                          ACEND10                    46.3                                  50.5                              51.8
                                                          PHEND10                    51.1                                  55.6                              53.3
                                                          CHRYD12                    52.7                                  58.7                              64.4
                                                          PERYD12                    29.7                                  18.4              Q               35.2
                                               NAPHTHALENE*                          16.1                                  15.9                              20.7
                                           CI-NAPHTHALENES,                          17.9                                  16.9                              15.3
                                           C2-NAPHTHALENES                           20.8                                  21.9                              17.7
                                           C3-NAPHTHALENES                           47.7                                  48.6                              44.5
                                           C4-NAPHTHALENES                           35.1                                  25.0                              31.1
                                                     BIPHENYL                        5.4                     J             4.2               J               4.3                J
                                           ACENAPHTHYLENE                            0.4                     J             0.8               J               0.4                J
                                             ACENAPHTHENE*                           1.3                     J             0.8               J               1.0                J





                                                      Mussel Watch Project Year 9 - PAH Data (Tissue)

                                                       INVEST#                  PRBB                                PRBM                           PRBJ
                                                              ID            Puerto Rico                        Puerto Rico                     Puerto Rico
                                                            SITE       Bahia De Boqueron                     Bahia Montalva                  Bahia De Jobos
                                                   LABSAMNO                     K8122                               K8124                          K8126
                                               SANTLE TYPE                      SAMP                                SAMP                           SAMP
                                                           UNIT                 ng/g                                ng/g                           ng/g
                                                  PNA Analyte                   Conc              DB QUAL           Conc        DB QUAL            Conc          DB QUAL

                                                 FLUORENE*                      3.9                   J             3.4               J            3.1                J
                                              CI-FLUORENES                      13.0                  J             12.6              J            11.6               J
                                              C2-FLUORENES                      24.6                                30.8                           43.2
                                              O-FLUORENES                       56.2                                33.4                           51.2
                                          PHENANTHRENE*                         9.9                                 11.4                           6.2
                                              ANTHRACENE*                       1.3                   J             2.6               J            0.8                J
                                           CI-PHEN-ANTHR                        17.1                                19.2                           16.3
                                           C2-PBEN-ANTHR                        19.2                                30.1                           26.1
                                           C3-PHEN-ANTHR                        24.3                                27.9                           20.4
                                           C4-PHEN ANTHR                        11.0                                7.7               J            8.1                J
                                                DIBENZOTIRO                     0.5                   J             1.0               J            0.6                J
                                                    CI-DIBEN                    1.9                   J             2.9               J            2.8                J
                                                    C2-DIBEN                    5.9                                 5.5                            7.6
                                                    C3-DIBEN                    5.6                                 9.9                            5.9
                                          FLUORANTHENE*                         39.6                                28.7                           9.9
                                                    PYRENE*                     17.9                                17.5                           11.4
                                          CI-FLUORAN PYR                        17.6                                17.2                           11.8
                                          BENaANTHRACENE*                       3.8                                 3.0                            0.9                J
                                                 CHRYSENE*                      13.8                                2.8               J            3.5                J
                                              CI-CHRYSENES                      3.9                   J             4.4               J            4.0                J
                                              C2-CHRYSENES                      4.1                   J             4.7               J            2.9                J
                                              C3-CHRYSENES                                           ND                             ND                              ND
                                              C4-CHRYSENES                                           ND                             ND                              ND
                                     I BENb/BENkFLUORAN                         8.7                                 6.6                            1.7
                                              BENePYRENE *                      5.0                                 4.3                            2.1
                                              BENaPYRENE *                      1.3                   J             0.4               J            0.0              ND
                                                 PERYLENE*                      0.9                   J             0.9               J            0.8                J
                                                I123cdPYRENE                    1.4                                 0.5               J            0.2                J
                                              DBahANTHRA *                      0.2                   J             0.2               J            0.1                J
                                              BghiPERYLENE                      2.2                                 1.5               J            1.0                J
                                                 TOTALPAHs                      459.5               0.0             425.2          0.0             389.3
                                          S&T Total PAHs (*)                    150.2                               133.1                          96.6




                                        mm MMM m1mm m mmm m m m
                                               Mussel Watch Project Year 9 - PAK Data (Tissue)

                                                INVEST#              PRBB                          PRBM                         PRBJ
                                                      D:)         Puerto Rico                    Puerto Rico                Puerto Rico
                                                    SITE      Bahia De Boqueron                Bahia Montalva             Bahia De Jobos
                                            LABSAMNO                 K8122                         K8124                        K8126
                                         SAMPLE TYPE                 SAMP                          SAW                          SAMP
                                                   UNIT              ng/g                           ng/g                        ng/g
                                            PNA Analyte              Conc            DBQUAL         Conc       DB QUAL          Conc        DB QUAL



                                     2-METHYLNAPH                                                   9.5                         8.1
                                      I-METHYLNAPH*                  8.8                            7.5                         7.3
                                    2,6-DRvMTHNAPH *                 5.2                 J          7.2                         6.7
                                   1,6,7-TRIMETHNAPH *               3.3                 J          3.8            J            5.5            J
                                     I-METHYLPBEN                    3.4                 J          9.1                         4.3            J




 I
 I
 I
,I
 I
 I'
 I
 I                 PAH QC Data
 I                    (Tissue)
 I
.I -
 I
. I
 I
 I ,
 I
 I
 I                                          .
 1                        39
 I





                                                Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                     INVEST#       Lab QA Sample                          ABLR                       Lab QA Sample                      RPD Lab QA Sample
                                             ID      Proc Blank                       Aransas Bay                          ABLR                                       ABLR
                                          SITE                                         Long Reef                        Long Reef                                     Long Reef
                                  LABSAMNO               Q9490                            K8032                            Q9492                                      Q9493
                              SAWLE TYPE                 BLANK                            SAMT                             DUP -                                      MS
                                          UNIT           ng/g                             ng/g                             ng/g                                         %
                                 PNA Analyte    I        Conc          DB; QUAL           Conc        DB QUAL              Conc          DB QUAL                      Recovery      DB QUAL

                             RECEIPT DATE                                                 12/17/93                         12/17/93                                   12/17/93
                                    QCBATCH              M1410                            M1410                            M1410                                      M1410
                       EXTRACTION DATE                   07/21/94                         07/21/94                         07/21/94                                   07/21/94
                                     METHOD              GCMS                             GCMS                             GCMS                                       GCMS
                           ANALYSIS DATE                 09/03/94                         09/04/94                         09/03/94                                   09/03/94
                                     MATRIX              TISSUE                           TISSUE                           TISSUE                                     TISSUE
                                      WETWT                                               10.05                            10.14                                      10.12
                                      DRYWT              10.00                            1.65                             1.67                                       1.69
                                     WTUNITS             GRAMS            DRY             GRAMS          DRY               GRAMS            DRY                       GRAMS           DRY
                                  PCTSOLIDS                                               16.4%                            16.5%                                      16.7%
                                     % LIPIDS                                             18.74                            15.32                                      17.54
           Surrogate
                             Recoveries PAHs
                                     NAPHD8              61.8                             55.4                             46.7                                       45.7
                                     ACEND10             62.5                             60.2                             54.7                                       49.4
                                     PHENDIO             60.3                             58.0                             58.7                                       58.8
                                     CHRYD12             63.3                             67.3                             64.0                                       60.0
                                     PERYD12             26.5                             9.6              Q               3.6                Q                       4.2               Q
                           NAPHTHALENE*                  1.2                              14.2                             17.0                         17.9          97.6
                       Cl-NAPHTFIALENES                  0.9                J             10.9                             13.3                         19.8                           NA
                       C2-NAPHTHALENES                                    ND              29.0                             40.7                         33.6                           NA
                       C3-NAPHTHALENES                                    ND              91.4                             104.1                        13.0                           NA
                       C4-NAPHTHALENES                                    ND              110.9                            91.4                         19.3                           NA
                                BIPHENYL                 0.7                J             6.8              J               8.6                J         24.1          107.1
                       ACENAPHTHYLENE                    0.1                J             2.4              J               2.7                J         11.6          72.8
                         ACENAPHTHENE                    0.1                J             1.6              J               2.0                J         18.9          98.9





                                                   Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#       Lab QA Sample                             ABLR                         Lab QA Sample                        RPD Lab QA Sample
                                                ID       Proc Blank                        Aransas Bay                             ABLR                                          ABLR
                                             SITE                                           Long Reef                           Long Reef                                    Long Reef
                                    LABSAMNO               Q9490                                K8032                              Q9492                                         Q9493
                                SAMPLE TYPE               BLANK                                 SAMP                               DUP                                           MS
                                            UNIT             ng/g                               ng/g                               ng/g                                            6/.
                                   PNA Analyte      I        Conc          DB QUAL              Conc         DB QUAL               Conc           DB QUAL                     Recovery         DBQUAL


                                   FLUORENE*                 0.2                 J              4.8               J                5.3                 J          8.1            105.5
                               Cl-FLUORENES                                    ND               35.2                               34.0                           3.4                               NA
                               C2-FLUORENES                                    ND               173.4                              173.1                          0.1                               NA
                               C3-FLUORENES                                    ND               216.9                              180.6                          18.3                              NA
                                                                                                                                                                                               . .............I.. . . ....... ...........
                           PHENANTHRENE*                     1.4                                33.3                               24.1                           32.3           84.6
                               ANTHRACENE*                   0.1                 J              4.4               J                3.1                 J          33.7           0.0                Q
                            Cl-PHEN-ANTHR                                      ND               82.1                               61.7                           28.4                              NA
                            C2-PHEN-ANTHR                                      ND               114.0                              99.7                           13.4                              NA
                            C3-PHEN-ANTHR                                      ND               78.9                               70.3                           11.5                              NA
                            C4-PBEN ANTHR                                      ND               31.1                               24.31                          24.5                              NA
                                                                                                                                                                                           . . . . .......... ... . ............ . ..
                                 DIBENZOTHIO                 0.1                 J              2.8                                3.6                            26.4           82.8
                                      CI-DIBEN                                 ND               18.7                               14.3                           26.5                              NA
                                      C2-DIBEN                                 ND               41.6                               29.4                           34.3                              NA
                                      C3-DIBEN                                 ND               28.1                               29.1                           3.4                               NA
                          FLUORANTHENE *                     0.2                 J              7.0                                7.0                            0.0            96.0
                                      PYRENE *               0.3                                8.0                                8.4                            5.0            97.6
                          Cl-FLUORAN PYR                                       ND               14.8                               12.43                          17.3                              NA
                        BENaANTHRACENE*                      0.0                 J              1.2               J                1.8                 J          39.7           56.4
                                   CHRYSENE*                 0.1                 J              3.6               J                3.6                 J          1.1            110.7
                               Cl-CHRYSENES                                    ND               3.2               J                1.7                 J          59.1                              NA
                               C2-CHRYSENES                                    ND               4.4               J                5.1                 J          15.1                              NA
                               C3-CHRYSENES                                    ND                                ND                                   ND                                            NA
                               C4-CHRYSENES                                    ND                                ND                                   ND                                            NA
             TOTAL BENk/BENbFLUORAN                          0.1                                2.9                                4.8                            48.6           105.0
                               BENePYRENE *                  0.2                 J              1.7                                2.7                            46.5           106.4
                               BENaPYRENE *                  0.0                 J              0.5               J                0.6                 J          13.1           20.0               Q





                                                 Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                      R,TVEST#      Lab QA Sample                            ABLR                       Lab QA Sample                        RPD Lab QA Sample
                                              ID       Proc Blank                       Aransas Bay                            ABLR                                       ABLR
                                           SITE                                          Long Reef                         Long Reef                                   Long Reef
                                  LABSAMNO               Q9490                               K8032                             Q9492                                      Q9493
                              SAUTLE TYPE               BLANK                                SAMP                              DUP                                         MS
                                           UNIT           ng/g                               ngIg                              ng/g                                         %
                                  PNA Analyte             Conc           DBQUAL              Conc        DB QUAL               Conc          DB QUAL                    Recovery         DB QUAL


                                  PERYLENE*               0.3                 J              4.0                               11.3                          95.7         110.0
                               1123cdPYRENE               0.0                 J              0.6              J                1.8                           94.1         103.3
                             DBahANTHRA                   0.0                 J              0.4              J                1.4                J          114.9        103.7
                              BghiPERYLENE                0.07                J              0.9              J                2.29                          88.1         98.5
                                                                                                                                                                                              ... ..... . . . ..............


                                 TOTALPAHs                5.9                                1185.3                            1096.9                        7.7          1761.9
                          S&T Total PAHs                  6.29                               153.7                             158.89                        3.3


                          2-METHYLNAPH *                  0.5                 J              6.5                               7.6                           16.1         101.0
                          I-METHYLNAPH *                  0.5                 J              4.5                               5.8                           24.8         111.5
                         2,6-DIMETUNAPH *                 0.4                 J              18.0                              18.3                          1.4          106.7
                     1,6,7-TRIMETHNAPH *                  0.2                 J              16.4                              15.8                          3.4          98.8
                          I-METIMPBEN *                   0.19                J              17.0                              14.84                         13.5         97.2





                                                  Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                       INVEST#      Lab QA Sample                            BSSI                         Lab QA Sample                       RPD Lab QA Sample
                                               ID      Proc Blank                       Breton Sound                            BSSI                                       BSSI
                                            SITE                                         Sable Island                       Sable Island                               Sable Island
                                   LABSAMNO                Q9495                             K8038                              Q9497                                      Q9498
                               SAMPLE TYPE                 BLANK                             SANT                               DUP                                          MS
                                           UNIT            ng/g                              ng/g                               ng/g                                          %
                                  PNA Analyte              Conc          DB QUAL             Conc          DB QUAL              Conc          DB QUAL                    Recovery         DB QUAL


                              RECEIPT DATE                                                   01/15/93                           01/15/93                                 01/15/93
                                     QCBATCH               M1411                             M1411                              M1411                                      M1411
                        EXTRACTION DATE                    07/25/94                          07/25/94                           07/25/94                                 07/25/94
                                       METHOD              GCMS                              GCMS                               GCMS                                       GCMS
                            ANALYSIS DATE                  09/05/94                          09/05/94                           09/05/94                                 09/05/94
                                       MATRIX              TISSUE                            TISSUE                             TISSUE                                   TISSUE
                                       WETWT                                                 10.03                              10.01                                      10.01
                                       DRYWT               10.00                             0.75                               0.77                                       0.79
                                       WTUNITS             GRAMS            DRY              GRAMS            DRY               GRAMS            DRY                     GRAMS               DRY
                                   PCTSOLIDS                                                 7.4%                               7.7%                                       7.9%
                                       % LIPIDS                                              17.4                               21.78                                      14.38
           Surrogate
                              Recoveries PAHs
                                       NAPHD8              37.6                              63.8                               48.3                                       57.8
                                       ACEND10             40.4                              57.7                               56.4                                       58.7
                                       PHEND10             41.3                              61.1                               53.6                                       69.5
                                       CHRYD12             42.5                              56.9                               61.8                                       73.1
                                       PERYD12             17.6               Q              19.1               Q               18.1                Q                      28.1
                                                                                                                                                                                                  ..........
                            NAPHTHALENE*                   1.2                               26.2                               24.9                          4.9          116.9
                        Cl-NAPHTHALENES                    1.1                J              27.3                               29.9                          9.4                            NA
                        C2-NAPHTHALENES                                      ND              83.2                               89.6                          7.5                            NA
                        C3-NAPHTHALENES                                      ND              282.3                              254.2                         10.5                           NA
                        C4-NAPHTHALENES                                      ND              468.4                              537.5                         13.7                           NA
                                 BIPBENYL                  0.6                J              15.5               J               12.7                J         19.7         111.0
                        ACENAPHTHYLENE                     0.1                J              3.6                J               2.8                 J         24.7         112.4
                          ACENAPHTHENE*                    0.1                J              5.0                J               3.4                 J         36.7         116.1





                                                  Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                       INVEST#      Lab QA Sample                            BSSI                         Lab QA Sample                       RPD Lab QA Sample
                                               ID      Proc Blank                       Breton Sound                            BSSI                                       BSSI
                                            SITE                                         Sable Island                       Sable Island                               Sable Island
                                   LABSAMNO              Q9495                               K8038                              Q9497                                      Q9498
                               SAMPLE TYPE              BLANK                                SAMP                               DUP                                          NIS
                                           UNIT            ng/g                              ng/g                               ng/g                                          %
                                  PNA Analyte              Conc          DB QUAL             Conc          DB QUAL              Conc          DB QUAL                    Recovery         D13 QUAL


                                  FLUORENE*                0.2                J              16.5                               14.4                J         13.9         113.5
                              Cl-FLUORENES                                   ND              106.6                              79.5                          29.1                            NA
                              C2-FLUORENES                                   ND              251.9                              286.7                         12.9                            NA
                              C3-FLUORENES                                   ND              502.0                              495.7                         1.3                             NA
                                                                                                                                                                                     . . .......... . ..-.... .. .....
                          PHENANTHRENE*                    0.3                J              67.6                               53.9                          22.5         88.5
                              ANTHRACENE*                  0.1                J              6.8                J               4.0                 J         52.4         15.9               Q
                           Cl-PHEN-ANTHR                                     ND              183.9                              191.9                         4.2                             NA
                           C2-PBEN-ANTBR                                     ND              627.1                              575.9                         8.5                             NA
                           C3-PHEN      ANTHR                                ND              464.8                              560.2                         18.6                            NA
                           C4-PHEN ANTHR                                     ND              297.7                              342.9                         14.1                            NA
                                                                                                                                                                                         . . ......... . ......... . . ...... . ..
                                DIBENZOTHIO                0.2                J              9.5                                7.1                           29.7         133.1              Q
                                    Cl-DIBEN                                 ND              54.6                               60.1                          9.5                             NA
                                    C2-DIBEN                                 ND              261.2                              246.1                         6.0                             NA
                                    C3-DIBEN                                 ND              347.6                              320.2                         8.2                             NA
                         FLUORANTHENE *                    0.1                J              59.9                               43.9                          30.7         94.2
                                    PYR.ENE*               0.2                J              82.1                               68.1                          18.7         134.1              Q
                          Cl-FLUORAN PYR                                     ND              119.3                              136.8                         13.6                            NA
                                                                                                                                                                                           ..........
                       BENaANTHRACENE*                     0.1                J              11.5                               12.6                          9.1          88.1
                                  CHRYSENE*                0.1                J              63.2                               48.6                          26.1         92.7
                              Cl-CHRYSENES                                   ND              63.0                               48.8                          25.4                            NA
                              C2-CHRYSENES                                   ND              36.1                               31.3                          14.4                            NA
                              C3-CHRYSENES                                   ND                               ND                                  ND                                          NA
                              C4-CHRYSENES                                   ND                               ND                                  ND                                          NA
             TOTAL BENk/BENbFLUORAN                        0.1                               19.7                               17.9                          9.8          100.1
                              BENePYRENE *                 0.0                J              20.1                               17.2                          15.6         101.5
                              BENaPYRENE *                 0.0                J              2.0                J               1.9                 J         5.6          51.4





                                                 Mussel Watch Project Year 9 - PAH QC Data (Tissue)

                                      INVEST4      Lab QA Sample                           BSSI                       Lab QA Sample                      RPD Lab QA Sample
                                              ID      Proc Blank                      Breton Sound                           BSSI                                     BSSI
                                          SITE.                                        Sable Island                      Sable Island                              Sable Island
                                  LABSAMNO              Q9495                              K8038                             Q9497                                    Q9498
                              SAWLE TYPE               BLANK                               SAMP                              DUP                                       MS
                                          UNIT           ng/9                              ng/g                              ng/g                                       %
                                 PNA Analyte             Conc          DB QUAL             Conc         DBQUAL               Conc          DB QUAL                  Recovery         DBQUAL

                                 PERYLENE*               0.3                J              43.0                              36.3                        17.1         118.1
                               I123cdPYRENE              0.1                J              1.8               J               1.8                J        1.9          87.1
                             DBahANTHRA                  0.1                J              0.8               J               1.1                J        28.1         105.2
                              BghiPERYLENE               0.07               J              2.7               J               2.8                J        5.3          98.3   . .....   .............. . ......

                                 TOTALPAHs               4.7                              4634.5                             4662.7
                          S&T Total PAHs                 4.94                              592.3                             515.0                                    1916.0


                          2-METHYLNAPH                   0.5                J              16.4                              16.6                        1.3          109.8
                          I-METHYLNAPH*                  0.6                J              10.9                              13.3                        20.4         119.5
                        2,6-DIMETHNAPH *                 0.3                J              43.3                              37.4                        14.7         109.0
                     1,6,7-TRIMETHNAPH *                 0.4                J              47.0                              41.4                        12.6         111.6
                          1 -METHYLPHEN *                0.07               J              54.5                              63.2                        14.8         118.9





                                               Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                      INVEST#      Lab QA Sample                        FBFO                     Lab QA Sample                     RPD Lab QA Sample
                                              ID,    Proc Blank                     Florida Bay                         FBFO                                     FBFO
                                           SITE                                         Flamingo                        Flamingo                                 Flamingo
                                  LABSAMNO               Q9500                          K8093                           Q9502                                    Q9503
                               SAMPLE TYPE               BLANK                          SAMP                            DUP                                      MS
                                          UNIT           ng/g                           ng/g                            ng/g                                      %
                                  PNA Analyte            Conc         DB QUAL           Conc       DB QUAL              Conc         DB QUAL                     Recovery     DB QUAL


                              RECEIPT DATE                                              01/27/94                        01/27/94                                 01/27/94
                                    QCBATCH              M1412                          M1412                           M1412                                    M1412
                        EXTRACTION DATE                  08/01/94                       08/01/94                        08/01/94                                 08/01/94
                                      METHOD             GCMS                           GCMS                            GCMS                                     GCMS
                            ANALYSIS DATE                09/05/94                       09/05/94                        09/05/94                                 09/05/94
                                      MATRIX                                            TISSUE                          TISSUE                                   TISSUE
                                      WETWT                                             10.03                           10.01                                    10.02
                                      DRYWT              10.00                          1.04                            1.02                                     0.99
                                      WTUNITS            GRAMS           DRY            GRAMS         DRY               GRAMS           DRY                      GRAMS           DRY
                                   PCTSOLIDS                                            10.4%                           10.2%                                    9.8%
                                      % LIPIDS                                          6.25                            7.74                                     8.34
                                                                                                                                                                                      ... . .... ....
             Surrogate
                              Recoveries PAHs
                                      NAPHD8             55.2                           58.3                            51.2                                     53.3
                                      ACEND10            51.8                           57.5                            50.3                                     55.5
                                      PHEND10            53.4                           65.9                            58.9                                     63.2
                                      CHRYD12            47.2                           63.8                            57.8                                     50.4
                                      PERYD12            8.5               Q            21.4                            25.6                                     22.7
                            NAPHTHALENE*                 2.8                            25.4                            29.7                       15.8          114.8
                        Cl-NAPHTHALENES                  1.3               J            56.7                            53.6                       5.7                            NA
                        C2-NAPHTHALENES                                   ND            70.5                            64.7                       8.6                            NA
                        C3-NAPHTHALENES                                   ND            122.0                           112.2                      8.3                            NA
                        C4-NAPHTHALENES                                   ND            98.9                            76.3                       25.8                           NA
                                 BIPHENYL                0.4               J            9.3             J               10.6              J        12.7          108.2
                        ACENAPHTHYLENE                   0.1               J            2.8             J               3.1               J        12.6          103.7
                           ACENAPHTHENE*                 0.2               J            1.8             J               1.4               J        22.5          109.5





                                                   Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                         INVEST#       Lab QA Sample                           FBFO                       Lab QA Sample                        RPD Lab QA Sample
                                                 ID       Proc Blank                       Florida Bay                           FBFO                                       FBFO
                                              SITE                                          Flamingo                          Flamingo                                    Flamingo
                                     LABSAMNO               Q9500                              K8093                             Q9502                                      Q9503
                                 SAWLE TYPE                BLANK                               SAW                               DUP                                          MS
                                             UNIT             ng/9                             ng/g                              ng/g                                          %
                                    PNA Analyte               Conc          DB QUAL            Conc        DB QUAL               Conc          DB QUAL                    Recovery          DB QUAL


                                    FLUORENE*                 0.2                J             8.4              J                7.1                 J         17.1         109.3
                                CI-FLUORENES                                    ND             36.9                              31.1                          16.8                             NA
                                C2-FLu6RENEs                                    ND             114.9                             141.7                         20.9                             NA
                                0-FLUORENES                                     ND             135.8                             96.9                          33.4                             NA
                            PHENANTHRENE                      0.6                              20.5                              17.9                          13.6         94.5
                                ANTHRACENE*                   0.1                J             3.9              J                4.9                 J         22.3         24.6                  Q
                             CI-PHEN-ANTHR                                      ND             49.7                              42.9                          14.7                             NA
                             C2-PHEN-ANTHR                                      ND             91.5                              70.3                          26.2                             NA
                             C3-P]HEN-ANTHR                                     ND             80.5                              59.6                          29.7                             NA
                             C4-PHEN ANTBR                                      ND             31.0                              22.96                         29.8                             NA
                                                                                                                                                                                      ...............................
                                  DIBENZOTHIO                 0.1                J             2.0              J                1.6                 J         22.1         87.8
                                       Cl-DIBEN                                 ND             5.7              J                5.4                 J         5.8                              NA
                                       C2-DIBEN                                 ND             16.9                              15A                           10.7                             NA
                                       C3-DIBEN                                 ND             17.8                              18.1                          1.8                              NA
                             FLUORANTBENE*                    0.2                J             39.7                              33.9                          15.8         95.9
                                       PYRENE*                0.2                J             38.3                              32.2                          17.1         96.7
                            C I -FLUORAN PYR                                    ND             49.7                              37.79                         27.2                             NA
                        BENaANTHRACENE                        0.0                J             9.0                               5.2                           53.2         85.5
                                    CHRYSENE*                 0.1                J             13.9                              15.1                          8.5          109.5
                                Cl-CHRYSENES                                    ND             13.3                              11.2                J         16.8                             NA
                                C2-CHRYSENES                                    ND             9.9                               7.9                 J         22.4                             NA
                                C3-CHRYSENES                                    ND                             ND                                  ND                                           NA
                                C4-CHRYSENES                                    ND                             ND                                  ND                                           NA
               TOTAL BENk/BENbFLUORAN                         0.1                              11.2                              8.4                           27.9         103.1
                                BENePYRENE *                  0.1                J             8.4                               7.7                           8.8          115.0
                                BENaPYRENE *                  0.0                J             0.8              J                0.9                 J         11.2         62.9





                                                  Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#       Lab QA Sample                          FBFO                      Lab QA Sample                      RPD Lab QA Sample
                                                ID      Proc Blank                       Florida Bay                          FBFO                                     FBFO
                                             SITE                                         Flamingo                        Flamingo                                   Flamingo
                                    LABSAMNO              Q9500                              K8093                            Q9502                                    Q9503
                                SAMPLE TYPE               BLANK                              SAMP                             DUP                                        MS
                                            UNIT            ng/g                             ng/g                             ng/g                                       %
                                    PNA Analyte             Conc          DB QUAL            Conc       DB QUAL               Conc         DB QUAL                   Recovery         D13 QUAL


                                   PERYLENE*                0.5                J             1.7             J                0.8               J         70.9         84.9
                                 I123cdPYRENE               0.0                J             2.7                              1.9                         33.8         103.6
                               DBahANTHRA *                 0.0                J             0.3             J                0.3               J         3.3          102.9
                                BghiPERYLENE                0.03               J             9.1                              7.4                         20.5         108.0                ..... .......


                                   TOTALPAHs                6.9                              1210.4                           1058.0                      13.4
                            S&T Total PAHS                  7.48                             298.7                            274.85                      8.3


                            2-METHYLNAPH *                  0.6                J             39.6                             34.5                        13.8         108.5
                            1 -METHYLNAPH *                 0.6                J             17.1                             19.1                        11.0         118.0
                          2,6-DIMETHNAPH *                  0.6                J             32.3                             28.6                        12.4         103.6
                       1,6,7-TRIMETHNAPH *                  0.1                J             18.7                             15.7                        17.3         104.2
                            I-MET14YLPHEN *                 0.07               J             9.7                              9.23                        4.4          100.8





                                                 Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#       NIST SRM 1974a                     Lab QA Sample                     Lab QA Sample                      Lab QA Sample
                                                ID    Consensus Values                     SRM 1974a                          SRM 1974a                          SRM[ 1974a
                                             SITE
                                    LABSAMNO                 SRM                               Q9491                              Q9501                              Q9496
                                SAWLE TYPE                                                     SRM                                SRM                                SRM
                                            UNIT             ng/g                              ng/g                               ng/g                               ng/g
                                    PNA Analyte              Conc            Std Dev           Conc          DB QUAL              Conc          DB QUAL              Conc         DBQUAL


                                RECEIPT DATE
                                      QCBATCH                                                  M1410                              M1412                              M1411
                          EXTRACTION DATE                                                      07/21/94                           08/01/94                        07/25/94
                                       METHOD                                                  GCMS                               GCMS                               GCMS
                             ANALYSIS DATE                                                     09/03/94                           09/05/94                        09/05/94
                                        MATRIX                                                 TISSUE                             TISSUE                          TISSUE
                                         WETWT                                                 5.02                               5.01                               5.00
                                         DRYWT                                                 0.49                               0.59                               0.44
                                       WTUNITS                                                 GRAMS            DRY               GRAMS            DRY            GRAMS              DRY
      to                             PCTSOLIDS                                                 9.8%                               11.8%                              8.8%
                                       % LIPIDS                                                3.9                                5.58                               4.1
              Surrogate
                               Recoveries PAI-Is
                                        NAPHD8                                                 56.8                               50.0                               37.7
                                       ACENDIO                                                 61.3                               48.6                               55.5
                                       PHENDIO                                                 69.8                               60.0                               59.1
                                       CHRYD12                                                 68.0                               52.4                               68.1
                                       PERYD12                                                 14.4               Q               22.5                               23.6
                              NAPHTHALENE*                   14.9              8.5             34.3                               31.6                               39.1
                          Cl-NAPHTHALENES                                                      24.6               J               31.9                               32.7              J
                          C2-NAPHTHALENES                                                      44.5                               30.8                               71.5
                          C3-NAPHTHALENES                                                      115.8                              114.8                              166.1
                          C4-NAPHTHALENES                                                      165.8                              168.4                              322.3
                                   BIPHENYL *                4.1               1.4             10.3               J               19.0              J                12.0              J
                          ACENAPHTHYLENE,                    4.9               2.0             9.1                J               11.5              J                14.2              J
                           ACENAPHTHENE                      3.1               1.1             5.8                J               7.3               J                7.4               J




                                             M M M M im M @ w M M M @ @, = M
                                                 Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                       INVEST#       NIST SRM 1974a                    Lab QA Sample                      Lab QA Sample                     Lab QA Sample
                                               ID    Consensus Values                     SRM 1974a                         SRM 1974a                         SRM 1974a

                                            SITE
                                    LABSAMNO                SRM                               Q9491                             Q9501                             Q9496
                                SAWLE TYPE                                                    SRM                               SRM                               SRM
                                            UNIT            ng/g                              ng/g                              ng/g                              ng/g
                                   PNA Analyte              Conc            Std Dev           Conc         DB QUAL              Conc          DB QUAL             Conc          DB QUAL


                                   FLUORENE*                4.2               0.8             6.3               J               9.7                J              6.2                 J
                               Cl-FLUORENES                                                   37.4              J               35.6               J              49.2                J
                               C2-FLUORENES                                                   137.2                             125.5                             159.1
                               C3-FLUORENES                                                   233.0                             195.9                             362.2
                           PHENANTHRENE *                   17.9              5.1             39.7                              22.2                              30.4
                               ANTHRACENE *                 7.3               2.8             11.7              J               9.5                J              6.6                 J
                            Cl-PHEN-ANTHR                                                     71.6                              51.9                              74.6
                            C2-PHEN-ANTUR                                                     227.0                             185.9                             286.1
                            C3-PHEN-ANTHR                                                     550.1                             418.5                             672.2
                            C4-PHEN ANTHR                                                     252.47                            207.08                            281.83
                                                                                                                                                                                    .... . .................... ......
                                 DIBENZOTMO                                                   4.0               J               2.9                J              6.6                 J
                                     Cl-DIBEN                                                 25.4                              20.1                              24.5
                                     C2-DIBEN                                                 138.8                             89.1                              169.2
                                     C3-DEBEN                                                 232.3                             145.3                             265.5
                            FLUORANTHENE*                   187.0             55.0            233.5                             173.1                             305.9
                                     PYRENE*                178.0             43.0            209.7                             162.7                             290.7
                           Cl-FLUORAN        PYR                                              174.16                            144.62                            234.38
                        BENaANTHRACENE *                    37.4              9.2             27.4                              34.4                              34.1
                                   CHRYSENE*                89.0              21.9            113.0                             81.7                              134.6
                               Cl-CHRYSENES                                                   64.2                              58.4                              93.0
                               C2-CHRYSENES                                                   49.1                              42.6                              81.4
                               C3-CHRYSENES                                                   5.9               J                                ND               8.3                 J
                               C4-CHRYSENES                                                   16.84             J                                ND               13.71               J
                                                                                                                                                                             . . ..... . ... ...
               TOTAL BENk/BENbFLUOR N                                                         104.0                             71.8                              104.7
                               BENePYRENE *                 91.3              21.0            123.4                             85.9                              112.9
                               BENaPYRENE *                 17.5              3.8             13.5                              11.2                              14.6




    mmm mm m mom mm mm m m M M mm
                                                    Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                          INVEST#       NIST SRM 1974a.                      Lab QA Sample                       Lab QA Sample                        Lab QA Sample
                                                  ID    Consensus Values                       SRM 1974a                            SRM 1974a.                          SRM 1974a

                                               SITE
                                      LABSAMNO                  SRM                                 Q9491                               Q9501                                Q9496
                                  SAWLE TYPE                                                        SRM                                 SRM                                  SRM
                                              UNIT              ng/g                                ng/g                                ng/g                                 ng/g
                                     PNA Analyte                Conc             Std Dev            Conc          DB QUAL               Conc          DB QUAL                Conc          DB QUAL

                                     PERYLENE*                  7.2                2.2              18.6                                9.2                 J                19.6
                                   1123cdPYRENE                 16.1               4.6              18.2                                10.6                                 16.9
                                DBahANTHRA *                    2.6                1.1              4.6                J                2.7                 J                4.1                J
                                  BghiPERYLENE                  27.5               6.7              32.74                               24.22                                29.48               ............. . ......


                                    TOTAL PAHs                  710.1                               3586.1                              2847.4                               4557.8
                              S&T Total PAHs                                                        913.08                              739.72                               1090.02


      U1                      2-METHYLNAPH                      7.3                3.1              13.2               J                18.8                                 15.9               J
                              I-METHYLNAPH*                     4.4                1.9              11.4               J                13.1                                 16.8
                            2,6-DIMETHNAPH *                    5.8                4.2              13.0               J                13.3                J                10.8               J
                         1,6,7-TRIMETHNAPH *                    5.0                2.5              9.5                J                20.5                                 12.0               J
                              I-MEMYLPHEN *                     10.6                 3              14.03              J                14.02               J                16.5




                                                                                      @Mwa M, MM MM mom
                                                Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#       Lab QA Sample                    Lab QA Sample                     Lab QA Sample                      Lab QA Sample
                                                ID   GERG Std Chk III                  GERG Std Chk                       GERG Std Chk                      GERG Std Chk
                                             SITE    LABORATORY
                                    LABSAMNO            RUNNING                              W1770                             W1773                              W1775
                                SAUTLE TYPE             AVERAGE                              REF                               REF                                REF
                                            UNIT           nglamp                            ng/amp                            ng/amp                             ng/amp
                                    PNA Analyte            Average         Std Dev.          Conc          DB QUAL             Conc          DB QUAL              Conc         DB QUAL


                                RECEIPT DATE
                                      QCBATCH                                                M1410                             M1410                              M1410
                          EXTRACTION DATE
                                        METHOD                                               GCMS                              GCMS                               GCMS
                              ANALYSIS DATE                                                  09/03/94                          09/04/94                           09/04/94
                                        MATRIX                                               OIL                               OIL                                OIL
                                        WETWT
                                        DRYWT
                                        VITUNITS
                                     PCTSOLIDS
                                        % LIPIDS
              Surrogate
                                Recoveries PAHs
                                        NAPHD8                                                                NA                                 NA                                NA
                                        ACENDIO                                                               NA                                 NA                                NA
                                        PHEND10                                                               NA                                 NA                                NA
                                        CHRYD12                                                               NA                                 NA                                NA
                                        PERYD12                                                               NA                                 NA                                NA
                                                                                                                                                                                . . . ....... . .
                              NAPHTHALENE*                 576.2            20.2             506.2                             519.6                              510.3
                          Cl-NAPHTTIALENES                 2434.8           125.9            2097.3                            2168.2                             2094.1
                          C2-NAPHTHALENES                  1902.8           160.0            2456.7                            2547.7                             2385.7
                          C3-NAPHTHALENES                  1440.7           217.6            2281.0                            2363.8                             2155.1
                          C4-NAPHTHALENES                  789.3            158.7            1430.3                            1518.4                             1330.8
                                   BIPHENYL *              193.9            20.4             189.2                             187.6                              200.2
                          ACENAPHTHYLENE                    1.3              0.5             1.1                J              1.1                J               0.5               J
                            ACENAPHTHENE*                    17.4            1.7             17.2               J              14.5               J               16.3              J




    MM
                                                 Mussel Watch Project Year 9 - PAR QC Data (Tissue)


                                         INVEST#       Lab QA Sample                     Lab QA Sample                       Lab QA Sample                      Lab QA Sample
                                                 ID   GERG Std Chk III                    GERG Std Chk                       GERG Std Chk                        GERG Std Chk
                                              SITE     LABORATORY
                                     LABSAMNO             RUNNING                               W1770                              W1773                               W1775
                                 SAWLE TYPE               AVERAGE                               REF                                REF                                 REF
                                             UNIT             ng/amp                            nglamp                             ng/amp                              ng/amp
                                     PNA Analyte              Average        Std Dev.           Conc          DB QUAL              Conc          DB QUAL               Conc         DB QUAL

                                    FLUORENE*                 93.2              7.6             89.6                               86.3                                88.7
                                Cl-FLUORENES                  213.3             31.4            274.9                              254.3                               254.8
                                C2-FLUORENES,                 343.7             35.0            555.8                              525.9                               552.8
                                C3-FLUORENES                  370.1             61.6            698.4                              671.2                               646.1
                             PHENANTHRENE*                    266.0             23.0            260.9                              261.8                               239.4
                                ANTHRACENE*                   5.9               2.8             6.1                J               6.8                 J               10.6               J
                              Cl-PHEN-ANTHR                   583.2             91.0            688.4                              699.9                               693.2
                              C2-PBEN-ANTHR                   656.2             106.3           852.2                              911.9                               842.4
                              C3-PHEN-ANTHR                   481.9             128.7           871.6                              913.2                               844.4
                              C4-PHEN ANTHR                   212.4             75.3            456.1                              505.34                              463.3
                                  DIBENZOTHIO                 218.9             22.1            192.6                              194.7                               191.8
                                       Cl-DIBEN               414.9             66.3            479.8                              486.9                               488.6
                                       C2-DIBEN               571.6             106.8           805.5                              833.1                               782.8
                                       C3-DIBEN               506.5             90.8            792.3                              845.6                               735.5
                             FLUORANTHENE*                    5.0               1.1             4.9                J               10.0                J               5.7                J
                                       PYRENE*                13.1              2.3             11.3               J               14.4                J               8.8                J
                            Cl-FLUORAN PYR                    94.0              18.2            102.4                              110.63                              110.74
                          BENaANTHRACENE*                     5.6               1.0             5.5                J               7.0                 J               4.6                J
                                    CHRYSENE*                 52.4              5.4             53.1                               46.6                                49.3
                                Cl-CHRYSENES                  91.4              63.5            89.6                               88.9                                90.2
                                C2-CHRYSENES                  115.5             77.6            143.1                              135.8                               132.9
                                C3-CHRYSENES                  30.4              22.2            19.7               J               23.1                                26.5
                                C4-CHRYSENES                  21.5              18.0            21.2                               22.03                               23.39
                TOTAL BENk/BENbFLUORAN                        3.5               0.4             7.8                                8.3                                 7.4
                                BENePYRENE *                  11.3              1.1             11.5               J               12.9                J               11.2               J
                                BENaPYRENE *                  2.0               0.7             1.7                J               1.7                 J               2.4                1




                                                                                                                                       mom, momm M
                                                Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#       Lab QA Sample                   Lab QA Sample                     Lab QA Sample                     Lab QA Sample
                                               ID    GERG Std Chk III                  GERG Std Chk                     GERG Std Chk                      GERG Std Chk
                                             SITE    LABORATORY
                                    LABSAMNO            RUNNING                            W1770                             W1773                            W1775
                                SAMPLE TYPE             AVERAGE                              REF                              REF                               REF
                                            UNIT           ng/amp                          ng/amp                            ng/amp                           ng/amp
                                    PNA Analyte            Average        Std Dev.           Conc         DB QUAL             Conc         DB QUAL              Conc         DB QUAL


                                   PERYLENE*                2.0             0.6               1.9              J              2.0               J               2.3               J
                                 1123cdPYRENE               0.9             0.3              0.7               J              1.1               J               0.9               J
                               DBahANTHRA *                 1.8             0.5               1.7              J              2.2               J               1.5               J
                                 BghiPERYLENE               4.2             0.9               3.7              J              4.19              J               4.08 . . . ....... . ....J........ . ..

                                  TOTAL PA-Hs              12752.3                         16483.0                           17008.5                          16009.1
                             S&T Total PAHs (*)            5072.3                          4583.16                           4621.27                          4569.21


                             2-METHYLNAPH *                1347.9           70.7           1153.3                            1211.5                           1160.1
                             I-METHYLNAPH*                 1086.9           58.1           944.0                             956.7                            934.0
                           2,6-DIMETHNAPH *                775.3            64.6           743.5                             726.9                            752.5
                        1,6,7-TRIMETHNAPH *                438.9            30.2           421.9                             394.9                            401.1
                             1-METHYLP14EN *               177.6            21.4           159.66                            157.88                           170.25




                                  MM M M so M MM @'M M am
                                                 Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                         INVEST#      Lab QA Sample                      Lab QA Sample                    Lab QA Sample                     Lab QA Sample
                                                ID    GERG Std Chk                      GERG Std Chk III                  GERG Std Chk                       GERG Std Chk
                                              SITE                                      LABORATORY
                                     LABSAMNO               W1789                          RLNNING                              W1792                             W1794
                                 SAMPLE TYPE                REF                            AVERAGE                              REF                               REF
                                             UNIT           nglamp                            ng/amp                            ng/amp                            ng/amp
                                    PNA Analyte             Conc          DB QUAL             Average         Std Dev.          Conc          DB QUAL             Conc          DB QUAL


                                 RECEIPT DATE
                                       QCBATCH              M1412                                                               M1412                             M1412
                           EXTRACTION DATE
                                        METHOD              GCMS                                                                GCMS                              GCMS
                              ANALYSIS DATE                 09/05/94                                                            09/05/94                          09/06/94
                                         MATRIX             OIL                                                                 OIL                               OIL
                                          WETWT
                                          DRYWT
                                        WTUNITS
                                      PCTSOLIDS
                                       % LIPIDS
               Surrogate
                                Recoveries PAHs
                                         NAPHD8                              NA                                                                  NA                                 NA
                                        ACENDIO                              NA                                                                  NA                                 NA
                                        PHEND10                              NA                                                                  NA                                 NA
                                        CHRYD12                              NA                                                                  NA                                 NA
                                        PERYD12                              NA                                                                  NA                                 NA
                              NAPHTHALENE                   547.4                             576.2            20.2             541.2                             519.1
                           Cl-NAPHTHALENES                  2199.2                            2434.8           125.9            2179.6                            2152.4
                           C2-NAPHTHALENES                  2482.4                            1902.8           160.0            2519.0                            2472.2
                           C3-NAPHTHALENES                  2252.0                            1440.7           217.6            2319.9                            2331.1
                           C4-NAPHTHALENES                  1428.5                            789.3            158.7            1492.4                            1485.4
                                    BIPHENYL                188.4                             193.9            20.4             200.4                             181.8
                           ACENAPHTHYLENE                   0.6                J               1.3              0.5             1.2                J              0.5                J
                             ACENAPHTHENE*                  15.4               J               17.4             1.7             16.7               J              16.2               J




                         im mm.= Mao                                                             MM @'M M NwM M M M
                                                  Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                          INVEST#      Lab QA Sample                       Lab QA Sample                    Lab QA Sample                      Lab QA Sample
                                                  ID    GERG Std Chk                      GERG Std Chk III                   GERG Std Chk                       GERG Std Chk
                                               SITE                                        LABORATORY
                                      LABSAMNO                W1789                          RUNNING                               W1792                              W1794
                                   SAMPLE TYPE                REF                            AVERAGE                               REF                                REF
                                              UNIT            ng/amp                             ng/amp                            ng/amp                             ng/amp
                                      PNA Analyte             Conc         DB QUAL               Average        Std Dev.           Conc          DB QUAL              Conc         DB QUAL


                                     FLUORENE*                84.0                               93.2              7.6             86.2                               82.5
                                  Cl-FLUORENES                246.3                              213.3             31.4            271.1                              254.4
                                  C2-FLUORENES                526.6                              343.7             35.0            570.9                              525.2
                                  C3-FLUORENES                643.9                              370.1             61.6            697.8                              667.4
                              PHENANTHRENE*                   245.0                              266.0             23.0            252.8                              247.0
                                  ANTHRACENE*                 8.9                J               5.9               2.8             9.1                 J              10.0               J
                               Cl-PHEN-ANTHR                  659.9                              583.2             91.0            675.4                              683.4
                               C2-PHEN-ANTHR                  844.6                              656.2             106.3           866.3                              889.1
                               C3-PHEN ANTHR                  825.6                              481.9             128.7           869.4                              903.4
                               C4-PHEN ANTUR                  433.2                              212.4             75.3            469.23                             510.5
                                   DIBENZOTHIO                200.7                              218.9             22.1            198.4                              193.9
                                        Cl-DIBEN              467.6                              414.9             66.3            473.7                              507.2
                                        C2-DIBEN              758.1                              571.6             106.8           790.9                              843.3
                                        C3-D1BEN              763.4                              506.5             90.8            787.3                              824.3
                             FLUORANTHENE *                   3.6                J               5.0               1.1             4.6                 J              5.5                J
                                        PYRENE*               10.7               J               13.1              2.3             11.5                J              8.6                J
                             Cl-FLUORAN PYR                   92.85                              94.0              18.2            102.68                             120.31
                           BENaANTHRACENE*                    4.2                J               5.6               1.0             5.7                 J              5.2                J
                                     CHRYSENE*                47.4                               52.4              5.4             44.4                               49.6
                                  CI-CHRYSENES                81.2                               91.4              63.5            86.0                               92.1
                                  C2-CHRYSENES                126.3                              115.5             77.6            133.1                              138.4
                                  C3-CHRYSENES                25.8                               30.4              22.2            22.9                               27.1
                                  C4-CHRYSENES                16.42              J               21.5              18.0            20.36                              21.23
                 TOTAL BENk/BENbFLUORAN                       6.2                                3.5               0.4             6.8                                7.1
                                  BENePYRENE *                12.4               J               11.3              1.1             11.8                J              12.2               J
                                  BENaPYRENE *                1.0                J               2.0               0.7             1.3                 J              2.7                J



                       mmm = MIM M M mmm MM M M MM
                                                Mussel Watch Project Year 9 - PAH QC Data (Tissue)


                                        INVEST#     Lab QA Sample                     Lab QA Sample                   Lab QA Sample                     Lab QA Sample
                                               ID    GERG Std Chk                    GERG Std Chk III                  GERG Std Chk                     GERG Std Chk
                                             SITE                                     LABORATORY
                                    LABSAMNO               W1789                         RUNNING                             W1792                           W1794
                                 SAUTLE TYPE               REF                          AVERAGE                              REF                               REF
                                            UNIT           ng/amp                          ng/amp                            ng/amp                          ng/amp
                                    PNA Analyte            Conc        DB QUAL             Average        Std Dev.           Conc         DB QUAL             Conc         D13 QUAL

                                   PERYLENE*               2.6                               2.0             0.6             2.6                              2.1
                                  I123cdPYRENE             1.1                               0.9             0.3             0.7                              0.9
                               DBahANTHRA *                1.4                               1.8             0.5             1.3                              1.2
                                 BghiPERYLENE              3.63                              4.2             0.9             4.4                               4.49


                                   TOTALPAHs               16258.2                         12752.3                           16748.9                         16799.3
                             S&T Total PAHs                4645.71                         5072.3                            4778.85


      c.n
      C-n                    2-MIETHYLNAPH                 1210.8                          1347.9            70.7            1208.1                          1178.7
                             I-METHYLNAPH*                 988.5                           1086.9            58.1            971.5                            973.7
                           2,6-DMETHNAPH *                 707.4                           775.3             64.6            747.2                            695.0
                        1,6,7-TRUvIETHNAPH *               390.3                           438.9             30.2            424.0                           402.3
                             I-METHYLPHEN *                176.59                          177.6             21.4            238.47                           178.41



 I
 I
 I
 I
 I
 I-
 I
.I                 . PAH Data
 i                 (Sediment)
 I
 I
 I
 I
 I
 I
 I
 I
 I
                         1%
 I





                                                  Mussel Watch Project Year 9 - PAH Data (Sediment)


                          INVEST#          FBFO                      FBFO                    FBFO                     FBJB                     FBJB,                    FBJB
                                  ID   Florida Bay              Florida Bay              Florida Bay              Florida Bay              Florida Bay              Florida Bay
                               SITE      Flamingo                 Flamingo                 Flamingo                   Joe Bay                  Joe Bay                  Joe Bay
                      LABSAMNO             K8098                     K8099                   K8100                    K8113                    K8114                    K8115
                   SAMPLE TYPE             SAW                       SAW                     SAW                      SAW                      SAW                      SAW
                              UNIT         ng/g                      ng1g                    ng/g                     ng/g                     ng/g                     ng/g
                      PNA Analyte          Conc      D13 QUAL        Conc     DD QUAL        Conc      DB QUAL        Conc      DB QUAL        Conc      DB QUAL        Conc      DB Q.UAL

                  RECEIPT DATE           01/27/94                 01/27/94                 01/27/94                   01/27/94                 01/27/94                 01/27/94
                        QCBATCH            M2106                     M2106                   M2106                    M2106                    M2106                    M2106
            EXTRACTION DATE              07/19/94                 07/19/94                 07/19/94                   07/19/94                 07/19/94                 07/19/94
                          METHOD           GCMS                      GCMS                    GCMS                     GCMS                     GCMS                     GCMS
                ANALYSIS DATE            08/06/94                 08/06/94                 08/09/94                   08/07/94                 08/07/94                 08/07/94
                          MATRIX       SEDIMENTS                SEDIMENTS                SEDIMENTS                SEDIMENTS                SEDIMENTS                SEDIMENTS
                          SUBMAT
                          WETWT            30.03                     30.07                   30.22                    30.21                    30.16                -@o 1-9
                          DRYWT            8.95                      8.27                    8.05                     8.73                     9.46                     8.87
                          ViTUNITS       GRAMS          DRY       GRAMS          DRY       GRAMS         DRY          GRAMS       DRY          GRAMS       DRY          GRAMS       DRY
                       PCTSOLIDS           29.8%                     27.5%                   26.7%                    28.9%                    31.3%                    29.4%
              Surrogate
                  Recoveries PAHs

                          NAPHD8           75.0                      70.8                    61.2                     67.0                     85.6                     81.0
                          ACEND10          77.2                      76.0                    67.4                     73.2                     91.7                     79.8

                          PHENDIO          68.9                      72.7                    60.0                     65.2                     80.7                     75.5
                          CHRYD12          79.6                      71.2                    66.3                     78.3                     94.7                     81.7
                          PERYD12          73.7                      63.4                    64.0                     60.7                     74.3                     70.2
                                                                                                                                                                               ......... . ..
               NAPHTHALENE                 4.3                       2.5                     3.0                      2.5                      1.4                      1.7
            Cl-NAPHTHALENES                6.6                       2.3                     2.8                      2.5                      1.3                      1.5
            C2-NAPHTHALENES                5.4                       1.6                     2.5                      1.7                      1.3                      1.3
            C3-NAPHTHALENES                6.7           J           2.8          1          3.7                                   ND                       ND                       ND

            C4-NAPHTHALENES                4.9                                   ND                       ND                       ND                       ND                       ND
                     BIPHENYL              1.0                       0.5                     0.7                      0.4                      0.3                      0.4
            ACENAPHTHYLENE                 10.0                      0.3                     0.5                      0.2                      0.3                      0.2
               ACENAPHTHENE*               0.7                       0.2                     0.3                      0.1                      0.2                      0.2





                                                 Mussel Watch Project Year 9 - PAH Data (Sediment)


                           INVEST#          FBFO                     FBFO                     FBFO                     FBJB                     FBJB                     FBJB
                                  ID    Florida Bay              Florida Bay              Florida Bay              Florida Bay              Florida Bay              Florida Bay
                                SITE     Flamingo                 Flamingo                 Flamingo                    Joe Bay                  Joe Bay                  Joe Bay
                       LABSAMNO             K8098                    K8099                    K8100                    K8113                    K8114                    K8115
                   SAMPLE TYPE              SAMP                     SAMP                     SAND                     SAMP                     SAMP                     SAMP
                               UNIT         ng/g                     ng/g                     ng/g                     ng/g                     ng/g                     ng/g
                      PNA Analyte           Conc      DB QVAL        Conc      DB QUAL        Conc      DB QUAL        Conc     DB QUAL         Conc     DB QUAL         Conc     DB QUAL


                      FLUORENE*             4.4            1         0.3           1          0.4           1          0.4           1          0.3                      0.4           1
                  Cl-FLUORENES              3.5            1                      ND          1.0           1                      ND           0.5                                  ND
                  C2-FLUORENES              10.0                                  ND          1.9           1                      ND           1.2           1                      ND
                  O-FLUORENES               13.6                                  ND          6.3           1                      ND           2.3           1                      ND
               PHENANTHRENE*                18.0                     1.3                      1.8                      1.6                      1.4                      1.1
                  ANTHRACENE*               56.7                     0.3                      0.9                      0.3                      0.6                      0.3
                Cl-PHEN-ANTHR               22.3                                  ND          21.3                     0.8                      1.3                      0.7
                C2-PHEN-ANTHR               27.5                                  ND          38.0                     1.6                      2.6                      1.0
                C3-PHEN-ANTHR               22.3                                  ND          22.4                     1.2                      1.1                      1.6
                C4-PHEN ANUR                10.2           1                      ND                      ND                       ND                       ND                       ND
                                                                                                                                                                                ............ . .
                    DIBENZOTHIO             0.9                      0.1                      0.2                      0.1                      0.1                      0.1
                         Cl-DIBEN           1.8                                   ND                      ND                       ND                       ND                       ND

                         C2-DIBEN           4.1            1                      ND                      ND                       ND                       ND                       ND

                         O-DIBEN            6.1            1                      ND                      ND                       ND                       ND                       ND
               FLUORANTHENE*                86.1                     1.7                      5.5                      2.4                      3.6                      1.4           1
                         PYRENE*            80.0                     1.3                      5.3                      1.3                      3.4                      1.1
              Cl-FLUORAN PYR                66.6                     1.0                      3.8           J          1.0           1          2.4           1          0.4
              BENaANTHRACENE*               49.6                     1.3           1          1.6                      0.4           1          1.2           J          0.9           J
                      CHRYSENE*             65.1                     0.9                      2.9                      0.6                      1.5                      0.7
                  Cl-CHRYSENES              28.5                     0.6                      3.4                      0.5                      1.8           1                      ND
                  C2-CHRYSENES              15.0                     0.9                      2.1           1          0.5           J          1.4           1                      ND
                  O-CHRYSENES,              1.0            1                      ND                      ND                       ND                       ND                       ND

                  C4-CHRYSENES              7.1                                   ND                      ND                       ND                       ND                       ND
                  BENbFLUORAN               50.2                     0.8                      2.5           1          0.7                      1.6                      0.6
                  BENkFLUORAN,              50.2                     0.8                      2.5                      0.7                      1.6                      0.6
                  BENePYRENE *              35.7                     0.6                      2.1                      0.5                      1.2                      0.5
                  BENaPYRENE *              40.7                     0.6                      2.3                      0.5                      1.4                      0.5




                                             mmmmmmm M M mmmm M M
                                                   Mussel Watch Project Year 9 - PAH Data (Sediment)


                            INVEST#          FBFO                      FBFO                     FBFO                     FBJB                     FBJB                     FBJB,
                                   ID    Florida Bay               Florida Bay              Florida Bay              Florida Bay              Florida Bay               Florida Bay
                                 SITE     Flamingo                  Flamingo                 Flamingo                    Joe Bay                  Joe Bay                  Joe Bay
                        LABSAMNO             K8098                     K8099                    K8100                    K8113                    K8114                    K8115
                    SAMPLE TYPE              SAMP                      SAMP                     SAMP                     SAMP                     SAMP                     SAMP
                                UNIT         ng/g                      nglg                     nglg                     ng/g                     ng/g                     ng/g
                       PNA Analyte           Conc      DB QUAL         Conc      DB QUAL        Conc      DB QUAL        Conc      DB QUAL        Conc      DB QUAL        Conc       DB QUAL


                       PERYLENE*             9.5            1          0.1           J          0.6           1          0.2           1          0.4                      0.1
                     1123cdPYRENE            26.3                      0.5                      1.7                      0.6                      1.0                      0.4
                   DBahANTHRA *              7.0                       0.1                      0.4                      0.1                      0.2                      0.1
                    BghiPERYLENE             27.3                      0.6                      2.2                      0.6                      1.4                      0.6      . .....


                       TOTALPAHs             877.6                     23.8                     145.8                    23.6                     39.8                     18.2
                  (w/o PERYLENE)


                S&T Total PAHs               479.0                     15.4                     32.4                     14.8                     19.5                     11.7


                2-METHYLNAPH *               4.4                       1.2                      1.8                      1.4                      0.8                      0.8
                I -METHYLN, - H *            2.2                       1.1                      1.0                      1.1                      0.5                      0.7
              2,6-DIMETHNAPH *               2.8                       0.4                      0.9                      0.5                      0.3                      0.5
              1,6,7-TRIMETHNAPH *            1.4                       0.3                      0.5                      0.5                      0.2                      0.2
                I-NIETHYLPHEN *              9.4                       0.6                      0.6                      0.2                      0.7                      0.2
              Surrogate Recoveries
                            NAPHD8           75.0                      70.8                     61.2                     67.0                     85.6                     81.0
                           ACENDIO           77.2                      76.0                     67.4                     73.2                     91.7                     79.8
                           PHENDIO           68.9                      72.7                     60.0                     65.2                     80.7                     75.5
                           CHRYD12           79.6                      71.2                     66.3                     78.3                     94.7                     81.7
                           PERYD12           73.7                      63.4                     64.0                     60.7                     74.3                     70.2




 I
 I
 I
 I
 I
 I
 I
:I                PAH QC Data
 I                 (Sediment)
 I
 I
 I
 I
 I
 I
 I
I I
 I
                         1%
 I





                                             Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                         INVEST#       Lab QA Sample                   Lab QA Sample                    Lab QA Sample
                                                                ID       Proc Blank                          FBFO                             FBFO
                                                              SITE                                       Florida Bay                      Florida Bay
                                                     LABSAMNO                Q9572                           Q9574                            Q9575
                                                 SAMPLE. TYPE             BLANK                               MS                              MSD
                                                             UNIT            ng/g                              %                                %
                                                    PNA Analyte              Conc         DB QUAL          Recovery        DB QUAL          Recovery        DB QUAL


                                                 RECEIPT DATE
                                                       QCBATCH               M2106                           M2106                            M2106
                                           EXTRACTION DATE                07/19/94                         07/19/94                         07/19/94
                                                        METHOD               GCMS                            GCMS                             GCMS
                                              ANALYSIS DATE               08/06/94                         08/06/94                         08/06/94
                                                         MATRIX         SEDIMENTS                       SEDIMENTS                        SEDIMENTS
                                                         SUBMAT
                                                          WETWT                                              30.12                            30.10
                                                          DRYWT              10.00                           8.03                             8.02
                                                        WTUNITS           GRAMS              DRY           GRAMS             DRY            GRAMS             DRY
       CA
       Go                                             PCTSOLIDS                                              26.7%                            26.7%
                                         Surrogate
                                                Recoveries PAHs
                                                         NAPHD8              75.0                            69.0                             73.3
                                                        ACEND10              60.7                            75.0                             75.6
                                                        PHENDIO              50.6                            76.2                             75.6
                                                        CHRYD12              63.2                            69.2                             62.4
                                                        PERYD12              26.9             Q              56.2                             63.3
                                               NAPHTHALENE*                  0.7              J              86.7                             82.7
                                           Cl-NAPHTHALENES                   0.4              J                               NA                               NA

                                           C2-NAPHTHALENES                                   ND                               NA                               NA
                                           C3-NAPHTHALENES                                   ND                               NA                               NA

                                           C4-NAPHTHALENES                                   ND                               NA                               NA
                                                    BIPHENYL *               0.2              J              83.8                             87.3
                                           ACENAPHTHYLENE,                   0.0              J              90.2                             90.1
                                             ACENAPHTHENE*                   0.1              J              92.8                             92.0


          NC=Non Certified





                                                 Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                             INVEST#        Lab QA Sample                      Lab QA Sample                      Lab QA Sample
                                                                     H)        Proc Blank                            FBFO                               FBFO
                                                                  SITE                                           Florida Bay                        Florida Bay
                                                         LABSAMNO                Q9572                               Q9574                              Q9575
                                                     SAUTLE TYPE                BLANK                                MS                                 MSD
                                                                 UNIT             ng/g                                 %                                  %
                                                        PNA Analyte               Conc          DB QUAL           Recovery         DB QUAL           Recovery          DB QUAL


                                                        FLUORENE*                 0.1                J               96.1                               92.3
                                                     Cl-FLUORENES                                   ND                                 NA                                 NA
                                                     C2-FLUORENES                                   ND                                 NA                                 NA
                                                     O-FLUORENES                                    ND                                 NA                                 NA
                                                PRENANTFMNE *                     0.6                J               84.2                               82.0
                                                     ANTHRACENE*                  0.1                J               74.2                               77.2
                                                 Cl-PHEN-ANTHR                                      ND                                 NA                                 NA
                                                 C2-PHEN-ANTER                                      ND                                 NA                                 NA
                                                 O-PHEN-ANTIM                                       ND                                 NA                                 NA
                                                 C4-PHEN ANTHR                                      ND                                 NA                                 NA
                                                     DIBENZOTfHO                  0.0                J               75.5                               78.5
                                                           Cl-DIBEN                                 ND                                 NA                                 NA
                                                           C2-DIBEN                                 ND                                 NA                                 NA

                                                           O-DIBEN                                  ND                                 NA                                 NA
                                                FLUORANTHENE *                    0.2                J               114.8                              69.2
                                                           PYRENE*                0.3                J               81.9                               72.1
                                                Cl-FLUORAN PYR                                      ND                                 NA                                 NA
                                            BENaANTHRACENE *                      0.0                J               69.9                               107.5
                                                        CHRYSENE*                 0.1                J               86.9                               95.0
                                                     Cl-CHRYSENES                                   ND                                 NA                                 NA
                                                     C2-CH RYSENES,                                 ND                                 NA                                 NA
                                                     O-CHRYSENES                                    ND                                 NA                                 NA
                                                     C4-CHRYSENES,                                  ND                                 NA                                 NA
                                                     BENbFLUORAN                  0.0                J               99.2                               95.6
                                                     BENkFLUORAN                  0.0                J               88.9                               86.5
                                                     BENePYRENE *                 0.0                1               88.2                               91.0
            NC=Non Certified                         BENaPYRENE *                 0.0                J               92.0                               92.1




                                  mmmmmm M M M MMMM M ==
                                              Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                          INVEST#      Lab QA Sample                    Lab QA Sample                    Lab QA Sample
                                                                 ID       Proc Blank                          FBFO                            FBFO
                                                              SITE                                        Florida Bay                      Florida Bay
                                                      LABSAMNO              Q9572                             Q9574                           Q9575
                                                  SAWLE TYPE               BLANK                               MS                             MSD
                                                              UNIT           ng/g                              %                                 %
                                                     PNA Analyte             Cone          DB QUAL         Recovery        DB QUAL          Recovery        DB QUAL


                                                    PERYLENE *               0.1               J              88.6                            92.2

                                                   1123cdPYRENE              0.0               J              75.2                            78.9
                                                 DBahANTHRA *                0.0               J              77.8                            84.1
                                                  BghiPERYLENE               0.0               J              78.5                            71.2


                                                    TOTAL PAHs               2.9                        AVG % RECOV                     AVG % RECOV
                                                (w/o PERYLENE)                                                86.9                            86.3
                                              S&T Total PAHS M               3.2


                                              2-METHYLNAPH *                 0.2               1              83.8                            83.3
                                              I-METHYLNAPH *                 0.2               J              93.6                            94.2
                                            2,6-DIMETHNAPH *                 0.2               J              82.7                            82.5
                                          1,6,7-TRIMETHNAPH *                0.1               J              97.4                            96.3
                                              I-NIETHYLPHEN *                0.1               J              88.7                            83.6
                                              Surrogate Recoveries
                                                          NAPHD8             75.0                             69.0                            73.3

                                                         ACEND10             60.7                             75.0                            75.6

                                                         PHEND10             50.6                             76.2                            75.6

                                                         CHRYD12             63.2                             69.2                            62.4
                                                         PERYD12             26.9              Q              56.2                            63.3











           NC=Non Certified





                                                  Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                  INVEST#        NIST SRM 1941 a                 Lab QA Sample                  Lab QA Sample                  Lab QA Sample
                                                          ID      Certified Values                 SRM 1941 a                  GERG Std Chk III                GERG Std Chk
                                                        SITE                                                                    LABORATORY
                                              LABSAMNO                  SRM                            Q9573                       RUNNING                           W1538
                                           SAMPLE TYPE                                                 SRM                         AVERAGE                           REF
                                                       UNIT             ng1g                           ng/g                          ng/amp,                         ng/amp
                                              PNA Analyte              Values            Range         Conc        DD QUAL           Average         Std Dev         Conc        DB QUAL


                                          RECEIPT DATE
                                                 QCBATCH                                               M2106                                                         M2106
                                    EXTRACTION DATE                                                  07/19/94
                                                  METHOD                                               GCMS                                                          GCMS
                                        ANALYSIS DATE                                                08/06/94                                                        08/05/94
                                                  MATRIX                                          SEDIMENTS                                                          OIL
                                                  SUBMAT            SEDIMENT
                                                  WETWT
                                                  DRYWT                                                1.01
                                                  WTUNITS                                            GRAMS            DRY
        0)
                                               PCTSOLIDS
                                 Surrogate
                                          Recoveries PAHs

                                                  NAPHD8                                               78.9                                                                          NA
                                                  ACENDIO                                              83.5                                                                          NA
                                                  PHENDIO                                              82.8                                                                          NA
                                                  CHRYD12                                              77.4                                                                          NA
                                                  PERYD12                                              65.2                                                                          NA
                                       NAPHTUALENE                      1010             +/-140        792.3                          576.2            20.2          549.1
                                    Cl-NAPHTHALENES                                                    368.5                         2434.8            125.9         2284.9
                                    C2-NAPHTHALENES                                                    223.5                         1902.8            160.0         2103.2
                                    C3-NAPHTHALENES                                                    182.9                         1440.7            217.6         1605.5
                                    C4-NAPHTHALENES                                                    67.7             J             789.3            158.7         508.7
                                             BIPHENYL *              NC 175              +/-18         70.5             J             193.9            20.4          192.5

                                    ACENAPHTHYLENE                    NC 37              +/-14         61.7                            1.3              0.5          0.8

                                     ACENAPHTHENE                     NC 41              +/-10         40.9             J             17.4              1.7          19.2


            NC=Non Certified





                                                     Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                      INVEST#         NIST SRM 194 1 a                  Lab QA Sample                     Lab QA Sample                   Lab QA Sample
                                                              ID       Certified Values                   SRM 1941a                     GERG Std Chk III                  GERG Std Chk
                                                           SITE                                                                          LABORATORY
                                                  LABSAMNO                    SRM                             Q9573                         RUNNING                              W1538
                                              SAMPLE TYPE                                                     SRM                           AVERAGE                              REF.
                                                           UNIT               ng/g                            ng/g                               ng/amp                          ng/amp
                                                 PNA Analyte                Values             Range          Conc         DB QUAL               Average        Std Dev          Coric        DB QUAL


                                                 FLUORENE*                    97               +/-8.6         75.9                               93.2             7.6            96.3
                                             Cl-FLUORENES                                                     68.0               J               213.3            31.4           226.7
                                             C2-FLUORENES                                                     122.4                              343.7            35.0           364.2
                                             C3-FLUORENES                                                     141.3                              370.1            61.6           406.8
                                        P14ENANTIMNE *                        489              +/-23          434.6                              266.0            23.0           279.9
                                             ANTHRACENE*                      184              +/-14          156.6                              5.9              2.8            12.0               J
                                          Cl-PHEN-ANTHR                                                       269.7                              583.2            91.0           600.3
                                          C2-PHEN-ANTMR                                                       236.9                              656.2            106.3          722.3
                                          C3-PHEN-ANTHR                                                       196.6                              481.9            128.7          567.1
                                          C4-PHEN ANTHR                                                       105.1              J               212.4            75.3           210.0
                                              DIBENZOTHIO                  NC 70               +/-9.4         45.1               J               218.9            22.1           202.6
                                                    Cl-DIBEN                                                  63.2               J               414.9            66.3           412.1
                                                    C2-DIBEN                                                  102.8              J               571.6            106.8          486.8
                                                    C3-DIBEN                                                  99.6               J               506.5            90.8           469.0
                                         FLUORANTHENE*                        981              +/-78          812.9                              5.0              1.1            3.8                J
                                                    PYRENE*                   811              +/-24          650.7                              13.1             2.3            10.4               J
                                        Cl-FLUORAN PYR.                                                       400.3                              94.0             18.2           70.8
                                     BENaANTHRACENE                           427              +/-25          336.5                              5.6              1.0            3.4                J
                                                 CHRYSENE*                    380              +/-24          498.8                              52.4             5.4            57.9
                                             Cl-CHRYSENES                                                     254.9                              91.4             63.5           75.2
                                             C2-CHRYSENES                                                     152.8                              115.5            77.6           97.9
                                             C3-CHRYSENES                                                     12.2               J               30.4             22.2           16.4               J
                                             C4-CHRYSENES                                                     85.4               J               21.5             18;0           13.9               J
                                             BENbFLUORAN                      740              +/-110         523.1                              3.5              0.4            4.3                J
                                             BENkFLUORAN                      361              +/-18          523.1                              3.5              0.4            4.3                J
                                             BENePYRENE *                     553              +/-59          445.1                              11.3             1.1            12.4               J
             NC=Non Certified                BENaPYRENE *                     628              +/-52          481.4                              2.0              0.7            2.2                J





                                                    Mussel Watch Project Year 9 - PAH QC Data (Sediment)

                                                     INVEST#         NIST SRM 1941 a                  Lab QA Sample                     Lab QA Sample                   Lab QA Sample
                                                              ED      Certified Values                   SRM 1941a                    GERG Std Chk III                  GERG Std Chk
                                                           SITE                                                                        LABORATORY
                                                 LABSAMNO                    SRM                             Q9573                        RUNNING                              W1538
                                             SAWLE TYPE                                                      SRM                          AVERAGE                              REF
                                                          UNIT               ng/g                            ng/g                            ng/amp                            ng/amp
                                                 PNA Analyte               Values             Range,         Conc        DB QUAL             Average         Std Dev           Conc        DB QUAL


                                                PERYLENE*                    452              +/-58          271.2            J                2.0             0.6             1.0              J
                                              1123cdPYRENE                   501              +/-72          371.7                             0.9             0.3             0.4              J
                                            DBahANTHRA *                     74               +/-6.8         93.3                              1.8             0.5             1.4              J
                                             BghiPERYLENE                    525              +/-67          388.8                             4.2             0.9             4.1              J


                                               TOTAL PAHs                                                    9956.5                          12750.2                           12698.6
                                           (w/o PERYLENE)
                                         S&T Total PAHs (*)                                                  5766.2                          5072.3                            4962.9


                                         2-METHYLNAPH *                                                      246.4                           1347.9            70.7            .1244.3
                                         I-METHYLNAPH *                                                      122.2                           1086.9            58.1            1040.6
                                       2,6-DIMETHNAPH *                                                      113.1                           775.3             64.6            784.6
                                    1,6,7-TRIMETHNAPH *                                                      52.4                            438.9             30.2            482.0
                                         I-MIETHYLPHEN *                  NC 101              +/-27          71.6                            177.6             21.4            170.0
                                         Surrogate Recoveries
                                                      NAPHD8                                                 78.9                                                                              NA

                                                    ACEND10                                                  83.5                                                                              NA

                                                     PBEND10                                                 82.8                                                                              NA

                                                    CHRYD12                                                  77.4                                                                              NA
                                                     PERYD12                                                 65.2                                                                             -NA










             NC=Non Certified




i
. I
 I
@ I
@ I
 I
 I
 .1
.I         Pesticide and PCB Results
 I
 I
 I
 I
 I
 I
 I               ..
 I
 I
 I                     CA
 I




 I
 I
 'I
 I
 I
 I
 I
 I          Pesticides and PCBs Data
 I                   (Tissue)
 I
 I
 I
 I
 I
 I
 I
 I
1 1
                         65
 I






                                                         Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                 INVEST4                 LMSB                                 LMPI                                  LMAC                                 CCNB                            ABLR

                                         ID      L. Laguna Madre                       L. Laguna Madre                      L. Laguna Madre                       Corpus Christi                    Aransas Bay
                                      SITE               South Bay                            Port Isabel                    Arroyo Colorado                        Nueces Bay                           Long Reef
                           LABSAMNO                      K8008                                K8016                                 K8012                                K8018                           K8032
                         SAMPLE TYPE                     SAW                                  SAMP                                  SAW                                  SAMP                            SAMP
                                     UNIT                ng/g dry                             ng/g dry                              ng/g dry                             ng/g dry                        ng/g dry
                                   Analyte               Cone           D13 QUAL              Cone            MQUAL                 Cone            DB QUAL              Cone          DB QUAL           C2nC         DB QUAL

                        RECEIPT DATE                     12/10/93                             12/10/93                              12/10/93                             12/16/93                        12/17/93
                               QCBATCH                   M1410                                M1410                                 M1410                                M1410                           M1410
                 EXTRACTION DATE                         07/21/94                             07/21/94                              07/21/94                             07/21/94                        07/21/94
                                METHOD                   GCECD                                GCECD                                 GCECD                                GCECD                           GCECD
                     ANALYSIS DATE                       08/27/94                             08/27/94                              08/27/94                             08/27/94                        09/27/94
                                 MATRIX                  TISSUE                               TISSUE                                TISSUE                               TISSUE                          TISSUE
                                  WETWT                  10.23                                10.02                                 10.15                                10.03                           10.05
                                  DRYWT                  1.06                                 1.32                                  1.70                                 2.21                            1.65
                                WTUNITS                  GRAMS                                GRAMS                                 GRAMS                                GRAMS                           GRAMS
                              % SOLIDS                   10.3                                 13.2                                  16.7                                 22.0                            16.4
                               % LIPIDS                  4.1                                  3.3                                   10.9                                 2.0                             18.7
       C; Surrogate Recoveries
       Cr             Pesticides & PCBs
                                   DBOFB                 66.1                                 59.4                                  58.8                                 57.2                            72.4
                                 PCB#103                 68.9                                 58.5                                  62.2                                 55.7                            74.3
                                 PCB#198                 71.6                                 64.4                                  68.4                                 63.1                            74.2
                           TOTAL BHCs                    '1.7                                 1.5                                   4.6                                  9.9                             1.8
             TOT CHLORDANES (S&T)                        0.0                ND                3.2                                   1.1                  J               6.9                             22.3
                           TOTAL DDTs                    3.8                  J               10.6                                  32.3                                 29.1                            14.5
                   TOTAL PCBs (S&T)                      14.9                                 70.3                                  24.7                 J               99.1                            26.3              J
                           ALPHA-BHC                     1.3                                  0.9                                   0.9                                  1.1                             0.6
                                      HCB,               0.0                ND                0.1                  J                0.1                  J               0.0              ND             0.2               J
                              BETA-BHC                   0.4                  J               0.6                  J                3.7                                  1.3                             1.1
                           GAMMA-BFIC                    0.0                ND                0.0                 ND                0,0                ND                7.5                             0.0             ND
                           DELTA-BHC                     0.0                ND                0.0                ND                 0.0                ND                0.0              ND             0.0             ND
                          HEPTACHLOR                     0.0                ND                1.0                                   0.9                                  0.2                             0.1               J
                      HEPTA-EPOXDE                       0.0                ND                0.5                  J                0.2                  J               0.8                             1.1
                     OXYCHLORDANE                        010                ND                0.6                                   2.3                                  0.5                             0.3               J
               GAMMA-CHLORDANE                           0.0                ND                0.8                                   0.4                  J               2.4                             1.0
                 ALPHA-CHLORDANE                         0.0                ND                0.8                                   0.0                ND                2.8                             19.3
                 TRANS-NONACHLOR                         0.0                ND                0.9                                   0.0                ND                3.0                             2.0
                      CIS-NONACHLOR                      0.0                ND                0.7                  J                0.7                                  1.9                             0.9






                                              Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                             INVEST#            LMSB                               LWI                              LMAC                            CCNB,                       ABLR


                                    ID     L. Laguna Madre                  L. Laguna Madre                   L. Laguna Madre                  Corpus Christi                Aransas Bay
                                  SITE         South Bay                        Port Isabel                   Arroyo Colorado                   Nueces Bay                    Long Reef
                         LABSAMNO               K8008                              K8016                            K8012                           K8018                       K8032
                      SAMPLE TYPE               SAW                                SAMP                             SAMP                            SAW                         SAMP
                                 UNIT           ng/g dry                         ng1g dry                         ng/g dry                        ng/g dry                     ng/g dry
                               Analyte            Conc          DD QUAL            Cone          DB QUAL            Cone          DB QUAL           Conc         DB QUAL         Conc        DB QUAL

                             ALDRIN               1.2                              0.0              ND              0.1                 1           1.4                          0.7
                            DIELDRIN              0.0              ND              0.8                              1.8                             2.1                          2.0
                             ENDRIN               0.0              ND              0.0              ND              0.2                 J           4.4                          0.0           ND
                               MIREX              0.1                1             0.4                J             0.6                             0.1              J           0.0           ND
                   2,4'DDE (0,PIDDE)              0.0              ND              0.0              ND              0.0              ND             1.1                          0.0           ND
                   4,4'DDE (P,PIDDE)              3.6                              5.1                              32.3                            20.3                         11.1
                   2,4'DDD (0,PDDD)               0.0              NTD             1.9                              0.0              ND             0.5                          0.0           ND
                   4,4'DDD (P,P'DDD)              0.0              ND              2.0                              0.0              ND             4.4                          1.5
                   2,4'DDT (0,PDDT)               0.0              ND              0.3                J             0.0              ND             1.1                          0.2              1
                   4,4'DDT (PPDDT)                0.2                J             1.4                              0.0              ND             1.7                          1.8
             PCB # (CLORINATION)
                              8 (CL2)             0.0              ND              1.3                J             0.0              ND             0.5              J           0.4              J
                             18 (CL3)             0.0                J             0.7                J             1.1                 J           0.6              J           0.0           ND
                             28 (CL3)             0.0              ND              2.3                              0.0              ND             0.0             ND           0.0           ND
                             44 (CL4)             0.0              ND              1.5                J             0.4                             2.0                          3.6
                             52 (CL4)             0.6                J             4.2                              0.7                             3.0                          0.5              J
                             66 (CL4)             0.0              ND              4.5                              0.0              ND             1.5                          0.0           ND
                             101 (CL5)            2.2                              4.2                              2.8                             3.9                          0.9              J
                             105 (CL5)            0.0              ND              2.0                              0.0              ND             1.5                          0.2              J
                       110/77 (CL5/4)             0.0              ND              0.0              ND              0.0              ND             0.0             ND           0.0           ND
                   118/108/149(CL5/5/6)           0.0              ND                                               0.0              ND             6.1                          0.3              J
                             128 (CL6)            0.0              ND              0.3                J             0.3                 J           0.9                          0.4              1
                             138 (CL6)            0.0              ND              2.6                              1.8                             6.6                          1.7
                             126 (CL5)            0.0              ND              0.0              ND              0.0              ND             0.0             ND           0.0           ND
                             153 (CL6)            1.4                J             3.3                              0.7                 J           9.9                          1.0              J
                             170 (CL7)            0.0              ND              3.4                              1.1                 J           0.9                          0.6              1
                             180 (CL7)            0.2                J             0.0              ND              0.4                 J           5.9                          1.0              J
                   187/182/159(CL7n/6)            0.0              ND              0.8                J             0.0              ND             5.5                          0.7              J
                             195 (CL8)            1.3                J             0.0              ND              0.9                 J           1.0                          0.0           ND
                             206 (CL9)            0.0              ND              0.0              ND              0.0              ND             0.0             ND           0.0           ND
                           209 (CL 10)            0.0              ND              0.0              ND              0.0              ND             0.5              J           0.0           ND




                                                                           fan                                                 M m m m                                                ml@ so m
                                                      Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                 INVEST#              MBAR                             SAPP                              ESSP                             ESBD                             MBGP


                                         ID     Mesquite Bay                    San Antonio Bay                    Espiritu Santo                   Espiritu Santo                  Matagorda Bay
                                      SITE            Ayres Reef               Panther Point Reef                 South Pass Reef                  Bill Day's Reef                  Gallinipper Point
                            LABSAMNO                  K8020                            K8026                             K8030                            K8028                            K8024
                          SAMPLE TYPE                 SAMP                             SAMP                              SAMP                             SAMP                             SAMP
                                      UNIT            ng/g dry                         ng/g dry                          ng/g dry                         ng/g dry                         ng/g dry
                                    Analyte           Cone        DB QUAL              Cone           DB QUAL            Cone         DB QUAL             Cone         DB QUAL             Cone          DB QUAL

                         RECEIPT DATE                 12116/93                         12116/93                          12/17/93                         12/17/93                         12/16/93
                               QCBATCH                M1410                            M1410                             M1410                            M1410                            M1410
                   EXTRACTION DATE                    07/21/94                         07/21/94                          07/21/94                         07/21/94                         07/21/94
                                 METHOD               GCECD                            GCECD                             GCECD                            GCECD                            GCECD
                      ANALYSIS DATE                   08/27/94                         08/28/94                          08/28/94                         08/28/94                         08/28/94
                                  MATRIX              TISSUE                           TISSUE                            TISSUE                           TISSUE                           TISSUE
                                  WETWT               10.02                            10.02                             10.02                            10.04                            10.04
                                  DRYWT               1.37                             1.81                              1.90                             1.28                             1.65
                                WTUNITS               GRAMS                            GRAMS                             GRAMS                            GRAMS                            GRAMS
                               % SOLIDS               13.7                             18.0                              18.9                             12.8                             16.4
                                % LIPIDS              10.9                             15.3                              14.9                             6.2                              14.7
      0)      Surrogate Recoveries
      00               Pesticides & PCBs
                                   DBOFB              63.9                             59.2                              67.3                             60.9                             62.5
                                  PCB#103             64.0                             53.4                              63.0                             61.2                             60.2
                                  PCB#198             75.6                             69.8                              82.3                             68.6                             74.5
                            TOTAL BHCs                12.3                             5.0                               13.1                             3.2                              6.4
               TOT CHLORDANES (S&T)                   2.7              J               2.3                               4.5                              2.4               J              5.9
                            TOTAL DDTs                13.7                             16.6                              15.6                             11.6                             58.9
                    TOTAL PCBs (S&T)                  38.6                             45.0                              87.9                             59.6              J              90.1
                            ALPHA-BHC                 1.6                              1.1                               1.1                              1.8                              1.2
                                       HCB            0.0             ND               0.0                 J             0.1               J              0.0               ND             0.0               J
                               BETA-BHC               2.5                              2.7                               3.4                              1.5                              4.6
                            GAMMA-BHC                 7.2                              0.7                               8.0                              0.0               ND             0.7
                            DELTA-BHC                 1.1                              0.5                 J             0.7                              0.0               ND             0.0              ND
                           HEPTACHLOR                 0.0             ND               0.5                 J             0.5               J              0.0               ND             0.7
                        HEPTA-EPOXIDE                 0.5              J               0.0               ND              0.0             ND               0.8               J              0.0              ND
                      OXYCHLORDANE                    0.0             ND               0.5                               0.5                              0.0               ND             0.5
                 GAMMA-CHLORDANE.                     0.7              J               0.7                               0.7                              0.3                              1.7
                  ALPHA-CHLORDANE                     1.0                              0.0               ND              2.7                              1.2                              3.4
                  TRANS-NONACHLOR                     1.3                              1.8                               1.3                              0.4               J              1.9
                       CIS-NONACHLOR                  0.9                              1.6                               1.8                              0.0               ND             2.7




     mm                                           mm mmmm mmm m
                                               Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                               INVEST#           MBAR                             SAPP                            ESSP                           ESBD                            MBGP


                                       ID    Mesquite Bay                  San Antonio Bay                   Espiritu Santo                 Espiritu Santo                 Matagorda Bay
                                    SITE       Ayres Reef                 Panther Point Reef                South Pass Reef                 Bill Day's Reef               Gallinipper Point
                           LABSAMNO              K8020                            K8026                           K8030                          K8028                           K8024
                        SAMPLE TYPE              SAW                              SANT                            SAMP                           SAMP                            SAMP
                                   UNIT         ng1g dry                        ng/g dry                        ng1g dry                       ng/g dry                        ng/g dry
                                 Analyte          Conc         DB QUAL            Cone          DB QUAL           Conc         DB allE_ Conc                   DB QUAL           Conc         DB QUAL

                               ALDRIN             0.6              J              0.5                             0.7                            0.0               ND            0.0             ND
                             DIELDRIN             1.3                             1.6                             2.2                            2.2                             2.1
                               ENDRIN             0.0             ND              0.0              ND             0.0             ND             0.0               ND            0.0             ND
                                 MIREX            0.2              J              0.9                             0.8                            0.1               J             1.0
                    2,4'DDE (0,P'DDE)             0.0             ND              0.0              ND             0.3               J            0.0               ND            0.0             ND
                    4,4'DDE (PP'DDE)              12.0                            11.2                            10.0                           11.4                            48.4
                    2,4'DDD (0,?DDD)              0.0             ND              0.0              ND             0.0             ND             0.0               ND            0.2
                    4,4'DDD (PP'DDD)              0.0             ND              2.9                             2.8                            0.0               ND            7.0
                    2,4'DDT (0,FDDT)              0.7              J              0.9                             1.1                            0.0               ND            1.1
                    4,4'DDT (PPDDT)               1.0                             1.7                             1.4                            0.1               J             2.1
   0)         PCB # (CLORINATION)
   CD                           8 (CL2)           0.5                             0.2                J            0.4                            0.0               ND            0.7               J
                               18 (CL3)           0.7              J              0.6                             1.7                            0.6               J             0.9               J
                               28 (CL3)           0.0             ND              1.4                             0.9                            0.0               ND            3.0
                               44 (CL4)           2.5                             4.8                             5.7                            0.4                             3.9
                               52 (CL4)           1.0                             1.3                             1.4                            0.4               J             2.9
                               66 (CL4)           1.4                             1.2                             0.0             ND             0.0               ND            1.5
                               101 (CL5)          0.9                             0.9                             0.7               J            1.3               J             4.7
                               105 (CL5)          0.0             ND              0.3                J            0.0             ND             0.0               ND            1.3
                         I iom (CL5/4)            0.0             ND              0.0              ND             0.0             ND             0.0               ND            0.0             ND
                    118/108/149(CLS/5/6)          0.0             ND              1.5                             1.7                            0.0               ND            6.0
                               128 (CL6)          0.5              J              0.6                J            0.5               J            0.0               ND            1.7
                               138 (CL6)          2.6                             3.1                             2.8                            1.1               J             6.7
                               126 (CL5)          0.0             ND              0.0              ND             0.0             ND             0.0               ND            0.0             ND
                               153 (CL6)          2.8                             1.5                             1.7                            4.4                             5.6
                               170 (CL7)          1.4              1              1.2                             2.4                            2.1                             1.1               J
                               ISO (CL7)          0.2              J              0.5                J            3.6                            0.1               J             1.9
                    187/182/159(CL7n/6)           1.2                             1.1                             1.1                            0.5               1             3.4
                               195 (CLS)          1.0                             0.5                J            15.5                           14.3                            0.8               J
                               206 (CL9)          0.0             ND              0.0              ND             0.0             ND             0.0               ND            0.0             ND
                            209 (CLIO)            0.0             ND              0.0                             0.7                                              J             0.0             ND




                             M M M;M M Imm M M M M M M Mon M
                                                  Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                    INVEST#               MBCB                            BRCL                            GBTD                             GBOB                             GBSC

                                            ID     Matagorda Bay                     Brazos River                   Galveston Bay                    Galveston Bay                    Galveston Bay
                                         SITE      Carancahua Bay                    Cedar Lakes                    Todd's Dump                      Offats Bayou                     Ship Channel
                               LABSAMNO                   K8022                           K8004                           K8000                            K8006                            K8002
                            SAMPLE TYPE                   SAMP                            SAMP                            SAW                              SAMP                             SAMP
                                         UNIT             ng1g dry                        ng/g dry                        ng1,g dry                        ng/g dry                         ng/g dry
                                      Analyte             Conc          DB QUAL           Conc        DB QUAL             Conc         DB QUAL             Conc         DB QUAL             Conc         DB QUAL

                           RECEIPT DATE                   12/16/93                        12/09/93                        12/09/93                         12/09/93                         12/09/93
                                  QCBATCH                 M1410                           M1410                           M1410                            M1410                            M1410
                     EXTRACTION DATE                      07/21/94                        07/21/94                        07/21/94                         07/21/94                         07/21/94
                                    METHOD                GCECD                           GCECD                           GCECD                            GCECD                            GCECD
                         ANALYSIS DATE                    08/28/94                        08127/94                        08/27/94                         08/27/94                         08/27/94
                                    MATRIX                TISSUE                          TISSUE                          TISSUE                           TISSUE                           TISSUE
                                     WETWT                10.05                           10.31                           10.38                            10.22                            5.04
                                     DRYWT                1.30                            1.43                            2.06                             2.03                             0.90
                                   WTUNITS                GRAMS                           GRAMS                           GRAMS                            GRAMS                            GRAMS
                                  % SOLIDS                13.0                            13.8                            19.9                             19.9                             17.8
                                   % LIPIDS               11.5                            4.4                             13.0                             12.1                             9.4
                Surrogate Recoveries
                          Pesticides & PCBs
                                      DBOFB               64.6                            62.0                            58.4                             58.4                             66.0
                                    PCB#103               63.5                            67.7                            60.0                             59.7                             64.8
                                    PCB# 198              75.1                            70.6                            70.7                             67.7                             77.4
                               TOTAL BHCs                 7.2                             2.4              J              11.2                             7.0                              21.7
                 TOT CHLORDANES (S&T)                     5.5                             3.2                             17.0                             60.7                             80.6
                               TOTAL DDTs,                30.4                            53.6                            15.9                             43.5                             107.5
                       TOTAL PCBs (S&T)                   66.2                            50.5             J              99.6                             142.5                            549.3
                               ALPHA-BHC                  2.0                             1.4                             1.5                              0.9                              5.4
                                         HCB              0.0              ND             0.6              J              0.5               J              0.2               J              0.8               J
                                  BETA-BHC                4.0                             1.0                             5.7                              4.2                              8.3
                              GAMMA-BHC                   1.1                             0.0            ND               3.5                              1.9                              5.3
                               DELTA-BHC                  0.0              ND             0.0            ND               0.6                              0.0             ND               2.7
                             HEPTACHLOR                   0.0              ND             0.0            ND               0.7                              1.4                              2.4
                          HEPTA-EPOXIDE                   1.3                             1.2                             5.1                              4.5                              15.3
                         OXYCHLORDANE                     1.1                             0.6              J              1.2                              2.4                              5.8
                   GAMIVIA-CHLORDANE                      2.0                             1.3                             4.9                              29.9                             36.9
                     ALPHA-CHLORDANE                      2.2                             0.7                             4.6                              26.5                             28.2
                     TRANS-NONACHLOR                      2.1                             1.3                             6.6                              28.2                             34.6
                         CIS-NONACHLOR                    1.9                             1.2                             3.7                              13.7                             19.6





                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                    INVEST#             MBCB                            BRCL                          GBTD                              GBOB                            GBSC


                                           ID,    Matagorda Bay                    Brazos River                   Galveston Bay                   Galveston Bay                   Galveston Bay
                                         SITE     Carancahua. Bay                   Cedar Lakes                   Todd's Dump                      Offats Bayou                    Ship Channel
                                LABSAMNO                K8022                           K8004                         K8000                             K8006                           K8002
                            SAWLE TYPE                  SAW                             SAMP                          SAW                               SAW                             SAMP
                                        UNIT          ng/g dry                        ng/g dry                       ng/g dry                        ng1g dry                         ng/g dry
                                      Analyte            Conc         DB QUAL           Conc        DB QUAL            Conc          DB QUAL            Conc         DB QUAL            Conc          DB QUAL

                                    ALDRIN               0.9                            2.4                            1.7                              0.5                             0.0              ND
                                  DIELDRIN               2.8                            1.5                            8.6                              10.0                            26.2
                                    ENDRIN               0.0              ND            0.0             ND             0.0              ND              0.0             ND              0.8                J
                                      MIREX              1.4                            2.9                            0.3                J             0.9                             0.0              ND
                        2,4'DDE (0,FDDE)                 0.0              ND            0.5              J             0.0              ND              0.0             ND              5.5
                        4,4'DDE (P,FDDE)                 24.0                           47.6                           5.8                              20.0                            39.6
                        2,4'DDD (0,P'DDD)                0.0              ND            0.2              J             0.4                J             1.5                             4.6
                        4,4'DDD (P,FDDD)                 3.4                            3.7                            9.1                              12.7                            51.1
                        2,4'DDT (O,FDDT)                 1.1                            0.0             ND             0.0              ND              6.3                             0.0              ND
                        4,4'DDT (PPDDT)                  1.8                            1.5                            0.6                              3.0                             6.6
                  PCB # (CLORINATION)
                                     8 (CL2)             0.0              ND            1.6                            0.8                J             0.0             ND              2.9
                                    18 (CL3)             0.8                J           0.2              J             0.7                J             0.7                J            2.1                J
                                    28 (CL3)             4.1                            0.0             ND             0.2                J             6.0                             14.0
                                    44 (CL4)             8.0                            0.7              J             4.1                              6.9                             18.1
                                    52 (CL4)             1.1                J           2.4                            4.2                              6.4                             34.9
                                    66 (CL4)             2.2                            1.3              J             2.6                              3.6                             12.8
                                    101 (CL5)            2.4                            3.5                            4.8                              7.9                             36.3
                                    105 (CL5)            0.0              ND            0.0             ND             3.3                              3.5                             17.8
                             110/77 (CL5/4)              0.0              ND            0.0             ND             0.0              ND              0.0             ND              0.0              ND
                        118/108/149(CL5/5/6)             3.8                            4.2                            5.6                              12.9                            36.6
                                    128 (CL6)            1.0                J           1.5                            0.7                J             1.1                             5.3
                                    138 (CL6)            3.5                            4.3                            5.5                              6.7                             31.9
                                    126 (CL5)            0.0              ND            0.0             ND             0.0              ND              0.0             ND              0.0              ND
                                    153 (CL6)            1.9                            5.3                            9.6                              10.2                            36.2
                                    170 (CL7)            2.6                            0.0             ND             1.1                              1.3                             2.3
                                    180 (CL7)            0.1                J           0.0             ND             2.1                              5.9                             22.5
                        187/182/159(CL7/7/6)             0.9                J           1.3              J             4.9                              2.9                             12.7
                                    195 (CL8)            0.7                J           0.0             ND             0.0              ND              0.6                J            0.0              ND
                                    206 (CL9)            0.0              ND            0.0             ND             0.0              ND              0.0             ND              0.0              ND
                                 209 (CLIO)              0.0              ND            0.0             ND             0.0              ND              0.1                J            0.0              ND



                            mmm mmm@ M MMIM M@ M M M@
                                                . Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                   INVEST#             SLBB                           CLLC                              VBSP                           CLCL                             TBLF


                                           ID     Sabine Lake                   Calcasieu Lake                   Vermillion Bay                   Caillou Lake                   Terrebonne Bay
                                         SITE   Blue Buck Point                  Lake Charles                     Southwest Pass                   Caillou Lake                    Lake Felicity
                               LABSAMNO                K8010                          K8014                             K8040                          K8034                            K8036
                           SAWLE TYPE                  SAM[P                          SAW                               SAW                            SAMP                             SAMP
                                        UNIT           ng/g dry                       ng/g dry                          ng/g dry                       ng/g dry                         ng/g dry
                                      Analyte          Conc        DB QUAL            Conc          DB QUAIL            Conc         DB QUAL           Conc         DB QUAL             Conc           DB QUAL

                           RECEIPT DATE                12/10/93                       12/10/93                          01/13/94                       01/13/94                         01/13/94
                                 QCBATCH               M1410                          M1410                             M1411                          M1410                            M1410
                    EXTRACTION DATE                    07/21/94                       07/21/94                          07/25/94                       07/21/94                         07/21/94
                                   METHOD              GCECD                          GCECD                             GCECD                          GCECD                            GCECD
                        ANALYSIS DATE                  08/27194                       08/27/94                          08/27/94                       08/28/94                         08/28/94
                                    MATRIX             TISSUE                         TISSUE                            TISSUE                         TISSUE                           TISSUE
                                    WETWT              10.06                          10.01                             10.02                          10.04                            10.01
                                    DRYWT              1.54                           2.06                              0.96                           1.33                             1.82
                                  WTUNITS              GRAMS                          GRAMS                             GRAMS                          GRAMS                            GRAMS
                                 % SOLIDS              15.3                           20.6                              9.5                            13.2                             18.2
      -4                          % LIPIDS             9.7                            12.4                              15.1                           15.0                             13.2
      tQ       Surrogate Recoveries
                         Pesticides & PCBs
                                     DBOFB             65.5                           46.0                              77.8                           69.9                             67.2
                                    PCB#103            67.9                           44.0                              76.1                           63.1                             63.0
                                    PCB#198            83.4                           54.2                              81.8                           88.0                             84.5
                             TOTAL BHCs                7.6                            11.5                              4.7                            2.9               J              4.4
                TOT CHLORDANES (S&T)                   7.0                            13.1                              22.6                           8.6                              3.4
                             TOTAL DDTs                13.1                           35.1                              44.2                           12.7                             10.4
                      TOTAL PCBs (S&T)                 81.6                           255.4                             99.2                           58.5              J              33.1               J
                               ALPHA-BHC               0.9                            1.4                               1.5                            1.5                              1.3
                                         HCB           0.0            ND              1.9                               0.2               J            0.2               J              0.2                J
                                 BETA-BHC              6.3                            8.3                               1.6                            0.8               J              2.0
                             GAAQvIA-BHC               0.4             J              1.3                               1.1                            0.6               J              0.3                J
                               DELTA-BHC               0.0            ND              0.5               J               0.5               J            0.0             ND               0.9
                             HEPTACHLOR                1.1                            0.8                               0.6               J            0.9                              0.3                J
                         HEPTA-EPOXIDE                 0.8                            1.9                               3.5                            2.5                              0.4                J
                        OXYCHLORDANE                   0.0            ND              0.5                               0.6               J            1.1                              0.0              ND
                   GAMMA-CHLORDANE                     2.1                            21.8                              1.9                            1.9                              0.9
                    ALPHA-CHLORDANE                    2.4                            5.1                               15.5                           3.2                              1.6
                    TRANS-NONACHLOR                    2.7                            5.9                               3.0                            2.0                              1.1
                      - CIS-NONACHLOR                  2.4                            3.5                               3.2                            1.1                              0.5                J






                                                  Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                  INVEST#              SLBB                           CLLC                              VBSP                            CLCL                            TBLF


                                           ID     Sabine Lake                   Calcasieu Lake                   Vennillion Bay                    Caillou Lake                  Terrebonne Bay
                                        SITE    Blue Buck Point                  Lake Charles                     Southwest Pass                   Caillou Lake                    Lake Felicity
                               LABSAMNO                K8010                          K8014                             K8040                           K8034                           K8036
                           SANTLE TYPE                 SAW                            SAW                               SAJVT                           SAMP                            SAMP
                                        UNIT        ng1g dry                        ng1g dry                         ng/g dry                        ng/g dry                         ng/g dry
                                      Analyte          Conc        DB QUAL            Conc          DB QUAL             Conc         DB QUAL            Conc        DB QUAL             Conc           DB QUAL

                                    ALDRIN             0.8                            0.0               ND              1.0               J             1.2                             0.6
                                  DIELDRIN             3.5                            8.3                               18.4                            4.9                             1.2
                                    ENDRIN             0.6              J             3.3                               2.4                             0.1              J              0.0                 ND
                                     MIREX             1.3                            1.7                               0.3               J             1.0                             0.1                 J
                        2,4'DDE (0,P'DDE)              0.0            ND              0.0               ND              0.0              ND             0.0            ND               0.0                 ND
                        4,4'DDE (PPDDE)                7.2                            27.9                              27.0                            8.6                             8.7
                        2,4'DDD (0,P'DDD)              0.1              J             1.6                               0.6               J             0.1              J              0.0                 ND
                        4,4'DDD (PP'DDD)               4.4                            5.0                               13.3                            3.3                             1.3
                        2,4'DDT (0,P'DDT)              0.4              J             0.0               ND              0.1               J             0.1              J              0.0                 J
                        4,4'DDT (P,P'DDT)              1.0                            0.6                               3.3                             0.7              J              0.3                 J
                  PCB # (CLORINATION)
                                     8 (CL2)           0.0            ND              0.5                J              1.4               J             0.5              J              0.4                 J
                                    18 (CL3)           0.5              J             2.2                               3.5                             1.0              J              1.5
                                    28 (CL3)           1.3              J             5.3                               0.3               J             2.6                             0.9                 J
                                    44 (CL4)           1.0              J             4.5                               2.8                             1.4              J              1.2
                                    52 (CL4)           1.5                            25.1                              0.7               J             1.9                             0.8                 J
                                    66 (CL4)           3.6                            6.4                               0.7               J             1.6                             0.7                 J
                                  101 (CL5)            2.7                            16.5                              3.6                             2.7                             1.5
                                  105 (CL5)            5.3                            5.4                               1.0               J             0.9              J              0.0                 ND
                             110/77 (CL514)            0.0            ND              0.0               ND              6.8                             0.0            ND               0.0                 ND
                        118/108/149(CL5/5/6)           4.6                            19.1                              1.7               J             3. 1                            2.2
                                  128 (CL6)            0.9              J             2.5                               2.4                             0.9              J              0.4                 J
                                  138 (CL6)            5.3                            14.7                              9.2                             4.3                             1.6
                                  126 (CL5)            0.0            ND              0.0               ND              0.0             ND              0.0            ND               0.0                 ND
                                  153 (CL6)            6.4                            20.3                              4.1                             3.6                             1.6
                                  170 (CL7)            1.5                            1.7                               1.4               J             1.2              J              1.2
                                  180 (CL7)            1.4                            4.7                               1.1               J             0.7              J              1.0                 J
                        187/182/159(CL7n/6)            4.3                            5.2                               4.0                             1.7                             0.7                 J
                                  195 (CL8)            0.0            ND              0.8               J               0.2               J             0.3              J              0.6                 J
                                  206 (CL9)            0.0            ND              0.0               ND              0.0             ND              0.0            ND               0.0                 ND
                                 209 (CL 10)           0.7              J             0.0               ND              0.8               J             0.6              J              0.0                 J






                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                INVEST#                MRPL                             BSSI                          LBMP                          LBNO                             MSPC


                                        ID      Mississippi River                  Breton Sound                  Lake Borgne                   Lake Borgne                   Mississippi Sound
                                     SITE         Pass a Loutre                     Sable Island                      Point                    New Orleans                      Pass Christian
                           LABSAMNO                    K8042                            K8038                         K8044                         K8046                            K8052
                         SAMPLE TYPE                   SAW                              SAMP                          SAMP                          SAMP                             SAMP
                                     UNIT              ng/g dry                         ng/g dry                      ng1g dry                      ng/g dry                         ng/g dry
                                   Analyte             Conc           DB QUAL           Conc         DB QUAL          Conc        DB QUAL           Conc        DB QUAL              Conc            D13 QUAL

                        RECEIPT DATE                   01/15/93                         01/15/93                      01/15/93                      01/15/93                         01/16/94
                               QCBATCH                 M1411                            M1411                         M1411                         M1411                            M1411
                  EXTRACTION DATE                      07/25/94                         07/25/94                      07/25/94                      07/25/94                         07/25/94
                                METHOD                 GCECD                            GCECD                         GCECD                         GCECD                            GCECD
                      ANALYSIS DATE                    08/27/94                         08/27/94                      08/27/94                      08/27/94                         08/27/94
                                 MATRIX                TISSUE                           TISSUE                        TISSUE                        TISSUE                           TISSUE
                                 WETWT                 10.05                            10.03                         10.03                         10.02                            10.01
                                 DRYWT                 0.46                             0.75                          0.87                          0.92                             1.29
                               WTUNITS                 GRAMS                            GRAMS                         GRAMS                         GRAMS                            GRAMS
                              % SOLIDS                 4.5                              7.4                           8.6                           9.2                              12.9
                               % LIPIDS                11.5                             17.4                          15.6                          17.1                             12.6
             Surrogate Recoveries
                      Pesticides & PCBs
                                  DBOFB                74.5                             76.9                          78.3                          70.5                             74.5
                                 PCB#103               71.5                             75.9                          79.1                          69.1                             73.3
                                 PCB#198               79.2                             82.5                          82.2                          72.8                             77.8
                           TOTAL BHCs                  4.2                 J            4.7              J            2.5              J            4.8                              2.8                  J
              TOT CHLORDANES (S&T)                     5&5                              56.9                          15.1                          24.0                             18.9
                           TOTAL DDTs                  125.7                            92.6                          10.2                          12.3                             34.2
                    TOTAL PCBs (S&T)                   620.6                            366.5                         53.0             J            68.9             J               74.8
                           ALPHA-BHC                   1.3                 J            1.6                           0.8              J            1.3                              0.9
                                      HCB              0.4                 J            0.0             ND            0.0              J            0.1              J               0.0                  J
                              BETA-BHC                 0.5                 J            1.6                           1.2                           2.5                              0.7                  J
                           GAAC%4A-BHC                 0.9                 J            1.1              J            0.4              J            1.0              J               1.1
                           DELTA-BHC                   1.4                 J            0.4              1            0.1              J            0.1              J               0.1                  J
                          HEPTACHLOR                   0.5                 J            0.6              J            0.6              J            1.0              J               0.9
                       HEPTA-EPOXIDE                   4.5                              6.0                           1.2                           1.6                              1.8
                     OXYCHLORDANE                      2.5                              2.1                           0.7              J            1.1                              1.1
                GAMIVIA-CHLORDANE                      17.2                             15.2                          0.8              J            1.7                              5.5
                  ALPHA-CHLORDANE                      32.0                             31.7                          11.2                          18.8                             9.5
                  TRANS-NONACHLOR                      21.5                             18.7                          2.1                           2.6                              6.7
                      CIS-NONACHLOR                    10.6                             10.0                          1.5                           3.0                              3.6






                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                 INVEST#               MRPL                             BSSI                          LBMP                          LBNO                             MSPC


                                        ID      Mississippi River                  Breton Sound                  Lake Borgne                   Lake Borgne                    Mississippi Sound
                                      SITE        Pass a Loutre                     Sable Island                      Point                    New Orleans                      Pass Christian
                             LABSAMNO                  K8042                            K8038                         K8044                         K8046                            K8052
                         SAMPLE TYPE                   SAMP                             SAMP                          SAMP                          SAMP                             SAMP
                                     UNIT           ng/g dry                          ng/g dry                      ng/g dry                      n g/g dry                        ng/g dry
                                   Analytc             Conc           DB QUAL           Conc         DB QUAL          Conc        DB QUAL           Conc        DB QUAL              Conc            DB QUAL

                                 ALDRIN                2.1                              2.6                           0.6              J            0.5              J               0.2                  J
                               DIELDRIN                26.2                             34.4                          3.0                           4.2                              4.9
                                 ENDRIN                2.9                              3.3                           1.4                           0.6              J               1.0
                                   MIREX               0.6                 J            0.0             ND            0.0            ND             0.1              J               2.2
                     2,4'DDE (0,P'DDE)                 0.0               ND             0.0             ND            1.3                           0.5              J               1.0
                     4,4'DDE (P,P'DDE)                 65.2                             50.9                          5.9                           7.2                              22.7
                     2,4'DDD (0,P'DDD)                 4.5                              3.7                           0.0              J            0.0              J               0.7                  J
                     4,4'DDD (P,P'DDD)                 38.4                             27.2                          1.8                           2.6                              7.1
                     2,4'DDT (0,P'DDT)                 3.8                              1.3                           0.0            ND             0.0            ND                0.0                  ND
                     4,4'DDT (PP'DDT)                  13.8                             9.4                           1.1              J            2.1                              2.7
               PCB # (CLORINATION)
                                  8 (CL2)              2.8                 J            0.9               J           1.9              J            3.3                              0.3                  J
                                 IS (CL3)              7.3                              0.0             ND            2.4                           5.2                              1.5                  1
                                 28 (CL3)              3.2                 J            1.5               J           0.1              J            1.0              J               0.4                  J
                                 44 (CL4)              10.1                             7.5                           1.9              J            2.3                              2.8
                                 52 (CL4)              14.9                             10.8                          0.9              J            1.0              J               1.3                  J
                                 66 (CL4)              4.8                              2.9                           0.0            ND             0.3              J               0.8                  J
                                 101 (CL5)             27.7                             16.1                          6.0                           4.5                              6.5
                                 105 (CL5)             3.4                 J            4.8                           0.3              J            0.6              J               0.5                  J
                          110/77 (CL5/4)               53.4                             36.1                          2.6                           5.1                              6.2
                     118/108/149(CL5/5/6)              13.5                             9.9                           0.6              J            0.9              J               2.9
                                 128 (CL6)             9.3                              5.3                           0.9              J            0.7              J               1.2                  J
                                 138 (CL6)             44.4                             30.7                          2.o              J            3.3                              4.4
                                 126 (CL5)             0.0               ND             0.0             ND            0.0            ND             0.0            ND                0.0                  ND
                                 153 (CL6)             56.8                             24.4                          0.1              J            0.0              J               1.4                  J
                                 170 (CL7)             4.3                 1            2.5               J           1.5              J            1.2              J               1.0                  J
                                 180 (CL7)             11.0                             7.3                           0.5              J            0.6              J               2.5
                     187/182/159(CL7/7/6)              26.6                             14.9                          0.4              J            1.0              J               1.5                  J
                                 195 (CL8)             0.0               ND             0.0             ND            0.9              J            0.0            ND                0.3                  J
                                 206 (CL9)             1.3                 J            0.6               J           0.0            ND             0.0            ND                0.2                  J
                              209 (CL 10)              1.1                 J            0.0             ND            0.7              J            0.3              J               0.3                  J






                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                INVEST#                MSPI3                           MBCP                          MBHI                             PBPH                               PBIB


                                       ID      Mississippi Sound                  Mobile Bay                     Mobile Bay                     Pensacola Bay                      Pensacola Bay
                                     SITE       Pascagoula Bay                         Reef                     Hollingers Is.                   Public Harbor                     Indian Bayou
                           LABSAMNO                    K8054                           K8048                         K8050                            K8058                              K8056
                        SAMPLE TYPE                    SAW                             SAMP                          SAMP                             SAMP                               SAMP
                                    UNIT               ng/g dry                        ng1g dry                      ng/g dry                         ng/g dry                           ng/g dry
                                  Analyte              Conc           DB QUAL          Conc       DB QUAL            Cone          DB QUAL            Conc           DB QUAL             Conc          DB QUAL

                       RECEIPT DATE                    01/16/94                        01/16/94                      01/16/94                         01/17/94                           01/17/94
                              QCBATCH                  M1411                           M1411                         M1411                            M1411                              M1411
                 EXTRACTION DATE                       07/25/94                        07/25/94                      07/25/94                         07/25/94                           07/25/94
                               METHOD                  GCECD                           GCECD                         GCECD                            GCECD                              GCECD
                     ANALYSIS DATE                     08/27/94                        08/27/94                      08/27/94                         08/27/94                           08/27/94
                                MATRIX                 TISSUE                          TISSUE                        TISSUE                           TISSUE                             TISSUE
                                WETWT                  10.02                           10.02                         10.03                            10.05                              10.01
                                 DRYWT                 0.83                            1.64                          1.26                             1.41                               0.67
                               WTUNITS                 GRAMS                           GRAMS                         GRAMS                            GRAMS                              GRAMS
                             % SOLIDS                  8.2                             16.4                          12.6                             14.1                               6.7
                              % LIPIDS                 11.7                            20.3                          14.8                             19.3                               12.9
      '4    Surrogate Recoveries
                      Pesticides & PCBs
                                  DBOFB                70.8                            74.5                          71.5                             62.8                               77.4
                               PCB# 103                69.9                            68.8                          69.6                             64.1                               77.6
                               PCB# 198                75.9                            78.4                          76.3                             64.1                               80.6
                           TOTAL BHCs                  .2.8                J           10.5                          5.1                              5.2                                3.4               J
             TOT CHLORDANES (S&T)                      12.1                            20.0                          28.1                             18.8                               21.9
                           TOTAL DDTs                  28.4                            136.8                         255.7                            27.3                               21.4
                   TOTAL PCBs (S&T)                    328.8                           152.2                         342.4                            308.5                              535.3
                           ALPHA-BHC                   0.7                 J           6.2                           1.0                              1.0                                0.6               J
                                     HCB               0.0                 J           0.0             J             0.2               J              0.1                J               0.2               J
                             BETA-BHC                  0.5                 J           1.8                           1.4                              1.3                                1.0               J
                          GAMMA-BHC                    1.0                 J           2.1                           2.1                              1.8                                0.7               J
                           DELTA-BHC                   0.6                 J           0.3             J             0.6               J              1.2                                1.0               J
                         HEPTACHLOR                    0.4                 J           1.5                           0.2               J              0.7                J               0.0              ND
                      HEPTA-EPOXIDE                    1.0                 1           1.6                           2.7                              2.5                                1.2               J
                     OXYCHLORDANE                      1.0                 1           1.0                           1.5                              0.9                                1.0               J
               GAMMA-CHLORDANE                         2.4                             1.8                           8.7                              3.8                                1.5               J
                 ALPHA-CHLORDANE                       7.1                             13.9                          16.1                             11.0                               15.8
                 TRANS-NONACHLOR                       3.6                             3.0                           9.0                              4.7                                4.8
                     CIS-NONACHLOR                     23.2                            2.5                           7.9                              4.4                                3.9






                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                n,4VEST#              MSPB                            MBCP                           MBHI                             PBPH                              PBIB


                                       IlD     Mississippi Sound                  Mobile Bay                     Mobile Bay                      Pensacola Bay                     Pensacola Bay
                                     SITE       Pascagoula Bay                        Reef                      Hollingers Is.                   Public Harbor                     Indian Bayou
                           LABSAMNO                  K8054                            K8048                          K8050                            K8058                             K8056
                        SAMPLE TYPE                   SAND                            SAJVJP                         SAW                              SAMP                              SAMP
                                    UNIT            ng/g dry                        ng/g dry                      ng/g dry                          ng/g dry                          ng/g dry
                                  Analyte             Conc            DB QUAL         Conc        DB QUAL            Conc          DB QUAL            Conc           DB QUAL            Conc           DB QUAL

                                ALDRIN                0.2                  J          0.8                            1.0                              0.2                 J             0.8                 J
                                DIELDRIN              3.8                             6.6                            9.7                              8.4                               4.1
                                ENDRIN                1.4                             2.3                            2.3                              1.3                               1.2                 J
                                  MIREX               1.0                  J          0.4              J             0.3                J             0.8                               1.0                 J
                    2,4'DDE (0,P'DDE)                 0.8                  J          35.7                           70.5                             0.0               ND              0.0               ND
                    4,4'DDE (P,P'DDE)                 21.9                            75.8                           127.5                            17.5                              16.0
                    2,4'DDD (O,PDDD)                  0.2                  J          3.4                            7.3                              0.5                 J             0.6                 J
                    4,4'DDD (P,P'DDD)                 3.1                             18.0                           36.8                             5.0                               3.1
                    2,4'DDT (O,IPDDT)                 0.1                  J          0.4              J             8.5                              0.8                               0.2                 J
                    4,4'DDT (P,PDDT)                  2.3                             3.5                            5.1                              3.6                               1.6
              PCB # (CLORINATION)
                                 8 (CL2)              0.7                  J          0.8              J             1.3                J             3.1                               0.5                 J
                                18 (CL3)              2.8                             3.3                            4.3                              2.4                               2.5                 J
                                28 (CL3)              0.4                  J          0.1              J             1.0                J             2.8                               2.4                 J
                                44 (CL4)              1.9                  1          2.4                            4.4                              4.1                               4.0
                                52 (CL4)              3.6                             3.4                            5.2                              7.5                               18.9
                                66 (CL4)              1.2                  J          0.9              J             1.1                J             2.5                               3.8
                                101 (CL5)             7.4                             8.2                            8.8                              21.5                              42.7
                                105 (CL5)             86.9                            14.3                           60.6                             3.2                               6.4
                         110/77 (CL5/4)               9.4                             6.3                            15.5                             27.3                              45.9
                    118/108/149(CL5/5/6)              4.1                             3.4                            6.4                              13.6                              25.5
                                128 (CL6)             1.9                  J          2.0                            2.8                              3.8                               7.8
                                138 (CL6)             10.4                            10.3                           20.1                             23.0                              41.6
                                126 (CL5)             0.0                ND           0.0            ND              0.0              ND              0.0               ND              0.0               ND
                                153 (CL6)             7.7                             5.3                            15.7                             30.1                              56.6
                                170 (CL7)             1.8                  J          0.9              J             1.2                J             1.0                 J             2.0                 J
                                180 (CL7)             6.4                             2.0                            9.7                              3.3                               1.3                 J
                    187/182/159(CL7n/6)               6.3                             5.7                            2.4                              3.8                               6.6
                                .195 (CL8)            0.2                  J          2.9                            0.0              ND              0.0               ND              0.1                 J
                                206 (CL9)             0.0                ND           0.0            ND              1.0                J             0.4                 J             0.5                 J
                                209 (CL 10)           0.1                  J          0.0            ND              0.2                J             0.0               ND              0.0               ND



                                                   = M mm M M = M mi M M M = M M
                                                   Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                              INVEST#              CBJB                               CBBL                              CBPP                               CBBB                             PCLO

                                     ID   Choctawhatchee Bay                Choctawhatchee Bay                 Choctawhatchee Bay                 Choctawhatchee Bay                  Panama City
                                   SITE        Joe's Bayou                        Ben's Lake                        Postil Point                     Boggy Bayou                    Little Oyster Bar
                         LABSAMNO                  K8066                              K8064                             K8060                              K8062                            K8068
                      SAMPLE TYPE                  SAMP                               SAMP                              SANT                               SAMP                             SAMP
                                  UNIT             ng/g dry                           ng/g dry                          ng1g dry                           ng/g dry                         ng/g dry
                                Analyte            Conc          DB QUAL              Cone          DB QUAL             Conc           DB QUAL             Conc           DB QUAL           Conc        DB QUAL

                     RECEIPT DATE                  01/19/94                           01/19/94                          01/17/94                           01/17/94                         01/19/94
                            QCBATCH                M1411                              M1411                             M1411                              M1411                            M1411
               EXTRACTION DATE                     07/25/94                           07/25/94                          07/25/94                           07/25/94                         07/25/94
                             METHOD                GCECD                              GCECD                             GCECD                              GCECD                            GCECD
                   ANALYSIS DATE                   08/28/94                           08/28/94                          08/28/94                           08/28/94                         08/28/94
                              MATRIX               TISSUE                             TISSUE                            TISSUE                             TISSUE                           TISSUE
                               WETWT               10.04                              10.03                             10.03                              10.02                            10.42
                               DRYWT               0.84                               0.94                              1.14                               1.11                             0.71
                             WTUNITS               GRAMS                              GRAMS                             GRAMS                              GRAMS                            GRAMS
                           % SOLIDS                8.4                                9.4                               11.4                               11.1                             6.8
                            % LIPIDS               9.4                                5.9                               12.2                               14.7                             32.2
          Surrogate Recoveries
      co            Pesticides & PCBs
                                DBOFB              74.2                               70.2                              69.7                               71.3                             77.6
                              PCB#103              74.2                               69.5                              67.8                               70.0                             80.4
                             PCB# 198              78.3                               69.9                              75.4                               75.5                             81.0
                         TOTAL BHCs                2.0                                2.0                               3.8                                3.1                              6.5
           TOT CHLORDANES (S&T)                    12.7                               20.8                              27.3                               35.0                             19.7
                         TOTAL DDTs                67.2                               236.2                             332.3                              301.7                            3381.6
                 TOTAL PCBs (S&T)                  117.8                              41.9                              168.4                              165.6                            211.1
                         ALPHA-BHC                 0.3                                0.3                               0.7                                0.5                              2.2
                                   HCB             0.1                                0.1                               0.1                                0.1                              0.0            ND
                           BETA-BHC                0.4                                0.9                               1.5                                1.0                              0.9
                        GAMMA-BHC                  0.5                                0.4                               0.5                                0.6                              3.4
                         DELTA-BHC                 0.8                J               0.3                               1.1                                1.0                              0.0            ND
                       HEPTACHLOR                  0.3                J               0.0                               0.1                                0.8                              0.9
                    HEPTA-EPOXIDE                  1.9                                10.8                              1.7                                6.0                              1.5
                   OXYCHLORDANE                    0.8                                0.9                               1.2                                1.5                              1.2
             GAMMA-CHLORDANE                       2.8                                7.1                               8.3                                13.0                             4.2
               ALPHA-CHLORDANE                     5.8                                6.3                               15.5                               15.6                             11.3
               TRANS-NONACHLOR                     4.7                                3.6                               10.0                               12.5                             5.9
                   CIS-NONACHLOR                   2.3                                1.1                               5.2                                6.0                              2.5





                                                Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                              INVEST#              CBJB                               CBBL                              CBPP                               CBBB                            PCLO

                                     ID   Choctawhatchee Bay                Choctawhatchee Bay                 Choctawhatchee Bay                 Choctawhatchee Bay                  Panama City
                                   SITE        Joe's Bayou                        Berfs Lake                        Postil Point                     Boggy Bayou                    Little Oyster Bar
                          LABSAMNO                 K8066                              K8064                             K8060                              K8062                           K8068
                      SAMPLE TYPE                  SAMP                               SAMP                              SAMP                               SAMP                            SAMP
                                  UNIT           ng/g dry                          ng/g dry                          ng/g dry                           ng/g dry                           ng/g dry
                                Analyte            Conc          DB QUAL              Conc          DB QUAL             Conc           DB QUAL             Conc           DB QUAL          Conc         DB QUAL

                              ALDRIN               0.3                                0.2                               0.8                                2.4                             1.7
                            DIELDRIN               5.6                                16.4                              7.7                                16.1                            3.2
                              ENDRIN               1.7                                0.5                               1.1                                1.7                             21.9
                                MIREX              0.7                                0.1                               0.6                                0.3                1            0.1              J
                  2,4'DDE (0,P'DDE)                1.2                                1.8                               1.6                                1.1                             14.8
                  4,4'DDE (P,P'DDE)                24.0                               120.0                             175.6                              158.6                           2063.7
                  2,4'DDD (0,P'DDD)                4.9                                7.5                               9.0                                8.9                             66.4
                  4,4'DDD (P,P'DDD)                34.1                               101.6                             135.3                              121.8                           1060.1
                  2,4'DDT (0,P'DDT)                0.4                                1.6                               1.1                                1.7                             18.2
                  4,4'DDT (P,PDD-f)                2.5                                3.6                               9.6                                9.6                             158.5
            PCB # (CLORINATION)
                               8 (CL2)             0.4                                0.5                               1.6                J               1.0                1            0.0             ND
                              18 (CL3)             1.1                                0.4                               4.1                                2.6                             2.5              1
                              28 (CL3)             2.5                                0.7                               1.8                                4.1                             0.5              J
                              44 (CL4)             2.9                                1.6                               4.3                                3.8                             3.1
                              52 (CL4)             3.6                                0.7                               3.6                                6.0                             1.6              1
                              66 (CL4)             3.3                                0.3                               1.0                                1.6                             0.6
                              101 (CL5)            6.1                                1.6                               6.1                                7.2                             4.9
                              105 (CL5)            1.6                                0.7                               1.0                                1.6                             0.0             ND
                       110/77 (CL5/4)              15.6                               3.1                               9.6                                16.3                            4.3
                  118/108/149(CL5/5/6)             6.2                                1.5                               3.0                                6.6                             3.3
                              128 (CL6)            0.6                                0.1                               0.9                                1.3                             2.5
                              138 (CL6)            4.4                                2.7                               12.8                               10.6                            8.0
                              126 (CL5)            0.0               ND               0.0              ND               0.0               ND               0.0               ND            0.0             ND
                              153 (CL6)            5.0                                2.7                               15.5                               9.3                             1.9
                              170 (CL7)            1.8                                1.1                               2.4                                1.8                             1.9
                              180 (CL7)            3.3                                LO                                2.9                                1.9                             10.3
                  187/182/159(CL7n/6)              0.8                                0.8                               7.7                                5.0                             2.7
                              195 (CL8)            0.0               ND               0.0              ND               0.4                                0.2                             49.0
                              206 (CL9)            0.0               ND               0.1               1               0.0               ND               0.3                1            0.0             ND
                           209 (CLIO)              0.0               ND               0.0              ND               0.2                                0.2                             1.4






                                                        Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                  INVEST#               AESP                              CKBP                                TBOT                                TBPB                                TBHB


                                          ID     Apalachec Bay                            Cedar Key                      Tampa Bay                           Tampa Bay                            Tampa Bay
                                       SITE       Spring Creek                            Black Point                  Old Tampa Bay                        Papys Bayou                          Hillsborough
                            LABSAMNO                    K8070                             K8072                               K8080                               K8078                               K8084
                         SAMPLE TYPE                    SAMP                              SAMP                                SAMP                                SAMP                                SAMP
                                      UNIT              ng/g dry                          ng1g dry                            ng/g dry                            ng/g dry                            ng/g dry
                                    Analyte             Conc          MQUAL               Cone           DB QUAL              Conc           MQUAL                Conc           DB QUAL              Conc           DB QUAL

                        RECEIPT DATE                    01/20/94                          01/20/94                            01/21/94                            01/21/94                            01/23/94
                                QCBATCH                 M1411                             M1411                               M1412                               M1412                               M1412
                  EXTRACTION DATE                       07/25/94                          07/25/94                            08/01/94                            08/01/94                            08/01/94
                                 METHOD                 GCECD                             GCECD                               GCECD                               GCECD                               GCECD
                      ANALYSIS DATE                     08/28/94                          08/28/94                            08/31/94                            08/30/94                            08/31/94
                                  MATRIX                TISSUE                            TISSUE                              TISSUE                              TISSUE                              TISSUE
                                  WETWT                 10.00                             10.00                               10.27                               10.36                               10.34
                                   DRYWT                0.71                              0.79                                0.80                                1.37                                1.66
                                WTUNITS                 GRAMS                             GRAMS                               GRAMS                               GRAMS                               GRAMS
                               % SOLIDS                 7.0                               7.9                                 7.8                                 13.2                                16.1
     00                         % LIPIDS                12.2                              9.0                                 3.8                                 7.8                                 8.2
             Surrogate Recoveries
                       Pesticides & PCBs
                                   DBOFB                70.6                              71.0                                68.3                                67.5                                62.3
                                  PCB#103               68.8                              69.6                                64.7                                64.2                                57.2
                                  PCB#198               70.9                              73.9                                74.4                                72.7                                66.2
                            TOTAL BHCs                  11.9                              1.9                 J               4.8                 J               3.8                                 4.5
              TOT CHLORDANES (S&T)                      90.1                              8.0                                 9.5                                 23.7                                125.0
                            TOTAL DDTs                  8.4                J              26.2                                19.3                                20.7                                64.5
                    TOTAL PCBs (S&T)                    168.9                             42.6                J               82.1                J               106.5                               203.8
                            ALPHA-BHC                   0.9                1              0.6                 J               2.1                                 1.2                                 1.1
                                       HCB              0.3                J              0.1                 J               0.0                 J               0.0                 J               0.0                 J
                               BETA-BHC                 3.3                               0.7                 J               0.6                 J               1.3                                 0.7
                           GAMMA-BHC                    1.2                J              0.4                 J               1.3                                 1.2                                 2.6
                            DELTA-BHC                   6.4                               0.2                 J               0.8                 J               0.2                 J               0.1                 J
                          HEPTACHLOR                    2.2                               0.0                 J               0.1                 J               0.1                 J               2.4
                       HEPTA-EPOXIDE                    1.4                               0.5                 J               1.1                 J               1.8                                 4.3
                      OXYCHLORDANE                      0.5                J              0.5                 J               0.5                 J               1.6                                 3.1
                GAMMA-CHLORDANE                         0.1                J              1.1                 J               3.6                                 7.7                                 115.3
                 ALPHA-CHLORDANE                        76.0                              5.6                                 2.9                                 7.4                                 78.7
                 TRANS-NONACHLOR                        10.4                              1.9                                 5.4                                 14.4                                39.6
                      CIS-NONACHLOR                     3.2                               0.8                 J               3.6                                 9.9                                 17.4




     mmmmm Mw @,Mm mmmw M M M M M
                                                    Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                 INVEST#               AESP                              CKBP                               TBOT                               TBPB                                TBHB


                                         ID     Apalachee Bay                        Cedar Key                         Tampa Bay                          Tampa Bay                           Tampa Bay
                                      SITE       Spring Creek                       Black Point                      Old Tampa Bay                        Papys Bayou                        Hillsborough
                             LABSAMNO                  K8070                             K8072                              K8080                              K8078                               K8084
                         SANVLE TYPE                   SAW                               SAMP                               SAMP                               SAMP                                SAMP
                                      UNIT          ng/g dry                          ng/g dry                           ng/g dry                           ng/g dry                            ng/g dry
                                   Analyte             Conc         DB QUAL              Conc          DB QUAL              Conc          DB QUAL              Conc          DB QUAL               Conc           DB QUAL

                                 ALDRIN                3.7                               0.3                J               0.1                J               0.0                 ND              1.7
                               DIELDRIN                0.7                               0.6                J               1.1                J               3.9                                 9.9
                                 ENDRIN                27.7                              2.6                                0.0               ND               0.0                 ND              0.0               ND
                                   MIREX               0.4                J              0.0              ND                0.3                J               3.5                                 2.6
                     2,4'DDE (0,P'DDE)                 0.0              ND               1.3                                1.7                                0.7                 J               4.0
                     4,4'DDE (P,P'DDE)                 0.0              ND               18.5                               13.4                               15.9                                37.0
                     2,4'DDD (0,P'DDD)                 0.2                J              0.8                J               0.2                J               0.1                 J               2.0
                     4,4'DDD (PP'DDD)                  2.2                               4.6                                3.5                                3.7                                 13.1
                     2,4'DDT (0,P'DDT)                 0.0              ND               0.0              ND                0.0               ND               0.0                 ND              2.8
                     4,4013T (P,PDDT)                  6.0                               0.8                                0.6                1               0.3                 1               5.6
               PCB # (CLORINATION)
        00                        8 (CL2)              0.0              ND               0.7                J               1.8                J               0.0                 ND              0.0               ND
                                 18 (CL3)              4.3                               1.6                J               1.1                J               1.6                                 2.4
                                 28 (CL3)              0.0              ND               0.0              ND                1.2                1               0.4                 J               2.2
                                 44 (CL4)              12.0                              1.1                J               2.1                J               1.7                                 5.0
                                 52 (CL4)              1.9                J              0.4                J               1.5                J               1.5                                 5.3
                                 66 (CL4)              5.0                               0.0              ND                2.0                J               0.9                 J               3.1
                                 101 (CL5)             10.2                              1.2                J               7.2                                6.0                                 7.7
                                 105 (CL5)             1.1                J              0.1                J               0.7                J               0.7                 J               2.7
                          110/77 (CL5/4)               10.5                              1.0                J               7.0                                7.3                                 27.6
                     118/108/149(CL5/5/6)              3.7                               0.5                J               1.8                J               4.3                                 12.9
                                 128 (CL6)             0.0                J              0.2                J               0.2                J               0.3                 J               0.2                 J
                                 138 (CL6)             3.4                               1.5                J               2.8                                4.1                                 7.9
                                 126 (CL5)             0.0              ND               0.0              ND                0.0               ND               0.0                 ND              0.0               ND
                                 153 (CL6)             18.7                              0.3                J               1.5                J               4.4                                 16.0
                                 170 (CL7)             2.5                J              1.6                J               2.5                J               2.3                                 2.8
                                 180 (CL7)             2.7                J              1.8                J               3.0                                2.2                                 2.6
                     187/182/159(CL7/7/6)              2.2                J              0.3                J               1.2                J               3.3                                 5.6
                                 1195 (CL8)            1.3                J              5.8                                0.7                J               9.9                                 1.0                 J
                                 206 (CL9)             0.0              ND               0.0              ND                0.0               ND               0.0                 ND              0.0               ND
                              209 (CLIO)               0.3                J              0.7                J               0.0               ND               1.1                 J               0.0               ND






                                                    Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                            INVEST#                 TBMK                                TBKA                              TBNP                                CBBI                                 RBHC

                                    ID         Tampa Bay                           Tampa Bay                          Tampa Bay                        Charlotte Harbor                       Rookery Bay
                                 SITE      Mullet Key Bayou                      Knights Airport                     Navarez Park                         Bird Island                       Henderson Creek
                       LABSAMNO                     K8088                               K8074                             K8082                               K8086                                K8090
                    SAMPLE TYPE                     SAW                                 SAMP                              SANT                                SAMP                                 SAMP
                                UNIT                ng1g dry                            ng1g dry                          ng/g dry                            ng/g dry                             ng/g dry
                              Analyte               Conc           DB QUAL              Conc          DB QUAL             Conc           DB QUAL              Conc           DB QUAL               Conc            DB QUAL

                   RECEIPT DATE                     01/23/94                            01/21/94                          01/21/94                            01/23/94                             01/23/94
                          QCBATCH                   M1412                               M1411                             M1412                               M1412                                M1412
             EXTRACTION DATE                        08/01/94                            07/25/94                          08/01/94                            08/01/94                             08/01/94
                           METHOD                   GCECD                               GCECD                             GCECD                               GCECD                                GCECD
                 ANALYSIS DATE                      08/31/94                            08/28/94                          08/31/94                            09/26/94                             09/26/94
                            MATRIX                  TISSUE                              TISSUE                            TISSUE                              TISSUE                               TISSUE
                             WETWT                  10.25                               10.00                             10.20                               10.31                                10.15
                             DRYWT                  1.75                                1.25                              1.64                                1.33                                 1.21
                           WTUNITS                  GRAMS                               GRAMS                             GRAMS                               GRAMS                                GRAMS
                         % SOLIDS                   17.1                                12.5                              16.1                                12.9                                 11.9
                          % LIPIDS                  9.0                                 14.9                              6.9                                 5.9                                  4.3
       grrogate Recoveries
                  Pesticides & PCBs
                              DBOFB                 70.0                                73.1                              65.4                                68.5                                 73.1
                            PCB#103                 88.1                                75.1                              76.7                                71.5                                 75.2
                            PCB#198                 81.2                                81.9                              83.9                                67.8                                 74.9
                       TOTAL BHCs                   2.8                                 5.2                               2.5                                 0.5                 J                0.2                  J
         TOT CI]LORDANES (S&T)                      6.8                                 80.8                              25.0                                14.4                                 9.3
                       TOTAL DDTs                   7.9                                 198.8                             25.8                                12.2                                 11.7
               TOTAL PCBs (S&T)                     54.8                                712.8                             140.2                               34.3                                 13.6                 J
                       ALPHA-BHC                    0.9                                 0.4                J              2.0                                 0.0               ND                 0.0                  ND
                                 HCB;               0.0               ND                0.3                J              0.0               ND                0.0               ND                 0.0                  ND
                         BETA-BHC                   1.3                                 0.7                J              0.0               ND                0.3                 J                0.2                  J
                      GAMMA-BHC                     0.5                 J               3.4                               0.5                J                0.2                 J                0.0                  ND
                       DELTA-BHC                    0.0               ND                0.7                J              0.0               ND                0.0               ND                 0.0                  ND
                     HEPTACHLOR                     0.0               ND                0.5                J              0.0               ND                0.0               ND                 0.0                  ND
                  HEPTA-EPOXIDE                     0.7                                 1.8                               1.1                                 0.3                 J                0.0                  ND
                 OXYCHLORDANE                       0.8                                 4.8                               1.2                                 0.4                 1                0.2                  J
           GAMMA-CHLORDANE                          2.2                                 30.2                              10.8                                1.4                                  0.3                  J
             ALPHA.-CHLORDANE                       2.6                                 36.7                              9.3                                 10.8                                 8.4
             TRANS-NONACHLOR                        3.5                                 41.7                              14.6                                3.3                                  0.9
                 CIS-NONACHLOR                      1.7                                 19.8                              8.3                                 2.0                                  0.8                  J





                                                   Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                            INVEST#              TBMK                                 TBKA                              TBNP                               CBBI                                 RBHC


                                    ID        Tampa Bay                           Tampa Bay                         Tampa Bay                       Charlotte Harbor                       Rookery Bay
                                 SITE      Mullet Key Bayou                     Knights Airport                    Navarez Park                        Bird Island                      Henderson Creek
                        LABSAMNO                 K8088                                K8074                             K8082                              K8086                                K8090
                    SAMPLE TYPE                  SAW                                  SAMP                              SANT                               SAMP                                 SAMP
                                UNIT            ng1g dry                            ng/g dry                          ng1g dry                           ng/g dry                            ng/g dry
                              Analyte              Conc           DB QUAL             Conc           DB QUAL            Conc           DB QUAL             Conc           DB QUAL               Cone            DB QUAL

                            ALDRIN                 0.0                ND              0.1                J              0.0               ND               0.0                ND                0.0                   ND
                          DIELDRIN                 1.3                                11.9                              3.9                                1.9                                  0.5                   J
                            ENDRIN                 0.0                ND              0.7                J              0.0               ND               0.0                ND                0.0                   ND
                              MIREX                0.4                 J              1.3                               2.4                                0.0                ND                0.0                   ND
                2,4'DDE (0,P'DDE)                  3.7                                5.6                               1.0                                0.5                 J                8.7                   M
                4,4'DDE (P,P'DDE)                  4.0                                160.7                             13.1                               11.0                                 2.3
                2,4'DDD (0,P'DDD)                  0.3                 1              3.0                               0.7                                0.1                                  0.0                   ND
                4,4'DDD (PP'DDD)                   0.0                ND              21.9                              3.5                                0.0                ND                0.3                   J
                2,4'DDT (0,P'DDT)                  0.0                ND              3.2                               7.5                                0.0                ND                0.0                   ND
                4,4'DDT (PPDDT)                    0.0                ND              4.4                               0.0               ND               0.6                 J                0.3
          PCB # (CLORINATION)
       00                    8 (CL2)               0.8                 J              1.9                               0.0               ND               5.7                                  2.7
        CO                  18 (CL3)               0.6                 J              7.3                               1.1                J               0.0                ND                0.0                   ND
                            28 (CL3)               0.0                ND              12.9                              0.5                J               0.3                 J                0.1                   J
                            44 (CL4)               0.7                 J              16.9                              1.3                                0.8                 J                0.3                   J
                            52 (CL4)               0.0                ND              27.3                              1.8                                0.2                 J                0.0                   J
                            66 (CL4)               0.7                                16.8                              2.5                                0.0                ND                0.0                   ND
                            101 (CL5)              8.9                                41.9                              8.9                                0.6                 J                0.1                   J
                            105 (CL5)              0.0                ND              8.4                               0.0               ND               0.1                 J                0.0                   J
                     110/77 (CL5/4)                3.3                                45.6                              8.3                                0.0                ND                0.0                   ND
                118/108/149(CL5/5/6)               1.5                                40.2                              5.4                                1.3                 J                0.0                   ND
                            128 (CL6)              0.0                ND              2.6                               0.1                                0.1                 J                0.0                   ND
                            138 (CL6)              1.1                 1              34.2                              24.1                               1.6                                  0.6                   J
                            126 (CL5)              0.0                ND              0.0               ND              0.0               ND               0.0                ND                0.0                   ND
                            153 (CL6)              0.0                ND              56.0                              7.0                                1.2                 J                0.2                   J
                            170 (CL7)              0.4                 J              1.4                J              0.5                J               2.1                                  0.9                   J
                            180 (CL7)              0.0                ND              15.6                              1.1.               J               1.2                 J                0.1                   J
                187/182/159(CL7/7/6)               0.6                                21.8                              5.5                                0.6                 J                0.0                   ND
                            195 (CL8)              6.6                                12.4                              0.0               ND               0.0                ND                0.0                   ND
                            206 (CL9)              0.0                ND              1.2                J              0.0               ND               0.0                ND                0.0                   ND
                         209 (CL 10)               0.4                                0.2                J              0.3                                0.0                ND                0.0                   ND




    mmmmmmmmm MM MIMMMMMMM
                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                INVEST#               FBFO                              FBFO                             FBFO                             FBJB.                             FBJB

                                        ID       Florida Bay                       Florida Bay                      Florida Bay                      Florida Bay                       Florida Bay
                                     SITE             Flamingo                          Flamingo                         Flamingo                         Joe Bay                           Joe Bay
                           LABSAMNO                   K8092                             K8093                            K8094                            K8107                             K8108
                        SAMPLE TYPE                   SAMP                              SAW                              SAMP                             SAMP                              SAMP
                                    UNIT              ng/g dry                          ng/g dry                         ng/g dry                         ng/g dry                          ng/g dry
                                  Analyte             Cone          DB QUAL             Conc         DB QUAL             Cone         DB QUAL             Conc          DD QUAL             Cone          DB QUAL

                       RECEIPT DATE                   01/27/94                          01/27/94                         01/27/94                         01/27/94                          01/27/94
                              QCBATCH                 M1412                             M1412                            M1412                            M1412                             M1412
                 EXTRACTION DATE                      08/01/94                          08/01/94                         08/01/94                         08/01/94                          08/01/94
                               METHOD                 GCECD                             GCECD                            GCECD                            GCECD                             GCECD
                     ANALYSIS DATE                    08/31/94                          09/30/94                         09/01/94                         09/26/94                          09/27/94
                                MATRIX                TISSUE                            TISSUE                           TISSUE                           TISSUE                            TISSUE
                                 WETWT                10.19                             10.03                            10.35                            5.50                              10.41
                                 DRYWT                1.60                              1.04                             1.18                             0.60                              1.00
                               WTUNITS                GRAMS                             GRAMS                            GRAMS                            GRAMS                             GRAMS
                              % SOLIDS                15.7                              10.4                             11.4                             11.0                              9.6
                               % LIPIDS               9.3                               6.3                              7.4                              4.5                               4.5
      00     Surrogate Recoveries
                      Pesticides & PCBs
                                  DBOFB               71.3                              71.9                             55.8                             61.2                              66.8
                                 PCB#103              86.6                              74.4                             74.5                             62.8                              69.7
                                 PCH#198              93.5                              78.1                             69.8                             60.5                              68.8
                           TOTAL BHCs                 2.2                               4.3                              4.1                              0.3                               0.4
              TOT CHLORDANES (S&I)                    4.8                               3.5                              1.4                              2.4                               3.9
                           TOTAL DDTs                 41.4                              30.1                             27.7                             72.8                              51.2
                   TOTAL PCBs (S&T)                   159.8                             43.4                             106.0                            28.2                              15.1
                           ALPHA-BHC                  1.9                               2.2                              3.7                              0.0               ND              0.2
                                      HCB             0.0               ND              0.0              ND              0.0             ND               0.0               ND              0.0
                              BETA-BHC                0.1                               0.5               1              0.0             ND               0.0               ND              0.0              ND
                          GAMMA-BHC                   0.3                               1.3                              0.0             ND               0.3                1              0.2               1
                           DELTA-BHC                  0.0               ND              0.4                              0.4              1   .           0.0               ND              0.0              ND
                          HEPTACHLOR.                 0.0               ND              0.5                              0.0             ND               0.0               ND              0.2
                       HEPTA-EPOXIDE                  0.1                               0.5                              0.0             ND               0.0                1              0.1
                     OXYCHLORDANE                     0.3                               0.2                              0.0             ND               0.3                               0.1
                GAMMA-CHLORDANE                       3.7                               0.3                              0.0             ND               0.1                               0.1
                 ALPHA-CHLORDANE                      3.1                               2.2                              1.4                              1.8                               3.0
                 TRANS-NONACHLOR                      1.6                               0.3                              0.0             ND               0.5                J              0.6
                      CIS-NONACHLOR                   0.6                               0.3                              0.0             ND               0.1                1              0.3




                M                     mean M MON M M M M MIM M- M M M M
                                                 Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                INVEST#              FBFO                            FBFO                           FBFO                            FBJB                            FBJB


                                       ID       Florida Bay                      Florida Bay                    Florida Bay                    Florida Bay                      Florida Bay
                                     SITE        Flamingo                         Flamingo                       Flamingo                           Joe Bay                         Joe Bay
                            LA13SAMNO                K8092                           K8093                          K8094                           K8107                           K8108
                        SAMPLE TYPE                  SAMP                            SAW                            SAMP                            SAMP                            SAMP
                                    UNIT          ng1g dry                        ng/g dry                       ng/g dry                           ng/g dry                        ng/g dry
                                  Analyte            Conc         DB QUAL            Conc         DB QUAL           Conc         DB QUAL            Conc         DB QUAL            Conc         DB QUAL

                                ALDRIN               0.1                1            0.0                ND          0.0              ND             0.0                ND           0.2
                              DIELDRrN               0.8                             1.0                            0.0              ND             0.8                1            0.7
                                ENDRIN               0.0                ND           0.0                ND          0.0              ND             0.0                ND           0.0                ND
                                  MIREX              0.2                1            0.0                ND          0.0              ND             0.0                ND           0.0                ND
                     2,4'DDE (0,P'DDE)               19.9               M            22.1               M           10.6             M              66.4               M            45.7               M
                     4,4'DDE (P,FDDE)                14.2                            6.1                            8.2                             6.3                             4.8
                     2,4'DDD (0,P'DDD)               1.8                             0.0                ND          0.0              ND             0.0                ND           0.0                ND
                     4,4'DDD (P,P'DDD)               5.0                             1.5                            0.0              ND             0.1                1            0.0                ND
                     2,4'DDT (0,P'DDT)               0.0                ND           0.0                ND          9.0                             0.0                ND           0.0                ND
                     4,4'DDT (PP'DDT)                0.6                J            0.4                1           0.0              ND             0.0                ND           0.7                J
      Go       PCB # (CLORINATION)
      U1                         8 (CL2)             0.0                ND           1.1                1           0.0              ND             4.8                             2.3
                                18 (CL3)             0.9                1            0.0                ND          0.9              1              0.0                ND           0.0                ND
                                28 (CL3)             3.1                             0.7                J           0.0              ND             2.9                1            0.2                1
                                44 (CL4)             2.6                             0.7                1           0.0              ND             1.1                1            0.9                1
                                52 (CL4)             4.5                             0.5                1           0.0              ND             0.0                ND           0.1                1
                                66 (CL4)             7.3                             3.9                            0.0              ND             0.0                ND           0.0                ND
                                101 (CL5)            6.0                             0.8                1           0.0              ND             0.0                ND           0.0                1
                                105 (CL5)            0.0                ND           0.0                ND          0.0              ND             0.0                1            0.1                1
                          110/77 (CL5/4)             17.8                            6.6                            1.3              1              0.0                ND           0.0                ND
                     118/108/149(CL5/5/6)            4.8                             1.0                J           0.0              ND             0.0                ND           0.0                ND
                                128 (CL6)            3.2                             0.3                1           0.0              ND             0.2                             0.1
                                138 (CL6)            2.8                             1.0                1           34.7                            0.9                             0.7
                                126 (CL5)            0.0                ND           0.0                ND          0.0              ND             0.0                ND           0.0                ND
                                153 (CL6)            3.5                             0.6                1           0.0              ND             0.1                             0.1
                                170 (CL7)            17.5                            2.3                            0.0              ND             1.7                             1.0
                                180 (CL7)            2.5                             0.0                ND          0.0              ND             0.2                1            0.1
                     1871182/159(CL7/7/6)            0.2                J            0.2                1           10.5                            0.0                ND           0.1
                                195 (CL8)            0.0                ND           0.0                ND          0.0              ND             0.0                ND           0.2                1
                                206 (CL9)            0.0                ND           0.0                ND          0.0              ND             0.0                ND           0.0                ND
                              209 (CL 10)            0.0                ND           0.0                ND          0.0              ND             0.0                ND           0.0                ND

                              I




                                                     m m mm @ m m m m mm                                                                                                                                                      m
                                                    Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                          INVEST#               FBJB                            BHKF                           PRBB                           PRBM                         PRBJ


                                                  ID       Florida Bay                     Bahia Honda                    Puerto Rico                    Puerto Rico                  Puerto Rico
                                               SITE             Joe Bay                    Key Florida                         Boqueron                       Montalva              Bahia De Jobos
                                    LABSAMNO                    K8109                           K8076                          K8122                          K8124                        K8126
                                  SAMPLE TYPE                   SAM[P                           SAMP                           SAW                            SAMP                         SAMP
                                              UNIT              ng/g dry                        ng/g dry                       ng/g dry                       ng/g dry                     ng/g dry
                                            Analyte             Conc          DB QUAL           Conc         DB QUAL           Conc         DB QUAL           Conc       DB QUAL           Cone        DB QUAL

                                 RECEIPT DATE                   01127/94                        01/21/94                       02/16/94                       02/16/94                     02/16/94
                                        QCBATCH                 M1412                           M1412                          M1412                          M1412                        M1412
                           EXTRACTION DATE                      08/01/94                        08/01/94                       08/01/94                       08/01/94                     08/01/94
                                         METHOD                 GCECD                           GCECD                          GCECD                          GCECD                        GCECD
                               ANALYSIS DATE                    09/01/94                        08/31/94                       09/01/94                       09/01/94                     09/01/94
                                          MATRIX                TISSUE                          TISSUE                         TISSUE                         TISSUE                       TISSUE
                                          WETWT                 10.38                           10.26                          10.02                          10.06                        10.19
                                           DRYWT                1.09                            1.82                           1.62                           1.66                         1.65
                                        VTrUNITS                GRAMS                           GRAMS                          GRAMS                          GRAMS                        GRAMS
                                       % SOLIDS                 10.5                            17.7                           16.2                           16.5                         16.1
                                        % LIPIDS                7.1                             10.9                           5.0                            5.8                          6.1
         Go           Surrogate Recoveries
         0)                    Pesticides & PCBs
                                           DBOFB                60.9                            56.9                           56.6                           62.0                         63.8
                                          PCB#103               57.4                            67.3                           54.0                           58.9                         61.1
                                          PCB#198               58.6                            64.9                           56.2                           62.5                         64.4
                                    TOTAL BHCs                  2.3                             2.5                            1.1                            2.2                          1.7
                       TOT CHLORDANES (S&T)                     2.2                             1.1                            0.8                            2.1                          0.7
                                    TOTAL DDTs                  93.0                            1.5                            3.2                            7.8                          3.0
                            TOTAL PCBs (S&T)                    51.8                            23.8                           60.3                           245.5                        32.3
                                    ALPHA-BHC                   1.0                             1.0                            0.8                            1.1                          1.0
                                               HCB              0.1                             0.1                            0.1                            0.0                          0.1
                                       BETA-BHC                 0.4                             1.2                            0.2                            0.6                          0.1
                                    GANOAA-BHC                  0.6                1            0.0             ND             0.0             ND             0.3             1            0.2              1
                                    DELTA-BHC                   0.3                1            0.3              1             0.0               1            0.2             1            0.3              J
                                   HEPTACHLOR                   0.1                1            0.0             ND             0.0             ND             0.1             1            0.1              1
                                HEPTA-EPOXIDE                   0.5                             0.3                            0.2                            0.7                          0.3
                              OXYCHLORDANE                      0.6                             0.6                            0.3                            0.5                          0.1
                         GAMMA-CHLORDANE                        0.5                1            0.0             ND             0.1                            0.6                          0.1
                          ALPHA-CHLORDANE                       1.4                             0.7                            0.6                            1.2                          0.3
                          TRANS-NONACHLOR                       0.3                             0.1              1             0.0               J            0.1             1            0.0            ND
                               CIS-NONACHLOR                    0.4                1            0.0             ND             0.2                            0.2                          0.2





                                               Mussel Watch Project Year 9 - Pesticides and PCBs Data (Tissue)



                                      INVEST#             FBJB                         BHKF                         PRBB                      PRBM                        PRBJ


                                             ID       Florida Bay                  Bahia Honda                 Puerto Rico                 Puerto Rico                Puerto Rico
                                           SITE           Joe Bay                  Key Florida                  Boqueron                    Montalva                Bahia De Jobos
                                  LABSAMNO                K8109                        K8076                        K8122                     K8124                       K8126
                               SAAVLE TYPE                SAW                          SAMP                         SAMP                       SAMP                       SAMP
                                          UNIT            ng/g dry                   ng1g dry                    ng/g dry                    ng/g dry                  ng/g dry
                                        Analyte           Conc         DD QUAL         Conc        DB QUAL          Conc       DB QUAL         Conc       DB QUAL         Conc       DB QUAL

                                      ALDRIN              0.0               J          0.0            ND            0.0             J          0.2            J           0.0           ND
                                     DIELDRIN             1.0                          0.8                          0.9                        0.8                        0.6            J
                                      ENDRIN              0.6               J          0.0            ND            0.2             J          0.0            J           0.2            J
                                        MIREX             0.0               ND         0.0            ND            0.0           ND           0.3            J           0.0           ND
                            2,4'DDE (0,P'DDE)             87.3              m          0.6                          0.0           ND           1.2                        0.6            J
                            4,4'DDE (P,FDDE)              4.7                          0.8                          1.3                        2.7                        1.0
                            2,4'DDD (0,P'DDD)             0.1               J          0.0            ND            0.1             J          1.5                        0.1            J
                            4,4'DDD (P,FDDD)              0.0               ND         0.0            ND            1.1                        2.4                        1.3
                            2,4'DDT (0,P'DDT)             0.0               J          0.0            ND            0.8                        0.0           ND           0.0           ND
                            4,411313T (PPIDDT)            0.9                          0.0            ND            0.0           ND           0.0           ND           0.0           ND
                      PCB # (CLORINATION)
                                       8 (CL2)            1.0               J          0.5             J            0.5             J          0.3            J           0.9            J
        00                            18 (CL3)            0.4               J          0.4             J            0.6             J          0.0           ND           0.0           ND
         4                            28 (CL3)            0.7               J          0.0            ND            0.7             J          1.2            J           0.2            J
                                      44 (CL4)            1.5               J          0.5             J            0.6             J          0.7            J           0.5            J
                                      52 (CL4)            2.3                          0.7             J            0.3             J          1.2            J           0.3            J
                                      66 (CL4)            0.7               J          2.9                          0.3             J          41.7                       1.5.
                                      101 (CL5)           1.3               J          0.0            ND            3.0                        3.2                        0.6            J
                                      105 (CL5)           0.0               ND         0.0            ND            0.0           ND           1.1            J           0.2            J
                                110/77 (CL5/4)            9.2                          0.0            ND            7.8                        8.9                        4.2
                            118/108/149(CL5/5/6)          0.0               ND         0.0            ND            1.0             J          0.8            J           0.2            J
                                      128 (CL6)           0.3               J          0.0            ND            0.2             J          1.4                        0.1            J
                                      138 (CL6)           1.3               1          1.0             1            3.2                        6.1                        1.4
                                      126 (CL5)           0.0               ND         0.0            ND            0.0           ND           5.1                        0.0           ND
                                      153 (CL6)           0.0               ND         0.0            ND            5.1                        22.3                       1.2            J
                                      170 (CL7)           2.5                          2.0                          1.8                        3.0                        1.6
                                      180 (CL7)           0.6               J          0.7             J            0.6             J          2.7                        0.4            J
                            187/182/159(CL7n/6)           0.2               J          0.7             J            1.1             J          16.1                       0.1            J
                                      195 (CL8)           0.1               J          0.0            ND            0.5             J          0.0           ND           0.5            J
                                      206 (CL9)           0.0               ND         0.0            ND            0.0             J          0.0           ND           0.0           ND
                                    209 (CL 10)           0.6               J          0.5             J            0.2             J          1.2            J           0.1




 I
 I
 I
 I
 I
 I
 I
 I       Pesticides and PCBs QC Data
 I                 (Tissue)
 I
 I
 I
 I
 I
 I
 I
 I
 1

                       88
 I





                                  Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)


                                            INVEST#      LAB QA SAMPLE                        ABLR                LAB QA SAMPLE                 LAB QA SAMPLE
                                                    ED     PROC BLANK                     Aransas Bay                     ABLR                         ABLR
                                                 SITE                                         Long Reef                   Long Reef                    Long Reef
                                         LABSAMNO                Q9490                        K8032                       Q9492                        Q9493
                                     SAMPLE TYPE                 BLANK                        SAW                         DUP                            MS
                                                 UNIT            ng1g                         ng/g                        ng/g                            %
                                               Analyte           Conc         DB QUAL         Conc       DB QUAL          Conc        DB QUAL          Recovery      DB QUAI

                                    RECEIPT DATE                                              12/17/93                    12/17/93                     12/17/93
                                           QCBATCH               M1410                        M1410                       M1410                        M1410
                              EXTRACTION DATE                    07/21/94                     07/21/94                    07/21/94                     07/21/94
                                            METHOD               GCECD                        GCECD                       GCECD                        GCECD
                                  ANALYSIS DATE                  08/26/94                     09/27/94                    08/26/94                     08/27/94
                                             MATRIX              TTSSUE                       TISSUE                      TISSUE                       TISSUE
                                            SUBMAT
                                             WETWT                                            10.05                       10.14                        10.12
                                             DRYWT               10.00                        1.65                        1.67                         1.69
      00                                   WTUNITS               GRAMS           DRY          GRAMS        DRY            GRAMS          DRY           GRAMS            DRY
     (.0                                 PCTSOLIDS                                            16.4%                       16.5%                        16.7%
                                        Lipid Weight
                                           % LIPIDS                                           18.74                       15.32                        17.54
                          Surrogate Recoveries
                                   Pesticides & PCBs
                                              DBOFB              61.8                         72.4                        59.2                         58.3
                                             PCB#103             67.0                         74.3                        65.1                         54.8
                                             PCB#198             60.1                         74.2                        69.7                         66.4
                                       TOTAL BHCs                0.0             ND           1.8            J            5.1                                           NA
                           TOT CHLORDANES (S&T)                  0.0             ND           5.0                         4.8                                           NA
                                       TOTAL DDTs                0.0             ND           14.5                        9.3                                           NA
                                TOTAL PCBs (S&T)                 2.2              J           26.3           J            39.6            J                             NA
                                        ALPHA-BHC                0.0             ND           0.6                         0.3             J            84.3
                                                 HCB             0.0             ND           0.2            J            @0.1            J            96.3
                                          BETA-BHC               0.0             ND           1.1                         0.0            ND            91.6
                                       GAMMA-BHC                 0.0             ND           0.0           ND            4.6                          98.6





                                    Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)


                                              INVEST#       LAB QA SAMPLE                        ABLR                   LAB QA SAMPLE                 LAB QA SAMPLE
                                                      ID      PROC BLANK                      Aransas Bay                     ABLR                            ABLR
                                                    SITE                                       Long Reef                    Long Reef                      Long Reef
                                          LABSAMNO                Q9490                          K8032                        Q9492                           Q9493
                                       SAMPLE TYPE               BLANK                           SAMP                           DUP                             MS
                                                   UNIT             ng/g                           ng/g                         ng/g                             %
                                                 Analyte            Conc          DB QUAL          Conc       DB QUAL           Conc         D13 QUAL       Recovery         DB QUAL

                                          DELTA-BHC                 0.0              ND            0.0           ND             0.2               J           88.0
                                        HEPTACHLOR                  0.0              ND            0.1            J             0.0             ND            76.2
                                    HEPTA-EPOXIDE                   0.0              ND            1.1                          0.0             ND            62.1
                                    OXYCIRLORDANE                   0.0              ND            0.3            J             0.5               J           88.5
                              GAMMA-CHLORDANE                       0.0              ND            1.0                          1.0                           79.2
                               ALPHA-CHLORDANE                      0.0              ND            1.9                          2.8                           92.4
                               TRANS-NONACHLOR                      0.0              ND            2.0                          1.9                           79.7
                                    CIS-NONACHLOR                   0.0              ND            0.9                          1.1                           71.6
                                               ALDRIN               0.0              ND            0.7                          1.5                           74.4
                                             DIELDRIN               0.0              ND            2.0                          1.7                           69.7
                                               ENDRIN               0.0              ND            0.0           NID            0.0             ND            98.2
                                                 MIREX              0.0              ND            0.0           ND             0.1               J           87.8
                                    2,4'DDE (0,P'DDE)               0.0              ND            0.0           ND             0.0             ND            67.2
                                    4,4'DDE (P,P'DDE)               0.0              ND            11.1                         9.2                           72.1
                                    2,4'DDD (0,PDDD)                0.0              ND            0.0           ND             0.0             ND            61.9
                                    4,4'DDD (P,P'DDD)               0.0              ND            1.5                          0.0             ND            118.0
                                    2,4'DDT (0,P'DDT)               0.0              ND            0.2            J             0.2               J           69.3
                                    4,4'DDT (PP'DDT)                0.0              ND            1.8                          0.0             ND            90.5
                             PCB # (CLORrNATION)
                                                8 (CL2)             0.0              ND            0.4            J             0.6               J           120.2
                                               18 (CL3)             0.0              ND            0.0           ND             1.1               J           61.2
                                               28 (CL3)             0.0              ND            0.0           ND             0.0             ND            109.1
                                               44 (CL4)             0.0              ND            3.6                          0.7               J           88.0
                                               52 (CL4)             0.0              ND            0.5            J             1.0               1           97.8
                                               66 (CL4)             0.0              ND            0.0           ND             0.0             ND            107.2
                                              101 (CL5)             0.0              ND            0.9            J             1.3                           94.9





                                 Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)



                                           INVEST#      LAB QA SAMPLE                      ABLR.                LAB QA SAMPLE                LAB QA SAMPLE
                                                   ID     PROCBLANK                     Aransas Bay                    ABLR                          ABLR
                                                SITE                                     Long Reef                   Long Reef                    Long Reef
                                        LABSAMNO              Q9490                        K8032                       Q9492                         Q9493
                                    SAMPLE TYPE              BLANK                         SAMP                         DUP                           MS
                                                UNIT            ng/g                         ng/g                       ng/g                           %
                                              Analyte           Conc         DB QUAL         Conc      DB QUAL          Conc        DB QUAL       Recovery        DB QUAL

                                           105 (CL5)            0.0             ND           0.2           J            0.0            ND            98.9
                                     110/77 (CL5/4)             0.0             ND           0.0          ND            0.0            ND                            NA
                                  118/108/149(CL5/5/6)          0.0             ND           0.3           J            0.0            ND            115.8
                                           128 (CL6)            0.0             ND           0.4           1            0.0            ND            114.8
                                           138 (CL6)            0.0             ND           1.7                        2.5                          100.6
                                           126 (CL5)            0.0             ND           0.0          ND            0.0            ND                            NA
                                           153 (CL6)            0.0             ND           1.0           J            1.4                          68.0
                                           170 (CL7)            0.0             ND           0.6           J            5.1                          105.3
                                           180 (CL7)            0.0             ND           1.0           J            0.1             J            101.2
      CD                          187/182/159(CL7/7/6)          0.0             ND           0.7           J            0.9             J            97.3
                                           195 (CL8)            0.0             ND           0.0          ND            1.2                          108.1
                                           206 (CL9)            0.0             ND           0.0          ND            0.0            ND            85.8
                                         209 (CL 10)            0.0             ND           0.0          ND            0.8             J            105.7





                                  Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)




                                                   ID      PROCBLANK                      Breton Sound                      BSSI                        BSSI
                                                 SITE                                      Sable Island                Sable Island                  Sable Island
                                            INVEST#      LAB QA SAMPLE                         BSSI                LAB QA SAMPLE                 LAB QA SAMPLE



                                        LABSAMNO                Q9495                          K8038                        Q9497                       Q9498
                                    SAMPLE TYPE                 BLANK                          SAMP                         DUP                           MS
                                                UNIT            ng1g                           ng1g                         ng/g                           %
                                              Analyte           Conc          DB QUAL          Conc       DB QUAL           Conc        DB QUAL         Recovery      DB QUAL

                                    RECEIPT DATE                                               01/15/93                     01/15/93                    01/15/93
                                          QCBATCH               M1411                          M1411                        M1411                       M1411
                              EXTRACTION DATE                   07/25/94                       07/25/94                     07/25/94                    07/25/94
                                           METHOD               GCECD                          GCECD                        GCECD                       GCECD
                                  ANALYSIS DATE                 08/26/94                       08/27/94                     08/26/94                    08/27/94
                                            MATRIX              TISSUE                         TISSUE                       TISSUE                      TISSUE
                                            SUBMAT
                                             WETWT                                             10.03                        10.01                       10.01
                                             DRYWT              10.00                          0.75                         0.77          0.58          0.79
                                           WTUNITS              GRAMS            DRY           GRAMS        DRY             GRAMS         DRY           GRAMS           DRY
      CD
      ND                                 PCTSOLIDS                                             7.4%                         7.7%                        7.9%
                                        Lipid Weight
                                           % LIPIDS                                            17.40                        21.78                       14.38
                         Surrogate Recoveries
                                  Pesticides & PCBs
                                              DBOFB             57.3                           76.9                         72.4                        74.1
                                            PCB#103             65.8                           75.9                         72.3                        74.1
                                            PCB#198             63.1                           82.5                         79.5                        80.6
                                      TOTAL BHCs                0.0              ND            4.7            J             4.0             J                           NA
                           TOT CHLORDANES (S&T)                 0.0              ND            56.9                         53.5                                        NA
                                      TOTAL DDTs                0.3               J            92.6                         87.8                                        NA
                                TOTAL PCBs (S&T)                5.6               J            366.5                        347.2                                       NA
                                        ALPHA-BHC               0.0              ND            1.6                          1.2             J           77.1
                                                 HCB,           0.0              ND            0.0           ND             0.0             J           86.9
                                          BETA-BHC              0.0              ND            1.6                          1.3                         61.0
                                      GAMIVIA-BHC               0.0              ND            1.1            J             1.2             J           82.9





                                   Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)


                                              INVEST#      LAB QA SAMPLE                            BSSI                 LAB QA SAMPLE                  LAB QA SAMPLE
                                                      ID     PROC BLANK                       Breton Sound                        BSSI                          BSSI
                                                   SITE                                        Sable Island                  Sable Island                   Sable Island
                                          LABSAMNO                Q9495                             K8038                       Q9497                           Q9498
                                      SAMPLE TYPE                BLANK                              SAMP                          DUP                             MS
                                                  LJNIT             ng1g                            ng/g                          ng/g                            %
                                                 Analyte            Conc          DB QUAL           Conc       DB QUAL            Conc        DB QUAL        Recovery         DB QUAL

                                          DELTA-BHC                 0.0              ND             0.4             J             0.2              J            75.4
                                        HEPTACHLOR                  0.0              ND             0.6             J             0.4              J            79.0
                                   HEPTA-EPOXI]DE                   0.0              ND             6.0                           5.8                           71.6
                                   OXYCHLORDANE                     0.0              ND             2.1                           2.5                           95.8
                              GAMMA-CHLORDANE                       0.2                             15.2                          14.8                          80.7
                               ALPHA-CHLORDANE                      0.0              ND             31.7                          28.7                          75.3
                               TRANS-NONACHLOR                      0.0              ND             18.7                          18.6                          77.8
                                   CIS-NONACHLOR                    0.0              ND             10.0                          9.3                           75.6
                                              ALDRIN                0.0              ND             2.6                           3.0                           80.1
                                             DIELDRIN               0.0              ND             34.4                          31.9                          64.6
                                              ENDRIN                0.1               J             3.3                           3.2                           94.7
                                                MIREX               0.0              ND             0.0           ND              0.0            ND             92.1
                                   2,4'DDE (0,P'DDE)                0.0              ND             0.0           ND              0.0            ND             61.7
                                   4,4'DDE (P,PDDE)                 0.3                             50.9                          49.3                          63.0
                                   2,4'DDD (0,P'DDD)                0.0              ND             3.7                           3.0                           72.7
                                   4,4'DDD (PP'DDD)                 0.0              ND             27.2                          24.8                          85.0
                                   2,4'DDT (0,P'DDT)                0.0              ND             1.3                           1.2              J            73.0
                                   4,4'DDT (P,P'DDT)                0.0              ND             9.4                           9.5                           87.5
                              PCB    (CLORINATION)
                                                 8(CL2)             0.0              ND             0.9             J             0.7              J            99.2
                                              18 (CL3)              0.0              ND             0.0           ND              0.0            ND             85.5
                                              28 (CL3)              0.0              ND             1.5             J             1.4              J            89.2
                                              44 (CL4)              0.2                             7.5                           6.7                           89.6
                                              52 (CL4)              0.0              ND             10.8                          9.0                           97.3
                                              66 (CL4)              0.0              ND             2.9                           3.7                           73.9
                                             101 (CL5)              0.0              ND             16.1                          17.3                          99.1





                           Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)



                                  INVEST#    LAB QA SAMPLE                 BSSI             LAB QA SAMPLE          LAB QA SAMPLE
                                         ID   PROC BLANK               Breton Sound               BSSI                   BSSI
                                       SITE                             Sable Island           Sable Island           Sable Island
                                LABSAMNO          Q9495                    K8038                 Q9497                   Q9498
                             SAMPLE TYPE         BLANK                     SAMP                   DUP                     MS
                                      UNIT         ng/g                    ng1g                   ng/g                     %
                                     Analyte       Conc       DB QUAL      Conc     DD QUAL       Conc     DB QUAL     Recovery    DB QUAL

                                  105(CL5)         0.0          ND         4.8                    4.2                    97.8
                              I I om (CL5/4)       0.0          ND         36.1                   32.0                                NA
                           118/108/149(CL5/5/6)    0.0          ND         9.9                    8.4                    93.7
                                  128 (CL6)        0.0          ND         5.3                    5.6                    107.4
                                  138(CL6)         0.4                     30.7                   29.3                   84.0
                                  126 (CLS)        0.0          ND         0.0        ND          0.0         ND                     NA
                                  153 (CL6)        0.0          ND         24.4                   22.0                   55.3
                                  170(CL7)         0.7                     2.5         J          2.5          J         102.8
                                  180(CL7)         0.2                     7.3                    7.6                    93.3
                           187/182/159(CL7n/6)     0.0          ND         14.9                   14.7                   89.1
                                  195(CL8)         0.0          ND         0.0        ND          0.0         ND         102.5
                                  206 (CL9)        0.0          ND         0.6         J          0.8          J         93.4
                                 209 (CLIO)        0.0          ND         0.0        ND          0.0         ND         104.2





                                  Mussel Watch Project Year 9                             Pesticides and PCBs QC Data (Tissue)



                                              INVEST#     LAB QA SAMPLE                        FBFO                LAB QA SAMPLE                LAB QA SAMPLE
                                                     ID     PROCBLANK                     Florida Bay                     FBFO                         FBFO
                                                   SITE                                        Flamingo                   Flamingo                     Flamingo
                                          LABSAMNO                Q9500                        K8093                      Q9502                        Q9503
                                      SAMPLE TYPE                 BLANK                        SAMP                       DUP                            MS
                                                  UNIT            ng/g                         ng/g                       ng/g                            %
                                                Analyte           Conc         DB QUAL         Conc      DBQUAL           Conc         DB QUAL         Recovery      DB QUAL

                                     RECEIPT DATE                                              01/27/94                   01/27/94                     01/27/94
                                            QCBATCH               M1412                        M1412                      M1412                        M1412
                                EXTRACTION DATE                   08/01/94                     08/01/94                   08/01/94                     08/01/94
                                             METHOD               GCECD                        GCECD                      GCECD                        GCECD
                                   ANALYSIS DATE                  08/30/94                     08/30/94                   08/30/94                     08/30/94
                                              MATRIX                                           TISSUE                     TISSUE                       TISSUE
                                             SUBMAT
                                               WETWT                                           10.03                      10.01                        10.02
                                               DRYWT              10.00                        1.04                       1.02                         0.99
                                             WTUNITS,             GRAMS           DRY          GRAMS        DRY           GRAMS          DRY           GRAMS            DRY
                                          PCTSOLIDS                                            10.4%                      10.2%                        9.8%
                                         Lipid. Weight
                                            % LIPIDS                                           6.25                       7.74                         8.34
                           Surrogate Recoveries
                                    Pesticides & PCBs
                                               DBOFB              57.9                         71.9                       67.7                         68.7
                                              PCB#103             66.2                         74.4                       71.2                         66.1
                                              PCB#198             58.7                         78.1                       72.9                         75.0
                                        TOTAL BHCs                0.0             ND           4.3                        3.4               J                           NA
                            TOT CHLORDANES (S&T)                  0.0             ND           3.5           J            2.6               J                           NA
                                        TOTAL DDTs                0.0             ND           30.1                       19.4                                          NA
                                 TOTAL PCBs (S&T)                 4.9              J           43.4          J            27.6              J                           NA
                                          ALPHA-BHC               0.0             ND           2.2                        2.0                          83.0
                                                   HCB            0.0             ND           0.0          ND            0.1               J          99.8
                                           BETA-BHC               0.0             ND           0.5           J            0.4               J          70.7
                                        GAMMA-BHC                 0.0             ND           1.3                        0.9               J          92.3





                                   Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)



                                             INVEST#     LAB QA SAMPLE                       FBFO                LAB QA SAMPLE                LAB QA SAMPLE
                                                    ID     PROCBLANK                     Florida Bay                     FBFO                        FBFO
                                                  SITE                                    Flamingo                    Flamingo                     Flamingo
                                         LABSAMNO              Q9500                         K8093                       Q9502                       Q9503
                                     SAMPLE TYPE              BLANK                          SAMP                        DUP                           MS
                                                 'UNIT           ng/g                        ng/g                        ng/g                           %
                                               Analyte           Conc         DB QUAL        Conc       DB QUAL          Conc        DB QUAL       Recovery       DB QUAL

                                         DELTA-BHC               0.0            ND           0.4            J            0.0            ND           81.2
                                       HEPTACHLOR                0.0            ND           0.5            J            0.4             J           82.7
                                   HEPTA-EPOXIDE                 0.0            ND           0.5            J            .0.2            J           77.3
                                   OXYCHLORDANE                  0.0            ND           0.2            J            0.0            ND           97.0
                             GAMMA-CHLORDANE                     0.0            ND           0.3            J            0.0            ND           89.9
                               ALPHA-CHLORDANE                   0.0            ND           2.2                         1.8                         82.7
                               TRANS-NONACHLOR                   0.0            ND           0.3            J            0.2             J           80.4
                                   CIS-NONACHLOR                 0.0            ND           0.3            J            0.2             J           83.8
                                             ALDRIN              0.0            ND           0.0           ND            0.0            ND           82.4
    @O                                     DIELDRIN              0.0            ND           1.0                         1.0             J           76.6
                                             ENDRIN              0.0            ND           0.0           ND            0.0            ND           90.3
                                               MIREX             0.0            ND           0.0           ND            0.0            ND           93.3
                                   2,4'DDE (0,P'DDE)             0.0            ND           22.1                        12.7                        52.9
                                   4,4'DDE (P,P'DDE)             0.0            ND           6.1                         5.0                         84.6
                                   2,4'DDD (0,P'DDD)             0.0            ND           0.0           ND            0.0            ND           100.5
                                   4,4'DDD (P,PDDD)              0.0            NJ)          1.5                         1.4                         101.6
                                   2,4'DDT (0,P'DDI)             0.0            ND           0.0           ND            0.0            ND           85.5
                                   4,4'DDT (PP'DDT)              0.0            ND           0.4            J            0.3             J           92.2
                            PCB # (CLORINATION)
                                              8 (CL2)            0.0            ND           1.1            J            0.6             J           88.7
                                             18 (CL3)            0.0            ND           0.0           ND            0.0            ND           80.7
                                             28 (CL3)            0.0            ND           0.7            J            0.1             J           86.9
                                             44 (CL4)            0.3                         0.7            J            0.4             J           91.3
                                             52 (CL4)            0.0            ND           0.5            J            0.8             J           102.5
                                             66 (CL4)            0.0            ND           3.9                         1.4             J           83.5
                                             101 (CL5)           0.0            ND           0.8            J            0.8             J           94.6





                                  Mussel Watch Project Year 9 - Pesticides and PCBs, QC Data (Tissue)


                                            RqVEST#      LAB QA SAMPLE                        FBFO                LAB QA SAMPLE                LAB QA SAMPLE
                                                     ID    PROCBLANK                      Florida Bay                     FBFO                        FBFO
                                                  SITE                                     Flamingo                    Flamingo                     Flamingo
                                          LABSAMNO              Q9500                         K8093                       Q9502                       Q9503
                                      SAMPLE TYPE              BLANK                          SAMP                        DUP                           MS
                                                 UNIT            ng/g                         ng1g                        ng/g                           %
                                               Analyte           Conc         DB QUAL         Cone      DB QUAL           Conc        DB QUAL       Recovery       DB QUAL

                                            105 (CL5)            0;0             ND           0.0          ND             0.0            ND           93.8
                                       I iom (CL5/4)             0.0             ND           6.6                         3.7                                         NA
                                   118/108/149(CL5/5/6)          0.0             ND           1.0            J            0.1             J           104.7
                                            128 (CL6)            0.0             ND           0.3            J            0.0            ND           106.7
                                            138 (CL6)            0.3                          1.0            J            1.0             J           88.7
                                            126 (CL5)            0.0             ND           0.0          ND             0.0            ND                           NA
                                            153 (CL6)            0.0             ND           0.6            J            0.5             J           80.7
                                            170 (CL7)            0.5                          2.3                         2.0                         106.5
                                            180 (CL7)            0.2              J           0.0          ND             0.1             J           105.4
                                   187/182/159(CL7/7/6)          0.0             ND           0.2            J            0.4             J           102.8
                                            195 (CL8)            0.0             ND           0.0          ND             0.0            ND           106.9
                                            206 (CL9)            0.0             ND           0.0          ND             0.0            ND           87.2
                                           209 (CLIO)            0.0             ND           0.0          ND             0.0            ND           99.6




              mmmm M mm mm Mmm mm m mom m
                                  Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)



                                        INVEST#          NIST SRM 1974a                   LAB QA SAMPLE                 LAB QA SAMPLE                LAB QA SAMPLE
                                                ID   CONSENSUS VALUES                         SRM 1974a                     SRM 1974a                    SRM 1974a
                                             SITE
                                    LABSAMNO                    SRM                               Q9491                         Q9501                        Q9496
                                 SAMPLE TYPE                                                      SRM                           SRM                          SRM
                                            UNIT                ng/g                              ng/g                          ng/g                         ng/g
                                          Analyte               Cone             DB QUAL          Cone        DB QUAL           Cone        DB QUAL          Cone         DB QUAL


                                RECEIPT DATE
                                       QCBATCH                                                    M1410                         M1412                        M1411
                          EXTRACTION DATE                                                         07/21/94                      08/01/94                     07/25/94
                                        METHOD                                                    GCECD                         GCECD                        GCECD
                              ANALYSIS DATE                                                       08/26/94                      08/30/94                     08/26/94
                                         MATRIX                                                   TISSUE                        TISSUE                       TISSUE
                                        SUBMAT
                                         WETWT                                                    5.02                          5.01                         5.00
                                         DRYWT                                                    0.49                          0.59                         0.44
                                       WTUNITS                                                    GRAMS          DRY            GRAMS         DRY            GRAMS           DRY
                                     PCTSOLIDS                                                    9.8%                          11.8%                        8.8%
                                    Lipid Weight
                                       % LIPIDS                                                   3.90                          5.58                         4.10
                      Surrogate Recoveries
                               Pesticides & PCBs
                                          DBOFB                                                   67.7                          58.2                         71.7
                                         PCB#103                                                  70.8                          62.6                         75.4
                                         PCB#198                                                  70.8                          63.5                         76.5
                                   TOTAL BHCs                                                     8.2                           4.6             J            3.4
                       TOT CHLORDANES (S&T)                                                       49.7                          34.0                         46.6
                                   TOTAL DDTs;                                                    136.9                         90.4                         137.8
                            TOTAL PCBs (S&T)                                                      2778.5                        2740.4                       3664.5
                                    ALPHA-BHC                                                     3.1                           3.4                          2.2               J
                                             HCB                                                  0.4             J             0.3             J            0.4               J
                                      BETA-BHC                                                    3.1                           0.0            ND            0.1               J
                                   GAMMA-BHC                    2.7               +/-2.87         1.9             J             1.1             J            1.0               J





                                              Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)



                                                     INVEST#               NIST SRM 1974a                              LAB QA SAMPLE                         LAB QA SAMPLE                         LAB QA SAMPLE
                                                               ID      CONSENSUS VALUES                                     SRM 1974a                             SRM 1974a                             SRM 1974a
                                                           SITE
                                                LABSAMNO                             SRM                                         Q9491                                  Q9501                                 Q9496
                                            SAMPLE TYPE                                                                          SRM                                    SRM                                   SRM
                                                           UNIT                      ng/g                                        ng/g                                   ng/g                                  ng/g
                                                        Analyte                      Conc                  DB QUAL               Conc            DD QUAL                Conc           DB QUAL                Conc             DB QUAL


                                                DELTA-BHC                                                                        0.0                 ND                 0.0                ND                 0.0                  ND
                                             HEPTACHLOR                              4.5                     +/-4.17             13.8                                   0.0                ND                 0.5                    J
                                        HEPTA-EPOXIDE                                                                            0.0                 ND                 0.0                ND                 0.0                  ND
                                        OXYCHLORDANE                                                                             6.6                                    4.9                                   7.0
                                 GAMMA-CHLORDANE                                                                                 16.5                                   12.1                                  18.4
                                   ALPHA-CHLORDANE                                                                               17.5                                   17.8                                  26.3
                                  TRANS-NONACHLOR                                    17.5                    +/-6.20             18.4                                   16.2                                  19.8
                                        CIS-NONACHLOR                                15.6                    +/-2.80             12.6                                   8.7                                   12.2
                                                      ALDRIN                         7.0                     +/-8.24             0.0                 ND                 0.0                ND                 0.5                    J
                                                   DIELDRIN                          6.8                     +/-2.48             8.2                                    7.0                                   11.8
                                                      ENDRIN                                                                     0.0                 ND                 0.0                ND                 2.3
                                                        MIREX                        1.4                     +/-1.01             0.0                 ND                 0.8                  J                0.6                    J
                                        2,4'DDE (0,P'DDE)                                                                        0.0                 ND                 0.0                ND                 2.0                    J
                                        4,4'DDE (P,P'DDE)                            50.5                    +/-13.6             48.6                                   34.2                                  56.4
                                        2,4'DDD (0,PDDD)                             14.4                    +/-3.80             9.3                                    7.3                                   6.9
                                        4,4'DDD (P,P'DDD)                            42.1                    +/-12.8             68.1                                   42.1                                  61.7
                                        2,4'DDT (0,P'DDT)                            6.0                     +/-3.16             8.0                                    4.8                                   6.2
                                        4,4'DDT (P,P'DDT)                            3.1                                         2.9                                    2.0                                   4.7
                                PCB # (CLORINATION)
                                                       8 (CL2)                       5.7                     +/-2.3              7.6                                    6.5                                   4.5                    J
                                                      18 (CL3)                       30.7                    +/-8.1              33.3                                   27.7                                  34.6
                                                      28 (CL3)                       65.8                    +/-24.7             149.8                                  80.3                                  118.3
                                                      44 (CL4)                       61.8                    +/-27.3             90.7                                   74.7                                  103.3
                                                      52 (CL4)                       104.0                   +/-37.              146.4                                  124.3                                 165.7
                                                      66 (CL4)                       103.0                   +/-31.              124.6                                  91.5                                  139.1
                                                    101 (CL5)                        129.0                   +/44                176.4                                  137.5                                 187.7





                                           Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Tissue)


                                                 INVEST#               NIST SRM 1974a                            LAB QA SAMPLE                       LAB QA SAMPLE                        LAB QA SAMPLE
                                                            ID     CONSENSUS VALUES                                  SRM 1974a                            SRM 1974a                           SRM 1974a
                                                        SITE
                                              LABSAMNO                          SRM                                        Q9491                               Q9501                               Q9496
                                         SAWLE TYPE                                                                        SRM                                 SRM                                 SRM
                                                       UNIT                     ng/g                                       ng/g                                ng/g                                ng/g
                                                     Analyte                    Conc                 DB QUAL               Conc          DB QUAL               Conc           DB QUAL              Conc             DB QUAL

                                                 105 (CL5)                      55.6                                       66.2                                45.5                                65.6
                                           110/77 (CL5/4)                                                                  0.0               ND                274.0                               304.3
                                      118/108/149(CL5/5/6)                      133.0                   +/-33              162.4                               123.2                               182.0
                                                 128 (CL6)                      21.7                    +/-6.3             25.6                                19.8                                32.6
                                                 138 (CL6)                      147.0                   +/-36              157.8                               116.5                               200.0
                                                 126 (CL5)                                                                 0.0               ND                0.0                ND               0.0                  ND
                                                 153 (CL6)                      147.0                   +/-38              211.3                               186.6                               226.4
                                                 170 (CL7)                      4.4                     +/-2.3             8.1                                 7.4                                 7.5
                                                 180 (CL7)                      13.2                    +/-3.3             31.9                                25.1                                39.5
                                      187/182/159(CL7/7/6)                      32.2                    +/-8.9             38.1                                31.8                                42.7
         0                                       195 (CL8)                      0.7                     +/-.38             0.0               ND                0.0                ND               0.0                  ND
         0                                       206 (CL9)                      0.5                     +1-.40             0.0               ND                1.3                 J               0.3                   J
                                                209 (CLIO)                      1.1                     +/-1.4             0.0               ND                0.0                ND               0.2                   J




 I
 I
 I
 I
 I
 I
 I
.I          Pesticides and PCBs Data
 I                 (Sediment)
 I
 I
 I
 I
 I
 I
 I
 I
 I
                          101
 I -                        -





                                   Mussel Watch Project Year 9 - Pesticides and PCBs Data (Sediment)

                                  INVEST#:        FBFO,                  FBFO                  FBFO                   FBJB                  FBJB                   FBJB
                                          ID: Florida Bay            Florida Bay           Florida Bay            Florida Bay            Florida Bay           Florida Bay
                                       SITE:      Flamingo               Flamingo              Flamingo               Joe Bay               Joe Bay                Joe Bay
                              LA13SAMMO:          K8098                  K8099                 K8100                  K8113                 K8114                  K8115
                           SAMPLE TYPE:           SAW                    SAMP                  SAMP                   SAMP                  SAMP                   SAMP
                                      UNIT:       ng/g                   ng/g                  ng/g                   ng/g                  ng/g                   ng/g
                                     Analyte      Conc     DB QUAL       ConC     DB QuAL      eonC     DB QUAL       ConC     DB QUAL      ConC      DB QUAL      ConC     DB QUAL

                          RECEIPT DATE:           01/27/94               01/27/94              01/27/94               01/27/94              01/27/94               01/27/94
                                 QCBATCH:         M2106                  M2106                 M2106                  M2106                 M2106                  M2106
                    EXTRACTION DATE:              07/19/94               07/19/94              07119/94               07/19/94              07/19/94               07/19/94
                                  METHOD:         GCECD                  GCECD                 GCECD                  GCECD                 GCECD                  GCECD
                        ANALYSIS DATE:            08/09/94               08/09/94              08/09/94               08/09/94              08/09/94               08/09/94
                                  MATRIX:     SEDIMENTS             SEDIMENTS              SEDIMENTS              SEDIMENTS             SEDIMENTS              SEDIMENTS
                                   WETWT:         30.03                  30.07                 30.22                  30.21                 30.16                  30.19
                                   DRYWT:         8.95                   8.27                  8.05                   8.73                  9.46                   8.87
                                 WTUNITS:         GRAMS       DRY        GRAMS      DRY        GRAMS       DRY        GRAMS       DRY       GRAMS       DRY        GRAMS       DRY
                                % SOLIDS:         29.80                  27.49                 26.65                  28.88                 31.35                  29.37
                    Surrogate Recoveries
                         Pesticides & PCBs
                                    DBOFB:        89.1                   91.2                  79.4                   81.8                  95.1                   92.6
                                   PCB#103:       84.9                   88.6                  79.4                   80.7                  91.9                   93.1
                                   PCB#198:       89.3                   92.9                  79.1                   82.2                  95.4                   93.9
                              TOTAL BHCs          0.03                   0.04                  0.03                   0.05                  0.02                   0.04
                   OT CHLORDANES (S&T)            0.0         ND         0.0         1         0.0         ND         0.0          1        0.0         ND         0.0         ND
                              TOTAL DDTs          1.2                    0.2                   1.7                    0.7                   0.2                    0.0
                       TOTAL PCBs (S&T)           4.6                    11.9                  2.4                    2.3                   2.3                    2.3
                              ALPHA-BHC           0.0                    0.0                   0.0                    0.0                   0.0                    0.0
                                        HCB       0.0                    0.0                   0.0                    0.0                   0.0                    0.0
                                 BETA-BHC         0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                             GAMM[A-BHC           0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                              DELTA-BHC           0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                             HEPTACHLOR           0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                         HEPTA-EPOXIDE            0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                        OXYCHLORDANE              0.0         ND         0.0        ND         0.0         ND         0.0         ND        0.0         ND         0.0         ND
                     AMMA-CHLORDANE               0.0         ND         0.0        ND-        0.0          1         0.0         ND        0.0         ND         0.0         ND
                    ALPHA-CHLORDANE               0.0         ND         0.0         1         0.0         ND         0.0          1        0.0         ND         0.0         ND
                    TRANS-NONACHLOR               0.0         ND         0.0        ND         0.0         ND         0.0          1        0.0         ND         0.0         ND
                         CIS-NONACHLOR            0.0         ND         0.0        ND         0.0         ND         0.0          1        0.0         ND         0.0         ND




                                   M M so MM M M M M M O.M M M M M M
                                   Mussel Watch Project Year 9 - Pesticides and PCBs Data (Sediment)

                                   INVEST#:       FBFO                   FBFO                   FBFO                  FBJB                   FBJB                   FBJB
                                          ID: Florida Bay            Florida Bay            Florida Bay           Florida Bay            Florida Bay            Florida Bay
                                       SITE:   Flamingo               Flamingo               Flamingo                 Joe Bay                Joe Bay                Joe Bay
                               LABSAMNO:          K8098                  K8099                  K8100                 K8113                  K8114                  K8115
                           SAMPLE TYPE:           SAW                    SAW                    SAW                   SAW                    SAW                    SAW
                                      UNIT:       ng/g                   ng/g                   ng/g                  ng/g                   ng/g                   ng/g
                                     Analyte      ConC     DB QUAL       ConC     DB QUAL       ConC    DB QUAL       ConC     DB QUAL       ConC     DB QUAL       ConC    DB QUAL

                                   ALDRIN         0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                 DIELDRIN         0.0           J        0.0         ND         0.0        ND         0.0         ND         U           ND         0.0        ND
                                   ENDRIN         0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                     MIREX        0.0         ND         0.0         ND         0.0        ND         0.0         ND         0@0         ND         0.0        ND
                        2,4'DDE (0,P'DDE)         0.0           1        0.0         ND         0.0         1         0.6                    0.0          1         0.0        ND
                        4,4'DDE (P,P'DDE)         0.7                    0.1          1         0.2                   0.1                    0.0          1         0.0          1
                        2,4'DDD (0,P'DDD)         0.0           1        0.1          1         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                        4,4'DDD (P,P'DDD)         0.4                    0.0         ND         0.1         1         0.0         ND         0.0         ND         0.0        ND
                        2,4'DDT (0,P'DDT)         0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                        4,4'DDT (P,P'DDT)         0.0           1        0.0         ND         1.4                   0.0         ND         0.1          1         0.0        ND
                    CB # (CLORINATION)
       0
                                    8 (CL2)       0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   18 (CL3)       0.0         ND         0.0         ND         0.0        ND         0.0         ND         0,0         ND         0.0        ND
                                   28 (CL3)       0.2           1        0.0         ND         0.0        ND         0.0         ND         6.0         ND         0.0        ND
                                   44 (CL4)       0.1           1        0.0          1         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   52 (CL4)       0.2           1        0.1          1         0.0         1         0.0         ND         0.0          1         0.0        ND
                                   66 (CL4)       0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   10 1 (CL5)     0.1                    0.0          1         0.0         1         0.0         ND         0.0         ND         0.0          1
                                   105 (CL5)      0.0                    0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                             110/77 (CL5/4)       0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                        118/108/149(CL5/5/6)      0.1           1        0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   128 (CL6)      0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   138 (CL6)      0.1           1        0.1          1         0.1         1         0.0          1         0.0          1         0.0          1
                                   126 (CL5)      0.0         ND         0.0         ND         0.0        ND         0.0          1         0.0         ND         0.0          1
                                   153 (CL6)      0.1           1        0.1          1         0.0         1         0.0          1         0.0         ND         0.0        ND
                                   170 (CL7)      0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   180 (CL7)      0.1           1        0.1          1         0.0         1         0.0          1         0.0         ND         0.0          1
                        187/182/159(CL7/7/6)      0.0         ND         0.0         ND         0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   195 (CL8)      0.0         ND         0.5                    0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                   206 (CL9)      0.0           1        3.0                    0.0        ND         0.0         ND         0.0         ND         0.0        ND
                                 209 (CL 10)      0.0         ND         0.4                    0.0        ND         0.0         ND         0.0         ND         0.0        ND




 I
 I
 I
 I
 I
 I
 I
 I       Pesticides and PCBs QC Data
 I               (Sediment)
 I
 I
 I
 I
 I
 I
 I
 I
 1                     104
 1




                         M M mom M-M M M-M MM M
                                Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Sediment)


                                           INVEST#      Lab QA Sample                       FBFO                  Lab QA Sample                  Lab QA Sample
                                                  ID       Proc Blank                   Florida Bay                     FBFO                           FBFO
                                                SITE                                        Flamingo                Florida Bay                    Florida Bay
                                       LABSAMNO               Q9572                         K8100                       Q9574                          Q9575
                                   SAMPLE TYPE                BLANK                         SANT                        MS                             MSD
                                               UNIT           nglg                          nglg                         %                               %
                                             Analyte          Conc          DB QUAL         Conc      DB QUAL           Recovery     DB QUAL           Recovery       DB QUAL


                                   RECEIPT DATE
                                         QCBATCH              M2106                         M2106                       M2106                          M2106
                             EXTRACTION DATE                  07/19/94                      07/19/94                    07/19/94                       07/19/94
                                          METHOD              GCECD                         GCECD                       GCECD                          GCECD
                                ANALYSIS DATE                 08/08/94                      08/09/94                    08/09/94                       08/09/94
                                           MATRIX         SEDIMENTS                     SEDIMENTS                   SEDIMENTS                      SEDIMENTS
                                            WETWT                                           30.22                       30.12                          30.10
                                            DRYWT             10.00                         8.05                        8.03                           8.02
                                          WTUNITS             GRAMS            DRY          GRAMS        DRY            GRAMS           DRY            GRAMS            DRY
                                        % SOLIDS                                            26.7%                       26.7%                          26.7%
                        Surrogate Recoveries
                                 Pesticides & PCBs
                                             DBOFB            83.1                          79.4                        80.5                           84.1
                                           PCB#103            83.1                          79.4                        82.8                           84.5
                                           PCB#198            85.9                          79.1                        81.6                           84.4
                                     TOTAL BHCs               0.00             ND           0.03          J                             NA                              NA
                         TOT CHLORDANES (S&T)                 0.0              ND           0.0          ND                             NA                              NA
                                     TOTAL DDTs               0.0              ND           1.7                                         NA                              NA
                              TOTAL PCBs (S&T)                3.1                J          2.4           J




                                   M M fm so M M M,M M am M @ M- M M M
                                Mussel Watch Project Year 9 - Pesticides and PCBs.QC Data (Sediment)


                                           INVEST#      Lab QA Sample                       FBFO                  Lab QA Sample                  Lab QA Sample
                                                   D)      Proc Blank                   Florida Bay                     FBFO                           FBFO
                                                SITE                                     Flamingo                   Florida Bay                     Florida Bay
                                       LABSAMNO              Q9572                          K8100                       Q9574                          Q9575
                                   SAMTLE TYPE              BLANK                           SAMP                          MS                           MSD
                                               UNIT           ng1g                          ng1g                          %                               %
                                             Analyte          Conc           DB QUAL        Conc      DB QUAL        Recovery        DB QUAL         Recovery         DB QUAL

                                       ALPHA-BHC              0.0               ND          0.0            J            80.6                           79.6
                                                HCB           0.0                J          0.0            J            89.8                           89.9
                                         BETA-BHC             0.0               ND          0.0          ND             70.4                           65.3
                                     GAMMA-BHC                0.0               ND          0.0          ND             90.6                           87.3
                                       DELTA-BHC              0.0               ND          0.0          ND             66.9                           73.9
                                     HEPTACHLOR               0.0               ND          0.0          ND             80.4                           79.7
                                HEPTA-EPOXIDE                 0.0               ND          0.0          ND             83.7                           73.5
                                OXYCBLORE)ANE                 0.0               ND          0.0          ND             104.5                          101.1
                           GAMMA-CHLORDANE                    0.0               ND          0.0            J            89.3                           85.3
                            ALPHA-CHLORDANE                   0.0               ND          0.0          ND             91.4                           88.2
                            TRANS-NONACHLOR                   0.0               ND          0.0          ND             88.8                           86.2
                                CIS-NONACBLOR                 0.0               ND          0.0          ND             90.8                           84.6
                                            ALDRIN            0.0               ND          0.0          ND             87.3                           88.6
                                         DIELDRIN             0.0               ND          0.0          ND             76.2                           71.8
                                            ENDRIN            0.0               ND          0.0          ND             93.7                           82.6
                                             MIREX            0.0               ND          0.0          ND             92.9                           92.7
                                2,4'DDE (0,P'DDE)             0.0               ND          0.0            J            77.1                           77.3
                                4,4'DDE (P,P'DDE)             0.0               ND          0.2                         85.2                           88.8
                                2,4'DDD (0,P'DDD)             0.0               ND          0.0          ND             96.9                           91.6
                                4,4'DDD (P,PDDD)              0.0               ND          0.1            J            97.3                           89.5
                                2,4'DDT (0,P'DDT)             0.0               ND          0.0          ND             88.8                           84.6
                                4,4'DDT (P,P'DDT)             0.0               ND          1.4                         55.3                           49.7




    mmm mm ww"Mmm 0"Man man mmmm
                                Mussel Watch Project Year 9                             Pesticides and PCBs QC Data (Sediment)


                                         INVEST#       Lab QA Sample                      FBFO                  Lab QA Sample                  Lab QA Sample
                                                  ID      Proc Blank                  Florida Bay                     FBFO                           FBFO
                                               SITE                                     Flamingo                  Florida Bay                    Florida Bay
                                      LABSAMNO              Q9572                         K8100                       Q9574                          Q9575
                                  SAMPLE TYPE              BLANK                          SANT                         MS                            MSD
                                              UNIT           ng1g                         ng1g                          %                              %
                                            Analyte          Conc;         DB QUAL        Conc       DBQUAL        Recovery        DB QUAL        Recovery         DB QUAL


                        PCB     (CLORINATION)
                                           8 (CL2)           0.0              ND          0.0           ND            89.2                           88.7
                                          18 (CL3)           0.0              ND          0.0           ND            94.2                           89.6
                                          28 (CL3)           0.0              ND          0.0           ND            97.2                           96.8
                                          44 (CL4)           0.0              ND          0.0           ND            98.3                           95.0
                                          52 (CL4)           0.0              ND          0.0            J            102.6                          101.5
                                          66 (CL4)           0.0              ND          0.0           ND            80.8                           79.8
                                         101 (CL5)           0.0              ND          0.0            J            98.0                           96.3
                                         105 (CL5)           0.0              ND          0.0           ND            102.2                          96.4
                                    I I on7 (CL5/4)          0.0              ND          0.0           ND            112.6                          110.3
                                118/108/149(CL5/5/6)         0.0              ND          0.0           ND            99.1                           98.5
        4                                128 (CL6)           0.0              ND          0.0           ND            107.8                          93.2
                                         138 (CL6)           0.0               J          0.1            J            98.7                           95.7
                                         126 (CL5)           0.0              ND          0.0           ND            106.8                          102.7
                                         153 (CL6)           0.0              ND          0.0            J            71.7                           70.9
                                         170 (CL7)           0.4                          0.0           ND            97.9                           98.3
                                         180 (CL7)           0.0              ND          0.0            J            90.8                           92.2
                                187/182/159(CL7/7/6)         0.0              ND          0.0           ND            82.8                           79.1
                                         195 (CL8)           0.0              ND          0.0           ND            95.9                           96.0
                                         206 (CL9)           0.0              ND          0.0           ND            78.9                           79.6
                                       209 (CLIO)            0.0              ND          0.0           ND            95.4                           95.3
                          Surrogate Recoveries
                                         DBOFB%              83.1                         79.4                        80.5                           84.1
                                        PCB#103%             83.1                         79.4                        82.8                           84.5
                                        PCB#198%             85.9                         79.1                        81.6                           84.4




                           M M am so No M,M M M @ M,M M M M M
                         Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Sediment)


                                                INVEST#             NIST SRM 1941 a           Lab QA Sample
                                                      ID            Certified Values            SRM 1941 a
                                                    SITE
                                             LABSAMNO                    SRM                      Q9573
                                          SAMPLE TYPE                                              SRM
                                                   UNIT                  ng/g                      ng/g
                                                  Analyte               Values        Range        Conc         DB QUAL


                                         RECEIPT DATE
                                               QCBATCH                                            M2106
                                     EXTRACTION DATE                                              07/19/94
                                                METHOD                                            GCECD
                                        ANALYSIS DATE                                             08/08/94
                                                MATRIX                                          SEDIMENTS
                                                 WETWT
                                                 DRYWT                                             1.01
                                               WrUNITS                                            GRAMS           DRY
                                              % SOLIDS
                                 Surrogate Recoveries
     Go                                 Pesticides & PCBs
                                                 DBOFB                                             93.9
                                                PCB#103                                            88.1
                                                PCB#198                                            90.4
                                           TOTAL BHCs                                              0.57
                                  TOT CHLORDANES (S&T)                                             1.9             J
                                           TOTAL DDTs                                              10.7
                                      TOTAL PCBs (S&T)                                            271.0




                                  M M M so M M Im M M, no M Uo M M M M
                                Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Sediment)


                                                             INVEST#                   NIST SRM 1941 a                   Lab QA Sample
                                                                     ID                 Ceitified Values                   SRM 1941 a
                                                                  SITE
                                                         LABSAMNO                             SRM                            Q9573
                                                      SAWLE TYPE                                                               SRM
                                                                 UNIT                         ng/g                             ng/g
                                                                Analyte                      Values           Range            Conc           DB QUAL


                                                         ALPHA-BHC                                                             0.4                 J
                                                                  HCB                         70.0            +/-25            53.7
                                                           BETA-BHC                                                            0.0               ND
                                                        GAMMA-BHC                                                              0.2                 J
                                                         DELTA-BHC                                                             0.0               ND
                                                       HEPTACHLOR                                                              0.0               ND
                                                   HEPTA-EPOXIDE                                                               0.0               ND
                                                   OXYCHLORDANE                            NC 2.6             +/-.19           0.2                 J
                                             GAMMA-CHLORDANE                                                                   1.1
                                               ALPHA-CHLORDANE                                2.3             +/-.56           1.4
                                               TRANS-NONACHLOR                                1.3             +/-.13           0.5                 J
                                                   CIS-NONACHLOR                                                               0.6                 J
                                                              ALDRIN                                                           0.0               ND
                                                            DIELDRIN                       NC 1.3             +/-.37           2.1
                                                              ENDRIN                                                           0.0               ND
                                                               N4IREX                                                          0.0               ND
                                                   2,4'DDE (0,P'DDE)                          0.7             +/-. I 1         0.0               ND
                                                   4,4'DDE (P,P'DDE)                          6.6             +/-.56           5.5
                                                   2,4'DDD (0,P'DDD)                                                           0.6                 J
                                                   4,4'DDD (P,P'DDD)                          5.1             +/-.58           4.1
                                                   2,4'DDT (0,P'DDT)                                                           0.0               ND
                                                   4,4'DDT (P,P'DDI)                       NC 1.3             +/-.10           0.6





                                  Mussel Watch Project Year 9 - Pesticides and PCBs QC Data (Sediment)


                                                               INVEST#                     NIST SRM 1941 a                    Lab QA Sample
                                                                        ID                  Certified Values                     SRM 1941 a
                                                                     SITE
                                                            LABSAMNO                              SRM                               Q9573
                                                        SAMPLE TYPE                                                                  SRM
                                                                     UNIT                         ng/g                               ng/g
                                                                   Analyte                       Values            Range             Conc            DB QUAL


                                             PCB     (CLORINATION)
                                                                  8 (CL2)                       NC 1.4             +/-.19            1.6
                                                                18 (CL3)                        NC 1.2             +/-.16            2.7
                                                                28 (CL3)                        NC 9.8             +/-3.7            7.0
                                                                44 (CL4)                          4.8              +/-.62            4.0
                                                                52 (CL4)                          6.9              +/-.56            11.4
                                                                66 (CU)                           6.8              +/-1.4            6.0
                                                               101 (CL5)                          11.0             +/-1.6            11.6
                                                               105 (CL5)                          3.7              +/-.27            1.5
                                                          110/77 (CL5/4)                          9.5              +/-.85            18.1
                                                     118/108/149(CL5/5/6)                         10.0             +/- 1. 1          5.7
                                                               128 (CL6)                          1.9              +/-.32            0.0                ND
                                                               138 (CL6)                          13.4             +/-.97            10.7
                                                               126 (CL5)                                             +/-             2.6
                                                               153 (CL6)                          17.6             +/-1.9            10.9
                                                               170 (CL7)                          3.0              +/-.46            23.3
                                                               180 (CL7)                          5.8              +/-.58            7.2
                                                     187/182/159(CL7n/6)                        NC 7.0             +/-2.6            3.7
                                                               195 (CL8)                                             +/-             1.3
                                                               206 (CL9)                          3.7              +/-.87            1.4                 J
                                                             209 (CL 10)                          8.3              +/-.49            4.6
                                               Surrogate Recoveries
                                                               DBOFB%                                                                93.9
                                                              PCB#103%                                                               88.1
                                                              PCB#198%                                                               90.4




 I
 I
 I
 I
 I
 I
 I
.I
 I             Trace Metal Results
 I
 I
 I
 I
 I
 I
 I
 I'
 I
                          ill
 I




  I
  I
  I
  I
  I
  I
  I
  I                        Trace Metal Data                             I
  I                                (Tissue)
  I
  I
  I
  I
  I
  I
  I
  I
  1
                                         112
  I                                                                           ..





                                                  Mussel Watch Project Year 9 - Trace Metal (Tissue)


                  SITE      LAB      REP         OTHDG              ADG            HGDG          WET WT.          AD         HGDG          NAAD         MOIST        UNIT UNIT
                            SAMP     NO.         DATE               DATE           DATE              RECD        WT.           WT.          WT.           (%)        TM     QUAL.


               LMSB         K8009       1        12/19/94           12/21/94       1/16/95            57.63        0.1982       0.2113        0.3831        89.17    ppm      Dry
               LMPI         K8017       1        12/19/94           12/21/94       1/16/95            30.31        0.2054       0.2009        0.3985        87.43    ppm      Dry
               LMAC         K8013       1        12/19/94           12/21/94       1/16/95            46.05        0.2110       0.1988        0.4099        83.58    ppm      Dry
               CCNB         K8019       1        12/19/94           12/21/94       1/16/95            42.89        0.2036       0.2128        0.3988        82.79    ppm      Dry
               ABLR         K8033       1        12/20/94           12/21/94       1/16/95           225.77        0.2019       0.2147        0.3979        85.35    ppm      Dry
               MBAR         K8021       1        12/20/94           12/21/94       1/16/95            97.19        0.2177       0.1973        0.4132        86.82    ppm      Dry
               SAPP         K8027       1        12/20/94           12/21/94       1/16/95            93.48        0.2108       0.1931        0.3987        86.82    ppm      Dry
               ESSP         K8031       1        12/20/94           12/21/94       1/16/95            81.45        0.2191       0.2019        0.4058        82.25    ppm      Dry
               ESBD         K8029       1        12/20/94           12/21/94       1/16/95            68.06        0.2082       0.2138        0.4229        89.32    ppm      Dry
               MBGP         K8025       1        12/20/94           12/21/94       1/16/95            86.94        0.2182       0.1979        0.4182        84.33    ppm      Dry
               MBCB         K8023       1        12/20/94           12/21/94       1/16/95           181.88        0.2103       0.1994        0.4143        90.15    ppm      Dry
               BRCL         K8005       1        12/19/94           12/21/94       1/16/95            28.46        0.2155       0.1937        0.3804        86.93    ppm      Dry
               GBTD         K8001       1        12/19/94           12/21/94       1/16/95           245.33        0.2179       0.1925        0.4229        83.54    ppm      Dry
               GBOB         K8007       1        12/19/94           12/21/94       1/16/95            79.51        0.2183       0.2024        0.3835        80.53    ppm      Dry
               GBSC         K8003       1        12/19/94           12/21/94       1/16/95               6.32      0.1979       0.2052        0.3948        79.91    ppm      Dry
               SLBB         K8011       1        12/19/94           12/21/94       1/16/95            48.30        0.2075       0.2067        0,4155        85.76    ppm      Dry
               CLLC         K8015       1        12/19/94           12/21/94       1/16/95            39.04        0.2048       0.1993        0.3936        82.63    ppm      Dry
               VBSP         K8041       1        12/20/94           12/21/94       1/16/95            37.89        0.2169       0.2076        0.3625        83.16    ppm      Dry
               CLCL         K8035       1        12/20/94           12/21/94       1/16/95            56.72        0.2109       0.1942        0.4125        83.59    ppm      Dry
               TBLF         K8037       1        12/19/94           12/21/94       1/16/95            45.50        0.2165       0.1954        0.4050        82.26    ppm      Dry
               MERPL        K8043       1        12/20/94           12/21/94       1116195            77.43        0.2083       0.2034        0.3988        90.82    ppm      Dry
               BSSI         K8039       1        12/20/94           12/21/94       1/16/95           168.42        0.2092       0.1959        0.4282        89.92    ppm      Dry
               LBMP         K8045       1        12/20/94           1/12/95        1/16/95            91.20        0.2054       0.1961        0.3962        88.82    ppm      Dry
               LBNO         K8047       1        12/20/94           12/21/94       1/16/95           135.20        0.2162       0.1996        0.4169        88.80    ppm      Dry
               MSPC         K8053       1        12/20/94           12/21/94       1/16/95            66.12        0.2066       0.2057        0,4042        86.36    ppm      Dry
               MSPB         K8055       1        12/20/94           12/21/94       1/16/95            70.31        0.2027       0.1925        0.4070        88.14    ppm      Dry
               MBCP         K8049       1        12/20/94           12/21/94       1/16/95           120.30        0.2089       0.2144        0.4068        81.75    ppm      Dry
               MBHI         K8051       1        12/20/94           12/21/94       1/16/95            65.93        0.2105       0.1939        0.4063        84.70    ppm      Dry
               PBPH         K8059       1        12/20/94           1/5/95         1/16/95            43.75        0.1988       0.2050        0.4125        82.90    ppm      Dry
               PBIB         K8057       1        12/20/94           12/21/94       1/16/95            47.55        0.2090       0.1999        0.4149        89.86    ppm      Dry
               CBJB         K8067       1        12/20/94           12/21/94       1/16/95            25.56        0.2235       0.2088        0.3975        87.56    ppm      Dry
               CBBL         K8065       1        12/20/94           12/21/94       1/16/95            21.31        0.2074       0.1928        0.3924        90.47    ppm      Dry
               CBPP         K8061       1        12/20/94           12/21/94       1/16/95            29.46        0.2112       0.2089        0.3918        85.98    ppm      Dry





                                                   Mussel Watch Project Year 9 - Trace Metal (Tissue)



                  SITE      LAB       REP       OTHDG               ADG             HGDG          WET WT.         AD         HGDG          NAAD         MOIST       UNIT     UNIT
                           SANT       NO.        DATE               DATE            DATE             RECD        WT.           WT.          WT.           N          TM     QUAL.


                CBBB       K8063        1       12/20/94            12/21/94        1/16/95            46.73       0.2111       0.2125        0.3741        87.85    ppm      Dry
                PCLO       K8069        1       12/20/94            12/21/94        1/16/95            29.12       0.2157       0.1957        0.3885        89.18    ppm      Dry
                AESP       K8071        1       12/20/94            12/21/94        1/16/95            34.44       0.2041       0.2096        0.4192        90.39    ppm      Dry
                CKBP       K8073        1       12/20/94            1/5/95          1/16/95            39.12       0.1937       0.2015        0.4056        87.27    ppm      Dry
                TBOT       K8081        1       12/20/94            1/5/95          1/16/95            51.86       1.0000       0.1983        0.4025        91.96    ppm      Dry
                TBPB       K8079        1       12/20/94            12/21/94        1/16/95            35.29       0.2184       0.2058        0.3897        84.70    ppm      Dry
                TBBB       K8085        1       12/20/94            1/12/95         1/16/95          111.60        0.2159       0.2066        0.4176        85.56    ppm      Dry
                TBMK       K8089        1       12/20/94            115195          1/16/95          104.08        0.2075       0.2028        0.3902        87.32    ppm      Dry
                TBKA       K8075        1       12/20/94            12/21/94        1/16/95            86.84       0.2065       0.2068        0.4146        84.77    ppm      Dry
                TBNP       K8083        1       .12/20/94           115195          1/16/95            36.83       0.2107       0.2093        0.4156        83.52    ppm      Dry
                CBBI       K8087        1       12/20/94            115195          1/16/95            61.55       0.1941       0.2015        0.4242        86.21    ppm      Dry
                RBHC       K8091        1       12/20/94            1/5/95          1/16/95            76.57       0.2089       0.2102        0.4185        89.07    ppm      Dry
                FBFO       K8095        1       12/20/94            1/5/95          1/16/95            79.48       0.2090       0.2092        0.4010        84.66    ppm      Dry
                FBFO       K8096        2       12/20/94            1/26/95         1/16/95          100.67        0.2026       0.2129        0.4189        87.13    ppm      Dry
                FBFO       K8097        3       12/20/94            1/5/95          1/16/95          121.44        0.2114       0.2047        0.4005        89.90    ppm      Dry
                FBJB       K81 10       1       12/20/94            1/12/95         1/16/95            20.51       0.2096       0.2088        0.3932        91.27    ppm      Dry
                FBJB       K8111        2       12/20/94            1/12/95         1/16/95            23.83       0.1998       0.1983        0.4183        90.47    ppm      Dry
                FBJB       K8112        3       12/20/94            1/5/95          1/16/95            13.16       0.2035       0.2082        0.3971        90.50    ppm      Dry
                BHKF       K8077        1       12/20/94            12/21/94        1116195            60.30       0.2030       0.2029        0.4018        82.89    ppm      Dry
                PRBB       K8127        1       12/20/94            1/5/95          1/16/95            34.71       0.2064       0.2050        0.4135        87.93    ppm      Dry
                PRBM       K8125        1       12/20/94            1/5/95          1/16/95            22.59       0.2028       0.2048        0.3907        88.31    ppm      Dry
                PRBJ       K8123        1       12/20/94            1/5/95          1/16/95            26.14       0.2050       0.1927        0.3882        87.45    ppm      Dry





                                                        Mussel Watch Project Year 9 - Trace Metal (Tissue)


                   SITE      LAB        REP          Ag          Al      As          Cd         Cr          CU         Fe          Hg       Mn          Ni        Pb         Se         Sn       z
                             SANT       NO.


                LMSB         K8009         1       1.02        693       9.9       1.81       0.54        50.0       470       0.124        15.1      0.81      0.67      2.53       0.00      1023
                LMPI         K8017         1       1.28        648      12.1       1.48       0.88       141.6       632       0.059        23.8      0.96      0.96      3.24       0.30      4237
                LMAC         K8013         1       0.55        652      19.7       1.49       0.59        29.2       391       0.128        19.2      0.75      0.57      3.16       0.00       422
                CCNB         K8019         1       1.28        223       7.0       5.68       0.00        78.5       183       0.108        9.3       0.71      1.05      3.86       0.00      2997
                ABLR         K8033         1       1.71        903       4.9       4.25       0.00        82.4       246       0.067        13.4      1.90      0.70      2.82       0.00       931
                MBAR         K8021         1       3.58        450       4.5       5.81       0.00       137.8       271       0.073        11.1      1.97      0.73      3.46       0.00      1232
                SAPP         K8027         1       3.04       1197       4.2       6.35       0.85       114.1       463       0.058        21.8      2.51      0.83      2.97       0.00       804
                ESSP         K8031         1       2.91        251       7.3       3.58       0.50        81.0       222       0.059        12.3      1.59      0.51      3.82       0.00       711
                ESBD         K8029         1       1.32        151       9.3       3.13       0.79        79.9       214       0.138        9.1       2.26      0.42      2.29       0.00       930
                MBGP         K8025         1       3.16       1541       7.1       3.85       1.38       112.7       667       0.092        17.3      1.93      1.01      3.77       0.00      2028
                MBCB         K8023         1       5.84        352       6.9       5.23       2.15       184.0       378       0.132        11.5      2.31      0,50      3.41       0.00      2230
                BRCL         K8005         1       1.60       1401       6.3       2.65       2.56        94.1      1310       0.107        27.5      1.94      0.98      3.09       0.00      1733
                GBTD         K8001         1       1.29        114       6.7       3.06       0.00        84.7       155       0.041        8.7       1.72      0.38      2.78       0.34      1736
                GBOB         K8007         1       0.90          64      7.2       1.89       0.00        98.4       141       0.035        17.3      0.93      0.88      2.20       0.00      4679
                GBSC         K8003         1       1.75        627       6.3       4.29       2.36       130.6       512       0.054        69.6      1.95      1.40      5.39       0.89      3946
                SLBB         K8011         1       4.03       1131      10.3       5.48       2.52       201.6      1175       0.089        45.3      2.00      0.88      3.75       0.20      3713
                CLLC         K8015         1       1.46        538       6.8       2.66       1.25        90.4       411       0.104        21.1      1.90      0.80      3.81       0.32      2963
                VBSP         K8041         1       3.58        150       7.3       6.81       0.00       243.8       250       0.034        9.8       1.44      0.50      3.86       0.15      1858
                CLCL         K8035         1       1.10        855       7.5       4.43       1.61       116.2       470       0.053        16.6      1.95      0.69      2.02       0.16      1587
                TBLF         K8037         1       0.32        306       8.8       1.65       0.34        72.2       296       0.037        10.0      1.64      0.60      2.40       0.00      1213
                MRPL         K8043         1       7.68        609       5.5       17.72      1.08       398.1       542       0.098        36.5      3.00      0.68      4.92       0.29      6204
                BSSI         K8039         1       3.84        178       6.3       14.39      0.00       279.0       208       0.057        11.6      2.31      0.49      4.00       0.00      4170
                LBMP         K8045         1       1.87        129       4.9       9.30       1.16       189.0       199       0.130        15.5      2.38      0.46      3.61       0.00      3650
                LBNO         K8047         1       1.31        204       4.2       5.75       0.00       147.9       239       0.104        8.7       2.17      0.50      2.92       0.00      3390
                MSPC         K8053         1       4.22        236       8.4       9.09       0.00       131.6       344       0.135        24.9      1.40      0.87      3.54       0.00      5620
                MSPB         K8055         1       2.95       1089      19.4       3.01       2.99       176.3       774       0.149        28.4      1.59      1.06      3.39       0.22      4949
                MBCP         K8049         1       1.15        315      10.1       2.30       0.00        35.2       169       0.059        16.7      1.26      0.30      2.40       0.00       463
                MBHI         K8051         1       4.47       1317       7.1       5.90       1.61       263.5       644       0.074        33.4      2.61      0.84      2.08       0.00      6961
                PBPH         K8059         1       1.87          91     11.9       3.21       0.00        36.9       254       0.093        10.8      0.76      0.46      3.44       0.18      1668
                PBIB         K8057         1       3.41       1313       9.0       4.11       1.41        58.7       935       0.175        25.7      1.50      0.74      3.27       0.15      1322
                CBJB         K8067         1       0.61        705      16.0       2.17       0.95       226.5      1068       0.187        12.1      1.18      1.41      4.31       0.20      3375
                CBBL         K8065         1       3.73        451      11.7       1.97       0.71       207.5       545       0.165        14.3      1.15      1.79      5.63       0.26      2890
                CBPP         K8061         1       3.06        276      13.3       1.89       0.00        34.1       365       0.152        12.5      0.81      5.03      4.97       0.00      1755





                                                      Mussel Watch Project Year 9 - Trace Metal (Tissue)


                  SITE       LAB       REP          Ag        Al       As          Cd        Cr          CU        Fe          Hg       Mn          Ni       Pb         Se        Sn        Zn
                            SAMP       NO.


               CBBB         K8063         1      16.65       933      11.1      2.82       1.14      145.0       596       0.206        14.0     1.24      4.27      5.55      0.24      3194
               PCLO         K8069         1       0.57       624      11.1      1.47       0.87        28.4      637       0.366        12.5     1.46      1.20      3.29      0.00      2587
               AESP         K8071         1       0.86       490      19.0      3.12       0.91        24.0      396       0.228        15.8     0.97      0.63      3.80      0.00        665
               CKBP         K8073         1       0.51       318      16.4      2.67       1.05        18.9      359       0.193        20.7     0.94      0.62      2.92      0.00        619
               TBOT         K8081         1       2.68       167       4.1      3.98       0.00      106.7       559       0.329        11.7     1.77      0.91      3.24      0.00      7590
               TBPB         K8079         1       1.70       180       7.7      2.14       0.67        71.3      269       0.282        0.0      1.15      1.26      2.65      0.00      2047
               TBHB         K8085         1       1.39        86       5.5      2.06       0.74        55.2      138       0.151        10.8     0.74      0.90      2.19      0.27      2324
               TBMK         K8089         1       0.47       138      12.4      1.58       0.00        14.7      141       0.163        5.2      0.85      0.41      1.54      0.00        306
               TBKA         K8075         1       3.54        81       8.5      1.36       0.55        76.6      177       0.127        11.6     0.84      1.33      2.75      0.33      4328
               T'BNP        K8083         1       1.57        58      42.6      0.83       0.00        54.6      126       0.121        6.3      0.91      0.70      2.18      0.00      2545
               CBBI         K8087         1       2.73       188      12.1      2.15       0.62      110.1       222       0.184        6.9      0.81      0.42      2.25      0.00      2916
               RBHC         K8091         1       1.94       173      11.9      1.49       0.75        65.5      231       0.195        5.7      0.74      0.34      2.35      0.00        967
               FBFO         K8095         1       1.33        65      15.7      1.05       0.90      521.5       155       0.098        5.4      0.45      0.44      1.76      0.60      4394
               FBFO         K8096         2       0.85        53      14.7      0.00       0.00          0.0     127       0.206        4.1      0.60      0.34      1.47      0.00        638
               FBFO         K8097         3       1.27        59      13.4      2.47       0.00        77.5      148       0.252        4.7      0.59      0.26      1.39      0.00      1134
               FBJB         K81 10        1       1.17       325       7.7      1.59       1.28        49.7      442       0.271        10.9     1.07      0.30      4.92      0.00        963
               FBJB         K8111         2       0.94       469       5.8      1.38       0.96        51.6      305       0.280        13.3     1.23      0.38      4.10      0.00        705
               FBJB         K8112         3       1.07       424       7.6      1.70       1.43        46.7      374       0.318        13.6     1.06      0.34      4.58      0.00        920
               BHKF         K8077         1       0.00        39      74.2      2.88       0.91          6.1     107       0.098        5.3      2.95      0.29      2.05      0.00        124
               PRBB         K8127         1       0.20       620       9.1      0.44       1.02        53.3      444       0.081        27.3     1.83      0.25      2.31      1.25        907
               PRBM         K8125         1       1.37       227      13.4      0.53       0.62      189.3       238       0.100        10.5     0.87      0.23      4.02      0.00      2334
               PRBJ         K8123         1       0.56       448      12.3      0.95       0.00      120.5       334       0.096        18.5     0.73      0.28      3.43      0.00        689




 I
 I
 I
 I
 I
 I
 I
II           Trace Metal QC Data
 I                 (Tissue)
 I
 I
 I
 I
 I
 I
 I
 I
 1

                       117
 1





                                              Mussel Watch Project Year 9 - Trace Metal QC Data (Tissue)


                    SITE       LAB            ADG           HGDG           OTHDG          SAMP      WET WT ADWT HGDWT NAADWT MOIST                            UNIT    UNIT
                              SAMP            DATE          DATE           DATE           TYPE       RECD                                            N        TM      QUAL


                             DLDRY                                                      DLDRY                                                                 PPM     DRY
                 LMSB          8009           12/21/94      1/16/95        12/19/94       SAMP           57.63  0.1982     0.2113      0.3831      89.17      PPM     DRY
                 LMIPI         8017           12/21/94      1116195        12/19/94       SAMP           30.31  0.2054     0.2009      0.3985      87.43      PPM     DRY
                 LMAC          8013           12/21/94      1/16/95        12/19/94       SANT           46.05  0.2110     0.1988      0.4099      83.58      PPM     DRY
                 CCNB          8019           12/21/94      1/16/95        12/19/94       SANT           42.89  0.2036     0.2128      0.3988      82.79      PPM     DRY
                 ABLR          8033           12/21/94      1/16/95        12/20/94       SANT     -    225.77  0.2019     0.2147      0.3979      85.35      PPM     DRY
                 MBAR          8021           12/21/94      1/16/95        12/20/94       SANT           97.19  0.2177     0.1973      0.4132      86.82      PPM     DRY
                 SAPP          8027           12/21/94      1/16/95        12/20/94       SAMP           93.48  0.2108     0.1931      0.3987      86.82      PPM     DRY
                 SAPP        8027DUP          12/21/94      1/16/95        12/20/94       LDUP                  0.2136     0.2000      0.4202                 PPM     DRY
                 ESSP          8031           12/21/94      1116195        12/20/94       SAMP           81.45  0.2191     0.2019      0.4058      82.25      PPM     DRY
                 ESBD          8029           12/21/94      1116195        12/20/94       SAMP           68.06  0.2082     0.2138      0.4229      89.32      PPM     DRY
                 MBGP          8025           12/21/94      1/16/95        12/20/94       SAMP           86.94  0.2182     0.1979      0.4182      84.33      PPM     DRY
                 MBCB          8023           12/21/94      1/16/95        12/20/94       SANT          181.88  0.2103     0.1994      0.4143      90.15      PPM     DRY
                 BRCL          8005           12/21/94      1/16/95        12/19/94       SAMP           28.46  0.2155     0.1937      0.3804      86.93      PPM     DRY
                 GBTD          8001           12/21/94      1/16/95        12/19/94       SAMP          245.33  0.2179     0.1925      0.4229      83.54      PPM     DRY
     00          GBTD        8001DUP          12/21/94      1/16/95        12/19/94       LDUP                  0.1992     0.1948      0.3859                 PPM     DRY
                 GBOB          8007           12/21/94      1/16/95        12/19/94       SAMP           79.51  0.2183     0.2024      0.3835      80.53      PPM     DRY
                 GBSC          8003           12/21/94      1/16/95        12/19/94       SAMP             6.32 0.1979     0.2052      0.3048      79.91      PPM     DRY
                 SLBB          8011           12/21/94      1/16/95        12/19/94       SAMP           48.30  0.2075     0.2067      0.4155      85.76      PPM     DRY
                 SLBB        8011SPK          12/21/94      1/16/95        12/19/94        MS                   0.2155     0.2140      0.4310                 PPM     DRY
                 SLBB         SPIKE                                                       SPIKE                                                               PPM     DRY
                 CLLC          8015           12/21/94      1/16/95        12/19/94       SAMP           39.04  0.2048     0.1993      0.3936      82.63      PPM     DRY
                 VBSP          8041           12/21/94      1/16/95        12/20/94       SANT           37.89  0.2169     0.2076      0.3625      83.16      PPM     DRY
                 CLCL          8035           12/21/94      1/16/95        12/20/94       SAMP           56.72  0.2109     0.1942      0.4125      83.59      PPM     DRY
                 TBLF          8037           12/21/94      1/16/95        12/19/94       SAMP           45.50  0.2165     0.1954      0.4050      82.26      PPM     DRY
                 TBLF        8037SPK          12/21/94      1/16/95        12/19/94        ms                   0.2112     0.2093      0.4080                 PPM     DRY
                 TBLF         SPIKE                                                       SPIKE                                                               PPM     DRY
                 NfRPL         8043           12/21/94      1116195        12/20/94       SAMP           77.43  0.2083     0.2034      0.3988      90.82      PPM     DRY
                 BSSI          8039           12/21/94      1/16/95        12/20/94       SAMP          168.42  0.2092     0.1959      0.4282      89.92      PPM     DRY
                 LBMP          8045           1/12/95       1/16/95        12/20/94       SANT           91.20  0.2054     0.1961      0.3962      88.82      PPM     DRY
                 LBNO          8047           12/21/94      1/16/95        12/20/94       SANT          135.20  0.2162     0.1996      0.4169      88.80      PPM     DRY
                 LBNO        8047DUP          12/21/94      1/16/95        12/20/94       LDUP                  0.2160     0.1999      0.4268                 PPM     DRY
                 MSPC          8053           12/21/94      1/16/95        12/20/94       SAMP           66.12  0.2066     0.2057      0.4042      86.36      PPM     DRY
                 MSPB          8055           12/21/94      1/16/95        12/20/94       SAM?           70.31  0.2027     0.1925      0.4070      88.14      PPM     DRY




                                                m mm,mmm mmm = m = m m m
                                                Mussel Watch Project Year 9 - Trace Metal QC Data (Tissue)


                     SITE        LAB            ADG             HGDG            OTHDG          SANT       WET WT ADWT HGDWT NAADWT MOIST                               UNIT     UNIT
                                SAMP            DATE            DATE            DATE           TYPE        RECD                                                        TM       QUAL


                  MSPB        8055SPK           12/21/94        1/16/95         12/20/94        MS                     0.2017      0.1914      0.4357                  PPM      DRY
                  MSPB         SPIKE                                                           SPIKE                                                                   PPM      DRY
                  MBCP           8049           12/21/94        1116195         12/20/94       SANT           120.30   0.2089      0.2144      0.4068       81.75      PPM      DRY
                  MBHI           8051           12/21/94        1/16/95         12/20/94       SAMP            65.93   0.2105      0.1939      0.4063       84.70      PPM      DRY
                  PBPH           8059           115195          1/16/95         12/20/94       SAMP            43.75   0.1988      0.2050      0.4125       82.90      PPM      DRY
                  PBIB           8057           12/21/94        1/16/95         12/20/94       SANT            47.55   0.2090      0.1999      0.4149       89.86      PPM      DRY
                  CBJB           8067           12/21/94        1/16/95         12/20/94       SANT            25.56   0.2235      0.2088      0.3975       87.56      PPM      DRY
                  CBBL           8065           12/21/94        1/16/95         12/20/94       SANT            21.31   0.2074      0.1928      0.3924       90.47      PPM      DRY
                  CBBL        8065DUP           12/21/94        1/16/95         12/20/94       LDUP                    0.1999      0.1981      0.3995                  PPM      DRY
                  CBPP           8061           12/21/94        1116195         12/20/94       SAMP            29.46   0.2112      0.2089      0.3918       85.98      PPM      DRY
                  CBBB           8063           12/21/94        1/16/95         12/20/94       SANT            46.73   0.2111      0.2125      0.3741       87.85      PPM      DRY
                  PCLO           8069           12/21/94        1/16/95         12/20/94       SANT            29.12   0.2157      0.1957      0.3885       89.18      PPM      DRY
                  AESP           8071           12/21/94        1/16/95         12/20/94       SAMP            34.44   0.2041      0.2096      0.4192       90.39      PPM      DRY
                  BBPR           8127           1/5/95          1/16/95         12/20/94       SAMP            34.71   0.2064      0.2050      0.4135       87.93      PPM      DRY
                  CKBP           8073           1/5/95          1/16/95         12/20/94       SAMP            39.12   0.1937      0.2015      0.4056       87.27      PPM      DRY
                  TBOT           8081           115195          1/16/95         12/20/94       SAMP            5L86    1.0000      0.1983      0.4025       91.96      PPM      DRY
                  TBPB           8079           12/21/94        1116195         12/20/94       SAMP            35.29   0.2184      0.2058      0.3897       84.70      PPM      DRY
                  TBPB        8079SPK           12/21/94        1/16/95         12/20/94        MS                     0.2075      0.2124      0.4214                  PPM      DRY
                  TBPB          SPIKE                                                          SPIKE                                                                   PPM      DRY
                  T`BHB          8085           1/12/95         1/16/95         12/20/94       SANT           111.60   0.2159      0.2066      0.4176       85.56      PPM      DRY
                  T`BMK          8089           1/5/95          1/16/95         12/20/94       SAMP           104.08   0.2075      0.2028      0.3902       87.32      PPM      DRY
                  TBKA           8075           12/21/94        1/16/95         12/20/94       SAMP            86.84   0.2065      0.2068      0.4146       84.77      PPM      DRY
                  TBNP           8083           1/5/95          1/16/95         12/20/94       SANT            36.83   0.2107      0.2093      0.4156       83.52      PPM      DRY
                  CBBI           8087           1/5/95          1/16/95         12/20/94       SANT            61.55   0.1941      0.2015      0.4242       86.21      PPM      DRY
                  RBHC           8091           1/5/95          1/16/95         12/20/94       SAMP            76.57   0.2089      0.2102      0.4185       89.07      PPM      DRY
                  FBFO 1         8095           1/5/95          1/16/95         12/20/94       SANT            79.48   0.2090      0.2092      0.4010       84.66      PPM      DRY
                  FBFO 2         8096           1/26/95         1/16/95         12/20/94       SAMP           100.67   0.2026      0.2129      0.4189       87.13      PPM      DRY
                  FBFO 3         8097           115195          1116195         12/20/94       SAMP           121.44   0.2114      0.2047      0.4005       89.90      PPM      DRY
                  FBJB 1         8110           1/12/95         1/16/95         12/20/94       SAMP            20.51   0.2096      0.2088      0.3932       91.27      PPM      DRY
                  FBLB 2         8111           1/12/95         1/16/95         12/20/94       SAMP            23.83   0.1998      0.1983      0.4183       90.47      PPM      DRY
                  FBJB 3         8112           1/5/95          1/16/95         12/20/94       SAMP            13.16   0.2035      0.2082      0.3971       90.50      PPM      DRY
                  BHKF           8077           12/21/94        1/16/95         12/20/94       SAMP            60.30   0.2030      0.2029      0.4018       82.89      PPM      DRY
                  BJPR.          8123           1/5/95          1/16/95         12/20/94       SAMP            26,14   0.2050      0.1927      0.3882       87.45      PPM      DRY
                  BMPR           8125           1/5/95          1/16/95         12/20/94       SANT            22.59   0.2028      0.2048      0.3907       88.31      PPM      DRY





                                                  Mussel Watch Project Year 9 - Trace Metal QC Data (Tissue)


               SITE        LAB            Ag         Al          As        Cd           Cr         CU         Fe        Hg           Mn          Ni         Pb          Se        Sn           Zn
                          SAMP


                         DLDRY              0.10       121         0.41      0.003       0.50       0.16        493      0.012          3.8       0.15        0.11        0.60      0.14         2.3
            LMSB           8009             1.02       693         9.9       1.81        0.54       50.0        470      0.124        15.1        0.81        0.67        2.53      0.00       1023
            LMPI           8017             1.28       648         12.1      1.48        0.88      141.6        632      0.059        23.8        0.96        0.96        3.24      0.30       4237
            LMAC           8013             0.55       652         19.7      1.49        0.59       29.2        391      0.128        19.2        0.75        0.57        3.16      0.00         422
            CCNB           8019             1.28       223         7.0       5.68        0.00       78.5        183      0.108          9.3       0.71        1.05        3.86      0.00       2997
            ABLR           8033             1.71       903         4.9       4.25        0.00       82.4        246      0.067        13.4        1.90        0.70        2.82      0.00         931
            MBAR           8021             3.58       450         4.5       5.81        0.00      137.8        271      0.073        11.1        1.97        0.73        3.46      0.00       1232
            SAPP           8027             3.04      1197         4.2       6.35        0.85      114.1        463      0.058        21.8        2.51        0.83        2.97      0.00         804
            SAPP         8027DUP            3.36      1289         5.1       6.33        1.25      114.9        609      0.064        25.2        2.51        0.83        3.54      0.00         845
            ESSP           8031             2.91       251         7.3       3.58        0.50       81.0        222      0.059        12.3        1.59        0.51        3.82      0.00         711
            ESBD           8029             1.32       151         9.3       3.13        0.79       79.9        214      0.138          9.1       2.26        0.42        2.29      0.00         930
            MBGP           8025             3.16      1541         7.1       3.85        1.38      112.7        667      0.092        17.3        1.93        1.01        3.77      0.00       2028
            MBCB           8023             5.84       352         6.9       5.23        2.15      184.0        378      0.132        11.5        2.31        0.50        3.41      0.00       2230
            BRCL           8005             1.60      1401         6.3       2.65        2.56       94.1       1310      0.107        27.5        1.94        0.98        3.09      0.00       1733
            GBTD           8001             1.29       114         6.7       3.06        0.00       84.7        155      0.041          8.7       1.72        0.38        2.78      0.34       1736
       b)
            GBTD         8001DUP            1.37        99         7.1       2.89        0.00       83.1        154      0.037          8.1       1.94        0.41        2.72      0.31       1720
            GBOB           8007             0.90        64         7.2       1.89        0.00       98.4        141      0.035        17.3        0.93        0.88        2.20      0.00       4679
            GBSC           8003             1.75       627         6.3       4.29        2.36      130.6        512      0.054        69.6        1.95        1.40        5.39      0.89       3946
            SLBB           8011             4.03      1131         10.3      5.48        2.52      201.6       1175      0.089        45.3        2.00        0.88        3.75      0.20       3713
            SLBB         8011 SPK         13.87       1206         18.5      7.88       11.16      223.6       2184      0.558        86.8       18.39        5.00        17.0      3.84       3914
            SLBB          SPIKE           11.60         93         9.3       2.32        9.28       18.6       1160      0.467        46.4        18.6        4.6         15.5        4.6      185.6
            CLLC           8015             1.46       538         6.8       2.66        1.25       90.4        411      0.104        21.1        1.90        0.80        3.81      0.32       2963
            VBSP           8041             3.58       150         7.3       6.81        0.00      243.8        250      0.034          9.8       1.44        0.50        3.86      0.15       1858
            CLCL           8035             1.10       855         7.5       4.43        1.61      116.2        470      0.053        16.6        1.95        0.69        2.02      0.16       1587
            TBLF           8037             0.32       306         8.8       1.65        0.34       72.2        296      0.037        10.0        1.64        0.60        2.4       0.00       1213
            TBLF         8037SPK          13.41        383         19.0      3.81        7.65       88.7       1283      0.456        49.5       18.06        4.69        16.7      4.14       1567
            TBLF          SPIKE           12.25         95         9.8       2.37        9.80       18.9       1225      0.478        47.3        18.9        4.7         16.3        4.7      473.5
            MRPL           8043             7.68       609         5.5       17.72       1.08      398.1        542      0.098        36.5        3.00        0.68        4.92      0.29       6204
            BSSI           8039             3.84       178         6.3       14.39       0.00      279.0        208      0.057        11.6        2.31        0.49        4.0       0.00       4170
            LBMP           8045             1.87       129         4.9       9.30        1.16      189.0        199      0.130        15.5        2.38        0.46        3.61      0.00       3650
            LBNO           8047             1.31       204         4.2       5.75        0.00      147.9        239      0.104          8.7       2.17        0.50        2.92      0.00       3390
            LBNO         8047DUP            1.27       222         4.8       5.53        0.00      150.7        277      0.088          8.7       2.09        0.47        3.15      0.00       3496
            MSPC           8053             4.22       236         8.4       9.09        0.00      131.6        344      0.135        24.9        1.40        0.87        3.54      0.00       5620
            MSPB           8055             2.95      1089         19.4      3.01        2.99      176.3        774      0.149        28.4        1.59        1.06        3.39      0.22       4949





                                                   Mussel Watch Project Year 9 - Trace Metal QC Data (Tissue)


               SITE         LAB           Ag          Al          As         Cd          Cr         CU          Fe        Hg           Mn          Ni          Pb         Se          Sn          Zn
                          SAMP


            MSPB         8055SPK          16.70         1183        29.5       5.27       13.24     198.0       2291       0.723         89.4       19.43        5.32       22.3        3.49      5315
            MSPB,         SPIKE           11.48          99         9.2        2.48        9.18        19.8     1148       0.522         49.6        19.8        5.0        15.3        5.0       495.8
            MBCP            8049             1.15       315         10.1       2.30        0.00        35.2       169      0.059         16.7        1.26        0.30       2.40        0.00        463
            MBHI            8051'            4.47       1317        7.1        5.90        1.61     263.5         644      0.074         33.4        2.61        0.84       2.08        0.00      6961
            PBPH            8059             1.87        91         11.9       3.21        0.00        36.9       254      0.093         10.8        0.76        0.46       3.44        0.18      1668
            PBIB            8057             3.41       1313        9.0        4.11        1.41        58.7       935      0.175         25.7        1.50        0.74       3.27        0.15      1322
           -CBJB            8067             0.61       705         16.0       2.17        0.95     226.5       1068       0.187         12.1        1.18        1.41       4.31        0.20      3375
            CBBL            8065             3.73       451         11.7       1.97        0.71     207.5         545      0.165         14.3        1.15        1.79       5.63        0.26      2890
            CBBL         8065DUP             3.84       445         14.3       2.03        0.64     212.7         570      0.181         12.2        1.28        2.04       5.48        0.29      2955
            CBPP            8061             3.06       276         13.3       1.89        0.00        34.1       365      0.152         12.5        0.81        5.03       4.97        0.00      1755
            CBBB            8063          16.65         933         11.1       2.82        1.14     145.0         596      0.206         14.0        1.24        4.27       5.55        0.24      3194
            PCLO            8069             0.57       624         11.1       1.47        0.87        28.4       637      0.366         12.5        1.46        1.20       3.29        0.00      2587
            AESP            8071             0.86       490         19.0       3.12        0.91        24.0       396      0.228         15.8        0.97        0.63       3.80        0.00        665
            BBPR            8127             0.20       620         9.1        0.44        1.02        53.3       444      0.081         27.3        1.83        0.25     2.306         1.25        907
            CKBP            8073             0.51       318         16.4       2.67        1.05        18.9       359      0.193         20.7        0.94        0.62       2.92        0.00        619
        N)  TBOT            8081             2.68       167         4.1        3.98        0.00     106.7         559      0.329         11.7        1.77        0.91       3.24        0.00      7590
            TBPB,           8079             1.70       180         7.7        2.14        0.67        71.3       269      0.282          0.0        1.15        1.26       2.65        0.00      2047
            TBPI3        8079SPK          15.29         280         20.2       4.74       10.41        90.5     1558       0.779         49.3       19.75        5.64       19.1        4.34      2480
            TBPB;         SPIKE           11.87          96         10.7       2.41        9.49        19.3     1187       0.471         48.2        19.3        4.8        15.8        4.8       481.9
            TBHB            8085             1.39        86         5.5        2.06        0.74        55.2       138      0.151         10.8        0.74        0.90       2.19        0.27      2324
            TBMK            8089             0.47       138         12.4       1.58        0.00        14.7       141      0.163          5.2        0.85        0,41     1.543         0.00        306
            T'BKA           8075             3.54        81         8.5        1.36        0.55        76.6       177      0.127         11.6        0.84        1.33       2.75        0.33      4328
            TBNP            8083             1.57        58         42.6       0.83        0.00        54.6       126      0.121          6.3        0.91        0.70       2.18        0.00      2545
            CBBI            8087             2.73       188         12.1       2.15        0.62     110.1         222      0.184          6.9        0.81        0.42       2.25        0.00      2916
            RBHC            8091             1.94       173         11.9       1.49        0.75        65.5       231      0.195          5.7        0.74        0.34     2.351         0.00        967
            FBFO 1          8095             1.33        65         15.7       1.05        0.90     521.5         155      0.098          5.4        0.45        0.44     1.758         0.60      4394
            FBFO 2          8096             0.85        53         14.7       0.00        0.00        0.0        127      0.206          4.1        0.60        0.34     1.467         0.00        638
            FBFO 3          8097             1.27        59         13.4       2.47        0.00        77.5       148      0.252          4.7        0.59        0.26     1.394         0.00      1134
            FBJB 1          8110             1.17       325         7.7        1.59        1.28        49.7       442      0.271         10.9        1.07        0.30     4.921         0.00        963
            FBLB, 2         8111             0.94       469         5.8        1.38        0.96        51.6       305      0.280         13.3        1.23        0.38     4.102         0.00        705
            FBJB 3          8112             1.07       424         7.6        1.70        1.43        46.7       374      0.318         13.6        1.06        0.34     4.579         0.00        920
            BHKF            8077             0.00        39         74.2       2.88        0.91        6.1        107      0.098          5.3        2.95        0.29       2.05        0.00        124
            BJPR            8123             0.56       448         12.3       0.95        0.00     120.5         334      0.096         18.5        0.73        0.28     3.428         0.00        689
            BMPR            8125             1.37       227         13.4       0.53        0.62     189.3         238      0.100         10.5        0.87        0.23     4.019         0.00      2334




 I
 I                   I
 I
 I
 I
 I
 I
 I            Trace Metal Data
 I               (Sediment)
 I
 I
 I
 I
 I
 I
 I
 I
 1                     122
 I





                                                      Mussel Watch Project Year 9 - Trace Metal Data (Sediment)








     Site Lab Rep. ADG              HGDG       OTHDG    Wet Wt. AD          FIGD    OTHDG     Moist.  Unit   Unit Al        Ag As Cd Cr Cu                   Fe     Mn     Ni     Pb Sb Se             Sn    Zn     Hg
            Samp    No.     Date      Date      Date      Rec'd     Wt.      Wt.      Wt.      (%)    (trn)  Qua].
    FBFO    K8098     1   10/26/94  10/26/94   11/7/94    19.94     0.208   0.207    0.5128   57.92   pprn   dry   16600  0.033   9.33  0.257  51.2  44.20  9260    68     9.1   8.71  0.15   0.56   0.19   42.10 0.042
    FBFO    K8099     2   10/26/94  10/26/94   iin/94     24.88     0.21    0.195    0.5201   58.16   pprn   dry   117000.000     4.84  0.061  33.5 2.14    12200   109    9.3   4.07  <0. 1  0.43   0.00   8.73  0.032
    FBFO    K8100     3   10/26/94  10/26/94   11/7/94    20.39     0.209   0.204    0.5183   60.57   pprn   dry   17100  0.029   11.30 0.156  52.8 3.70    9580    66     8.7   6.46  0.19   0.49   0.12   15.20 0.030
    FBJB    K8113     1   10/26/94  10/26/94   11/7/94    26.00     0.214   0.199    0.4996   59.42   pprn   dry   12300  0.000   4.54  0.062  33.4   1.75  12400   116    7.3   5.12  0.16   0.33   0.00   8.37  0.050
    FBJB    K8114     2   10/26/94  10/26/94   11/7/94    24.93     0.203   0.193    0.4993   57.80   pprn   dry   18200  0.000   11.70 0.131  40.9   3.94  10100   71     8.6   6.04  0.23   0.52   0.14   14.70 0.019
    IFBJB   K8115     3   10/26/94  10/26/94   11/7/94    25.86     0.202   0.199    0.5177   54.02   pprn   diy   117000.000     4.64  0.035  29.1   1.49  11400   109    6.6   3.06  0.10   0.46   0.21   9.25  6.037





         b-D




  I
  I
  I
  I
  I
  I
  I
  I                       Trace Metal QC Data
  I                                 (Sediment)
  I
  I
  I
  I
  I
  I
  I
  I
  1
                                               124
  1 -





                                             Mussel Watch Project Year 9 - Trace Metal QC Data (Sediment)






            Site       Lab       Samp ADG           HGDG       OT'BDG Samp          Wet Wt.       Ad        HGD     OTTED Moist.       Unit   Unit     Al        Ag        As       Cd        Cr        CU
                       Samp        ID      Date       Date      Date       Type       Rec'd      Wt.        Wt.       Wt.       (0/6)  (trn)  Qual.

                     DLDRY                                               DLDRY                                                         pprn   dry     200      0.013      0.25     0.018      0.1       0.44
            FBFO       8098      K8098   10/26/94   10/26/94   11/7/94 SAMP           19.94     0.208     0.2066    0.5128     57.92   pprn   dry    16600     0.033      9.33     0.257      51.2      44.20
            FBFO    8098-DUP K8098       10/26/94   10/26/94   11/7/94 LDUP                     0.2033    0.2078    0.5056             pprn   dry    16900     0.045      10.60    0.322      51.4      30.30
            FBFO       8099      K8099   10/26/94   10/26/94   11/7/94     SAMP       24.88     0.2102    0.1954    0.5201     58.16   pprn   dry    11700     0.000      4.84     0.061      33.5      2.14
            FBFO       SPIKE     K8099   10/26/94   10/26/94   11/7/94   SPKLEV                                                        pprn   dry              0.997      20.40    4.990      102.0     49.90
            FBFO    8099-SPK     K8099   10/26/94   10/26/94   iin194       MS                  0.2006    0.1959    0.4892             pprn   dry    11300     1.030      26.40    5.080      137.0     50.80
            FBFO       8100      K8100   10/26/94   10/26/94   11/7/94     SAMP       20.39     0.2085    0.2039    0.5183     60.57   pprn   dry    17100     0.029      11.30    0.156      52.8      3.70
            FBJB       8113      K8113   10/26/94   10/26/94   nn194       SAMP       26.00     0.2135    0.1989    0.4996     59.42   pprn   dry    12300     0.000      4.54     0.062      33.4      1.75
            FBJB    8113-DUP K8113       10/26/94   10/26/94   11/7/94     LDUP                 0.2111    0.2023    0.4997             pprn   dry    12500     0.000      5.26     0.073      32.2      1.69
            FBJB       8114      K8114   10/26/94   10/26/94   11/7/94     SAMT       24.93     0.2033    0.1927    0.4993     57.80   pprn   dry    18200     0.000      11.70    0.131      40.9      3.94
            FBJB       SPIKE     K8114   10/26/94   10/26/94   11/7/94 SPKLEV                                                          pprn   dry              0.973      19.50    4.870      100.0     48.70
            FBJB    8114-SPK     K8114   10/26/94   10/26/94   11/7/94      MS                  0.2055    0.1956    0.5124             pprn   dry    18500     1.030      31.40    4.950      152.0     47.70
            JFBJB      8115      K8115   10/26/94   10/26/94   11/7/94     SAMP       25.86     0.2023    0.1989    0.5177     54.02   pprn   dry    11700     0.000      4.64     0.035      29.1      1.49
      N)





                                             Mussel Watch Project Year 9 - Trace Metal QC Data (Sediment)






                                            Site       Lab       Samp,     Fe       Mn      Ni        Pb     Sb       Se       Sn      Zn       Hg Comments
                                                       Samp       ID

                                                     DLDRY                100.0     3.5     0.4     0.15     0.10    0.10     0.10     1.50     0.01
                                            FBFO       8098      K8098    9260      68      9.1     8.71     0.15    0.56     0.19     42.10    0.042
                                            FBFO    8098-DUP     K8098    9320      68      10.2    8.16     0.19    0.46     0.21     44.00    0.048
                                            FBFO       8099      K8099    12200     109     9.3     4.07     <0. 1   0.43     0.00     8.73     0.032
                                            FBFO       SPIKE     K8099              499     199.0   12.50    4.09    49.90    4.24     249.00   0.510 Not spiked A], Fe
                                            FBFO    8099-SPK     K8099    12100     587     202.0   15.80    3.96    42.70    3.24     290.00   0.497
                                            FBFO       8100      K8100    9580      66      8.7     6.46     0.19    0.49     0.12     15.20    0.030
                                            FBJB       8113      K8113    12400     116     7.3     5.12     0.16    0.33     0.00     8.37     0.050
                                            FBJB    8113-DUP     K8113    12200     112     7.3     4.88     0.00    0.44     0.00     8.42     0.049
                                            FBJB       8114      K8114    10100     71      8.6     6.04     0.23    0.52     0.14     14.70    0.019
                                            FBJB       SPIKE     K8114              487     195.0   12.20    3.90    48.70    4.14     243.00   0.511 Not spiked Al, Fe
                                            FBJB    8114-SPK     K8114    9990      596     203.0   17.50    4.13    42.70    3.45     287.00   0.497
                                            JFBJB      8115      K8115    11400     109     6.6     3.06     0.10    0.46     0.21     9.25     0.037




  I
  I
  I
  I
  I
  I
I I
  I                         Butyltin Results
  I
  I
  I
  I
  I
  I
  I
  I
  I
  1                                        127
  -I




  I
  I
  I
  I
  I
  I
  I
  .I              Butyltin Data
  I                  (Tissue)
  I
  I
  I
  I
  I
  I
  I
  I
  1
                         128
  I






                                                                                Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                    Site       Lab Sample ID          File No.         Matrix           Sample Type          Dry Weight (g)          Wet Weight (g)           Concentration Basis         % solid      % Moisture        % Lipid       Organism        Page Number


                    LMSB            K8008             K8008            TISSUE              SAMP                    1.04                    10.08                       Dry                  10.32          89.68           4.11         Mussel           TBT 199
                    LMPI            K8016             K8016            TISSUE              SAMP                    1.32                    10.01                       Dry                  13.19          86.81           3.28         Mussel           TBT 199
                    LMAC            K8012             K8012            TISSUE              SAMP                    1.69                    10.12                       Dry                  16.70          83.30           10.92        Mussel           TBT 199
                    CCNB            K8018             K8018            TISSUE              SAMP                    2.21                    10.05                       Dry                  21.98          78.02           2.04         Mussel           TBT 199
                    ABLR            K8032             K8032            TISSUE              SAMP                    1.67                    10.16                       Dry                  16.43          83.57           18.74        Mussel           TBT 199
                    MBAR            K8020             K8020            TISSUE              SAMP                    1.41                    10.30                       Dry                  13.69          86.31           10.87        Mussel           TBT 199
                    SAPP            K8026             K8026            TISSUE              SAMP                    1.81                    10.03                       Dry                  18.04          81.96           15.31        Mussel           TBT 199
                    ESSP            K8030             K8030            TISSUE              SAMP                    1.90                    10.04                       Dry                  18.93          81.07           14.93        Mussel           TBT 199
                    ESBD            K8028             K8028            TISSUE              SAW                     1.27                    10.12                       Dry                  12.55          87.45           6.24         Mussel           TBT 199
                    MBGP            K8024             K8024            TISSUE              SAMP                    1.65                    10.06                       Dry                  16.40          83.60           14.69        Mussel           TBT 199
                    MBCB            K8022             K8022            TISSUE              SAMP                    1.32                    10.18                       Dry                  12.97          87.03           11.50        Mussel           TBT 199
                    BRCL            K8004             K8004            TISSUE              SAMP                    1.39                    10.05                       Dry                  13.83          86.17           4.41         Mussel           TBT 199
                    GBTD,           K8000             K8000            TISSUE              SAMP                    2.00                    10.07                       Dry                  19.86          80.14           13.00        Mussel           TBT 199
                    GBOB            K8006             K8006            TISSUE              SAM?                    2.02                    10.16                       Dry                  19.88          80.12           12.13        Mussel           TBT 199
                    GBSC            K8002             K8002            TISSUE              SAMP                    0.36                    2.02                        Dry                  17.78          82.22           9A4          Mussel           TBT 199
                    SLBB            K8010             K8010            TISSUE              SAMP                    1.54                    10.08                       Dry                  15.28          84,72           9.66         Mussel           TBT 199
                    CLLC            K8014             K8014            TISSUE              SANT                    2.09                    10.16                       Dry                  20.58          79.52           12.43        Mussel           TBT 199
                    VBSP            K8040             K804OF           TISSUE              SAMP                    0.97                    10.18                       Dry                  9.53           90.47           15.05        Mussel           TBT 201
                    CLCL            K8034             K8034F           TISSUE              SAMP                    1.33                    10.06                       Dry                  13.22          86.78           )5.01        Mussel           TBT 201
                    TBLF            K8036             K8036F           TISSUE              SAMP                    1.83                    10.07                       Dry                  18.18          81.82           13.19        Mussel           TBT 201
                    MRPL            K8042             K8042F           TISSUE              SAN?                    0.46                    10.15                       Dry                  4.53           95.47           11.53        Mussel           TBT 201
                    BSSI            K8038             K8038F           TISSUE              SAMP                    1.12                    15.09                       Dry                  7.43           92.57           17.40        Mussel           TBT 288
                    LBMP            K8044             K8044F           TISSUE              SAMP                    1.31                    15.12                       Dry                  8.63           91.37           15.57        Mussel           TBT 288
                    LBNO            K8046             K8D46F           TISSUE              SANT                    1.40                    15.27                       Dry                  9.19           90.81           17.06        Mussel           TBT 288
                    MSPC            K8052             K8052F           TISSUE              SAMP                    1.29                    10.03                       Dry                  12.86          87.14           12.58        Mussel           TBT 201
                    MSPB            K8054             K054RF           TISSUE              SAMP                    1,24                    15.05                       Dry                  8.25           91.75           11.65        Mussel           TBT 299
                    MBCP            K8048             K8048F           TISSUE              SAMP                    2.52                    15.37                       Dry                  16.40          83.60           20.34        Mussel           TBT 298
                    MBHI            K8050             K805OF           TISSUE              SAMP                    1.28                    10.19                       Dry                  12.56          87.44           14.78        Mussel           TBT 201
                    PBPH            K8058             K8058F           TISSUE              SXMP                    2.13                    15.11                       Dry                  14.07          85.93           19.29        Mussel           TBT 288
                    PBIB            K8056             K056RF           TISSUE              SAMP                    1.00                    14.99                       Dry                  6.67           93.33           12.90        Mussel           TBT 299
                    CBJB            K8066             K066RF           TISSUE              SAMP                    1.28                    15.26                       Dry                  8.39           91.61           9.42         Mussel           TB,r 299
                    CBBL            K8064             K064RF           TISSUE              SAMP                    1.41                    14.98                       Dry                  9.41           90.59           5.87         Mussel           TBT 299
                    CBPP            K8060             K806OF           TISSUE              SANT                    1.73                    15.14                       Dry                  11.39          88.61           12.23        Mussel           TBT 288
                    CBBB            K8062             K8062F           TISSUE              SANT                    1.11                    10.05                       Dry                  11.05          88.95           14.70        Mussel           TBT 201






                                                                            ,Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                   Site       Lab Sample ID         File No.        Matrix          Sample Type         Dry Weight (g)         Wet Weight (g)          Concentration Basis         % solid     % Moisture       % Lipid      Organism        Page Number


                   PCLO            K8068            K8068F          TISSUE              SAW                   0.71                    10.00                     Dry                 7.10          92.90           32.15        Mussel          TBT 201
                   AESP            K8070            K807OF          TISSUE              SAM?                  1.06                    15.08                     Dry                 7.05          92.95           12.17        Mussel          TBT 288
                   CKBP            K8072            K8072F          TISSUE              SAM?                  1.19                    15.17                     Dry                 7.85          92.15           9.04         Mussel          TBT 288
                   TBOT            K8080            K809OF          TISSUE              SANT                  1.18                    15.07                     Dry                 183           92.17           3,77         Mussel          TBT 288
                   TBPB            K8078            K8078F          TISSUE              SANT                  1.98                    15.03                     Dry                 13.17         86.83           7.75         Mussel          TBT 288
                   TBHB            K8084            K084RF          TISSUE              SAMP                  2.43                    15.12                     Dry                 16.07         83.93           8.20         Mussel          TBT 299
                   TBMK            K8088            K088RF          TISSUE              SAW                   2.57                    15.06                     Dry                 17.06         82.94           8.99         Mussel          TBT 299
                   TBKA            K8074            K8074F          TISSUE              SAW                   1.90                    15.19                     Dry                 12.52         87.48           14.91        Mussel          TBT 288
                   TBNP            K8082            K8082F          TISSUE              SAND                  2.42                    15.01                     Dry                 16.12         83.88           6.85         Mussel          TBT 288
                   CBBI            K8086            K086RF          TISSUE              SAW                   1.94                    15.09                     Dry                 12.86         87.14           5.92         Mussel          TBT299
                   PBHC            K8090            K090RF          TISSUE              SAW                   1.26                    10.55                     Dry                 11.94         88.06           433          Mussel          TBT 299
                   FBFO            K8092            K92FR           TISSUE              SAW                   2.37                    15.11                     Dry                 15.69         84,31           9.25         Mussel          TBT299
                   FBFO            K8093            K93FR           TISSUE              SAW                   1.58                    15.24                     Dry                 10.37         89.63           10.88        Mussel          TBT 299
                   FBFO            K8094            K94FR           TISSUE              SAW                   1.70                    14.98                     Dry                 11.35         88.65           T40          Mussel          TBT 299
                   FBJB            K8110            KI IORF         TISSUE              SAW                   0.40                    3.64                      Dry                 10.99         89.02           4.46         Mussel          TBT 298
                   FBJB            K8111            KIIIRF          TISSUE              SAW                   0.42                    4.38                      Dry                 9.58          90.42           4.47         Mussel          TBT 298
                   FBJB            K8112            KI 12RF         TISSUE              SAW                   0.15                    1.43                      Dry                 10.47         89.53           7.09         Mussel          TBT 298
                   BHKF            K8076            K076RF          TISSUE              SAW                   2.69                    15.17                     Dry                 17.73         82.27           6.25         Mussel          TBT 299
                   PRBB            K8126            K8126R          TISSUE              SAND                  0.94                    5.82                      Dry                 16.16         83.84           6.11         Mussel          TBT 287
                   PR13M           K8124            K8124R          TISSUE              SAW                   0.39                    2.36                      Dry                 16.53         83.47           5.79         Mussel          TBT 287
                   PRBJ            K8122            K8122F          TISSUE              SANT                  0.59                    3.65                      Dry                 16.15         83.85           4.98         Mussel          TBT 287






                                                                             Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                    Site      Lab Sample ID,        File No.        Matrix          Sample Type         Receive Date         Extraction Date        Analysis Date        Units         Tripropyltin % recovery           Tetrabutyltin        TetrabutyltinQ


                    LMSB           K8008            K8008           TISSUE              SAM?               12/10/93              9/21/94                6/9/95          ng Sn/g                    37                         0.08                    J
                    LWI            K8016            K8016           TISSUE              SAW                12/10/93              9/21/94                6/10/95         ng Sn/g                    54                         0.04                    J
                    LMAC           K8012            K8012           TISSUE              SAW                12/10/93              9/21/94                6/9/95          ng Sn/g                    54                         0.06                    J
                    CCNB           K8018            K8018           TISSUE              SAW                12/16/93              9/21/94                6/10/95         ng Sn/g                    50                         0.09                    J
                    ABLR           K8032            K8032           TISSUE              SAW                12/17/93              9/21/94                6/10/95         ng Sn/g                    35                         0.12                    J
                    MBAR           K8020            K8020           TISSUE              SAW                12/16/93              9/21/94                6/10/95         ng Sn/g                    91                         0.04                    J
                    SAPP           K8026            K8026           TISSUE              SAW                12/16/93              9/21/94                6/10/95         ng Sn1g                    41                         0.10                    J
                    ESSP           K8030            K8030           TISSUE              SAW                12/17/93              9/21/94                6/10/95         ng Sn/g                    48                         0.08                    J
                    ESBD           K8028            K8028           TISSUE              SAW                12/17/93              9/21/94                6/10/95         ng Sn/g                    36                         0.52                    J
                    MBGP           K8024            K8024           TISSUE              SAW                12/16/93              9121/94                6/10/95         ng Sn/g                    37                         0.20                    J
                    MBCB           K8022            K8022           TISSUE              SAW                12/16/93              9/21/94                6/10/95         ng Sn/g                    38                         0.32                    J
                    BRCL           K8004            K8004           TISSUE              SAW                12/9/93               9/21/94                6/9/95          ng Sn/g                    56                         0.11                    J
                    GBTD           K8000            K8000           TISSUE              SAW                1219/93               9/21/94                6/9195          ng Sn1g                    42                         0.19                    J
                    GBOB           K8006            K8006           TISSUE              SAW                1219/93               9/21/94                619195          ng Sn/g                    56                         0.09                    J
                    GBSC           K8002            K8002           TISSUE              SAW                12/9/93               9/21/94                6/9/95          ng Sn/g                    30                         0.52                    1
                    SLBB           K8010            K8010           TISSUE              SAW                12/10/93              9/21/94                619195          ng Sn1g                    50                         0.24                    J
                    CLLC           K8014            K8014           TISSUE              SANT               12/10/93              9/21/94                61919S          ng Sn/g                    45                         0.11                    J
                    VBSP           K8040            K804OF          TISSUE              SAW                1/13/94               10/4/94                6/21/95         ng Sn/g                    67                                               ND
                    CLCL           K8034            K8034F          TISSUE              SAW                1/13/94               10/4/94                6/21/95         ng Sn/g                    117                        0.19
                    TBLF           K8036            K8036F          TISSUE              SAW                1/13/94               10/4/94                6/21/95         ng Sn/g                   .118                        0.20                    J
                    MRPL           K8042            K8042F          TISSUE              SAW                1/15/94               10/4/94                6/21/95         ng Sn/g                    39                         0.69                    J
                    BSSI           K8038            K8038F          TISSUE              SAW                1/15/94               6120/95                6/26/95         ng Sn/g                    50                         0.24                    J
                    LBMP           K8044            K8044F          TISSUE              SAW                1/15/94               6/20/95                6/26/95         ng Sn/g                    68                         1.15                    1
                    LBNO           K8046            K8046F          TISSUE              SAW                1/15/94               6/20/95                6/26/95         ng Sn/g                    48                         0.35                    J
                    MSPC           K8052            K8052F          TISSUE              SAW                1/16/94               10/4/94                6/22/95         ng Sn/g                    73                         9.40                    J
                    MSPB           K8054            K054RF          TISSUE              SAW                1/16194               7/17/95                7/20/95         ng Sn/g                    61                         0.41                    J
                    MBCP           K8048            K8048F          TISSUE              SAW                12/10/93              6/20/95                6/27/95         ng Sn/g                    53                         0.10                    J
                    MBHI           K8050            K805OF          TISSUE              SAW                1/16/94               1014/94                6/21/95         ng Sn/g                    120                        1.39                    J
                    PBPH           K8058            K8058F          TISSUE              SAW                1/17/94               6120195                6/27/95         ng Sn/g                    38                         0.25                    J
                    PBIB           K8056            K056RF          TISSUE              SAW                1/17/94               7/17/95                7/20/95         ng Sn/g                    87                         0.58                    J
                    CBJB           K8066            K066RF          TISSUE              SAW                1119194               7/17/95                7/20/95         ng Sn/g                    79                         2.06                    J
                    CBBL           K8064            K064RF          TISSUE              SAW                1/19/94               7/17/95                V20/95          ng Sn/g                    59                         3.09                    J
                    CBPP           K8060            K806OF          TISSUE              SAW                1/17194               6/20/95                6n6195          ng Sn/g                    so                         0.07                    J
                    CBBB           K8062            K8062F          TISSUE              SAW                1/17/94               10/4/94                6/22/95         ng Sn/g                    85                         0.89                    J






                                                                              Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                     Site      Lab Sample ID         File No.         Matrix         Sample Type          Receive Date         Extraction Date        Analysis Date        Units         Tripropyltin % recovery            Tetrabutyltin        TetrabutyltinQ


                   PCLO             K8068            K8068F           TISSUE             SAW                 1119/94               10/4/94                6/22/95         ng Sn/g                    41                          6.50                    J
                   AESP             K8070            K807OF           TISSUE             SAW                 MO/94                 6/20/95                6/26/95         ng Sn/g                    62                          0.43                    J
                   CKBP             K8072            K8072F           TISSUE             SAW                 MO/94                 6/20/95                6/26/95         ng Sn/g                    39                          0.43                    J
                   TBOT             K8080            K808OF           TISSUE             SAW                 1121194               6)2DJ95                6f26195         ng Sn/g                    59                          0.59                    J
                   TBPB             K8078            K8078F           TISSUE             SANT                1/21/94               6/20/95                6/26/95         ng Sn/g                    46                          1.07                    J
                   TBHB             K8084            K084RF           TISSUE             SANT                1/23/94               7/17/95                7/20/95         ng Sn/g                    110                         2.99                    J
                   TBMK             K8088            K088RF           TISSUE             SANT                1/23/94               7/17/95                V20/95          ng Sn/g                    89                          0.26                    J
                   TBKA             K8074            K8074F           TISSUE             SAW                 1/21/94               6/20/95                6/26/95         ng Sn/g                    67                          0.13                    J
                   TBNP             K8082            K8082F           TISSUE             SAW                 1/21/94               6/20/95                6/26/95         ng Sn/g                    42                          0.46                    J
                   CBBI             K8086            K086RF           TISSUE             SAW                 1/23/94               7/17/95                7/20/95         ng Sn/g                    84                          0.24                    J
                   RBHC             K8090            K090RF           TISSUE             SAW                 1/23/94               7/17/95                7/20/95         ng Sn/g                    48                          4.04                    J
                   FBFO             K8092            K92FR            TISSUE             SAW                 1/27/94               7/17/95                8/7/95          ng Sn/g                    60                          0.75                    J
                   FBFO             K8093            K93FR            TISSUE             SAW                 1/27/94               7/17/95                8n19S           ng Sn/g                    51                          2.59                    J
                   FBFO             K8094            K94FR            TISSUE             SAW                 1/27/94               7/17/95                8n195           ng Sn/g                    93                          2.57                    J
                   FBJB             K81 10           KI IORF          TISSUE             SAW                 1/27/94               7/14/95                7/19/95         ng Sn/g                    66                          12.25                   J
                   FBIB             K81 11           KI I I RF        TISSUE             SANT                1/27/94               7/14/95                7/19/95         ng Sn/g                    105                         6.97                    J
       CIO         FBJB             K8112            K I 12RF         TISSUE             SANT                1/27/94               7/14/95                7/19/95         ng Sn/g                    106
                   BHKF             K8076            K076RF           TISSUE             SAW                 1/21/94               7/17/95                7/20/95         ng Sn/g                    56                          0.22                    J
                   PRBB             K8126            K8126R           TISSUE             SAW                 2/16/94               6/19/95                6/25/95         ng Sn/g                    65                          0.76                    1
                   PRBM             K8124            K8124R           TISSUE             SAW                 2/16/94               6/19/95                6/25/95         ng Sn/g                    47                          1.75                    J
                   PRBJ             K8122            K8122F           TISSUE             SAW                 2/16/94               6/19/95                6/24/95         ng Sn/g                    47                          1.95                    J






                                                                               Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                      Site     Lab Sample ID          File No.         Matrix          Sample Type         Tributyltin      TributyltinQ        Dibutyltin      DibutyltinQ          Monobutyltin            MonobutyltinQ


                    LMSB            K8008             K8008          TISSUE               SAW                 12.67                 J              2.43                J                   0.28                       J
                    LWI             K8016             K8016          TISSUE               SAW                 269.50                               32.57                                   1.84                       J

                    LMAC            K8012             K8012          TISSUE               SAW                 1.00                  J              0.17                J                   0.42                       J
                    CCNB            K8018             K8018          TISSUE               SAW                 20.53                                6.33                J                   0.57                       J
                    ABLR            K8032             K8032          TISSUE               SAW                 0.67                  J              0.07                J                   0,31                       J
                    MBAR            K8020             K8020          TISSUE               SAW                 0.25                  J              0.88                J                   0.95                       J

                    SAPP            K8026             K8026          TISSUE               SAW                 1.00                  J              0.45                J                   0,75                       J
                    ESSP            K8030             K8030          TISSUE               SANT                3.41                  J              0.05                J                   0,48                       J
                    ESBD            K8028             K8028          TISSUE               SAW                 19.69                                3.91                J                   0.64                       J
                    MBGP            K8024             K8024          TISSUE               SAW                 33.46                                3.78                J                   0.09                       J
                    MBCB            K8022             K8022          TISSUE               SAW                 6.27                  J              0.37                J                   0.52                       J
                    BRCL            K8004             K8004          TISSUE               SAW                 13.91                 1              1.04                J                   OAO                        J
                    GBTD            K8000             K8000          TISSUE               SAW                 220.30                               24.50                                   2.17                       J
                    GBOB            K8006             K8006          TISSUE               SANT                48.72                                8.91                J                   0.93                       J
                    OBSC            K8002             K8002          TISSUE               SAW                 285.02                               31.60               J                   0.83                       J
                    SLBB            K8010             K8010          TISSUE               SAW                 105.11                               10.73               J                   0.74                       J
                    CLLC            K8014             K8014          TISSUE               SAW                 207.55                               16.91                                   1 A4                       J
                    VBSP            K8040             K8040F         TISSUE               SAW                 0.69                  J              0,30                J                   10.39                      J
                    CLCL            K8034             K8034F         TISSUE               SAW                 1.94                                 0.91                                    0.84
                    TBLF            K8036             K8036F         TISSUE               SAW                 0.82                  J              1.36                J                   O@04                       J
                    MRPL            K8042             K8042F         TISSUE               SAW                 142.50                               7AS                 J                   1.13                       J
                    BSS1            K8038             K8038F         TISSUE               SAW                 14.18                 J              0.69                J                   0.14                       J
                    LBMP            K8044             K8044F         TISSUE               SAW                 0.00               ND                0.25                J                   1@11                       J
                    LBNO            K8046             K8046F         TISSUE               SAW                 2.18                  J              0.00             ND                     0.00                    ND
                    MSPC            K8052             K8052F         TISSUE               SAW                 12.64                 J              1,26                J                   0@11                       J
                    MSPB            K8054             K054RF         TISSUE               SAMP                95.17                                32.76                                   12.89                      J
                    MBCP            K8048             K8048F         TISSUE               SAW                 0.00               ND                0.27                J                   0.13                       J
                    MBM             K8050             K805OF         TISSUE               SAW                 117.03                               7.24                J                   0.55                       J
                    PBPH            K8058             K8058F         TISSUE               SAW                 75.79                                0.40                J                   0.27                       1
                    PBIB            K8056             K056RF         TISSUE               SAW                 32.38                                3.43                1                   2.58                       J
                    CBJB            K8066             K066RF         TISSUE               SAW                 284.25                               190.98                                  38.31
                    CBBL            K8064             K064RF         TISSUE               SAW                 44.46                                19.70                                   1.99                       J
                    CBPP            K8060             K8060F         TISSUE               SAW                 0,00               ND                0.00             ND                     0.33                       J
                    CBBB            K8062             K8062F         TISSUE               SAW                 40.89                                4.19                J                   1.55                       J






                                                                               Mussel Watch Project Year 9 - Butyltin Data (Tissue)


                      Site      Lab Sample ID         File No.        Matrix           Sample Type         Tributyltin      TributyltinQ        Dibutyltin      DibutyltinQ          Monobutyltin            MonobutyltinQ


                    PCLO            K8068             K8068F          TISSUE              SAW                                    ND                5.08                J                   6.02                       J
                    AESP            K8070             K807OF          TISSUE              SAW                  0,00              ND                0.00              ND                    0.07                       J
                    CKBP            K8072             K8072F          TISSUE              SAW                  3.94                 J              0.00              ND                    0.05                       J
                    TBOT            K8080             K808OF          TISSUE              SAW                  1.91                 J              0.00              ND                    0.42                       J

                    TBpB            K8078             K8078F          TISSUE              SAW                  3.96                 J              0.00              ND                    0.64                       J
                    TBHB            K8084             K094RF          TISSUE              SAW                  17).29                              106.08                                  29.14

                    TBMK            K8088             K088RF          TISSUE              SAW                  2.50                 J              0.65                J                   0.22                       J

                    TBKA            K8074             K8074F          TISSUE              SAW                  55.63                               20.69                                   0.00                     ND
                    TBNP            K8082             K8082F          TISSUE              SAW                  0.00              ND                0.61                J                   0.08
                    CBBI            K8086             K086RF          TISSUE              SAW                  14.60                               4.51                J                   3.46                       J
                    RBHC            K8090             K090RF          TISSUE              SAW                  6.13                 J              7@60                J                   2.40
                    FBFO            K8092             K92FR           TISSUE              SAW                  378.10                              184.48                                  60.72
                    FBFO            K8093             K93FR           TISSUE              SAW                  6.77                 J              4.87                J                   0.52                       J
                    FBFO            K8094             K94FR           TISSUE              SAW                  3.77                 J              1.95                J                   1.72                       1
                    FBJB            K8110             KI IORF         TISSUE              SAW                  1.63                 J              1.77                J                   8.41                       J
                    FBJB            K81 11            KI I I RF       TISSUE              SAW                  6.55                 J              2.80                J                   3.41                       1
                    FBJB            K8112             K I 12RF        TISSUE              SAW                                                                                     *insufficient sample
                    BHKF            K8076             K076RF          TISSUE              SAW                  5.70                 J              0.35                J                   0.21                       J

                    PRBB            K8126             K8126R          TISSUE              SAW                  160.18                              24.45                                   6.15                       J

                    PRBM            K8124             K8124R          TISSUE              SAW                  48.21                J              6.68                J                   4.43                       J
                    PR13J           K8122             K8122F          TISSUE              SAW                  158.41                              3.91                J                   2.25                       J




  I
  I
  I
: I
  I
  I
  I
  .I           Butyltin QC Data
  I                 (Tissue)
  I
  I
  I
  I
  I
  I
  I
  I
  1
                        135
  I





                                                            Mussel Watch Project Year 9 - Butyltin QC Data (Tissue)






               Site                                         CCNB                       CCNI3                       CCNB                                                                               PBPH                      PBPH
               Lab Sample ID                                K8018                      Q9895                       Q9896                    Q9898                       Q9897                         K8058                     Q9910
               File No.                                     K8018                      Q9895                       Q9896                    Q9898                       Q9897                         K8058F                    Q991OF
               Matrix                                       TISSUE                     TISSUE                      TISSUE                   TISSUE                      TISSUE                        TISSUE                    TISSUE


               Sample Type                                  SAMP                       DUP/MS*                     DUPJMS*                     LBS                      BLANK                         SAMP                      DUP
               Dry Weight (g)                               2.21                       1.39                        1.39                        1.00                       1.56                        1.42                      1.41
               Wet Weight (g)                               10.05                      10.16                       10.12                       NA                         NA                          10.09                     10.02
               Concentration Basis                          Dry                        Dry                         Dry                         Dry                        Dry                         Dry                       Dry
               % solid                                      21.98                      13.69                       13.69                       NA                         NA                          14.07                     14.07
               % Moisture                                   78.02                      86.31                       86.31                       NA                         NA                          85.93                     85.93
               % Lipid                                      2.04                       2.04                        2.04                        NA                         NA                          19.29                     19.29
               Organism                                     Mussel                     Mussel                      Mussel                   Mussel                      Mussel                        Mussel                    Mussel


               Page Number                                  TBT 199                    TBT 199                     TBT 199                  TBT 199                     TBT 199                       TBT 201                   TBT 201
               Receive Date                                 12/16/93                   12/16/93                    12/16/93                    NA                         NA                          1/17/94                   1/17/94
               Extraction Date                              9/21/94                    9/21/94                     9/21/94                  9/21/94                     9/21/94                       10/4/94                   10/4/94
     0)        Analysis Date                                6110195                    6110195                     6/10/95                  6/10/95                     6/10/95                       6/22/95                   6/22/95
               Units                                        ng Sn/g                    ng Sn/g        %            %                           %                        ng Sn/g                       ng Sn/g                   ng Sn/g

               Tripropyltin % recovery                      91                         31                          35                          43                         31                          38                        108

               Tetrabutyltin                                0.04           J           206.97        57.1          46                          128                        0.39            J           2.97           J          0.74
               Tributyltin                                  0.25           J           181.75         53           33                          118                        0.86            J           53.58                     60.62
               Dibutyltin'                                  0.88           J           160.92        43.4          60                          90                         0.24            J           0.88           1          3.89
               Monobutyltin                                 0.95           J           26.44         13.1          18                          40                         0.25            J           1.16           J          0.31          J










               MS    Matrix Spike
               MSD   Matrix Spike Duplicate
               I     Analytical Interference

                     Recovery Outside QC
               ND    Non Dew
               NA    Not Applicable
                     Samples mixed, see case nanrative





                                                            Mussel Watch Project Year 9 - Butyltin QC Data (Tissue)





                                                                                                                                     FBFO STATION               FBFO STATION               FBFO STATION
                Site                                        PBPH                                                                             3                          3                          3
                Lab Sample ID                               Q9911                   Q9913                      Q9912                         K8094                   Q12532                     Q12533                    Q12531
                File No.                                    Q991 IF                 Q9913F                     Q9912F                        K94FR                   Q12532                     Q12533                    Q12531
                Matrix                                      TISSUE                  TISSUE                     TISSUE                        TISSUE                  TISSUE                     TISSUE                    TISSUE


                Sample Type                                 MS                         LBS                     BLANK                         SAMIP                      DUP                        MS                        LBS
                Dry Weight (g)                              1.41                       1.00                      1.06                        1.70                       1.72                       1.71                      1.00
                Wet Weight (g)                              10.02                      NA                        NA                          14.98                      11.48                      15.07                     NA
                Concentration Basis                         Dry                        Dry                       Dry                         Dry                        Dry                        Dry                       Dry
                % solid                                     14.07                      NA                        NA                          11.35                      11.35                      11.35                     NA
                % Moisture                                  85.93                      NA                        NA                          88.65                      88.65                      88.65                     NA
                % Lipid                                     19.29                      NA                        NA                          7.40                       7.40                       7.40                      NA
                Organism                                    Mussel                  Mussel                     Mussel                        Mussel                  Mussel                     Mussel                    Mussel

                Page Number                                 TBT 201                 TBT 201                    TBT 201                       TBT 299                 TBT 299                    TBT 299                   TBT 299
                Receive Date                                1/17194                    NA                        NA                          1/24/94                 1/24/94                    1/24/94                      NA
                Extraction Date                             10/4/94                 10/4/94                    10/4/94                       7117/95                 7/17/95                    7/17/95                   7/17/95
                Analysis Date                               6/22/95                 6/22/95                    6/22/95                       8n195                   7/20/95                    7/20/95                   7/20/95
                Units                                       %                          %                       ng Sn/g                       ng Sn/g                 ng Sn/g                       %                         %


                Tripropyltin % recovery                     78                         39                        100                         93                         79                         51                        90

                Tetrabutyltin                               93                         112                       0.39           J            2.57           J           2.1            J           113                       118
                Tributyltin                                 126                        108                       0.41           J            3.77           J           3.18           J           78                        108
                Dibutyltin                                  77                         60                        0.23           J            1.95           J           2.46           J           69                        88
                Monobutyltin                                25                         12                        0.49           J            1.72           J           0.66           J           43                        71










                MS    Matrix Spike
                MSD   Matrix Spike Duplicate
                I     Analytical Interference

                      Recovery Outside QC
                ND    Non Dew
                NA    Not Applicable
                      Samples mixed, see case narrative





                                                           Mussel Watch Project Year 9 - Butyltin QC Data (Tissue)




                                                                                                                                                                                           FBFO STATION                FBFO STATION
                 Site                                                                    PBPH                       PBPH                      PBPH                                                  3                            3
                 Lab Sample ID                           Q12530                          K8058                   Q12276                     Q12277                    Q12278                        K8094                        K8094
                 File No.                                Q12530                          K8058F                  Q12276                     Q2277R                    Q12279                        K9094F                       Q12273
                 Matrix                                  TISSUE                          TISSUE                  TISSUE                     TISSUE                    TISSUE                        TISSUE                       TISSUE
                 Sample Type                             BLANK                           SAMP                       DVP                       MS                      BLANK                         SAMP                         DUP
                 Dry Weight (g)                              1.79                        2.13                       2.12                      2.12                       1.49                       1.71                         1.73
                 Wet Weight (g)                              NA                          15.14                      15.07                     15.07                      NA                         15.14                        15.24
                 Concentration Basis                         Dry                         Dry                        Dry                       Dry                        Dry                        Dry                          Dry
                 ï¿½ solid                                     NA                          14.07                      14.07                     14.07                      NA                         11.35                        11.35
                 ï¿½ Moisture                                  NA                          85.93                      85.93                     85.93                      NA                         88.65                        88.65
                 ï¿½ Lipid                                     NA                          19.29                      19.29                     19.29                      NA                         7.40                         7.40
                 Organism                                  Mussel                        Mussel                     Mussel                    Mussel                   Mussel                       Mussel                       Mussel
                 Page Number                             TBT 299                         TBT 288                 TBT 288                    TBT 288                   TBT 288                       TBT 287                      TBT 287
                 Receive Date                                NA                          1/17194                    1/17/94                   1/17/94                    NA                         1/27194                      1117/94
                 Extraction Date                           7/17/95                       6/20/95                    6/20/95                   6/20/95                  6/20/95                      6/19/95                      6/19/95
          00     Analysis Date                             7/20/95                       6/26/95                    6/26/95                   6127/95                  6126/95                      6/24/95                      6/24/95
                 Units                                     ng Sn/g                       ng Sn/g                    ng Sn/g                     %                      ng Sn/g                      ng Sn/g                      %
                 Tripropyltin % recovery                     89                          38                         39                          61                       101                        29                           20
                 Tetrabutyltin                               1.49            J           0.25           J           2.14            J           118                      2.97          J            0.6             J            0.41
                 Tributyltin                                 0.89            J           75.79                      91.77                       84                                   ND             1.56            J            1.60
                 Dibutyltin                                  0.18            J           0.40           J           1.78            J           50                                    ND            0.77            J                        ND
                 IMonobutyltin                               0.33            1           0.27           1           1.57            J           17                       0.37          J            1.81            J            0.46







                 MS    Matrix Spike
                 MSD   Matrix Spike Duplicate
                 I     AnslYtical interference


                       Rewy
                          ,!q Outside QC
                 ND    Non Detect
                 14A   Not Applicable
                       Samples mixed, see case narrative





                                                              Mussel Watch Project Year 9 - Butyltin QC Data (Tissue)






                 Site                                                                                               PBHC                        RBHC                     RBHC
                 Lab Sample ID                                Q12274                  Q12275                        K8091                       K8091                    K8091                       QW27                    Q12526
                 File No.                                     Q12274                  Q12275                        K091 RR                     Q2528R                   Q2529R                      Q2527R                  Q12526
                 Matrix                                       TISSUE                  TISSUE                        TISSUE                      TISSUE                   TISSUE                      TISSUE                  TISSUE


                 Sample Type                                  LBS                     BLANK                         SAMP                        DUP                         MS                          LBS                  BLANK
                 Dry Weight (g)                               1.00                       1.45                       1.01                        1.02                        1.01                        1.00                    0.49
                 Wet Weight (g)                               NA                         NA                         15.14                       15.24                       NA                          NA                      NA
                 Concentration Basis                          Dry                        Dry                        Dry                         Dry                         Dry                         Dry                     Dry
                 % solid                                      NA                         NA                         11.94                       11.94                       11.94                       NA                      NA
                 % Moisture                                   NA                         NA                         88.06                       88.06                       88.06                       NA                      NA
                 % Lipid                                      NA                         NA                         4.33                        4.33                        4.33                        NA                      NA
                 Organism                                     Mussel                  Mussel                        Mussel                      Mussel                   Mussel                      Mussel                  Mussel

                 Page Number                                  TBT 287                 TBT 287                       TBT 298                     TBT 298                  TBT 298                     TBT 298                 TBT 298
                 Receive Date                                 NA                         NA                         1/23/94                     1/23/94                  1/23/94                        NA                      NA
                 Extraction Date                              6/20/95                 6/20/95                       7/14/95                     7/14/95                  7/14/95                     7/14/95                 7/14/95
          C.0    Analysis Date                                6/26/95                 6/26/95                       7/21/95                     7/21/95                  7/21/95                     7/19/95                 7/19/95
                 Units                                        %                       ng Sn/g                       ng Sn/g                     %                           %                           %                    ng Sn/g


                 Tripropyltin % recovery                      51                         25                         38                          60                          37                          44                      87

                 Tetrabutyltin                                NA                         1.65          J            0.63            J           1.59            J           119                         85                      4.92           J
                 Tributyltin                                  75.10                      2.15          J            2.09            J           5.47            J           115                         119                     0.49           J
                 Dibutyltin                                   53.50                                   ND            3.51            J           3.44            J           79                          98                      5.1            J
                 Monobutyltin                                 25.71                      1.39          J            1.23            1           2.68            J           41                          7 4                     3.85           J










                 MS    Matrix Spike
                 MSD Matrix Spike Duplicate
                 I     Analytical Interference
                 I     <MDL
                 Q     Rewv@ery Outside QC
                 ND    Non Detect
                 NA    Not Applicable
                       Samples mixed, see ease narmfive




 I
 I
 I
 I
 I
 I
 I
 I      I         Butyltin Data
 I                  (Sediment)
 I
 I
 I
 I
 I
 I
 I
 I
 1                       140
 1






                                                     Mussel Watch Project Year 9 - Butyltin Data (Sediment)





            Lab Sample                                 Sample    Dry Weight                       Concentration                                                         Page      Receive
     Site        ID        File No.     Matrix         Type           (g)       Wet Weight (g)         Basis        % solid    % Moisture % Lipid Organism            Number       Date


    FBFO       K8098       F8098F     SEDIMENT         SAMP           15.28          51.28             Dry           29.80        70.20         NA          NA        TBT 207     1/27/94
    FBFO       K8099       K8099F     SEDIMENT         SAMP           15.01          54.58             Dry           27.50        72.50         NA          NA        TBT 207     1/27/94
    FBFO       K8100       K810OF     SEDIMENT         SAMP           10.03          37.64             Dry           26.65        73.35         NA          NA        TBT 207     1/27/94
    FBJB       K8113       K8113F     SEDIMENT         SAMP           15.00          51.94             Dry           28.88        71.12         NA          NA        TBT 207     1/27/94
    FBJB       K8114       K8114F     SEDIMENT         SAMP           7.51           23.96             Dry           31.35        68.65         NA          NA        TBT 207     1/27/94
    FBJB       K8115       K8115F     SEDIMENT         SAMP           15.00          51.07             Dry           29.37        70.63         NA          NA        TBT 207     1/27/94






                                                      Mussel Watch Project Year 9 - Butyltin Data (Sediment)







             Lab Sample                                Sample      Extraction    Analysis              Tripropyltin %
      Site        ID        File No.     Matrix         Type         Date          Date       Units       recovery      Tetrabutyltin     TetrabutyltinQ     Tributyltin   TributyltinQ



     FBFO       K8098       F8098F    SEDIMENT         SAMP         10/11/94     10/17/94    ng Sn/g         90                                 ND              49.50
     FBFO       K8099       K8099F    SEDIMENT         SAMP         10/11/94     10/17/94    ng Sn/g         82                                 ND              52.50
     FBFO       K8100       K810OF    SEDIMENT         SAMP         10/11/94     10/17/94    ng Sn/g         86                                 ND              54.30
     FBJB       K8113       K8113F    SEDIMENT         SAMP         10/11/94     10/17/94    ng Sn/g         87                                 ND              53.80
     FBJB       K8114       K8 I 14F  SEDIMENT         SAMP         10/11/94     10/17/94    ng Sn/g         78                                 ND              51.40
     FBJB       K8115       K8115F    SEDIMENT         SAW          10/11/94     10/17/94    ng Sn/g         89                                 ND              59.30






                                                      Mussel Watch Project Year 9 - Butyltin Data (Sediment)







             Lab Sample                                Sample
     Site         ID       File No.      Matrix         Type      Dibutyltin    DibutyltinQ     Monobutyltin       MonobutyltinQ



    FBFO        K8098      F8098F     SEDIMENT         SAMP           5.30            J              0.40                 J
    FBFO        K8099      K8099F     SEDIMENT         SAMP           3.70            J              0.20                 J
    FBFO        K8100      K810OF     SEDIMENT         SAMP           4.70            J              0.60                 J
    FBJB        K8113      K8113F     SEDIMENT         SAMP           2.80            J              0.40                 J
    FBJB        K8114      K8114F     SEDIMENT         SAMP           1.90            J                                  ND
    FBJB        K8115      K8115F     SEDIMENT         SAMP           2.50            J              0.10                 J



 I
 I
 I
 I
 I
 I
 I
 I              Butyltin QC Data
 I                 (Sediment)
 I
 I
 I
 I
 I
 I
 I
II
: I
                        144
 1                        -




                                                                     wmmm on mmm M M M @ M M
                                                                 Mussel Watch Project Year 9 - Butyltin QC Data (Sediment)


                        Site                         FBIB                       FBJB                       FBJB                                                                     NRCC PACS- I                RANGE
                        Lab Sample ID                K8114                      Q1 1002                 Q11004                    Q11006                     Q11005                       Q 11003
                        File No.                     K8 144F                    Q1 1002                 Q 11004                   Q1 1006                    QIIO05                       Q 11003
                        Matrix                  SEDIMENT                   SEDIMENT                  SEDIMENT                   SEDIMENT                   SEDIMENT                  SEDIMENT


                        Sample Type                  SAMP                       DUP                        MS                        LBS                     BLANK                        SRM


                        Dry Weight (9)               TSI                        7.50                       7.50                      1.00                       12.19                     0.30


                        Wet Weight (g)               23.96                      23.92                      23.92                     NA                         NA                        0.30
                        Concentration
                        Basis                        Dry                        Dry                        Dry                       Dry                        Dry                       Dry
                        % solid                      31.35                      31.35                      31.35                     NA                         NA                        100.00
                        % Moisture                   68.65                      68.65                      68.65                     NA                         NA                        0.00
                        % Lipid                      NA                         NA                         NA                        NA                         NA                        NA
                        Organism                     NA                         NA                         NA                        NA                         NA                        NA


                        Page Number                  TBT 207                    TBT 207                 TBT 207                   TBT 207                    TBT 207                      TBT 207
                        Receive Date                 1/27/94                    1/27/94                 1/27/94                      NA                         NA                        NA


                        Extraction Date              10/11194                   10/11/94                10/11/94                  10111194                   10/11/94                     10/11/94
                        Analysis Date                10/17/94                   10/17/94                10/17/94                  tO/17/94                   10/17/94                     10/17/94
                        Units                        ng Sn/g                    ng Sn/g                    %                         %                       ng Sn/g                      ng Sn1g


                        Tripropyltin %
                        recovery                     78                         81                         92                        82                         85                        89


                        Tetrabutyltin                             ND                        ND             109                       101                                    ND                         ND         NA
                        Tributyltin                  51.4                       49.3                       88                        99                                     ND            1234                 1050-1490
                        Dibutyltin                   1.9                        1.8                        94                        96                                     ND            1028.6               980-1340
                        Monobutyltin                              ND                        ND             56                        84                                     ND            240.1                 110-450



 I
 I
 I
 I
 I
 I
 I
 I              Method Detection
 I                    Limits
 'I
 I
 I
 I
 I
 I
 I
 I
 1
                         146
 1



    I
    I
    I
    . I
    I
    I
    I
    II                                   PAH
    I                 Method Detection Limits
    I
    I
    I
I I
    I
    I
.   I
,-: I
.   1
                                              147                          1
    I







                           Mussel Watch Project Year 9 - Method Detection Limits PAH

                                                              Sediments Tissues
                         Sample Weight (g)                         15.0         1.0
                         Final Voltune, (ml)                       1.00         1.00
                         Units                                  ng/g Dry ng/g Dry
                         ,Compound
                         NAPHTHALENE                               1.1          6.2
                         Cl-NAPHTHALENES                           2.3          19.6
                         C2-NAPHTHALENES                           1.2          17.3
                         C3- & C4-NAPHTHALENES                     1.3          24.8
                         BIPHENYL                                  0.4          .9.2
                         ACENAPHTHYLENE,                           0.5,         7.3
                         ACENAPHTHENE                              0.6          8.5
                         FLUORENE,                                 0.6          9.3
                         Cl- to O-FLUORENES                        1.2          18.6
                         PHENANTHRENE                              0.6          3.5
                         ANTHRACENE                                0.5          2.3
                         C 1 - to C4-PHENANTHRENES
                              & ANTHRACENES                        1.1          29.9
                         DIBENZOTHIOPHENE                          0.5          2.2
                         Cl- tO C3-DIBENZOTHIOPH                   1.0          4.4
                         FLUORANTHENE                              0.3          4.2
                         PYRENE                                    0.4          4.4
                         C I -FLUORANTHENES &
                              & PYRENES                            0.7          8.7
                         BENaANTHRACENE                            0.4          5.1
                         CHRYSENE                                  0.3          11.1
                         C I - to C4-CHRYSENES                     0.7          22.1
                         BENbFLUORANTHENE                          0.3          4.0
                         BENkFLUORANTHENE                          0.3          4.0
                         BENePYRENE                                0.2          2.5
                         BENaPYRENE                                0.3          4.9
                         PERYLENE                                  2.7          4.8
                         I123cdPYRENE                              0.3          5.6
                         DBahANTHRACENE                            0.4          2.8
                         BghiPERYLENE                              0.3          3.0


                         2-METHYLNAPHTHALENE                       1.2          10.5
                         I-METHYLNAPHTHALENE                       1.1          9.0
                         2,6-DIMETHNAPHTHALENE                     0.6          8.7
                         1,6,7-TRIMETHNAPH                         0.7          12.4
                         I-METHYLPHENANTHREN                       0.5          14.9



                                                                      148




 I
 I
 I
 I
 I
 I
 I
.I           Pesticides and PCBs
 I         Method Detection Limits
 I
 I
 I
 I
 I
 I
 I
 I
 1
                      149
 1                           -.






                  Mussel Watch Project Year 9 - Method Detection Limits Pesticide and PCBs


                                                    SEDIMENTS                                                   TISSUES
                                           NML                           MDL                           MDL                           MDL
              Dry Weight (g)               14.58                                                       1.37
              Wet Weight (g)                                             29.35                                                       15.20
              Concentration Basis          Dry                           Wet                           Dry                           Wet
             Pnits                         ng/g                          ng/g                          ng/g                          ng/g

              Alpha BHC                    0.09                          0.05                          0.34                          0.03
              HCB                          0.05                          0.03                          0.40                          0.04
              Beta BHC                     0.03                          0.02                          0.17                          0.02
              Gamma BHC                    0.04                          0.02                          0.25                          0.02
              Delta BHC                    0.17                          0.09                          0.89                          0.08
              Hepta Chlor                  0.19                          0.09                          0.53                          0.05
              Hepta Epoxide                0.32                          0.16                          0.09                          0.01
              Oxychlordane                 0.18                          0.09                          0.85                          0.08
              Gamma Chlordane              0.05                          0.02                          0.29                          0.03
              Alpha Chlordane              0.04                          0.02                          0.49                          0.04
              Trans-Nonachlor              0.04                          0.02                          0.25                          0.02
              Cis-Nonachlor                0.03                          0.01                          0.29                          0.03
              Aldrin                       0.04                          0.02                          0.41                          0.04
              Dieldrin                     0.42                          0.21                          1.02                          0.09
              Endrin                       NA                            NA                            1.01                          0.09
              Mirex                        0.04                          0.02                          0.28                          0.02
              2,4'DDE                      0,05                          0.02                          0.44                          0.04
              4,4'DDE                      0.06                          0.03                          0.92                          0.08
              2,4'DDD                      0.04                          0.02                          0.17                          0.02
              4,4'DDD                      0,11                          0.05                          0.28                          0.03
              2,4'DDT                      0.33                          0.16                          0.31                          0.03
              4,4'DDT                      0.08                          0.04                          0.83                          0.07
              Endosulfan 11                0*01                          0.04                          0.83                          0.08


              PC138                        0.14                          0.07                          1.40                          0.13
              PCB18                        0.07                          0.04                          1.08.                         0.10
              PCB28                        0.06                          0.03                          0.75                          0.07
              PCB52                        0.07                          0.04                          1.00                          0.09
              PCB44                        0.08                          0.04                          0.62                          0.06
              PCB66                        0.10                          0.05                          0.65                          0.06
              PCB101                       0.09                          0.05                          0.47                          0.04
              PCBl 18/108                  0.32                          0.16                          1.31                          0.12
              PCB153                       0.15                          0.08                          2.61                          0.24
              PCB105                       0.17                          0.09                          1.18                          0.11
              PCB138                       0.17                          0.08                          1.02                          0.09
              PCB187/182/159               0.11                          0.05                          0.38                          0.03
              PCB128                       0.22                          0.11                          0.62                          0.06
              PCB180                       0.09                          0.05                          0.76                          0.07
              PCB170                       0.12                          0.06                          2.35                          0.21
              PCB195                       0.11                          0.06                          0.82                          0 * 07
              PCB206                       0.13                          0.06                          0.48                          0.04
              PCB209                       0.22                          0.11                          1.10                          0.10




                                                                                 150




 I
 I
 I
 I
 I
 I
 I
 I               Trace Metal
 I         Method Detection Limits
 I
 I
 I
 I
 I
 I
 I
 I
 1
                      151
 I





                                                                   Mussel Watch Project Year 9
                                                    Method Detection Limits - Trace Metals (ppm)




                              Ag       At      As       Ba         Cd          Cr       CU         Hg       Fe      Ni         Pb        Sb     Se      Sn      v      Zn


            Sediment:        0.026    444      0.29      5        0.008       0.11     0.44      0.0075    40.5    0.72       0.35      0.4    0.17    0.11     2      2.2


            Tissue:          0.035             0.17      5        0.008       0.12     0.25       0.034     12.8   0.17       0.12             0.49    0.19     2      1.9




 I
 I
 I
 I
 I
 I
 I                    I
,I                Butyltin
 I        Method Detection Limits
 I
 I
 I
 I
 I
 I
 I
 I
 1
                      153
 1






                                         Mussel Watch Project Year 9 - Method Detection Limits Butyltin








                                         Matrix      Dry Weight (g)      Units     Tetrabutyltin     Tributyltin     Dibutyltin     Monobutyltin



                                       SEDIMENT           15.00          ng/g          1.00              1.00           1.00            1.00


                                        TISSUE             3.63          ng/g          4.69             5.53            5.56            6.45

































                                                                                                      DATE DUE


















                                                                                 GAYLOFIDINo. 2333                                   PRINTED IN U,S.A.

















                                                                                              3 6668 14106 7407